Chemistry 16 Comprehensive Samplex for Long Exam 2 September 7, 2012 Answer Key For Non-Problem Solving

Instructions: Answer as many items as you can. Read each question carefully and answer honestly. All information you need is in this paper. Good luck!

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MULTIPLE CHOICE. Choose the letter corresponding to the best answer. D. Same subshell and orbitals but Which of the following set of quantum different shells numbers is possible? A. n=1, l=0, ml=1, ms=1/2 3. For systems with positive changes in B. n=5, l=3, ml=-2, ms=-1/2 enthalpy and entropy, processes become C. n=2, l=1, ml=0, ms=0 spontaneous at __ D. None of these A. All temperatures Two electrons in the same atom which have B. Low C. High identical values of quantum numbers l and ml are said to be in ___ D. Absolute zero A. The same shell and subshell but in 4. Which of the following is a polar molecule? different orbitals A. RbCl B. Same shell but different subshells and B. BF3 orbitals C. CCl4 D. PCl3 C. Same shell, subshell and orbitals

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Which of the following is false about the structure of thiocyanate ion? A. The C-N bond is a double bond. B. There are no lone pairs on C. C. There is a lone pair of electrons on N. D. The C-H bond is a single bond. Of the following, which is a state function? A. H B. q C. w D. All of the above The shorter the internuclear distance between two bonded atoms, the A. Less energy needed to break the bond B. Less multiple bonding character there is C. More resonance D. More energy needed to break the bond Which of the following is an unstable species and is bound not to exist? A. H2 B. He2+ C. Be2+ D. Be2 Which of the following pairs have similar molecular geometry? A. CH3+, CH3B. PF5, ClF5 C. H2O, NH2D. None of these Which of the following ions has the largest atomic radius? A. Na+ B. Mg+ C. O2D. FWhich of the following atoms has the largest first ionization energy? A. Rb B. Sr C. Al D. All have same magnitude of energy. What is the correct electronic configuration for a nickel atom? A. 1s22s22p64s23d23d23d23d13d1 B. 1s22s22p6 3s2 3p6 4s2 4p63d13d1 C. 1s22s22p63s23p63d10

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D. none of these The Lewis structure for calcium hydride is A. [H:]-[Ca]2+[H:]B. [H:]-[Ca] + C. H-Ca-H D. Ca-H Which of the following is best represented by a set of resonance structures? A. Ammonium B. Methane C. Oxygen difluoride D. Sulfur dioxide What is the formal charge on N in nitrate ion? A. 2 B. 2C. 1 D. 1If there is a negative change in the Gibbs energy, then the reaction is said to be ___. A. Reversible B. Spontaneous C. Exothermic D. Endothermic In the experiment on Corrosion, the portion of the nail that was oxidized was ___ in color and acted as the __. A. White, anode B. Pink, anode C. Blue green, cathode D. Blue green, anode In the experiment on Corrosion, zinc acted as the __ while the nail is the __ A. Protected Anode; Sacrificial Cathode B. Protected Cathode; Sacrificial Anode C. Sacrificial Cathode; Protected Anode D. Sacrificial Anode; Protected Cathode Which of the following reactions is nonspontaneous? A. Neutralization of NaOH and HCl B. Freezing water in room temperature C. Combustion of octane fuel D. None of the above Which of the following statements is false? A. Ferrous hydroxide is formed by adding soluble Fe3+ sample to NaOH or NH3.

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B. Calcium will not precipitate to limiting and excess ammonia. C. A Prussian blue precipitate will form when Fe2+ is added to potassium ferricyanide. D. The formula of the brown ring in the nitrate test is [Fe(NO)]2+. 21. Which of the following ionic compounds has the highest entropy? A. Calcium chloride B. Magnesium arsenate C. Sodium oxalate D. Tin(IV) oxide For numbers 22-26, refer to the structure of capsaicin below:

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The EGG, MGG, and hybridization of O1 is: A. Tetrahedral; angular; sp2 B. Trigonal planar; trigonal pyramidal; sp3 C. Tetrahedral; angular; sp3 D. Trigonal planar; angular; sp2 The difference/s between C2 and C5 is: A. Their EGG and hybridization B. Their MGG and hybridization C. Their EGG and MGG D. Their EGG, MGG, and hybridization How many and bonds are in capsaicin? A. 43 ; 5 B. 42 ; 4 C. 42 ; 5 D. 43 ; 4 What is the hybridization overlap in O4? A. sp2 sp3 B. sp3 sp2 C. sp2 sp2 D. sp3 sp3 The formal charge of N3 is __ and the hybridization overlap in C N3 C is __. A. 0; sp2-sp3-sp2 B. 0; sp3-sp3-sp2 C. +1; sp3-sp3-sp2 D. +1; sp2-sp3-sp2 Which of the following is true?

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A. Manganese(II) cations are dominant in basic medium. B. When organic chlorine and iodine are combined in a toluene-water mixture, there will be no visible reaction. C. A more acidic medium promotes corrosion of metals. D. Zinc, Nickel, and Cobalt can act as sacrificial anodes for Iron. What is the net heat change if 25.0 mL of 3.78 M hydrochloric acid is neutralized by 50.0 mL of 1.90 M potassium hydroxide? A. -5.27 kJ B. 5.27 kJ C. 5.30 kJ D. -5.30 kJ What is the De Broglie wavelength and frequency of a photon with mass 1.0810-24 nanograms? A. 2.0510-7 m; 1.471014 s-1 B. 2.0510-6 m; 1.471015 s-1 C. 2.0510-6 m; 1.471014 s-1 D. 2.0510-7 m; 1.471015 s-1 If the uncertainty for a velocity of a photon is 3.1410-15 m/s, given that the mass of the photon is 7.0910-9 kg, what is the uncertainty of the position of the photon? A. 2.3710-12 m B. 2.6310-12 m C. 2.8610-12 m D. 2.4510-12 m Nitrogen gas and Hydrogen gas react to form ammonia gas. Given that Hf of ammonia is -46.3 kJ, how many grams of ammonia are produced if 176.7 kJ of heat is released? A. 65.0 g B. 130.0 g C. 7.63 g D. 3.81 g Which ion/s can give an interfering false ring for nitrate test? A. Thiocyanate only B. Ammonium and thiocyanate C. Thiocyanate, Bromide, Iodide D. Sulfate, Bromide, Thiocyanate

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II.

MODIFIED TRUE OR FALSE. Write TRUE if the statement is true. Otherwise, determine what part of the statement made it false and offer corrections. 1. In the ozone layer, O3(g) absorbs harmful UV radiation and forms oxygen gas and gaseous oxygen atom. The entropy change for this process is equal to zero More moles are produced in the process, therefore entropy change is positive. 2. The 4f orbitals can accommodate a maximum of 10 e- 14e-. 3. Hesss Law is a consequence of the first law of thermodynamics. TRUE 4. On a humid day, we can observe water vapor to condense along the outer wall of cold drink bottles. The formation of the vapor is an endothermic process. TRUE 5. The form of carbon with a Ho formation value of zero is diamond graphite, not diamond. 6. The azimuthal principal quantum number tells us how far from the nucleus an electron is. 7. The oxidation state assigned to P in the phosphate ion is +5. TRUE 8. In the aluminum atom, the outermost electron has the quantum numbers n=3, l=1, ml=1 -1, not 1, and ms=+1/2. 9. qsoln is still part of qcal even if the volumes of the solution used for calibration and calculation are not constant constant. 10. XeO2F2 has a trigonal bipyramidal electron group geometry, and a square pyramidal seesaw molecular group geometry. 11. Naphthalene, C10H8, is made up of two benzene rings stacked or glued together. The number of dominant resonance structures of naphthalene is two three. 12. The order of hydrohalidic acids ionic character in increasing order is: I < Br < Cl < F F < Cl < Br < I. 13. Prussian blue precipitate from potassium ferricyanide ferrocyanide indicates the presence of Fe3+ ions, while from potassium ferrocyanide ferricyanide indicates the presence of Fe2+ ions. 14. The net dipole moment of water explains sodium chlorides miscibility in it. TRUE 15. In excess ammonia, Zn2+ will form a colorless complex [Zn(NH3)2]2+ [Zn(NH3)4]2+, while in excess NaOH, Zn2+ will form a colorless complex [Zn(OH)4]2-. 16. Nitrate ion does not exhibit exhibit pi bond delocalization. 17. Adding potassium ferricyanide to Zn2+ will form yellow precipitate KZn[Fe(CN)6], while adding potassium ferrocyanide will form white precipitate KZn3[Fe(CN)6] K2Zn3[Fe(CN)6]. 18. There will be an exothermic change in heat if the system gives off heat to the surroundings, and the surroundings does work to the system system does work to the surroundings. 19. An exothermic reaction from low entropy to high entropy will only proceed at high temperatures at any temperature. 20. If a reaction is endothermic from high entropy to low entropy, the reverse reaction is non-spontaneous spontaneous. CAUSE AND EFFECT. Determine the effect of the cause stated in the first column on the parameter in the second assuming all other variables are held constant.

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Effects: Increase, Decrease, No Effect Cause 1. Actual molarity of the acid is greater than the recorded value. 2. The cylinder used for measuring the base solution was wet. 3. The student pulled the thermometer out of the set-up to take temperature readings. 4|DLRC Chem 16 LE2 Samplex

Parameter

Effect No Effect

Magnitude of calculated H

Decrease Decrease

4. There is a tiny hole in the cork, exposing the inside of the calorimeter. 5. Actual molarity of the base is greater than the recorded value.

Magnitude of calculated Ccal

Decrease Decrease

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Effects: Becomes present, Becomes absent, No Effect (stays the same) Cause Parameter Mossy Zinc and Aluminum metal were accidentally coiled together with iron Corroded Zinc nail. Gelatin mixture was accidentally Appearance of Prussian blue added with concentrated NaOH (after 1 day) KMnO4 was accidentally added in Persistence of Pink Color excess. Litmus paper was accidentally dipped into unknown solution with NaOH. Indication of gaseous ammonia Dissolution to deep blue complex Pink-red toluene layer Yellow toluene layer

Effect Absent Absent Present No Effect (blue litmus paper will be seen either way, but the validity of the test will be absent) No Effect Present Absent

10. Copper(II) nitrate was added with NaOH, then with excess ammonia. 11. Bromide sample was accidentally contaminated with iodide sample for KMnO4 elimination test.

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