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POAC
Q20. Calculate the number of g of CO
2
which can be produced by burning 90.0 g of ethane, C
2
H
6
, in excess oxygen
(a) (b) (c) (d)
Q21. What mass of AgCl can be obtained from 100 g of [Ag(NH
3
)
2
]Cl be means of the reaction
( )
3 3 4 3
2
2 2 Ag NH Cl HNO AgCl NH NO ( + +
Q22. CaC
2
is made in an electric furnace by the reaction CaO +3C CaC
2
+CO. How much CaO is to be added to the furnace
charge for each 40 tons of CaC
2
produced ?
Q23. How much 83.4 %pure salt cake (Na
2
SO
4
) could be produced from 250 kg to 94.5 % pure salt in the reaction 2NaCl +H
2
SO
4
Na
2
SO
4
+2HCl ?
Q24. How many kg of H
2
SO
4
can be prepared from 3.00 kg of cuprite, Cu
2
S, if each atom of S in Cu
2
S is converted into 1
molecule of H
2
SO
4
?
2 2 2 3 2
4FeS O Fe O SO + + ;
2 2 3
SO O SO + ;
3 2 2 4
SO H O H SO +
Q25. Polyethylene can be produced from calcium carbide according to the following sequence of reactions :
2 2
; CaC H O CaO HC CH + +
2 2 2
HC CH H H C CH + = ; ( )
2 2 2 2
n
nH C CH CH CH =
Q26. The roasting of 100.0 g of copper ore yeilded 75.4 g of 89.5% pure copper. If the ore is composed of Cu
2
S and CuS with 11.0
% inert impurity, calculate the percent if Cu
2
S in the ore. The equation are Cu
2
S +O
2
2Cu +SO
2
and CuS +O
2
Cu +
SO
2
Q27. What mass of CO would be produced by the reaction of 16.0 g of O
2
with excess carbon according to the equation 2C +O
2
2CO
Q28. Carbon disulfide, CS
2
can be made from byproduct SO
2
. The overall reaction is 5C +2SO
2
CS
2
+4CO. How much CS
2
can be poroduced from 540 kg of waste SO
2
conversion is 82.0 % ?
Q29. How many kg of pure H
2
SO
4
could be obtained from 2.00 kg of pure iron pyrites (FeS
2
) according to the following reaction
Q30. Find the no. of mol of chloride ion needed to react with sufficient silver nitrate to make 10.0 g of AgCl. What mass of CaCl
2
is required to provide this number of mol of Cl
1
Q31. A 1.2048 g smaple of impure Na
2
CO
3
is dissolved and allowed to react with a solution of CaCl
2
. The resulting CaCO
3
, after
precipitation, filteration and drying , was found to weight 1.0362 g. Assuming that the impurities do not contribute to weight
of the precipitate, calculate the percent purity of the Na
2
CO
3
Q32. How much bismuth nitrate. Bi(NO
3
)
3
. 5H
2
O , would be formed from a solution of 15.0 g of bismuth in nitric acid.
Q33. Most commerical hydrochloric acid is prepared by heating NaCl with concentrated H
2
SO
4
. How much sulphuric acid
containing 90.0 % H
2
SO
4
by weight is needed for the production of 2000 kg concentrated hydrochloric acid containing 42.0
% HCl by weight ?
Q34. A 1.00 g total sample of a mixture of CaCO
3
(s) (FW =100) glass beads liberates 0.220 g of CO
2
(MW =44.0) upon
treatement with excess HCl (MW =36.5) Glass does not react with HCl (a) calculate the weight of CaCO
3
in the original
mixture (b) Calculate the weight percent of calcium in the original mixture
Q35. A carbonate. MCO
3
of an unknown metal is treated with HCl to produce CO
2
. Upon treating 1.00 g of MCO
3
with excess
HCl 0.522 gm of CO
2
is produced . Find the weight percnt of calciumin the original mixture
Q36. Four grams of a mixture of calcium carbonate and sand is treated with an excess of hydrochloric acid and 0.880 g of CO
2
is
produced. What is the percent of CaCO
3
in the original mixture ?
Q37. A mixture containing only FeCl
3
and AlCl
3
weights 5.95 g. The chlorides are converted in the hyudrous oxides and ignited to
Fe
2
O
3
and Al
2
O
3
. The oxide mixture weights 2.62 g. Calculate percent Fe and Al in the original mixture
Q38. An impure sample of zinc blende contains 40% zinc; the impurity being silica . If 100 grams of the sample is roasted to
oxidise all the ZnS to ZnO, what will be the weight of the roasted sample ? (At.. Weight of zinc =65.38)
(a) 78.3 grams (b) 87.3 grams (c) 83.7 grams (d) 90.2 grams
Q39. The plastics induxtry uses large amunts of phthalic anhydride, C
8
H
4
O
3
, made by the controlled oxidation of napthalene
10 8 2 8 4 3 2
2 9 2 4 C H O C H O H O + + . Since come of the napthalene is oxidised to other products, only 70.0 % of the
maximum yeild predicted by the equation is actually obtained. How many phthalic anhydride would be produced in practice
by the oxidation of 200 gm of C
10
H
8
?
Q40. A mixture of NaHCO
3
and Na
2
CO
3
weighed 1.0235g. The dissolved mixture was reacted with excess Ba(OH)
2
to form
2.1028 g BaCO
3
, by the reaction ( )
2 3 3
2
2 Na CO Ba OH BaCO NaOH + + ;
( )
3 3 2
2
NaHCO Ba OH BaCO NaOH H O + + + What was the percentage NaHCO
3
in the original mixture ?