CLASS ROOM ASSIGNMENT CHEMISTRY BATCH: XII NEW + OLD

ATOM, ELECTRON, PROTON, NEUTRON: 01. The atomic wt. of two elements A and B are 20 & 40 resp. if X g of A contains Y atoms, how many atoms are present in 2X g of B. 02. Which of the following contain/(s) same no. of proton (a) NH3 (b) H2O (c) HF (d)PH3 [6.0224x1023] [y atoms]

BASIC MOLE

CRA NO: 1.2

03. Calculate the total number of electrons present in 1.6g of CH4. 04. Find (i) Total number of neutrons and (ii) Total mass of neutrons in 7 mg of
14

C (assume that the mass of a neutron= mass of hydrogen atom) [24.088 x 1020, 0.004 g]

05. Calculate the total number of electrons present in 18 ml of water 06. Calculate the number of electrons, protons and neutrons in 1 mole of O2 ions

[10 x 6.022 x 1023]

[10 x 6.022 x 1023,8 x 6.022 x 1023, 8 x 6.022 x 1023] 07. Maximum no. of hydrogen atoms are in (a) 16 gm CH4 (b) 31.2 gm of C6H6 (c) 34.2 gm C12H22O11 (d) 36 gm glucose [a]

08. The wt. of NO having the same no. of oxygen atom present in 9.2 gm of NO2 is (a) 9.2 gm ATOMIC MASS UNIT 09. Simplify for x, mass of
No atoms of 2
12

(b) 6 gm

(c) 12 gm

(d) 24 gm

[c]

C+1.2 g of

12

C0.1 No atoms of

12

C = x mol of

12

C. [0.5 mol]

10. Mass of one atom of X is 6.6421023 g. What is its atomic mass? How many moles are contained in 40 kg of X? [1000 mol] 11. Mass of one atom of an element X is 2.3248110 12. Mass of one atom of an element A is 3.985410 [2.509210
22 23

g. Express this is amu. g. How many atoms are contained in 1 g of the element of A?

23

atom] [6.721020 atoms]

13. Analysis of chlorophyll shows that it contains 2.68 per cent magnesium. How many atoms of magnesium does 1 g of chlorophyll contain?

14. A certain compound has the molecular formula X4O6. if 10 g of X4O6 has 5.72 g X, atomic mass of X is (a) 32 amu (b) 37 amu (c) 42amu (d) 98 amu [25] [A]

15. How many atoms are there in 100 amu of He? MOLECULE, COMPOUND: 16. We are given 10 gm of P4O10 calculate (a) No. of molecules (c) No. of O atoms (b) No. of P atoms (d) No. of e,p, & n

17. From 200mg of CO2, 1021 molecules are removed. How many moles of CO2 are left? 18. Calculate the no. of O atoms and its weight in 50 g of CaCO3.

[0.00288] [24 g]

19. Haemoglobin is the oxygen-carrying molecule of red blood cells consisting of protein and nonprotein substance. The non protein substance is called heme. A sample of heme weighing 35.2 mg contains 3.19 mg of iron. If a heme molecule contains one atom of iron, what is the molecular wt of heme? g/mol] [617.93

20. Dexedrine is a solid with molecular formula C9H13N. Its density is 0.949 gm/ml. Calculate (a) no. of moles of Dexedrine in 62.87 g sample (b) total no of atoms in 18.04 g of Dexedrine (c) volume of 4.50 mol of Dexedrine [0.466 mole] [18.5 x 1023] [640.15 ml]

(d) weight of Dexedrine that contains exactly the same no. of H atoms as there are in 171.1 g of water CHARGE ON IONS: 21. Calculate the total charge in coulomb on the following: (a) 20 ions of Al3+ (c) 10 mmoles of CO32 22. Find the charge in coulomb on 1 g ion of N3 MINIMUM MOLECULAR WEIGHT: 23. Insulin contains 3.4% S, find its minimum molecular weight [941.17 gm] (b) 18 kg of NH4+ (d) 30 gm ions of Ca+2 [2.894 x 105 coulomb]

24. A drug is stable in a dimer form only. Percentage of nitrogen in one molecule of drug is 7.2%. Calculate the minimum molecular weight of that drug. GM ATOM, GM MOLECULE, GM IONS: 25. How many grams are contained in 1 g atom of Na (a) 13 g (b) 23 g (c) 1 g (d) 1/23 g [b]

26. 3 mole of ammonia contains (a) 18 gm hydrogen (b) 42 gm nitrogen (c) both (d) none [b]

27. Total no. of atoms present in a box containing 7 gm atoms of C12H22O11 and 3 moles of NH3 would be (a) 327 N0 (b) 315 N0 (c)317 N0 (d)327 x 1024 (e) none

28. Calculate the total no. of atoms in the following (a) 28.0 gm mole of P4 (c) A mixture of 10 gm moles of glucose and 20 mole of sucrose PERCENT BY WEIGHT, MOL FRACTION: 29. A mixture contains 30% NaCl and rest KCl. What would be the wt. of KCl in 70 gm of mixture? [49 gm] (b) 8 gm atom of nitrogen (d) 10 gm ion of SO32

30. A mixture contains 30% NaCl by mole and rest KCl. what would be the wt. of KCl in 70 gm of mixture 31. A, B, & C are mixed in the molar ratio of 1:2:3, find the mole fraction of A, B, C. [1/6,2/6,3/6]

32. Equal moles of water and urea are taken in a flask. What is mass percentage of urea in the solution? [23.077]

CARAT:

33. Calculate the no. of gold particles in 20 carat ring whose weight is 400mg.(atomic weight of Au=197)
MISCELLANEOUS PROBLEMS: 34. Calculate the following: (a) number of atoms in 2.3 kg
23 11 Na

(Na = 23)

(b) number of atoms in 32 kg Br2 (Br = 80) (c) number of molecules in 51 g of NH3 (N=14, H=1) (d) number of formula units in 159 g PbCrO4 (Pb=206,Cr=52) (e) number of SO42 ions in 14.3 g Cr2(SO4)3 (O=16, S=32) [6.021025 Na atoms, 2.4081023 Br atoms, 3No molecules, 0.494 No, 6.5581022 SO24 ions]

35. Write the weight of following in gm (a) weight of 4NA O atoms (c) weight of 7 gm ions of [Fe(CN)6]
4

(b) weight of 5 mole of sucrose (d) weight of 3.0112 x 1023 ions of [Cu(NH3)4]2+

(e) 1 x 1022 molecules of CuSO4.5H2O 36. Calculate the total no. of e,p & n, in the following (a) 18 gm water +14 gm atoms of nitrogen (c) 1.5056 x 1021 ions of [Cu(NH3)4]2+ (b) 18 gm NH4+ (d) 19 gm of H3O+

37. Calculate the atomic mass of silver if its one million atoms weight 1.79 x 1016 gm 38. Calculate the ratio of no. of oxygen atoms present in 3.2 mg of SO2 to the no. of S atoms present in 5 millimoles of Na2S2O3.5H2O 39. How much Mg is present in Mg (NO3)2 that contains 20gm of nitrogen

40. We are given an alloy of Cu & Zn, weighing 7.65 gm % by weight of Cu is 85% calculate (a) weight of Zn (b) mole fraction of Zn
millimoles of sodium nitrate and No/6 molecules of NO2. 42. Calculate the molecular weight of a compound that consists 40 carbon atoms, 30 hydrogen atoms, 7 nitrogen atoms 8 sulphur atoms, 12 oxygen atoms and 7 x 1021 gm of other atoms.

(c) gm atoms of Cu

(d) total no. of gm atoms

41. Calculate the total no. of oxygen and nitrogen atoms present in a mixture containing 8.2 gm of calcium 10

43. How many year it would take to spend Avogadro number of rupees at the rate of 10 Lacs rupees per second? [1.9099 x1010 year] 44. One atom of an element X weighs 6.644 x 1023 g. Calculate the number of gram atoms in 40 kg of it. (1000) 45. A metal M of atomic weight 54.94, has a density of 7.42g/cc. Calculate the apparent volume occupied by one atom of the metal. [1.23 x1023cc]

46. Three atoms of magnesium combine with 2 atoms of nitrogen. What will be the weight of magnesium which combines with 1.86g of nitrogen? 47. The nucleus of one atom X is supposed to be a sphere with a radius 5 x10 atomic nucleus if the atomic weight of X is 19.
13

[4.86 g] . Find the density of the matter in the [6.02x1013g/ml]

48. Copper forms two oxides. For the same amount of copper, twice as much oxygen was used to form the first oxide than to form the second one. What is the ratio of the valencies of copper in the first and the second oxides?(2:1) 49. How many litres of pure liquid CCl4 (d=1.5 gm/cc) must be measured out to contain 1x1025 CCl4 molecules? [1.61 lt.]

50. A dot at the end of this sentence has a mass of about 1microgram.Assuming that the black stuff is carbon, calculate the approximate number of atoms of carbon needed to make such a dot. [5 x1016] [4.91x1021]

51. How many iron atoms are present in a stainless steel ballbearing having a radius 0.1 inch? The stainless steel contains 85.6% Fe by weight and has a density of 7.75g/cc.

52. A sample of potato starch was ground in a ball mill to give a starch like molecule of lower molecular weight. The product analyzed 0.086% phosphorus. If each molecule is assumed to contain one atom of phosphorus, what is the molecular weight of material? 53. Ratio of carbon to hydrogen atom is maximum in : (a) 16 g CH4 54. Ratio of n:p in NH4 is: (a) 7/11 (e)none 55. Which of the following has the highest mass: (a) 12g of C atom (b)13 g H atom (c)9000 mmoles of NH3 (d)80 g moles of H2SO4 (b) 7/10 (c)1 (d)11/10
+

[3.6x104amu]

(b) 31.2 g C6H4

(c) 34.2 g C12H22O11

(d) 36 g C6H12O6

56.Weight ratio of Fe:C in Fe2(Fe(CN)6) is: (a) 3/7 (e)None 57. How many moles of e are there in 1kg bunch of electrons. (b) 7/5 (c) 7/3 (d) 5/7