Steam engineering principles and heat transfer

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Engineering Units
An overview of the units of measurement used in the Steam and Condensate Loop including temperature, pressure, density, volume, heat, work and energy. Use the quick links below to take you to the main sections of this tutorial:

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Contact Us Throughout the engineering industries, many different definitions and units have been proposed and used for mechanical and thermal properties. The problems this caused led to the development of an agreed international system of units (or SI units: Systme International d'Units). In the SI system there are seven well-defined base units from which the units of other properties can be derived, and these will be used throughout the Steam Engineering Tutorials. The SI base units include length (in metres), mass (in kilograms), time (in seconds) and temperature (in kelvin). The first three will hopefully need no further explanation, while the latter will be discussed in more detail later. The other SI base units are electric current (in amperes), amount of substance (in moles) and luminous intensity (in candela). These may be familiar to readers with a background in electronics, chemistry and physics respectively, but have little relevance to steam engineering nor the contents of these tutorials. Table 2.1.1 shows the derived units that are relevant to this subject, all of which should be familiar to those with any general engineering background. Some of these quantities have been assigned special names after famous pioneers in the development of science and engineering.

Table 2.1.1 Named quantities in derived SI units There are many other quantities that have been derived from SI base units, which will also be of significance to anyone involved in steam engineering. These are provided in Table 2.1.2.

Table 2.1.2 Other quantities in derived SI units

Dot notation
This convention is used to identify a compound unit incorporating rate, for example: m = Mass (e.g. kg) = Mass flow per time unit (e.g. kg/h) = Mass flowrate

Multiples and submultiples

Table 2.1.3 gives the SI prefixes that are used to form decimal multiples and submultiples of SI units. They allow very large or very small numerical values to be avoided. A prefix attaches directly to the name of a unit, and a prefix symbol attaches directly to the symbol for a unit. In summary: one thousand metres may be shown as 1 km, 1000 m or 10 m.

Table 2.1.3 Multiples and submultiples used with SI units

Special abbreviations used in steam flowmetering applications

For historical reasons, International Standard ISO 5167 (supersedes BS 1042) which refers to flowmetering, use the following abbreviations in Table 2.1.4.

Table 2.1.4 Symbols used in flowmetering applications

STP - Standard temperature and pressure

These are the standard conditions for measurement of the properties of matter. The standard temperature is the freezing point of pure water, 0C or 273.16K. The standard pressure is the pressure exerted by a column of mercury (symbol Hg) 760 mm high, often designat ed 760 mm Hg. This pressure is also called one atmosphere and is equal to 1.01325 x 10 6 dynes per square centimetre, or approximately 14.7 lb per square inch. The density (mass per volume) of a gas is usually reported as its value at STP. Properties that cannot be measured at STP are measured under other conditions; usually the values obtained are then mathematically extrapolated to their values at STP.

Symbols
Table 2.1.5 shows the symbols and typical units used in the Steam Engineering Tutorials.

Table 2.1.5 Symbols and units of measure used in the Steam Engineering Tutorials

Subscripts used with properties

When using enthalpy, entropy and internal energy, subscripts as shown below are used to identify the phase, for example: Subscript f = Fluid or liquid state, for example hf: liquid enthalpy Subscript fg = Change of state liquid to gas, for example hfg: enthalpy of evaporation Subscript g = Total, for example hg: total enthalpy Note that, by convention, the total heat in superheated steam is signified by h. It is also usual, by convention, to signify sample quantities in capital letters, whilst unit quantities are signified in lower case letters. For example: Total enthalpy in a sample of superheated steam - H kJ Specific enthalpy of superheated steam - h kJ/kg Top

Temperature
The temperature scale is used as an indicator of thermal equilibrium, in the sense that any two systems in contact with each other with the same value are in thermal equilibrium.

The Celsius (C) scale

This is the scale most commonly used by the engineer, as it has a convenient (but arbitrary) zero temperature, corresponding to the temperature at which water will freeze.

The absolute or K (kelvin) scale

This scale has the same increments as the Celsius scale, but has a zero corresponding to the minimum possible temperature when all molecular and atomic motion has ceased. This temperature is often referred to as absolute zero (0 K) and is equivalent to -273.16C. The two scales of temperature are interchangeable, as shown in Figure 2.1.1 and expressed in Equation 2.1.1.

Fig. 2.1.1 Comparison of kelvin and Celsius temperatures Equation 2.1.1 The SI unit of temperature is the kelvin, which is defined as 1 273.16 of the thermodynamic temperature of pure water at its triple point (0C). An explanation of triple point is given in Tutorial 2.2. Most thermodynamic equations require the temperature to be expressed in kelvin. However, temperature difference, as used in many heat transfer calculations, may be expressed in either C or K. Since both scales have the same increments, a temperature difference of 1C has the same value as a temperature difference of 1 K. Top

Pressure
The SI unit of pressure is the pascal (Pa), defined as 1 newton of force per square metre (1 N/m). As Pa is such a small unit the kPa (1 kilonewton/m) or MPa (1 Meganewton/m) tend to be more appropriate to steam engineering. However, probably the most commonly used metric unit for pressure measurement in steam engineering is the bar. This is equal to 105 N/m, and approximates to 1 atmosphere. This unit is used throughout these tutorials. Other units often used include lb/in (psi), kg/cm, atm, in H 2O and mm Hg. Conversion factors are readily available from many sources.

Fig. 2.1.2 Comparison of absolute and gauge pressures

Absolute pressure (bar a)

This is the pressure measured from the datum of a perfect vacuum i.e. a perfect vacuum has a pressure of 0 bar a.

Gauge pressure (bar g)

This is the pressure measured from the datum of the atmospheric pressure. Although in reality the atmospheric pressure will depend upon the climate and the height above sea level, a generally accepted value of 1.013 25 bar a (1 atm) is often used. This is the average pressure exerted by the air of the earth's atmosphere at sea level. Gauge pressure = Absolute pressure - Atmospheric pressure Pressures above atmospheric will always yield a positive gauge pressure. Conversely a vacuum or negative pressure is the pressure below that of the atmosphere. A pressure of -1 bar g corresponds closely to a perfect vacuum.

Differential pressure
This is simply the difference between two pressures. When specifying a differential pressure, it is not necessary to use the suffixes 'g' or 'a' to denote either gauge pressure or absolute pressure respectively, as the pressure datum point becomes irrelevant. Therefore, the difference between two pressures will have the same value whether these pressures are measured in gauge pressure or absolute pressure, as long as the two pressures are measured from the same datum.

Density and specific volume

The density of a substance can be defined as its mass (m) per unit volume (V). The specific volume (vg) is the volume per unit mass and is therefore the inverse of density. In fact, the term 'specific' is generally used to denote a property of a unit mass of a substance (see Equation 2.1.2).

Equation 2.1.2 Where:

= Density(kg/m) m = Mass (kg) V = Volume(m) vg = Specific volume (m/kg)

The SI units of density () are kg/m, whilst conversely the units of specific volume (v g) are m/kg. Another term used as a measure of density is specific gravity. It is a ratio of the density of a substance (s) and the density of pure water (w) at standard temperature and pressure (STP). This reference condition is usually defined as being at atmospheric pressure and 0C. Sometimes it is said to be at 20C or 25C and is referred to as normal temperature and pressure (NTP).

Equation 2.1.3 The density of water at these conditions is approximately 1 000 kg/m. Therefore substances with a density greater than this value will have a specific gravity greater than 1, whereas substances with a density less than this will have a specific gravity of less than 1. Since specific gravity is a ratio of two densities, it is a dimensionless variable and has no units. Therefore in this case the term specific does not indicate it is a property of a unit mass of a substance. The specific gravity is also sometimes known as the relative density of a substance. Top

Heat, work and energy

Energy is sometimes described as the ability to do work. The transfer of energy by means of mechanical motion is called work. The SI unit for work and energy is the joule, defined as 1 N m. The amount of mechanical work done can be determined by an equation derived from Newtonian mechanics: Work = Force x Displacement It can also be described as the product of the applied pressure and the displaced volume: Work = Applied pressure x Displaced volume

Example 2.1.1
An applied pressure of 1 Pa (or 1 N/m) displaces a volume of 1 m. How much work has been done ? Work done = 1 N/m x 1 m = 1 N m (or 1 J) The benefits of using SI units, as in the above example, is that the units in the equation actually cancel out to give the units of the product. The experimental observations of J. P. Joule established that there is an equivalence between mechanical energy (or work) and heat. He found that the same amount of energy was required to produce the same temperature rise in a specific mass of water, regardless of whether the energy was supplied as heat or work. The total energy of a system is composed of the internal, potential and kinetic energy. The temperature of a substance is directly related to its internal energy (ug). The internal energy is associated with the motion, interaction and bonding of the molecules within a substance. The external energy of a substance is associated with its velocity and location, and is the sum of its potential and kinetic energy. The transfer of energy as a result of the difference in temperature alone is referred to as heat flow. The watt, which is the SI unit of power, can be defined as 1 J/s of heat flow. Other units used to quantify heat energy are the British Thermal Unit (Btu: the amount of heat to raise 1 lb of water by 1F) and the kilocalorie (the amount of heat to raise 1 kg of water by 1C). Conversion factors are readily available from numerous sources.

Specific enthalpy
This is the term given to the total energy, due to both pressure and temperature, of a fluid (such as water or steam) at any given time and condition. More specifically it is the sum of the internal energy and the work done by an applied pressure (as in Example 2.1.1). The basic unit of measurement is the joule (J). Since one joule represents a very small amount of energy, it is usual to use kilojoules (kJ) (1 000 Joules). The specific enthalpy is a measure of the total energy of a unit mass, and its units are usually kJ/kg.

Specific heat capacity

The enthalpy of a fluid is a function of its temperature and pressure. The temperature dependence of the enthalpy can be found by measuring the rise in temperature caused by the flow of heat at constant pressure. The constant-pressure heat capacity cp, is a measure of the change in enthalpy at a particular temperature. Similarly, the internal energy is a function of temperature and specific volume. The constant-volume heat capacity cv, is a measure of the change in internal energy at a particular temperature and constant volume. Because the specific volumes of solids and liquids are generally smaller, then unless the pressure is extremely high, the work done by an applied pressure can be neglected. Therefore, if the enthalpy can be represented by the internal energy component alone, the constant-volume and constant-pressure heat capacities can be said to be equal. Therefore for, solids and liquids: cp cv

Another simplification for solids and liquids assumes that they are incompressible, so that their volume is only a function of temperature. This implies that for incompressible fluids the enthalpy and the heat capacity are also only functions of temperature. The specific heat capacity represents the amount of energy required to raise 1 kg by 1C, and can be thought of as the abilit y of a substance to absorb heat. Therefore the SI units of specific heat capacity are kJ/kg K (kJ/kg C). Water has a very large specific heat capacity (4.19 kJ/kg C) compared with many fluids, which is why both water and steam are considered to be good carriers of heat. The amount of heat energy required to raise the temperature of a substance can be determined from Equation 2.1.4.

Equation 2.1.4 Where:

Q = Quantity of energy (kJ) m = Mass of the substance(kg) cp = Specific heat capacity of the substance (kJ/kgC) T = Temperature rise of the substance (C)
This equation shows that for a given mass of substance, the temperature rise is linearly related to the amount of heat provided, assuming that the specific heat capacity is constant over that temperature range.

Example 2.1.2
Consider a quantity of water with a volume of 2 litres, which is raised from a temperature of 20C to 70C. At atmospheric pressure, the density of water is approximately 1 000 kg/m. As there are 1 000 litres in 1 m, then the densi ty can be expressed as 1 kg per litre (1 kg/l). Therefore the mass of the water is 2 kg. The specific heat capacity for water can be taken as 4.19 kJ/kg C over low ranges of temperature. Therefore: Q = 2 kg x 4.19 kJ/kg C x (70 - 20)C = 419 kJ If the water was then cooled to its original temperature of 20C, it would also provide this amount of energy in the cooling application.

Entropy (S)
Entropy is a measure of the degree of disorder within a system. The greater the degree of disorder, the higher the entropy. The SI units of entropy are kJ/kg K (kJ/kg C). In a solid, the molecules of a substance arrange themselves in an orderly structure. As the substance changes from a solid to a liquid, or from a liquid to a gas, the arrangement of the molecules becomes more disordered as they begin to move more freely. For any given substance the entropy in the gas phase is greater than that of the liquid phase, and the entropy in the liquid phase is more than in the solid phase. One characteristic of all natural or spontaneous processes is that they proceed towards a state of equilibrium. This can be seen in the second law of thermodynamics, which states that heat cannot pass from a colder to a warmer body. A change in the entropy of a system is caused by a change in its heat content, where the change of entropy is equal to the heat change divided by the average absolute temperature, Equation 2.1.5.

Equation 2.1.5 When unit mass calculations are made, the symbols for entropy and enthalpy are written in lower case, Equation 2.1.6.

Equation 2.1.6 To look at this in further detail, consider the following examples:

Example 2.1.3
A process raises 1 kg of water from 0 to 100C (273 to 373 K) under atmospheric conditions.

Specific enthalpy at 0C (hf) = 0 kJ/kg (from steam tables) Specific enthalpy of water at 100C (hf) = 419 kJ/kg (from steam tables)
Calculate the change in specific entropy Since this is a change in specific entropy of water, the symbol 's' in Equation 2.1.6 takes the suffix 'f' to become sf.

Example 2.1.4
A process changes 1 kg of water at 100C (373 K) to saturated steam at 100C (373 K) under atmospheric conditions. Calculate the change in specific entropy of evaporation Since this is the entropy involved in the change of state, the symbol 's' in Equation 2.1.6 takes the suffix 'fg' to become sfg.

Specific enthalpy of evaporation of steam at 100C (373 K) (hfg) = 2 258 kJ/kg (from steam tables) Specific enthalpy of evaporation of water at 100C (373 K) (hfg) = 0 kJ/kg (from steam tables)

The total change in specific entropy from water at 0C to saturated steam at 100C is the sum of the change in specific entropy for the water, plus the change of specific entropy for the steam, and takes the suffix 'g' to become the total change in specific entropy sg.

Example 2.1.5
A process superheats 1 kg of saturated steam at atmospheric pressure to 150C (423 K). Determine the change in entropy.

Equation 2.1.6

As the entropy of saturated water is measured from a datum of 0.01C, the entropy of water at 0C can, for practical purposes, be taken as zero. The total change in specific entropy in this example is based on an initial water temperature of 0C, and therefore the final result happens to be very much the same as the specific entropy of steam that would be observed in steam tables at the final condition of steam at atmospheric pressure and 150C. Entropy is discussed in greater detail in Tutorial 2.15, Entropy - A Basic Understanding, and in Tutorial 2.16, Entropy - Its Practical Use.

What is Steam?
The properties of steam explained here, including the ability of steam under pressure to carry, and then give up, large amounts of energy. Topics include saturated steam tables, dryness fraction and flash steam. Use the quick links below to take you to the main sections of this tutorial:

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Contact Us A better understanding of the properties of steam may be achieved by understanding the general molecular and atomic structure of matter, and applying this knowledge to ice, water and steam. A molecule is the smallest amount of any element or compound substance still possessing all the chemical properties of that substance which can exist. Molecules themselves are made up of even smaller particles called atoms, which define the basic elements such as hydrogen and oxygen.

The specific combinations of these atomic elements provide compound substances. One such compound is represented by the chemical formula H2O, having molecules made up of two atoms of hydrogen and one atom of oxygen. The reason water is so plentiful on the earth is because hydrogen and oxygen are amongst the most abundant elements in the universe. Carbon is another element of significant abundance, and is a key component in all organic matter. Most mineral substances can exist in the three physical states (solid, liquid and vapour) which are referred to as phases. In the case of H2O, the terms ice, water and steam are used to denote the three phases respectively. The molecular arrangement of ice, water, and steam is still not fully understood, but it is convenient to consider the molecules as bonded together by electrical charges (referred to as the hydrogen bond). The degree of excitation of the molecules determines the physical state (or phase) of the substance. Top

Triple point
All the three phases of a particular substance can only coexist in equilibrium at a certain temperature and pressure, and this is known as its triple point. The triple point of H2O, where the three phases of ice, water and steam are in equilibrium, occurs at a temperature of 273.16 K and an absolute pressure of 0.006 112 bar. This pressure is very close to a perfect vacuum. If the pressure is reduced further at this temperature, the ice, instead of melting, sublimates directly into steam. Top

Ice
In ice, the molecules are locked together in an orderly lattice type structure and can only vibrate. In the solid phase, the movement of molecules in the lattice is a vibration about a mean bonded position where the molecules are less than one molecular diameter apart. The continued addition of heat causes the vibration to increase to such an extent that some molecules will eventually break away from their neighbours, and the solid starts to melt to a liquid state. At atmospheric pressure, melting occurs at 0C. Changes in pressure have very little effect on the melting temperature, and for most practical purposes, 0C can be taken as the melting point. However, it has been shown that the melting point of ice falls by 0.0072C for each additional atmosphere of pressure. for example, a pressure of 13.9 bar g woul d be needed to reduce the melting temperature by 0.1C. Heat that breaks the lattice bonds to produce the phase change while not increasing the temperature of the ice, is referred to as enthalpy of melting or heat of fusion. This phase change phenomenon is reversible when freezing occurs with the same amount of heat being released back to the surroundings. For most substances, the density decreases as it changes from the solid to the liquid phase. However, H2O is an exception to this rule as its density increases upon melting, which is why ice floats on water. Top

Water
In the liquid phase, the molecules are free to move, but are still less than one molecular diameter apart due to mutual attraction, and collisions occur frequently. More heat increases molecular agitation and collision, raising the temperature of the liquid up to its boiling temperature.

Enthalpy of water, liquid enthalpy or sensible heat (hf) of water

This is the heat energy required to raise the temperature of water from a datum point of 0C to its current temperature. At this reference state of 0C, the enthalpy of water has been arbitrarily set to zero. The enthalpy of all other states can then be identified, relative to this easily accessible reference state. Sensible heat was the term once used, because the heat added to the water produced a change in temperature. However, the accepted terms these days are liquid enthalpy or enthalpy of water. At atmospheric pressure (0 bar g), water boils at 100C, and 419 kJ of energy are required to heat 1 kg of water from 0C to its boiling temperature of 100C. It is from these figures that the value for the specific heat capacity of water (cp) of 4.19 kJ/kg C is derived for most calculations between 0C and 100C. Top

Steam
As the temperature increases and the water approaches its boiling condition, some molecules attain enough kinetic energy to reach velocities that allow them to momentarily escape from the liquid into the space above the surface, before falling back into the liquid. Further heating causes greater excitation and the number of molecules with enough energy to leave the liquid increases. As the water is heated to its boiling point, bubbles of steam form within it and rise to break through the surface. Considering the molecular arrangement of liquids and vapours, it is logical that the density of steam is much less than that of water, because the steam molecules are further apart from one another. The space immediately above the water surface thus becomes filled with less dense steam molecules. When the number of molecules leaving the liquid surface is more than those re-entering, the water freely evaporates. At this point it has reached boiling point or its saturation temperature, as it is saturated with heat energy. If the pressure remains constant, adding more heat does not cause the temperature to rise any further but causes the water to form saturated steam. The temperature of the boiling water and saturated steam within the same system is the same, but the heat energy per unit mass is much greater in the steam. At atmospheric pressure the saturation temperature is 100C. However, if the pressure is increased, this will allow the addition of more heat and an increase in temperature without a change of phase. Therefore, increasing the pressure effectively increases both the enthalpy of water, and the saturation temperature. The relationship between the saturation temperature and the pressure is known as the steam saturation curve (see Figure 2.2.1).

Fig. 2.2.1 Steam saturation curve Water and steam can coexist at any pressure on this curve, both being at the saturation temperature. Steam at a condition above the saturation curve is known as superheated steam:

Temperature above saturation temperature is called the degree of superheat of the steam. Water at a condition below the curve is called sub-saturated water.

If the steam is able to flow from the boiler at the same rate that it is produced, the addition of further heat simply increases the rate of production. If the steam is restrained from leaving the boiler, and the heat input rate is maintained, the energy flowing into the boiler will be greater than the energy flowing out. This excess energy raises the pressure, in turn allowing the saturation temperature to rise, as the temperature of saturated steam correlates to its pressure.

Enthalpy of evaporation or latent heat (hfg)

This is the amount of heat required to change the state of water at its boiling temperature, into steam. It involves no change in the temperature of the steam/water mixture, and all the energy is used to change the state from liquid (water) to vapour (saturated steam). The old term latent heat is based on the fact that although heat was added, there was no change in temperature. However, the accepted term is now enthalpy of evaporation. Like the phase change from ice to water, the process of evaporation is also reversible. The same amount of heat that produced the steam is released back to its surroundings during condensation, when steam meets any surface at a lower temperature. This may be considered as the useful portion of heat in the steam for heating purposes, as it is that portion of the total heat in the steam that is extracted when the steam condenses back to water.

Enthalpy of saturated steam, or total heat of saturated steam

This is the total energy in saturated steam, and is simply the sum of the enthalpy of water and the enthalpy of evaporation. Equation 2.2.1 Where:

hg = Total enthalpy of saturated steam (Total heat) (kJ/kg) hf = Liquid enthalpy (Sensible heat) (kJ/kg) hfg = Enthalpy of evaporation (Latent heat) (kJ/kg)
The enthalpy (and other properties) of saturated steam can easily be referenced using the tabulated results of previous experiments, known as steam tables. Top

The saturated steam tables

The steam tables list the properties of steam at varying pressures. They are the results of actual tests carried out on steam. Table 2.2.1 shows the properties of dry saturated steam at atmospheric pressure - 0 bar g.

Table 2.2.1 Properties of saturated steam at atmospheric pressure

Example 2.2.1
At atmospheric pressure (0 bar g), water boils at 100C, and 419 kJ of energy are required to heat 1 kg of water from 0C to its saturation temperature of 100C. Therefore the specific enthalpy of water at 0 bar g and 100C is 419 kJ/kg, as shown in the steam tables (see Table 2.2.2). Another 2 257 kJ of energy are required to evaporate 1 kg of water at 100C into 1 kg of steam at 100C. Therefore at 0 bar g the specific enthalpy of evaporation is 2 257 kJ/kg, as shown in the steam tables (see Table 2.2.2).

However, steam at atmospheric pressure is of a limited practical use. This is because it cannot be conveyed under its own pressure along a steam pipe to the point of use. Note: Because of the pressure/volume relationship of steam, (volume is reduced as pressure is increased) it is usually generated in the boiler at a pressure of at least 7 bar g. The generation of steam at higher pressures enables the steam distribution pipes to be kept to a reasonable size. As the steam pressure increases, the density of the steam will also increase. As the specific volume is inversely related to the density, the specific volume will decrease with increasing pressure. Figure 2.2.2 shows the relationship of specific volume to pressure. This highlights that the greatest change in specific volume occurs at lower pressures, whereas at the higher end of the pressure scale there is much less change in specific volume.

Fig. 2.2.2 Steam pressure/specific volume relationship The extract from the steam tables shown in Table 2.2.2 shows specific volume, and other data related to saturated steam. At 7 bar g, the saturation temperature of water is 170C. More heat energy is required to raise its temperature to saturation point at 7 bar g than would be needed if the water were at atmospheric pressure. The table gives a value of 721 kJ to raise 1 kg of water from 0C to its saturation temperature of 170C. The heat energy (enthalpy of evaporation) needed by the water at 7 bar g to change it into steam is actually less than the heat energy required at atmospheric pressure. This is because the specific enthalpy of evaporation decreases as the steam pressure increases. However, as the specific volume also decreases with increasing pressure, the amount of heat energy transferred in the same volume actually increases with steam pressure.

Table 2.2.2 Extract from the saturated steam tables Top

Dryness fraction
Steam with a temperature equal to the boiling point at that pressure is known as dry saturated steam. However, to produce 100% dry steam in an industrial boiler designed to produce saturated steam is rarely possible, and the steam will usually contain droplets of water. In practice, because of turbulence and splashing, as bubbles of steam break through the water surface, the steam space contains a mixture of water droplets and steam. Steam produced in any shell-type boiler (see Block 3), where the heat is supplied only to the water and where the steam remains in contact with the water surface, may typically contain around 5% water by mass. If the water content of the steam is 5% by mass, then the steam is said to be 95% dry and has a dryness fraction of 0.95. The actual enthalpy of evaporation of wet steam is the product of the dryness fraction () and the specific enthalpy (hfg) from the steam tables. Wet steam will have lower usable heat energy than dry saturated steam. Equation 2.2.2 Therefore: Equation 2.2.3 Because the specfic volume of water is several orders of magnitude lower than that of steam, the droplets of water in wet steam will occupy negligible space. Therefore the specific volume of wet steam will be less than dry steam: Equation 2.2.4 Where vg is the specific volume of dry saturated steam.

Example 2.2.2
Steam at a pressure of 6 bar g having a dryness fraction of 0.94 will only contain 94% of the enthalpy of evaporation of dry saturated steam at 6 bar g. The following calculations use figures from steam tables:

The steam phase diagram

The data provided in the steam tables can also be expressed in a graphical form. Figure 2.2.3 illustrates the relationship between the enthalpy and temperature of the various states of water and steam; this is known as a phase diagram.

Fig. 2.2.3 Temperature enthalpy phase diagram As water is heated from 0C to its saturation temperature, its condition follows the saturated water line until it has receiv ed all of its liquid enthalpy, hf, (A - B). If further heat continues to be added, the water changes phase to a water/vapour mixture and continues to increase in enthalpy while remaining at saturation temperature ,hfg, (B - C). As the water/vapour mixture increases in dryness, its condition moves from the saturated liquid line to the saturated vapour line. Therefore at a point exactly halfway between these two states, the dryness fraction () is 0.5. Similarly, on the saturated steam line the steam is 100% dry. Once it has received all of its enthalpy of evaporation, it reaches the saturated steam line. If it continues to be heated after this point, the pressure remains constant but the temperature of the steam will begin to rise as superheat is imparted (C - D). The saturated water and saturated steam lines enclose a region in which a water/vapour mixture exists - wet steam. In the region to the left of the saturated water line only water exists, and in the region to the right of the saturated steam line only superheated steam exists. The point at which the saturated water and saturated steam lines meet is known as the critical point. As the pressure increases towards the critical point the enthalpy of evaporation decreases, until it becomes zero at the critical point. This suggests that water changes directly into saturated steam at the critical point. Above the critical point the steam may be considered as a gas. The gaseous state is the most diffuse state in which the molecules have an almost unrestricted motion, and the volume increases without limit as the pressure is reduced. The critical point is the highest temperature at which water can exist. Any compression at constant temperature above the critical point will not produce a phase change. Compression at constant temperature below the critical point however, will result in liquefaction of the vapour as it passes from the superheated region into the wet steam region. The critical point occurs at 374.15C and 221.2 bar a for steam. Above this pressure the steam is termed supercritical and no well-defined boiling point applies. Top

Flash steam
The term 'flash steam' is traditionally used to describe steam issuing from condensate receiver vents and open-ended condensate discharge lines from steam traps. How can steam be formed from water without adding heat? Flash steam occurs whenever water at high pressure (and a temperature higher than the saturation temperature of the low-pressure liquid) is allowed to drop to a lower pressure. Conversely, if the temperature of the high-pressure water is lower than the saturation temperature at the lower pressure, flash steam cannot be formed. In the case of condensate passing through a steam trap, it is usually the case that the upstream temperature is high enough to form flash steam. See Figure 2.2.4.

Fig. 2.2.4 Flash steam formed because T1 > T2 Consider a kilogram of condensate at 5 bar g and a saturation temperature of 159C passing through a steam trap to a lower pressure of 0 bar g. The amount of energy in one kilogram of condensate at saturation temperature at 5 bar g is 671 kJ. In accordance with the first law of thermodynamics, the amount of energy contained in the fluid on the low-pressure side of the steam trap must equal that on the high-pressure side, and constitutes the principle of conservation of energy. Consequently, the heat contained in one kilogram of low-pressure fluid is also 671 kJ. However, water at 0 bar g is only able to contain 419 kJ of heat, subsequently there appears to be an imbalance of heat on the low-pressure side of 671 - 419 = 252 kJ, which, in terms of the water, could be considered as excess heat. This excess heat boils some of the condensate into what is known as flash steam and the boiling process is called flashing. Therefore, the one kilogram of condensate which existed as one kilogram of liquid water on the high pressure side of the steam trap now partly exists as both water and steam on the low-pressure side. The amount of flash steam produced at the final pressure (P2) can be determined using Equation 2.2.5:

Equation 2.2.5

Where:

P1 = Initial pressure P2 = Final pressure hf = Liquid enthalpy (kJ/kg) hfg = Enthalpy of evaporation (kJ/kg)
Example 2.2.3 The case where the high pressure condensate temperature is higher than the low pressure saturation temperature
Consider a quantity of water at a pressure of 5 bar g, containing 671 kJ/kg of heat energy at its saturation temperature of 159C. If the pressure was then reduced down to atmospheric pressure (0 bar g), the water could only exist at 100C and contain 419 kJ/kg of heat energy. This difference of 671 - 419 = 252 kJ/kg of heat energy, would then produce flash steam at atmospheric pressure.

The proportion of flash steam produced can be thought of as the ratio of the excess energy to the enthalpy of evaporation at the final pressure.

Example 2.2.4 The case where the high pressure condensate temperature is lower than the low pressure saturation temperature
Consider the same conditions as in Example 2.2.3, with the exception that the high-pressure condensate temperature is at 90C, that is, subcooled below the atmospheric saturation temperature of 100C. Note: It is not usually practical for such a large drop in condensate temperature from its saturation temperature (in this case 159C to 90C); it is simply being used to illustrate the point about flash ste am not being produced under such circumstances. In this case, the sub-saturated water table will show that the liquid enthalpy of one kilogram of condensate at 5 bar g and 90C is 377 kJ. As this enthalpy is less than the enthalpy of one kilogram of saturated water at atmospheric pressure (419 kJ), there is no excess heat available to produce flash steam. The condensate simply passes through the trap and remains in a liquid state at the same temperature but lower pressure, atmospheric pressure in this case. See Figure 2.2.5.

Fig. 2.2.5 No flash steam formed because T1 < T2 The vapour pressure of water at 90C is 0.7 bar absolute. Should the lower condensate pressure have been less than this, flas h steam would have been produced.

The principles of conservation of energy and mass between two process states
The principles of the conservation of energy and mass allow the flash steam phenomenon to be thought of from a different direction. Consider the conditions in Example 2.2.3. 1 kg of condensate at 5 bar g and 159C produces 0.112 kg of flash steam at atmospheric pressure. This can be illustrated schematically in Figure 2.2.6. The total mass of flash and condensate remains at 1 kg.

Fig. 2.2.6 The principle of energy conservation between two process states The principle of energy conservation states that the total energy in the lower-pressure state must equal the total energy in the higher-pressure state. Therefore, the amount of heat in the flash steam and condensate must equal that in the initial condensate of 671 kJ. Steam tables give the following information:

Total enthalpy of saturated water at atmospheric pressure (hf) = 419 kJ/kg Total enthalpy in saturated steam at atmospheric pressure (hg) = 2 675 kJ/kg Therefore, at the lower pressure state of 0 bar g, Total enthalpy in the water = 0.888 kg x 419 kJ / kg = 372 kJ (A) Total enthalpy in the steam = 0.112 kg x 2 675 kJ / kg = 299 kJ (B) Total enthalpy in condensate and steam at the lower pressure = A + B = 671 kJ
Therefore, according to the steam tables, the enthalpy expected in the lower-pressure state is the same as that in the higher-pressure state, thus proving the principle of conservation of energy.

Superheated Steam
An explanation of the properties and uses of superheated steam (such as for electricity generation). Including explanations of the Rankine and Carnot thermodynamic cycles, superheated steam tables and the Mollier (H-S) chart. Use the quick links below to take you to the main sections of this tutorial:

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Contact Us If the saturated steam produced in a boiler is exposed to a surface with a higher temperature, its temperature will increase above the evaporating temperature. The steam is then described as superheated by the number of temperature degrees through which it has been heated above saturation temperature. Superheat cannot be imparted to the steam whilst it is still in the presence of water, as any additional heat simply evaporates more water. The saturated steam must be passed through an additional heat exchanger. This may be a second heat exchange stage in the boiler, or a separate superheater unit. The primary heating medium may be either the hot flue gas from the boiler, or may be separately fired.

Fig. 2.3.1 Steam and force on a turbine blade Superheated steam has its applications in, for example, turbines where the steam is directed by nozzles onto a rotor. This causes the rotor to turn. The energy to make this happen can only have come from the steam, so logically the steam has less energy after it has gone through the turbine rotor. If the steam was at saturation temperature, this loss of energy would cause some of the steam to condense. Turbines have a number of stages; the exhaust steam from the first rotor will be directed to a second rotor on the same shaft. This means that saturated steam would get wetter and wetter as it went through the successive stages. Not only would this promote waterhammer, but the water particles would cause severe erosion within the turbine. The solution is to supply the turbine with superheated steam at the inlet, and use the energy in the superheated portion to drive the rotor until the temperature/pressure conditions are close to saturation; and then exhaust the steam. Another very important reason for using superheated steam in turbines is to improve thermal efficiency. The thermodynamic efficiency of a heat engine such as a turbine, may be determined using one of two theories:

The Carnot cycle, where the change in temperature of the steam between the inlet and outlet is compared to the inlet temperature. The Rankine cycle, where the change in heat energy of the steam between the inlet and outlet is compared to the total energy taken from the steam.

Note: The values used for the temperature and energy content in the following examples are from steam tables.

Example 2.3.1
A turbine is supplied with superheated steam at 90 bar a @ 450C. The exhaust is at 0.06 bar a (partial vacuum) and 10% wet. Saturated temperature = 36.2C.

2.3.1.1 Determine the Carnot efficiency (C)

Equation 2.3.1

2.3.1.2 Determine the Rankine efficiency (R)

For the theoretical Rankine Cycle, Figure 2.3.2, it is assumed that there are no frictional losses in the turbine, perfect expansion of the steam occurs in the turbine (isentropic), and ignores energy added by the feedpump returning condensate to the boiler.

Fig. 2.3.2 Basic Rankine cycle Using Example 2.3.1 where: - A turbine is supplied with superheated steam at 90 bar a @ 450C. - The exhaust is at 0.06 bar a (partial vacuum) and 10% wet. - Saturated temperature = 36.2C. This data can be plotted on the temperature / enthalpy curve as illustrated in Figure 2.3.3:

Fig. 2.3.3 Temperature / enthalpy curve + figures from example 2.3.1

Equation 2.3.2

Examination of the figures for either of the cycles indicates that to achieve high efficiency:


Notes:

The temperature or energy at the turbine inlet should be as high as possible. This means as high a pressure and temperature as is practically possible. Superheated steam is the simplest way of providing this. The temperature or energy in the exhaust must be as low as possible. This means as low a pressure and temperature as is practically possible, and is usually achieved by a condenser on the turbine exhaust.

Top

The figures calculated in Examples 2.3.1.1 and 2.3.1.2 are for thermodynamic efficiency, and must not be confused with mechanical efficiency. Although the efficiency figures appear to be very low, they must not be viewed in isolation, but rather used to compare one type of heat engine with another. For example, gas turbines, steam engines and diesel engines.

Superheated steam tables

The superheated steam tables display the properties of steam at various pressures in much the same way as the saturated steam tables. However, with superheated steam there is no direct relationship between temperature and pressure. Therefore at a particular pressure it may be possible for superheated steam to exist at a wide range of temperatures. In general, saturated steam tables give gauge pressure, superheated steam tables give absolute pressure.

Table 2.3.1 Extract from superheated steam tables

Example 2.3.2
How much more heat does superheated steam with a temperature of 400C and a pressure of 1.013 bar a (0 bar g) have than saturated steam at the same pressure?

hg for saturated steam at 1.013 bar a = 2 676 kJ/kg (from saturated steam tables) hg for steam at 1.013 bar a and 400C = 3 278 kJ/kg (from superheated steam tables) Enthalpy in the superheat = 3 278 kJ/kg - 2 676 kJ/kg: = 602 kJ/kg Enthalpy in the superheat
This may sound a useful increase in energy, but in fact it will actually make life more difficult for the engineer who wants to use steam for heating purposes. From the energy in the superheat shown, the specific heat capacity can be determined by dividing this value by the temperature difference between saturation temperature (100C) and the superheated steam temperature (400C):

However, unlike the specific heat capacity of water, the specific heat capacity for superheated steam varies considerably with pressure and temperature and cannot be taken as a constant. The value of 2.0 kJ/kg C given above is therefore only the mean spe cific heat capacity over the specified temperature range for that pressure. There is no direct relationship between temperature, pressure and the specific heat capacity of superheated steam. There is, however, a general trend towards an increase in specific heat capacity with increasing pressure at low degrees of superheat, but this is not always the case.

Typical value range: 2.0 kJ/kg C at 125C and 1.013 bar a (0 bar g) 3.5 kJ/kg C at 400C and 120 bar a.
Can superheated steam be used in process heat exchangers and other heating processes?
Although not the ideal medium for transferring heat, superheated steam is sometimes used for process heating in many steam plants around the world, especially in the HPIs (Hydrocarbon Processing Industries) which produce oils and petrochemicals. This is more likely to be because superheated steam is already available on site for power generation, being the preferred energy source for turbines, rather than because it has any advantage over saturated steam for heating purposes. To be clear on this point, in most cases, saturated steam should be used for heat transfer processes, even if it means desuperheating the steam to do so. HPIs often desuperheat steam to within about ten degrees of superheat. This small degree of superheat is removed readily in the first part of the heating surface. Greater amounts of superheat are more difficult, and often uneconomic to deal with and (for heating purposes) are best avoided. There are quite a few reasons why superheated steam is not as suitable for process heating as saturated steam: Superheated steam has to cool to saturation temperature before it can condense to release its enthalpy of evaporation. The amount of heat given up by the superheated steam as it cools to saturation temperature is relatively small in comparison to its enthalpy of evaporation. If the steam has only a few degrees of superheat, this small amount of heat is quickly given up before it condenses. However, if the steam has a large degree of superheat, it may take a relatively long time to cool, during which time the steam is releasing very little energy. Unlike saturated steam, the temperature of superheated steam is not uniform. Superheated steam has to cool to give up heat, whilst saturated steam changes phase. This means that temperature gradients over the heat transfer surface may occur with superheated steam.

In a heat exchanger, use of superheated steam can lead to the formation of a dry wall boiling zone, close to the tube sheet. This dry wall area can quickly become scaled or fouled, and the resulting high temperature of the tube wall may cause tube failure. This clearly shows that in heat transfer applications, steam with a large degree of superheat is of little use because it:

Gives up little heat until it has cooled to saturation temperature. Creates temperature gradients over the heat transfer surface as it cools to saturation temperature. Provides lower rates of heat transfer whilst the steam is superheated. Requires larger heat transfer areas.

So, superheated steam is not as effective as saturated steam for heat transfer applications. This may seem strange, considering that the rate of heat transfer across a heating surface is directly proportional to the temperature difference across it. If superheated steam has a higher temperature than saturated steam at the same pressure, surely superheated steam should be able to impart more heat? The answer to this is 'no'. This will now be looked at in more detail. It is true that the temperature difference will have an effect on the rate of heat transfer across the heat transfer surface, as clearly shown by Equation 2.5.3. Equation 2.5.3 Where:

= Heat transferred per unit time (W) U = Overall thermal transmittance (heat transfer coefficient) (W/m2C) A = Heat transfer area (m2) T = Temperature difference between primary and secondary fluid (C)
Equation 2.5.3 also shows that heat transfer will depend on the overall heat transfer coefficient 'U', and the heat transfer area 'A'. For any single application, the heat transfer area might be fixed. However, the same cannot be said of the 'U' value; and this is the major difference between saturated and superheated steam. The overall 'U' value for superheated steam will vary throughout the process, but will always be much lower than that for saturated steam. It is difficult to predict 'U' values for superheated steam, as these will depend upon many factors, but generally, the higher the degree of superheat, the lower the 'U' value. Typically, for a horizontal steam coil surrounded with water, 'U' values might be as low as 50 to 100 W/m2)C for superheated steam but 1 200 W/m2)C for saturated steam, as depicted in Figure 2.3.4. For steam to oil applications, the 'U' values might be considerably less, perhaps as low as 20 W/m2)C for superheated steam and 150 W/m2)C for saturated steam. In a shell and tube heat exchanger, 100 W/m2)C for superheated steam and 500 W/m2)C for saturated steam can be expected. These figures are typical; actual figures will vary due to other design and operational considerations.

Figure 2.3.4 Typical U values for superheated and saturated steam coils in water Although the temperature of superheated steam is always higher than saturated steam at the same pressure, its ability to transfer heat is therefore much lower. The overall effect is that superheated steam is much less effective at transferring heat than saturated steam at the same pressure. The next Section 'Fouling' gives more detail. Not only is superheated steam less effective at transferring heat, it is very difficult to quantify using Equation 2.5.3, temperature of the steam will fall as it gives up its heat while passing along the heating surface. = U A T, as the

Predicting the size of heat transfer surfaces utilising superheated steam is difficult and complex. In practice, the basic data needed to perform such calculations is either not known or empirically obtained, putting their reliability and accuracy in doubt. Clearly, as superheated steam is less effective at transferring heat than saturated steam, then any heating area using superheated steam would have to be larger than a saturated steam coil operating at the same pressure to deliver the same heat flowrate. If there is no choice but to use superheated steam, it is not possible to maintain steam in its superheated state throughout the heating coil or heat exchanger, since as it gives up some of its heat content to the secondary fluid, it cools towards saturation temperature. The amount of heat above saturation is quite small compared with the large amount available as condensation occurs. The steam should reach saturation relatively soon in the process; this allows the steam to condense to produce higher heat transfer rates and result in a higher overall 'U' value for the whole coil, see Figure 2.3.5. To help to enable this, superheated steam used for heat transfer purposes should not hold more than about 10C of superheat.

Figure 2.3.5 Less superheat allows the steam to condense in the major part of the coil thus increasing the overall U value approaching that of saturated steam. If this is so, it is relatively easy and practical to design a heat exchanger or a coil with a heating surface area based upon saturated steam at the same pressure, by adding on a certain amount of surface area to allow for the superheat. Using this guideline, the first part of a coil will be used purely to reduce the temperature of superheated steam to its saturation point. The rest of the coil will then be able to take advantage of the higher heat transfer ability of the saturated steam. The effect is that the overall 'U' value may not be much less than if saturated steam were supplied to the coil. From practical experience, if the extra heating area needed for superheated steam is 1% per 2C of superheat, the coil (or heat exchanger) will be large enough. This seems to work up to 10C of superheat. It is not recommended that superheated steam above 10C of super heat be used for heating purposes due to the probable disproportionate and uneconomic size of the heating surface, the propensity for fouling by dirt, and the possibility of product spoilage by the high and uneven superheat temperatures.

Fouling
Fouling is caused by deposits building up on the heat transfer surface adding a resistance to heat flow. Many process liquids can deposit sludge or scale on heating surfaces, and will do so at a faster rate at higher temperatures. Further, superheated steam is a dry gas. Heat flowing from the steam to the metal wall must pass through the static films adhering to the wall, which resist heat flow. By contrast, the condensation of saturated steam causes the movement of steam towards the wall, and the release of large quantities of latent heat right at the condensing surface. The combination of these factors means that the overall heat transfer rates are much lower where superheated steam is present, even though the temperature difference between the steam and the secondary fluid is higher.

Example 2.3.3 Sizing a tube bundle for superheated steam

Superheated steam at 3 bar g with 10C of superheat (154C) is to be used as the primary heat source for a shell and tube pro cess heat exchanger with a heating load of 250 kW, heating an oil based fluid from 80C to 120C (making t he arithmetic mean secondary temperature (T AM) 100C). Estimate the area of primary steam coil required. (Arithmetic mean temperature differences are used to keep this calculation simple; in practice, logarithmic mean temperatures would be used for greater accuracy. Please refer to Tutorial 2.5 'Heat Transfer' for details on arithmetic and logarithmic mean temperature differences). First, consider the coil if it were heated by saturated steam at 3 bar g (144C). The 'U' value for saturated steam heating oil via a new carbon steel coil is taken to be 500 W/m2C.

Other applications using superheated steam

All the above applies when steam is flowing through a relatively narrow passage, such as the tubes in a shell and tube heat exchanger or the plates in a plate heat exchanger. In some applications, perhaps a drying cylinder in a paper machine, superheated steam is admitted to a greater volume, when its velocity plummets to very small values. Here, the steam near the wall of the cylinder quickly drops in temperature to near saturation and condensation begins. The heat flow through the wall is then the same as if the cylinder were supplied with saturated steam. Superheat is present only within the 'core' in the steam space and has no discernible effect on heat transfer rates. There are instances where the presence of superheat can actually reduce the performance of a process, where steam is being used as a

process material. One such process might involve moisture being imparted to the product from the steam as it condenses, such as, the conditioning of animal feedstuff (meal) prior to pelletising. Here the moisture provided by the steam is an essential part of the process; superheated steam would overdry the meal and make pelletising difficult.

The effects of reducing steam pressure

In addition to the use of an additional heat exchanger (generally called a 'superheater'), superheat can also be imparted to steam by allowing it to expand to a lower pressure as it passes through the orifice of a pressure reducing valve. This is termed a throttling process with the lower pressure steam having the same enthalpy (apart from a small amount lost to friction in passing through the valve) as the upstream high pressure steam. However, the temperature of the throttled steam will always be lower than that of the supply steam. The state of the throttled steam will depend upon:

The pressure of the supply steam. The state of the supply steam. The pressure drop across the valve orifice.

For supply steam below 30 bar g in the dry saturated state, any drop in pressure will produce superheated steam after throttling. The degree of superheat will depend on the amount of pressure reduction. For supply steam above 30 bar g in the dry saturated state, the throttled steam might be superheated, dry saturated, or even wet, depending on the amount of pressure drop. For example, dry saturated steam at 60 bar g would have to be reduced to approximately 10.5 bar g to produce dry saturated steam. Any less of a pressure drop will produce wet steam, while any greater pressure drop would produce superheated steam. Equally, the state of the supply steam at any pressure will influence the state of the throttled steam. For example, wet steam at a pressure of 10 bar g and 0.95 dryness fraction would need to be reduced to 0.135 bar g to produce dry saturated steam. Any less of a pressure drop would produce wet steam while any greater pressure drop would superheat the throttled steam.

Example 2.3.4 Increasing the dryness of wet steam with a control valve
Steam with a dryness fraction () of 0.95 is reduced from 6 bar g to 1 bar g, using a pressure reducing valve. Determine the steam conditions after the pressure reducing valve.

This quantity of heat energy is retained by the steam as the pressure is reduced to 1 bar g.

As the actual enthalpy of the steam at 1 bar g is less than the enthalpy of dry saturated steam at 1 bar g, then the steam is not superheated and still retains a proportion of moisture in its content.

Since the total enthalpy after the pressure reducing valve is less than the total enthalpy of steam at 1 bar g, the steam is still wet.

Example 2.3.5 Superheat created by a control valve

Steam with a dryness fraction of 0.98 is reduced from 10 bar g down to 1 bar g using a pressure reducing valve (as shown in Figure 2.3.6).

Determine the degree of superheat after the valve. As in the previous example (2.3.3), the specific enthalpy of dry saturated steam (hg) at 1 bar g is 2 706.7 kJ/kg. The actual total enthalpy of the steam is greater than the total enthalpy (hg) of dry saturated steam at 1 bar g. The steam is therefore not only 100% dry, but also has some degree of superheat.

The excess energy = 2 741.7 - 2 706.7 = 35 kJ/kg, and this is used to raise the temperature of the steam from the saturation temperature of 120C to 136C.

Fig. 2.3.6 The creation of superheat by pressure reduction The degree of superheat can be determined either by using superheated steam tables, or by using a Mollier chart. Top

The Mollier chart

The Mollier chart is a plot of the specific enthalpy of steam against its specific entropy (sg).

Fig. 2.3.7 Enthalpy - entropy or Mollier chart for steam Figure 2.3.7 shows a simplified, small scale version of the Mollier chart. The Mollier chart displays many different relationships between enthalpy, entropy, temperature, pressure and dryness fraction. It may appear to be quite complicated, due to the number of lines:

Constant enthalpy lines (horizontal). Constant entropy lines (vertical). The steam saturation curve across the centre of the chart divides it into a superheated steam region, and a wet steam region. At any point above the saturation curve the steam is superheated, and at any point below the saturation curve the steam is wet. The saturation curve itself represents the condition of dry saturated steam at various pressures. Constant pressure lines in both regions. Constant temperature lines in the superheat region. Constant dryness fraction () lines in the wet region.

A perfect expansion, for example within a steam turbine or a steam engine, is a constant entropy process, and can be represented on the chart by moving vertically downwards from a point representing the initial condition to a point representing the final condition. A perfect throttling process, for example across a pressure reducing valve, is a constant enthalpy process. It can be represented on the chart by moving horizontally from left to right, from a point representing the initial condition to a point representing the final condition. Both these processes involve a reduction in pressure, but the difference lies in the way in which this is achieved. The two examples shown in Figure 2.3.8 illustrate the advantage of using the chart to analyse steam processes; they provide a pictorial representation of such processes. However, steam processes can also be numerically represented by the values provided in the superheated steam tables.

Fig. 2.3.8 Examples of expansion and throttling

Example 2.3.6 Perfect isentropic expansion resulting in work

Consider the perfect expansion of steam through a turbine. Initially the pressure is 50 bar a, the temperature is 300C, and the final pressure is 0.04 bar a. As the process is a perfect expansion, the entropy remains constant. The final condition can then be found by dropping vertically downwards from the initial condition to the 0.04 bar a constant pressure line (see Figure 2.3.9). At the initial condition, the entropy is approximately 6.25 kJ/kg C. If this line is followed vertically downwards until 0.0 4 bar a is reached, the final condition of the steam can be evaluated. At this point the specific enthalpy is 1 890 kJ/kg, and the dryness fraction is 0.72 (see Figure 2.3.9). The final condition can also be determined by using the superheated steam tables.

Fig. 2.3.9 Enthalpy - entropy or Mollier chart for steam - Example Since the entropy of dry saturated steam at 0.04 bar a (8.473 kJ/kgC) is greater than the entropy of the superheated steam at 50 bar a/300C (6.212 kJ/kgC), it follows that some of the dry saturated steam must have condensed to maintain the constant entropy. As the entropy remains constant, at the final condition:

Note: The values used for the temperature and energy content in the following examples are from steam tables.

These answers correspond closely with the results obtained using the Mollier chart. The small difference in value between the two sets of results is to be expected, considering the inaccuracies involved in reading off a chart such as this.

Steam Quality
Steam should be available at the point of use in the correct quantity, at the correct pressure, clean, dry and free from air and other incondensable gases. This tutorial explains why this is necessary, and how steam quality is assured.

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Contact Us Steam should be available at the point of use:

In the correct quantity At the correct temperature and pressure Free from air and incondensable gases Clean Dry

Correct quantity of steam

The correct quantity of steam must be made available for any heating process to ensure that a sufficient heat flow is provided for heat transfer. Similarly, the correct flowrate must also be supplied so that there is no product spoilage or drop in the rate of production. Steam loads must be properly calculated and pipes must be correctly sized to achieve the flowrates required.

Correct pressure and temperature of steam

Steam should reach the point of use at the required pressure and provide the desired temperature for each application, or performance will be affected. The correct sizing of pipework and pipeline ancillaries will ensure this is achieved. However, even if the pressure gauge is correctly displaying the desired pressure, the corresponding saturation temperature may not be available if the steam contains air and/or incondensable gases.

Air and other incondensable gases

Air is present within the steam supply pipes and equipment at start-up. Even if the system were filled with pure steam the last time it was used, the steam would condense at shutdown, and air would be drawn in by the resultant vacuum. When steam enters the system it will force the air towards either the drain point, or to the point furthest from the steam inlet, known as the remote point. Therefore steam traps with sufficient air venting capacities should be fitted to these drain points, and automatic air vents should be fitted to all remote points. However, if there is any turbulence the steam and air will mix and the air will be carried to the heat transfer surface. As the steam condenses, an insulating layer of air is left behind on the surface, acting as a barrier to heat transfer.

Fig. 2.4.1 Steam process equipment with an automatic air vent and strainers

Steam and air mixtures

In a mixture of air and steam, the presence of air will cause the temperature to be lower than expected. The total pressure of a mixture of gases is made up of the sum of the partial pressures of the components in the mixture. This is known as Dalton's Law of Partial Pressures. The partial pressure is the pressure exerted by each component if it occupied the same volume as the mixture:

Equation 2.4.1 Note: This is a thermodynamic relationship, so all pressures must be expressed in bar a.

Example 2.4.1
Consider a steam/air mixture made up of steam and air by volume. The total pressure is 4 bar a. Determine the temperature of the mixture:

Therefore the steam only has an effective pressure of 3 bar a as opposed to its apparent pressure of 4 bar a. The mixture would only have a temperature of 134C rather than the expected saturation temperature of 144C. This phenomena is not only of importance in heat exchange applications (where the heat transfer rate increases with an increase in temperature difference), but also in process applications where a minimum temperature may be required to achieve a chemical or physical change in a product. For instance, a minimum temperature is essential in a steriliser in order to kill bacteria.

Other sources of air in the steam and condensate loop

Air can also enter the system in solution with the boiler feedwater. Make-up water and condensate, exposed to the atmosphere, will readily absorb nitrogen, oxygen and carbon dioxide: the main components of atmospheric air. When the water is heated in the boiler, these gases are released with the steam and carried into the distribution system. Atmospheric air consists of 78% nitrogen, 21% oxygen and 0.03% carbon dioxide, by volume analysis. However, the solubility of oxygen is roughly twice that of nitrogen, whilst carbon dioxide has a solubility roughly 30 times greater than oxygen! This means that 'air' dissolved in the boiler feedwater will contain much larger proportions of carbon dioxide and oxygen: both of which cause corrosion in the boiler and the pipework. The temperature of the feedtank is maintained at a temperature typically no less than 80C so that oxygen and carbon dioxide can be liberat ed back to the atmosphere, as the solubility of these dissolved gases decreases with increasing temperature. The concentration of dissolved carbon dioxide is also kept to a minimum by demineralising and degassing the make-up water at the external water treatment stage. The concentration of dissolved gas in the water can be determined using Henry's Law. This states that the mass of gas that can be dissolved by a given volume of liquid is directly proportional to the partial pressure of the gas. This is only true however if the temperature is constant, and there is no chemical reaction between the liquid and the gas.

Cleanliness of steam
Layers of scale found on pipe walls may be either due to the formation of rust in older steam systems, or to a carbonate deposit in hard water areas. Other types of dirt which may be found in a steam supply line include welding slag and badly applied or excess jointing material, which may have been left in the system when the pipework was initially installed. These fragments will have the effect of increasing the rate of erosion in pipe bends and the small orifices of steam traps and valves. For this reason it is good engineering practice to fit a pipeline strainer (as shown in Figure 2.4.2). This should be installed upstream of every steam trap, flowmeter, pressure reducing valve and control valve.

Fig. 2.4.2 A pipeline strainer Steam flows from the inlet A through the perforated screen B to the outlet C. While steam and water will pass readily through the screen, dirt will be arrested. The cap D can be removed, allowing the screen to be withdrawn and cleaned at regular intervals. When strainers are fitted in steam lines, they should be installed on their sides so that the accumulation of condensate and the problem of waterhammer can be avoided. This orientation will also expose the maximum strainer screen area to the flow. A layer of scale may also be present on the heat transfer surface, acting as an additional barrier to heat transfer. Layers of scale are often a result of either:

Incorrect boiler operation, causing impurities to be carried over from the boiler in water droplets. Incorrect water treatment in the boiler house.

The rate at which this layer builds up can be reduced by careful attention to the boiler operation and by the removal of any droplets of moisture.

Dryness of steam
Incorrect chemical feedwater treatment and periods of peak load can cause priming and carryover of boiler feedwater into the steam mains, leading to chemical and other material being deposited on to heat transfer surfaces. These deposits will accumulate over time, gradually reducing the efficiency of the plant. In addition to this, as the steam leaves the boiler, some of it must condense due to heat loss through the pipe walls. Although these pipes may be well insulated, this process cannot be completely eliminated. The overall result is that steam arriving at the plant is relatively wet, and the droplets of moisture carried along with the steam can erode pipes, fittings and valves especially if velocities are high. It has already been shown that the presence of water droplets in steam reduces the actual enthalpy of evaporation, and also leads to the formation of scale on the pipe walls and heat transfer surface. The droplets of water entrained within the steam can also add to the resistant film of water produced as the steam condenses, creating yet another barrier to the heat transfer process. A separator in the steam line will remove moisture droplets entrained in the steam flow, and also any condensate that has gravitated to the bottom of the pipe. In the separator shown in Figure 2.4.3 the steam is forced to change direction several times as it flows through the body. The baffles create an

obstacle for the heavier water droplets, while the lighter dry steam is allowed to flow freely through the separator. The moisture droplets run down the baffles and drain through the bottom connection of the separator to a steam trap. This will allow condensate to drain from the system, but will not allow the passage of any steam.

Fig. 2.4.3 A steam separator

Waterhammer
As steam begins to condense due to heat losses in the pipe, the condensate forms droplets on the inside of the walls. As they are swept along in the steam flow, they then merge into a film. The condensate then gravitates towards the bottom of the pipe, where the film begins to increase in thickness. The build up of droplets of condensate along a length of steam pipework can eventually form a slug of water (as shown in Figure 2.4.4), which will be carried at steam velocity along the pipework (25 - 30 m/s).

Fig. 2.4.4 Formation of a solid slug of water This slug of water is dense and incompressible, and when travelling at high velocity, has a considerable amount of kinetic energy. The laws of thermodynamics state that energy cannot be created or destroyed, but simply converted into a different form. When obstructed, perhaps by a bend or tee in the pipe, the kinetic energy of the water is converted into pressure energy and a pressure shock is applied to the obstruction. Condensate will also collect at low points, and slugs of condensate may be picked up by the flow of steam and hurled downstream at valves and pipe fittings. These low points might include a sagging main, which may be due to inadequate pipe support or a broken pipe hanger. Other potential sources of waterhammer include the incorrect use of concentric reducers and strainers, or inadequate drainage before a rise in the steam main. Some of these are shown in Figure 2.4.5. The noise and vibration caused by the impact between the slug of water and the obstruction, is known as waterhammer. Waterhammer can significantly reduce the life of pipeline ancillaries. In severe cases the fitting may fracture with an almost explosive effect. The consequence may be the loss of live steam at the fracture, creating a hazardous situation. The installation of steam pipework is discussed in detail in Block 9, Steam Distribution.

Fig. 2.4.5 Potential sources of waterhammer

Heat Transfer
Steam is often generated to provide heat transfer to a process. Modes of heat transfer (conduction, convection, radiation) within or between media are explained, together with calculations and other issues such as heat transfer barriers. Use the quick links below to take you to the main sections of this tutorial:

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Contact Us In a steam heating system, the sole purpose of the generation and distribution of steam is to provide heat at the process heat transfer surface. If the required heat input rate and steam pressure are known, then the necessary steam consumption rate may be determined. This will allow the size of the boiler and the steam distribution system to be established. Top

Modes of heat transfer

Whenever a temperature gradient exists, either within a medium or between media, the transfer of heat will occur. This may take the form of either conduction, convection or radiation.

Conduction
When a temperature gradient exists in either a solid or stationary fluid medium, the heat transfer which takes place is known as conduction. When neighbouring molecules in a fluid collide, energy is transferred from the more energetic to the less energetic molecules. Because higher temperatures are associated with higher molecular energies, conduction must occur in the direction of decreasing temperature. This phenomenon can be seen in both liquids and gases. However, in liquids the molecular interactions are stronger and more frequent, as the molecules are closer together. In solids, conduction is caused by the atomic activity of lattice vibrations as explained in Tutorial 2.2. The equation used to express heat transfer by conduction is known as Fourier's Law. Where there is a linear temperature distribution under steady-state conditions, for a one-dimensional plane wall it may be written as:

Equation 2.5.1 Where:

= Heat transferred per unit time (W) k = Thermal conductivity of the material (W/m K or W/mC) A = Heat transfer area (m) T = Temperature difference across the material (K or C) = Material thickness (m)
Example 2.5.1
Consider a plane wall constructed of solid iron with a thermal conductivity of 70 W/mC, and a thickness of 25 mm. It has a s urface area of 0.3 m by 0.5 m, with a temperature of 150C on one side and 80C on the other. Determine the rate of heat transfer:

The thermal conductivity is a characteristic of the wall material and is dependent on temperature. Table 2.5.1 shows the variation of thermal conductivity with temperature for various common metals.

Table 2.5.1 Thermal conductivity (W/m C) Considering the mechanism of heat transfer in conduction, in general the thermal conductivity of a solid will be much greater than of a liquid, and the thermal conductivity of a liquid will be greater than of a gas. Air has a particularly low thermal conductivity and this is why insulating materials often have lots of air spaces.

Convection
The transfer of heat energy between a surface and a moving fluid at different temperatures is known as convection. It is actually a combination of the mechanisms of diffusion and the bulk motion of molecules. Near the surface where the fluid velocity is low, diffusion (or random molecular motion) dominates. However, moving away from the surface, bulk motion holds an increasing influence. Convective heat transfer may take the form of either forced convection or natural convection. Forced convection occurs when fluid flow is induced by an external force, such as a pump or an agitator. Conversely, natural convection is caused by buoyancy forces, due to the density differences arising from the temperature variations in the fluid. The transfer of heat energy caused by a phase change, such as boiling or condensing, is also referred to as a convective heat transfer process. The equation for convection is expressed by Equation 2.5.2 which is a derivation of Newton's Law of Cooling:

Equation 2.5.2 Where:

= Heat transferred per unit time (W) A = Heat transfer area of the surface (m) h = Convective heat transfer coefficient of the process (W/m K or W/mC) T = Temperature difference between the surface and the bulk fluid (K or C)
Example 2.5.2
Consider a plane surface 0.4 m by 0.9 m at a temperature of 20C. A fluid flows over the surface with a bulk temperature of 50C. The convective heat transfer coefficient (h) is 1 600 W/mC. Determine the rate of heat transfer:

Radiation
The heat transfer due to the emission of energy from surfaces in the form of electromagnetic waves is known as thermal radiation. In the absence of an intervening medium, there is a net heat transfer between two surfaces of different temperatures. This form of heat transfer does not rely on a material medium, and is actually most efficient in a vacuum. Top

The general heat transfer equation

In most practical situations, it is very unusual for all energy to be transferred by one mode of heat transfer alone. The overall heat transfer process will usually be a combination of two or more different mechanisms. The general equation used to calculate heat transfer across a surface used in the design procedure and forming a part of heat exchange theory is: Equation 2.5.3 Where:

= Heat transferred per unit time (W (J/s)) U = Overall heat transfer coefficient (W/m K or W/mC) A = Heat transfer area (m) T = Temperature difference between the primary and secondary fluid (K or C)
Note: will be a mean heat transfer rate (
M

) if T is a mean temperature difference (T LM or T AM).

The overall heat transfer coefficient (U)

This takes into account both conductive and convective resistance between two fluids separated by a solid wall. The overall heat transfer coefficient is the reciprocal of the overall resistance to heat transfer, which is the sum of the individual resistances.

The overall heat transfer coefficient may also take into account the degree of fouling in the heat transfer process. The deposition of a film or scale on the heat transfer surface will greatly reduce the rate of heat transfer. The fouling factor represents the additional thermal resistance caused by fluid impurities, rust formation or other reactions between the fluid and the wall. The magnitude of the individual coefficients will depend on the nature of the heat transfer process, the physical properties of the fluids, the fluid flowrates and the physical layout of the heat transfer surface. As the physical layout cannot be established until the heat transfer area has been determined, the design of a heat exchanger is by necessity, an iterative procedure. A starting point for this procedure usually involves selecting typical values for the overall heat transfer coefficient of various types of heat exchanger. An accurate calculation for the individual heat transfer coefficients is a complicated procedure, and in many cases it is not possible due to some of the parameters being unknown. Therefore, the use of established typical values of overall heat transfer coefficient will be suitable for practical purposes.

Temperature difference T
Newton's law of cooling states that the heat transfer rate is related to the instantaneous temperature difference between the hot and the cold media. In a heat transfer process, this temperature difference will vary either with position or with time. The general heat transfer equation was thus developed as an extension to Newton's law of cooling, where the mean temperature difference is used to establish the heat transfer area required for a given heat duty.

Mean temperature difference T M

The determination of the mean temperature difference in a flow type process like a heat exchanger will be dependent upon the direction of flow. The primary and secondary fluids may flow in the same direction (parallel flow/co-current flow), in the opposite direction (countercurrent flow), or perpendicular to each other (crossflow). When saturated steam is used the primary fluid temperature can be taken as a constant, because heat is transferred as a result of a change of phase only. The result is that the temperature profile is no longer dependent on the direction of flow. However, as the secondary fluid passes over the heat transfer surface, the highest rate of heat transfer occurs at the inlet and progressively decays along its travel to the outlet. This is simply because the temperature difference between the steam and secondary fluid reduces with the rise in secondary temperature. The resulting temperature profile of the steam and secondary fluid is typically as shown in Figure 2.5.1.

Fig. 2.5.1 Product temperature rise (LMTD) The rise in secondary temperature is non-linear and is best represented by a logarithmic calculation. For this purpose the mean temperature difference chosen is termed the Logarithmic Mean Temperature Difference or LMTD or T LM. An easier (but less accurate) way to calculate the mean temperature difference is to consider the Arithmetic Mean Temperature Difference or AMTD or T AM. This considers a linear increase in the secondary fluid temperature and for quick manual calculations, will usually give a satisfactory approximation of the mean temperature difference to be used in Equation 2.5.3. The AMTD temperature profile is shown in Figure 2.5.2.

Fig. 2.5.2 Product temperature rise (AMTD) The arithmetic mean temperature difference (AMTD):

Where:

T p1 = Primary fluid in temperature T p2 = Primary fluid out temperature T s1 = Secondary fluid in temperature T s2 = Secondary fluid out temperature
For steam, where the temperature of the primary fluid (steam) remains constant, this equation may be simplified to:

Equation 2.5.4 Where:

T s = Steam temperature (C) T 1 = Secondary fluid in temperature (C) T 2 = Secondary fluid out temperature (C)
Because there is no temperature change on the steam side, the AMTD normally provides a satisfactory analysis of the heat transfer process, which is easy to manipulate in manual calculations. However, a log mean temperature difference can also be used, which accounts for the non-linear change in temperature of the secondary fluid. The log mean temperature difference (LMTD):

For steam, where the temperature of the primary fluid (steam) remains constant, this equation may be simplified to:

Equation 2.5.5 Where:

T s = Steam temperature (C) T 1 = Secondary fluid in temperature (C) T 2 = Secondary fluid out temperature (C) ln = A mathematical function known as 'natural logarithm'
Both Equations 2.5.4 and 2.5.5 assume that there is no change in the specific heat capacity or the overall heat transfer coefficient, and that there are no heat losses. In reality the specific heat capacity may change as a result of temperature variations. The overall heat transfer coefficient may also change because of variations in fluid properties and flow conditions. However, in most applications the deviations will be almost negligible and the use of mean values will be perfectly acceptable. In many cases the heat exchange equipment will be insulated from its surroundings, but the insulation will not be 100% efficient. Therefore, the energy transferred between the steam and the secondary fluid may not represent all of the heat lost from the primary fluid.

Example 2.5.3
Steam at 2 bar g is used to heat water from 20C to 50C. The saturation temperature of steam at 2 bar g is 134C. Determine the arithmetic and the log mean temperature differences:

In this example the AMTD and the LMTD have a similar value. This is because the secondary fluid temperature rise is small in comparison with the temperature difference between the two fluids.

Example 2.5.4
Consider a pressurised process fluid tank, which is heated from 10C to 120C using steam at 4.0 bar g. The saturation temper ature of steam at 4.0 bar g is 152C. Determine the arithmetic and log mean temperature differences:

Because the secondary fluid temperature rise is large in comparison with the temperature difference between the two fluids, the discrepancy between the two results is more significant. By using the AMTD rather than the LMTD, the calculated heat transfer area would be almost 15% smaller than that required. Top

Barriers to heat transfer

The metal wall may not be the only barrier in a heat transfer process. There is likely to be a film of air, condensate and scale on the steam side. On the product side there may also be baked-on product or scale, and a stagnant film of product. Agitation of the product may eliminate the effect of the stagnant film, whilst regular cleaning on the product side should reduce the scale. Regular cleaning of the surface on the steam side may also increase the rate of heat transfer by reducing the thickness of any layer of scale, however, this may not always be possible. This layer may also be reduced by careful attention to the correct operation of the boiler, and the removal of water droplets carrying impurities from the boiler.

Fig. 2.5.3 Heat transfer layers

Filmwise condensation
The elimination of the condensate film, is not quite as simple. As the steam condenses to give up its enthalpy of evaporation, droplets of water may form on the heat transfer surface. These may then merge together to form a continuous film of condensate. The condensate film may be between 100 and 150 times more resistant to heat transfer than a steel heating surface, and 500 to 600 times more resistant than copper.

Dropwise condensation
If the droplets of water on the heat transfer surface do not merge immediately and no continuous condensate film is formed, 'dropwise' condensation occurs. The heat transfer rates which can be achieved during dropwise condensation, are generally much higher than those achieved during filmwise condensation. As a larger proportion of the heat transfer surface is exposed during dropwise condensation, heat transfer coefficients may be up to ten times greater than those for filmwise condensation. In the design of heat exchangers where dropwise condensation is promoted, the thermal resistance it produces is often negligible in comparison to other heat transfer barriers. However, maintaining the appropriate conditions for dropwise condensation have proved to be very difficult to achieve. If the surface is coated with a substance that inhibits wetting, it may be possible to maintain dropwise condensation for a period of time. For this purpose, a range of surface coatings such as Silicones, PTFE and an assortment of waxes and fatty acids are sometimes applied to surfaces in a heat exchanger on which condensation is to be promoted. However, these coatings will gradually lose their effectiveness due to processes such as oxidation or fouling, and film condensation will eventually predominate. As air is such a good insulator, it provides even more resistance to heat transfer. Air may be between 1 500 and 3 000 times more resistant to heat flow than steel, and 8 000 to 16 000 more resistant than copper. This means that a film of air only 0.025 mm thick may resist as much heat transfer as a wall of copper 400 mm thick! Of course all of these comparative relationships depend on the temperature profiles across each layer. Figure 2.5.4 illustrates the effect this combination of layers has on the heat transfer process. These barriers to heat transfer not only increase the thickness of the entire conductive layer, but also greatly reduce the mean thermal conductivity of the layer. The more resistant the layer to heat flow, the larger the temperature gradient is likely to be. This means that to achieve the same desired product temperature, the steam pressure may need to be significantly higher. The presence of air and water films on the heat transfer surfaces of either process or space heating applications is not unusual. It occurs in all steam heated process units to some degree. To achieve the desired product output and minimise the cost of process steam operations, a high heating performance may be maintained by reducing the thickness of the films on the condensing surface. In practice, air will usually have the most significant effect on heat transfer efficiency, and its removal from the supply steam will increase heating performance.

Fig. 2.5.4 Temperature gradients across heat transfer layers Top

Defining the overall heat transfer coefficient (U value)

The five main most commonly related terms associated with the subject of heat transfer are:

1. Heat flowrate (W) 2. Thermal conductivity k (W / mC) 3. Thermal resistivity r (mC / W) 4. Thermal resistance R (m C / W) 5. Thermal transmittance U (W / m C)
The following text in this Tutorial describes them and how they are related to each other. The traditional method for calculating heat transfer across a plane wall considers the use of an overall heat transfer coefficient 'U', or more correctly, the overall thermal transmittance between one side of the wall and the other. U values are quoted for a wide range and combination of materials and fluids and are usually influenced by empirical data and operating experience. The previously mentioned films of condensate, air, scale, and product either side of the metal wall can have a significant effect on the overall thermal transmittance and because of this, it is worth considering the whole issue of heat transfer across a simple plane wall and then a multi-layer barrier.

Heat transfer by conduction through a simple plane wall

A good way to start is by looking at the simplest possible case, a metal wall with uniform thermal properties and specified surface temperatures.

Fig. 2.5.5 Conductive heat transfer through a plane wall T 1 and T 2 are the surface temperatures either side of the metal wall, of thickness L; and the temperature difference between the two surfaces is T. Ignoring the possible resistance to heat flow at the two surfaces, the process of heat flow through the wall can be derived from Fourier's law of conduction as shown in Equation 2.5.1. The term 'barrier' refers to a heat resistive film or the metal wall of a heat exchanger.

Equation 2.5.1 Where:

= Heat transferred per unit time (W) A = Heat transfer area (m) k = Thermal conductivity of the barrier (W / m K or W / mC) T = Temperature difference across the barrier (K or C) = Barrier thickness (m)

It is possible to rearrange Equation 2.5.1 into Equation 2.5.6.

Equation 2.5.6 Where:

= Heat transferred per unit time (W) A = Heat transfer area (m) T = Temperature difference across the barrier (C) = Barrier thickness / material thermal conductivity

It can be seen from their definitions in Equation 2.5.6 that

is the thickness of the barrier divided by its inherent property of thermal will increase, and if the value of the barrier

conductivity. Simple arithmetic dictates that if the length ( ) of the barrier increases, the value

conductivity (k) increases, then the value of will decrease. A characteristic that would behave in this fashion is that of thermal resistance. If the length of the barrier increases, the resistance to heat flow increases; and if the conductivity of the barrier material increases the resistance to heat flow decreases. It can be concluded that the term in Equation 2.5.6 relates to the thermal resistance of a barrier of known length.

The results of simple electrical theory parallel the equations appertaining to heat flow. In particular, the concept of adding resistances in series is possible, and is a useful tool when analysing heat transfer through a multi-layer barrier, as will be seen in a later section of this tutorial. Equation 2.5.6 can now be restated in terms of thermal resistance, where:

as shown in Equation 2.5.7

Equation 2.5.7 Where:

= Heat transferred per unit time (W) A = Heat transfer area (m) T = Temperature difference across the barrier (C) R = Thermal resistance of the barrier (m C / W)
Thermal resistance denotes a characteristic of a particular barrier, and will change in accordance to its thickness and conductivity. In contrast, the barrier's ability to resist heat flow does not change, as this is a physical property of the barrier material. This property is called 'thermal resistivity'; it is the inverse of thermal conductivity and is shown in Equation 2.5.8.

Equation 2.5.8 Where:

r = Thermal resistivity (mC / W) k = Thermal conductivity (W / mC)

Relating the overall resistance to the overall U value

The usual problem that has to be solved in heat transfer applications is the rate of heat transfer, and this can be seen from the general heat transfer formula, Equation 2.5.3.

Equation 2.5.3 Where: U = The overall thermal transmittance (W / m C) By comparing Equations 2.5.3 and 2.5.7, it must be true that:

and therefore,

Equation 2.5.9 Therefore, U value (thermal transmittance) is the inverse of resistance.

Heat flow through a multi-layer barrier

As seen in Figure 2.5.4, a practical application would be the metal wall of a heat exchanger tube or plate which uses steam on one side to heat water on its other. It can also be seen that various other barriers are present slowing down the heat flow, such as an air film, a condensate film, a scale film, and a stationary film of secondary water immediately adjacent to the heating surface. These films can be thought of as 'fouling' the flow of heat through the barrier, and consequently these resistances are considered by heat exchanger designers as 'fouling factors'. All of these films, in addition to the resistance of the metal wall, constitute a resistance to heat flow and, as in an electrical circuit, these resistances can be added to form an overall resistance. Therefore:

Equation 2.5.10 Where:

R1 = Resistance of the air film R2 = Resistance of the condensate film R3 = Resistance of the scale film on the steam side R4 = Resistance of the of the metal wall R5 = Resistance of the scale film on the water side R6 = Resistance of the product film
As resistance is as shown in Equation 2.5.6, then Equation 2.5.10 can be rewritten as Equation 2.5.11:

Equation 2.5.11

Table 2.5.2 Typical thermal conductivities of various materials The thermal conductivities will alter depending on the film material (and temperature). For instance, air roughly has thirty times greater resistance to heat flow than water. For this reason, it is relatively more important to remove air from the steam supply before it reaches the heat exchanger, than to remove water in the form of wet steam. Of course, it is still sensible to remove wet steam at the same time. The resistance of air to steel is roughly two thousand times more, and the resistance of air to copper is roughly twenty thousand times more. Because of the high resistances of air and water to that of steel and copper, the effect of small thicknesses of air and water on the overall resistance to heat flow can be relatively large. There is no point in changing a steel heat transfer system to copper if air and water films are still present; there will be little improvement in performance, as will be proven in Example 2.5.5. Air and water films on the steam side can be eradicated by good engineering practice simply by installing a separator and float trap set in the steam supply prior the control valve. Scale films on the steam side can also be reduced by fitting strainers in the same line. Scale on the product side is a little more difficult to treat, but regular cleaning of heat exchangers is sometimes one solution to this problem. Another way to reduce scaling is to run heat exchangers at lower steam pressures; this reduces the steam temperature and the tendency for scale to form from the product, especially if the product is a solution like milk.

Example 2.5.5
Consider a steam to water heat exchanger where the air film, condensate film and scale on the steam side is 0.2 mm thick; on the water side, the water and scale films are 0.05 mm and 0.1 mm thick respectively. The thickness of the steel walled heating surface is 6 mm.

Table 2.5.3 The resistance of the barriers including steel tube From Equation 2.5.6: 1. Calculate the overall U value (U1) from the conditions shown in Table 2.5.3

Equation 2.5.11

2. Remove the air and the condensate from the steam supply Now consider the same heat exchanger where the air and condensate have been removed by a separator in the steam supply. Calculate U2

It can be seen from U2 that by fitting a separator in the steam supply to this heat exchanger, and assuming that all air and condensate has been removed from the steam, the thermal transmittance is more than 11 times greater than the original value.

3. Remove the scale on the steam and water sides Now consider reducing the scale on the steam side by fitting a strainer in the steam line, and reducing the scale on the water side by operating at a lower steam pressure.

The thermal transmittance has increased another fourfold by eradicating the scale. 4. Revert to the original conditions but change from steel tube to copper tube of the same thickness.

Table 2.5.4 The resistance of the barriers including copper tube

It can be seen that the greater conductivity offered by the copper over the steel has made very little difference to the overall thermal transmittance of the heat exchanger, due to the dominating effect of the air and other fouling factors. Please note that, in practice, other factors will influence the overall U value, such as the velocities of the steam and water passing through the heat exchanger tubes or plates, and the combination of heat transfer by convection and radiation. Also, it is unlikely that the fitting of a separator and strainer will completely eradicate the presence of air, wet steam, and scale from inside a heat exchanger. The above calculations are only being shown to highlight the effects of these on heat transfer. However, any attempt to remove such barriers from the system will generally prove successful, and is virtually guaranteed to increase heat transfer in steam heating plant and equipment as soon as this is done. Rather than having to calculate individual resistances of film barriers, Tables exist showing overall U values for different types of heat exchange application such as steam coil heating of water or oil. These are documented in Tutorial 2.10, 'Heating with coils and jackets'. U values for heat exchangers vary considerably due to factors such as design ('shell and tube' or 'plate and frame' construction), material of construction, and the type of fluids involved in the heat transfer function.

Methods of Estimating Steam Consumption

How to calculate steam requirements for flow and non-flow applications. Including warm-up, heat losses and running loads. Use the quick links below to take you to the main sections of this tutorial:

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Contact Us The optimum design for a steam system will largely depend on whether the steam consumption rate has been accurately established. This will enable pipe sizes to be calculated, while ancillaries such as control valves and steam traps can be sized to give the best possible results. The steam demand of the plant can be determined using a number of different methods:

Calculation - By analysing the heat output on an item of plant using heat transfer equations, it may be possible to obtain an estimate for the steam consumption. Although heat transfer is not an exact science and there may be many unknown variables, it is possible to utilise previous experimental data from similar applications. The results acquired using this method are usually accurate enough for most purposes. Measurement - Steam consumption may be determined by direct measurement, using flowmetering equipment. This will provide relatively accurate data on the steam consumption for an existing plant. However, for a plant which is still at the design stage, or is not up and running, this method is of little use. Thermal rating - The thermal rating (or design rating) is often displayed on the name-plate of an individual item of plant, as provided by the manufacturers. These ratings usually express the anticipated heat output in kW, but the steam consumption required in kg/h will depend on the recommended steam pressure.

A change in any parameter which may alter the anticipated heat output, means that the thermal (design) rating and the connected load (actual steam consumption) will not be the same. The manufacturer's rating is an indication of the ideal capacity of an item and does not necessarily equate to the connected load.

Calculation
In most cases, the heat in steam is required to do two things:

To produce a change in temperature in the product, that is providing a 'heating up' component. To maintain the product temperature as heat is lost by natural causes or by design, that is providing a 'heat loss' component.

In any heating process, the 'heating up' component will decrease as the product temperature rises, and the differential temperature between the heating coil and the product reduces. However, the heat loss component will increase as the product temperature rises and more heat is lost to the environment from the vessel or pipework. The total heat demand at any time is the sum of these two components. The equation used to establish the amount of heat required to raise the temperature of a substance (Equation 2.1.4, from Tutorial 2.1), can be developed to apply to a range of heat transfer processes. Equation 2.1.4 Where:

Q = Quantity of energy (kJ) m = Mass of the substance (kg) cp = Specific heat capacity of the substance (kJ/kg C ) T = Temperature rise of the substance (C)
In its original form this equation can be used to determine a total amount of heat energy over the whole process. However, in its current form, it does not take into account the rate of heat transfer. To establish the rates of heat transfer, the various types of heat exchange application can be divided into two broad categories:

Top

Non-flow type applications - where the product being heated is a fixed mass and a single batch within the confines of a vessel. Flow type applications - where a heated fluid constantly flows over the heat transfer surface.

Non-flow type applications

In non-flow type applications the process fluid is held as a single batch within the confines of a vessel. A steam coil situated in the vessel, or a steam jacket around the vessel, may constitute the heating surface. Typical examples include hot water storage calorifiers as shown in Figure 2.6.1 and oil storage tanks where a large circular steel tank is filled with a viscous oil requiring heat before it can be pumped. Some processes are concerned with heating solids; typical examples are tyre presses, laundry ironers, vulcanisers and autoclaves. In some non-flow type applications, the process heat up time is unimportant and ignored. However, in others, like tanks and vulcanisers, it may not only be important but crucial to the overall process.

Fig. 2.6.1 Hot water storage - a non-flow application Consider two non-flow heating processes requiring the same amount of heat energy but different lengths of time to heat up. The heat transfer rates would differ while the amounts of total heat transferred would be the same. The mean rate of heat transfer for such applications can be obtained by modifying Equation 2.1.4 to Equation 2.6.1:

Equation 2.6.1 Where:

= Mean heat transfer rate (kW (kJ/s) m = Mass of the fluid (kg) cp = Specific heat capacity of the fluid (kJ/kg C) T = Increase in fluid temperature (C) t = Time for the heating process (seconds)
Example 2.6.1
Calculating the mean heat transfer rate in a non-flow application. A quantity of oil is heated from a temperature of 35C to 120C over a period of 10 minutes (600 seconds). The volume of the oil is 35 litres, its specific gravity is 0.9 and its specific heat capacity is 1.9 kJ/kg C over that temperature range. Determine the rate of heat transfer required: As the density of water at Standard Temperature and Pressure (STP) is 1 000 kg/m

Equation 2.6.1 can be applied whether the substance being heated is a solid, a liquid or a gas. However, it does not take into account the transfer of heat involved when there is a change of phase. The quantity of heat provided by the condensing of steam can be determined by Equation 2.6.2:

Equation 2.6.2 Where:

Q = Quantity of heat (kJ) ms = Mass of steam (kg) hfg = Specific enthalpy of evaporation of steam (kJ/kg)
It therefore follows that the steam consumption can be determined from the heat transfer rate and vice-versa, from Equation 2.6.3: Equation 2.6.3 Where:

= Mean heat transfer rate (kW or kJ/s) s = Mean steam consumption (kg/s) hfg = Specific enthalpy of evaporation of steam (kJ/kg)
If it is assumed at this stage that the heat transfer is 100% efficient, then the heat provided by the steam must be equal to the heat requirement of the fluid to be heated. This can then be used to construct a heat balance, in which the heat energy supplied and required are equated: Primary side = = Secondary side

Equation 2.6.4 Where:

= Mean steam consumption rate (kg/s) hfg = Specific enthalpy of evaporation of steam (kJ/kg) = Mean heat transfer rate (kW (kJ/s)) m = Mass of the secondary fluid (kg) cp = Specific heat capacity of the secondary fluid (kJ/kg C) T = Temperature rise of the secondary fluid (C)
s

= Time for the heating process

Example 2.6.2
A tank containing 400 kg of kerosene is to be heated from 10C to 40C in 20 minutes (1 200 seconds), using 4 bar g steam. The kerosene has a specific heat capacity of 2.0 kJ/kg C over that temperature range. hfg at 4.0 bar g is 2 108.1 kJ/kg. The tank is well insulated and heat losses are negligible. Determine the steam flowrate

In some non-flow type applications, the length of time of the batch process may not be critical, and a longer heat up time may be acceptable. This will reduce the instantaneous steam consumption and the size of the required plant equipment. Top

Flow type applications

Typical examples include shell and tube heat exchangers, see Figure 2.6.2 (also referred to as non-storage calorifiers) and plate heat exchangers, providing hot water to heating systems or industrial processes. Another example would be an air heater battery where steam gives up its heat to the air that is constantly passing through.

Fig 2.6.2 Non-storage calorifier Figure 2.6.3 provides a typical temperature profile in a heat exchanger with a constant secondary fluid flowrate. The condensing temperature (T s) remains constant throughout the heat exchanger. The fluid is heated from T 1 at the inlet valve to T 2 at the outlet of the heat exchanger.

Fig. 2.6.3 Typical temperature profile in a heat exchanger For a fixed secondary flowrate, the required heat load ( ) is proportional to the product temperature rise (T). Using Equation 2.6.1:

Equation 2.6.1

As flowrate is mass flow per unit time, the secondary flowrate is depicted in equation 2.6.1 as:

This can be represented by

, where

is the secondary fluid flowrate in kg/s, and is shown in equation 2.6.5.

Equation 2.6.5 Where:

= Mean heat transfer rate (kW) = Mean secondary fluid flowrate (kg/s) cp = Specific heat capacity of the secondary fluid (kJ/kg K) or (kJ/kgC) T = Temperature rise of the secondary fluid (K or C)
A heat balance equation can be constructed for flow type applications where there is a continuous flow of fluid: Primary side = = Secondary side

Equation 2.6.6 Where: Mean steam consumption rate (kg/s)

= hfg = Specific enthalpy of evaporation of steam (kJ/kg) = Mean heat transfer rate (kW (kJ/s)) = Mass flowrate of the secondary fluid (kg/s) cp = Specific heat capacity of the secondary fluid (kJ/kg C) T = Temperature rise of the secondary fluid (C)
s Mean steam consumption
The mean steam consumption of a flow type application like a process heat exchanger or heating calorifier can be determined from Equation 2.6.6, as shown in Equation 2.6.7.

Equation 2.6.7 Where:

= Mean steam consumption rate (kg/s) = Mass flowrate of the secondary fluid (kg/s) cp = Specific heat capacity of the secondary fluid (kJ/kg C) T = Temperature rise of the secondary fluid (C) hfg = Specific enthalpy of evaporation of steam (kJ/kg)
s
Equally, the mean steam consumption can be determined from Equation 2.6.6 as shown in Equation 2.6.8.

Equation 2.6.8 But as the mean heat transfer is, itself, calculated from the mass flow, the specific heat, and the temperature rise, it is easier to use Equation 2.6.7.

Example 2.6.3
Dry saturated steam at 3 bar g is used to heat water flowing at a constant rate of 1.5 l/s from 10C to 60C. hfg at 3 bar g is 2 133.4 kJ/kg, and the specific heat of water is 4.19 kJ/kg C Determine the steam flowrate: As 1 litre of water has a mass of 1 kg, the mass flowrate = 1.5 kg/s

Equation 2.6.7

At start-up, the inlet temperature, T 1 may be lower than the inlet temperature expected at the full running load, causing a higher heat demand. If the warm-up time is important to the process, the heat exchanger needs to be sized to provide this increased heat demand. However, warm-up loads are usually ignored in flow type design calculations, as start-ups are usually infrequent, and the time it takes to reach design conditions is not too important. The heat exchanger heating surface is therefore usually sized on the running load conditions. In flow type applications, heat losses from the system tend to be considerably less than the heating requirement, and are usually ignored. However, if heat losses are large, the mean heat loss (mainly from distribution pipework) should be included when calculating the heating surface area.

Warm-up and heat loss components

In any heating process, the warm-up component will decrease as the product temperature rises, and the differential temperature across the heating coil reduces. However, the heat loss component will increase as the product and vessel temperatures rise, and more heat is lost to the environment from the vessel or pipework. The total heat demand at any time is the sum of these two components. If the heating surface is sized only with consideration of the warm-up component, it is possible that not enough heat will be available for the process to reach its expected temperature. The heating element, when sized on the sum of the mean values of both these components, should normally be able to satisfy the overall heat demand of the application. Sometimes, with very large bulk oil storage tanks for example, it can make sense to maintain the holding temperature lower than the required pumping temperature, as this will reduce the heat losses from the tank surface area. Another method of heating can be employed, such as an outflow heater, as shown in Figure 2.6.4.

Fig. 2.6.4 An outflow heater Heating elements are encased in a metal shroud protruding into the tank and designed such that only the oil in the immediate vicinity is drawn in and heated to the pumping temperature. Heat is therefore only demanded when oil is drawn off, and since the tank temperature is lowered, lagging can often be dispensed with. The size of outflow heater will depend on the temperature of the bulk oil, the pumping temperature and the pumping rate. Adding materials to open topped process tanks can also be regarded as a heat loss component which will increase thermal demand. These materials will act as a heat sink when immersed, and they need to be considered when sizing the heating surface area. Whatever the application, when the heat transfer surface needs calculating, it is first necessary to evaluate the total mean heat transfer rate. From this, the heat demand and steam load may be determined for full load and start-up. This will allow the size of the control valve to be based on either of these two conditions, subject to choice.

Measurement of Steam Consumption

Methods of measuring steam consumption, from the very basic to sophisticated flow metering, are explained in this tutorial. Use the quick links below to take you to the main sections of this tutorial:

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By a steam flowmeter
The use of a steam flowmeter may be used to directly measure the steam usage of an operational item of plant. This may be used to monitor the results of energy saving schemes and to compare the efficiency of one item of plant with another. The steam can then be costed as a raw material at any stage of the production process, so that the cost of individual product lines may be determined. It is only in comparatively rare cases that a meter cannot measure steam flow. Care should be taken, however, to ensure that the prevailing

steam pressure is considered and that no other calibration factor has been overlooked. Steam flowmetering is discussed in detail in Block 4.

Fig. 2.7.1 Typical steam flowmeter installation Top

By a condensate pump
A less accurate method of estimating the steam consumption is by incorporating a counter into the body of a positive displacement pump used to pump condensate from the process. Each discharge stroke is registered, and an estimate of the capacity of each stroke is used to calculate the amount of steam condensed over a given time period.

Fig. 2.7.2 Positive displacement pump with cycle counter A purpose built electronic pump monitor can be used which enables this to be carried out automatically, converting the pump into a condensate meter. The electronic pump monitor can be read locally or can return digital data to a central monitoring system. If the pump is draining a vented receiver, a small allowance has to be made for flash steam losses. Top

By collecting the condensate

Steam consumption can also be established directly, by measuring the mass of condensate collected in a drum over a period of time. This may provide a more accurate method than using theoretical calculations if the flash steam losses (which are not taken into account) are small, and can work for both non-flow and flow type applications. However, this method cannot be used in direct steam injection applications, humidification or sterilisation processes, where it is not possible to collect the condensate. Figure 2.7.3 shows a test being carried out on a jacketed pan. In this case an empty oil drum and platform scales are shown, but smaller plant can be tested just as accurately using a bucket and spring balance. This method is quite easy to set up and can be relied upon to give accurate results.

Fig. 2.7.3 Equipment for measurement of steam consumption The drum is first weighed with a sufficient quantity of cold water. Steam is then supplied to the plant, and any condensate is discharged below the water level in the container to condense any flash steam. By noting the increase in weight over time, the mean steam consumption can be determined. Although this method gives the mean rate of steam consumption, if the weight of condensate is noted at regular intervals during the test, the corresponding steam consumption rates can be calculated. Any obvious peaks will become apparent and can be taken into account when deciding on the capacity of associated equipment. It is important to note that the test is conducted with the condensate discharging into an atmospheric system. If the test is being used to quantify steam consumption on plant that would otherwise have a condensate back pressure, the steam trap capacity must relate to the expected differential pressure. Care must also be taken to ensure that only condensate produced during the test run is measured. In the case of the boiling pan shown, it would be wise to drain the jacket completely through the drain cock before starting the test. At the end, drain the jacket again and add this condensate to that in the container before weighing. The test should run for as long as possible in order to reduce the effect of errors of measurement. It is always advisable to run three tests under similar conditions and average the results in order to get a reliable answer. Discard any results that are widely different from the others and, if necessary, run further tests. If the return system includes a collecting tank and pump, it may be possible to stop the pump for a period and measure condensate volume by carefully dipping the tank before and after a test period. Care must be taken here, particularly if the level change is small or if losses occur due to flash steam.

Thermal Rating
Design ratings for items of plant can be both helpful and misleading, as changing any factor can alter the predicted heat output. Also, how to calculate steam load requirements from the kW rating.

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Contact Us Some items of manufactured plant are supplied with information on thermal output. These design ratings can be both helpful and misleading. Ratings will usually involve raising a stated amount of air, water or other fluid through a given temperature rise, using steam at a specified pressure. They are generally published in good faith with a reasonable allowance for fouling of the heat transfer surface. It must be clear that changing any factor at all will alter the predicted heat output and thereby the steam consumption. A secondary fluid which is colder than specified will increase the demand, while steam at less than the specified pressure will reduce the ability to transfer heat. Temperature and pressure can often be measured easily so that corrections can be applied. However, flowrates of air, water and other fluids may be far more difficult to measure. Undetected fanbelt slip or pump impeller wear can also lead to discrepancies, while lower than expected resistances applied to pumps and fans can cause flowrates to be higher than the design values. A more common source of error arises from the assumption that the manufacturer's rating equates to actual load. A heat exchanger may be capable of meeting or exceeding a given duty, but the connected load may often only be a fraction of this. Clearly it is useful to have information on the thermal rating of plant, but care must be taken when relating this to an actual heat load. If the load is quoted in kW, and the steam pressure is given, then steam flowrate may be determined as shown in Equation 2.8.1:

Equation 2.8.1

Fig. 2.8.1 Typical heat exchanger manufacturers name-plate

Energy Consumption of Tanks and Vats

The heating of liquids in tanks and vats is an important requirement in process industries. There are many types of tank with different uses. Determination of heat requirements, heat transfer and heat loss calculations are all covered in this tutorial.

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Contact Us The heating of liquids in tanks is an important requirement in process industries such as the dairy, metal treatment and textile industries. Water may need to be heated to provide a hot water utility; alternatively, a liquid may need to be heated as part of the production process itself, whether or not a chemical reaction is involved. Such processes may include boiler feedtanks, wash tanks, evaporators, boiling pans, coppers, calandrias and reboilers. Tanks are often used for heating processes, of which there are two major categories:

Totally enclosed tanks, such as those used for storing fuel oil, and where heat load calculations are generally straightforward. Open topped tanks, where heat load calculations may be complicated by the introduction of articles and materials, or by evaporative losses.

Open and closed tanks are used for a large number of process applications: Boiler feedtanks - The boiler feedtank is at the heart of any steam generation system. It provides a reservoir of returned condensate and treated make-up water, for feeding the boiler. One reason for heating the water is to reduce oxygen entering the boiler, with (theoretically) 0 ppm oxygen at 100C. Boiler feedtanks are normally operated at between 80C and 90C.

o o

Hot water tanks - Hot water is required for a number of processes in industry. It is often heated in simple, open or closed tanks which use steam as the heating medium. The operating temperature can be anywhere between 40C and 85C depending on the application. Degreasing tanks - Degreasing is the process where deposits of grease and cooling oil are removed from metal surfaces, after machining and prior to the final assembly of the product. In a degreasing tank, the material is dipped into a solution, which is heated by coils to a temperature of between 90C and 95C. Metal treatment tanks - Metal treatment tanks, which are sometimes called vats, are used in a number of different processes: To remove scale or rust. To apply a metallic coating to surfaces.

The treatment temperatures typically range from 70C to 85C. Oil storage tanks - Storage tanks are required to hold oils which cannot be pumped at ambient temperatures, such as heavy fuel oil for boilers. At ambient temperatures, heavy oil is very thick and must be heated to 30C - 40C in order to reduce its viscosity and allow it to be pumped. This means that all heavy oil storage tanks need to be provided with heating to facilitate pumping. Heating tanks used in process industries - Heating tanks are used by a number of process industries, see Table 2.9.1.

Table 2.9.1 Process industries which use heating tanks In some applications the process fluid may have achieved its working temperature, and the only heat requirement may be due to losses from the solid surface of the walls and/or the losses from the liquid surface. This Tutorial will deal with the calculations which determine the energy requirements of tanks: the following two Tutorials (2.10 and 2.11) will deal with how this energy may be provided. When determining the heat requirement of a tank or vat of process fluid, the total heat requirement may consist of some or all of a number of key components:

The heat required to raise the process fluid temperature from cold to its operating temperature. The heat required to raise the vessel material from cold to its operating temperature. The heat lost from the solid surface of the vessel to the atmosphere. The heat lost from the liquid surface exposed to the atmosphere. The heat absorbed by any cold articles dipped into the process fluid.

However, in many applications only some of the above components will be significant. For example, in the case of a totally enclosed wellinsulated bulk oil storage tank, the total heat requirement may be made up almost entirely of the heat required to raise the temperature of the fluid. Items 1 and 2, the energy required to raise the temperature of the liquid and the vessel material, and item 5, the heat absorbed by any cold articles dipped into the process fluid, can be found by using the Equation 2.6.1. Generally, data can be accurately defined, and hence the calculation of the heat requirement is straightforward and precise.

Equation 2.6.1 Items 3 and 4, the heat losses from the vessel and liquid surfaces can be determined by using Equation 2.5.3. However, heat loss calculations are much more complex, and usually empirical data, or tables based on several assumptions have to be relied upon. It follows that heat loss calculations are less accurate.

Equation 2.5.3

Heat loss from the solid surface of the vessel to the atmosphere
Heat will only be transferred provided there is a difference in temperature between the surface and the ambient air. Figure 2.9.1 provides some typical overall heat transfer coefficients for heat transfer from bare steel flat surfaces to ambient air. If the bottom of the tank is not exposed to ambient air, but is positioned flat on the ground, it is usual to consider this component of the heat loss to be negligible, and it may safely be ignored.

For 25 mm of insulation, the U value should be multiplied by a factor of 0.2. For 50 mm of insulation, the U value should be multiplied by a factor of 0.1.

The overall heat transfer coefficients provided in Figure 2.9.1 are for 'still air' conditions only.

Fig. 2.9.1 Typical overall heat transfer coefficients from flat steel surfaces Table 2.9.2 shows multiplication factors which need to be applied to these values if an air velocity is being taken into account. However, if the surface is well insulated, the air velocity is not likely to increase the heat loss by more than 10% even in exposed conditions.

Table 2.9.2 Effect on heat transfer with air movement Velocities of less than 1 m/s can be considered as sheltered conditions, whilst 5 m/s may be thought of as a gentle breeze (about 3 on the Beaufort scale), 10 m/s a fresh breeze (Beaufort 5), and 16 m/s a moderate gale (Beaufort 7). For bulk oil storage tanks, the overall heat transfer coefficients quoted in Table 2.9.3 may be used.

Table 2.9.3 Overall heat transfer coefficients for oil tanks

Water tanks: heat loss from the water surface to the atmosphere
Figure 2.9.2 relates heat loss from a water surface to air velocity and surface temperature. In this chart 'still' air is considered to have a velocity of 1 m/s, tanks in sheltered positions outdoors consider velocities at about 4 m/s, whilst tanks in exposed positions outdoors are considered with velocities at about 8 m/s. This chart provides the heat loss in W/m rather than the units of the overall heat transfer coefficient of W/mC. This means that this value must be multiplied by the surface area to provide a rate of heat transfer, as the water to air temperature difference has already been taken into account. Heat losses from the water surface, as shown in Figure 2.9.2 are not significantly affected by the humidity of the air. The full range of humidities likely to be encountered in practice is covered by the thickness of the curve. However, the graph considers heat losses with an air temperature of 15.6C and 55% air humidity. Different conditions to these can be calculated from theCalculators on this website. To determine the heat loss from the chart, the water surface temperature must be selected from the top scale. A line should then be projected vertically downwards to the (bold) heat loss curve. For indoor tanks a line should be projected horizontally from the intersection to the left-hand scale. For outdoor tanks a horizontal line should be projected either left or right until it intersects the required location, either sheltered or exposed. A projection vertically downwards will then reveal the heat loss on the bottom scale. In most cases, the heat loss from the liquid surface is likely to be the most significant heat loss element. Where practical, heat loss can be limited by covering the liquid surface with a layer of polystyrene spheres which provide an insulating 'blanket'. Any solution to reduce heat losses becomes even more important when tanks are located outside in exposed positions as portrayed by the graph in Figure 2.9.2.

Fig. 2.9.2 Heat loss from water surfaces

Example 2.9.1
For the tank shown in Figure 2.9.3, determine: Part 1. The mean heat transfer rate required during start-up. Part 2. The maximum heat transfer rate required during operation.

Fig. 2.9.3

The tank is unlagged and open topped and is situated on a concrete floor inside a factory. It is 3 m long by 3 m wide by 2 m high. Tank total surface area = 24 m (excluding base). Heat transfer coefficient from tank/air, U1 = 11 W/mC. The tank is /3 full of a weak acid solution (cp = 3.9 kJ/kgC) which has the same density as water (1 000 kg/m)

The tank is fabricated from 15 mm mild steel plate. (Density = 7 850 kg/m, cp = 0.5 kJ/kgC) The tank is used on alternate days, when the solution needs to be raised from the lowest considered ambient temperature of 8 C to 60C in 2 hours, and remain at that temperature during the day. When the tank is up to temperature, a 500 kg steel article is to be dipped every 20 minutes without the tank overflowing. (cp = 0.5 kJ/kgC)
M (start-up)

Part 1 Determine the mean heat transfer rate required during start-up This is the sum of: A1. Heating the liquid
M (liquid)

A2. Heating the tank material

M (tank)

A3. Heat losses from the sides of the tank A4. Heat losses from the liquid surface Part 1.1 Heating the liquid
M (liquid)

M (sides)

M (surface)

Equation 2.6.1

Equation 2.5.3 Where: T is the mean temperature difference T M

Part 2 Determine the running load, that is the maximum heat transfer rate required during operation

(operation)

In operating conditions, the liquid and tank (A1 and A2, from Part 1) are already up to operating temperature, so the heating components = 0. In operating conditions, the heat losses from the liquid and tank (A3 and A4, from Part 1) will be greater. This is because of the greater difference between the liquid and tank temperatures and the surroundings.

Immersing the article in the liquid is clearly the objective of the process, so this heat load must be calculated and added to the running load heat losses.

Part 2.1 Heat losses from tank sides

Equation 2.5.3 Where:

Equation 2.6.1

Note that the operational energy requirement (59 kW) is significantly less than the start-up energy requirement (367 kW). This is typical, and, where possible, the start-up period may be extended. This will have the effect of reducing the maximum energy flowrate and has the benefits of levelling demand on the boiler, and making less demand on the temperature control system. For tanks that are to operate continuously, it is often only necessary to calculate the operating requirements i.e. the Part 2 calculations.

Heating with Coils and Jackets

Indirect heating of fluids is covered in this tutorial including layouts, control and drainage of coils and jackets, and heat transfer calculations.

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Contact Us Vessels can be heated in a number of different ways. This tutorial will deal with indirect heating. In these systems, the heat is transferred across a heat transfer surface. Options include:

Submerged steam coils - A widely used form of heat transfer involves the installation inside a tank of a steam coil immersed in a process fluid. Steam jackets - Steam circulates in the annular space between a jacket and the vessel walls, and heat is transferred through the wall of the vessel.

Submerged steam coils

The use of tank coils is particularly common in marine applications where cargoes of crude oil, edible oils, tallow and molasses are heated in deep tanks. Many of these liquids are difficult to handle at ambient temperatures due to their viscosity. Steam heated coils are used to raise the temperature of these liquids, lowering their viscosity so that they become easier to pump. Tank coils are also extensively used in electroplating and metal treatment. Electroplating involves passing articles through several process tanks so that metallic coatings can be deposited on to their surfaces. One of the first stages in this process is known as pickling, where materials such as steel and copper are treated by dipping them in tanks of acid or caustic solution to remove any scale or oxide (e.g. rust) which may have formed.

Steam coil sizing

Having determined the energy required (in Tutorial 2.9), and with knowledge of the steam pressure/temperature in the coil, the heat transfer surface may be determined using Equation 2.5.3:

Equation 2.5.3 The heat transfer area calculated is equivalent to the surface area of the coil, and will enable an appropriate size and layout to be specified.

Determining the 'U' value

To calculate the heat transfer area, a value for the overall heat transfer coefficient, U, must be chosen. This will vary considerably with the thermal and transport properties of both fluids and a range of other conditions. On the product side of the coil a thermal boundary layer will exist in which there is a temperature gradient between the surface and the bulk fluid. If this temperature difference is relatively large, then the natural convective currents will be significant and the heat transfer coefficient will be high. Assisted circulation (such as stirring) that will induce forced convection, will also result in higher coefficients. As convection is partially dependent on the bulk motion of the fluid, the viscosity (which varies with temperature) also has an important bearing on the thermal boundary layer. Additional variations can also occur on the steam side of the coil, especially with long lengths of pipe. The coil inlet may have a high steam velocity and may be relatively free from water. However, further along the length of the coil the steam velocity may be lower, and the coil may be running partially full of water. In very long coils, such as those sometimes found in seagoing tankers or in large bulk storage tanks, a significant pressure drop occurs along the length of the coil. To acheive the mean coil temperature, an average steam pressure of approximately 75% of the inlet pressure may be used. In extreme cases the average pressure used may be as low as 40% of the inlet pressure. Another variable is the coil material itself. The thermal conductivity of the coil material may vary considerably. However, overall heat transfer is governed to a large extent by the heat resistant films, and the thermal conductivity of the coil material is not as significant as their combined effect. Table 2.10.1 provides typical overall heat transfer coefficients for various conditions of submerged steam coil application. 'U' values for steam pressures between 2 bar g and 6 bar g should be found by interpolation of the data in the table.

The range of figures shown in Table 2.10.1 demonstrates the difficulty in providing definitive 'U' values. Customary figures at the higher end of the scale will apply to installations that are supplied with clean dry steam, small coils and good condensate drainage. The lower end is more applicable to poor quality steam, long coils and poor condensate drainage. The recommended overall heat transfer coefficients will apply to typical conditions and installations. These recommended rates are empirically derived, and will generally ensure that a generous safety margin applies to the coil sizing. In the case of fluids other than water, the heat transfer coefficient will vary even more widely due to the way in which viscosity varies with temperature. However, the values shown in Table 2.10.2 will serve as a guide for some commonly encountered substances, while Table 2.10.3 gives typical surface areas of pipes per metre length.

Example 2.10.1
Continuing from Example 2.9.1 determine: Part 1. The average steam mass flowrate during start-up. (Mean heat load = 367 kW) Part 2. The heat transfer area required. Part 3. A recommended coil surface area. Part 4. The maximum steam mass flowrate with the recommended heat transfer area. Part 5. A recommendation for installation, including coil diameter and layout. The following additional information has been provided:

Steam pressure onto the control valve = 2.6 bar g (3.6 bar a). A stainless steel steam coil provides heat. Heat transfer coefficient from steam/coil/liquid, U = 650 W/mC

Part 1 Calculate the average steam mass flowrate during start-up Steam pressure onto the control valve = 2.6 bar g (3.6 bar a) Critical pressure drop (CPD) will occur across the control valve during start-up, therefore the minimum steam pressure in the heating coil should be taken as 58% of upstream absolute pressure. An explanation of this is given in Block 5.

Part 2 Calculate the heat transfer area required.

Part 3 A recommendation for coil surface area Because of the difficulties in providing accurate 'U' values, and to allow for future fouling of the heat exchange surface, it is usual to add 10% to the calculated heat transfer area.

Part 4 The maximum steam mass flowrate with the recommended heat transfer area Maximum heat transfer (and hence steam demand) will occur when the temperature difference between the steam and the process fluid is at its maximum, and should take into consideration the extra pipe area allowed for fouling. (a) Consider the maximum heating capacity of the coil Using Equation 2.5.3: = UAT
(coil)

(b) Steam flowrate to deliver 519 kW

Part 5 A recommendation for installation, including coil diameter and layout (a) Determine coil diameter and length

From Table 2.10.3, a 100 mm pipe has a surface area of 0.358 m/m run. This application will require:

It may be difficult to accommodate this length of large bore heating pipe to install in a 3 m 3 m tank. One solution would be to run a bank of parallel pipes between steam and condensate manifolds, set at different heights to encourage condensate to run to the lower (condensate) manifold. The drain line must fall from the bottom of the condensate manifold down to the steam trap (or pump-trap). See Figure 2.10.1 for a suggested layout.

Fig. 2.10.1 Possible layout of coils in a rectangular tank Note the steam supply is situated at one end of its manifold, whilst the trap set is at the other end. This will help steam to flow and push condensate through the coils. In the application, the steam and condensate headers would each be 2.8 m long. As the condensate manifold is holding condensate, the heat from it will be small compared to the steam manifold and this can be ignored in the calculation. The steam manifold should be 100 mm diameter as determined by the previous velocity calculation. This will provide a heating area of: 2.8 m x 0.358 m/m = 1.0 m Consequently 7 m - 1 m = 6 m of heat transfer area is still required, and must be provided by the connecting pipes. Arbitrarily selecting 32 mm pipe as a good compromise between robustness and workability:

The lengths of the connecting pipes are 2.5 m.

CHECK

It is necessary to confirm the steam velocity through the connecting tubes: On the basis of proportionality of heat transfer area, the steam header will condense:

This leaves 86% of the 850 kg/h = 731 kg/h of steam which must pass through the 18 connecting pipes and also into the lower (condensate) manifold.

Other steam coil layouts

The design and layout of the steam coil will depend on the process fluid being heated. When the process fluid to be heated is a corrosive solution, it is normally recommended that the coil inlet and outlet connections are taken over the lip of the tank, as it is not normally advisable to drill through the corrosion resistant linings of the tank side. This will ensure that there are no weak points in the tank lining, where there is a risk of leakage of corrosive liquids. In these cases the coil itself may also be made of corrosion resistant material such as lead covered steel or copper, or alloys such as titanium. However, where there is no danger of corrosion, lifts over the tank structure should be avoided, and the steam inlet and outlet connections may be taken through the tank side. The presence of any lift will result in waterlogging of a proportion of the coil length, and possibly waterhammer, noise and leaking pipework. Steam heating coils should generally have a gradual fall from the inlet to the outlet to ensure that condensate runs toward the outlet and does not collect in the bottom of the coil. Where a lift is unavoidable, it should be designed to include a seal arrangement at the bottom of the lift and a small bore dip pipe, as shown in Figure 2.10.2.

Fig. 2.10.2 Tank with a rising discharge pipe The seal arrangement allows a small amount of condensate to collect to act as a water seal, and prevents the occurrence of steam locking. Without this seal, steam can pass over any condensate collecting in the bottom of the pipe, and close the steam trap at the top of the riser. The condensate level would then rise and form a temporary water seal, locking the steam between the bottom of the riser and the steam trap. The steam trap remains closed until the locked steam condenses, during which time the coil continues to waterlog. When the locked steam condenses and the steam trap opens, a slug of water is discharged up the riser. As soon as the water seal is broken, steam will enter the rising pipe and close the trap, while the broken column of water falls back to lie at the bottom of the heating coil. The small bore dip pipe will only allow a very small volume of steam to become locked in the riser. It enables the water column to be easily maintained without steam bubbling through it, ensuring there is a steady and continuous condensate flow to the outlet. When the seal is ultimately broken, a smaller volume of water will return to the heating coil than with an unrestricted large bore riser, but as the water seal arrangement requires a smaller volume of condensate to form a water seal, it will immediately re-form. If the process involves articles being dipped into the liquid, it may not be convenient to install the coil at the bottom of the tank - it may be damaged by the objects being immersed in the solution. Also, during certain processes, heavy deposits will settle at the bottom of the tank and can quickly cover the heating surface, inhibiting heat transfer. For these reasons side hung coils are often used in the electroplating industry. In such cases serpentine or plate-type coils are arranged down the side of a tank, as shown in Figure 2.10.3. These coils should also have a fall to the bottom with a water seal and a small bore dip-pipe. This arrangement has the advantage that it is often easier to install, and also easier to remove for periodic cleaning if required.

Fig. 2.10.3 Side hung coils If articles are to be dipped into the tank, it may not be possible to use any sort of agitator to induce forced convection and prevent temperature gradients occurring throughout the tank. Whether bottom or side coils are used, it is essential that they are arranged with adequate coverage so that the heat is distributed evenly throughout the bulk of the liquid. The diameter of the coil should provide sufficient length of coil for good distribution. A short length of coil with a large diameter may not provide adequate temperature distribution. However a very long continuous length of coil may experience a temperature gradient due to the pressure drop from end to end, resulting in uneven heating of the liquid. Whilst the next two headings, 'Sizing the control valve' and 'The condensate removal device' are included in this Tutorial, the new reader should refer to later Tutorials for full and comprehensive information, before attempting sizing and selection of equipment.

Control valve arrangement

The control valve set may be either one or two valves in parallel. A single control valve, large enough to cope with the maximum flowrate encountered at start-up, may be unable to control flow accurately at the minimum expected flowrate. This could cause erratic temperature control. An alternative is to fit two temperature control valves in parallel:

One valve (running valve) sized to control at the lower flowrate. A second valve (starting valve) to pass the difference between the capacity of the first valve, and the maximum flowrate.

The starting valve would have a set-point slightly lower than the running valve, so it would close first, leaving the running valve to control at low loads.

Sizing the control valve

The control valve set (either one valve or two valves in parallel). The coil has been sized on mean heat transfer values. However, it may be better to size the control valve to supply the maximum (start-up) load. With large coils in tanks, this will help to maintain a degree of steam pressure throughout the length of the coil when the steam is turned on, helping to push condensate through the coil to the steam trapping device. If the control valve were sized on mean values, steam pressure in the coil at start-up will tend to be lower and the coil may flood.

Using one valve

Continuing with Example 2.10.1 the maximum steam load is 850 kg/h and the coil is designed to deliver this at a pressure of 1.1 bar g. A steam valve sizing chart would show that a K v of about 20 is required to pass 850 kg/h of steam with a pressure of 2.6 bar g at the inlet of the control valve, and Critical Pressure Drop (CPD) across the valve. (Tutorial 6.4 will show how the valve size can be determined by calculation). A DN40 control valve with a larger Kvs of 25 would therefore need to be selected for the application. If one valve is to be used, this valve must ensure the maximum heat load is catered for, while maintaining the required steam pressure in the coil to assist the drainage of condensate from it at start-up. However, for reasons previously explained, two valves may be better. The running load is 52 kW and with the coil running at 1.1 bar g, the running steam load:

The steam valve sizing chart shows a Kv of 2 is required to pass 85 kg/h with 3.6 bar upstream, operating at critical pressure drop. A DN15 KE type valve (Kvs = 4) and a DN25 piston actuated valve (Kvs = 18.6) operating together will cater for the start-up load. When approaching the control temperature, the larger valve would be set to shut down, allowing the smaller valve to give good control.

The condensate removal device

The selection and sizing of the condensate removal device will be very much influenced by the condensate backpressure. For the purpose of this example, it is assumed the backpressure is atmospheric pressure. The device should be sized so it is able to satisfy both of the following conditions:

Pass 850 kg/h of condensate with 1.1 bar g in the coil, i.e. the full-load condition. Pass the condensate load when steam pressure in the coil equals the condensate backpressure, i.e. the stall load condition.

If the steam trap is only sized on the first condition, it is possible that it may not pass the stall load (the condition where the product approaches its required temperature and the control valve modulates to reduce steam pressure). The stall load may be considerable. With respect to nonflow type applications such as tanks, this may not be too serious from a thermal viewpoint because the contents of the tank will almost be at the required temperature, and have a huge reservoir of heat.

Any reduction in heat transfer at this part of the heating process may therefore have little immediate effect on the tank contents. However, condensate will back up into the coil and waterhammer will occur, along with its associated symptoms and mechanical stresses. Tank coils in large circular tanks tend to be of robust construction, and are often able to withstand such stresses. Problems can however occur in rectangular tanks (which tend to be smaller), where vibration in the coil will have more of an effect on the tank structure. Here, the energy dissipated by the waterhammer causes vibration, which can be detrimental to the life of the coil, the tank, and the steam trap, as well as creating unpleasant noise. With respect to flow-type applications such as plate heat exchangers, a failure to consider the stall condition will usually have serious implications. This is mainly due to the small volume in the heat exchanger. For heat exchangers, any unwanted reduction in the heating surface area, such as that caused by condensate backing up into the steam space, can affect the flow of heat through the heating surface. This can cause the control system to become erratic and unstable, and processes requiring stable or accurate control can suffer with poor performance. If heat exchangers are oversized, sufficient heating surface may remain when condensate backs up into the steam space, and reduction of thermal performance may not always occur. However, with heat exchangers not designed to cope with the effects of waterlogging, this can lead to corrosion of the heating surface, inevitably reducing the service life of the exchanger. Waterlogging can, in some applications, be costly. Consider a waterlogging air heater frost coil. Cold air at 4C flowing at 3 m/s can soon freeze condensate locked in the coils, resulting in premature and unwarranted failure. Proper drainage of condensate is essential to maintain the service life of any heat exchanger and air heater. Steam traps are devices which modulate to allow varying amounts of condensate to drain from applications under varying conditions. Float traps are steam traps designed to modulate and release condensate close to steam temperature, offering maximum plant performance, maximum plant life, and maximum return on plant investment. When stall conditions occur, and a steam trap cannot be used, an automatic pump-trap or pump and trap in combination will ensure correct condensate drainage at all times, thus maximising the thermal capability and lifetime costs of the plant.

Steam jackets
The most commonly used type of steam jacket consists simply of an outer cylinder surrounding the vessel, as shown in Figure 2.10.4. Steam circulates in the outer jacket, and condenses on the wall of the vessel. Jacketed vessels may also be lagged, or may contain an internal air space surrounding the jacket. This is to ensure that as little steam as possible condenses on the outer jacket wall, and that the heat is transferred inwards to the vessel.

Fig. 2.10.4 A conventional jacketed vessel The heat transfer area (the vessel wall surface area), can be calculated in the same manner as with a steam coil, using Equation 2.5.3 and the overall heat transfer coefficients provided in Table 2.10.4. Although steam jackets may generally be less thermally efficient than submerged coils, due to radiation losses to the surroundings, they do allow space for the vessels to be agitated so that heat transfer is promoted. The U values listed in Table 2.10.4. are for moderate non-proximity agitation. Commonly the vessel walls are made from stainless steel or glass lined carbon steel. The glass lining will offer an additional corrosion resistant layer. The size of the steam jacket space will depend on the size of the vessel, but typically the width may be between 50 mm and 300 mm.

Heating Vats and Tanks by Steam Injection

Direct steam injection involves the discharge of steam bubbles into a liquid at a lower temperature to transfer heat. This tutorial explains the process and the methods used, including the relevant heat transfer calculations. Use the quick links below to take you to the main sections of this tutorial:

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Heating Vats and Tanks by Steam Injection

Direct steam injection involves the discharge of a series of steam bubbles into a liquid at a lower temperature. The steam bubbles condense and give up their heat to the surrounding liquid. Heat is transferred by direct contact between the steam and the liquid, consequently this method is only used when dilution and an increase in liquid mass is acceptable. Therefore, the liquid being heated is usually water. Direct steam injection is seldom used to heat solutions in which a chemical reaction takes place, as the dilution of the solution would reduce the reaction rate and lower the productivity. Direct steam injection is the most widely used method for boiler feedtank heating throughout industry. This method is often chosen because of its simplicity. No heat transfer surface or steam trap set is required, and there is no need to consider the condensate return system.

Steam consumption calculations

During direct steam injection, heat is transferred in a different manner to indirect heat exchange. As the heat is not transferred across a surface, and the steam mixes freely with the process fluid being heated, the amount of usable heat in the steam must be calculated in a different way. This can be found using Equation 2.11.1:

Equation 2.11.1 Where:

= Mean steam flowrate (kg/s)

= Mean heat transfer rate kW (kJ/s) Specific enthalpy of steam (taken at the pressure supplying the control valve) hg = (kJ/kg) T = Final temperature of the water (C) cp = Specific heat capacity of water (kJ/kg C)
Equation 2.11.1 shows that steam injection utilises all of the enthalpy of evaporation (or latent heat) and a proportion of the liquid enthalpy contained in the steam. The actual proportion of the liquid enthalpy used will depend on the temperature of the water at the end of the injection process. One major difference between indirect heating and direct steam injection, is that the volume (and mass) of the process fluid is increased as steam is added, by the amount of steam injected. Another difference is that, when calculating the steam flowrate to a steam coil, the pressure in the coil is considered, but for steam injection, the pressure before the control valve is considered. In some cases (where the liquid surface is not at the overflow pipe level), this will increase the head of liquid over the injector as time progresses. However, this increase is likely to be small and is rarely taken into account in calculations.

Factors influencing the heat transfer rate

In Equation 2.11.1, the steam consumption rate is directly related to the heat requirement. Unless the steam injection system is designed so that all conditions are conducive to maximum heat transfer, the steam bubbles may simply break the surface of the liquid and escape to the atmosphere; some of the heat contained in the steam will be lost to atmosphere and the actual heat transfer rate to the water will be less than anticipated. In the case of a submerged coil, the maximum heat transfer rate at the start of the warm-up period will depend on the maximum steam flowrate allowed through the control valve and its associated pipework, and the maximum heat output allowed by the coil surface area. During direct steam injection, it might be expected that the maximum heat transfer rate at the very start of the warm-up period is dependent on the maximum flowrate through the control valve, and the pipe or injector itself. However, as implied above, it will also depend on other factors such as:

Size of the steam bubble - Condensation of a steam bubble will depend on the heat transfer across the surface of the bubble. To ensure that the steam bubble is completely condensed, the surface area/volume ratio must be as large as possible. Smaller bubbles have a greater surface area per unit volume than larger bubbles, so it is desirable to produce very small bubbles. The differential pressure (between the steam pipe and the point where the steam is discharged into the water) as the bubble emerges will also affect the size of the steam bubble. The specific volume of steam will increase as the pressure is reduced, so that a drop in pressure will increase the size of the steam bubble as it escapes into the liquid. Even if the steam bubble is emitted from a very small hole, the bubble may increase significantly in size if the steam pressure is high. Consequently, a lower pressure in the sparge pipe is better.

Head of liquid over the injection point - The head of liquid over the injection point will create a backpressure so that the differential pressure will be less than the steam pressure. If the head of liquid is large and the steam pressure in the sparge pipe is low, there may only be a very small change in pressure so that the size of the bubbles formed is kept to a minimum. A greater head of liquid over the point of injection will give the steam bubbles maximum opportunity to condense before they reach the surface.

Velocity of the bubble - The velocity of the bubble at the point of injection will also depend on the difference between the steam pressure and the liquid head. It is desirable to keep this differential pressure as low as possible, so that bubble velocities are also as low as possible and the bubbles are given the maximum time to condense before they reach the surface. Temperature of the liquid - The rate at which the steam will condense is directly proportional to the temperature difference between the steam and the liquid being heated. As with all heat transfer processes, the rate of heat exchange is directly proportional to the temperature differential. It is always advisable to ensure that the temperature of the liquid is correctly controlled and is kept to the minimum required for the application, so that the maximum heat transfer rate is maintained and there is no wastage of energy.

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Sparge pipes
This is simply a pipe mounted inside the tank, with the holes drilled at regular positions (typically 4 o'clock and 8 o'clock) when viewed from the end, equally spaced along the length of the pipe, and with the end blanked off. The steam exits the pipe through the holes as small bubbles, which will either condense as intended or reach the surface of the liquid (see Figure 2.11.1). Sparge pipes are inexpensive to make and easy to install, but are prone to cause high levels of vibration and noise. A much more effective method is to use a properly designed steam injector.

Fig. 2.11.1 Sparge hole orientation

Example 2.11.1 - Determine the steam load to heat a tank of water by steam injection

Fig. 2.11.4 The tank used in Example 2.9.1 These calculations (steps 1 to 5) are based on Examples 2.9.1 and 2.10.1 as far as heat losses are concerned, but with the tank containing water (cp = 4.19 kJ/kg C), instead of weak acid solution and the water being heated by steam injection rather than a steam coil. Step 1 - find the energy required to heat up 12 000 kg of water from 8C to 60C in 2 hours by using Equation 2.6.1:

Equation 2.6.1 Where:

= Mean heat transfer rate to heat the water (kW) m = 12 000 kg cp = 4.19 kJ/kg C T = 60 - 8 = 52C t = 2 hours x 3 600 = 7 200 seconds

Steam is supplied to the control valve at 2.6 bar g. In order to calculate the mean steam flowrate, it is necessary to determine the total enthalpy in the steam (hg) at this pressure. It can be seen from Table 2.11.1 (an extract from steam tables) that the total enthalpy of steam (h g) at 2.6 bar g is 2733.89 kJ/kg.

Table 2.11.1 Extract from steam tables Step 2 - find the mean steam flowrate to heat the water by using Equation 2.11.1:

Equation 2.11.1 Where:

= Mean steam flowrate to heat the water in the tank (kg/s) = (water) = Mean heat transfer rate to heat the water = 363 kW hg = Total enthalpy in the steam supplying the control valve = 2733.89 kJ/kg T = Final water temperature = 60C cp = Specific heat of water = 4.19 kJ/kg C
s
Therefore, from Equation 2.11.1;

Step 3 - find the mean steam flowrate to heat the tank material (steel). From Example 2.9.1, the mean heat transfer rate for the tank material =
(tank)

= 14 kW

The mean steam flowrate to heat the tank material is calculated by again using Equation 2.11.1:

Equation 2.11.1 Where:

= Mean steam flowrate to heat the tank material (kg/s) = (tank) = Mean heat transfer rate to heat the tank material = 14 kW hg = Total enthalpy in the steam supplying the control valve = 2733.89 kJ/kg T = Final tank temperature = 60C cp = Specific heat of the tank material (steel) = 0.5 kJ/kg C
s
Therefore, from Equation 2.11.1

Step 4 - find the mean steam flowrate to make up for the heat losses from the tank during warm-up. From Example 2.9.1: The mean heat losses from the tank and water surface =
(sides)

(surface)

The heat losses from the tank and water surface = 7 kW + 8 kW The heat losses from the tank and water surface = 15 kW Whilst it is reasonable to accept that the steam's liquid enthalpy will contribute to the rise in temperature of the water and the tank material, it is more difficult to accept how the steam's liquid enthalpy would add to the heat lost from the tank due to radiation. Therefore, the equation to calculate the steam used for heat losses (Equation 2.11.2) considers only the enthalpy of evaporation in the steam at atmospheric pressure.

Equation 2.11.2 Where:

= Mean steam flowrate to provide the heat losses from the tank (kg/s) = (sides) + (surface) (kW) 2256.7 = Enthalpy of evaporation at atmospheric pressure (kJ/kg)
s
Therefore, from Equation 2.11.2;

Step 5 - Determine the steam load to heat a tank of water by steam injection. The total mean steam flowrate can be calculated as follows:

It is important to remember with steam injection systems that the final mass of liquid is equal to the mass of cold liquid, plus the mass of steam added. In this example, the process started with 12 000 kg of water. During the required heat-up period of 2 hours steam has been injected at the rate of 569 kg/h. The mass of liquid has therefore, increased by 2 h x 569 kg/h = 1 138 kg. The final mass of the liquid is: 12 000 kg + 1 138 kg = 13 138 kg The additional 1 144 kg of condensate has a volume of about 1 144 litres (1.44 m) and will also have increased the water level by: Clearly, the process tank needs to have sufficient space above the starting water level to allow for this increase. For safety, an overflow should always be included in the tank construction where steam injection is involved. Alternatively, if the process requirement had been to finish with a mass of 12 000 kg, the mass of water at the beginning of the process would be: Top

Steam injectors
A more effective alternative to the sparge pipe is the steam injector as shown in Figure 2.11.6. The injector draws in cold liquid and mixes it with steam inside the injector, distributing heated liquid to the tank. The engineered design of the injector body is more sophisticated than the simple sparge pipe, and allows steam at higher pressures to be used. A turbulent zone is created within the body of the injector, which ensures that thorough mixing of the steam and liquid occurs, even at relatively high pressures. This has the effect of agitating and circulating the liquid so that a constant temperature is maintained throughout the tank, without temperature stratification or cold spots. These injectors are more compact than sparge pipes, consequently any interference with objects that may be dipped in the tank can be avoided. They are more robust and generally quieter than sparge pipes, although noise problems may still be encountered if not installed correctly.

Noises pertaining to steam injectors

When using high pressure steam injectors three distinct noise levels are produced under the following conditions:

Normal running - Where steam pressures at the injector inlet are above 2 bar g, the noise produced during normal running conditions can be described as a soft roar. Noise is caused by the condensation of steam inside the discharge tube, as it mixes with recirculating water drawn through the holes into the casting body. Under normal conditions the discharge from the injector tube is approximately 10C hotter than t he incoming water.

This type of noise increases with steam pressure, water temperature and the number of injectors, but it is rarely objectionable at steam pressures below 8 bar g. Although strong circulation of the tank contents occurs at pressures above 8 bar g, little vibration should be experienced.

Incomplete condensation - This is characterised by a soft bumping noise and is sometimes accompanied by heavy vibration. It occurs when the liquid temperature is too high (usually above 90C). When the liquid is too hot the injector becomes l ess efficient and a proportion of the steam escapes from the discharge tube. At higher steam pressures, condensation of the steam may cause vibration, which is not recommended for atmospheric tanks. However, in cylindrical pressure vessels of a robust design, this may not cause any problems.

Low flowrates - When the steam pressure at the inlet to the injector falls below 1.5 bar g, a distinctive crackling can be heard. Under these conditions steam is unable to give up its enthalpy of evaporation before it leaves the injector tube. At low flowrates the steam is travelling at a lower velocity than in the other modes of operation, and collapsing steam bubbles are found on the body casting and in the connecting pipework, inducing cavitation. This noise is often considered objectionable, and may be found if the steam injector system has been oversized. Noise may also be caused by poor installation of the injector. The sides of a rectangular tank may be made from fairly flexible panels. Connecting an injector to the middle of a flexible panel may induce vibration and noise. It may often be better to mount the injector nearer the corner of the tank where the structure is stiffer.

Example 2.11.2
Based on data from Example 2.11.1, propose a steam injection system. Required steam injection rate = 569 kg/h The steam injection pressure = 1.0 bar

The largest injector (IN40M) has a capacity of 400 kg/h at 1.0 bar, so this application will require: Ideally, because of the low pressures involved, the injectors would be installed at opposite ends of the tank to give good mixing. An alternative would be to use higher pressure steam. This would allow the use of just one, smaller injector, reducing costs and still providing good mixing. Top

Alternative method of calculating injected steam load

The previous method used in this Tutorial to calculate the mean steam flowrate requires the mean heat load to be calculated first. This is depicted by Equation 2.11.1:

Equation 2.11.1 Where: = Mean heat transfer rate (kW) If the mean heat transfer rate is not known, another method can be used to determine the mean steam flowrate. This requires the use of a heat balance as described below. It should be noted that both methods return exactly the same result, so whichever is used depends upon the user's choice.

Calculating the mean steam flowrate by means of a heat balance

A heat balance is considered where the initial heat content in the water plus the heat added by the steam equals the final heat content. The heat balance equation for the water in the tank is shown in Equation 2.11.4:

Equation 2.11.3 Where:

m = Initial mass of water in the tank (kg) h1 = The heat in the water at the initial temperature (kJ/kg) ms = The mass of steam to be injected to raise the water temperature (kg) hg = The total enthalpy of the steam onto the control valve (kJ/kg) h2 = The heat in the water at the final temperature (kJ/kg)
Mass of steam to be injected The mass of steam to be injected can be determined more directly from Equation 2.11.4, which is developed from Equation 2.11.3.

Equation 2.11.4 Where:

ms = The mass of steam to be injected (kg)

m h2 h1 hg

= Initial mass of water in the tank (kg) = The heat in the water at the final temperature (kJ/kg) = The heat in the water at the initial temperature (kJ/kg) = The total enthalpy of the steam upstream of the control valve (kJ/kg)

Example 2.11.3
Consider the same conditions as that in Example 2.11.1.

Conducting a heat balance on the water in the tank by using Equation 2.11.4:

Equation 2.11.4 Where:

ms = The mass of steam to be injected to raise the water temperature (kg) m = 12 000 kg h2 = 251.4 kJ/kg h1 = 33.5 kJ/kg hg = 2 733.9 kJ/kg

Conducting a heat balance on the tank material

Using the heat balance Equation 2.11.4 with regard to the steel tank.

Equation 2.11.4 Where:

ms = Mass of steam to be injected to raise the tank temperature

m h2 h1 hg

= 3 886 kg = 30 kJ/kg = 4 kJ/kg = 2 733.9 kJ/kg

The heat losses from the sides of the tank and the water surface are the same as previously calculated, that is 24 kg/h.

This is the same result as that obtained previously in this Tutorial from Equations 2.11.1 and 2.11.2, and proves that either method can be used to calculate the mean steam flowrate to heat the tank and its contents.

Steam Consumption of Pipes and Air Heaters

Steam will condense and give up its enthalpy of evaporation on the walls of any pipe or tube at a lower temperature. It is not usually possible or necessary to calculate steam consumption exactly. This tutorial allows satisfactory estimates to be made for most practical purposes.

The printable version of this page has now been replaced byThe Steam and Condensate Loop Book View the complete collection of Steam Engineering Tutorials Contact Us Steam will condense and give up its enthalpy of evaporation on the walls of any pipe or tube exposed to ambient air. In some cases, such as steam mains, heat transfer is minimised by the lagging of the pipes. In other cases such as air heater batteries, heat transfer may be promoted by the use of fins on the outside of the pipes. It is not usually possible or necessary to calculate steam consumption exactly. The examples in this Tutorial allow sufficient estimates to be made for most practical purposes.

Steam mains
In any steam system, the condensation of steam caused by the pipe itself must be taken into account. The rate of condensation will be at its highest during the warming up period, and it is this that should govern the size of steam traps used for mains drainage. With the steam main in use, there will also be a smaller (but continual) heat loss from the pipe. Both of these components can be calculated as the 'warming up load' and the 'running load'.

Warm-up load
Heat will initially be required to bring the cold pipe up to working temperature. It is good practice to do this slowly for safety reasons, the pipes also benefit from reduced thermal and mechanical stress. This will result in fewer leaks, lower maintenance costs, and a longer life for the pipe. Slow warm-up can be achieved by fitting a small valve in parallel with the main isolating valve, (Figure 2.12.1). The valve can be sized depending on the warm-up time required. Automating the warm-up valve to open slowly on large pipes can improve safety. A single main isolating valve can be used successfully, but, as it will be sized to pass the pipeline design flow requirements, it will be oversized during the warm-up period and will consequently operate very close to its seat at this time. A separator placed before the valve will ensure the steam passing through is dry, protecting the trim from premature wear.

The time taken to warm up any steam main should be as long as possible within acceptable limits to minimise mechanical pipework stress, optimise safety and reduce start-up loads.

Fig. 2.12.1 Automatic warm-up valve in a Bypass If 10 minutes can be taken instead of 5 minutes, the initial steam flowrate will be reduced by half. A warm-up time of 20 minutes will reduce the warm-up load even further. The steam flowrate required to bring a pipework system up to operating temperature is a function of the mass and specific heat of the material, the temperature increase, the enthalpy of evaporation of the steam used, and the allowable time. This may be expressed by Equation 2.12.1: Equation 2.12.1 Where: = Mean rate of condensation of steam (kg/h) W = Total weight of pipe plus flanges and fittings (kg) T s = Steam temperature (C) T amb = Ambient temperature (C) cp = Specific heat of pipe material (kJ/kgC) hfg = Enthalpy of evaporation at operating pressure (kJ/kg) t = Time for warming up (minutes) Note: The constant 60 and time in minutes gives the solution in kg/h.
s

Table 2.12.1 Typical specific heat capacities of metal pipes

Example 2.12.1 Heat losses from a steam pipeline

A system consists of 100 m of 100 mm carbon steel main, which includes 9 pairs of PN40 flanged joints, and one isolating valve.

cp for steel = 0.49 kJ/kgC The ambient/starting temperature is 20C and the steam pressure is 14.0 bar g, 198C from steam tables (see Table 2.12.2).

Table 2.12.2 Extract from steam tables Determine: Part 1 - The warm-up condensing rate for a warm-up time of 30 minutes. Part 2 - The running load if the insulation thickness is 75 mm. Part 1 - Calculate the warm-up load Equation 2.12.1 To find W, find the mass of the various steam main items from Table 2.12.3. 100 mm steel main = 16.1 kg/m 100 mm flanges to PN40 = 16.0 kg per pair 100 mm stop valve = 44.0 kg each Therefore: W = (100 x 16.1) + (9 x 16) + (1 x 44) = 1 798 kg So, the mean warming up load:

Note: This condensing rate will be used to select an appropriate warm-up control valve. When selecting steam traps, this condensing rate should be multiplied by a factor of two to allow for the lower steam pressure that will occur until warm-up is completed, then divided by the number of traps fitted to give the required capacity of each trap.

Table 2.12.3 Typical weights of steel pipe, flanges and bolts, and isolating valves in kg Part 2 - Running load Steam will condense as heat is lost from the pipe to the environment: The rate of condensation depends on the following factors: The steam temperature. The ambient temperature. The efficiency of the lagging. Table 2.12.4 gives typical heat emission rates expected from unlagged steel pipes in still air at 20C.

Table 2.12.4 Heat emission from unlagged steel pipes freely exposed in air at 20 C (W/m) Distribution mains will normally be lagged however, and is obviously an advantage if flanges and other items of pipeline equipment are lagged too. If the main is flanged, each pair of flanges will have approximately the same surface area as 300 mm of pipe of the same size. The rate of heat transfer increases when a heat transfer surface is subjected to air movement. In these cases, the multiplication factors, as shown in Table 2.12.5, should be considered. If finned or corrugated tubing is fitted, then the maker's figures for heat emission should always be used. In everyday terms, air velocities up to 4 or 5 m/s (approximately 10 mph) represent a

gentle breeze, between 5 and 10 m/s (approximately 10 - 20 mph) a strong breeze. Typical air duct velocities are around 3 m/s, in comparison.

Table 2.12.5 Approximate increase in emission due to air movement over pipes with a high emissivity Note: Exact figures are difficult to determine, as many factors are involved. The factors in Table 2.12.5 are derived and give a rough indication of how much the figures in Table 2.12.4 should be multiplied. Pipes subjected to air movement up to around 1 m/s can be thought of as being in still air, and heat losses are fairly constant up to this point. As a guide, painted pipes will have a high emissivity, oxidised steel a medium emissivity, and polished stainless steel a low emissivity. The reduction in heat losses will depend on the type and thickness of the lagging material used, and on its general condition. For most practical purposes, the lagging of steam lines will reduce the heat emissions in Table 2.12.4 by the insulation factors (f) shown in Table 2.12.6. Note that these factors are nominal values only. For specific calculations, consult the insulation manufacturer.

Table 2.12.6 Insulation factors (f) The heat loss from insulated mains can be expressed as follows in Equation 2.12.2:

Equation 2.12.2 Where: = Rate of condensation (kg/h) = Heat emission rate from Table 2.12.4 (W/m) L = Effective length of pipe allowing for flanges and fittings (m) f = Insulation factor (from Table 2.12.6) hfg = Enthalpy of evaporation at operating pressure (kJ/kg) Note: f = 1.0 if the main is not insulated. The factor 3.6 in Equation 2.12.2 provides a solution in kg/h
s

Determine the length, L: Assuming an allowance equivalent to 0.3 m for each pair of flanges, and 1.2 m for each stop valve, the total effective length (L) of the steam main in this example is:

L = 100 + (9 x 0.3) + (1 x 1.2) L = 103 m Determine the heat emission rate, : The temperature of the steam at 14.0 bar gauge is 198C and, with the ambient temperature 20C, the temperature difference is 178C. From Table 2.12.4: Heat loss for a 100 mm pipe 1 374 W/m Determine the insulation factor, f: The insulation factor for 75 mm insulation on 100 mm pipe at 14 bar g (from Table 2.12.6) is approximately 0.07.

As can be seen from this example, the warm-up load of 161 kg/h (see Example 2.12.1, Part 1) is substantially greater than the running load of 18.3 kg/h, and, in general, steam traps sized on the warm-up duty will automatically cater for the running load. If the steam line above was unlagged or the lagging was damaged, the running load would have been approximately fourteen times greater. With an uninsulated pipe, or a poorly insulated pipe, always compare the running and warm-up loads. The higher load should be used to size the steam traps, as described above. Ideally, the quality of insulation should be improved. Note: When calculating warming up losses, it is sensible to consider the correct pipe specification, as pipe weights can vary between different pipe standards.

Air heating
The density and specific heat of air changes slightly with temperature. For most practical purposes, when heating air for HVAC and process applications with the approach mentioned below, a nominal figure of 1.3 kJ/mC can be used for specific heat and 1.3 kg/m for density.

Air heating pipes

Heated air is required for many applications including:

Space heating. Ventilation. Process applications.

Fig. 2.12.2 Finned tube The equipment required often consists of a matrix of tubes filled with steam, installed across an air stream. As the air passes over the tubes, heat is transferred from the steam to the air. Often, in order to minimise the size and mass of the equipment, and allow it to be installed in confined spaces with reduced support works, and to limit the cost, the rate of heat transfer from the tubes to the air is increased by the addition of fins to the outer wall of the tube. This has the effect of increasing the heat transfer area available, and thus reducing the amount of piping required. Figure 2.12.2 shows an example of a finned tube. Broadly, air heaters may be divided into two categories:

Unit heaters. Air heater batteries.

Unit heaters
These consist of a heater battery and fan in one compact casing (Figure 2.12.3). The primary medium (steam) condenses in the heater battery, and air is warmed as it blows across the coils and is discharged into the space. Unit heaters can be arranged to have fresh air inlet ducting, but more often operate with recirculated air.

Fig. 2.12.3 Unit heater The warm air can be discharged vertically downwards or horizontally. Steam pressure, mounting heights, the type of discharge and leaving temperatures are all inter-related and the manufacturer's data should be consulted before selecting the unit heater. Most units are available with low, medium or high speed fans which affect the rated output, and again the manufacturer's data should be consulted, as the noise levels on high speed may be unacceptable.

Air heater batteries

These are really larger and more sophisticated versions of unit heaters, see Figure 2.12.4. They are available in many configurations including roof mounted, or horizontal types, and a fan and filter may also be incorporated. They are usually integrated into a ducted air system.

Adjustable louvres may be provided to adjust the ratio of fresh to recirculated air. A number of heater banks may be incorporated to provide frost protection.

Fig. 2.12.4 Ducted air system with air heater batteries Manufacturers of unit heaters and air heater batteries usually give the output of their heaters in kW at a working pressure. From this, the condensing rate can be calculated by dividing the heat output by the enthalpy of evaporation of steam at this pressure. The solution will be in kg/s; multiplying by 3 600 (seconds in an hour) will give the solution in kg/h. Thus a 44 kW unit heater working at 3.5 bar g (hfg = 2 120 kJ/kg from steam tables) will condense:

Note: The constant 3 600 is included in the formula to give flowrate in kg/h rather than kg/s. If the manufacturer's figures are not available but the following are known: The volumetric flowrate of air being heated. The temperature rise of the air being heated. The steam pressure in the heater. Then the approximate rate of condensation can be calculated using Equation 2.12.3:

Equation 2.12.3 Where:

s

= Rate of steam condensation (kg/h) = Volumetric flowrate of air being heated (m/s)

T = Air temperature rise (C) cp = Specific heat of air at constant pressure (1.3 kJ/mC) hfg = Enthalpy of evaporation of steam in the coils (kJ/kg) Note: The constant 3 600 gives the solution in kg/h rather than kg/s. Horizontal pipes assembled into coils with several rows of pipes one above the other, and relying upon natural convection, become less effective as the number of pipes is increased. When calculating the rate of condensation for such coils, the figures given in Table 2.12.5 should be multiplied by the emission factors in Table 2.12.7. Vertically installed heating pipes are also less effective than horizontal pipes. The condensation rate of such pipes can be determined by multiplying the figures in Table 2.12.4 by the factors in Table 2.12.6. Table 2.12.7 can also be used to find the rate of condensation in horizontal pipes used for heating still air. In this instance use the Equation 2.12.4:

Equation 2.12.4 Where: = Rate of steam condensation (kg/h) = Heat emission from Table 2.12.4 (W/m) L = Effective length of pipe (metres) hfg = Enthalpy of evaporation at the working pressure (kJ/kg) Note: The constant 3.6 has been included in the equation to give
s

in kg/h.

Table 2.12.7 Approximate reduction in emission of banked horizontal pipes

Table 2.12.8 Approximate reduction in emission of banked vertical pipes

Effects of air flowrate

When a fan is used to increase the flow of air over pipe coils, the rate of condensation will increase. The figures for heat emission from bare steel pipes (Table 2.12.4), can be used when multiplied in accordance with the factors in Tables 2.12.5, 2.12.7 and 2.12.8 where appropriate. If finned tubing is being considered, then the makers figures for heat emission should be used in all cases.

Example 2.12.2 Calculate the steam load on an air heater battery

An air heater battery raises the temperature of air flowing at 2.3 m / s from 18C to 82C (T = 64C) with steam at 3.0 bar g in the coils.

Table 2.12.9 Extract from steam tables The rating of the battery is unknown, but the condensing rate of steam can be calculated using Equation 2.12.3:

Equation 2.12.3 Where: = Rate of condensation (kg/h) = Air flowrate 2.3 m/s T = Air temperature 82 - 18C = 64C cp = Specific heat of air at constant pressure (1.3 kJ/mC) hfg = Enthalpy of evaporation of steam in the coils 2 133 kJ/kg (from steam tables) Note: The constant 3 600 is included in the equation to give flowrate in kg/h rather than kg/s.
s

Steam Consumption of Heat Exchangers

Different types of heat exchanger are explained and compared in this tutorial, together with steam consumption calculations and other issues such as the relevance of the starting load.

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Contact Us The term heat exchanger strictly applies to all types of equipment in which heat transfer is promoted from one medium to another. A domestic radiator, where hot water gives up its heat to the ambient air, may be described as a heat exchanger. Similarly, a steam boiler where combustion gases give up their heat to water in order to achieve evaporation, may be described as a fired heat exchanger. However, the term is often more specifically applied to shell and tube heat exchangers or plate heat exchangers, where a primary fluid such as steam is used to heat a process fluid. A shell and tube heat exchanger used to heat water for space heating (using either steam or water) is often referred to as a non-storage calorifier. (A storage calorifier, as shown in Figure 2.13.1, is constructed differently, it usually consists of a hot water storage vessel with a primary heating coil inside).

Fig. 2.13.1 A storage calorifier installation Manufacturers often provide a thermal rating for their heat exchangers in kW, and from this the steam consumption may be determined, as for air heater batteries. However, heat exchangers (particularly shell and tube) are frequently too large for the systems which they are required to serve. A non-storage calorifier (as shown in Figure 2.13.2) will normally be selected from a standard range of sizes, and may often have a much larger capacity than the design figure. For the hot water heating of buildings there may also be certain safety factors included in the heat load calculations. Plate heat exchangers may also be chosen from a standard range of sizes if the units are brazed or welded. However, there is more flexibility in the sizing of gasketed plate heat exchangers, where plates can often be added or removed to achieve the desired heat transfer area. In many cases, plate heat exchangers are oversized simply to reduce the pressure drop for the secondary fluid. On existing plant, an indication of actual load may be obtained if the flow and return temperatures and the pumping rate are known. However, it is important to note that throughput as given on the pump maker's plate will probably relate to a pressure head, which may or may not be present in practice.

Fig. 2.13.2 A Non-storage calorifier installation

Steam consumption calculations for heat exchangers

Shell and tube heat exchangers and plate heat exchangers are typical examples of flow type applications. Therefore, when determining the steam consumption for these applications, Equation 2.6.5 should be used. The start-up load may be ignored if it occurs rarely, or if the time taken to reach full-load output is not too important. Heat exchangers are more often sized on the full running load, with the possible addition of safety factors. Heat losses are rarely taken into account with these flow type applications, as they are significantly less than the full running load. Shell and tube heat exchangers are usually lagged to prevent heat loss, and to prevent possible injury to personnel. Plate heat exchangers tend to be more compact and have a much smaller surface area exposed to the ambient air, in relation to the size of the unit.

Example 2.13.1
Determine the heat load and steam load of the following non-storage heating calorifier A heating calorifier is designed to operate at full-load with steam at 2.8 bar g in the primary steam space. The secondary water flow and return temperatures are 82C and 71C respectively, at a pumped water rate of 7.2 kg/s. cp for water = 4.19 kJ/kgC

Table 2.13.1 Extract from steam tables Part 1 - Determine the heat load The full-load may be calculated using Equation 2.6.5:

Equation 2.6.5 Where:

= Quantity of heat energy (kW) kJ/s) = Secondary fluid flowrate = 7.2 kg/s cp = Specific heat capacity of the water = 4.19 kJ/kgC T = Temperature rise of the substance (82 - 71) = 11C = 7.2 kg/s 4.19 kJ/kgC 11C = 332 kW
Part 2 - Determine the steam load The full-load condensing rate can be determined using the left hand side of the heat balance Equation 2.6.6:

Equation 2.6.6 Where:

= Steam consumption (kg/s) hfg = Specific enthalpy of evaporation (kJ/kg) = Heat transfer rate (kW)
s
Rearranging: a 332 kW calorifier working at 2.8 bar g (hfg = 2 139 kJ/kg from steam tables) will condense:

Plate heat exchangers

A plate heat exchanger consists of a series of thin corrugated metal plates between which a number of channels are formed, with the primary and secondary fluids flowing through alternate channels. Heat transfer takes place from the primary fluid steam to the secondary process fluid in adjacent channels across the plate. Figure 2.13.3 shows a schematic representation of a plate heat exchanger.

Fig. 2.13.3 Schematic diagram of a plate heat exchanger A corrugated pattern of ridges increases the rigidity of the plates and provides greater support against differential pressures. This pattern also creates turbulent flow in the channels, improving heat transfer efficiency, which tends to make the plate heat exchanger more compact than a traditional shell and tube heat exchanger. The promotion of turbulent flow also eliminates the presence of stagnant areas and thus reduces fouling. The plates will usually be coated on the primary side, in order to promote the dropwise condensation of steam. The steam heat exchanger market was dominated in the past by the shell and tube heat exchanger, whilst plate heat exchangers have often

been favoured in the food processing industry and used water heating. However, recent design advances mean that plate heat exchangers are now equally suited to steam heating applications. A plate heat exchanger may permit both the condensing and sub-cooling of condensate within a single unit. If the condensate is drained to an atmospheric receiver, by reducing the condensate temperature, the amount of flash steam lost to the atmosphere through the receiver vent is also reduced. This can eliminate the need for a separate sub-cooler or flash steam recovery system. Although a nominal heat transfer area may theoretically be calculated using Equation 2.5.3, plate heat exchangers are proprietary designs and will normally be specified in consultation with the manufacturers.

Gasketed plate heat exchangers (plate and frame heat exchangers)

In a gasketed plate heat exchanger the plates are clamped together in a frame, and a thin gasket (usually a synthetic polymer) seals each plate around the edge. Tightening bolts fitted between the plates are used to compress the plate pack between the frame plate and the pressure plate. This design allows easy dismantling of the unit for cleaning, and allows the capacity of the unit to be modified by the simple addition or removal of plates. The use of gaskets gives a degree of flexibility to the plate pack, offering some resistance to thermal fatigue and sudden pressure variations. This makes some types of gasketed plate heat exchanger an ideal choice as a steam heater for instantaneous hot water supply, where the plates will be exposed to a certain amount of thermal cycling. The limitation in the use of the gasketed plate heat exchanger lies in the operating temperature range of the gaskets, which places a restriction on the steam pressure that may be used on these units.

Brazed plate heat exchangers

In a brazed plate heat exchanger all the plates are brazed together (normally using copper or nickel) in a vacuum furnace. It is a development of the gasketed plate heat exchanger, and was developed to provide more resistance to higher pressures and temperatures at a relatively low cost. However, unlike the gasketed unit, the brazed plate heat exchanger cannot be dismantled. If cleaning is required it must be either back-flushed or chemically cleaned. It also means that these units come in a standard range of sizes, consequently oversizing is common. While the brazed heat exchanger has a more robust design than the gasketed type, it is also more prone to thermal fatigue due to its more rigid construction. Any sudden or frequent changes in temperature and load should therefore be avoided, and greater attention should be paid to the control on the steam side to avoid thermal stress. Brazed heat exchangers are more suitable (and primarily used) for applications where temperature variations are slow, such as in space heating. They may also successfully be used with secondary fluids which expand gradually, such as thermal oil.

Welded plate heat exchangers

In a welded plate heat exchanger the plate pack is held together by welded seams between the plates. The use of laser welding techniques allows the plate pack to be more flexible than a brazed plate pack, enabling the welded unit to be more resistant to pressure pulsation and thermal cycling. The high temperature and pressure operating limits of the welded unit mean that these heat exchangers normally have a higher specification, and are more suited to heavy duty process industry applications. They are often used where a high pressure or temperature performance is required, or when viscous media such as oil and other hydrocarbons are to be heated.

Shell and tube heat exchangers

The shell and tube heat exchanger is probably the most common method of providing indirect heat exchange in industrial process applications. A shell and tube heat exchanger consists of a bundle of tubes enclosed in a cylindrical shell. The ends of the tubes are fitted into tube sheets, which separate the primary and the secondary fluids. Where condensing steam is used as the heating medium, the heat exchanger is usually horizontal with condensation taking place inside the tubes. Sub-cooling may also be used as a means to recover some extra heat from the condensate in the heat exchanger. However, if the degree of sub-cooling required is relatively large it is often more convenient to use a separate condensate cooler.

Steam heated non-storage calorifiers

A common design for a steam to water non-storage calorifier is shown in Figure 2.13.4. This is known as a 'one shell pass two tube pass' type of shell and tube heat exchanger and consists of a U-tube bundle fitted into a fixed tube sheet.

Fig. 2.13.4 Schematic diagram of a shell and tube heat exchanger It is said to have 'one shell pass' because the secondary fluid inlet and outlet connections are at different ends of the heat exchanger, consequently the shell side fluid passes the length of the unit only once. It is said to have two tube passes because the steam inlet and outlet connections are at the same end of the exchanger, so that the tube-side fluid passes the length of the unit twice. A pass partition (also called a partition plate or a feather plate) divides up the exchanger header, so that the tube-side fluid is diverted down the U-tube bundle rather than straight through the header. This is a comparatively simple and inexpensive design because only one tube sheet is required, but it is limited in use to relatively clean fluids as the tubes are more difficult to clean. Note; it is more difficult to replace a tube with these types of heat exchanger. Baffles are usually provided in the shell, to direct the shell-side fluid stream across the tubes, improving the rate of heat transfer, and to support the tubes.

Starting from cold

As mentioned in Tutorial 2.7, the start-up load can often be ignored if it seldom occurs or if the time taken to reach full-load output is not critical. For this reason, control valves and heat exchangers will often be found to be sized on full-load plus the usual safety factors. With systems that shut down at night and weekends, secondary water temperature can be low at start-up on a cold winter morning, and condensing rates in heating calorifiers will be higher than the full-load condition. Consequently, pressure in the steam space may be considerably below the pressure at which the heat exchanger normally operates, until the secondary inlet temperature rises to its design figure. From a thermal viewpoint, this may not pose a problem - the system simply takes longer to heat up. However, if the designer has not taken this situation into consideration, an inadequate steam trapping and condensate removal system can cause condensate to accumulate in the steam space. This can cause:

Internal corrosion. Mechanical stress due to distortion. Noise, due to waterhammer.

These will cause problems for heat exchangers not designed to withstand such conditions.

Estimating heating loads

Buildings - A practical, subjective method to estimate a heating load is to look at the building itself. Calculations can be complicated, involving factors such as the number of air changes and heat transfer rates through cavity walls, windows and roofs. However, a reasonable estimate can usually be obtained by taking the total building volume and simply allowing 30 - 40 W/m of space up to 3 000 m, and 15 - 30 W/m if above 3 000 m. This will give a reasonable estimate of the heating load when the outside temperature is around a design condition of -1C. A practical way to establish steam consumption for an existing installation is to use an accurate reliable steam flowmeter.

Example 2.13.2 Determine the design rating of a heating calorifier from actual measured conditions
The design rating of a heating calorifier is unknown, but the steam load is measured at 227 kg/h when the outside temperature is 7C and the inside temperature is 19C, a difference of 12C. The calorifier is also designed to provide 19C inside temperature when the outside temperature is -1C, a difference of 20C. The steam load at the design condition can be estimated simply by the ratio of the temperature differences:

Hot water storage calorifiers

Hot water storage calorifiers are designed to raise the temperature of the entire contents from cold to the storage temperature within a specified period. The mean rate at which steam is condensed during the heat up or recovery period can be calculated using Equation 2.13.1.

Equation 2.13.1 Where:

= Mean rate of condensation (kg/h) m = Mass of water heated (kg) cp = Specific heat of water (kJ/kgC) T = Temperature rise (C) hfg = Enthalpy of evaporation of steam (kJ/kg) t = Recovery time (hours)
s
Example 2.13.2 Calculate the mean steam load of a storage calorifier
A storage calorifier has a capacity of 2 272 litres (2 272 kg), and is designed to raise the temperature of this water from 10C to 60C in hour with steam at 2 bar g. cp for water = 4.19 kJ/kg C

Table 2.13.2 Extract from steam tables What is the mean rate at which steam is condensed?

Equation 2.13.1

Where:

m = 2 272 kg T = 60C - 10C = 50C hfg = 2 163 kJ/kg t = hour

This mean value can be used to size the control valve. However, when the temperature of water may be at its lowest value, for example 10C, the high condensing rate of steam may be more than the fully open control valve can pass, and the coil will be starved of steam. The pressure in the coil will drop significantly, with the net effect of reducing the capacity of the steam trapping device. If the trapping device is wrongly sized or selected, condensate may back up into the coil, reducing its ability to transfer heat and achieve the required heat up time. Waterhammer may result, causing severe noise and mechanical stresses to the coil. However, if condensate is not allowed to back up into the coil the system should still maintain the correct heat up time. The solution is to ensure proper condensate drainage. This could be achieved either by a steam trap or automatic pump-trap depending on the system needs. (Refer to Tutorial 13.1 - Condensate Removal from Heat Exchangers).

Other shell and tube steam heaters

In other heat exchangers using steam an internal floating head may be used, which is generally more versatile than the fixed head of the U-tube exchangers. They are more suitable for use on applications with higher temperature differences between the steam and secondary fluid. As the tube bundle can be removed they can be cleaned more easily. The tube-side fluid is often directed to flow through a number of passes to increase the length of the flow path. Exchangers are normally built with between one and sixteen tube passes, and the number of passes is selected to achieve the designed tubeside velocity. The tubes are arranged into the number of passes required by dividing up the header using a number of partition plates. Two shell passes are occasionally created by fitting a longitudinal shell-side baffle down the centre of the exchanger, where the temperature difference would be unsuitable for a single pass. Divided flow and split flow arrangements are also used where the pressure drop rather than the heat transfer rate is the controlling factor in the design, to reduce the shell-side pressure drop. Steam may also be used to evaporate (or vaporise) a liquid, in a type of shell and tube heat exchanger known as a reboiler. These are used in the petroleum industry to vaporise a fraction of the bottom product from a distillation column. These tend to be horizontal, with vaporisation in the shell and condensation in the tubes (see Figure 2.13.5).

Fig. 2.13.5 A kettle reboiler In forced circulation reboilers the secondary fluid is pumped through the exchanger, whilst in thermosyphon reboilers natural circulation is maintained by differences in density. In kettle reboilers there is no circulation of the secondary fluid, and the tubes are submerged in a pool of liquid.

Table 2.13.3 Typical heat transfer coefficients for some shell and tube heat exchangers Although it is desirable to achieve dropwise condensation in all these applications, it is often difficult to maintain and is unpredictable. To remain practical, design calculations are generally based on the assumption of filmwise condensation. The heat transfer area for a shell and tube heat exchanger may be estimated using Equation 2.5.3. Although these units will also normally be specified in consultation with the manufacturers, some typical overall heat transfer coefficients where steam is used as the heating medium (and which include an allowance for fouling) are provided in Table 2.13.3, as a guide.

Corrugated tube heat exchangers

One evolution in the design of the traditional shell and tube heat exchanger, is the recent development of the corrugated tube heat exchanger. This is a single passage fixed plate heat exchanger with a welded shell, and rectilinear corrugated tubes that are suitable for low viscosity fluids. In a similar manner to the plate heat exchangers, the corrugated tubes promote turbulent operating conditions that maximise heat transfer and reduce fouling. Like the traditional shell and tube heat exchangers, these units are commonly installed horizontally. However, in the corrugated tube heat exchanger the steam should always be on the shell side.

Spiral heat exchangers

Spiral heat exchangers share many similar characteristics with shell and tube and plate heat exchangers and are used on many of the same applications. They consist of fabricated metal sheets that are cold worked and welded to form a pair of concentric spiral channels, which are closed by gasketed end-plates bolted to an outer case. Turbulence in the channels is generally high, with identical flow characteristics being obtained for both fluids. They are also relatively easy to clean and can be used for very heavy fouling fluids and slurries. The use of only a single pass for both fluids, combined with the compactness of the unit, means that pressure drops across the connections are usually quite low.

Fig. 2.13.6 Corrugated tube heat exchangers

Steam Consumption of Plant Items

The steam consumption of other common plant items, including heater batteries, calorifiers, drying cylinders, presses and tracer lines. Use the quick links below to take you to the main sections of this tutorial:

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Contact Us The examples in the following sections within this Tutorial are a revision of previously mentioned equipment, and indicate the steam consumption of other common plant items. Top

Heater batteries

Fig. 2.14.1 Typical air heater battery installation

Most manufacturers of unit heaters and air heater batteries give the output of their equipment in kW. The condensing rate may be determined from this by dividing the equipment rating (in kW) by the enthalpy of evaporation of the steam at the operating pressure (in kJ/kg) to give a steam flowrate in kg/s. Multiplying the result by 3 600 will give kg/h.

Equation 2.8.1 Thus a unit heater rated at 44 kW when supplied with steam at 3.5 bar g (hfg = 2 210 kJ/kg) will condense:

If the manufacturer's figures are not available, but the following is known:

The volumetric air flowrate. The temperature rise. The steam pressure.

Then the condensing rate can be determined by using Equation 2.12.3:

Equation 2.12.3 Where:

= Condensing rate (kg/h) = Volumetric air flowrate (m/s) T = Temperature rise (C) cp = Specific heat of air at constant pressure (kJ/mC) hfg = Enthalpy of evaporation at operating steam pressure (kJ/kg)
s
Note: The factor 3 600 gives the answer in kg/h Without more formal data, the following figures may be used as an approximation:

Density of air 1.3 kg/m Specific heat of air cp (by volume) 1.3 kJ/mC Specific heat of air cp (by mass) 1.0 kJ/kgC
Example 2.14.1
An air heater designed to raise air temperature from -5 to 30C is fitted in a duct 2 m x 2 m. The air velocity in the duct is 3 m/s, steam is supplied to the heater battery at 3 bar g, and the specific heat of air is taken as 1.3 kJ/mC. Determine the steam condensing rate (
s

):

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Heating calorifiers

Fig. 2.14.2 Typical heating calorifier installation As with air heaters, most heating calorifier manufacturers will usually provide a rating for their equipment, and the steam consumption may be determined by dividing the kW rating by the enthalpy of steam at the operating pressure to produce a result in kg/s (see Equation 2.8.1). However, calorifiers are frequently too large for the systems they serve because:

The initial heat load calculations on the building they serve will have included numerous and over-cautious safety factors. The calorifier itself will have been selected from a standard range, so the first size up from the calculated load will have been selected. The calorifier manufacturer will have included his own safety factor on the equipment.

An estimate of the actual load at any point in time may be obtained if the flow and return temperatures and the pumping rate are known. Note however that the pressure head on the discharge side affects the throughput of the pump, and this may or may not be constant.

Example 2.14.2
4 l/s of low temperature hot water (flow/return = 82/71C) is pumped around a heating system. Determine the heat output: Heat output = Water flowrate x specific heat of water x temperature change Heat output = 4 l/s x 4.19 kJ/kgC x (82 - 71C) Heat output = 184 kW An alternative method of estimating the load on a heating calorifier is to consider the building being heated. The calculations of heat load can be complicated by factors including:

Air changes. Heat transfer rates through walls, windows and roofs.

However, a reasonable estimate may be obtained by taking the volume of the building and allowing a heating capacity of 30 W/m. This will give the running load for an inside temperature of about 20C when the outside temperature is about -1C. Typical flow and return temperatures for:

Low temperature hot water (LTHW) systems are 82C and 71C (T = 11C). Medium temperature hot water (MTHW) systems are 94C and 72C (T = 22C).

Figures for high temperature hot water (HTHW) systems vary considerably, and must be checked for each individual application.

Example 2.14.3
The steam flow to a heating calorifier has been measured as 227 kg/h when the outside temperature is 7C and the inside temperature is 18C. If the outside temperature falls to -1C, and the inside temperature is 19C, determine the approximate steam flowrate. This can be calculated by proportionality.

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Hot water storage calorifiers

Hot water storage calorifiers are designed to raise the temperature of their entire contents from cold to storage temperature within a specified time period.

Fig. 2.14.3 Typical hot water storage calorifier installation Typical UK values are:

Cold water temperature 10C Hot water temperature 60C

Heat up time (also referred to as 'recovery time') = 1 hour. The mass of water to be heated may be determined from the volume of the vessel. (For water, density = 1 000 kg/m, and specific heat (cp) = 4.19 kJ/kgC).

Example 2.14.4
A storage calorifier comprises of a cylindrical vessel, 1.5 m diameter and 2 m high. The contents of the vessel are to be heated to 60C in 1 hour. The incoming water temperature is 10C, and the steam pressure is 7 bar g. Determine the steam flowrate:

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Drying cylinders
Drying cylinders vary significantly in layout and application and, consequently, in steam consumption. Apart from wide variations in size, steam pressure, and running speed, cylinders may be drained through the frame of the machines, as in textile can dryers, or by means of a blow-through system in the case of high speed paper machines. Conversely, film dryers and slow speed paper machines may use individual steam traps on each cylinder. Demand will vary from small standing losses from a cylinder drying sized cotton thread, to the heavy loads at the wet end of a paper machine or in a film dryer.

Fig. 2.14.4 Drying cylinders

Because of this, accurate figures can only be obtained by measurement. However, certain trusted formulae are in use, which enable steam consumption to be estimated within reasonable limits. In the case of textile cylinder drying machines, counting the number of cylinders and measuring the circumference and width of each will lead to the total heating surface area. The two ends of each cylinder should be included and 0.75 m per cylinder should be added to cover doll heads and frames except where individual trapping is used. The radiation loss from the machine, while standing, measured in kg of steam per hour, can be estimated by multiplying the total area by a factor of 2.44. The running load in kg per hour will be obtained by using a factor of 8.3. (In imperial units the area will be measured in square feet and the corresponding factors will be 0.5 and 1.7 respectively). This is based on a machine drying piece goods at a rate of 64 to 73 metres per minute, (70 to 80 yards per minute), but by making allowances, it can be used for machines working under different conditions. Where the amount of moisture to be removed is known, steam consumption can be calculated using the empirical Equation 2.14.1, assuming that the wet and dry weights of the material being handled are known.

Equation 2.14.1 Where:

= Mass flowrate of steam (kg/h) Ww = Throughput of wet material (kg/h Wd = Throughput of dry material (kg/h) T 2 = Temperature of material leaving the machine (C) T 1 = Temperature of material entering the machine (C) hfg = Enthalpy of evaporation of steam in cylinders (kJ/kg)
s
The factors in the equation above are empirically derived constants: 1.5 = Factor applied to cylinder dryers. 2 550 = Average water enthalpy + enthalpy of evaporation required to evaporate moisture. 1.26 = Average specific heat of material. Drying cylinders tend to have a heavy start-up load due to the huge volume of the steam space and the mass of metal to be heated, and a factor of three times the running load should be allowed in sizing steam traps. It must also be remembered that air can cause particular difficulties, such as prolonged warming up times and uneven surface temperature. Special provision must therefore be made for venting air from the cylinders. Top

Presses
Presses, like drying cylinders, come in all shapes, sizes and working pressures, and are used for many purposes, such as moulding plastic powders, preparing laminates, producing car tyres (see Figure 2.14.4), and manufacturing plywood. They sometimes also incorporate a cooling cycle. Clearly, it would be difficult to calculate steam loads with any accuracy and the only way of getting credible results is by measurement. This type of equipment may be 'open', allowing a radiation loss to atmosphere, or 'closed', when the two heating surfaces are in effect insulated from each other by the product. Although some heat is absorbed by the product, the net result is that the steam consumption is much the same whether the plant is working or standing idle, although fluctuations will occur during opening and closing.

Fig. 2.14.5 Tyre press

Steam consumption can sometimes be estimated using the basic heat transfer Equation 2.5.3:

Equation 2.5.3 Where:

= Heat transferred per unit time (W) U = Overall heat transfer coefficient (W/m K or W/m C) A = Heat transfer area (m) T = Temperature difference between the steam and the product (K or C)
The U values shown in Figure 2.9.1 may sometimes be used. They can give reasonable results in the case of large platen presses but are less accurate when small numbers of intricately shaped moulds are considered, mainly due to the difficulty of estimating the surface area. A feature of this type of plant is the small steam space, and a relatively high steam load when warming up from cold. To account for this and the load fluctuations, steam traps should be sized with a factor of 2 times the running load. Temperature control can be very accurate using pilot operated direct acting reducing valves, giving a constant and consistent steam pressure corresponding to the required surface temperature. These are sized simply on the designed steam load. Top

Tracer lines
Pipelines carrying viscous fluids are frequently maintained at an elevated temperature by means of steam tracers. These usually consist of one or more small bore steam lines running alongside the product line, the whole being covered in insulation. In theory, the exact calculation of steam consumption is difficult, as it depends on:

The degree of contact between the two lines, and whether heat conducting pastes are used. The temperature of the product. The length, temperature and pressure drop along the tracer lines. The ambient temperature. Wind speed. The emissivity of the cladding.

Fig. 2.14.6 A steam tracer

Fig. 2.14.7 Jacketed pipeline

Fig. 2.14.8 Heated sampling point

In practice, it is usually safe to assume that the tracer line simply replaces radiation losses from the product line itself. On this basis, the steam consumption of the tracer line may be taken as a running load being equal to the radiation loss from the product lines. Table 2.14.1 provides heat losses from insulated pipes with either 50 or 100 mm of insulation.

Table 2.14.1 Typical heat losses from insulated pipes (W/m) with wind speed of 10 m/s (36 km/h) Once the heat loss has been determined, steam consumption can be calculated using Equation 2.12.4:

Equation 2.12.4 Where:

= Steam demand (kg/h) = Heat loss from Table 2.14.1 (W/m) L = Length of traced product line (m) hfg = Enthalpy of evaporation at operating pressure (kJ/kg)
s
Note: The factor 3.6 gives the answer in kg/h

Example 2.14.5
A 50 m long x 200 mm pipe contains a liquid product at 120C. The ambient temperature is 20C, the pipe has 50 mm of insulation, and steam is supplied at 7 bar g to the tracer(s). Determine the steam consumption: Pipe length (L) = 50 m Temperature difference between product and ambient = 120C - 20C = 100C Heat loss per metre from the pipe ( = 97 W/m (from Figure 2.14.1)

hfg of steam at 7 bar g = 2 048 kJ/kg (steam tables)

For jacketed lines, the heat loss may be assumed to be the same as that from a steam main which has a diameter equal to that of the jacket; also taking any insulation into account. When sizing the steam traps, a factor of 2 times the running load should be used to cover start-up conditions, but any temperature control valve can be sized to handle the design load only. Sizing the tracer line Example 2.14.5 calculates the steam tracer load on the basis of the heat loss from the pipe. In practice, the tracer line will not be exactly sized to match this heat loss. Table 2.14.2 shows the useful heat output from 15 mm and 20 mm steel and copper tracer lines operating at different pressures alongside product lines at different temperatures. The Table accounts for heat losses from the tracer lines to the surrounding air through the insulation.

Table 2.14.2 Useful heat outputs from steel and copper tracer lines In Example 2.14.5, the heat loss from the pipe was 97 W/m. The tracer line has to be able to supply at least this rate of heat transfer. Table 2.14.2 shows that, by interpolation, the useful heat output from a 15 mm steel tracer line is 33 W/m for a product temperature of 120C and a steam pressure of 5 bar g. The number of tracers required to maintain the product temperature of 120C are therefore:

Therefore three 15mm steel tracer lines will be required for this application as shown in Figure 2.14.9.

Fig. 2.14.9 Three 15 mm tracer lines fitted to a 200 mm process pipe

Entropy - A Basic Understanding

Entropy is a concept some find difficult to grasp, but in truth it does not deserve such notoriety. Look upon Entropy as a road map that connects thermodynamic situations. This tutorial hopes to shed some light on this subject, by approaching it from first principles. Use the quick links below to take you to the main sections of this tutorial:

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What is entropy?
In some ways, it is easier to say what it is not! It is not a physical property of steam like pressure or temperature or mass. A sensor cannot detect it, and it does not show on a gauge. Rather, it must be calculated from things that can be measured. Entropy values can then be listed and used in calculations; in particular, calculations to do with steam flow, and the production of power using turbines or reciprocating engines. It is, in some ways, a measure of the lack of quality or availability of energy, and of how energy tends always to spread out from a high temperature source to a wider area at a lower temperature level. This compulsion to spread out has led some observers to label entropy as 'time's arrow'. If the entropy of a system is calculated at two different conditions, then the condition at which the entropy is greater occurs at a later time. The increase of entropy in the overall system always takes place in the same direction as time flows. That may be of some philosophical interest, but does not help very much in the calculation of actual values. A more practical approach is to define entropy as energy added to or removed from a system, divided by the mean absolute temperature over which the change takes place.

To see how this works, perhaps it is best to start off with a diagram showing how the enthalpy content of a kilogram of water increases as it is heated to different pressures and evaporated into steam. Since the temperature and pressure at which water boils are in a fixed relationship to each other, Figure 2.15.1 could equally be drawn to show enthalpy against temperature, and then turned so that temperature became the vertical ordinates against a base of enthalpy, as in Figure 2.15.2.

Fig. 2.15.1 The enthalpy/pressure diagram

Fig. 2.15.2 The temperature/enthalpy diagram Lines of constant pressure originate on the saturated water line. The horizontal distance between the saturated water line and the dry saturated steam line represents the amount of latent heat or enthalpy of evaporation, and is called the evaporation line; (enthalpy of evaporation decreases with rising pressure). The area to the right of the dry saturated steam line is the superheated steam region, and lines of constant pressure now curve upwards as soon as they cross the dry saturated steam line. A variation of the diagram in Figure 2.15.2, that can be extremely useful, is one in which the horizontal axis is not enthalpy but instead is enthalpy divided by the mean temperature at which the enthalpy is added or removed. To produce such a diagram, the entropy values can be calculated. By starting at the origin of the graph at a temperature of 0C at atmospheric pressure, and by adding enthalpy in sm all amounts, the graph can be built. As entropy is measured in terms of absolute temperature, the origin temperature of 0C is taken as 273.15 K. The specific

heat of saturated water at this temperature is 4.228 kJ/kg K. For the purpose of constructing the diagram in Figure 2.15.3 the base temperature is taken as 273 K not 273.15 K. By assuming a kilogram of water at atmospheric pressure, and by adding 4.228 kJ of energy, the water temperature would rise by 1 K from 273 K to 274 K. The mean temperature during this operation is 273.5 K, see Figure 2.15.3.

Fig. 2.15.3 The cumulative addition of 4.228 kJ of energy to water from 0C

This value represents the change in enthalpy per degree of temperature rise for one kilogram of water and is termed the change in specific entropy. The metric units for specific entropy are therefore kJ/kg K. This process can be continued by adding another 4.228 kJ of energy to produce a series of these points on a state point line. In the next increment, the temperature would rise from 274 K to 275 K, and the mean temperature is 274.5 K.

It can be seen from these simple calculations that, as the temperature increases, the change in entropy for each equal increment of enthalpy reduces slightly. If this incremental process were continuously repeated by adding more heat, it would be noticed that the change in entropy would continue to decrease. This is due to each additional increment of heat raising the temperature and so reducing the width of the elemental strip representing it. As more heat is added, so the state point line, in this case the saturated water line, curves gently upwards. At 373.14 K (99.99C), the boiling point of water is reached at atmospheric pressure, and further additions of heat begin to boil off some of the water at this constant temperature. At this position, the state point starts to move horizontally across the diagram to the right, and is represented on Figure 2.15.4 by the horizontal evaporation line stretching from the saturated water line to the dry saturated steam line. Because this is an evaporation process, this added heat is referred to as enthalpy of evaporation. At atmospheric pressure, steam tables state that the amount of heat added to evaporate 1 kg of water into steam is 2256.71 kJ. As this takes place at a constant temperature of 373.14 K, the mean temperature of the evaporation line is also 373.14 K. The change in specific entropy from the water saturation line to the steam saturation line is therefore:

The diagram produced showing temperature against entropy would look something like that in Figure 2.15.4, where:

1 is the saturated water line. 2 is the dry saturated steam line. 3 are constant dryness fraction lines in the wet steam region. 4 are constant pressure lines in the superheat region.

Fig. 2.15.4 The temperature - entropy diagram

What use is the temperature - entropy diagram (or T - S diagram)?

One potential use of the T - S diagram is to follow changes in the steam condition during processes occurring with no change in entropy between the initial and final state of the process. Such processes are termed Isentropic (constant entropy).

Unfortunately, the constant total heat lines shown in a T - S diagram are curved, which makes it difficult to follow changes in such free and unrestricted expansions as those when steam is allowed to flow through and expand after a control valve. In the case of a control valve, where the velocities in the connecting upstream and downstream pipes are near enough the same, the overall process occurs with constant enthalpy (isenthalpic). In the case of a nozzle, where the final velocity remains high, the overall process occurs with constant entropy. To follow these different types of processes, a new diagram can be drawn complete with pressures and temperatures, showing entropy on the horizontal axis, and enthalpy on the vertical axis, and is called an enthalpy - entropy diagram, or H - S diagram, Figure 2.15.5.

Fig. 2.15.5 The H - S diagram The H - S diagram is also called the Mollier diagram or Mollier chart, named after Dr. Richard Mollier of Dresden who first devised the idea of such a diagram in 1904. Now, the isenthalpic expansion of steam through a control valve is simply represented by a straight horizontal line from the initial state to the final lower pressure to the right of the graph, see Figure 2.15.6; and the isentropic expansion of steam through a nozzle is simply a line from the initial state falling vertically to the lower final pressure, see Figure 2.15.7.

Fig. 2.15.6 Isenthalpic expansion, as through a control valve

Fig. 2.15.7 Isentropic expansion, as through a nozzle An isentropic expansion of steam is always accompanied by a decrease in enthalpy, and this is referred to as the 'heat drop' (H) between the initial and final condition. The H values can be simply read at the initial and final points on the Mollier chart, and the difference gives the heat drop. The accuracy of the chart is sufficient for most practical purposes. As a point of interest, as the expansion through a control valve orifice is an isenthalpic process, it is assumed that the state point moves directly to the right; as depicted in Figure 2.15.6. In fact, it does not do so directly. For the steam to squeeze through the narrow restriction it has to accelerate to a higher speed. It does so by borrowing energy from its enthalpy and converting it to kinetic energy. This incurs a heat drop. This part of the process is isentropic; the state point moves vertically down to the lower pressure. Having passed through the narrow restriction, the steam expands into the lower pressure region in the valve outlet, and eventually decelerates as the volume of the valve body increases to connect to the downstream pipe. This fall in velocity requires a reduction in kinetic energy which is mostly re-converted back into heat and re-absorbed by the steam. The heat drop that caused the initial increase in kinetic energy is reclaimed (except for a small portion lost due to the effects of friction), and on the H - S chart, the state point moves up the constant pressure line until it arrives at the same enthalpy value as the initial condition. The path of the state point is to be seen in Figure 2.15.8, where pressure is reduced from 5 bar at saturation temperature to 1 bar via, for example, a pressure reducing valve. Steam's enthalpy at the upstream condition of 5 bar is 2748 kJ/kg.

Fig. 2.15.8 The actual path of the state point in a control valve expansion It is interesting to note that, in the example dicussed above and shown in Figure 2.15.8, the final condition of the steam is above the saturation line and is therefore superheated. Whenever such a process (commonly called a throttling process) takes place, the final condition of the steam will, in most cases, be drier than its initial condition. This will either produce drier saturated steam or superheated steam, depending on the respective positions of the initial and final state points. The horizontal distance between the initial and final state points represents the change in entropy. In this example, although there was no overall change in enthalpy (ignoring the small effects of friction), the entropy increased from about 6.8 kJ/kg K to about 7.6 kJ/kg K.

Entropy always increases in a closed system

In any closed system, the overall change in entropy is always positive, that is, it will always increase. It is worth considering this in more detail, as it is fundamental to the concept of entropy. Whereas energy is always conserved (the first law of thermodynamics states that energy cannot be created or destroyed), the same cannot be said about entropy. The second law of thermodynamics says that whenever energy is exchanged or converted from one form to another, the potential for energy to do work gets less. This really is what entropy is all about. It is a measure of the lack of potential or quality of energy; and once that energy has been exchanged or converted, it cannot revert back to a higher state. The ultimate truth of this is that it is nature's duty for all processes in the Universe to end up at the same temperature, so the entropy of the Universe is always increasing.

Example 2.15.1
Consider a teapot on a kitchen table that has just been filled with a certain quantity of water containing 200 kJ of heat energy at 100C (37 3 K) from an electric kettle. Consider next that the temperature of the air surrounding the mug is at 20C, and that the amount of heat in the teapot water would be 40 kJ at the end of the process. The second law of thermodynamics also states that heat will always flow from a hot body to a colder body, and in this example, it is certain that, if left for sufficient time, the teapot will cool to the same temperature as the air that surrounds it. What are the changes in the entropy values for the overall process? For the teapot:

Because the heat is lost from the teapot, convention states that its change in entropy is negative. For the air: Initial air temperature = 293 K (20C) At the end of the process, the water in the teapot would have lost 160 kJ and the air would have gained 160 kJ; however, the air temperature would not have changed because of its large volume, therefore:

Because the heat is received by the air, convention states that its change in enthalpy is positive. Therefore:

Practical applications - Heat exchangers

In a heat exchanger using saturated steam in the primary side to heat water from 20C to 60C in the secondary side, the steam will condense as it gives up its heat. This is depicted on the Mollier chart by the state point moving to the left of its initial position. For steady state conditions, dry saturated steam condenses at constant pressure, and the steam state point moves down the constant pressure line as shown in Figure 2.15.9.

Example 2.15.2
This example considers steam condensing from saturation at 2 bar at 120C with an entropy of 7.13 kJ/kg K, and an enthalpy of about 2700 kJ/kg. It can be seen that the state point moves from right to left, not horizontally, but by following the constant 2 bar pressure line. The chart is not big enough to show the whole condensing process but, if it were, it would show that the steam's final state point would rest with an entropy of 1.53 kJ/kg K and an enthalpy of 504.8 kJ/kg, at 2 bar and 120C on the saturated water line.

Fig. 2.15.9 The initial path of the state point for condensing steam It can be seen from Figure 2.15.9 that, when steam condenses, the state point moves down the evaporation line and the entropy is lowered. However, in any overall system, the entropy must increase, otherwise the second law of thermodynamics is violated; so how can this decrease in entropy be explained? As for the teapot in the Example 2.15.1, this decrease in entropy only reflects what is happening in one part of the system. It must be remembered that any total system includes its surroundings, in Example 2.15.2, the water, which receives the heat imparted by the steam. In Example 2.15.2, the water receives exactly the same amount of heat as the steam imparts (it is assumed there are no heat losses), but does so at a lower temperature than the steam; so, as entropy is given by enthalpy/temperature, dividing the same quantity of heat by a lower temperature means a greater gain in entropy by the water than is lost by the steam. There is therefore an overall gain in the system entropy, and an overall spreading out of energy.

Table 2.15.1 Relative densities/specific heat capacities of various solids

Table 2.15.2 Relative densities/specific heat capacities of various liquids

Table 2.15.3 Specific heat capacities of gases and vapours

Entropy - Its Practical Use

Entropy can be used to understand thermodynamic applications from first principles. This tutorial gives practical examples of how this can be done. Use the quick links below to take you to the main sections of this tutorial:

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Practical use of entropy

It can be seen from Tutorial 2.15 that entropy can be calculated. This would be laborious in practice, consequently steam tables usually carry entropy values, based on such calculations. Specific entropy is designated the letter 's' and usually appears in columns signifying specific values for saturated liquid, evaporation, and saturated steam, sf, sfg and sg respectively. These values may equally be found in charts, and both Temperature - Entropy (T - S) and Enthalpy - Entropy (H - S) charts are to be found, as mentioned in Tutorial 2.15. Each chart has particular use

in specific circumstances. The T - S chart is often used to determine the properties of steam during its expansion through a nozzle or an orifice. The seat of a control valve would be a typical example. To understand how a T - S chart is applied, it is worth sketching such a chart and plotting the steam properties at the start condition, reading these from the steam tables.

Example 2.16.1
Steam is expanded from 10 bar a and a dryness fraction of 0.9 to 6 bar a through a nozzle, and no heat is removed or supplied during this expansion process. Calculate the final condition of the steam at the nozzle outlet? Specific entropy values quoted are in uni ts of kJ/kgC. At 10 bar a, steam tables state that for dry saturated steam:

As no heat is added or removed during the expansion, the process is described as being adiabatic and isentropic, that is, the entropy does not change. It must still be 6.1413 kJ/kgC at the very moment it passes the throat of the nozzle.

By knowing that this process is isentropic, it has been possible to calculate the dryness fraction at the outlet condition. It is now possible to consider the outlet condition in terms of specific enthalpy (units are in kJ/kg).

It can be seen that the specific enthalpy of the steam has dropped in passing through the nozzle from 2576.25 to 2489.30 kJ/kg, that is, a heat drop of 86.95 kJ/kg. This seems to contradict the adiabatic principle, which stipulates that no energy is removed from the process. But, as seen in Tutorial 2.15, the explanation is that the steam at 6 bar a has just passed through the nozzle throat at high velocity, consequently it has gained kinetic energy. As energy cannot be created or destroyed, the gain in kinetic energy in the steam is at the expense of its own heat drop. The above entropy values in Example 2.16.1 can be plotted on a T - S diagram, see Figure 2.16.1.

Fig. 2.16.1 The T - S diagram for Example 2.16.1

Further investigation of kinetic energy in steam

What is the significance of being able to calculate the kinetic energy of steam? By knowing this value, it is possible to predict the steam velocity and therefore the mass flow of steam through control valves and nozzles. Kinetic energy is proportional to mass and the square of the velocity. It can be further shown that, when incorporating Joule's mechanical equivalent of heat, kinetic energy can be written as Equation 2.16.1:

Equation 2.16.1 Where:

E = Kinetic energy (kJ) m = Mass of the fluid (kg) u = Velocity of the fluid (m/s) g = Acceleration due to gravity (9.80665 m/s) J = Joule's mechanical equivalent of heat (101.972 m kg/kJ)
By transposing Equation 2.16.1 it is possible to find velocity as shown by Equation 2.16.2:

Equation 2.16.2

For each kilogram of steam, and by using Equation 2.16.2

As the gain in kinetic energy equals the heat drop, the equation can be written as shown by Equation 2.16.3:

Equation 2.16.3 Where: h = Heat drop in kJ/kg

By calculating the adiabatic heat drop from the initial to the final condition, the velocity of steam can be calculated at various points along its path; especially at the throat or point of minimum pass area between the plug and seat in a control valve. This could be used to calculate the orifice area required to pass a given amount of steam through a control valve. The pass area will be greatest when the valve is fully open. Likewise, given the valve orifice area, the maximum flowrate through the valve can be determined at the stipulated pressure drop. See Examples 2.16.2 and 2.16.3 for more details.

Example 2.16.2
Consider the steam conditions in Example 2.16.1 with steam passing through a control valve with an orifice area of 1 cm. Cal culate the maximum flow of steam under these conditions. The downstream steam is at 6 bar a, with a dryness fraction of 0.8718. Specific volume of dry saturated steam at 6 bar a (sg) equals 0.3156 m/kg. Specific volume of saturated steam at 6 bar a and a dryness fraction of 0.8718 equals 0.3156 m/kg x 0.8718 which equates to 0.2751 m/kg. The heat drop in Example 2.16.1 was 86.95 kJ/kg, consequently the velocity can be calculated using Equation 2.16.3:

Equation 2.16.3

The mass flow is calculated using Equation 2.16.4:

Equation 2.16.4 An orifice area of 1 cm equals 0.0001 m

Point of interest
Thermodynamic textbooks will usually quote Equation 2.16.3 in a slightly different way as shown in Equation 2.16.5:

Equation 2.16.5 Where:

u = Velocity of the fluid in m/s h = Heat drop in J/kg 2 = Constant of proportionality incorporating the gravitational constant 'g'
Considering the conditions in Example 2.16.3:

This velocity is exactly the same as that calculated from Equation 2.16.3, and the user is free to practise either equation according to preference. The above calculations in Example 2.16.2 could be carried out for a whole series of reduced pressures, and, if done, would reveal that the flow of saturated steam through a fixed opening increases quite quickly at first as the downstream pressure is lowered. The increases in flow become progressively smaller with equal increments of pressure drops and, with saturated steam, these increases actually become zero when the downstream pressure is 58% of the absolute upstream pressure. (If the steam is initially superheated, CPD will occur at just below 55% of the absolute upstream pressure). This is known as the 'critical flow' condition and the pressure drop at this point is referred to as critical pressure drop (CPD). After this point has been reached, any further reduction of downstream pressure will not give any further increase in mass flow through the opening. In fact if, for saturated steam, the curves of steam velocity (u) and sonic velocity (s) were drawn for a convergent nozzle (Figure 2.16.2), it would be found that the curves intersect at the critical pressure. P1 is the upstream pressure, and P is the pressure at the throat.

Fig. 2.16.2 Steam and acoustic velocities through a nozzle The explanation of this, first put forward by Professor Osborne Reynolds (1842 - 1912) of Owens College, Manchester, UK, is as follows: Consider steam flowing through a tube or nozzle with a velocity u, and let s be the speed of sound (sonic velocity) in the steam at any given point, s being a function of the pressure and density of the steam. Then the velocity with which a disturbance such as, for example, a sudden change of pressure P, will be transmitted back through the flowing steam will be s - u. Referring to Figure 2.16.2, let the final pressure P at the nozzle outlet be 0.8 of its inlet pressure P1. Here, as the sonic velocity s is greater than the steam velocity u, s - u is clearly positive. Any change in the pressure P would produce a change in the rate of mass flow. When the pressure P has been reduced to the critical value of 0.58 P1, s - u becomes zero, and any further reduction of pressure after the throat has no effect on the pressure at the throat or the rate of mass flow. When the pressure drop across the valve seat is greater than critical pressure drop, the critical velocity at the throat can be calculated from the heat drop in the steam from the upstream condition to the critical pressure drop condition, using Equation 2.16.5. Top

Control valves
The relationship between velocity and mass flow through a restriction such as the orifice in a control valve is sometimes misunderstood.

Pressure drop greater than critical pressure drop

It is worth reiterating that, if the pressure drop across the valve is equal to or greater than critical pressure drop, the mass flow through the throat of the restriction is a maximum and the steam will travel at the speed of sound (sonic velocity) in the throat. In other words, the critical velocity is equal to the local sonic velocity, as described above. For any control valve operating under critical pressure drop conditions, at any reduction in throat area caused by the valve moving closer to its seat, this constant velocity will mean that the mass flow is simultaneously reduced in direct proportion to the size of the valve orifice.

Pressure drop less than critical pressure drop

For a control valve operating such that the downstream pressure is greater than the critical pressure (critical pressure drop is not reached), the velocity through the valve opening will depend on the application.

Pressure reducing valves

If the valve is a pressure reducing valve, (its function is to achieve a constant downstream pressure for varying mass flowrates) then, the heat drop remains constant whatever the steam load. This means that the velocity through the valve opening remains constant whatever the steam load and valve opening. Constant upstream steam conditions are assumed. It can be seen from Equation 2.16.4 that, under these conditions, if velocity and specific volume are constant, the mass flowrate through the orifice is directly proportional to the orifice area.

Equation 2.16.4

Temperature control valves

In the case of a control valve supplying steam to a heat exchanger, the valve is required to reduce the mass flow as the heat load falls. The downstream steam pressure will then fall with the heat load, consequently the pressure drop and heat drop across the valve will increase. Thus, the velocity through the valve must increase as the valve closes. In this case, Equation 2.16.4 shows that, as the valve closes, a reduction in mass flow is not directly proportional to the valve orifice, but is also modified by the steam velocity and its specific volume.

Example 2.16.3
Find the critical velocity of the steam at the throat of the control valve for Example 2.16.2, where the initial condition of the steam is 10 bar a and 90% dry, and assuming the downstream pressure is lowered to 3 bar a.

The velocity of the steam through the throat of the valve can be calculated using Equation 2.16.5:

Equation 2.16.5

The critical velocity occurs at the speed of sound, consequently 430 m/s is the sonic velocity for the Example 2.16.3.

Noise in control valves

If the pressure in the outlet of the valve body is lower than the critical pressure, the heat drop at a point immediately after the throat will be greater than at the throat. As velocity is directly related to heat drop, the steam velocity will increase after the steam passes the throat of the restriction, and supersonic velocities can occur in this region. In a control valve, steam, after exiting the throat, is suddenly confronted with a huge increase in space in the valve outlet, and the steam expands suddenly. The kinetic energy gained by the steam in passing through the throat is converted back into heat; the velocity falls to a value similar to that on the upstream side of the valve, and the pressure stabilises in the valve outlet and connecting pipework. For the reasons mentioned above, valves operating at and greater than critical pressure drop will incur sonic and supersonic velocities, which will tend to produce noise. As noise is a form of vibration, high levels of noise will not only cause environmental problems, but may actually cause the valve to fail. This can sometimes have an important bearing when selecting valves that are expected to operate under critical flow conditions. It can be seen from previous text that the velocity of steam through control valve orifices will depend on the application of the valve and the pressure drop across it at any one time.

Reducing noise in control valves

There are some practical ways to deal with the effects of noise in control valves. Perhaps the simplest way to overcome this problem is to reduce the working pressure across the valve. For instance, where there is a need to reduce pressure, by reducing pressure with two valves instead of one, both valves can share the total heat drop, and the potential for noise in the pressure reducing station can be reduced considerably. Another way to reduce the potential for noise is by increasing the size of the valve body (but retaining the correct orifice size) to help ensure that the supersonic velocity will have dissipated by the time the flow impinges upon the valve body wall. In cases where the potential for noise is extreme, valves fitted with a noise attenuator trim may need to be used. Steam velocities in control valve orifices will reach, typically, 500 m/s. Water droplets in the steam will travel at some slightly lower speed through a valve orifice, but, being incompressible, these droplets will tend to erode the valve and its seat as they squeeze between the two.

It is always sensible to ensure that steam valves are protected from wet steam by fitting separators or by providing adequate line drainage upstream of them. Top

Summing up of Tutorials 2.15 and 2.16

The T - S diagram, shown in Figure 2.16.1, and reproduced below in Figure 2.16.3, shows clearly that the steam becomes wetter during an isentropic expansion (0.9 at 10 bar a to 0.8718 at 6 bar a) in Example 2.16.1.

Fig. 2.16.3 A T-S diagram showing wetter steam from an isentropic expansion At first, this seems strange to those who are used to steam getting drier or becoming superheated during an expansion, as happens when steam passes through, for example, a pressure reducing valve. The point is that, during an adiabatic expansion, the steam is accelerating up to high speed in passing through a restriction, and gaining kinetic energy. To provide this energy, a little of the steam condenses (if saturated steam), (if superheated, drops in temperature and may condense) providing heat for conversion into kinetic energy. If the steam is flowing through a control valve, or a pressure reducing valve, then somewhere downstream of the valve's seat, the steam is slowed down to something near its initial velocity. The kinetic energy is destroyed, and must reappear as heat energy that dries out or superheats the steam depending on the conditions. The T - S diagram is not at all convenient for showing this effect, but the Mollier diagram (the H - S diagram) can do so quite clearly. The Mollier diagram can depict both an isenthalpic expansion as experienced by a control valve, (see Figure 2.15.6) by moving horizontally across the graph to a lower pressure; and an isentropic expansion as experienced by steam passing through a nozzle, (see Figure 2.15.7) by moving horizontally down to a lower pressure. In the former, the steam is usually either dried or superheated, in the latter, the steam gets wetter. This perhaps begs the question, 'How does the steam know if it is to behave in an isenthalpic or isentropic fashion?' Clearly, as the steam accelerates and rushes through the narrowest part of the restriction (the throat of a nozzle, or the adjustable gap between the valve and seat in a control valve) it must behave the same in either case. The difference is that the steam issuing from a nozzle will next meet a turbine wheel and gladly give up its kinetic energy to turn the turbine. In fact, a nozzle could be thought of as a device to convert heat energy into kinetic energy for this very purpose. In a control valve, instead of doing such work, the steam simply slows down in the valve outlet passages and its connecting pipework, when the kinetic energy appears as heat energy, and unwittingly goes on its way to give up this heat at a lower pressure. It can be seen that both the T - S diagram and H - S diagram have their uses, but neither would have been possible had the concept of entropy not been utilised.