Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 24.

1 Multiple-Choice and Bimodal Questions 1) The coordination num ers of co a!t(""") and of chromium(""") in their comp!e#es are a!ways $$$$$$$$$$% &) 4 B) ' C) 2 () ) *) + &nswer: * Diff: 1 Page Ref: Sec. 24.1 2) The coordination num er of p!atinum in comp!e#es is a!ways $$$$$$$$$$% &) 4 B) ' C) 2 () ) *) + &nswer: & Diff: 1 Page Ref: Sec. 24.1 )) (urin, the formation of a coordination compound, the meta! acts as a $$$$$$$$$$% &) Lewis acid B) Brnsted acid C) &rrhenius acid () Brnsted ase *) Lewis ase &nswer: & Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 4) (urin, the formation of a coordination compound, !i,ands act as $$$$$$$$$$% &) Lewis ases B) &rrhenius ases C) Brnsted acid () Lewis acids *) &rrhenius acids &nswer: & Diff: 1 Page Ref: Sec. 24.1 ') The coordination sphere of a comp!e# consists of $$$$$$$$$$% &) the centra! meta! ion on!y B) the !i,ands C) the centra! meta! ion and the !i,ands onded to it () the primary and secondary -a!encies *) coordination and steric num ers &nswer: C Diff: 1 Page Ref: Sec. 24.1 +) "n the fo!!owin, reaction, .i 2+ is actin, as a(n) $$$$$$$$$$% .i 2+ (,) + + / 2 0(!) .i(/ 2 0)+ 2+ (a1) &) o#idi2in, a,ent B) Lewis acid C) precipitatin, a,ent () so!-ent *) !i,and &nswer: B Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 3) /ow many d e!ectrons are in the co a!t ion of 4 ) [ Co(C.)+ ] 5 &) ) B) ' C) + () 3 *) 4 &nswer: C Diff: 1 Page Ref: Sec. 24.1 6) 7hat is the char,e on the comp!e# ion in M, 2 [ 8eC!+ ] 5 &) 29 B) 2: C) )9 () ): *) 49 &nswer: * Diff: 1 Page Ref: Sec. 24.1 ;) 7hat is the o#idation num er of chromium in [ Cr(./ ) ) 4 C! 2 ] C! 5 &) 9) B) :) C) :2 () 92 *) < &nswer: B Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 1<) 7hat is the !i,and in Ca ) [ 8e(C.)+ ] 2 5 &) Ca 2+ B) 8e)+ C) C. ) () 8e(C.)+ *) 8e 2+ &nswer: C Diff: 1 Page Ref: Sec. 24.1 11) 7hat is the char,e of the centra! meta! ion in Ca ) [ 8e(C.)+ ] 2 5 &) < B) 1: C) 2: () ): *) +: &nswer: ( Diff: 1 Page Ref: Sec. 24.1 12) 7hat is the o#idation num er of co a!t in [ Co(./ ) ) 4 82 ] 5 &) 9) B) :2 C) :1 () :) *) :+ &nswer: B Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 1)) The char,e of the comp!e# ion in [ =n(/ 2 0))C!] C! is $$$$$$$$$$% &) < B) 19 C) 2: () 1: *) 29 &nswer: ( Diff: 1 Page Ref: Sec. 24.1 14) The coordination num er for [ =n(/ 2 0))C!] C! is $$$$$$$$$$% &) ' B) 4 C) 2 () 1 *) + &nswer: B Diff: 2 Page Ref: Sec. 24.1 1') 7hat is the o#idation state of iron in Ca.a [ 8e(C.) + ] 5 &) < B) :2 C) :) () :4 *) :+ &nswer: C Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 1+) 7hat is the coordination num er of iron in Ca.a [ 8e(C.) + ] 5 &) 2 B) 6 C) 4 () + *) 12 &nswer: ( Diff: 1 Page Ref: Sec. 24.1 13) 7hat is the coordination num er of co a!t in [ Co(./ ) )' C!] (.0) ) 2 5 &) 12 B) 6 C) 4 () 2 *) + &nswer: * Diff: 1 Page Ref: Sec. 24.1 16) 7hat is the o#idation state of chromium in [ Cr(/ 2 0) 4 C! 2 ] 5
+

&) < B) :2 C) :) () 92 *) 9) &nswer: C Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 1;) 7hat is the coordination num er of chromium in [ Cr(/ 2 0) 4 C! 2 ] 5
+

&) 6 B) + C) 4 () 2 *) 12 &nswer: B Diff: 1 Page Ref: Sec. 24.1 2<) The >dentation> of a !i,and is defined y $$$$$$$$$$% &) how many >dents> or >deceptions> there are in the coordination sphere of a comp!e# species it forms B) how many e!ectron donor atoms it uti!i2es to form coordinate onds to the centra! meta! ion C) the tota! num er of !one pairs of e!ectrons it possesses () how many meta! ions it can se1uester from so!ution *) none of the a o-e &nswer: B Diff: 1 Page Ref: Sec. 24.2 21) *(T& is $$$$$$$$$$9dantate !i,and% &) mono B) i C) tri () tetra *) he#a &nswer: * Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 22) 7hat is the meta! ion in the porphyrin of heme5 &) iron B) ca!cium C) mo!y denum () ma,nesium *) ch!orophy!! &nswer: & Diff: 1 Page Ref: Sec. 24.2 2)) /ow many iron atoms are coordinated in a hemo,!o in mo!ecu!e5 &) 1 B) 2 C) ) () 4 *) ' &nswer: ( Diff: 1 Page Ref: Sec. 24.2 24) The correct name for [ .i(./ ) )+ ] (.0) )) is $$$$$$$$$$% &) dinitrohe#aamminenic?e! ("") B) he#aamminenic?e! (""") trinitrate C) dinitrohe#aamminenic?e!ate (""") () he#aamminenic?e! ("") nitrate *) he#aamminenic?e! (""") nitrate &nswer: * Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2') The names of comp!e# anions end in $$$$$$$$$$% &) 9o B) 9ium C) 9ate () 9ous *) 9ic &nswer: C Diff: 1 Page Ref: Sec. 24.3 2+) The correct name for .a ) [ Co8+ ] is $$$$$$$$$$% &) trisodium he#a?isf!uoroco a!t(""") B) trisodium he#a?isf!uoroco a!t("") C) trisodium he#a?isf!uoroco a!t("@) () sodium he#af!uoroco a!tate(""") *) sodium he#af!uoroco a!tate("@) &nswer: ( Diff: 1 Page Ref: Sec. 24.3 23) Tripheny!phosphine is often ,i-en the a re-iated formu!a AAh ) % The correct name for Bh(AAh ) ))C! is $$$$$$$$$$% &) ch!orotripheny!phosphinerhodium B) ch!orotripheny!phosphinerhodium(") C) tris(tripheny!phosphine)ch!ororhodium(") () ch!orotris(tripheny!phosphine)rhodium(") *) ch!orotris(tripheny!phosphine)rhodate(9") &nswer: ( Diff: 1 Page Ref: Sec. 24.3

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 26) "n $$$$$$$$$$, the onds are the same ut the spatia! arran,ement of the atoms is different% &) structura! isomers B) !in?a,e isomers C) coordination9sphere isomers () stereoisomers *) resonance structures &nswer: ( Diff: 1 Page Ref: Sec. 24.4 2;) & ,eometrica! isomer with !i?e ,roups !ocated on opposite sides of the meta! atom is denoted with the prefi# $$$$$$$$$$% &) cis9 B) trans9 C) is9 () tetra?is *) d9 &nswer: B Diff: 1 Page Ref: Sec. 24.4 )<) The comp!e# [ =n(./ ) ) 2 C! 2 ] does not e#hi it cis9trans isomerism% The ,eometry of this comp!e# must e $$$$$$$$$$%
2+

&) tetrahedra! B) tri,ona! ipyramida! C) octahedra! () s1uare p!anar *) either tetrahedra! or s1uare p!anar &nswer: & Diff: 1 Page Ref: Sec. 24.4

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )1) /ow many isomers e#ist for the octahedra! comp!e# ion [ Co(./ ) ) 4 82 ] 5
+

&) 1 B) 2 C) ) () 4 *) ' &nswer: B Diff: 1 Page Ref: Sec. 24.4 )2) Trans [ 8e(/ 2 0) 2 C!4 ] &) tetrahedra! B) octahedra! C) s1uare p!anar () tri,ona! ipyramida! *) !inear &nswer: B Diff: 1 Page Ref: Sec. 24.4 ))) Lin?a,e isomerism can on!y occur $$$$$$$$$$% &) in cis9isomers of octahedra! comp!e#es B) with co a!t comp!e#es C) with coordination num er + () with tetrahedra! comp!e#es *) with !i,ands that ha-e more than one possi !e donor atom &nswer: * Diff: 1 Page Ref: Sec. 24.4
2

must e $$$$$$$$$$%

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )4) Meta!s with $$$$$$$$$$ e!ectron confi,urations characteristica!!y form diama,netic, s1uare p!anar comp!e#es% &) d < B) d ; C) d + () d 6 *) d1< &nswer: ( Diff: 1 Page Ref: Sec. 24.6 )') 7hat transition meta! is responsi !e for the co!or of ru y5 &) man,anese B) co a!t C) titanium () ,o!d *) chromium &nswer: * Diff: 1 Page Ref: Sec. 24.6 24.2 Multiple-Choice Questions 1) 8ormation of a comp!e# species of M n + meta! ion with !i,ands often $$$$$$$$$$% &) >mas?s> ori,ina! chemica! properties of oth the M n + ion and the !i,ands B) reduces a-ai!a i!ity of the free M n + ions in so!ution C) may cause chan,es in the ease with which M n + is reduced or o#idi2ed () a!ters ori,ina! physica! properties of M n + *) a!! of the a o-e &nswer: * Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2) 7hat is the most common ,eometry found in four9coordinate comp!e#es5 &) s1uare p!anar B) octahedra! C) tetrahedra! () icosahedra! *) tri,ona! ipyramida! &nswer: C Diff: 1 Page Ref: Sec. 24.1 )) The minimum num er of unshared -a!ence e!ectron pairs in the !i,ands of a coordination compound is $$$$$$$$$$% &) 1 B) 2 C) ) () 4 *) ' &nswer: & Diff: 1 Page Ref: Sec. 24.1 4) The coordination num er of co a!t in CoC!) g './ ) is $$$$$$$$$$% &) 2 B) ) C) 4 () + *) 6 &nswer: ( Diff: 2 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds

) ') 7hat is the o#idation num er of .i in C.i(C.)' D 5

&) 1: B) 2: C) ): () 4: *) ': &nswer: B Diff: 1 Page Ref: Sec. 24.1 +) Chan,es in the coordination sphere of a comp!e# compound may !ead to chan,es in $$$$$$$$$$% &) co!or B) physica! properties C) chemica! properties () sta i!ity *) a!! of the a o-e &nswer: * Diff: 1 Page Ref: Sec. 24.1 3) "n the compound, Ca.a [ 8e(C.) + ] , what !i,ands are in the coordination sphere5 &) Ca 2+ B) .a + C) C. () / 2 0 *) none of the a o-e &nswer: C Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 6) 7hat are the respecti-e centra!9meta! o#idation state, coordination num er, and o-era!! char,e on the comp!e# ion in .a 2 [ Cr(./ ) ) 2 (.CE) 4 ] 5 &) :)F +F 91 B) :)F +F :1 C) :2F +F 92 () :2F 4F 91 *) :1F +F 92 &nswer: C Diff: 2 Page Ref: Sec. 24.1 ;) 7hich one of the fo!!owin, species is parama,netic5 &) Cu + B) Cr )+ C) =n () Ca *) &, +

&nswer: B Diff: 1 Page Ref: Sec. 24.1 1<) 7hich of the fo!!owin, comp!e#es has a coordination num er of +5 &) [ Co(en) 2 C!2 ] C) [ Cu(./ ) ) 4 ]
+

B) [ At(./ ) ) 2C! 2 ]
2+ +

() [ &,(./) ) 2 ] *) .one of these comp!e#es has coordination num er +% &nswer: & Diff: 2 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 11) /ow many !i,ands are there in the coordination sphere of [ Co(en) 2 C!2 ] 5
+

&) ) B) + C) 4 () 1 *) < &nswer: C Diff: 1 Page Ref: Sec. 24.1 12) 7hat is the char,e on the comp!e# ion in Ca 2 [ 8e(C.)+ ] 5 &) )9 B) 2: C) 29 () 19 *) 49 &nswer: * Diff: 3 Page Ref: Sec. 24.1 1)) & !i,and with a sin,!e donor atom is ca!!ed $$$$$$$$$$% &) a che!on B) a che!ate C) po!ydentate () monodentate *) identate &nswer: ( Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 14) 7hich of the fo!!owin, is not a che!atin, a,ent5 &) ch!oride anion B) *(T& C) porphine () ethy!enediamine *) o#a!ate anion &nswer: & Diff: 1 Page Ref: Sec. 24.2 1') 7hat is the purpose of addin, *(T& to prepared foods5 &) to ?eep ions such as Ca 2+ in so!ution so the foods !oo? ,ood B) to comp!e# trace meta! ions that cata!y2e decomposition reactions C) to comp!e# iron(""") ions so they can cata!y2e protein decomposition on coo?in, () to aid in rownin, of the surface durin, coo?in, *) to pre-ent disso!ution of the container in the food when stored for !on, periods of time &nswer: B Diff: 1 Page Ref: Sec. 24.2 1+) "n humans, what percent of a sor ed iron is found in !ood5 &) 1' B) 2' C) 4< () +< *) 3' &nswer: * Diff: 2 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 13) The coordination num er and o#idation num er of the centra! atom in CMn(C0) 4 Br2 D are $$$$$$$$$ and $$$$$$$$$, respecti-e!y% &) 4, :1 B) +, :1 C) ', :2 () 4, :2 *) +, :2 &nswer: * Diff: 2 Page Ref: Sec. 24.2 16) 7hat purpose wou!d sodium tripo!yphosphate ser-e in a deter,ent formu!ation5 &) to aid in remo-a! of rust stains from surfaces and from c!othes B) to aid in ?eepin, the inside of washin, machines c!ean and free from corrosion C) to impro-e the f!ow characteristics of the deter,ent in the o# () to comp!e# and hence se1uester meta! ions in hard water *) to reduce acteria! ,rowth in the deter,ent upon stora,e &nswer: ( Diff: 1 Page Ref: Sec. 24.2 1;) 7hat are the donor atoms in a porphine mo!ecu!e5 &) . B) 0 C) E () Br *) 8 &nswer: & Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2<) 7hat meta! is comp!e#ed in ch!orophy!!5 &) iron B) chromium C) man,anese () -anadium *) ma,nesium &nswer: * Diff: 1 Page Ref: Sec. 24.2 21) 7hat form of hemo,!o in is purp!ish9red5 &) myo,!o in B) deo#yhemo,!o in C) heme () o#yhemo,!o in *) none of the a o-e &nswer: B Diff: 1 Page Ref: Sec. 24.2 22) /ow many onds can ethy!enediamine form to a meta! ion5 &) 1 B) 2 C) ) () 4 *) + &nswer: B Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2) Based on entropy considerations a!one, which homo,eneous a1ueous e1ui!i rium wou!d e e#pected to !ie to the ri,ht5 &) &," 2 +2Br &,Br 2 +2" 2+ 2+ B) .i(/ 2 .C 2 / 4 ./ 2 )) + +./) .i(./ ) )+ + )/ 2 .C 2 / 4 ./ 2
2+ 2: C) CoC! 4 + +/ 2 0 Co(/ 2 0) + + 4C! 2+ 2 () 8e(./ ) )+ + C 2< / 1< . 4 8e(./ ) ) 2 (C 2< / 1< . 4 ) + 4./ )

*) Cu(./ ) ) 4

2+

: +/ 2 0 Cu(/ 2 0) + 2+ + 4./ )

&nswer: ( Diff: 4 Page Ref: Sec. 24.2 24) The che!ate effect is est attri uted to considerations of which type5 &) hydration B) entha!py C) entropy () hydro,en ondin, *) resonance &nswer: C Diff: 1 Page Ref: Sec. 24.2 2') 7hich one of the fo!!owin, species is a potentia! po!ydentate !i,and (che!atin, a,ent)5 &) B) C) () ./ ) C! C. / 20

2 *) C 2 0 4

&nswer: * Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2+) 7hat are the donor atoms in ferrichrome and how many of them are in one mo!ecu!e5 &) Cr, ' B) ., 4 C) 0, + () 8e, 4 *) E, + &nswer: C Diff: 1 Page Ref: Sec. 24.2 23) 7hich of the fo!!owin, is a po!ydentate !i,and5 &) ammonia B) o#a!ate ion C) ch!oride ion () water *) hydro#ide ion &nswer: B Diff: 1 Page Ref: Sec. 24.2 26) & comp!e# of correct!y written formu!a CAt(./ ) ) ) BrDBr g/ 2 0 has which set of !i,ands in its inner coordination sphere5 &) ) ./ ) B) ) ./ ) and 2 Br 9 C) ) ./ ) and 1 Br 9 () ) ./ , 1 Br 9 , and 1 / 2 0
)

*) ) ./ ) , 2 Br 9 , and 1 / 2 0 &nswer: C Diff: 1 Page Ref: Sec. 24.3

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2;) 7hich one of the fo!!owin, is the correct formu!a for potassium dia1uatetrach!oromo!y date (""")5 &) 4 2 CMo(/ 2 0) 2 C! 4 D B) 4CMo(/ 2 0) 2 C! 2 DC! 2 C) 4CMo(/ 2 0) 2 C! 4 D () MoC4(/ 2 0) 2 DC! 4 *) 4 )CMo(/ 2 0) 2 C! 4 D &nswer: C Diff: 1 Page Ref: Sec. 24.3 )<) (oes either or oth cis9 or trans9 CMn(en) 2 Br 2 D ha-e optica! isomers5 &) cis on!y B) trans on!y C) oth cis and trans () neither cis nor trans *) CMn(en) 2 Br 2 D does not e#hi it cis9trans isomerism% &nswer: & Diff: 1 Page Ref: Sec. 24.4 )1) Lin?a,e isomerism wou!d most !i?e!y occur when which of the fo!!owin, !i,ands is present5 &) B) C) () *) / 20 ./ ) C! A8 ) .CE

&nswer: * Diff: 1 Page Ref: Sec. 24.4

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )2) "somers whose !i,ands can ind direct!y to a meta! or e outside the !attice are ca!!ed $$$$$$$$$% &) !in?a,e isomers B) rotationa! isomers C) coordination sphere isomers () ,eometric isomers *) optica! isomers &nswer: C Diff: 1 Page Ref: Sec. 24.4 ))) 7hich of the fo!!owin, wi!! disp!ay optica! isomerism5 &) s1uare9p!anar CBh(C0) 2 C! 2 D9
2+ B) s1uare9p!anar CAt(/ 2 .C 2 / 4 ./ 2 ) 2 D )+ C) octahedra! CCo(./ ) ) + D 2+ () octahedra! CCo(./ ) )' C!D )+ *) octahedra! CCo(/ 2 .C 2 / 4 ./ 2 ) ) D

&nswer: * Diff: 2 Page Ref: Sec. 24.4 )4) 7hich one of the fo!!owin, comp!e#es wou!d most !i?e!y ha-e tetrahedra! ,eometry5
2 &) C.iC! 4 D 2+ B) CCo(/ 2 0) + D )+ C) CCr(./ ) ) + D ) () C8e(C.) + D *) CAt(./ ) ) 2 C! 2 D

&nswer: & Diff: 1 Page Ref: Sec. 24.4

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )') 7hich one of the fo!!owin, comp!e#es can e#hi it ,eometrica! isomerism5 &) CAt(./ ) ) 2 C! 2 D (s1uare p!anar) B) C=n(./ ) ) 2 C! 2 D (tetrahedra!) 2+ C) CCu(./ ) ) 4 D (s1uare p!anar)
2+ () CCu(./ ) ) ' C!D (octahedra!) *) &!! of the a o-e can e#hi it ,eometrica! isomerism%

&nswer: & Diff: 1 Page Ref: Sec. 24.4 )+) Coordination sphere isomers &) ha-e the same mo!ecu!ar formu!a and coordination num er% B) ha-e the same mo!ecu!ar formu!a ut different coordination num ers% C) ha-e different mo!ecu!ar formu!as ut the same coordination num er% () ha-e different mo!ecu!ar formu!as and different coordination num ers% *) are the same as resonance structures% &nswer: & Diff: 2 Page Ref: Sec. 24.4 )3) & racemic mi#ture is &) an e1ua! mi#ture of oth enantiomers of an optica!!y acti-e species% B) a mi#ture of an optica!!y acti-e species with an optica!!y inacti-e species% C) an e1ua! mi#ture of cis9 and trans9isomers% () a mi#ture of meta! ions and !i,ands in e1ui!i rium% *) a mi#ture of structura! isomers% &nswer: & Diff: 1 Page Ref: Sec. 24.4

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )6) Based on e!ectron confi,uration, which is most !i?e!y co!or!ess5
2+ &) CCu(./ ) ) 4 D 2+ B) CCd(./ ) ) 4 D 2+ C) C.i(./ ) ) + D 2+ () CCr(./ ) ) ' C!D 2+ *) CCo(./ ) ) + C!D

&nswer: B Diff: 3 Page Ref: Sec. 24.5 );) & comp!e# that a sor s !i,ht at 3<< nm wi!! appear $$$$$$$$$$% &) red B) ,reen C) ye!!ow () oran,e *) -io!et &nswer: B Diff: 3 Page Ref: Sec. 24.5 4<) & meta! comp!e# a sor s !i,ht main!y at 42< nm% 7hat is the co!or of the comp!e#5 &) ,reen B) ye!!ow C) red () oran,e *) purp!e &nswer: B Diff: 3 Page Ref: Sec. 24.5

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 41) 7hich one of the fo!!owin, su stances has three unpaired d e!ectrons5
2+ &) C=n(./ ) ) 4 D 4+ B) C@(/ 2 0) + D + C) C&,(./ ) ) 2 D 2+ () CCu(./ ) ) 4 D ) *) CCr(C.) + D

&nswer: * Diff: 2 Page Ref: Sec. 24.5, 24.6 42) 7hich one of the fo!!owin, comp!e# ions wi!! e parama,netic5
2+ &) C8e(/ 2 0) + D (!ow spin) )+ B) C8e(/ 2 0) + D (!ow spin) )+ C) CCo(/ 2 0) + D (!ow spin) 2+ () C=n(/ 2 0) 4 D 2+ *) C=n(./ ) ) 4 D

&nswer: B Diff: 2 Page Ref: Sec. 24.5, 24.6 4)) Comp!e#es containin, meta!s with d < e!ectron confi,urations are typica!!y co!or!ess ecause &) there is no d e!ectron that can e promoted -ia the a sorption of -isi !e !i,ht% B) the empty d or ita!s a sor a!! of the -isi !e wa-e!en,ths% C) there are no d e!ectrons to form onds to !i,ands% () a comp!e# must e char,ed to e co!ored% *) d e!ectrons must e emitted y the comp!e# in order for it to appear co!ored% &nswer: & Diff: 1 Page Ref: Sec. 24.6

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 44) Comp!e#es containin, meta!s with d1< e!ectron confi,urations are typica!!y $$$$$$$$$$% &) -io!et B) !ue C) ,reen () ye!!ow *) co!or!ess &nswer: * Diff: 1 Page Ref: Sec. 24.6 4') Comp!e#es containin, meta!s with which one of the fo!!owin, e!ectron confi,urations are usua!!y co!or!ess5 &) d 2 B) d1 C) d ' () d 6 *) d1< &nswer: * Diff: 1 Page Ref: Sec. 24.6 4+) 7hich one of the fo!!owin, is a stron,9fie!d !i,and5 &) C! B) ./ ) C) / 2 0 () 8 *) C. &nswer: * Diff: 1 Page Ref: Sec. 24.6

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 43) Consider a comp!e# in which man,anese (""") is onded to si# identica! !i,ands% 7hich one of the fo!!owin, !i,ands wi!! resu!t in the sma!!est -a!ue of G5 &) C! B) ./ ) C) / 2 0 () 8 *) C. &nswer: & Diff: 1 Page Ref: Sec. 24.6 46) Based on the crysta!9fie!d stren,ths 89 < C/ 2 C. < ./ ) < .0 29 < C. 9 which Co(""") comp!e# is most !i?e!y hi,h9spin5
)+ &) CCo(./ ) ) + D ) B) CCo(.0 2 ) + D ) C) CCo(C.) + D ) () CCo8 + D )+ *) CCo(C/ ) C.) + D

&nswer: ( Diff: 1 Page Ref: Sec. 24.6 4;) The attraction of a meta! to a neutra! !i,and is due to $$$$$$$$$$ ondin,% &) ionic B) co-a!ent C) ion9dipo!e () dipo!e9dipo!e *) hydropho ic &nswer: C Diff: 2 Page Ref: Sec. 24.6

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds '<) 7hich of the fo!!owin, statements is (are) fa!se5 &) The ,reater the ener,y ,ap in a meta! comp!e#, the shorter the wa-e!en,th of !i,ht the comp!e# wi!! a sor % B) Comp!e# co!or depends on oth the meta! and the !i,and% C) Meta! comp!e#es with an ammonia !i,and ha-e a !ar,er ener,y ,ap than the correspondin, f!uoride comp!e#es% () Etron, fie!d !i,ands are associated with !ow ener,y ,aps% *) Both & and C &nswer: ( Diff: 3 Page Ref: Sec. 24.6
'1) Based on the crysta!9fie!d stren,ths C! < 8 < / 2 0 < ./ ) < / 2 .C 2 / 4 ./ 2 , which octahedra! Ti(""") comp!e# e!ow has its d9d e!ectronic transition at shortest wa-e!en,th5 )+ &) CTi(./ ) ) + D )+ B) CTi(/ 2 .C 2 / 4 ./ 2 ) ) D )+ C) CTi(/ 2 0) + D ) () CTiC! + D ) *) CTi8 + D

&nswer: B Diff: 1 Page Ref: Sec. 24.6

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds '2) 7hich one of the fo!!owin, ions cannot form oth a hi,h spin and a !ow spin octahedra! comp!e# ion5 &) 8e)+ B) Co 2+ C) Cr )+ () Mn )+ *) Cr 2+ &nswer: C Diff: 2 Page Ref: Sec. 24.6 ')) Hsin, the fo!!owin, a re-iated spectrochemica! series, determine which comp!e# ion is most !i?e!y to a sor !i,ht in the red re,ion of the -isi !e spectrum%
sma!! sp!ittin, C! < / 2 0 < ./ ) < C. !ar,e sp!ittin, 2 &) CCuC! 4 D 2+ B) CCu(/ 2 0) 4 D 2+ C) CCu(./ ) ) 4 D 2 () CCu(C.) 4 D *) not enou,h information ,i-en to determine

&nswer: & Diff: 1 Page Ref: Sec. 24.6 '4) 7hich of the fo!!owin, cannot form oth hi,h9 and !ow9spin octahedra! comp!e#es5 &) Mn 2+ B) @ 2+ C) Co)+ () Cr 2+ *) &!! of the a o-e can form oth hi,h9 and !ow9spin comp!e#es% &nswer: B Diff: 2 Page Ref: Sec. 24.6

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds

'') 7hich of the fo!!owin, can form oth hi,h9 and !ow9spin octahedra! comp!e#es5 &) Cr 2+ B) Cr )+ C) =n 2+ () Cu + *) &!! of the a o-e can form either hi,h9 or !ow9spin comp!e#es% &nswer: & Diff: 1 Page Ref: Sec. 24.6 )+ '+) /ow many d e!ectrons are associated with the meta! ion in CCr(./ ) ) + D 5 &) 1 B) 2 C) ) () 4 *) ' &nswer: C Diff: 3 Page Ref: Sec. 24.6 24.3 Short Answer Questions 1) 7hat is the o#idation state of the iron atom in Ca.aC8e(C.) + D 5 &nswer: :) Diff: 2 Page Ref: Sec. 24.1 2) The most common coordination num ers are $$$$$$$$$$% &nswer: 4 and + Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )) 7hat is the coordination num er of the iron atom in Ca.aC8e(C.) + D 5 &nswer: + Diff: 1 Page Ref: Sec. 24.1 4) Ei#9coordinate comp!e#es ,enera!!y ha-e $$$$$$$$$$ ,eometry% &nswer: octahedra! Diff: 1 Page Ref: Sec. 24.1 ') The num er of >free> ch!oride ions in an ionic coordination compound can e determined y treatin, the compound with $$$$$$$$$$% &nswer: &,.0) Diff: 1 Page Ref: Sec. 24.1 +) The secondary -a!ence in meta! ion comp!e#es is ca!!ed the $$$$$$$$$% &nswer: coordination num er Diff: 1 Page Ref: Sec. 24.1 3) 7ernerIs theory of primary and secondary -a!ences for transition meta! comp!e#es has ,i-en us the concepts of $$$$$$$$$$ and $$$$$$$$$$% &nswer: o#idation state and coordination num er Diff: 1 Page Ref: Sec. 24.1

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 6) Transition meta! ions with empty -a!ence or ita!s act as $$$$$$$$$$% &nswer: Lewis acids Diff: 1 Page Ref: Sec. 24.1 ;) 7hat is the o#idation num er of the centra! meta! in CMo(/ 2 0) ' .0 ) DC! 2 &nswer: :) Diff: 1 Page Ref: Sec. 24.1 1<) (efine the che!ate effect% &nswer: Che!ate effect J an increased sta i!ity of comp!e# compounds formed with che!atin, (po!ydentate) !i,ands compared to those formed with monodentate !i,ands% Diff: 1 Page Ref: Sec. 24.2 11) The che!ate effect is enhanced y po!ydentate !i,and indin, ecause of the chan,e in $$$$$$$$$$% &nswer: entropy Diff: 2 Page Ref: Sec. 24.2 12) List three of the ten transition meta!s re1uired for human !ife% &nswer: &ny three of: Co, Cu, Cr, 8e, Mn, @, =n, .i, Mo, Cd Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 1)) Myo,!o in has $$$$$$$$$$ heme ,roup(s) that ind(s) $$$$$$$$$$% &nswer: 1F o#y,en Diff: 1 Page Ref: Sec. 24.2 14) "n photosynthesis, $$$$$$$$$$ mo!es of photons are re1uired to form one mo!e of $$$$$$$$$$% &nswer: 46F ,!ucose Diff: 2 Page Ref: Sec. 24.2 1') "n the !ea-es of p!ants, -isi !e !i,ht is a sor ed y a compound ?nown as $$$$$$$$$$, and is aided y a $$$$$$$$$$ ion onded to a porphyrin rin,% &nswer: ch!orophy!!F M, Diff: 2 Page Ref: Sec. 24.2 1+) 7hat is the mechanism used in humans to com at !ood acteria! ,rowth -ia depri-ation of iron5 &nswer: fe-er Diff: 2 Page Ref: Sec. 24.2 13) & !ar,e difference in formation constant (4f) of a po!y9 -ersus monodentate !i,and is ca!!ed $$$$$$$$$$% &nswer: che!ate effect Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 16) & compound that can occupy two coordination sites is a (an) $$$$$$$$$$% &nswer: identate !i,and Diff: 1 Page Ref: Sec. 24.2 1;) The porphyrin compound that contains M,("") is ca!!ed $$$$$$$$$$% &nswer: ch!orophy!! Diff: 1 Page Ref: Sec. 24.2 2<) The transport of iron into acteria is faci!itated y the formation of the comp!e# $$$$$$$$$$% &nswer: ferrichrome Diff: 1 Page Ref: Sec. 24.2 21) .ame the compound: 4 2 CCr(/ 2 0) 4 (C0) ) 2 D &nswer: potassium tetraa1uadicar onatochromate("") Diff: 3 Page Ref: Sec. 24.3 22) .ame .aCBu(/ 2 0) 2 (C 2 0 4 ) 2 D &nswer: sodium dia1uadio#a!atoruthenate (""") Diff: 1 Page Ref: Sec. 24.3

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 2)) Two compounds ha-e the same formu!a and contain an EC.9 !i,and% "n one compound the EC.9 !i,and is onded to the meta! atom -ia the . atom and in the other it is onded -ia the E atom% These two compounds are e#amp!es of $$$$$$$$$$ isomers% &nswer: !in?a,e Diff: 1 Page Ref: Sec. 24.4 24) .on superimposa !e isomers are $$$$$$$$$$ isomers% &nswer: optica!, chira!, enantiomeric Diff: 1 Page Ref: Sec. 24.4 2') /ow can hi,h9spin and !ow9spin transition meta! comp!e#es e distin,uished from each other5 &nswer: Ma,netic properties and a sorption spectra can e compared% Diff: 1 Page Ref: Sec. 24.6 24.4 True/ alse Questions 1) "f ch!oride is a !i,and to a transition meta! it wi!! not e precipitated y si!-er nitrate% &nswer: True Diff: 1 Page Ref: Sec. 24.1 2) The che!ate effect must a!ways occur with positi-e entha!py chan,e% &nswer: 8a!se Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds )) The co!or of hemo,!o in chan,es from purp!e to red when water disp!aces o#y,en on the mo!ecu!e% &nswer: 8a!se Diff: 1 Page Ref: Sec. 24.2 4) The heme unit of myo,!o in is ound to the protein -ia a nitro,en9containin, !i,and% &nswer: True Diff: 1 Page Ref: Sec. 24.4 ') &n en2yme must contain a meta! ion to e chira!% &nswer: 8a!se Diff: 1 Page Ref: Sec. 24.4 +) To separate racemic mi#tures the isomers must e in a chira! en-ironment% &nswer: True Diff: 1 Page Ref: Sec. 24.4 3) Kreen and oran,e are comp!ementary co!ors% &nswer: 8a!se Diff: 1 Page Ref: Sec. 24.5 6) Transition meta! comp!e#es, whose meta! ions ha-e some num er of unpaired e!ectrons, are parama,netic &nswer: True Diff: 1 Page Ref: Sec. 24.5

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds ;) The ener,y of a meta! !i,and comp!e# is hi,her than the ener,y of the separated components% &nswer: 8a!se Diff: 1 Page Ref: Sec. 24.6 1<) Transition meta! comp!e#es are co!ored ecause of the ener,y ,ap etween the d or ita!s% &nswer: True Diff: 1 Page Ref: Sec. 24.6 24.! "ssa# Questions. 1) 7hat is the purpose of addin, sodium tripo!yphosphate to a deter,ent5 &nswer: to se1uester the meta! ions in hard water to pre-ent their interference with the action of the deter,ent Diff: 1 Page Ref: Sec. 24.2 2) 7hat co!ors of !i,ht does ch!orophy!!9a a sor 5 &nswer: red and !ue Diff: 1 Page Ref: Sec. 24.2 )) /ow does an e!e-ated ody temperature depri-e some acteria in the ody of iron5 &nswer: in some acteria, siderophore production decreases as temperature increases Diff: 1 Page Ref: Sec. 24.2

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds 4) 7hat is a siderophore5 &nswer: a !i,and that forms an e#treme!y sta !e water9so!u !e comp!e#, such as ferrichrome, with iron Diff: 1 Page Ref: Sec. 24.2 ') 7hat is meant y the prefi# tetra?is9, and when is it used5 &nswer: "t means 4 and is used when there are 4 of a !i,and whose name inc!udes a Kree? prefi#% Diff: 1 Page Ref: Sec. 24.3 +) .ame the compound, CaC&!/ 4 D 2 &nswer: ca!cium tetrahydroa!uminate Diff: 1 Page Ref: Sec. 24.3 3) .ame the compound, C0s(en) ) D 2C.iC! 2 Br 2 D ) &nswer: tris(ethy!enediamine)osmium(""") di romodich!oronic?e!ate("") Diff: 2 Page Ref: Sec. 24.3
2+ 6) .ame the compound, Cu(/ 2 0) 4 %

&nswer: tetraa1uacopper("") Diff: 1 Page Ref: Sec. 24.3

Chemistry, 11e (Brown/LeMay/Brusten/Murphy) Chapter 24: Chemistry of Coordination Compounds ;) "n what two ways can an o Lect appear !ue5 &nswer: a sor a!! wa-e!en,ths e#cept !ue and ref!ect or transmit on!y !ue, or a sor the comp!ementary co!or of !ue and ref!ect or transmit a!! others Diff: 1 Page Ref: Sec. 24.5