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Steels
Outline of todays lecture Alloying elements The effect of carbon The effect of alloying elements on
microstructure Grain size softening during tempering Embrittlement during tempering Ductile-brittle Transition temperature Temperature of recrystallization Mechanical properties of ferrite Forming of carbides and nitrides
Impact Energy , KV
UTS
Carbon %
Structura stee s !oo stee s
Effect of C% on properties
"on#heat treatab e
Heat treatab e
The effect of alloying elements on the properties of steel '( )( -( /( 0( 1( 2( Solubility ! ferrite or austenite producing e( &on-e*uilibrium + , transformation Austenite grain gro.th Softening during tempering Embrittlement during tempering Ductile-brittle transition temperature 3ecrystallization4s temperature
Dissol5es
Dissol5es better in ferrite ! ferrite producing e(
r6 Al6 Si6 86 Mo6 96 Ti
Semi-austenitic
Ferriticperlitic
"erlitic: Sec( em
Ferriticperlitic
"erlitic: Sec( em
;edebutitic
;edebutitic
The
Conditions of &uenching >mportance of *uenching? .ith *uenching@tempering $allotropic transformation% the properties can be influenced in .ide range( onditions
=eating to the temperature of A- : A0BC Deeping at constant temperature till material if fully austenitized ooling faster the the critical cooling rate( "ractical condition? E B()F
C1)
(ractical conditions
MS G /HB C
The alloying decreases the critical cooling rate and the Ms temperature(
5critf
C*+ MS G -/B C
5.ater 5oil
B6))
Effect of through hardenability
$F%
The trough hardening diameter The ma<imal diameter of a bar6 .hich can be *uenched to contain 0BF of martensite( see more? lab practice7
Martensitic layer
T cooling 5critf
Temperature distribution
&i
9 o
9erification of material
=ardness
Technology information
Ma<imalJminimal hardness by *uenching =arness distribution in the cross section
3mpact energy
Tempering temperature! 2C
r6 Mn cases brittleness if slo.ly cooled at 0BB10BC 3eason? Enrichment of arbides6 nitrides6 phosphides at grain boundaries " maLes it .orse( &i together .ith r and Mn is disad5antageous B6)7B6-F Mo or B60B62F 8 and fast cooling is ad5antageous(
A-BBC A)BBC
lassification of steels
Classification according to
'% Steel production methods $old category% )% Structure at room temperature -% ontent of alloying elements
/% "urpose of utilization
"lloyed steels
- micro alloyed steels - lo. alloyed steels - medium alloyed steels - high alloyed steels NAlloy M B('F $Ti6 &i6 96 7% NAlloy M - F NAlloy M 'B F NAlloy E 'B F
Semi-austenitic
Ferriticperlitic
"erlitic: Sec( em
Ferriticperlitic
"erlitic: Sec( em
;edebutitic
;edebutitic
8tili6ation
Structural steels
Automotic industry6 machine industry 6 steel structures Thoughness is also a re*uirement M B61F
Tool steels
Machining and forming tools 8ear resistance6 stiffness6 hardness hardenable6 precipitation hardenable alloys
Designation of steels
According to different standards Most .ell-Lno.n standards? >nternational Standard #rganization American >ron and Steel >nstitute Society of Automoti5e Engineer American Society for Testing and Materials 37O "373 7"E "7TM
Designation of steels
E<ample? .erLstoffnumber
Material group Steel group ' ! steels ) ! hea5y metals - ! light metals / ! nonmetalic 7
'(/- BB <<
number Au< sign
7hort designation
sign S " ; E B 7
"pplication "rea Structural steel "ressure 5essel steel "ipe steels Steels for machines Steels for concrete 7
Main prop. 3e= $Mpa% 3e= $Mpa% 3e= $Mpa% 3e= $Mpa% 3e= $Mpa% 7
7tructural steels
A? hot rolled structural steels B? flat steel products for pressure 5essels Formable6 .eldable ? Steels for cold forming D? =eat treatable steels E? ase hardening steels F? &itridable steels G? other
For general purpose =ot rolled of forged state ertificate? 3m6 3e=6 A6 D96 chem( comp an not be used in some cases
arbon e*ui5alent $ less than B60F6 see later%
&ormalized during rolling Grain size number greater than 1 Au<iliary marL? &? normalised ;? impact energy )2 P at -0BC E(g(? S)20&6 S)20&;
"0 Thermomechanical rolled! 1elda'le! fine% grained steels Thermomechanical rolling? controlled recrystallisation during deformation &b alloying increases the recrystallisations Temperature The grain refinement is promoted by Tialloyinf Au<iliary marL? M E(g(? S-00M6 S-00M;
Better heat resistance6 used in heat treated state #il industry6 refineries6 hydogene appliances
"0 7heets and 'ands from high strength heat treata'le steels 8elded structures for high load at lo. or en5ironment temperature( ontainers6 bridges cranes etc( Au<iliary marL? R 8eldable but susceptible to cold cracLing E(g(? S/1BR;
B0 (lain and alloyed steels for elevated temperatures "lain steels $e(g(? ")-0G=%
Sield stress or creep strength is gi5en Steam boilers6 pressure 5essels Tp to A/BBC -
Three sub-classes
3oom temperature *uality $"7&%
T E -)BC
The impact energy is prescri ed #or structures &elo' "()*C +i alloying !CC lattice not sensiti,e to em rittlement Selection according to temperature and thic%ness Accepta le impact energy e,en at "-)) *C Cooling and cryogen technology E.g./ 001n+i2"3, 0-+i04, 56+i7
Micro alloying elements for grain refining and strengthening $Ti6 &b6 96 &6 B% 8eldability is influenced by? thicLness6 input energy6 design6 .elding process6 electrode
Martensitic steels
"ump parts6 5al5es6 turbine impellers Tp to -BBC -ig 0-B-0HB Mpa yield stress
Austenitic steels
8ide range of application From -'I1 to 1BBC applicable $F 6 no susceptibility to embrittlement after solution heat treatment6 there is no TTD9%
C0 Cold rolled flat products from lo1 car'on steels for cold forming
;o. carbon content6 ferritic steel 9ery lo. alloy content D B'7D B16 ? A6 or B ! surface *uality
A? surface insufficiency $e(g( scratch% allo.ed B? no surface imperfection allo.ed
E(g(? D B'Am
E(g(? D B- //BMB
C0 9ot rolled high strengh steel flat products for cold forming
For cold forming6 hot rolled6 .eldable high strength6 alloyed Thermo mechanical or normalizing rolled ;o. "erlite steels $Ti6 &b6 9% ! =S;A E(g(? S/)B& 6 S/1BM "lastically formable6 shearable6 bendable6 machinable 8elded structures6 automoti5e industry
D( 7teels
Good strength6 good formability 8heels6 car body6 bumper6 .ires6 building structures
T<3( steels
T3ansformation >nduced "lasticity Ferritic-austenitic-bainitic microstructure after hot forming Austenite transforms to martensite during further forming car body6 5ehicle industry
D( = T<3(
89
T:I9
3> steels
>nterstitial Free E<tra lo. content of alloying elements $-B-1B ppm% Good deep dra.ability6 formability6 no aging =ousehold appliances6 5ehicle o5erlay parts
B9 steels
BaLe =ardening ;o. carbon content alloys6 precipitation hardenable at A)BBC >ncreases the yield stress by A/B M"a though precipitation hardening $ and &% E(g(? after forming during painting 9ehicle body elements
Mn (1.4-1.65%) cheap >ncreased trough hardening diameter Susceptibility to o5er heating and embrittlement during tempering $fast cooling necessary% Must not be used for parts .ith ser5ice temperature belo. BC E(g(? )HMn1
Cr (even 2%) Most common alloying element Strongly >ncreases the trough hardening diameter and yield stress Good surface hardenability For lo. to middle stresses6 engine parts6 a<les E(g(? -/ r/
Cr-Mo (even 2% Cr, 0. -1.2% Mo) Mo eliminates the embrittlement during tempering r and Mo are strong carbide-forming elements6 tempering at higher temperatures $A1BBC % Significant strength and good toughness For middle sized part for high fatigue and impact loads( A<les6 parts .ith teeth E(g(? 0B rMo/
Cr-! (0."-1.1% Cr, 0.1-0.2% !) Similar to r-Mo steels a little cheaper but .orse toughness For middle sized part for high fatigue and impact loads( E(g(? 0' r9/
$oron steels Mn6 Mn- r alloying6 B micro alloying Though hardening diameter increases significantly Deli5ered generally in hot formed state Good toughness E(g(? )BMnB06 )2Mn rB0-)
Small size parts for modest loads pins6 gear pumps =arness? 00-1B =3 Tp to )B--B mm size E(g(? 'B6 '0
They are basically heat treatable steels Aim? 5ery hard .ear resistant surface layer Addition of nitride-forming elements $ r6 Al6 96 Ti% 3esults? .ear-resistant6 hard6 better fatigueresistance( Sensiti5e to high local pressures E(g(? -/ rAl&i2-'B
Free-cutting steels Steels for roll-bearings Spring steels Steels and nicLel alloys for cryogenic and ;o.Temperature application =eat resistant steels and nicLel alloys Steels and alloys for 5al5es of internal combustion engines
>ree%cutting steels
For high performance machining cells aim? brittle chip S and S:Bi alloying E(g(? ''SMn-26 'BS)B6 //SMn)H
Ruenching6 cooling to lo.er temp( $--BC %6 lo. temperature tempering ! 1) =3 E(g(? 'BB r16 'BB rMnMoSiH-/-16 'IMn r06 'H&i rMo'/-16 2BMn/6 D#?O10 r'/6 OHI rMo9'H-'6 HBMo r9/)-'16 OH)8Mo r91-0-/
7pring steels 3.
Storing of elastic energy =igh yield stress $'BBB-'-0B M"a% and acceptable ultimate tensile strain are necessary $1-HF% =eat treatable steels6 B(/-B(2F -content6 lo. temperature tempering $/0B-/HBC % For different purposes
7teels and nic@el alloys for cryogenic! lo1% temperature and heat resistant application
Tnalloyed J alloyed $corr( resistant too% Applicable up to IBBC Mo? carbide-forming increases strength The corrosion must be taLen into account beside of heat-loading( E(g(? 42CrMo5-6, 25CrMo4, #iCr20(i)l (#i alloy), *10Cr#iMoMn#+!$15-10-1
"roblem? #<idizing of steelsW surface o5er 0BBC Austenitic6 ferritic6 austenitic-ferritic steel reep resistant and strength are the characteristic properties Alloying .ith r6 Si6 Al Applicable e5en at IBBC -ig Groin coarsening can be a problem &i based superalloys $not iron alloysQ%
Austenitic
Grain coarsening is not significant e5en at higher temperatures6 bet.een 1BB-HBBC the X-phase causes brittlement6 e(g(? O'B&i rAlTi-)-)'
Austenitic-ferritic
>n o<idizing S-containing en5ironment6 e(g(? O'0 r&iSi)0-/
&i alloys
Pet engines6 rocLet industry6 e(g(? &i r)-Fe
9adfield steels
Austenitic6 high alloyed Mn steels A'()F 6 AB(/ Si6 A')(0F Mn >mpact .ear resistance6 hardening during .ear $cold forming% >nner not-hardened layer gi5es good toughness For dynamic and .ear loads 3ailroad s.itches6 e<ca5ator bucLet6
Tool 7teels
A? Tnalloyed tool steels B? =ot forming tool steels ? oldforming tool steels D? =igh speed steels
Aeneral re&uirements
=arness6 .ear resistance toughness =eat resistance 3esistance against thermal fatigue Appropriate trough hardening diameter
#nly base alloying and impurity elements $Mn6 Si6 S6 "% For hand tools E(g(? C 0-, C100 T marL? un-treated state
arbide compounds! hardness at high temperatures losed-dies for forging6 die-casting dies
For high performance machining( 1)-1/ =3c harness at A1BBC Main alloying elements ? 86 Mo6 96 o Special heat treatment method( $precipitation hardening% E(g(? =S1-0-)6 =S'B-/---'B
Surgery blades6 scalpel6 needles6 food industry blades E(g(? *12Cr1%, *105CrMo1", *"Cr#i)l1"-"
r-cardibes form at grain boundaries by slo. cooling at 1BB-HBBC 6 .hich spoils the corrosion resistance
an pre5ent by alloying of Ti and &b
=igh r and &i content A/B-1BF austenite at room temperature =igher strength Better stress-corrosion resitance an be applied as heat resistant steel as .ell( E(g(? O) r&i&)--/6 O) r&iMo u8&)0-2-/