IMDG1998

INTERNATIONAL MARITIME ORGANIZATION
INTERNATIONAL MARITIME DANGEROUS GOODS CODE (IMDG CODE)

Amendment 29-98
(including Supplement) This publication has been prepared and printed in such a way that the replacement pages can be inserted into the loose-leaf volumes of the 1994 Consolidated Edition of the IMDG Code, entirely replacing the amended/corrected pages
Published and printed in 1998 by the International Maritime Organization 4, Albert Embankment, London SE1-7SR ISBN 92-801-1465-4 Copyright IMO 1998 All rights reserved No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the International Maritime Organization
Sales number: IMO-213E
FOREWORD The International Convention for the Safety of Life at Sea, 1974 (SOLAS), as amended deals with various aspects of maritime safety and contains in part A of chapter VII the mandatory provisions governing the carriage of dangerous goods in packaged form or in solid form in bulk Regulation Vll/1-3 prohibits the carriage of dangerous goods except in accordance with the provisions of part A of chapter VII which are amplified by the International Maritime Dangerous Goods (IMDG) Code. Regulation II-2/54 of the SOLAS Convention specifies the special requirements for a ship intended to carry dangerous goods, the keel of which was laid or which was at a similar stage of construction on or after 1 September 1984. The International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78), deals with various aspects of prevention of marine pollution, and contains in its Annex III the mandatory provisions for the prevention of pollution by harmful substances carried by sea in packaged form Regulation 1(2) prohibits the carriage of harmful substances in ships except in accordance with the provisions of Annex III, which are also amplified by the IMDG Code. In accordance with the Provisions concerning Reports on Incidents Involving Harmful Substances (Protocol I to MARPOL 73/78), incidents involving losses of such substances from ships must be reported by the master or other person having charge of the ship concerned. Each substance defined as harmful to the marine environment is identified as a P MARINE POLLUTANT in its individual schedule of the IMDG Code and by the superscripts or
PP
in the General Index. Substances which may be considered harmful to the marine enviP PP
ronment only if they contain certain quantities of marine pollutants or superscript in the General Index.
are identified by the
The IMDG Code is recommended to Governments for adoption or for use as the basis for national regulations in pursuance of their obligations under regulation Vll/1-4 of the 1974 SOLAS Convention, as amended, and regulation 1(3) of Annex III of MARPOL 73/78 Observance of the Code harmonizes the practices and procedures followed in the carriage of dangerous goods by sea and ensures compliance with the mandatory provisions of the SOLAS Convention and of Annex III of MARPOL 73/78. The Code, which sets out in detail the requirements applicable to each individual substance, material or article, has undergone many changes, both in layout and content, in order to keep pace with the expansion and progress of industry IMO's Maritime Safety Committee (MSC) is authorized by the Organization's Assembly to adopt amendments to the Code, thus enabling IMO to respond promptly to developments in transport.
Amdt. 27-94
FOREWORD
During its seventeenth session (28 October to 8 November 1991), the Assembly adopted resolution A 717(17), "Co-ordination in Matters relating to Dangerous Goods and Hazardous Substances", in order to achieve and maintain a level of harmonization between the IMDG Code and the recommendations of the other transport modes. A revision of the Code was undertaken resulting in the latest set of amended pages (Amendment 29-98) which was adopted by the MSC at its sixty-ninth session (11 to 20 May 1998). The MSC unanimously agreed that Amendment 29 to the Code, its Annex I, the Emergency Procedures for Ships Carrying Dangerous Goods (EmS) and the Medical First Aid Guide for Use in Accidents Involving Dangerous Goods (MFAG) should be implemented on 1 January 1999, with a six month transitional period until 1 July 1999, on the understanding that Governments had the prerogative to implement an amendment in whole or in part at any earlier date following circulation of the adopted amendments by the Organization and that the Organization would be notified of any such early implementation.
Note on pagination a new page which has been inserted between existing pages is indicated by a number followed by -1, -2, -3 etc., a page which continues or extends a page is indicated by a number followed by a, b, c etc. (in a long sequence such as a table, this would continue as a1-, z1-, a4-, z4- etc.) Note on amended text changes to existing text or new texts are indicated by shading Where there are no changes resulting from Amendment 29 but a page does not exactly match a page of the 1994 Consolidated Edition as updated by Amendment 28-96 there is shading around the page number.
Amdt. 29-98
GENERAL INTRODUCTION
5.1.9
Class 9 Miscellaneous dangerous substances and articles. In this Code class 9 comprises: 1 substances and articles not covered by other classes which experience has shown or may show to be of such a dangerous character that the provisions of part A of chapter VII of the International Convention for the Safety of Life at Sea 1974, as amended should apply these include substances that are transported or offered for transport at temperatures equal to or exceeding 100 C in a liquid state and solids that are transported or offered for transport at temperatures equal to or exceeding 240 C; and substances not subject to the provisions of part A of chapter VII of the aforementioned Convention but to which the regulations of Annex III of the International Convention for the Prevention of Pollution from Ships 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78) apply. For the purposes of this Code dangerous goods with a melting point or initial melting point of 20 C or lower at a pressure of 101.3 kPa should be considered to be liquid unless there is an explicit or implicit indication to the contrary. A viscous substance for which a specific melting point cannot be determined should be subjected to the ASTM D-4359.90 test or to the test for determining fluidity (penetrometer test) prescribed in Appendix A.3 of Annex A of the European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR) with the modifications that the penetrometer shall conform to ISO 2137, 1985 and that the test shall be used for viscous substances of any class.
5.1.10
5.1.11 Non-classified materials: A GENERIC or NOT OTHERWISE SPECIFIED (N.O.S.) entry may be used to offer for transport by sea a substance material or article which is not listed by its name in the General Index. Such a substance material or article may be transported only after: - its dangerous hazardous and/or harmful properties have been determined; - it has been classified in accordance with the class definitions and criteria and; - the entry that most accurately describes the nature of the goods has been selected (see also subsection 7.1). Once the class of the goods has been established all applicable requirements for transport laid down in this Code should be complied with. Any substance material or article having or suspected of having explosive properties or characteristics should first be considered for classification in class 1. 5.2 5.2.1 Classification of substances, mixtures and solutions with multiple hazards The table of precedence of hazard characteristics in 5.2.6 should be used as a guide in determining the class of a substance mixture or solution having more than one hazard when it is not specifically listed by name in this Code. For substances mixtures or solutions having multiple hazards which are not specifically Instead by name the most stringent packaging group of those assigned to the respective hazards of the goods takes precedence over other packaging groups irrespective of the precedence of hazard table in 5.2.6. The precedence of hazard table indicates which of the hazards should be regarded as the primary hazard. The class which appears at the intersection of the horizontal line and the vertical column is the primary hazard and the remaining class is the subsidiary hazard. The packaging groups for each of the hazards associated with the substance mixture or solution should be determined by reference to the appropriate criteria. The most stringent of the groups so indicated should then become the packaging group of the substance mixture or solution.
5.2.2
IMDG CODE - PAGE 0019 Amdt. 29-98
5.2.3
The proper shipping name (see subsection 7.1 of this General Introduction) of a substance, mixture or solution when classified in accordance with 5.2.1 and 5.2.2 should be the most appropriate N.O.S. (not otherwise specified) entry in this Code for the class shown as the primary hazard. The precedence of hazard characteristics of the following substances materials and articles have not been dealt with in the precedence of hazard table as these primary hazards always take precedence: 1 substances and articles in class 1; 2 gases in class 2; 3 self-reactive and related substances and desensitized explosives in class 4.1; 4 pyrophoric substances in class 4.2; 5 substances in class 5.2; 6 substances in class 6.1 with a packaging group I vapour inhalation toxicity; 7 substances in class 6.2; and 8 materials in class 7.
5.2.4
5.2.5
Apart from excepted radioactive materials (where the other hazardous properties take precedence), radioactive materials having other hazardous properties should always be classified in class 7, with the greatest of the additional hazards being identified. Precedence of hazard table
Class and packaging group 3, I 3, II 3, III 4.1, II** 4.1, III** 4.2, II 4.2, III 4.3, I 4.3, II 4.3, III 51, I*** 51, II*** 5.1, III*** 6.1, I, Dermal 6.1, I, Oral 6.1, II, Inhalation 6.1, II, Dermal 6.1, II, Oral 6.1, III 4.2 4.3 6.1, I Dermal 3 3 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 5.1 6.1 6.1 6.1, I Oral 3 3 6.1 6.1 6.1 6.1 6.1 4.3 4.3 6.1 5.1 5.1 6.1 6.1, II 3 3 6.1 41 6.1 42 6.1 4.3 4.3 6.1 5.1 5.1 6.1 6.1 3 3 3* 41 41 4.2 42 4.3 4.3 4.3 5.1 5.1 5.1 8, I Liquid 3 8 8 8 8 4.3 8 8 5.1 8 8 8 8 8 8 8 8 8, I Solid 8 8 8 8 4.3 8 8 5.1 8 8 6.1 6.1 6.1 6.1 8 8 8, II Liquid 3 3 8 4.2 8 4.3 4.3 8 5.1 5.1 8 6.1 6.1 6.1 8 8 8 8, II Solid 41 8 4.2 8 4.3 4.3 8 5.1 5.1 8 6.1 6.1 6.1 6.1 6.1 8 8, III Liquid 3 3 3 4.2 42 4.3 4.3 4.3 5.1 5.1 5.1 6.1 6.1 6.1 6.1 6.1 8 8, III Solid 41 41 4.2 42 4.3 4.3 4.3 5.1 5.1 5.1 6.1 6.1 6.1 6.1 6.1 8
5.2.6
4.2 4.2
4.3 4.3 4.3 4.3
For hazards not shown in this table see 5.2.4.

* 6.1 for pesticides. ** Substances of class 4.1 other than self-reactive and related substances and desensitized explosives. *** There are at present no established criteria for determining packaging groups for liquids in class 5.1. For the time being, the degree of hazard is to be assessed by analogy with listed substances, allocating the substance to packaging group I (great), II (medium) or III (minor) danger. - Denotes an impossible combination.
5.3
Classification of solutions and mixtures subject to the provisions of part A of chapter VII of the International Convention for the Safety of Life at Sea, 1974, as amended
5.3.1 A solution or mixture containing a dangerous substance identified by name in this Code and one or more nondangerous substances should be shipped in accordance with the requirements for the dangerous substance except when 1 2 3 4 the solution or mixture is specifically listed elsewhere in this Code; or the schedule for the dangerous substance specifically indicates that it applies only to the pure or technically pure substance; or the class physical state or packaging group of the solution or mixture is not the same as that of the dangerous substance; or there is a significant change in the measures to be taken in an emergency.
5.3.2 When considering a solution or mixture in accordance with 5.3.1 due account should be given to whether the dangerous constituent comprising the solution or mixture has been identified as a marine pollutant. If this is the case the requirements of subsection 5.4 are also applicable. 5.3.3 For solutions and mixtures subject to 5.3.1 the qualifying word SOLUTION or MIXTURE as appropriate should be part of the proper shipping name e.g. BUTANE MIXTURE. 5.3.4 When the class physical state or packaging group has changed in comparison with the pure substance the solution or mixture should be shipped in accordance with the requirements for the changed hazard under an appropriate N.O.S. entry. 5.3.5 A mixture or solution containing one or more substances identified by name in this Code or classified under an N.O.S. or generic entry and one or more substances not subject to the provisions of this Code is not subject to the provisions of this Code if the hazard characteristics of the mixture or solution are such that they do not meet the criteria (including human experience criteria) for any class.
5.4
Classification of solutions, mixtures and isomers subject to the provisions of Annex III of the International Convention for the Prevention of Pollution from Ships, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78)
5.4.1 A solution or mixture contain no 10% or more of a marine pollutant or marine pollutants is a MARINE POLLUTANT 5.4.2 However certain marine pollutants do have an extreme pollution potential and are identified as severe marine pollutants in the individual schedules A solution or mixture containing 1% or more of these specific marine pollutant is MARINE POLLUTANT 5.4.3 A solution or mixture which does not fall within the criteria of classes 1 to 8 but which meets the criteria for marine pollutants under 5.4.1 or 5.4.2 should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. under UN No. 3082 and UN No. 3077 respectively in class 9 even though it is not listed by name in the appendices thereto. 5.4.4 An isomer of a substance identified as a marine pollutant and covered by a generic entry in classes 1 to 8, but which does not fall within the criteria of these classes should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. under UN No. 3082 and UN No. 3077 respectively in class 9 even though it is not listed by name in the appendices thereto.
6 6.1
STANDARDIZATION OF THE FLASHPOINT TEST METHOD The flashpoint of a flammable liquid is the lowest temperature of the liquid at which its vapour forms an ignitable mixture with air*. It gives a measure of the risk of formation of explosive or ignitable mixtures when the liquid escapes from its packing. A flammable liquid cannot be ignited so long as its temperature remains below the flashpoint. The flashpoint is not an exact physical constant for a given liquid It depends to some extent on the construction of the test apparatus used and on the testing procedure. Therefore flashpoint data should specify the name of the test apparatus. Several standard apparatuses are in current use. They all operate on the same principle a specified quantity of the liquid is introduced into a receptacle at a temperature well below the flashpoint to be expected then slowly heated periodically a small flame is brought near to the surface of the liquid. The flashpoint is the lowest temperature at which a flash is observed. The test methods can be divided into two groups depending on the use in an apparatus of an open receptacle (open cup methods) or a closed one which is only opened to admit the flame (closed cup methods). As a rule the flashpoints found in an open cup test are a few degrees higher than in a closed cup test. In general reproducibility in closed cup apparatus is better than in an open cup.
6.2
6.3
6.4
6.5
6.5.1 It's therefore recommended that flashpoints especially in the range around 23 C (73 F) should be determined by means of closed cup methods. 6.5.2 Flashpoint data in this Code are generally based on closed cup methods. In countries where it is customary to determine flashpoints by the open cup method the temperatures given by that method would need to be reduced to correspond with those in this Code. 6.6 The following documents describe methods used in certain countries to determine the flashpoint of substances in class 3: 1 France (Association francaise de normalisation (AFNOR) Tour Europe Cedex, 7, 92080 Pans la Defense); French Standard NF M 07 019; French Standard NF M 07 011/NFT 30 050/NFT 66 009; French Standard NF M 07 036. Germany (Deutscher Normenausschuss Burggrafenstrasse 6, 10787, Berlin) Standard DIN 53213 (for varnishes lacquers and similar viscous liquids with flashpoints below 65 C) Netherlands ASTM D 93 90 ASTM D 3278 89 ISO 1516 ISO 1523 ISO 3679 ISO 3680
2 3
Note: The flashpoint should not be confused with the ignition temperature, which is the temperature to which an explosive vapour-air mixture
must be heated to cause actual explosion. There is no relationship between the flashpoint and the ignition temperature.
7.1.3.2 When several names are in use for the same substance one or more of those names have been chosen as proper shipping names the rest being only synonyms are included on the individual schedules and in the General Index for reference purposes only. Initials or trade names alone should not be used to describe a substance unless they are abbreviations or names approved by the international Organisation for Standardization (ISO). Trade names may be utilized on documents and packages in addition to the proper shipping name. 7.1.4 A pesticide or pesticide preparation falling within the criteria of class 3 or class 6.1, which is a marine pollutant should be offered for transport under the appropriate pesticide entry as given in the Pesticides Table supplemented with the name and the concentration of the specific pesticide in parentheses and the words MARINE POLLUTANT (see subsection 9.3 of this General Introduction). Such a pesticide or pesticide preparation which does not fall under the criteria of these classes, but which meets the criteria for marine pollutants under 5.4.1 or 5.4.2 of this General Introduction should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., UN No. 3082 or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE , SOLID, N.O.S., UN No. 3077 under these entries in class 9 even though it is not listed by name in the appendices thereto. Care should be exercised in the selection of the portion of the entry, which constitutes the proper shipping name of the dangerous goods. Portions of an entry not highlighted by capital letters need not be considered as part of the proper shipping name. When conjunctions such as, and or on are not capitalized or when capitalized segments of an entry are punctuated by commas the entire capitalized portion of the entry need not necessarily be shown as the proper shipping name on documentation or packages. This is the case particularly when a combination of several distinct entries is listed under a single UN Number.
7.1.5
7.1.5.1 For proper shipping names to be used for dangerous goods shipped as limited quant ties see 18.7 and 18.8 of this General Introduction. 7.1.6 7.1.7 Proper shipping names may end with the qualifying words SOLUTION or MIXTURE, if the conditions stated in subsection 5.3 of this General Introduction are met. Where it is not already included the qualifying word LIQUID or SOLID as appropriate should be added to the proper shipping name of a substance which due to the differing physical states of the various isomers of the substance could be either liquid or solid (see 5.1.10 of this General Introduction) Where it is not already included the qualifying word MOLTEN should be added to the proper shipping name when a substance which is solid in accordance with the definition in 5.1.10 of this General Introduction is offered for transport in the molten state (e.g. ALKYLPHENOL, SOLID, N.O.S., MOLTEN). If the proper shipping name of a substance that is transposed or offered for transport in a liquid state at a temperature equal to or exceeding 100 C or in a solid state at temperatures equal to or exceeding 240 C does not convey the elevated temperature condition (for example by using the term MOLTEN or ELEVATED TEMPERATURE as part of the shipping name) the word HOT should immediately precede the proper shipping name on the transport document.
7.1.8
7.1.9
7.1.10 Proper shipping names may be used in the singular or plural as appropriate. Proper shipping names may be shown in plural where isomers of similar classification exist. Hydrates of inorganic substances may be included under the equivalent proper shipping name for the anhydrous substance as appropriate. In addition when qualifying words are used as part of the proper.
IMDG CODE - PAGE 0025 Amdt. 2896
shipping name their sequence on documentation or packages is optional Commercial or military names for goods of class 1 which contain the proper shipping name supplemented by additional descriptive text may be used. 7.1.11 Examples illustrating the selection of proper shipping names for such entries are: 1 UN No. 11 70 ETHANOL or ETHANOL SOLUTIONS The proper shipping name is the most appropriate of the following possible combinations: ETHANOL ETHANOL SOLUTIONS ETHANOL SOLUTION 2 UN No. 2583 ALKYLSULPHONIC or ARYLSULPHONIC ACIDS , SOLID with more than 5% free sulphuric acid The proper shipping name is the most appropriate of the following: ALKYLSULPHONIC ACIDS , SOLID ARYLSULPHONIC ACIDS, SOLID 3 UN No. 3207 ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND DISPERSION, WATER REACTIVE, FLAMMABLE, N.O.S. The proper shipping name is the most appropriate of the following: ORGANOMETALLIC COMPOUND, WATER-REACTIVE, FLAMMABLE, N.O.S. * ORGANOMETALLIC COMPOUND SOLUTION, WATER-REACTIVE, FLAMMABLE, N.O.S. * ORGANOMETALLIC COMPOUND DISPERSION, WATER-REACTIVE, FLAMMABLE, N.O.S. * 7.1.12 Practical considerations prohibit the listing of all dangerous goods by name in this Code. Therefore many dangerous goods must be transported under one of the N.O.S. (not otherwise specified) or generic entries in this Code Due to the highly generic nature of certain of these entries neither the entry itself nor its corresponding UN Number can provide sufficient information about the dangerous goods to ensure that appropriate response action is initiated in the event of an incident involving the goods. Thus, for the purpose of documentation and marking of packages, these entries should be supplemented, in parentheses, with the additional information required by 7.1.14. 7.1.13 Entries in this Code for which this additional information is necessary are listed below HOWEVER THERE ARE OTHER ENTRIES FOR WHICH THIS ADDITIONAL INFORMATION IS REQUIRED THIS IS INDICATED IN THE INDIVIDUAL SCHEDULES.
* These entries should be supplemented in parentheses, with the additional information required by 7.1.14
IMDG CODE - PAGE 0026 (first of thirteen pages) Amdt. 29-98
UN No. Proper Shipping Name

0020 0021 0190 0248 0249 0349 0350 0351 0352 0353 0354 0355 0356 0357 0358 0359 0382 0383 0384 0461 0462 0463 0464 0465 0466 0467 0468 0469 0470 0471 0472 0473 0474 0475 0476 0477 0478 AMMUNITION, TOXIC AMMUNITION, TOXIC SAMPLES, EXPLOSIVE, other than initiating explosive CONTRIVANCES, WATER-ACTIVATED CONTRIVANCES, WATER-ACTIVATED ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES EXPLOSIVE, N.O.S. ARTICLES EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. COMPONENTS, EXPLOSIVE TRAIN, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. ARTICLES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S.
IMDG Code Page

1210 1210 1134 1250 1250 1218 1211 1212 1213 1216 1217 1217 1217 1139 1139 1139 1249 1249 1249 1249 1212 1213 1214 1215 1212 1213 1214 1215 1212 1214 1215 1135 1136 1137 1138 1136 1138
IMDG CODE - PAGE 0026a (page 0026b follows) Amdt. 27-94

0479 0480 0481 0482 0485 1078 1224 1228 1325 1383 1409 1479 1544 1588 1601 1602 1693 1719 1759 1760 1903 1953 1954 1955 1956 1964 1965 1967 1968 1986 1987 SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. SUBSTANCES, EXPLOSIVE, VERY INSENSITIVE, N.O.S. SUBSTANCES, EXPLOSIVE, N.O.S. REFRIGERANT GAS, N.O.S. KETONES, LIQUID, N.O.S. MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. FLAMMABLE SOLID, ORGANIC, N.O.S. PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. METAL HYDRIDES, WATER REACTIVE, N.O.S. OXIDIZING SOLID, N.O.S. ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. CYANIDES, INORGANIC, SOLID, N.O.S. DISINFECTANT, SOLID, TOXIC, N.O.S. DYE, LIQUID, TOXIC, N.O.S. or DYE INTERMEDIATE, LIQUID, TOXIC,
IMDG Code Page

1136 1137 1140 1137 1138 2176 3248/3360 3135/3249/3361 4146 4255 4354-1 5163 6056 6115 6141 6142 6262 8136 8151 8147 8167 2125-1 2124 2125 2124 2147 2147 2152 2152 3104/3176/3303 3103/3175/3303
N.O.S.
TEAR GAS SUBSTANCE, LIQUID or SOLID, N.O.S. CAUSTIC ALKALI LIQUID, N.O.S. CORROSIVE SOLID, N.O.S. CORROSIVE LIQUID, N.O.S. DISINFECTANT, LIQUID, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, N.O.S. COMPRESSED GAS, FLAMMABLE, N.O.S. COMPRESSED GAS, TOXIC, N.O.S. COMPRESSED GAS, N.O.S. HYDROCARBON GAS, COMPRESSED, N.O.S. or HYDROCARBON GAS MIXTURE, COMPRESSED, N.O.S. HYDROCARBON GAS, LIQUEFIED, N.O.S. or HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S. INSECTICIDE GAS, TOXIC, N.O.S. INSECTICIDE GAS, N.O.S. ALCOHOLS, TOXIC, N.O.S. ALCOHOLS, N.O.S.
IMDG CODE - PAGE 0026b (page 0026c follows) Amdt. 29-98
UN No.
1988 1989 1992 1993 2003 2006 2206 2478 2571 2588 2693 2733 2734 2735 2757 2758 2759 2760 2761 2762 2763 2764
Proper Shipping Name

ALDEHYDES, TOXIC, N.O.S. ALDEHYDES, N.O.S. FLAMMABLE LIQUID, TOXIC, N.O.S. FLAMMABLE LIQUID, N.O.S. METAL ALKYLS, N.O.S. or METAL ARYLS, N.O.S. PLASTICS, NITROCELLULOSE-BASED, SELF-HEATING, N.O.S. ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC, N.O.S. ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S. ALKYLSULPHURIC ACIDS PESTICIDE, SOLID, TOXIC, N.O.S. BISULPHITES, AQUEOUS SOLUTION, N.O.S. AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. AMINES, LIQUID CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE,
IMDG Code Page

3105/3178/3305 3105/3177/3305 3127/3232/3346-1 3126/3230/3345 4243 4252 6166 3130/3242 8104 6221 8126 3106/3182-1/3306 8109-1 8109-2 6221 3270 6221 3270 6221 3270 6221 3270
N.O.S.
CARBAMATE PESTICIDE, SOLID, TOXIC CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23C ARSENICAL PESTICIDE, SOLID, TOXIC ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23C ORGANOCHLORINE PESTICIDE, SOLID, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23C TRIAZINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23C
IMDG CODE - PAGE 0026c (page 0026d follows) Amdt. 29-98

2771 2772 2775 2776 2777 2778 2779 2780 2781 2782 2788 2784 2786 2787 2788 2801 2810 2811 2818 2814 2845 2846 2900 2902 2903 2920 2921 THIOCARBAMATE PESTICIDE, SOLID, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C COPPER-BASED PESTICIDE, SOLID, TOXIC COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C MERCURY-BASED PESTICIDE , SOLID, TOXIC MERCURY-BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C BIPYRIDILIUM PESTICIDE, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C ORGANOTIN PESTICIDE, SOLID, TOXIC ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE TOXIC, flashpoint less than 23 C ORGANOTIN COMPOUND, LIQUID, N.O.S. DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. TOXIC LIQUID, ORGANIC, N.O.S. TOXIC , SOLID, ORGANIC, N.O.S. WATER REACTIVE SOLID, N.O.S. INFECTIOUS SUBSTANCES, AFFECTING HUMANS PYROPHORIC LIQUID, ORGANIC, N.O.S. PYROPHORIC SOLID, ORGANIC, N.O.S. INFECTIOUS SUBSTANCES, AFFECTING ANIMALS only PESTICIDE, LIQUID, TOXIC, N.O.S. PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flashpoint not less than 23 C CORROSIVE LIQUID, FLAMMABLE, N.O.S. CORROSIVE SOLID, FLAMMABLE, N.O.S.
IMDG Code Page

6221 3270 6221 3270 6221 3270 6221 3270 6221 3270 6221 3270 6221 3270 6214 8168 6270-1 6270-6 4368 6321 4254 4255 6322 6219 6220 8148 8151
IMDG CODE - PAGE 0026d (page 0026e follows) Amdt. 29-98

2922 2923 2924 2925 2926 2927 2928 2929 2930 2991 2992 2993 2994 2995 2996 2997 2998 3005 3006 3009 3010 CORROSIVE LIQUID, TOXIC, N.O.S. CORROSIVE SOLID, TOXIC, N.O.S. FLAMMABLE LIQUID, CORROSIVE, N.O.S. FLAMMABLE SOLID, CORROSIVE, ORGANIC, N.O.S. FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. TOXIC LIQUID, FLAMMABLE ORGANIC, N.O.S. TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C CARBAMATE PESTICIDE, LIQUID, TOXIC ARSENICAL PESTICIDE, LIQUID, TOXIC FLAMMABLE, flashpoint not less than 23 C ARSENICAL PESTICIDE, LIQUID, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C TRIAZINE PESTICIDE, LIQUID, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, TOXIC FLAMMABLE, flashpoint not less than 23 C THIOCARBAMATE PESTICIDE, LIQUID, TOXIC COPPER-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C COPPER-BASED PESTICIDE, LIQUID, TOXIC
IMDG Code Page

8149 8152 3126/3231/3346 4146-1 4147 6270-2 6270-7 6270-3 6270-8 6220 6219 6220 6219 6220 6219 6220 6219 6220 6219 6220 6219
IMDG CODE - PAGE 0026e (page 0026f follows) Amdt. 29-98

3011 3012 3013 3014 3015 3016 3017 3018 3019 3020 3021 3024 3025 3026 3027 3049 3050 3071 3077 3080 3082 3084 3085 3086 3087 3088 3093 MERCURY-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C MERCURY-BASED PESTICIDE, LIQUID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C ORGANOTIN PESTICIDE, LIQUID, TOXIC PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23 C c.c. COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint not less than 23 C COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC METAL ALKYL HALIDES, N.O.S. or METAL ARYL HALIDES, N.O.S. METAL ALKYL HYDRIDES, N.O.S. or METAL ARYL HYDRIDES, N.O.S. MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. CORROSIVE SOLID, OXIDIZING, N.O.S. OXIDIZING SOLID, CORROSIVE, N.O.S. TOXIC SOLID, OXIDIZING, N.O.S. OXIDIZING SOLID, TOXIC, N.O.S. SELF-HEATING SOLID, ORGANIC, N.O.S. CORROSIVE LIQUID, OXIDIZING, N.O.S.
IMDG Code Page

6220 6219 6220 6219 6220 6219 6220 6219 6220 6219 3270 3270 6220 6219 6221 4243 4244 6173 9029 6167 9028 8153 5164 6270-4 5165 4260 8153
IMDG CODE - PAGE 0026f (page 0026g follows) Amdt. 27-94

3094 3095 3096 3098 3099 3101 3102 3103 3104 3105 3106 3107 3108 3109 3110 3111 3112 3113 3114 3115 3116 3117 3118 3119 3120 3122 3123 3124 3125 CORROSIVE LIQUID, WATER-REACTIVE, N.O.S. CORROSIVE SOLID, SELF-HEATING, N.O.S. CORROSIVE SOLID, WATER-REACTIVE, N.O.S. OXIDIZING LIQUID, CORROSIVE, N.O.S. OXIDIZING LIQUID, TOXIC, N.O.S. ORGANIC PEROXIDE, TYPE B, LIQUID ORGANIC PEROXIDE, TYPE B, SOLID ORGANIC PEROXIDE, TYPE C, LIQUID ORGANIC PEROXIDE, TYPE C, SOLID ORGANIC PEROXIDE, TYPE D, LIQUID ORGANIC PEROXIDE, TYPE D, SOLID ORGANIC PEROXIDE, TYPE E, LIQUID ORGANIC PEROXIDE, TYPE E, SOLID ORGANIC PEROXIDE, TYPE F, LIQUID ORGANIC PEROXIDE, TYPE F, SOLID ORGANIC PEROXIDE, TYPE B, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE B, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE C, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE C, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE D, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE D, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE E, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE E, SOLID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED ORGANIC PEROXIDE, TYPE F, SOLID, TEMPERATURE CONTROLLED TOXIC LIQUID, OXIDIZING, N.O.S. TOXIC LIQUID, WATER-REACTIVE, N.O.S. TOXIC SOLID, SELF-HEATING, N.O.S. TOXIC SOLID WATER REACTIVE N.O.S.
IMDG Code Page

8150 8150 8150 5164 5165 5221 5222 5223 5224 5225 5226 5227 5228 5229 5230 5231 5232 5233 5234 5235 5236 5237 5238 5239 5240 62704 62705 62705 62705
IMDG CODE - PAGE 0026g (page 0026h follows) Amdt. 27-94

3126 3128 3129 3130 3131 3132 3134 3139 3140 3142 3143 3146 3147 3148 3156 3157 3158 3160 3161 3162 3163 3172 3175 3176 3178 3179 3180 3181 3182 3183 3184 3185 3186 3187 3188 SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S. SELF-HEATING SOLID, TOXIC, ORGANIC, N.O.S. WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. WATER-REACTIVE LIQUID, TOXIC, N.O.S. WATER-REACTIVE SOLID, CORROSIVE, N.O.S. WATER-REACTIVE SOLID, FLAMMABLE, N.O S WATER-REACTIVE SOLID TOXIC N.O.S. OXIDIZING LIQUID, N.O.S. ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. DISINFECTANT, LIQUID, TOXIC, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC N.O.S. ORGANOTIN COMPOUND, SOLID, N.O.S. DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE SOLID CORROSIVE,
IMDG Code Page

4261 4261 4367 4367 4369 4369 4369 5163 6056 6141 6142 6214 8168 4366 2125 2155-1 2142-1 21552 2155-1 2155-2 2155 6270-1 4173-1 4146-2 4146 4147 4146-1 4157-1 4157-1 4259-1 4259-2 4259-2 4259-1 42592 4259-2
N.O.S.
WATER-REACTIVE LIQUID, N.O.S. COMPRESSED GAS OXIDIZING, N.O.S. LIQUEFIED GAS, OXIDIZING, N.O.S. GAS, REFRIGERATED LIQUID, N.O.S. LIQUEFIED GAS, TOXIC FLAMMABLE, N.O.S. LIQUEFIED GAS FLAMMABLE, N.O.S. LIQUEFIED GAS, TOXIC N.O.S. LIQUEFIED GAS, N.O.S. TOXINS, EXTRACTED FROM LIVING SOURCES, N.O.S. SOLIDS CONTAINING FLAMMABLE LIQUID, N.O.S. FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. FLAMMABLE SOLID INORGANIC, N.O.S. FLAMMABLE SOLID TOXIC, INORGANIC, N.O.S. FLAMMABLE SOLID CORROSIVE, INORGANIC, N.O.S. METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE N.O.S. METAL HYDRIDES, FLAMMABLE, N.O.S. SELF HEATING LIQUID ORGANIC, N.O.S. SELF HEATING LIQUID, TOXIC ORGANIC, N.O.S. SELF-HEATING LIQUID, CORROSIVE ORGANIC, N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. SELF-HEATING LIQUID, CORROSIVE, INORGANIC, N.O.S.
IMDG CODE - PAGE 0026h (page 0026i follows) Amdt. 29-98
UN No.

COMPRESSED GAS, TOXIC, OXIDIZING, N.O.S. COMPRESSED GAS, TOXIC, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. COMPRESSED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, N.O.S. LIQUEFIED GAS, TOXIC, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, FLAMMABLE, CORROSIVE, N.O.S. LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. GAS, REFRIGERATED, LIQUID, OXIDIZING, N.O.S. GAS, REFRIGERATED, LIQUID, FLAMMABLE, N.O.S. NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 2% but not more than 10% nitroglycerin , by mass MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTANS MIXTURE, LIQUID, FLAMMABLE, N.O.S. NITROGLYCER!N MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin , by mass PENTAERYTHRITE TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S. with more than 10% but not more than 20% PETN, by mass PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23 C PHENOXYACETIC ACID, DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE flashpoint not less than 23 C PHENOXYACETIC ACID, DERIVATIVE PESTICIDE, LIQUID, TOXIC PYRETHROID PESTICIDE, SOLID, TOXIC PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC flashpoint less than 23 C PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE flashpoint not less than 23 C PYRETHROID PESTICIDE, LIQUID, TOXIC INSECTICIDE GAS, FLAMMABLE, N.O.S. INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S.
IMDG Code Page

2125-3 2125-1 2125-2 2125-3 2155-4 2155-2 2155-3 2155-4 2142-2 2142-1 4161-2 3134-2/32482/3360-2 3138-3/32651/3369-1 4164 6221 3270 6220 6219 6221 3270 6220 6219 2152-1 2152-1
3303 3304 3305 3306 3307 3308 3309 3310 3311

3312 3319 3336 3343 3344 3345 3346 3347 3348 3349 3350 3351 3352 3354 3355
IMDG CODE - PAGE 0026k (page 0026l follows) Amdt. 28-96
UN No.
IMDG Code Page
PAGE RESERVED
IMDG CODE - PAGE 0026l (page 0027 follows) Amdt. 28-96
7.1.14
The additional information to be shown in documentation and on packages should be a recognized chemical name currently used in readily available scientific and technical handbooks, journals and texts. Trade names should not be used for this purpose In the case of pesticides the technical name which should supplement the proper shipping name should be the ISO common name, other name(s) listed in The WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification or the name of the active substance. For pesticides, the concentration of the active substance(s) should be included in the documentation accompanying the shipment.
7.1.14.1 When a mixture of dangerous goods is described by one of the N.O.S. or generic entries listed in the preceding pages, the inclusion in parentheses of this additional information for each constituent that contributes to the hazard of the mixture may result in such a lengthy description that marking the entire description on the packages becomes impractical. In general not more than the two constituents which contribute most to the hazard of a mixture need be shown. 7.1.14.2 If a package containing a mixture bears a subsidiary risk label, one of the chemical names shown in parentheses should be the name of the constituent which leads to the use of the subsidiary risk label. 7.1.14.3 If a package contains a marine pollutant, the recognized chemical name (or in the case of pesticides, the ISO approved name) of the marine pollutant should always be shown. 7.2 7.2.1 7.2.1.1 Marking and labelling of packages Marking of packages Unless otherwise provided in this Code, each package containing dangerous goods should be durably marked with the proper shipping name (see subsection 7.1) of the contents, and, when assigned, the corresponding United Nations UN Number preceded by the letters "UN". In the case of unpackaged articles, the marking should be displayed on the article, on its cradle or on its handling, storage or launching device. A package containing a marine pollutant should also be durably marked with the MARINE POLLUTANT mark except: 1 packages containing marine pollutants in inner packagings with: - contents of 5 / or less for liquids, or - contents of 5 kg or less for solids, or 2 packages containing severe marine pollutants in inner packagings with: - contents of 0.5 / or less for liquids, or - contents of 500 g or less for solids. (See subsection 23.5 of this General Introduction) 7.2.1.3 The methods of marking as required in 7.2.1 on packages should be such that this information will still be identifiable on packages surviving at least three months immersion in the sea. In considering suitable marking methods, account should be taken of the durability of the packaging materials used and of the surface of the package.
7.2.1.2
7.2.1.4
Each package containing dangerous goods packed into a container should be marked as specified in this Code.
7.2.2 7.2.2.1
Labelling of packages Unless otherwise provided in this Code e.g. as provided in section 18 of this General Introduction, each package containing dangerous goods should be durably identified with distinctive label(s) or stencil(s) of the label(s) so as to make clear the dangerous properties of the goods. For goods of class1 in division 1.4, compatibility group S each package may alternatively be marked 1.4S. A package containing a dangerous substance with a low degree of danger and identified as such on the individual schedule may be exempt from these labelling requirements In these cases the individual schedules indicate that no hazard label is required. However, for certain substances, the package should be marked with appropriate text as indicated on the schedule. For example Proper shipping name Hay* Fishmeal Batteries, wet, non-spillable * No mark is required for the carriage of hay UN No. 1327 1374 2800 Class 4.1 4.2 8 Mark required on package
7.2.2.2
Class 4.2 Class 8
7.2.2.3
The method of affixing the label(s) or applying stencil(s) of label(s) on packages containing dangerous goods should be such that the label(s) or stencil(s) will still be identifiable on packages surviving at least three months' immersion in the sea. In considering suitable labelling methods account should be taken of the durability of the packaging materials used and the surface of the package. Substances which possess subsidiary dangerous properties should where so prescribed in the individual schedule also bear the label denoting this hazard. In all cases, subsidiary risk labels should not bear the class number. Substances of class 8 need not carry a subsidiary risk label of class 6.1 if the " toxicity" arises solely from the destructive effect on tissue. Substances of class 5.2 need not carry a subsidiary risk label of class 8 if the corrosivity hazard level is packaging group III. Placarding and marking of cargo transport units General requirements For the purposes of this subsection, a cargo transport unit is: 1 2 3 4 5 6 a road freight vehicle; a railway freight wagon; a freight container ; a road tank vehicle; a railway tank wagon; and a portable tank.
7.2.2.4
7.2.2.5 7.2.2.6
7.3 7.3.1 7.3.1.1
7.3.1.2
Enlarged labels (placards) and if applicable, marks and signs, should be affixed to the exterior surfaces of a cargo transport unit to provide a warning that the contents of the unit are dangerous goods and present risks, unless the labels and/or marks affixed to the packages are clearly visible from the exterior of the unit.
IMDG CODE - PAGE 0028

Amdt. 28-96
9 DOCUMENTATION OF DANGEROUS GOODS SHIPMENTS
9.1 When dangerous goods are offered for shipment similar documents to those required for other categories of goods have to be prepared. The form of these documents the particulars to be entered on them and the obligations they entail may be fixed by international conventions applying to certain modes of transport and by national legislation. 9.2 One of the primary requirements of a shipping document for dangerous goods is to convey the fundamental information relative to the hazards of the goods. It is, therefore necessary to include certain basic information on the document for a consignment of a (the) dangerous good(s) unless otherwise exempted or regulated in this Code. 9.3 The basic items of information necessary for each dangerous substance, material or article offered for shipment are: 1 The proper shipping name (see subsection 7.1 of this General Introduction). 2 The class and, when assigned the division of the goods In addition this may be followed by the class name: - For substances and articles of , the division should be followed immediately by the compatibility group and the stowage arrangement; - For gases possessing subsidiary hazards the information should be further amplified to indicate these hazards by adding the word "flammable" , 'oxidizing agent' and/or 'corrosive ', as appropriate; - For AEROSOLS (UN No. 1950) transported as limited quantities see 1882; - For class 7 radioactive materials the class should be followed immediately by the words 'RADIOACTIVE MATERIAL', unless this already appears in the proper shipping name. 3 The UN Number shown for the dangerous goods in the IMDG Code, preceded by the letters "UN" (Not required for consignments identified as dangerous goods in limited quantities of class/classes ). 4 Where assigned, the packaging group. 5 For class 7 radioactive materials only the class 7 schedule number. 6 Empty packagings including portable tanks and bulk packagings which contain the residue of dangerous goods should be so indicated by placing the words "EMPTY UNCLEANED" or "RESIDUE - LAST CONTAINED " before or after the proper shipping name. 7 If waste dangerous goods (other than radioactive wastes) are being transported for disposal, or for processing for disposal, the proper shipping name should be preceded by the word "WASTE". 8 The number and kind of packages and the total quantity of dangerous goods covered by the description (by volume or mass, and in the case of goods of by the net explosives mass of the contents).
See also section 7 of this General Introduction
9.4.1 If the dangerous goods documentation is presented to the carrier by means of electronic data processing (EDP) or electronic data interchange (EDI) transmission techniques the signature(s) may be replaced by the name(s) (in capitals) of the person authorized to sign. 9.5 The text of the above declaration, and the special information relative to the hazards of the goods to be carried (as in 9.3 above) should be incorporated into, or combined with, an existing transport or shipping document. The layout of the information on the document (or the order of transmission of the corresponding data by electronic or other automatic data processing (EDP) or electronic data interchange (EDI) techniques) should be as in 9.3. When an existing transport or shipping document or cargo handling form cannot be used for the purposes of dangerous goods documentation for multimodel transport a specimen declaration form has been prepared (see 9.11)*, which is suitable for use where the declaration is made on a separate document. It is not the intention to require a separate shipping document for dangerous goods when a shipment contains both dangerous and non-dangerous goods, or to restrict the number of individual descriptions that may appear on a single document. However if both dangerous and non-dangerous goods are listed on one document the dangerous goods should be listed first, or otherwise emphasized. Special information
9.6
9.7
9.7.1 Special information is required: 1 for goods of (see section 2 of the introduction to ); 2 for self reactive substances in class 4.1 exempted from displaying a subsidiary risk label of (see 6.1 of the introduction to class 4.1); 3 for certain organic peroxides exempted from displaying a subsidiary risk label of (see 5.1.1 of the introduction to class 5.2); 4 for infectious substances (see introduction to class 6.2); 5 for radioactive materials (see section 8 of the introduction to class 7). 9.7.2 In certain circumstances special certificates are required, such as: 1 a container packing certificate (see 12.3.7 of this General Introduction); 2 a vehicle declaration (see 17.7.7 of this General Introduction); 3 a weathering certificate as required in the individual schedules; 4 a certificate exempting a substance, material or article from the provisions of the IMDG Code (e.g. see individual entries for charcoal, fishmeal, seed cake); 5 for new self-reactive substances and organic peroxides or new formulations of currently assigned self-reactive substances and organic peroxides, a statement by the competent authority of the country of origin of the approved classification and conditions of carriage. 9.8 When packages containing dangerous goods are packed into a unit, e.g. freight container flat trailer or other vehicle intended for carriage by sea those responsible for the packing of the unit should provide a certificate or declaration in accordance with 12.3.7 or 17.7.7 of this General Introduction as appropriate. The container/vehicle/unit identification number(s) should also be indicated.
* The layout of this form complies with the recommendations contained in the Trade Data Elements Directory issued by the UN/ECE Working
Party on Facilitation of International Trade Procedures (United Nations publication ECE/ TRADE/200) in particular Recommendation No.1 (United Nations Lay-out Key for Trade Documents) (ECE/TRADE/ 137, edition 82.2) and Recommendation No.11 (Documentary Aspects of the International Transport of Dangerous Goods) (ECE/TRADE/204 edition 96.1).
9.9 9.9.1
Documentation of cargo transport units under fumigation Transport documents associated with the carriage of cargo transport units under fumigation should show the date of fumigation and the type and amount of the fumigant used. In addition instructions for disposal of a residual fumigant, including fumigation devices (if used), should be provided. Documentation required on board the ship
9.10
9.10.1 Each ship carrying dangerous goods or marine pollutants should have a special list or manifest setting forth, in accordance with regulation 5 of chapter VII of the International Convention for the Safety of Life at Sea 1974 as amended, and with regulation 4 of Annex III of the International Convention for the Prevention of Pollution from Ships 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78), the dangerous goods and their location. This dangerous goods or marine pollutants list or manifest should be based on the documentation and certification required in this Code and should at least contain, in addition to the information set forth in 9.3, the stowage location of these goods. 9.10.2 For consignments of dangerous goods, appropriate information should be immediately available at all times for use in emergency response to accidents and incidents involving dangerous goods in transport. The information should be available away from packages containing the dangerous goods and immediately accessible in the event of an incident. Methods of compliance include: 1 appropriate entries in the special list manifest or dangerous goods declaration; or 2 provision of a separate document such as a safety data sheet; or 3 provision of a separate document such as the Emergency Procedures for Ships Carrying Dangerous Goods (EmS) and Medical First Aid Guide for Use in Accidents Involving Dangerous Goods (MFAG) for use in conjunction with the transport document.
9.11
Example of a form which may be used as a combined transport document and container packing certificate for the multimodal transport of dangerous goods [new table].
MULTIMODAL DANGEROUS GOODS FORM
This form may be used as a dangerous goods declaration as it meets the requirements of SOLAS 74, chapter VII, regulation 5, MARPOL 73/78, Annex III, regulation 4 and section 9 of the General introduction to the IMDG Code. 1. Shipper/Consignor/Sender 2. Transport document number 3. Page 1 of ___ pages 4. Shipper's reference 5. Freight forwarders reference 6 Consignee 7. Carrier (to be completed by the carrier) SHIPPER'S DECLARATION I hereby declare that the contents of this consignment are fully and accurately described below by the proper shipping name and are classified packaged marked and labelled/placarded and are in all respects in proper condition for transport according to the applicable international and national government regulations. 8. This shipment is within the limitations prescribed for (Delete non-applicable) PASSENGER AND CARGO CARGO AIRCRAFT AIRCRAFT ONLY 10. Vessel/flight no and date 11. Port/place of loading 12. Port/place of discharge 14. Shipping marks 13. Destination Gross mass (kg) Net mass Cube (m )
3
9. Additional handling information
* Number and kind of packages description of goods
15. Container identification no. / 16. Seal number(s) vehicle registration no. CONTAINER/VEHICLE PACKING CERTIFICATE
17. Container/vehicle 18. Tare mass 19. Total gross (including tare) (kg) size & type (kg) 21. RECEIVING ORGANIZATION RECEIPT
I hereby declare that the goods described above have been Received the above number of packages/containers/trailers in apparent packed/loaded into the container/vehicle identified above in good order and condition unless stated hereon RECEIVING ORGANISAaccordance with the applicable provisions TION REMARKS. ** MUST BE COMPLETED AND SIGNED FOR ALL CONTAINER/VEHICLE LOADS BY PERSON RESPONSIBLE FOR PACKING/LOADING. 20. Name of company Haulier's name Vehicle reg. no. Name/status of declarant Place and date Signature of declarant DRIVER'S SIGNATURE Signature and date Name/status of declarant Place and date Signature of declarant 22. Name of company (OF SHIPPER, PREPARING THIS NOTE)
* DANGEROUS GOODS You must specify proper shipping name hazard class UN No., Packaging group (where assigned). Marine pollutant and observe the mandatory requirements under applicable national and international governmental regulations. For the purposes of the IMDG Code see paragraph 9.3. For the purposes of the IMDG Code see paragraphs 12.3.7 or 17.7.7.
IMDG CODE - PAGE 0039 (page 0039a follows) Amdt. 29-98
IMDG CODE - PAGE 0039 (page 0039a follows) Amdt 29-98
GENERAL INTRODUCTION Documentary aspects of the international transport of dangerous goods Container/Vehicle Packing Certificate (Box 20) The signature given in Box 20 must be that of the person controlling the container/vehicle operation. It is certified that. The container/vehicle was clean dry and apparently fit to receive the goods. If the consignments include goods of other than division 1.4 the container is structurally serviceable in conformity with section 12 of the introduction to of the IMDG Code. No incompatible goods have been packed into the container/vehicle unless specially authorized by the Competent Authority. All packages have been externally inspected for damage and only sound packages packed. Drums have been stowed in an upright position unless otherwise authorized by the Competent Authority. All packages have been properly packed and secured in the container/vehicle. When materials are transported in bulk packagings the cargo has been evenly distributed in the container/ vehicle. The packages and the container/vehicle have been properly marked labelled and placarded Any irrelevant marks labels and placards have been removed. When solid carbon dioxide (CO2 - dry ice) is used for cooling purposes the vehicle or freight container is externally marked or labelled in a conspicuous place e. g. at the door end with the words DANGEROUS CO2 GAS (DRY ICE) INSIDE - VENTILATE THOROUGHLY BEFORE ENTERING. When this Dangerous Goods Form is used as a container/vehicle packing certificate only not a combined document a dangerous goods declaration signed by the shipper or supplier must have been issued/received to cover each dangerous goods consignment packed in the container. Note: The container packing certificate is not required for tanks
IMDG CODE - PAGE 0039b (page 0040 follows) Amdt. 29-98
10 PACKING 10.1 10.2 The types of packages and packagings recommended in this Code are those which, based on extensive past experience, ensure a high degree of safety. Detailed specifications and a number of performance tests applicable to a wide range of packagings recommended in this Code are to be found in Annex I to this Code.
10.2.1 Dangerous goods of all classes other than classes 1, 2, 6.2 and 7 have for packing purposes been apportioned among three categories (packaging groups) according to the degree of danger they present great danger (packaging group I), medium danger (packaging group II) and minor danger (packaging group III). The packaging group to which a substance is assigned is given in the individual schedule. 10.2.2 Performance tests should be made on packagings representative of those to be used in commercial practices. A packaging destined to contain a dangerous substance with a low degree of danger, and identified as such in the individual schedule, may be exempt from the packaging performance tests. 10.2.3 Suitable evidence must be established and kept to enable the fact that the tests have been passed successfully to be verified. 10.2.4 Each packaging manufactured and intended for use according to this Code should bear the markings specified in section 6 of Annex I to this Code. 10.3 Equivalences In order to take into account progress in science and technology, there is no objection to the use of packagings having specifications different from those recommended in this Code, provided that they are at least equally effective acceptable to authorities concerned and able successfully to withstand the tests described in Annex I to this Code. Moreover, methods of testing, other than those described in Annex I to this Code, are acceptable provided that they be at least equally effective. 10.4 10.5 The strength of packagings should be such that they will retain their contents and keep them free from contamination under the normal conditions of carriage by sea. Parts of packagings which are in direct contact with dangerous substances should not be affected by chemical or other action of those substances. Where necessary, they should be provided with a suitable inner coating or treatment. Such parts of packagings should not incorporate constituents liable to react dangerously with the contents so as to form hazardous products or to weaken them significantly.
10.5.1 Cushioning and absorbent material should be inert and suited to the nature of the contents. 10.6 Particular recommendations in respect of certain packaging materials and specifications are dealt with in detail in the separate classes.
12 CONTAINER TRAFFIC 12.1 12.1.1 Applicability and definitions For the purposes of this section, a 'container' is a freight container used for the transport of packaged dangerous goods, a bulk packaging for solid dangerous goods or a portable tank used for the transport of liquid and solid dangerous substances, non-refrigerated liquefied gases and refrigerated liquefied gases. For the transport of solid dangerous goods in bulk packagings see also section 25 of this General Introduction. The requirements for portable tanks are given in section 13. For the purposes of this Code, freight container means an article of transport equipment that is of a permanent character and accordingly strong enough to be suitable for repeated use, specially designed to facilitate the transport of goods, by one or more modes of transport, without intermediate reloading and designed to be secured and/or readily handled having fittings for these purposes. The term freight container includes neither vehicle nor packaging. However a container that is carried on a chassis is included. Freight containers used for the transport of packaged dangerous goods or as bulk packagings for solid dangerous goods should be of adequate strength to resist the possible stress imposed by the conditions of the services in which they are employed and they should be adequately maintained. They should be approved in accordance with the International Convention for Safe Containers (CSC), 1972, as amended when applicable.
12.1.2
12.1.3
12.1.3.1 The International Convention for Safe Containers does not apply to offshore containers that are handled in open seas. The design and testing of offshore containers should take into account the dynamic lifting and impact forces that may occur when a container is handled in open seas in adverse weather and sea conditions. The requirement for such containers should be determined by the approving competent authority. Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas. Such containers should be clearly marked with the words OFFSHORE CONTAINER on the safety approval plate. 12.1.4 12.1.5 12.1.6 Closed freight container means a freight container which totally encloses the contents by permanent structures. Freight containers with fabric sides or tops are not closed freight containers for the purposes of this section. Open freight container means a freight container which is not a closed freight container. Container space means a distance not less than 6 metres (20 feet) fore and aft or not less than 2.4 metres (8 feet) athwartship. This distance may be occupied by a container or containers containing non-dangerous materials. Cellular ship means a ship in which containers are loaded under deck into specially designed slots giving a permanent stowage of the container during sea transport. Containers loaded on deck in such a ship are specially stacked and secured on fittings.
12.1.7
12.1.8
In relation to this section, the terms listed hereafter should be interpreted as described hereafter: 1 Packagings and packages refer to receptacles for dangerous goods and to receptacles containing dangerous goods respectively; 2 Packing and unpacking refer to the placing of packages containing dangerous goods into a freight container and their removal therefrom.
12.2 12.2.1
Permitted shipments Dangerous goods which have to be segregated from each other should not be carried in the same freight container However, dangerous goods which should be segregated AWAY FROM each other may be carried in the same freight container with the approval of the competent authority. In such cases an equivalent standard of safety must be maintained. Dangerous goods should only be transported in freight containers when they are packaged in accordance with section 10 of this General Introduction.
12.2.2
12.3 12.3.1
Freight container packing and certification Packages containing dangerous substances and any other goods should be tightly packed within the freight container or adequately braced and secured for the voyage. The packages should be packed in such a way that there will be a minimum likelihood of damage to fittings during transport. Such fittings on packages should be adequately protected. When a dangerous goods consignment forms only part of the load of a freight container , it should preferably be packed so as to be accessible from the doors of the freight container .
12.3.2
12.3.2.1 If container doors are locked, the means of locking should be such that, in case of emergency, the doors can be opened without delay (See IMO/ILO Guidelines for Packing Cargo in Freight Containers or Vehicles in the Supplement to this Code). 12.3.3 12.3.4 12.3.5 12.3.6 The requirements set out in section 9 of this General Introduction with respect to the documentation of packaged dangerous goods and freight containers used as bulk packagings for dangerous goods should be met. Freight containers into which dangerous goods are to be packed should be examined visually for damage and if there is evidence of material damage the freight container should not be packed. Irrelevant markings, labels, placards, orange panels and marine pollutant marks should be removed before packing a freight container . Packages should be examined and any found to be damaged, leaking or sifting should not be packed into a freight container . Care should be taken to see that excessive water, snow, ice or foreign matter adhering to packages is removed before packing into a freight container .
12.3.7 Those responsible for the packing of the dangerous goods into a freight container should provide a "container packing certificate" certifying that this has been properly carried out and embodying the following provisions*: -The freight container was clean, dry and apparently fit to receive the goods; -If the consignments include goods of , other than division 1.4, the freight container is structurally serviceable in conformity with section 12 of the introduction to of the IMDG Code; -Goods which should be segregated have not been packed together in the freight container , unless approved by the competent authority concerned in accordance with 12.2.1; -All packages have been externally inspected for damage and only sound packages have been packed; -Drums have been stowed in an upright position, unless otherwise authorized by the competent authority; -All packages have been properly packed in the freight container and secured; -When dangerous goods are transported in bulk packagings the cargo has been evenly distributed in the freight container ; -The freight container and the packages therein are properly marked, labelled and placarded; -When solid carbon dioxide (dry ice) is used for cooling purposes, the freight container is externally marked or labelled in a conspicuous place at the door end, with the words "DANGEROUS CO2 GAS (DRY ICE) INSIDE, VENTILATE THOROUGHLY BEFORE ENTERING"; -The dangerous goods declaration required in subsection 9.4 of the General Introduction to the International Maritime Dangerous Goods Code (IMDG Code) has been received for each dangerous goods consignment packed in the freight container . The functions of the documents required in 12.3.3 and 12.3.7 above may be incorporated into a single document, if not, it may be desirable to attach these documents one to the other. If these functions are incorporated into a single document, e.g. a dangerous goods declaration, a shipping note, etc., the inclusion of a phrase such as "It is declared that the packing of the freight container has been carried out in accordance with the provisions of 12.3.7 of section 12 of the General Introduction to the IMDG Code" may suffice. Note: The container packing certificate is not required for tanks. 12.3.8 The special dangerous goods list or manifest (required by regulation 5.3 of part A of chapter VII of the International Convention for the Safety of Life at Sea, 1974, as amended (and by regulation 4 (3) of Annex III of the International Convention for the Prevention of Pollution from Ships, 1973, as modified by the Protocol of 1978 relating thereto (MARPOL 73/78)) and/or a cargo plan should indicate clearly those containers in which dangerous goods are loaded and their location aboard the ship. The total quantity of each dangerous substance, in addition to the description as required under the above regulation, should also be shown in the list, manifest and/or cargo plan.
* See also MSC/Circ. 506/Rev.1 of 10 January 1990 on container packing certificates and vehicle packing declarations (see the Supplement to this Code).
12.4
Marking, labelling and placarding*
12.4.1 Each package containing dangerous goods packed into a freight container should be marked and labelled in accordance with the requirements of sections 7 and 8 of this General Introduction. 12.4.2 Marking and placarding of freight containers containing packaged dangerous goods or used as bulk packagings for dangerous goods should be carried out in accordance with the requirements of sections 7 and 8 of this General Introduction. 12.5 Stowage of containers on board ships
12.5.1 Containers should be examined for external signs of damage leakage or sifting of contents. Any container found to be damaged leaking or sifting should not be accepted for shipment until repairs have been effected or damaged receptacles removed. 12.5.2 The following requirements should apply for the stowage of containers on board ships: 1 A container packed or loaded with flammable gases or liquids having a flashpoint below 23C c.c. should only be stowed under deck together in the same cargo space with refrigerated or heated containers the coolant or heating equipment of which could provide a possible source of ignition if -the coolant compartment and the cooling or heating equipment of the cargo transport units comply with 21.4; and -the design construction and equipment of the cargo space complies with the requirements of regulation II-2/54 of SOLAS 1974 as amended; -otherwise the stowage is restricted to on deck only. 2 A temperature controlled container packed or loaded with flammable gases or liquids having a flashpoint below 23C c.c. should only be stowed under deck if the requirements under 1 above are met otherwise the stowage is restricted to on deck only. 3 A container packed or loaded with flammable gases or liquids having a flashpoint below 23C c.c. carried on deck should be stowed away from (as defined in 15.2 of this General Introduction) possible sources of ignition. 12.5.3 Where stowage is permitted on deck or under deck containers packed or loaded with marine pollutants should preferably be stowed under deck except when a weather deck provides equivalent protection. 12.5.4 Where stowage on deck only is required preference should be given to the stowage of containers packed or loaded with marine pollutants on well protected decks or to the stowage inboard in sheltered areas of exposed decks. 12.5.5 Containers should be secured in accordance with SOLAS, Chapter VII, regulation 6.6 - Cargo Securing Manual (See MSC/Circ.745 on the Guidelines for the Preparation of the Cargo Securing Manual in the Supplement to this Code).
* For containers under fumigation see subsection 3.5 of the IMO publication Recommendations on the Safe Use of Pesticides in Ships (See the Supplement to this Code).
13 PORTABLE TANKS AND ROAD TANK VEHICLES 13.1 GENERAL REQUIREMENTS FOR PORTABLE TANKS AND ROAD TANK VEHICLES FOR DANGEROUS SUBSTANCES OTHER THAN CLASS 2 Preamble The requirements of this subsection apply to portable tanks and road tank vehicles intended for the transport of dangerous substances except for those of class 2, by sea. In addition to these requirements, or unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC) 1972 as amended, should be fulfilled by any tank which meets the definition of a container within the terms of that Convention. The International Convention for Safe Containers does not apply to offshore tank-containers that are handled in open seas. The design and testing of offshore tank-containers should take into account the dynamic lifting and impact forces that may occur when a tank is handled in open seas in adverse weather and sea conditions. The requirements for such tanks should be determined by the approving competent authority (see also MSC/Circ.613 in the annex at the end of this section). Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas. Attention is drawn to the fact that no requirements have been included in respect of any additional fire-fighting equipment which may be necessary on ships transporting these tanks. In order to take into account progress in science and technology, the use of alternative arrangements may be considered where these offer at least equivalent safety in use in respect of compatibility with the properties of the substances transported and equivalent or superior resistance to impact, loading and fire. The appendix to this subsection comprises the list of dangerous substances showing the particular requirements which modify or supplement these general requirements for each particular substance. The appendix will need updating from time to time in the light of technical progress and to include new substances.
13.1.1 13.1.1.1
13.1.1.2 13.1.1.3
13.1.1.4
13.1.1.4.1 In general, where a substance has not been allocated a UN Number, it should be carried under the most suitable N.O.S. entry. However, the competent authority of the country of origin may issue interim approvals for shipment of substances not listed in the appendix to this subsection to which individual UN Numbers have already been assigned. The approval should accompany the shipment concerned and contain at a minimum the information normally provided in the list of substances and the conditions under which the particular substance should be carried. The approval should contain a note to the effect that this competent authority has undertaken action to include this substance in the appendix to subsection 13.1. 13.1.1.4.2 Solid dangerous substances which do not appear on the list in the appendix to this section but which may be transported in portable tanks in accordance with paragraphs 13.1.28.2.1 and 13.1.28.2.3 are not subject to approval by the competent authority of the country of origin as provided for in paragraph 13.1.1.4.1 in general. However, in the particular case provided for in paragraph 13.1.28.2.3 it is necessary to obtain competent authority approval but it is not necessary for that approval to contain a note to the effect that the competent authority has undertaken action to include this substance in the appendix to subsection 13.1. 13.1.1.5 These requirements do not apply to rail tank-wagons (except for materials of class 7), non-metallic tanks, tanks intended for the transport of liquids having a capacity of 450 litres or less, and tanks for substances of class 2.
13.1.2
Definitions
13.1.2.1 For the purposes of these requirements. 13.1.2.2 Portable tank means a tank having a capacity of more than 450 litres whose shell is fitted with items of service equipment and structural equipment necessary for the transport of dangerous substances whose vapour pressure is not more than 3 bar (absolute) at a temperature of 50 C. It is a tank that has stabilizing members external to the shell and is not permanently secured on board the ship Its contents should not be loaded or discharged while the tank remains on board. It should be capable of being loaded and discharged without the need of removal of its structural equipment and be capable of being lifted on and off the ship when loaded. NOTES: 1 2 Portable tanks being in conformity with the requirements of this section are not considered to be intermediate bulk containers (IBCs); IBCs being in conformity with the requirements of section 26 of this General Introduction are not considered to be portable tanks.
13.1.2.3 Shell means the tank proper including openings and their closures but does not include service equipment (see 13.1.2.4). 13.1.2.4 Service equipment of a shell means filling and discharge venting safety heating and heat insulating devices and measuring instruments. 13.1.2.5 Structural equipment means the reinforcing fastening protective or stabilizing members of the shell. 13.1.2.6 Maximum allowable working pressure means a pressure that is not less than the higher of the following two pressures measured at the top of the tank while in operating position: 1 2 The highest effective pressure allowed in the shell during filling or discharge; or the maximum effective gauge pressure to which tanks for liquids should be designed which is the sum of the following partial pressures minus 1 bar;
2.1 The vapour pressure (in bar) at 65 C; and 2.2 the partial pressure (in bar) of air or other gases in the ullage space being determined by a maximum ullage temperature of 65 C and a liquid expansion due to the increase of the bulk mean temperature of tr - tf (tf filling temperature usually 15 C, t - 50 C the maximum mean bulk temperature). 13.1.2.7 Test pressure means the maximum gauge pressure at the top of a tank during a hydraulic test. 13.1.2.8 Design pressure means the pressure used according to a recognized pressure vessel code as mentioned in 13.1.3.11 for the design of every element of the tank. The design pressure should never be less than the highest of the following three pressures: 1 2 the working pressure as given in 13.1.2.6.1; or the sum of the pressure as given in 13.1.2.6.2 and the dynamic head pressure determined on the basis of the dynamic forces due to inertia specified in 13.1.4.1 minus 1.0 bar such a dynamic head pressure should never be taken to be less than 0.35 bar; or the required test pressure divided by 1.5.
13.1.3.11 Tanks should be designed manufactured and tested in accordance with a recognized pressure vessel code taking into account the design pressure as defined in 13.1.2.8. 13.1.3.12 Tanks should be of a design capable of being stress analysed mathematically or experimentally by resistance strain gauges or by any other acceptable method. 13.1.3.13 Tanks should be designed and manufactured to withstand a test pressure equal to at least 1.5 times the maximum allowable working pressure. However the test pressure should never be lower than 1.5 bar. Specific requirements are laid down for various substances authorized to be carried in tanks in the appendix to this subsection. Attention is also drawn to the minimum shell thickness requirements specified in 13.1.5.1 to 13.1.5.8. 13.1.3.14 Tanks without vacuum relief valves should be designed to withstand an external pressure at least 0.4 bar above the internal pressure. Tanks equipped with vacuum relief valves should be designed to withstand an external overpressure of 0.21 bar or greater and should have their vacuum relief valve set to relieve at minus (-) 0.21 bar except that a greater negative setting may be utilized provided the external design pressure is not exceeded. All vacuum relief valves used on tanks for the transport of liquids with flashpoints below 61 C (c.c.) should be equipped with a flame trap. 13.1.3.15 Tanks intended to contain certain dangerous substances should be provided with additional protection which may take the form of additional thickness of the shell or a higher test pressure the additional thickness or higher test pressure being determined in the light of the dangers inherent in the substances concerned. The requirements for each substance are given in the list in the appendix to this subsection. 13.1.4 13.1.4.1 Design criteria Tanks and their fastenings should under the maximum permissible load be capable of absorbing the following dynamic forces: 1 in the direction of travel twice the total mass; 2 horizontally at right angles to the direction of travel the total mass (where the direction of travel is not clearly determined the maximum permissible load should be equal to twice the total mass); 3 vertically upwards the total mass; and 4 vertically downwards twice the total mass (total loading including the effect of gravity). 13.1.4.2 Under each of these loads the safety factors to be observed for the primary combined stress should be as follows: 1 for metals having a clearly defined yield point a safety factor of 1.5 in relation to the determined yield stress; or 2 for metals with no clearly defined yield point a safety factor of 1.5 in relation to the guaranteed 0.2% (1.0% for austenitic steels) proof stress. Note: The above loads do not give rise to an increase in the pressure in the vapour space.
13.1.4.3 At the test pressure the membrane stress in the shell should conform to the material-dependent limitations prescribed below: 1 for metals and alloys exhibiting a clearly defined yield point or characterized by a guaranteed conventional yield stress Re (generally 0.2% proof stress, for austenitic steels 1.0% proof stress) the membrane stress should not exceed 0.75Re or 0.50Rm, whichever is lower; 2 In the case of steel, the elongation at fracture in per cent should not be less than 10000/Rm, where Rm is in N/mm2, with an absolute minimum of 20% based on a standard gauge length of 50 mm In the case of aluminium, the elongation at fracture, in per cent should not be less than 10000/6Rm, where Rm is in N/mm2 with an absolute minimum of 12%. 13.1.4.4 The specimens used to determine the elongation at fracture should be taken transversely to the direction of rolling and be so secured that,
L0 = 5 d
or
LO = 5.65 A
where Lo = gauge length of the specimen before the test; d = diameter; and A = cross-sectional area of the test specimen.
13.1.5
13.1.5.1 13.1.5.2
Minimum shell thickness

The minimum shell thickness referred to in this subsection may be used only if design criteria calculations do not indicate that a greater thickness is required. The cylindrical portions and ends of tanks should have a thickness of not less than that determined by the following formula*.
e=
where e Rm A C C
C Rm A
= minimum required thickness of the metal to be used, in mm; 2 = guaranteed minimum tensile strength of the metal to be used, in N/mm ; = guaranteed minimum elongation (as a percentage) of the metal to be used on fracture under tensile stress, see 13.1.4.3; = 107 (equivalent to 5 mm mild steel) for tanks intended for the transport of powdery or granular solid substances and for tanks of not more than 1.80 m in diameter intended for the transport of liquids or = 128 (equivalent to 6 mm mild steel) for tanks of more than 1.80 m in diameter.
* The constant C is derived from the following formula
e 3 Rm A = e0 3 Rm 0 A0 C = e0 3 Rm0 A0
.
, where the sub-index 'o' refers to
mild steel and the part of the equation without sub-index 'o' refers to the metal used. The relationship with mild steel as employed by this Code is attached to the constant C where
13.1.1.9.3 The shell and items of equipment of each tank should be inspected and tested either together or separately first before being put into service (initial inspection and test) and thereafter at no more than five year intervals (periodic inspection and test). The initial inspection and test should include a check of the design characteristics an internal and external examination and a hydraulic pressure test. If the shell and equipment have been pressure tested separately they should together be subjected after assembly to a leakage test. The periodic inspections and tests should include an internal and external examination and as a general rule a pressure test: 1 Sheathing thermal insulation and the like should be removed only to the extent required for reliable appraisal of the tanks condition. The initial and periodic pressure tests should be carried out by the competent authority at the test pressure indicated on the data plate of the tank except in cases where periodic tests at lower test pressures are authorized; 2 The tank should be inspected for corroded areas dents or other conditions which indicate weakness that might render the tank unsafe in transport and while under pressure for leakage. If any evidence of such unsafe condition is discovered the tank should not be placed in or returned to service until it has been repaired and the test repeated has been passed. 13.1.1.9.4 Before tanks are put into service and thereafter at intervals midway between the five yearly inspection and tests specified in 13.1.1.9.3 the following tests and inspections should be performed: 1 a leakage test where required; 2 a test of satisfactory operation of all service equipment; and 3 an internal and external inspection of the tanks and their fittings with due regard to the substances transported. 13.1.1.9.5 The 2.5 year (midway) inspection and test may be carried out within 3 months of the specified date. The date of the 2.5 year inspection should be durably marked on or as near as possible to the metal identification plate required in 13.1.20.1. When marking is not done on the plate the characters should be at least 32 mm in height and of a contrasting colour to the tank. 13.1.19.6 The 2.5 year internal inspections may be waived or substituted for by other test methods by the competent authority in the case of tanks intended for dedicated transport. A portable tank may not be filled and offered for transport after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 13.1.19.3 and 13.1.19.4/13.1.15.3 and 13.1.15.4/13.2.13.3 and 13.2.13.4. However a portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection In addition a portable tank may be transported after the date of expiry of the last periodic test and inspection: 1 After emptying but before cleaning, for purposes of performing the next required test and inspection prior to refilling; and 2 Unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test and inspection in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this authorization should be entered in the dangerous goods shipping document. 13.1.19.7 When the tank is damaged it should be so repaired as to comply with these recommendations.
13.1.19.8 In all cases where cutting burning or welding operations on the shell of the tank have been effected that work should be to the approval of the competent authority and a hydrostatic test to at least the original test pressure should be carried out. 13.1.19.9 The certificate and the test report required under 13.1.19.1 and the certificate showing the results of the initial hydrostatic test for each tank issued by the competent authority or its approved inspecting agency should be retained by the authority or agency and the owners during the time the tank is in service. As a minimum the certificate issued under 13.1.19.1 should provide the information required in 13.1.20.1.
IMDG CODE - PAGE 0072a (page 0073 follows) Amdt. 29-98
(This page intentionally blank)
13.1.20 13.1.20.1
Marking Every tank should be fitted with a corrosion resistant metal plate permanently attached in a place readily accessible for inspection. At least the following particulars should be marked on the plate in characters at least 3 mm in height by stamping engraving embossing or any similar method. If for reasons of tank arrangements the plate cannot be permanently attached to the shell the shell should be marked with at least those particulars required by a recognized pressure vessel code in a manner prescribed by that code.
The plate should be kept free of paint to ensure that the markings will be legible at all times. Country of manufacture IMO tank type no Manufacturers name or mark Registration number Year of manufacture Test pressure Maximum allowable working pressure Water capacity at 20 C (The water capacity should be established to within 1% by practical test rather than by calculation) Maximum gross mass Original hydrostatic test date and witness identification Code to which tank is designed Metallurgic design temperature (only if above+ 50 C or below -20 C) Maximum allowable working pressure for coils (where coils used) Tank material Equivalent thickness in mild steel Lining material (if any) Capacity of each compartment (in compartmented tanks) Month year and test pressure of most recent periodic test month Stamp of expert who carried out most recent test year (bar) / (MPa)* (litres) (mm) (bar) / (MPa)* (kg) (bar) / (MPa)* (bar) / (MPa)* (litres) Approval country Approval number
* The unit used should be marked
13.1.55.2 The following requirements apply to tanks intended for the transport of organic peroxides (type F) with a SelfAccelerating Decomposition Temperature (SADT) of 55 C or more In case of conflict, these requirements prevail over 13.1 to 13.1.26. Emergencies to be taken into account are the self accelerating decomposition of the organic peroxide and the fire engulfment as described in 13.1.55.8. 13.1.55.3 Formulations of organic peroxides transported in portable tanks with an SADT less than 55 C have to be subjected to the temperature control requirements given in section 21 of this General Introduction. The additional requirements for transport in tanks of organic peroxides with an SADT less than 55 C should be specified by the competent authority of the country of origin and notification thereof should be sent to the competent authority of the country of destination. 13.1.55.4 Tanks should be designed for a test pressure of at least 0.4 MPa (4 bar). 13.1.55.5 Tanks should be fitted with temperature-sensing devices. 13.1.55.6 Tanks should be fitted with pressure relief devices and emergency relief devices. Vacuum-relief devices may also be used. Pressure relief devices should operate at pressures determined according to both the properties of the organic peroxide and the construction characteristics of the tank. Fusible elements are not allowed in the shell of the tank. 13.1.55.7 The pressure-relief devices should consist of spring loaded valves fitted to prevent significant build-up within the tank of the decomposition products and vapours released at a temperature of 50 C. The capacity and start-todischarge pressure of the relief valves should be based on the results of the tests specified in 13.1.55.1. The start to discharge pressure should however in no case be such that liquid would escape from the valve or valves if the tank is overturned. 13.1.55.8 The emergency-relief devices may be of the spring-loaded or frangible types designed to vent all the decomposition products and vapours evolved during a period of not less than one hour of complete fire-engulfment as calculated by the following equations.
q = 70961 F A0.82
where q = heat absorption [W];
2 A = wetted area [m ];
F = insulation factor [-]; F = 1 for non-insulated vessels; or for insulated vessels
F=
where
U(923 Tpo) 47032
1 1 K = heat conductivity of insulation layer (W m K ];
L = thickness of insulation layer [m];

2 1 U - K/L = heat transfer coefficient of the insulation [W m K ];
Tpo = temperature of peroxide at relieving conditions [K].
The start-to-discharge pressure of the emergency-relief device (s) should be higher than that specified in 13.1.55.7 and based on the results of the tests referred to in 13.1.55.1. The emergency-relief devices should be dimensioned in such a way that the maximum pressure in the tank never exceeds the test pressure of the tank. Note: An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria. 13.1.55.9 For insulated tanks the capacity and setting of emergency relief device or devices should be determined assuming a loss of insulation of 1% of the surface area.
13.1.55.10 Vacuum-relief devices and spring-loaded valves should be provided with flame arresters. Due attention should be paid to the reduction of the relief capacity caused by the flame arrester. 13.1.55.11 Service equipment such as valves and external piping should be so arranged that no organic peroxide remains in them after filling of the tank. 13.1.55.12 Tanks may be either insulated or protected by a sun shield. If the SADT of the organic peroxide in the tank is 55C or less, or the tank is constructed of aluminium, the tank should be completely insulated. The outer surface should be finished in white or bright metal. 13.1.55.13 The degree of filling should not exceed 90% at 15 C.
13.1.55.14 The marking as required in 13.1.20.2 should include the UN Number (UN No.) and the correct technical name with the approved concentration of the organic peroxide concerned. 13.1.60 Special requirements relating to tanks for the transport of toxic substances (class 6.1)
13.1.60.1 Reference should be made to the appendix to this subsection setting out the special requirements for individual substances of this class. 13.1.70 Special requirements relating to tanks for the transport of radioactive materials (class 7)
13.1.70.1 With the approval of the competent authority of the country of origin tanks may be used for the transport of radioactive materials listed in section 12 of the introduction to class 7 under the provisions of schedules 1,5,6,9,10 and 11 except uranium hexafluoride. 13.1.70.2 In addition to the requirements of this section the provisions of the appropriate class 7 schedule should be applied. 13.1.70.3 The degree of filling for tanks should not exceed 90% or alternatively any other value approved by the competent authority. 13.1.70.4 Tanks used for the transport of radioactive material should not be used for the transport of other goods. 13.1.80 Special requirements relating to tanks for the transport of corrosive substances (class 8)
13.1.80.1 The following general requirements relate particularly to tanks for the transport of corrosive substances (class 8). 13.1.80.2 The pressure relief devices of tanks used for the transport of class 8 substances should be inspected at intervals not exceeding one year. 13.1.80.3 Reference should be made to the appendix to this subsection setting out special requirements for individual substances of this class. 13.1.90 Special requirements relating to tanks for the transport of marine pollutants included in class 9 13.1.90.1 A tank used for the transport of an ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., MARINE POLLUTANT, UN No. 3082, should be at least a type 2 tank as defined in 13.1.2.14.
(s): (t): (u): (v): (w): (x):
No subsidiary risk label of class 8 required for concentrations below 80%. Maximum quantity per portable tank 2, 000 kg, loaded and unloaded in the molten state, transported as solid. When transported under heated conditions, the heating device should be fitted outside the shell. To be carried under special temperature conditions - see relevant individual schedule. Special filling limits are to be observed. The tank should not be filled to more than 88% of its capacity at any time during transport. The portable tank may be fitted with a device located under maximum filling conditions in the vapour space of the shell to prevent the build-up of excess pressure due to the slow decomposition of the substance transported. This device should also prevent an unacceptable amount of leakage of liquid in the case of overturning or entry of foreign matter into the tank. This device should be approved by the competent authority or its authorized body.
STOWAGE REQUIREMENTS
For stowage requirements, see individual schedules and section 14 of this General Introduction.
Minimum shell thickness in mild steel
9 8 mm 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 6 mm 6 mm 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class
Subsidiary risk label

4 Toxic Flam Iiq. Toxic Flam Iiq. Toxic Toxic Corrosive Corrosive
IMO tank type

5 1 1 1 1 1 2 1 1 1 1 1 2 2 2 2 1 2 2 1 2 1 1 2 2 1 2
Minimum Type of test pres- pressure- Bottom sure in relief openings bar devices
6 6.0 2.65 6.0 2.65 2.65 1.5 4.0 4.0 4.0 4.0 4.0 1.5 1.5 1.5 1.5 4.0 1.5 1.5 2.65 1.5 2.65 2.65 1.5 1.5 2.65 1.5 7 NF N N N N N NF NF NF NF NF N N N N N N N N N N N N N N N 8 C A B A A A C C C C C A A A A B A A B A B B A A B A
Special requirements
10 (a) (a), (b) (b) (b) (b) (b)
1 1052 1088 1089 1090 1091 1091 1092 1093 1098 1099 1100 1104 1105 1106 1107 1108 1109 1110 1111 1112 1113 1114 1120 1123 1125 1126
2 HYDROGEN FLUORIDE, ANHYDROUS ACETAL ACETALDEHYDE ACETONE or ACETONE SOLUTIONS ACETONE OILS (1) ACETONE OILS (2) ACROLEIN, INHIBITED ACRYLONITRILE, INHIBITED ALLYL ALCOHOL ALLYL BROMIDE ALLYL CHLORIDE AMYL ACETATES PENTANOLS AMYLAMINE AMYL CHLORIDE 1-PENTENE AMYL FORMATES normal-AMYL METHYL KETONE AMYL MERCAPTANS AMYL NITRATES AMYL NITRITE BENZENE BUTANOLS BUTYL ACETATES normal-BUTYLAMINE 1-BROMOBUTANE
3 8 3.1/3.2 3.1 3.1/3.2 3.2 3.2 6.1 3.2 6.1 3.2 3.1 3.3 3.2/3.3 3.2/3.3 3.2 3.1 3.3 3.3 3.2 3.3 3.1/3.2 3.2 3.2/3.3 3.2/3.3 3.2 3.2
IMDG CODE - PAGE 0087 (first of fourty nine pages) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Toxic Flam Iiq. Flam Iiq. Corrosive
IMO tank type

5 1 2 1 2 1 1 2 2 1 1 2 1 2 1 1 1 1 2 2 2 1 2 2 1 1 2
Minimum test pressure in bar

6 2.65 1.5 2.65 1.5 4.0 2.65 1.5 1.5 6.0 2.65 1.5 2.65 1.5 4.0 6.0 2.65 4.0 1.5 1.5 1.5 4.0 1.5 1.5 4.0 6.0 1.5
Type of pressure- Bottom relief openings devices

7 N N N N NF N N N NF N N N N NF N N N N N N N N N N N N 8 B A B A C A A A C B A A A C B B B A A A B A A B C A
10 (a), (b) (b)
1 1127 1128 1129 1130 1131 1133 1133 1134

1135
2 CHLOROBUTANES normal-BUTYL FORMATE BUTYRALDEHYDE CAMPHOR OIL CARBON DISULPHIDE ADHESIVES (1) ADHESIVES (2) CHLOROBENZENE ETHYLENE CHLOROHYDRIN COAL TAR DISTILLATES, FLAMMABLE (1) COAL TAR DISTILLATES, FLAMMABLE (2) COATING SOLUTION (1) COATING SOLUTION (2) CROTONALDEHYDE, STABILIZED CROTONYLENE CYCLOHEXANE CYCLOPENTANE DECAHYDRONAPHTHALENES (cis-, trans-) DIACETONE ALCOHOL DIBUTYL ETHERS 1,2-DICHLOROETHYLENE DICHLOROPENTANES ETHYLENE GLYCOL DIETHYL ETHER DIETHYLAMINE DIETHYL ETHER DIETHYL KETONE
3 3.1/3.2 3.2 3.2 3.3 3.1 3.1/3.2 3.2/3.3 3.3 6.1 3.2 3.2/3.3 3.1/3.2 3.2/3.3 6.1 3.1 3.1 3.1 3.3 3.2/3.3 3.3 3.2 3.3 3.3 3.1 3.1 3.2
1136 1136 1139 1139 1143 1144 1145 1146 1147 1148 1149 1150 1152 1153 1154 1155 1156
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Corrosive Corrosive Corrosive Corrosive Flam liq. Corrosive
IMO tank type

5 2 1 1 1 1 1 1 1 1 1 1 1 1 2 2 2 2 2 2 1 2 2 2 2

6 1.5 2.65 2.65 4.0 6.0 2.65 4.0 4.0 4.0 2.65 2.65 4.0 2.65 1.5 1.5 1.5 1.5 1.5 1.5 2.65 1.5 1.5 1.5 1.5

7 N N N N N N N NF N N N N N N N N N N N N N N N N 8 A B B B B B C C B B B B A A A A A B A B A A A A
10 (b) (b)
1 1157 1158 1159 1160 1160 1161 1162 1163 1164 1165 1166 1167 1169 1169 1170 1171 1172 1173 1175 1176 1177 1178 1179 1180 DIISOBUTYL KETONE DIISOPROPYLAMINE DIISOPROPYL ETHER
3 3.3 3.2 3.1 3.1/3.2 3.1 3.2 3.2 6.1 3.1 3.2 3.2 3.1 3.2 3.2/3.3 3.2/3.3 3.3 3.3 3.2 3.2 3.2 3.3 3.2 3.2 3.3
DIMETHYLAMINE, AQUEOUS SOLUTION (up to and including 40%) DIMETHYLAMINE, AQUEOUS SOLUTION (>40% TO 60%) DIMETHYL CARBONATE DIMETHYLDICHLOROSILANE DIMETHYLHYDRAZINE, UNSYMMETRICAL DIMETHYL SULPHIDE DIOXANE DIOXOLANE DIVINYL ETHER, INHIBITED EXTRACTS AROMATIC, LIQUID (1) EXTRACTS AROMATIC, LIQUID (2) ETHANOL and ETHANOL SOLUTIONS ETHYLENE GLYCOL MONOETHYL ETHER ETHYLENE GLYCOL MONOETHYL, ETHER ACETATE ETHYL ACETATE ETHYLBENZENE ETHYL BORATE 2-ETHYLBUTYL ACETATE 2-ETHYLBUTYRALDEHYDE ETHYL BUTYL ETHER ETHYL BUTYRATE
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Corrosive Flam Iiq. Corrosive Corrosive Corrosive Corrosive Corrosive
IMO tank type

5 1 2 1 2 1 2 2 1 1 1 1 2 2 1 1 1 1 1 1 2 2 2
6 2.65 1.5 2.65 1.5 2.65 1.5 1.5 6.0 2.65 4.0 4.0 1.5 1.5 2.65 4.0 6.0 2.65 4.0 2.65 1.5 1.5 1.5 7 N N N N N N N NF N N N N N N N NF N N N N N N 8 A A B A B A A C B B B A A B B B B B A A A A
10 (b) (b) (a) (b)
1 1288 1288 1289 1292 1293 1293 1294 1295 1296 1297 1298 1299 1300 1301 1302 1303 1304 1305 1306 1306 1307 1350 SHALE OIL (1) SHALE OIL (2)
3 3.2 3.2/3.3 3.2/3.3 3.3 3.2 3.2/3.3 3.2 4.3 3.2 3.1/3.2/ 3.3 3.1 3.3 3.2/3.3 3.2 3.1 3.1 3.2 3.2 3.2 3.2/3.3 3.2/3.3 4.1
SODIUM METHYLATE, SOLUTIONS in alcohols TETRAETHYL SILICATE TINCTURES MEDICINAL (1) TINCTURES MEDICINAL (2) TOLUENE TRICHLOROSILANE TRIETHYLAMINE TRIMETHYLAMINE, AQUEOUS, SOLUTION TRIMETHYLCHLOROSILANE TURPENTINE TURPENTINE SUBSTITUTE VINYL ACETATE, INHIBITED VINYL ETHYL ETHER, INHIBITED VINYLIDENE CHLORIDE, INHIBITED VINYL ISOBUTYL ETHER, INHIBITED VINYLTRICHLOROSILANE, INHIBITED WOOD PRESERVATIVES, LIQUID (1) WOOD PRESERVATIVES, LIQUID (2) XYLENES SULPHUR
9 10 mm 10 mm 6 mm 6 mm 6 mm 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 8 mm 6 mm 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5
UN No.
Substance
Class

4 Dangerous when wet Dangerous when wet Toxic Toxic Toxic Toxic Flam liq. Flam Iiq. Corrosive
IMO tank type

5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
6 10.0 10.0 4.0 4.0 4.0 2.65 2.65 2.65 4.0 4.0 2.65 4.0 4.0 4.0 4.0 4.0 4.0 4.0 2.65 4.0 4.0 4.0 4.0 4.0 7 N N N N N N N N NF NF N NF NF NF N N NF N N N N NF N N 8 C C C C C B B B C B B C C B B B C B A A B C B B
10 (a) (a) (m) (a), (m) (a), (m) (a), (b) (b) (b) (b)
1 1366 1370 1381 1422 1428 1445 1447 1470 1541 1545 1547 1553 1560 1569 1577 1578 1580 1590 1591 1593 1594 1595 1597 1598 DIETHYLZINC DIMETHYLZINC
3 4.2 4.2 4.2 4.3 4.3 5.1 5.1 5.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1
PHOSPHORUS, WHITE or YELLOW, UNDER WATER POTASSIUM SODIUM ALLOYS SODIUM BARIUM CHLORATE SOLUTION BARIUM PERCHLORATE SOLUTION LEAD PERCHLORATE SOLUTION ACETONE CYANOHYDRIN, STABILIZED ALLYL ISOTHIOCYANATE, STABILIZED ANILINE ARSENIC ACID, LIQUID ARSENIC TRICHLORIDE BROMOACETONE CHLORODINITROBENZENES, LIQUID CHLORONITROBENZENES, LIQUID CHLOROPICRIN DICHLOROANILINES, LIQUID ortho-DICHLOROBENZENE DICHLOROMETHANE DIETHYL SULPHATE DIMETHYL SULPHATE DINITROBENZENES, LIQUID DINITRO-o-CRESOL
9 13.1.5 6 mm 13.1.5 8 mm 13.1.5 6 mm 8 mm 8 mm 8 mm 8 mm 8 mm 13.1.5 6 mm 13.1.5 8 mm 8 mm 6 mm 13.1.5 6 mm 13.1.5 13.1.5
UN No.
Substance
Class

4 Toxic Toxic Oxidizing agent* Oxidizing agent
IMO tank type

5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
6 2.65 2.65 2.65 2.65 2.65 2.65 4.0 2.65 2.65 2.65 4.0 2.65 2.65 2.65 2.65 4.0 2.65 2.65 2.65 2.65 2.65 7 N N N N N N NF N N N NF N N N NF NF N N N N N 8 B B B C B B C C C C C A B A C C B B B C B
10 (c) (b) (b), (c) (c) (c) (X) (b), (c) (b), (c) (b) (b) (b)
1 1779 1780 1781 1782 1783 1784 1786 1787 1788 1789 1790 1791 1792 1793 1796 1798 1799 1800 1801 1802 1803 FORMIC ACID FUMARYL CHLORIDE
3 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8
HEXADECYLTRICHLOROSILANE HEXAFLUOROPHOSPHORIC ACID HEXAMETHYLENEDIAMINE SOLUTION HEXYLTRICHLOROSILANE HYDROFLUORIC ACID AND SULPHURIC ACID, MIXTURE HYDRIODIC ACID HYDROBROMIC ACID HYDROCHLORIC ACID (not more than 36% HCI) HYDROFLUORIC ACID HYPOCHLORITE SOLUTION IODINE MONOCHLORIDE ISOPROPYL ACID PHOSPHATE NITRATING ACID, MIXTURE NITROHYDROCHLORIC ACID NONYLTRICHLOROSILANE OCTADECYLTRICHLOROSILANE OCTYLTRICHLOROSILANE PERCHLORIC ACID not more than 50% acid PHENOLSULPHONIC ACID SOLUTION
* Not required if nitric acid content not more than 50%.
IMDG CODE - PAGE 0087m (page 0087n follows) Amdt. 29-98
9 6 mm 13.1.5 6 mm 6 mm 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 6 mm 8 mm 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 8 mm 6 mm
UN No.
Substance
Class

4 Corrosive Toxic Corrosive Flam Iiq. Oxidizing agent*
IMO tank type

5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1
6 2.65 2.65 2.65 4.0 2.65 2.65 2.65 2.65 2.65 2.65 2.65 2.65 4.0 2.65 2.65 2.65 2.65 2.65 2.65 7 N N N NF N N N N N N N N NF N N N N NF N 8 B A B C B B B B A B B C C B A B A C B
10 (b) (b) (c) (a) (c)
1 1804 1805 1808 1809 1810 1811 1812 1814 1814 1815 1816 1817 1818 1819 1819 1824 1824 1826 1827
2 PHENYLTRICHLOROSILANE PHOSPHORIC ACID, LIQUID PHOSPHORUS TRIBROMIDE PHOSPHORUS TRICHLORIDE PHOSPHORUS OXYCHLORIDE POTASSIUM HYDROGENDIFLUORIDE, SOLUTION POTASSIUM FLUORIDE, SOLUTION POTASSIUM HYDROXIDE, SOLUTION (Packaging group II) POTASSIUM HYDROXIDE, SOLUTION (Packaging group III) PROPIONYL CHLORIDE PROPYLTRICHLOROSILANE PYROSULPHURYL CHLORIDE SILICON TETRACHLORIDE SODIUM ALUMINATE SOLUTION (Packaging group II) SODIUM ALUMINATE SOLUTION (Packaging group III) SODIUM HYDROXIDE, SOLUTION (Packaging group II) SODIUM HYDROXIDE, SOLUTION (Packaging group III) NITRATING ACID, MIXTURE, SPENT STANNIC CHLORIDE, ANHYDROUS
3 8 8 8 6.1 8 8 6.1 8 8 3.2 8 8 8 8 8 8 8 8 8
* Not required if nitric acid content not more than 50%.
IMDG CODE - PAGE 0087n (page 0087o follows) Amdt. 28-96
9 8 mm 8 mm 8 mm 8 mm 8 mm 13.1.5 8 mm 13.1.5 8 mm 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Toxic Flam liq.*
IMO tank type

5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 2
6 4.0 4.0 2.65 4.0 2.65 2.65 4.0 2.65 4.0 2.65 2.65 2.65 2.65 2.65 2.65 2.65 1.5 2.65 1.5 7 NF NF N NF N N NF N NF NF NF N N N N N N N N 8 C C C C C B C B C C C A B B A B A A A
10 (c) (c), (f), (u), (v), (w) (c) (c) (c) (c) (b), (c) (b)
1 1828 1829 1830 1831 1832 1833 1834 1835 1836 1837 1838 1840 1843 1846 1848 1849 1862 1863 1863 1865 1866 1866 SULPHUR CHLORIDES
3 8 8 8 8 8 8 8 8 8 8 8 8 6.1 6.1 8 8 3.2 3.1/3.2 3.2/3.3 3.2 3.1/3.2 3.2/3.3
SULPHUR TRIOXIDE, INHIBITED or STABILIZED SULPHURIC ACID with more than 51% acid SULPHURIC ACID, FUMING SULPHURIC ACID, SPENT SULPHUROUS ACID SULPHURYL CHLORIDE TETRAMETHYLAMMONIUM HYDROXIDE (solutions) THIONYL CHLORIDE THIOPHOSPHORYL CHLORIDE TITANIUM TETRACHLORIDE ZINC CHLORIDE SOLUTION AMMONIUM DINITRO-ortho-CRESOLATE, aqueous SOLUTION CARBON TETRACHLORIDE PROPIONIC ACID SODIUM SULPHIDE, HYDRATED with at least 30% water (liquid) ETHYL CROTONATE FUEL AVIATION TURBINE ENGINE (1) FUEL AVIATION TURBINE ENGINE (2) normal-PROPYL NITRATE RESIN SOLUTION, flammable (1) RESIN SOLUTION, flammable (2)
Prohibited in tanks
1 2 2.65 1.5 N N A A 13.1.5 13.1.5
* If flashpoint 61C c.c. or below.
IMDG CODE - PAGE 0087o (page 0087p follows) Amdt. 28-96
9 8 mm 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 8 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 6 mm 13.1.5 6 mm 13.1.5 13.1.5
UN No.
Substance
Class

4 Corrosive Flam Iiq. Corrosive
IMO tank type

5 1 1 1 1 1 1 2 1 1 1 1 2 2 1 1 2 1 2 1 2 1 1 1 1 1

6 2.65 2.65 2.65 4.0 4.0 6.0 1.5 2.65 2.65 2.65 2.65 1.5 1.5 2.65 2.65 1.5 2.65 1.5 6.0 1.5 4.0 2.65 2.65 2.65 6.0

7 N N N N NF NF N N N N N N N N N N N N NF N NF N N N N 8 C B A B B C A C A C B A A B B A B A C A C C B B A
10 (c) (b) (b) (b) (c) (x) (b) (b) (b)
1 1873 1886 1887 1888 1891 1892 1897 1898 1902 1906 1908 1914 1915 1916 1917 1918 1919 1920 1921 1922 1935 1938 1939 1940 1941
2 PERCHLORIC ACID, with more than 50% but not more than 72% acid , by mass BENZYLIDENE CHLORIDE BROMOCHLOROMETHANE CHLOROFORM ETHYL BROMIDE ETHYLDICHLOROARSINE TETRACHLOROETHYLENE ACETYL IODIDE DIISOOCTYL ACID PHOSPHATE SLUDGE ACID CHLORITE SOLUTION BUTYL PROPIONATES CYCLOHEXANONE 2,2-DICHLORODIETHYL ETHER ETHYL ACRYLATE, INHIBITED ISOPROPYLBENZENE METHYL ACRYLATE, INHIBITED NONANES PROPYLENEIMINE, INHIBITED PYRROLIDINE CYANIDE SOLUTION, N.O.S. BROMOACETIC ACID SOLUTION PHOSPHORUS OXYBROMIDE THIOGLYCOLIC ACID DIBROMODIFLUOROMETHANE
3 5.1 6.1 6.1 6.1 6.1 6.1 6.1 8 8 8 8 3.3 3.3 6.1 3.2 3.3 3.2 3.3 3.2 3.2 6.1 8 8 8 9
IMDG CODE - PAGE 0087p (page 0087q follows) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Toxic Toxic Toxic Toxic Flam Iiq. Dangerous when wet
IMO tank type

5 1 1 2 1 1 2 2 1 1 1 2
6 2.65 2.65 1.5 2.65 2.65 1.5 1.5 4.0 4.0 2.65 1.5 7 N N N N N N N N NF N N 8 B B A B B A A C C B A
10 (j) (j) (b), (e) (b), (j) (I)
1 1986 1987 1987 1988 1989 1989 1990 1991 1992 1993 1993 1994 1999 2003
2 ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLS, N.O.S. ALCOHOLS, N.O.S. ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. ALDEHYDES, N.O.S. ALDEHYDES, N.O.S. BENZALDEHYDE CHLOROPRENE, INHIBITED FLAMMABLE LIQUID, TOXIC, N.O.S. FLAMMABLE LIQUID, N.O.S. FLAMMABLE LIQUID, N.O.S. IRON PENTACARBONYL TARS, LIQUID METAL ALKYLS, WATER-REACTIVE, N.O.S. or METAL ARYLS, WATER-REACTIVE, N.O.S. HYDROGEN PEROXIDE, AQUEOUS, SOLUTION with not less than 20% but not more than 60% hydrogen peroxide (stabilized as necessary) HYDROGEN PEROXIDE, STABILIZED, or AQUEOUS SOLUTION, STABILIZED, with more than 60% hydrogen peroxide CHLOROANILINES, SOLID CHLOROANILINES, LIQUID CHLOROPHENOLS, LIQUID CRESYLIC ACID
3 3.1/3.2/ 3.3 3.2 3.3 3.1/3.2/ 3.3 3.1/3.2 3.3 9 3.1 3.1/3.2/ 3.3 3.1/3.2 3.3 6.1 3.2/3.3 4.2
Prohibited in tanks
3 1 1.5 10.0 N N A C 13.1.5 10 mm (a)
2014
5.1
Corrosive
4.0
13.1.5
(e), (x)
2015 2018 2019 2021 2022
5.1 6.1 6.1 6.1 6.1
Corrosive Corrosive
1 1 1 1 1
4.0 4.0 4.0 2.65 2.65
N N N N N
C B B A B
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
(e), (x) (f) (b)
IMDG CODE - PAGE 0087q (page 0087r follows) Amdt. 29-98
9 13.1.5
UN No.
Substance
Class

4 Flam Iiq. Flam Iiq., Toxic Toxic Oxidizing agent* Oxidizing agent, Toxic Flam Iiq.
IMO tank type

5 1
6 4.0 7 N 8 B
10 (b)
1 2023 2029 EPICHLOROHYDRIN
3 6.1 8
HYDRAZINE, ANHYDROUS HYDRAZINE HYDRATE or HYDRAZINE AQUEOUS SOLUTION with not less than 37% but not more than 64% hydrazine, by mass NITRIC ACID, other than red fuming
Prohibited in tanks
1 4.0 N C 13.1.5 (b)
2030
2031
2.65
8 mm
(c)
2032 2038 2045 2046 2047 2048 2049 2050 2051 2052 2053 2054 2055 2056 2057 2058
NITRIC ACID, RED FUMING DINITROTOLUENES, LIQUID ISOBUTYRALDEHYDE CYMENES (ortho-, meta-, para-) DICHLOROPROPENES DICYCLOPENTADIENE DIETHYLBENZENES (ortho, meta-, para-) DIISOBUTYLENES, ISOMERIC, COMPOUNDS 2-DIMETHYLAMINOETHANOL DIPENTENE METHYL ISOBUTYL CARBINOL MORPHOLINE STYRENE MONOMER, INHIBITED TETRAHYDROFURAN TRIPROPYLENE VALERALDEHYDES
8 6.1 3.1 3.3 3.3 3.3 3.3 3.2 8 3.3 3.3 3.3 3.3 3.1/3.2 3.2/3.3 3.2
1 1 1 2 1 1 2 2 1 2 2 1 2 1 2 2
4.0 2.65 2.65 1.5 2.65 2.65 1.5 1.5 2.65 1.5 1.5 2.65 1.5 2.65 1.5 1.5
NF N N N N N N N N N N N N N N N
C B B A B A A A B A A B A B A A
8 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
(c)
* Packaging group I only.
IMDG CODE - PAGE 0087r (page 0087s follows) Amdt. 29-98
9 13.1.5 13.1.5 6 mm 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 6 mm 6 mm 13.1.5 13.1.5
UN No.
Substance
Class

4 Corrosive Toxic Flam liq. Toxic Toxic Flam Iiq.
IMO tank type

5 1 1 1 1 2 2 1 1 2 1 2 2 1 1 2 2 1 1 1 1 1 1 2 2
6 2.65 2.65 4.0 2.65 1.5 1.5 2.65 2.65 1.5 2.65 1.5 1.5 2.65 2.65 1.5 1.5 2.65 2.65 4.0 2.65 4.0 4.0 1.5 1.5 7 N N NF N N N N N N N N N N N N N N N NF N NF NF N N 8 B B C B A B B B A A A B A B A A B B C B C C B A
10 (f) (f)* (b) (b) (b) (b) (b) (b) (b)
1 2312 2313 2315 2317 2319 2320 2321 2322 2323 2324 2325 2326 2327 2328 2329 2330 2332 2333 2334 2335 2336 2337 2338 2339 PHENOL, MOLTEN PICOLINES
3 6.1 3.3 9 6.1 3.3 8 6.1 6.1 3.3 3.3 3.3 8 8 6.1 3.3 3.3 3.3 3.2 6.1 3.2 3.2 6.1 3.2 3.2
POLYCHLORINATED BIPHENYLS SODIUM CUPROCYANIDE, SOLUTIONS TERPENE HYDROCARBONS, N.O.S. TETRAETHYLENEPENTAMINE TRICHLOROBENZENES, LIQUID TRICHLOROBUTENE TRIETHYL PHOSPHITE TRIISOBUTYLENE 1,3,5-TRIMETHYLBENZENE TRIMETHYLCYCLOHEXYLAMINE TRIMETHYLHEXAMETHYLENEDIAMINES TRIMETHYLHEXAMETHYLENE DIISOCYANATE TRIMETHYL PHOSPHITE normal-UNDECANE beta-ACETALDEHYDE OXIME ALLYL ACETATE ALLYLAMINE ALLYL ETHYL ETHER ALLYL FORMATE PHENYL MERCAPTAN BENZOTRIFLUORIDE 2-BROMOBUTANE
* For gamma-PICOLINE only.
IMDG CODE - PAGE 0087w (page 0087x follows) Amdt. 28-96
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Corrosive Toxic Flam Iiq. Toxic, Corrosive Toxic Corrosive
IMO tank type

5 1 2 1 2 1 1 2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 2

6 2.65 1.5 2.65 1.5 2.65 2.65 1.5 2.65 2.65 2.65 2.65 2.65 2.65 2.65 4.0 4.0 2.65 2.65 2.65 2.65 2.65 6.0 1.5 1.5

7 N N N N N N N N N N N N N N N N N N N N N N N N 8 A A A A B B A B B B B A C B B B B B B B A C A A
10 (b), (c) (b) (b) (b) (b)
1 2340 2341 2342 2343 2344 2345 2346 2347 2348 2350 2351 2352 2353 2354 2356 2357 2358 2359 2360 2361 2362 2363 2364 2366
2 2-BROMOETHYL ETHYL ETHER 1-BROMO-3-METHYLBUTANE BROMOMETHYLPROPANES 2-BROMOPENTANE BROMOPROPANES 3-BROMOPROPYNE BUTANEDIONE BUTYL MERCAPTANS BUTYL ACRYLATES INHIBITED normal-BUTYL METHYL ETHER BUTYL NITRITES BUTYL VINYL ETHER, INHIBITED BUTYRYL CHLORIDE CHLOROMETHYL ETHYL ETHER 2-CHLOROPROPANE CYCLOHEXYLAMINE CYCLOOCTATETRAENE DIALLYLAMINE DIALLYL ETHER DIISOBUTYLAMINE 1,1-DICHLOROETHANE ETHYL MERCAPTAN PROPYLBENZENE DIETHYL CARBONATE
3 3.2 3.3 3.2 3.2 3.2/3.3 3.2 3.2 3.1/3.2 3.3 3.2 3.2/3.3 3.2 3.2 3.2 3.1 8 3.2 3.2 3.2 3.3 3.2 3.1 3.3 3.3
IMDG CODE - PAGE 0087x (page 0087y follows) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4
IMO tank type

5 2 2 1 1 1 1 2 1 1 1 1 1 1 1 1 1 2 2 1 1 1 1 1 1 1

6 1.5 1.5 2.65 6.0 2.65 2.65 1.5 4.0 2.65 4.0 2.65 2.65 2.65 2.65 4.0 2.65 1.5 1.5 2.65 2.65 2.65 4.0 2.65 2.65 2.65

7 N N N N N N N N N N N N N N NF N N N N N N NF N N N 8 A A B B B B A B A B B B B B C B A A B B B C B B B
10
1 2367 2368 2370 2371 2372 2373 2374 2375 2376 2377 2378 2379 2380 2381 2382 2383 2384 2385 2386 2387 2388 2389 2390 2391 2392
2 alpha-METHYLVALERALDEHYDE alpha-PINENE 1-HEXENE ISOPENTENES 1,2-DI(DIMETHYLAMINO)ETHANE DIETHOXYMETHANE 3,3-DIETHOXYPROPENE DIETHYL SULPHIDE 2,3-DIHYDROPYRAN 1,1-DIMETHOXYETHANE 2-DIMETHYLAMINOACETONITRILE 1,3-DIMETHYLBUTYLAMINE DIMETHYLDIETHOXYSILANE DIMETHYL DISULPHIDE DIMETHYLHYDRAZINE SYMMETRICAL DIPROPYLAMINE DI-normal-PROPYL ETHER ETHYL ISOBUTYRATE 1-ETHYLPIPERIDINE FLUOROBENZENE FLUOROTOLUENES FURAN 2-IODOBUTANE IODOMETHYLPROPANES IODOPROPANES
3 3.2 3.3 3.1 3.1 3.2 3.1/3.2 3.2 3.2 3.2 3.1/3.2 3.3 3.2 3.2 3.2 6.1 3.2 3.1/3.2 3.2 3.2 3.2 3.2 3.1 3.2 3.2 3.3
Toxic Corrosive Flam Iiq. Corrosive Corrosive
(b) (b) (b)
IMDG CODE - PAGE 0087y (page 0087z follows) Amdt. 28-96
9 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Corrosive Toxic Corrosive Flam Iiq. Toxic Flam Iiq. Corrosive Toxic
IMO tank type

5 2 1 1 1 2 1 1 2 1 1 2 1 2 2
6 1.5 2.65 2.65 2.65 1.5 4.0 2.65 1.5 4.0 2.65 1.5 4.0 1.5 1.5 7 N N N N N N N N NF N N N N N 8 A A C B A B B A B B A B A A
10 (b) (b) (b)
1 2393 2394 2395 2396 2397 2398 2399 2400 2401 2402 2403 2404 2405 2406 2407 2409 2410 2411 2412 2413 2414 2416 2426 2427 ISOBUTYL FORMATE ISOBUTYL PROPIONATE ISOBUTYRYL CHLORIDE
3 3.2 3.2 3.2 3.2 3.2 3.1 3.2 3.2 8 3.1 3.2 3.2 3.3 3.2 6.1 3.2 3.2 3.2 3.2 3.3 3.2 3.2 5.1 5.1
METHACRYLALDEHYDE, INHIBITED 3-METHYLBUTAN-2-ONE METHYL-tertiary-BUTYL ETHER 1-METHYLPIPERIDINE METHYL ISOVALERATE PIPERIDINE PROPANETHIOLS ISOPROPENYL ACETATE PROPIONITRILE ISOPROPYL BUTYRATE ISOPROPYL ISOBUTYRATE ISOPROPYL CHLOROFORMATE ISOPROPYL PROPIONATE 1,2,3,6-TETRAHYDROPYRIDINE BUTYRONITRILE TETRAHYDROTHIOPHENE TETRAPROPYL ORTHOTITANATE THIOPHENE TRIMETHYL BORATE AMMONIUM NITRATE, LIQUID (hot concentrated solution) POTASSIUM CHLORATE, AQUEOUS, SOLUTION
Prohibited in tanks
2 1 1 1 1 2 1 1 1 1.5 2.65 4.0 2.65 2.65 1.5 4.0 4.0 2.65 N N N N N N N NF N A B B A B B B B B 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 (b) (f), (n), (p)
IMDG CODE - PAGE 0087z (page 0087a1 follows) Amdt. 29-98
Minimum shell thickness In mild steel
9 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Flam Iiq. Corrosive Flam Iiq. Flam Iiq. Toxic
IMO tank type

5 1 1 2 1 1 1 1 1 1 2 2 2 2 2 1
6 6.0 2.65 1.5 2.65 2.65 4.0 2.65 2.65 2.65 1.5 1.5 1.5 1.5 1.5 2.65 7 NF N N N N N N N N N N N N N N 8 C B A B C B B B B B A A A A B
10 (b) (b)
1 2606 2607 2608 2610 2611 2612 2614 2615 2616 2617 2618 2619 2620 2621 2622 2626 2643 2644 2646 2650 2651 2653 2656 2661
2 METHYL ORTHOSILICATE ACROLEIN DIMER, STABILIZED NITROPROPANES TRIALLYLAMINE PROPYLENE CHLOROHYDRIN METHYL PROPYL ETHER METHALLYL ALCOHOL ETHYL PROPYL ETHERS TRIISOPROPYL BORATE METHYLCYCLOHEXANOLS, flammable VINYLTOLUENES, INHIBITED (ortho- meta-, para-) BENZYLDIMETHYLAMINE AMYL BUTYRATES ACETYL METHYL CARBINOL GLYCIDALDEHYDE CHLORIC ACID, AQUEOUS, SOLUTION with not more than 10% chloric acid METHYL BROMOACETATE METHYL IODIDE HEXACHLOROCYCLOPENTADIENE 1,1-DICHLORO-1-NITROETHANE 4,4'-DIAMINODIPHENYLMETHANE, molten or resolidified BENZYL IODIDE, molten or resolidified QUINOLINE HEXACHLOROACETONE
3 6.1 3.3 3.3 3.3 6.1 3.1 3.3 3.1 3.2/3.3 3.3 3.3 8 3.3 3.3 3.3 5.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1
Prohibited in tanks
1 1 1 1 1 1 1 1 2.65 4.0 4.0 2.65 2.65 2.65 2.65 2.65 N NF NF N N N N N B C C B B B B B 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 (b) (b) (f)
IMDG CODE - PAGE 0087e1 (page 0087f1 follows) Amdt. 28-96
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 8 mm
UN No.
Substance
Class

4
IMO tank type

5 1 1 2 1 1 1 1

6 2.65 2.65 1.5 2.65 2.65 4.0 2.65 2.65 2.65 2.65 2.65 4.0 2.65 2.65 2.65 1.5 1.5 2.65 4.0
Type of pressure relief devices

7 N N N N N N N N N N N N N N N N N N NF
Bottom openings
8 B B B B B B B A B B A B B B B B B B C
10
1 2662 2664 2667 2668 2669 2672 2677 2677 2679 2681 2681 2683 2684 2685 2686 2688 2689 2690 2692
2 HYDROQUINONE, LIQUID DIBROMOMETHANE BUTYLTOLUENES CHLOROACETONITRILE CHLOROCRESOLS, LIQUID AMMONIA SOLUTION (10%-35% ammonia) RUBIDIUM HYDROXIDE SOLUTION (Packaging group II) RUBIDIUM HYDROXIDE SOLUTION (Packaging group III) LITHIUM HYDROXIDE, SOLUTION CAESIUM HYDROXIDE, SOLUTION (Packaging group II) CAESIUM HYDROXIDE, SOLUTION (Packaging group III) AMMONIUM SULPHIDE, SOLUTION 3-(DIETHYLAMINO)PROPYLAMINE N,N-DIETHYLETHYLENEDIAMINE 2-DIETHYLAMINOETHANOL 1-CHLORO-3-BROMOPROPANE GLYCEROL-alpha-MONOCHLOROHYDRIN N-normal-BUTYLIMIDAZOLE BORON TRIBROMIDE
3 6.1 6.1 6.1 6.1 6.1 8 8
Flam Iiq.

(b) (b), (c)
8 8 8 8 8 3.3 8 8 6.1 6.1 6.1 8
1 1 1 1 1 1 1 1 2 2 1 1
Toxic Flam Iiq.* Corrosive Flam Iiq. Flam Iiq.
* If flashpoint 61 C c.c. or below.
IMDG CODE - PAGE 0087f1 (page 0087g1 follows) Amdt. 29-98
9 13.1.5 8 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4
IMO tank type

5 1 1 1 1 2 2 1 1

6 2.65 4.0 2.65 2.65 1.5 1.5 2.65 2.65

7 N NF N N N N N N 8 B c B B A A B B
10 (c)
1 2693 2699 2705 2707 2709 2710 2730 2732
2 BISULPHITES, AQUEOUS, SOLUTION, N.O.S. TRIFLUOROACETIC ACID 1-PENTOL DIMETHYLDIOXANES BUTYLBENZENES DIPROPYL KETONE NITROANISOLES, LIQUID NITROBROMOBENZENES AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. (1) AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. (2) AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Packaging group I) AMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. (Packaging group II) AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. N-normal-BUTYLANILINE BUTYRIC ANHYDRIDE
3 8 8 8 3.2/33 3.3 3.3 6.1 6.1
(f)
2733
3.1/3.2
Corrosive
4.0
13.1.5
(I)
2733
3.2/3.3
Corrosive
2.65
13.1.5
(I)
2734
Flam liq.
4.0
NF
6 mm

(j)
2734
Flam Iiq.
2.65
13.1.5
2735 2738 2739
8 6.1 8
1 1 2
2.65 2.65 1.5
N N N
B B B
13.1.5 13.1.5 13.1.5
IMDG CODE - PAGE 0087g1 (page 0087h1 follows) Amdt. 28-96
9
UN No.
Substance
Class

4 Flam Iiq. Corrosive Corrosive Flam Iiq. Corrosive Flam Iiq. Corrosive Corrosive Corrosive Flam Iiq. * Toxic Toxic
IMO tank type

5

6

7 8
10
1 2740 2743
2 normal-PROPYL CHLOROFORMATE normal-BUTYL CHLOROFORMATE
3 6.1 6.1
Prohibited in tanks
1 4.0 NF C 13.1.5 (b)
2744 2745 2746 2747 2748 2749 2750 2751 2752 2753 2754 2758 2760
CYCLOBUTYL CHLOROFORMATE CHLOROMETHYL CHLOROFORMATE PHENYL CHLOROFORMATE tertiary-BUTYLCYCLOHEXYL CHLOROFORMATE 2-ETHYLHEXYL CHLOROFORMATE TETRAMETHYLSILANE 1,3-DICHLOROPROPANOL-2 DIETHYLTHIOPHOSPHORYL CHLORIDE 1,2-EPOXY-3-ETHOXYPROPANE N-ETHYL-N-BENZYLTOLUIDINES, LIQUID N-ETHYLTOLUIDINES CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC
6.1 6.1 6.1 6.1 6.1 3.1 6.1 8 3.3 6.1 6.1 3.2 3.2
1 1 1 1 1 1 1 1 2 1 1 1 1
4.0 4.0 2.65 2.65 2.65 6.0 2.65 2.65 1.5 4.0 4.0 4.0 4.0
NF NF NF N NF N N N N N N NF NF
C C C B C C B B A B B C C
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
(b) (b) (b) (b) (b), (j) (b), (j)
2762
3.2
Toxic
4.0
NF
13.1.5
(b), (j)
2764
3.2
Toxic
4.0
NF
13.1.5
(b), (j)
IMDG CODE - PAGE 0087h1 (page 0087i1 follows) Amdt. 29-98
9 13.1.5
UN No.
Substance
Class

4 Toxic
IMO tank type

5 1
6 4.0 7 NF 8 C
10 (b), (j)
1 2772
2 THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC MERCURY BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 4-THIAPENTANAL ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOTIN COMPOUND, LIQUID, N.O.S. ACETIC ACID, GLACIAL or ACETIC ACID, SOLUTION more than 80% acid ACETIC ACID, SOLUTION, not less than 50% but not more than 80% acid , by mass (Packaging group II) ACETIC ACID, SOLUTION, more than 10% but less than 50% acid , by mass (Packaging group III) SULPHURIC ACID, with not more than 51% acid or BATTERY FLUID, ACID BATTERY FLUID ALKALI
3 3.2
2776
3.2
Toxic
4.0
NF
13.1.5
(b), (j)
2778 2780 2782 2784 2785 2787 2788 2789
3.2 3.2 3.2 3.2 6.1 3.2 6.1 8
Toxic Toxic Toxic Toxic Toxic Flam liq.*
1 1 1 1 1 1 1 1
4.0 4.0 4.0 4.0 2.65 4.0 4.0 2.65
NF NF NF NF N NF N N
C C C C B C B B
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
(b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j)
2790
2.65
13.1.5
2790
2.65
13.1.5
2796 2797
8 8
1 1
2.65 2.65
N N
C B
8 mm 13.1.5
(c)
IMDG CODE - PAGE 0087i1 (page 0087j1 follows) Amdt. 29-98
9 6 mm 6 mm 13.1.5
UN No.
Substance
Class

4
IMO tank type

5 1 1 1

6 2.65 2.65 4.0

7 N N N 8 B B B
10
1 2798 2799 2801
2 PHENYLPHOSPHORUS DICHLORIDE PHENYLPHOSPHORUS THIODICHLORIDE DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. (Packaging groups I and II) DYE, LIQUID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE, N.O.S. (Packaging group III) TOXIC LIQUID, ORGANIC, N.O.S. N-AMINOETHYLPIPERAZINE AMMONIUM HYDROGENDIFLUORIDE, SOLUTION AMMONIUM POLYSULPHIDE, SOLUTION (Packaging group II) AMMONIUM POLYSULPHIDE, SOLUTION (Packaging group III) AMYL ACID PHOSPHATE BUTYRIC ACID PHENOL SOLUTION (Packaging group II) PHENOL SOLUTION (Packaging group III) 2-CHLOROPYRIDINE ETHYL CHLOROTHIOFORMATE CAPROIC ACID 1,1,1-TRICHLOROETHANE PHOSPHOROUS ACID BISULPHATES, AQUEOUS SOLUTION VINYL BUTYRATE, INHIBITED ALDOL
3 8 8 8
2801 2810 2815 2817 2818 2818 2819 2820 2821 2821 2822 2826 2829 2831 2834 2837 2838 2839
8 6.1 8 8 8 8 8 8 6.1 6.1 6.1 8 8 6.1 8 8 3.2 6.1
Toxic Toxic Toxic Flam liq.
1 1 1 1 1 1 1 2 1 1 1 1 2 1 1 1 1 1
2.65 4.0 2.65 4.0 4.0 2.65 2.65 1.5 4.0 2.65 4.0 4.0 1.5 2.65 2.65 2.65 2.65 2.65
N N N N N N N N N N N N N N N N N N
A B A C B A A A B A B B B A B B A B
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5
(b), (j) (b), (c) (b) (b)
IMDG CODE - PAGE 0087j1 (page 0087k1 follows) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 10 mm 13.1.5 13.1.5 8 mm 13.1.5 13.1.5 13.1.5 8 mm 13.1.5 13.1.5 13.1.5 6 mm 8 mm 6 mm 13.1.5 6 mm 6 mm 6 mm
UN No.
Substance
Class

4 Toxic Toxic Flam Iiq. Toxic Toxic Toxic Toxic Corrosive Corrosive Corrosive
IMO tank type

5 2 1 1 1 1 2 1 1 2 2 1 1 1 1 1 1 1 1 1 1 1

6 1.5 2.65 2.65 10.0 2.65 1.5 2.65 2.65 1.5 1.5 2.65 4.0 4.0 2.65 4.0 4.0 4.0 2.65 6.0 4.0 4.0

7 N N N N N N N N N N NF N N NF NF NF NF N N N NF 8 A B B C B A C A A B C B B C C C C B C C C
10 (a) (b), (c) (b), (j) (b), (j) see 13.1.70 (k) (j), (k) (j), (k) (b), (k)
1 2840 2841 2842 2845 2849 2850 2851 2872 2873 2874 2879 2902 2903 2912 2920 2922 2922 2922 2924 2924 2927 BUTYRALDOXIME Dl-normal-AMYLAMINE NITROETHANE
3 3.3 3.3 3.3 4.2 6.1 3.3 8 6.1 6.1 6.1 8 6.1 6.1 7 8 8 8 8 3.1/3.2 3.2/3.3 6.1
PYROPHORIC LIQUID, ORGANIC, N.O.S. 3-CHLOROPROPANOL-1 PROPYLENE TETRAMER BORON TRIFLUORIDE DIHYDRATE DIBROMOCHLOROPROPANES N-N-Dl-normal-BUTYLAMINOETHANOL FURFURYI ALCOHOL SELENIUM OXYCHLORIDE PESTICIDE, LIQUID, TOXIC, N.O.S. PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S. (3) RADIOACTIVE MATERIALS, low specific activity (LSA), N.O.S. CORROSIVE LIQUID, FLAMMABLE, N.O.S. (2) (Packaging group II) CORROSIVE LIQUID, TOXIC, N.O.S. (Packaging group I) CORROSIVE LIQUID, TOXIC, N.O.S. (Packaging group II) CORROSIVE LIQUID, TOXIC, N.O.S. (Packaging group III) FLAMMABLE LIQUID, CORROSIVE, N.O.S. (1) FLAMMABLE LIQUID, CORROSIVE, N.O.S. (2) TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. (Packaging group II)
IMDG CODE - PAGE 0087k1 (page 0087l1 follows) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5
UN No.
Substance
Class

4 Flam Iiq. Corrosive Corrosive Flam Iiq. Toxic
IMO tank type

5 1 1 2 2 1 2 1 2 1 2 2 1 1 1 1 1

6 4.0 2.65 1.5 1.5 2.65 1.5 2.65 1.5 2.65 1.5 1.5 4.0 2.65 4.0 2.65 6.0

7 N N N N N N N N N N N N N NF N NF 8 B B A A B A B A B A A B B C B C
10 (b), (j) (a)
1 2929 2933 2934 2935 2936 2937 2941 2943 2945 2946 2947 2948 2949 2965 2966 2983
2 TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. (3) METHYL-2-CHLOROPROPIONATE ISOPROPYL-2-CHLOROPROPIONATE ETHYL-2-CHLOROPROPIONATE THIOLACTIC ACID alpha-METHYLBENZYL ALCOHOL, LIQUID FLUOROANILINES TETRAHYDROFURFURYLAMINE NMETHYLBUTYLAMINE 2-AMINO-5-DIETHYLAMINOPENTANE ISOPROPYL CHLOROACETATE 3-TRIFLUOROMETHYLANILINE SODIUM HYDROSULPHIDE, SOLUTION BORON TRIFLUORIDE DIMETHYL, ETHERATE THIOGLYCOL ETHYLENE OXIDE AND PROPYLENE OXIDE, MIXTURES, not more than 30% ethylene oxide HYDROGEN PEROXIDE, AQUEOUS SOLUTION, with not less than 8% but less than 20% hydrogen peroxide (stabilized as necessary) CHLOROSILANES, FLAMMABLE, CORROSIVE,
3 6.1 3.3 3.3 3.3 6.1 6.1 6.1 3.3 3.2 6.1 3.3 6.1 8 4.3 6.1 3.1
2984
5.1
2.65
13.1.5
(e), (x)
2985 2986 2987 2988 2991
N.O.S.
CHLOROSILANES, CORROSIVE, FLAMMABLE,
3.2 8 8 4.3 6.1
Corrosive Flam Iiq. Corrosive Flam Iiq. Flam Iiq.
1 1 1 1 1
4.0 4.0 4.0 4.0 4.0
NF NF N NF N
C C C C B
6 mm 6 mm 13.1.5 6 mm 13.1.5
(b) (b) (b), (j)
N.O.S.
CHLOROSILANES, CORROSIVE, N.O.S. CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S. CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3)
IMDG CODE - PAGE 0087l1 (page 0087m1 follows) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 13.1.5
UN No.
Substance
Class

4 Flam liq. Flam liq.
IMO tank type

5 1 1 1 1
6 4.0 4.0 4.0 4.0 7 N N N N 8 B B B B
10 (b), (j) (b), (j) (b), (j) (b), (j)
1 2992 2993 2994 2995
2 CARBAMATE PESTICIDE, LIQUID, TOXIC ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) ARSENICAL PESTICIDE, LIQUID, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) TRIAZINE PESTICIDE, LIQUID, TOXIC
3 6.1 6.1 6.1 6.1
2996
6.1
4.0
13.1.5
(b), (j)
2997
6.1
Flam liq.
4.0
13.1.5
(b), (j)
2998
6.1
4.0
13.1.5
(b), (j)
3005
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3)
6.1
Flam liq.
4.0
13.1.5
(b), (j)
3006
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC
6.1
4.0
13.1.5
(b), (j)
IMDG CODE - PAGE 0087m1 (page 0087n1 follows) Amdt. 29-98
9 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5 13.1.5
UN No.
Substance
Class

4 Flam liq. Flam liq. Flam Iiq. Flam Iiq. Flam Iiq. Flam Iiq. Toxic Flam Iiq. Toxic Flam Iiq.
IMO tank type

5 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1

6 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 2.65 4.0 4.0 4.0
Type of pressure relief devices

7 N N N N N N N N N N N N NF N NF NF N
Bottom openings
8 B B B B B P B B B B B B C B C C B
10 (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b), (j) (b) (b), (j) (b), (j)
1 3009 3010 3011 3012 3013 3014 3015 3016 3017 3018 3019 3020 3021 3022 3023 3024 3025
2 COPPER BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) COPPER BASED PESTICIDE, LIQUID, TOXIC MERCURY BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) MERCURY BASED PESTICIDE, LIQUID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3) ORGANOTIN PESTICIDE, LIQUID, TOXIC PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S. 1,2-BUTYLENE OXIDE, STABILIZED 2-METHYL-2-HEPTANETHIOL COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE (3)
3 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3.2 3.2 6.1 3.2 6.1
IMDG CODE - PAGE 0087n1 (page 0087o1 follows) Amdt. 28-96
9 13.1.5
UN No.
Substance
Class

4 Dangerous when wet Dangerous when wet Dangerous when wet Dangerous when wet Dangerous when wet Flam Iiq. Flam Iiq. Corrosive Dangerous when wet Toxic Flam Iiq.
IMO tank type

5 1
6 4.0 7 N 8 B
10 (b), (j)
1 3026
2 COUMARIN DERIVATIVE PESTICIDE, LIQUID, TOXIC METAL ALKYL HALIDES, WATER-REACTIVE, N.O.S. or METAL ARYL HALIDES, WATERREACTIVE, N.O.S. METAL ALKYL HYDRIDES, WATER-REACTIVE, N.O.S. or METAL ARYL HYDRIDES, WATERREACTIVE, N.O.S. ALUMINIUM ALKYLS ALUMINIUM ALKYL HALIDES MAGNESIUM ALKYLS CYCLOHEXYL MERCAPTAN 2-(2-AMINOETHOXY) ETHANOL normal-HEPTALDEHYDE NITROGLYCERIN SOLUTION IN ALCOHOL ALCOHOLIC BEVERAGES MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. VINYLPYRIDINES, INHIBITED ALUMINIUM ALKYL, HYDRIDES METHACRYLONITRILE, INHIBITED ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE,
3 6.1
3049
4.2
10.0
10 mm
(a)
3050
4.2
10.0
10 mm
(a)
3051 3052 3053 3054 3055 3056 3064 3065 3071 3073 3076 3079 3080
4.2 4.2 4.2 3.3 8 3.3 3.2 3.2/3.3 6.1 6.1 4.2 3.2 6.1
1 1 1 2 2 2
10.0 10.0 10.0 1.5 1.5 1.5
N N N N N N
C C C A B A
10 mm 10 mm 10 mm 13.1.5 13.1.5 13.1.5
(a) (a) (a)
Prohibited in tanks
2 1 1 1 1 1 1.5 4.0 2.65 10.0 4.0 4.0 N N N N NF N A B B C C C 13.1.5 13.1.5 13.1.5 10 mm 6 mm 13.1.5 (b) (b) (a) (b) (b)
N.O.S.
3082 3092 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 1-METHOXY-2-PROPANOL 9 3.3 2 2 1.5 1.5 N N A A 13.1.5 13.1.5
IMDG CODE - PAGE 0087o1 (page 0087p1 follows) Amdt. 29-98
9
UN No.
Substance
Class

4
IMO tank type

5

6

7 8
10
1 3109
2 ORGANIC PEROXIDE, TYPE F, LIQUID - tert-BUTYL HYDROPEROXIDE, not more than 72% with water - CUMYL HYDROPEROXIDE, not more than 90% with diluent type A - DI-tert-BUTYL PEROXIDE not more than 52% in diluent type B - ISOPROPYLCUMYL HYDROPEROXIDE not more than 72% in diluent type A - p-MENTHYL HYDROPEROXIDE, not more than 72% in diluent type A - PINANYL HYDROPEROXIDE, not more than 55% with diluent type A
52 52 52 52 52 52
Corrosive Corrosive Corrosive Corrosive Corrosive*
1 1 1 1 1 1
40 40 40 40 40 40
N N N N N N
B B B B B B
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
(q), (r) (q), (s) (q) (q) (q) (q)
3110
ORGANIC PEROXIDE, TYPE F, SOLID - DICUMYL PEROXIDE 52 1 40 N B 13.1.5 (q), (t)
3119
ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED - tert-BUTYL PEROXYACETATE, not more than 32% in diluent type B - tert-BUTYL PEROXY-2-ETHYLHEXANOATE, not more than 32% in diluent type B - tert-BUTYL PEROXYPIVALATE, not more than 27% in diluent type B - tert-BUTYL PEROXY-3,5,5TRIMETHYLHEXANOATE, not more than 32% in diluent type B - Dl-(3,5,5-TRIMETHYLHEXANOYL)PEROXIDE, not more than 38% in diluent type B 52 52 52 1 1 1 40 40 40 N N N B B B 13.1.5 13.1.5 13.1.5 (q) (q) (q)
52
40
13.1.5
(q)
52
40
13.1.5
(q)
* If concentration is greater than 56%.
IMDG CODE - PAGE 0087p1 (page 0087q1 follows) Amdt. 28-96
9
UN No.
Substance
Class

4
IMO tank type

5

6

7 8
10
1 3120 3145
2 ORGANIC PEROXIDE, TYPE F SOLID, TEMPERATURE CONTROLLED ALKYLPHENOLS, LIQUID, N.O.S. (including C2 to C12 homologues) HYDROGEN PEROXIDE AND PEROXYACETIC ACID MIXTURE, with acid (s), water and not more than 5% peroxyacetic acid, STABILIZED FLAMMABLE SOLID, ORGANIC, MOLTEN, N.O.S. PYROPHORIC ORGANOMETALLIC COMPOUND, WATER-REACTIVE, N.O.S. ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND DISPERSION, WATERREACTIVE, FLAMMABLE, N.O.S. CHLORATES INORGANIC, AQUEOUS SOLUTION,
2.65
13.1.5
(j)
3149
5.1
Corrosive
4.0
13.1.5
(e), (x)
3176 3203
4.1 4.2
Dangerous when wet
1 1
2.65 10.0
N N
C C
13.1.5 10 mm
(a), (f), (u) (a)
3207
4.3
Flam Iiq.
10.0
10 mm
(a)
3210 3211 3213 3214 3216 3218 3219 3246 3250
N.O.S.
PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. BROMATES INORGANIC, AQUEOUS SOLUTION,
5.1 5.1 5.1 5.1 5.1 5.1 5.1 6.1 6.1
Corrosive Corrosive
1 1 1 1 2 1 1 1 1
2.65 2.65 2.65 2.65 1.5 2.65 2.65 6.0 2.65
N N N N N N N NF N
B B B B B B B C C
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 6 mm 13.1.5
(b), (c) (f)
N.O.S.
PERMANGANATES INORGANIC, AQUEOUS SOLUTION, N.O.S. PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRATES, INORGANIC, AQUEOUS SOLUTION,
N.O.S.
NITRITES, INORGANIC, AQUEOUS SOLUTION,
N.O.S.
METHANESULPHONYL CHLORIDE CHLOROACETIC ACID, MOLTEN
IMDG CODE - PAGE 0087q1 (page 0087r1 follows) Amdt. 29-98
9
UN No.
Substance
Class

4
IMO tank type

5
6 7 8
10
2 ELEVATED, TEMPERATURE LIQUID, FLAMMABLE, N.O.S., with flashpoint above 61 C c.c. at or above its flashpoint ELEVATED TEMPERATURE LIQUID, N.O.S., at or above 100 C and below its flashpoint CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Packaging groups I and II) CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Packaging group III) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Packaging groups I and II) CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. (Packaging group III) CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Packaging groups I and II) CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Packaging group III) CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Packaging groups I and II) CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. (Packaging group III) ETHERS, N.O.S. (1) ETHERS, N.O.S. (2)
3256
3.3
1.5
13.1.5
(f)
3257 3264 3264
9 8 8
2 1 1
1.5 4.0 2.65
N N N
A B B
13.1.5 13.1.5 13.1.5
(f) (j), (k) (k)
3265
4.0
13.1.5
(j), (k)
3265
2.65
13.1.5
(k)
3266
4.0
13.1.5
(j), (k)
3266
2.65
13.1.5
(k)
3267
4.0
13.1.5
(j), (k)
3267 3271 3271
8 3.1/3.2 3.2/3.3
1 1 2
2.65 2.65 1.5
N N N
B B A
13.1.5 13.1.5 13.1.5
(k) (j) (j)
IMDG CODE - PAGE 0087r1 (page 0087s1 follows) Amdt. 28-96
9 13.1.5
UN No.
Substance
Class

4
IMO tank type

5 1
6 2.65 7 N 8 B
10
1 3302
2 2-DIMETHYLAMINOETHYL ACRYLATE SODIUM BOROHYDRIDE AND SODIUM HYDROXIDE SOLUTION with not more than 12% sodium borohydride and not more than 40% sodium hydroxide, by mass MERCAPTANS, LIQUID, FLAMMABLE, N.O.S, or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (Packaging group I) MERCAPTANS, LIQUID, FLAMMABLE, N.O.S, or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (Packaging group II) MERCAPTANS, LIQUID, FLAMMABLE, N.O.S, or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. (Packaging group III) PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PYRETHROID, PESTICIDE, LIQUID, FLAMMABLE, TOXIC PYRETHROID, PESTICIDE, LIQUID, TOXIC, FLAMMABLE PYRETHROID, PESTICIDE, LIQUID, TOXIC
3 6.1
3320
4.0
NF
6 mm
3336
3.1/3.2
6.0
6 mm
3336
3.1/3.2
2.65
13.1.5
3336 3346 3347 3348 3350 3351 3352
3.3 3.2 6.1 6.1 3.2 6.1 6.1
Toxic Flam. liq. Toxic Flam. Iiq.
2 1 1 1 1 1 1
1.5 4.0 4.0 4.0 4.0 4.0 4.0
N NF N N NF N N
B C B B C B B
13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5 13.1.5
(b), (j) (j) (j) (b), (j) (j) (j)
IMDG CODE - PAGE 0087u1 (page 0087v1 follows) Amdt. 29-98
PAGE RESERVED
IMDG CODE - PAGE 0087V1 (page 0088 follows) Amdt. 29-98
13.100 GENERAL REQUIREMENTS FOR PORTABLE TANKS AND ROAD TANK VEHICLES FOR NONREFRIGERATED LIQUEFIED GASES OF CLASS 2 Preamble The requirements of this subsection apply to portable tanks (type 5 tanks) and road tank vehicles (type 6 tanks) intended for the transport of non-refrigerated liquefied gases of class 2. In addition to these requirements and unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC), 1972, as amended should be fulfilled by any portable tank which meets the definition of a "container" within the terms of that Convention. The International Convention for Safe Containers does not apply to offshore tank-containers that are handled in open seas. The design and testing of offshore tank-containers should take into account the dynamic lifting and impact forces that may occur when a tank is handled in open seas in adverse weather and sea conditions. The requirements for such tanks should be determined by the approving competent authority (see MSC/Circ.613 in the annex at the end of this section). Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas. In order to take into account progress in science and technology the use of alternative arrangements which offer at least equivalent safety in use in respect of compatibility with the properties of the gases transported and equivalent or superior resistance to impact, loading and fire may be considered by the national competent authority. The requirements of this subsection are presented in two parts. The first contains general requirements applicable to portable tanks and road tank vehicles intended for the transport of non-refrigerated liquefied gases of class 2. The second contains the appendix* with a table showing the particular requirements which modify or supplement the general requirements of this subsection for each particular gas.
13.101 13.101.1
13.101.2
13.101.3
13.101.3.1 In general, where a substance has not been allocated a UN Number, it should be carried under the most suitable N.O.S. entry. However, the competent authority of the country of origin may issue interim approvals for shipment of gases not listed in the appendix to this subsection to which individual UN Numbers have already been assigned. The approval should accompany the shipment concerned and contain at a minimum the information normally provided in the list of non-refrigerated liquefied gases and the conditions under which the particular gases should be carried. The approval should contain a note to the effect that this competent authority has undertaken action to include this gas in the appendix to subsection 13.100. 13.101.4 13.101.5 Construction, equipment, testing, marking and operation of portable tanks and road tank vehicles should be subject to acceptance by the competent authority of the country in which they are approved. The requirements of this subsection do not apply to rail tank-wagons, non-metallic tanks or tanks having a capacity of 1.000 litres or less. IMO type 5 tanks certified prior to the implementation of these revised requirements and constructed in accordance with the requirements in force at the time may be permitted for use with competent authority approval. The approval should refer to this paragraph.
13.101.6
* The appendix will need updating from time to time in the light of technical progress and to include new substances.
13.102 13.102.1 13.102.2 Definitions For the purposes of these requirements. For the purposes of this subsection tank means a portable tank or the carrying tank of a road tank vehicle the shell of which is fitted with items of service equipment and structural equipment necessary for the transport of gases. A tank should be capable of being transported loaded and discharged without the need of removal of its structural equipment. Shell means the pressure vessel proper including openings and their closures. Service equipment of a shell means filling and discharge venting safety heating and heat insulating devices and measuring instruments. Structural equipment means the reinforcing fastening protective and stabilizing members external to the shell and for a road tank vehicle includes fastenings to running gear or chassis. Maximum allowable working pressure (MAWP) means the maximum gauge pressure permissible at the top of the tank in its operating position. It may be no less than the vapour pressure at the design reference temperature less one bar of any product which can be loaded and carried and any pressure which might be used during loading or unloading In no case should the MAWP be less than 7 bar.
13.102.3 13.102.4 13.102.5 13.102.6
13.102.7 13.102.8 13.102.9
Test pressure means the highest pressure which arises in the shell during the hydraulic pressure test. Discharge pressure means the highest pressure actually built up in the shell when it is being discharged by pressure. Leakage test is the test which submits the shell complete with those items of service equipment necessary for filling discharge safety and measuring to an effective internal pressure equivalent to the MAWP. The procedure to be adopted should be approved by the competent authority.
13.102.10 Total mass means the mass of the portable tank or road tank vehicle with the heaviest load authorized for transport. 13.102.11 Design reference temperature means the temperature at which the vapour pressure of the tank contents is determined for the purpose of calculating the MAWP. The design reference temperature should be less than the critical temperature of the gas to be transported to ensure that the gas at all times is liquefied. For portable tanks the temperature to be taken is as follows: 1 for a tank with a diameter of 1.5 metres or less 65 C; 2 for a tank with a diameter of more than 1.5 metres; 2.1 without insulation or sun shield 60 C; 2.2 with sun shield 55 C; and 2.3 with insulation 50 C*. For a road tank vehicle the temperature to be taken is to be agreed by the competent authorities.
* This reference temperature is envisaged but dependent on the quality of the insulation system.
13.115.3 The shell and items of equipment of each tank should be inspected and tested either together or separately first before being put into service (initial inspection and test) and thereafter at not more than five year intervals (periodic inspection and test). The initial inspection and test should include a check of the design characteristics and internal and external examination and a hydraulic pressure test. If the shell and equipment have been pressure tested separately they should together be subjected after assembly to a leakage test. All welds in the shell should be tested in the initial inspection by radiographic ultrasonic or another suitable non-destructive method. This does not apply to the metal sheathing of an insulation. The periodic inspections and tests should include an internal and external examination and as a general rule a pressure rest.
13.115.3.1
13.115.3.2
13.115.3.2.1 Sheathing thermal insulation and the like should be removed only to the extent required for reliable appraisal of the tank's condition. 13.115.3.3 The initial and periodic pressure tests should be carried out by an expert approved by the competent authority at the test pressure indicated on the data plate of the tank except in cases where periodic tests at lower test pressures are authorized. While under pressure the tank should be inspected for leakage or other conditions which indicate weaknesses that night render the tank unsafe in transport and if any evidence of such unsafe condition is discovered the tank should not be placed in or returned to service until it has been repaired and the test repeated has been passed. Before tanks are put into service and thereafter at intervals midway between the inspections and tests specified in 13.115.3 the following tests and inspections should be performed: 1 a leakage test where required; 2 a test of satisfactory operation of all service equipment; and 3 an internal and external inspection of the tanks and their fittings with due regard to the gases transported. 13.115.5 The 2.5 year (midway) inspection and test may be carried out within 3 months of the specified date. The date of the 2.5 year inspection should be durably marked on or as near as possible to the metal identification plate required in 13.117.1. When marking is not done on the plate the characters should be at least 32 mm in height and of a contrasting colour to the tank. The 2.5 year internal inspections may be waived or substituted by other test methods by the competent authority in the case of tanks intended for the transport of one substance. A portable tank may not be filled and offered for transport after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 13.1.19.3 and 13.1.19.4/13.115.3 and 13.115.4/13.213.3 and 13.213.4. However, a portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection In addition a portable tank may be transported after the date of expiry of the last periodic test and inspection. 1 After emptying but before cleaning for purposes of performing the next required test and inspection prior to refilling; and 2 Unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test and inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this authorization should be entered in the dangerous goods shipping document.
13.115.3.4
13.115.4
13.115.6
13.115.7 When a tank, other than its shell is damaged it should not be allowed for use unless it has been repaired, so as to comply with these requirements. When the shell is damaged it should be repaired and retested in conformity with 13.115.8. 13.115.8 In all cases where cutting, burning or welding operations on the shell of a tank have been effected that work should be to the approval of the competent authority and a hydrostatic test to at least the original test pressure should be carried out.
13.115.9 A certificate from the competent authority or its approved inspecting agency affirming that the tank complies with the requirements of this Code should be issued and should be retained by the authority and the owners during the time the tank is in service. All information required in 13.117.1 and 13.117.2 should also be included in this certificate. 13.116 Approval, testing and marking of type 6 tanks
13.116.1 Road tank vehicles are to be authorized for short international voyages only. 13.116.2 For any road tank vehicles intended for transport of a substance listed in the appendix to this subsection there should be in existence a valid certificate issued by or on behalf of the competent authority for road transport authorizing transport of that substance by road. 13.116.3 The competent authority for sea transport or a body authorized by that authority should issue additionally in respect of a road tank vehicle a certificate attesting compliance with the relevant design construction and equipment requirements of this subsection and, where appropriate the special requirements for the gases listed in the appendix to this subsection. The certificate should list the gases allowed to be transported. 13.116.4 A road tank vehicle should be periodically tested and inspected in accordance with the requirements of the competent authority for road transport. 13.116.5 Road tank vehicles should be marked in accordance with 13.117. However where the marking required by the competent authority for road transport is substantially in agreement with that of 13.117.1 it will be sufficient to endorse the plate attached to the road tank vehicle with "IMO type 6".
13.117
Marking
13.117.1 Every tank should be fitted with a corrosion resistant metal plate permanently attached in a place readily accessible for inspection. At least the following particulars should be marked on the plate in characters at least 3 mm in height by stamping, engraving, embossing or any similar method. If for reasons of tank arrangements the plate cannot be permanently attached to the shell the shell should be marked with at least those particulars required by a recognized pressure vessel code in a manner prescribed by that code.
The plate should be kept free of any paint to ensure that the markings will be legible at all times. Country of manufacture IMO tank type no. Manufacturer's name or mark Registration number Year of manufacture Approval country Approval number
UN No.
Gas
Class and subsidiary risk (s)
Maximum allowable working pressure (bar) (i) Small; (ii) Bare; (iii) Sun shield; (iv) Insulated.
Opening below liquid level
Pressure relief
Filling (kg/l)
2
1-CHLORO-2,2,2-TRIFLUOROETHANE (REFRIGERANT GAS R 133a)
4
7.0 7.0 7.0 7.0 31.0 27.5 24.2 21.8 23.1 20.8 18.6 16.6 8.9 7.8 7.0 7.0 20.0 18.0 16.0 14.5
1983
2.2
Allowed
Normal
1.18
2035
1,1,1-TRIFLUOROETHANE (REFRIGERANT GAS R 143a)
2.1
Allowed
Normal
0.76
2424
OCTAFLUOROPROPANE (REFRIGERANT GAS R 218)
2.2
Allowed
Normal
1.07
2517
1,CHLORO-1,1DIFLUOROETHANE (REFRIGERANT GAS R 142b) DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE, AZEOTROPIC MIXTURE, with approximately 74% dichlorodifluoromethane (REFRIGERANT GAS R 500)
2.1
Allowed
Normal
0.99
2602
2.2
Allowed
Normal
1.01
UN No.
Gas
Maximum allowable working pressure (bar) (i) Small; (ii) Bare; (iii) Sun shield; (iv) Insulated. 4 14.6 12.9 11.3 9.9 14.0 12.0 11.0 9.0 14.3 13.4 11.2 10.2 17.7 15.7 13.8 12.1
Pressure relief
Filling (kg/l)
8 The wall thickness should not be less than 8 mm. Wall thickness should be ultrasonically verified at intervals midway between the periodic hydraulic tests.
2.3 3057 TRIFLUOROACETYL CHLORIDE Corrosive
Not allowed
see 13.108.3
1.17
3070
ETHYLENE OXIDE AND DICHLORODIFLUOROMETHANE, MIXTURE, with not more than 12.5% ethylene oxide
2.2
Allowed
see 13.108.3
1.09
3153
PERFLUORO(METHYL VINYL ETHER)
2.1
Allowed
Normal
1.14
3159
1,1,1,2-TETRAFLUOROETHANE (REFRIGERANT GAS R 134a)
2.2
Allowed
Normal
1.04
3161
LIQUEFIED GAS, FLAMMABLE, N.O.S.
2.1
see 13.102.6
Allowed
Normal
see 13.119
3163
LIQUEFIED GAS, N.O.S.
2.2
see 13.102.6
Allowed
Normal
see 13.119
IMDG CODE - PAGE 0106i (page 0106j follows) Amdt. 29-98
UN No.
Gas
Maximum allowable working pressure (bar) (i) Small; (ii) Bare; (iii) Sun shield; (iv) Insulated. 4 34.4 30.8 27.5 24.5
Pressure relief
Filling (kg/l)
3220
PENTAFLUOROETHANE (REFRIGERANT GAS R 125)
2.2
Allowed
Normal
0.95
3252
DIFLUOROMETHANE (REFRIGERANT GAS R 32)
2.1
43.0 39.0 34.4 30.5
Allowed
Normal
0.78
3296
HEPTAFLUOROPROPANE (REFRIGERANT GAS R 227)
2.2
16.0 14.0 12.5 11.0
Allowed
Normal
1.20
3297
ETHYLENE OXIDE AND CHLOROTETRAFLUOROETHANE MIXTURE, with not more than 8.8% ethylene oxide
2.2
8.1 7.0 7.0 7.0 25.9 23.4 20.9 18.6
Allowed
Normal
1.16
3298
ETHYLENE OXIDE AND PENTAFLUOROETHANE MIXTURE, with not more than 7.9% ethylene oxide
2.2
Allowed
Normal
1.02
3299
ETHYLENE OXIDE AND TETRAFLUOROETHANE MIXTURE, with not more than 5.6% ethylene oxide
2.2
16.7 14.7 12.9 11.2
Allowed
Normal
1.03
IMDG CODE - PAGE 0106j (page 0106k follows) Amdt. 28-96
UN No.
Gas
Maximum allowable working pressure (bar) (i) Small; (ii) Bare; (iii) Sun shield; (iv) Insulated. 4 see 13.102.6 31.6 28.2 25.2 22.1 32.3 29.0 25.7 22.4 34.0 30.5 27.0 23.6 30.2 27.0 24.1 21.4
Pressure relief
Filling (kg/l)
1 3318
2 AMMONIA SOLUTION, with more than 50% ammonia
3 2.3 Corrosive
5 Allowed
6 see 13.108.3
7 see 13.119
3337
REFRIGERANT GAS R 404A
2.2
Allowed
Normal
0.82
3338
REFRIGERANT GAS R 407A
2.2
Allowed
Normal
0.94
3339
REFRIGERANT GAS R 407B
2.2
Allowed
Normal
0.93
3340
REFRIGERANT GAS R 407C
2.2
Allowed
Normal
0.95
IMDG CODE - PAGE 0106k (page 0107 follows) Amdt. 29-98
13.200 GENERAL REQUIREMENTS FOR PORTABLE TANKS AND ROAD TANK VEHICLES FOR REFRIGERATED LIQUEFIED GASES OF CLASS 2 Preamble
13.201
13.201.1 The requirements of this subsection apply to portable tanks (type 7 tanks) and road tank vehicles (type 8 tanks) intended for the transport of refrigerated liquefied gases of class 2. In addition to the requirements of this subsection and unless otherwise specified, the applicable requirements of the International Convention for Safe Containers (CSC), 1972, as amended, should be fulfilled by any portable tank which meets the definition of a "container" within the terms of that Convention. The International Convention for Safe Containers does not apply to offshore tank-containers that are handled in open seas. The design and testing of offshore tank-containers should take into account the dynamic lifting and impact forces that may occur when a tank is handled in open seas in adverse weather and sea conditions. The requirements for such tanks should be determined by the approving competent authority (see also MSC/Circ.613 in the annex at the end of this section). Such requirements should be based on MSC/Circ.860 Guidelines for the approval of offshore containers handled in open seas.
13.201.2 In order to take into account progress in science and technology, the use of alternative arrangements which offer at least equivalent safety in use in respect of compatibility with the properties of the substances transported and equivalent or superior resistance to impact, loading and fire may be considered by the national competent authority. 13.201.3 Existing tanks and their service equipment not conforming strictly to the requirements set forth, but having acceptable alternatives, may be considered by the competent authority for approval. In the approval it should be clearly stated that the basis for the issue of the certificate is this paragraph. In the certificate the entry should read "Approved in accordance with 13.201.3 of the IMDG Code ". 13.201.4 The appendix* to this subsection comprises the list of dangerous substances and also indicates any special requirements which modify or supplement these general requirements for each particular substance.
13.201.5 Construction, equipment, testing, marking and operation of portable tanks and road tank vehicles should be subject to acceptance by the competent authority of the country in which they are approved.
13.201.6 These requirements do not apply to rail tank-wagons, non-metallic tanks or tanks having a capacity of 1.000 litres or less. 13.202 Definitions
13.202.1 For the purposes of these requirements. 13.202.2 Type 7 tank means a thermally insulated portable tank fitted with items of service and structural equipment necessary for the transport of refrigerated liquefied gases. The portable tank should be capable of being transported, loaded and discharged without the need of removal of its structural equipment and should be capable of being lifted when full. It should not be permanently secured on board the ship.
* The appendix will need updating from time to time in the light of technical progress and to include new substances.
Its contents should not be loaded or discharged while the portable tank remains on board. 13.202.2.1 Type 8 tank means a road tank vehicle and includes a semi-trailer with a permanently attached thermally insulated tank fitted with items of service equipment and structural equipment necessary for the transport of refrigerated liquefied gases. It should be fitted with permanent attachments such that it can be secured on board ship. However, its contents should not be loaded or discharged whilst the vehicle remains on board. A road tank vehicle should only be carried on short international voyages. 13.202.3 Tank means a construction which normally consists of: 1 a jacket and one or more inner shells where the space between the shell or shells and the jacket incorporates thermal insulation and is exhausted of air (vacuum insulation); or 2 a jacket and an inner shell with ah intermediate layer of solid thermally insulating material (e.g. solid foam); or 3 an outer shell with an inner layer of solid thermally insulating material. 13.202.4 13.202.5 Shell means a pressure vessel proper, including openings and their closures. Service equipment of a tank means filling and discharge, venting, safety, thermal-insulating devices and measuring instruments. Structural equipment means the reinforcing, fastening, protective and stabilizing members external to a tank and includes for a road tank vehicle fastenings to running gear or chassis. Maximum allowable working pressure (MAWP) means the maximum effective gauge pressure permissible at the top of the shell of a loaded tank in its operating position. Test pressure means the maximum gauge pressure which arises in the shell during the pressure test. Leakage test means a test which consists of subjecting the shell, complete with its service equipment, to an effective internal pressure equivalent to the MAWP. The procedure to be adopted should be approved by the competent authority.
13.202.6
13.202.7
13.202.8 13.202.9
13.202.10 Total mass means the mass of the portable tank or road tank vehicle with the heaviest load authorized for transport. 13.202.11 Holding time means the time that will elapse from the moment the liquid starts boiling at atmospheric pressure up to the moment the pressure of the tank contents reaches the MAWP under equilibrium conditions. 13.202.12 Minimum design temperature means the lowest contents temperature at which the tank can be used. 13.202.13 Short international voyage means an international voyage in the course of which a ship is not more than 200 miles from a port or place in which the passengers and crew could be placed in safety. Neither the distance between the last port of call in the country in which the voyage begins.
13.213.4 Before a portable tank is put into service, and thereafter at intervals midway between the inspections and tests provided in 13.213.3, the following tests and inspections should be performed: 1 a leakage test, where required; 2 a test of satisfactory operation of all service equipment; 3 an external inspection of the portable tank and its fittings with due regard to the gases transported; and 4 a vacuum reading where applicable. 13.213.5 The 2.5 year (midway) inspection and test may be carried out within 3 months of the specified date. The date of the 2.5 year inspection should be durably marked on or as near as possible to the metal identification plate required in 13.215.1. When marking is not done on the plate, the characters should be at least 32 mm in height and of a contrasting colour to the tank. A portable tank may not be filled and offered for transport after the date of expiry of the last 5 year or 2.5 year periodic inspection and test as required by 13.1.19.3 and 13.1.19.4/13.115.3 and 13.115.4/13.213.3 and 13.213.4. However, a portable tank filled prior to the date of expiry of the last periodic inspection and test may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection In addition, a portable tank may be transported after the date of expiry of the last periodic test and inspection. 1 After emptying but before cleaning, for purposes of performing the next required test and inspection prior to refilling; and 2 Unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test and inspection, in order to allow the return of dangerous goods for proper disposal or recycling. Reference to this authorization should be entered in the dangerous goods shipping document. 13.213.6 When a portable tank is damaged it should not be allowed to be used until it has been repaired so as to comply with these requirements. When the shell is damaged it should be repaired and re-tested in conformity with 13.213.7. 13.213.7 In all cases where cutting, burning or welding operations on the shell of a portable tank have been carried out, that work should be to the satisfaction of the competent authority and a pressure test to at least the original test pressure should be carried out. 13.213.8 Certificates showing the results of the test should be issued by the competent authority. All information required in 13.215.1 and 13.215.2 should also be included in this certificate. 13.214 Approval, testing and marking of type 8 tanks
13.214.1 Road tank vehicles are to be authorized for short international voyages only. 13.214.2 For any road tank vehicle intended for transport of a substance listed in the appendix to this subsection there should be in existence a valid certificate issued by or on behalf of the competent authority for road transport authorizing transport of that substance by road.
13.214.3 The competent authority for sea transport or a body authorized by that authority should issue additionally in respect of a road tank vehicle a certificate attesting compliance with the relevant design construction and equipment requirements of this subsection and where appropriate the special requirements for the gases in the appendix to this subsection. The certificate should list the gases allowed to be transported. 13.214.4 A road tank vehicle should be tested and inspected in accordance with the requirements of the competent authority for road transport. 13.214.5 Road tank vehicles should be marked in accordance with 13.215. However where the marking required by the competent authority for road transport is substantially in agreement with that of 13.215.1 it will be sufficient to endorse the metal plate attached to the road tank vehicle with IMO type 8, the reference to holding time may be omitted.
13.215 Marking
13.215.1 Every tank should be fitted with a corrosion-resistant metal plate permanently attached in a place readily accessible for inspection. At least the following particulars should be marked on the plate in characters at least 3 mm in height by stamping, engraving, embossing or any similar method. If, for reasons of tank arrangements, the plate cannot be permanently attached to the shell, the shell should be marked with at least those particulars required by a recognized pressure vessel code in a manner prescribed by that code. The plate should be kept free of any paint to ensure that the markings will be legible at all times. Country of manufacture IMO tank type No. Manufacturers name or mark Registration number Year of manufacture Test pressure Maximum allowable working pressure Water capacity at 20 C of each compartment (The water capacity should be established to within 1% by practical test rather than by calculation). Original pressure test date and witness identification Code to which the shell is designed Minimum design temperature Maximum total mass Unladen (tare) mass Shell material Month year and test pressure of most recent periodic test month Stamp of expert who carried out most recent test The names, in full of the gases for whose transport the tank is approved Either "thermally insulated" or "vacuum-insulated" year (bar) / (MPa)* gauge (bar) / (MPa)* gauge (bar) / (MPa)* gauge (litres) Approval country Approval number
( C)
(kg) (kg)
* The unit used should be indicated.
15 SEGREGATION 15.1 15.1.1 15.1.2 General The requirements of this section should apply to all cargo spaces on deck or under deck of all types of ships and to all cargo transport units (CTUs). The International Convention for the Safety of Life at Sea, 1974, as amended, requires in regulation 6.1 of part A of chapter VII that incompatible goods shall be segregated from one another. For the Implementation of this requirement, two substances or articles are considered mutually incompatible when their stowage together may result in undue hazards In case of leakage or spillage, or any other accident. The extent of the hazard arising from possible reactions between incompatible dangerous goods may vary and so the segregation arrangements required should also vary as appropriate. Such segregation is obtained by maintaining certain distances between incompatible dangerous goods or by requiring the presence of one or more steel bulkheads or decks between them, or a combination thereof. Intervening spaces between such dangerous goods may be filled with other cargo compatible with the dangerous substances in question. The following segregation terms are used throughout this Code: .1 .2 .3 .4 AWAY FROM; "Separated from"; "Separated by a complete compartment or hold from"; "Separated longitudinally by an intervening complete compartment or hold from".
15.1.3 15.1.4
15.1.5
These terms are defined in 15.2 and their use in regard to the different modes of sea transport is explained further in the other subsections of this section. 15.1.6 The general requirements for segregation between the various classes of dangerous goods are shown in the "segregation table" of 15.1.17. in addition to these general requirements, there may be a need to segregate a particular substance, material or article from other goods which could contribute to its hazard. Particular requirements for segregation are indicated in the individual schedules and, in the case of conflicting requirements, always take precedence over the general requirements. For example: On the schedule for ACETYLENE, DISSOLVED, Class 2.1, UN No. 1001 the following particular segregation requirement is specified: SEPARATED FROM chlorine. 15.1.6.1 Where the Code Indicates a single secondary hazard (one subsidiary risk label), the segregation requirements applicable to that hazard should take precedence where they are more stringent than those of the primary hazard.
15.1.6.2 Except for , the segregation requirements for substances, materials or articles having more than two hazards (two or more subsidiary risk labels) are given in the individual schedules. For example: The schedule for BROMINE CHLORIDE, class 2.3, subsidiary risks 5.1 and 8, UN No. 2901 specifies Segregation as for class 5.1 but SEPARATED FROM class 7". 15.1.7 In the case of segregation from combustible material this should be understood not to include packaging materials or dunnage. Whenever dangerous goods are stowed together whether or not in a cargo transport unit the segregation of such dangerous goods from others should always be in accordance with the most stringent requirements for any of the dangerous goods concerned. For the purposes of 15.1.6.1 the segregation requirements corresponding to a subsidiary risk label of are those for division 1.3.
15.1.8
15.1.9
15.1.10 Notwithstanding 15.1.6.1, 15.1.6.2 and 15.1.13, substances of the same class may be stowed together without regard to segregation required by secondary hazards (subsidiary risk label (s)), provided the substances do not react dangerously with each other and cause. 1 2 3 4 combustion and/or evolution of considerable heat, evolution of flammable, toxic or asphyxiant gases, the formation of corrosive substances; or the formation of unstable substances.
15.1.11 Where the individual schedule specifies that "Segregation as for class " applies, the segregation requirements applicable to that class in table 15.1.17 should be applied However, for the purposes of interpreting paragraph 15.1.10 which permits substances of the same class to be stowed together provided they do not react dangerously with each other, the segregation requirements of the class as represented by the primary hazard class in the individual schedule should be applied For example UN No. 2965 - BORON TRIFLUORIDE DIMETHYL ETHERATE, Class 4.3 The schedule specifies "Segregation as for class 3, but ' away from' classes 3, 4.1 and 8" For the purposes of establishing the segregation requirements applicable in table 15.1.17, the class 3 column should be consulted This substance may be stowed together with other class 4.3 substances when they do not react dangerously with each other see 15.1.10 15.1.12 No segregation need be applied between dangerous goods of different classes which comprise the same substance but vary only in their water content, e. g. sodium sulphide in classes 4.2 and 8 15.1.13 Where for the purposes of segregation, terms such as " 'away from' class " are used in the individual schedules "class is deemed to include 1 all substances within class and
IMDG CODE - PAGE 0128 (page 0128a follows) Amdt 29-98
2 all substances for which a subsidiary risk label of ' class ' is required.
15.1.14 A closed cargo transport unit means a unit which totally encloses the contents by permanent structures. An open cargo transport unit means a unit which is not a closed cargo transport unit. Cargo transport units with fabric sides or tops are not closed cargo transport units for the purposes of this section. 15.1.15 For the purposes of segregating incompatible dangerous goods, the terms compartment and hold mean a cargo space enclosed by steel bulkheads or shell plating and by steel decks. The boundaries of such a space should be resistant to fire and liquid. 15.1.16 Stowage in a shelter-tween-deck cargo space is not considered to be on-deck stowage.
IMDG CODE - PAGE 0128a (page 0729 follows) Amdt 29-98
15.1.17 Segregation table. The following table shows the general requirements for segregation between the various classes of dangerous goods.
SINCE THE PROPERTIES OF SUBSTANCES OR ARTICLES WITHIN EACH CLASS MAY VARY GREATLY, THE INDIVIDUAL SCHEDULES SHOULD ALWAYS BE CONSULTED FOR PARTICULAR REQUIREMENTS FOR SEGREGATION AS, IN THE CASE OF CONFLICTING REQUIREMENTS. THESE TAKE PRECEDENCE OVER THE GENERAL REQUIREMENTS. SEGREGATION SHOULD ALSO TAKE ACCOUNT OF A SINGLE SUBSIDIARY RISK LABEL.
CLASS Explosives Explosives Explosives Flammable gases Non-toxic non-flammable gases Toxic gases Flammable liquids Flammable solids (including self reactive and related substances and desensitized explosives) Substances liable to spontaneous combustion Substances which, in contact with water emit flammable gases Oxidizing substances (agents) Organic peroxides Toxic substances Infectious substances Radioactive materials Corrosives Miscellaneous dangerous substances and articles 1.1, 1.2, 1.5 1.3, 1.6 1.4 2.1 2.2 2.3 3 4.1 4.2 4.3 5.1 5.2 6.1 6.2 7 8 9 1.1 1.3 1.2 1.4 2.1 2.2 2.3 1.5 1.6 * * * 4 2 2 4 4 4 4 4 4 2 4 2 4 X * * * 4 2 2 4 3 3 4 4 4 2 4 2 2 X 2 1 1 2 2 2 2 2 2 X 4 2 2 X * * 4 4 2 X X X 2 1 2 X 2 2 X 4 2 1 X 2 2 1 X X X 1 X 1 X X 1 X 2 1 X X 2 2 1 X X X 2 X 2 X X 2 X 2 1 X X 3 4 4 2 2 1 2 X X 2 1 2 2 X 3 2 X X 4.1 4.2 4.3 5.1 5.2 6.1 6.2 4 3 2 1 X X X X 1 X 1 2 X 3 2 1 X 4 3 2 2 1 2 2 1 X 1 2 2 1 3 2 1 X 4 4 2 X X X 1 X 1 X 2 2 X 2 2 1 X 4 4 2 2 X X 2 1 2 2 X 2 1 3 1 2 X 4 4 2 2 1 2 2 2 2 2 2 X 1 3 2 2 X 2 2 X X X X X X 1 X 1 1 X 1 X X X 4 4 4 4 2 2 3 3 3 2 3 3 1 X 3 3 X 7 2 2 2 2 1 1 2 2 2 2 1 2 X 3 X 2 X 8 4 2 2 1 X X X 1 1 1 2 2 X 3 2 X X 9 X X X X X X X X X X X X X X X X X
Numbers and symbols relate to the following terms as defined in this section 1 - AWAY FROM 2 - "Separated from" 3 Separated by a complete compartment or hold from" 4 - "Separated longitudinally by an intervening complete compartment or hold from" X - The segregation, if any, is shown in the individual schedules * - See subsection 6.2 of the introduction to for segregation within
IMDG CODE - PAGE 0129 Amdt 29-98
15.1.17 For the purposes of the segregation requirements for the various modes of carriage by sea this section has been subdivided as follows: 15.2 15.3 15.4 15.5 15.6 15.2 15.2.1 Segregation of packages. Segregation of freight containers on board container ships. Segregation of cargo transport units on board roll-on roll-off ships. Segregation in shipborne barges and on board barge-carrying ships. Segregation between bulk materials possessing chemical hazards and dangerous goods in packaged form.
Segregation of packages. Applicability
15.2.1.1 The requirements of this subsection apply to the segregation of .1 packages containing dangerous goods and stowed in the conventional way, .2 dangerous goods within cargo transport units (as listed in 7.3.1.1 of this General Introduction); and .3 dangerous goods stowed in the conventional way from those packed in such cargo transport units. 15.2.2 Segregation of packages containing dangerous goods and stowed in the conventional way.
15.2.2.1 Definitions of the segregation terms.
Legend: (1) Reference package .................................................................................... ......................................................
(2) Package containing incompatible goods (3) Deck resistant to fire and liquid
.....................................................................
NOTE: Full vertical lines represent transverse bulkheads between cargo spaces (compartments or holds) resistant to fire and liquid.
15.4 15.4.1 Segregation of cargo transport units on board roll-on roll-off ships Applicability
15.4.11 The requirements of this subsection apply to the segregation of cargo transport units which are carried on board roll on roll-off ships or in roll-on roll-off cargo spaces. 15.4.12 For roll-on roll off ships which carry freight containers on decks or in holds and when these cargo spaces are properly arranged for the permanent stowage of such containers during transport, the requirements of subsection 15.3 should apply to such spaces. 15.4.13 For roll on roll-off ships which incorporate conventional cargo spaces or any other method of stowage the appropriate subsection of this section should apply to the relevant cargo space.
HORIZONTAL SEGREGATION REQUIREMENT CLOSED VERSUS CLOSED ON DECK FORE AND AFT NO RESTRICTION UNDER DECK CLOSED VERSUS OPEN ON DECK UNDER DECK NO RESTRICTION OPEN VERSUS OPEN ON DECK AT LEAST 3 METRES UNDER DECK AT LEAST 3 METRES
AWAY FROM
NO RESTRICTION NO RESTRICTION
ATHWART SHIPS
NO RESTRICTION
NO RESTRICTION
NO RESTRICTION
NO RESTRICTION
AT LEAST 3 METRES
AT LEAST 3 METRES
"SEPARATED FROM"
FORE AND AFT
AT LEAST 6 METRES
AT LEAST 6 METRES OR ONE BULKHEAD AT LEAST 3 METRES OR ONE BULKHEAD
AT LEAST 6 METRES
AT LEAST 6 METRES OR ONE BULKHEAD AT LEAST 6 METRES OR ONE BULKHEAD AT LEAST 24 METRES + DECK
AT LEAST 6 METRES
AT LEAST 12 METRES OR ONE BULKHEAD AT LEAST 12 METRES or ONE BULKHEAD
ATHWARTSHIPS
AT LEAST 3 METRES
AT LEAST 3 METRES
AT LEAST 6 METRES
"SEPARATED BY A COMPLETE COMPARTMENT
FORE AND AFT
AT LEAST 12 METRES
AT LEAST 24 METRES DECK
AT LEAST 24 METRES
AT LEAST 36 METRES
TWO DECKS OR TWO BULKHEADS
ATHWART SHIPS
AT LEAST 12 METRES
AT LEAST 24 METRES + DECK TWO BULKHEADS OR AT LEAST 36 METRES + TWO DECKS PROHIBITED
AT LEAST 24 METRES
AT LEAST 24 METRES + DECK
AT LEAST 36 METRES
PROHIBITED
SEPARATED LONGITUDINALLY BY AN INTERVENING COMPLETE COMPARTMENT OR HOLD FROM"
FORE AND AFT
AT LEAST 36 METRES
AT LEAST 36 METRES
AT LEAST 48 METRES INCLUDING TWO BULKHEADS PROHIBITED
AT LEAST 48 METRES
PROHIBITED
ATHWARTSHIPS
PROHIBITED
PROHIBITED
PROHIBITED
PROHIBITED
NOTE: ALL BULKHEADS AND DECKS SHOULD BE RESISTANT TO FIRE AND LIQUID
17 CARRIAGE OF DANGEROUS GOODS ON ROLL-ON ROLL-OFF SHIPS 17.1 General
17.1.1 Because of the structural differences between roll-on roll-off ships and conventional ships, this section contains alternative and special or additional provisions for the transport of dangerous goods on these ships. 17.2 Applicability
17.2.1 The provisions of this section should apply to the loading and unloading of dangerous goods by means of vehicles, containers and other cargo transport units via ramps, etc. and to the loading and unloading of units by means of forklift trucks, cranes etc. 17.3 Definitions
17.3.1 For the purposes of this section, unit means any vehicle, container, tank intermediate bulk container (IBC), unit load or receptacle which is loaded and unloaded separately as one piece*. 17.3.2 Vehicle means any road freight or tank vehicle or railway freight or tank wagon permanently attached to an under frame and wheels or chassis and wheels, which is loaded and unloaded as a unit It also includes a trailer, semitrailer or similar mobile unit, except those used solely for the purposes of loading and unloading*. 17.3.3 For the purposes of this section, the term container includes a road or rail demountable container rigid or collapsible, having a net mass of more than 400 kg, a freight container , a demountable or portable tank a pressure vessel or any other receptacle having a capacity of 450 litres or more. 17.3.4 Closed type unit means a unit in which dangerous goods are totally enclosed by sufficiently strong boundaries such as a freight container , a tank or a vehicle Units with fabric sides or tops are not closed type units. 17.3.5 Ro-Ro ship (roll-on roll-off ship) means a ship which has one or more decks, either closed or open, not normally subdivided in any way and generally running the entire length of the ship, carrying goods which are normally loaded and unloaded in a horizontal direction. 17.3.6 Weather deck is a deck which is completely exposed to the weather from above and from at least two sides. 17.3.7 On Weather deck, for the purposes of this section, is equivalent to stowage "on deck" (see also appendix to section 14 of this General Introduction).
* For reasons of convenience, dangerous goods are generally referred to in this section as being loaded or packed into a unit or vehicle. Such references should be interpreted as including loading or packing on to a unit or vehicle, where the context so requires. The word "in", when used in relation to a unit or vehicle should be construed accordingly.
MDG CODE - PAGE 0141 Amdt. 27-94
17.3.8 Ro-Ro cargo space is a space not normally subdivided in any way and extending to either a substantial length or the entire length of the ship in which goods in or on rail or road cars, vehicles (including road or rail tankers) trailers, containers, pallets demountable tanks or in or on similar stowage units or other receptacles can be loaded and unloaded normally in a horizontal direction. Open Ro-Ro cargo space is a Ro-Ro cargo space either open at both ends or open at one end and provided with adequate natural ventilation effective over its entire length through permanent openings in the side plating or deckhead to the satisfaction of the Administration.
17.3.9
17.3.10 Closed Ro-Ro cargo space is a Ro-Ro cargo space which is neither an open Ro-Ro cargo space nor a weather deck. 17.3.11 Special category space is an enclosed space above or below the bulkhead deck, intended for the carriage of motor vehicles with fuel in their tanks for their own propulsion, into and from which such vehicles can be driven and to which passengers have access. 13.7.12 Vehicle deck, for the purposes of this section is either a closed Ro-Ro cargo space an open Ro-Ro cargo space, a special category space or a weather deck. 17.4 17.4.1 Marking, labelling and placarding. For marking, labelling and placarding requirements applicable to roll-on roll-off traffic see sections 7 and 8 of this General Introduction. General handling. Loading and unloading operations on each vehicle deck should take place under the surveillance of either a working party consisting of officers and other crew members or responsible persons appointed by the master
17.5 17.5.1
17.5.1.1 Passengers and other unauthorized persons should be excluded from vehicle decks on which dangerous goods have been loaded All doors leading directly to these decks should be securely closed during the voyage and notices or signs prohibiting entrance to such decks should be conspicuously displayed. 17.5.1.2 During the voyage, access to such decks by passengers and other unauthorized persons should only be permitted when such persons are accompanied by an authorized crew member. 17.5.1.3 The transport of dangerous goods should be prohibited on any vehicle deck on which the foregoing requirements cannot be met. 17.5.2 Closing arrangements for the openings between Ro-Ro cargo spaces and machinery and accommodation spaces should be such as to avoid the possibility of dangerous vapours and liquids entering such spaces Such openings should normally be kept securely closed when dangerous cargo is on board except to permit access by authorized persons or for emergency use. Flammable gases or liquids having a flashpoint of 23C c.c. or less should not be stowed in a closed Ro-Ro space or special category space unless; - the design, construction and equipment of the space comply with the requirements of Regulation II 2/54 of SOLAS as amended and the ventilation system is operated to maintain at least six air changes per hour, or;
17.5.3
- the ventilation system of the space is operated to maintain at least ten air changes per hour and noncertified safe electrical systems in the space are capable of being isolated by means other than removal of fuses in the event of failure of the ventilation system or any other circumstance likely to cause accumulation of flammable vapours. Otherwise stowage is restricted to on deck only. 17.5.4 Certain dangerous goods are required to be stowed in a mechanically ventilated space' When such goods are carried in a closed Ro-Ro cargo space or a special category space this space should be mechanically ventilated. Mechanically operated refrigeration or heating equipment fitted to any unit should not be operated during the voyage when stowed in a dosed Ro-Ro cargo space or a special category space. Electrically operated refrigeration or heating equipment fitted to any unit stowed in a closed Ro-Ro cargo space or special category space should not be operated when flammable gases or liquids having a flashpoint of 23C c.c. or less may be present in the unit or in the same space, unless; - the design, construction and equipment of the space comply with the requirements of Regulation II-2/54 of SOLAS as amended and the refrigeration or heating equipment of the unit complies with paragraph 21.4 of this General Introduction, or; - the ventilation system of the space is operated to maintain at least ten air changes per hour and all electrical systems in the space are capable of being isolated by means other than removal of fuses in the event of ventilation failure or other circumstance likely to cause accumulation of flammable vapours; 17.5.7 The master of a ship carrying dangerous goods on vehicle decks should ensure that during loading and unloading operations and during the voyage regular inspections of these decks are made by an authorized crew member or responsible person in order to achieve early detection of any hazard. Empty units not gas-free, or loaded with empty packagings or receptacles not gas-free, should comply with the provisions applicable to the products last contained in the unit packagings or receptacles. Stowage, segregation and securing of units Stowage of units on board roll-on roll off ships.
17.5.5 17.5.6
17.5.8 17.6 17.6.1
17.6.1.1 Units loaded with dangerous goods should be stowed in such a way that they are accessible at all times especially for fire fighting. 17.6.1.2 Stowage of tanks containing dangerous goods should be in accordance with the requirements of the individual schedules and section 14 of this General Introduction. 17.6.1.3 Stowage of dangerous goods in freight containers should be in accordance with the requirements of the individual schedules and section 12 of this General Introduction. 17.6.1.4 Ro-Ro ships may carry dangerous goods in units or stowed in the conventional way on vehicle decks, in cargo holds or on weather decks. The provisions for such stowage should be in compliance with the relevant provisions laid down elsewhere in this Code.
17.6.1.5 Dangerous goods required to be carried "on deck only" should not be carried on closed vehicle decks, but may be carried on open vehicle decks when authorized by the competent authority concerned. 17.6.1.6 Units packed or loaded with flammable gases or liquids having a flashpoint of 23C c.c. or less and carried on deck should be stowed AWAY FROM (as defined in 15.1.13 of this Genera! Introduction) possible sources of ignition. 17.6.1.7 For "containers under fumigation", see the schedule on page 9025-1 in class 9 and section 12.12.
17.6.2 General stowage precautions for substances harmful to the marine environment (MARINE POLLUTANTS).
17.6.2.1 Where stowage is permitted on deck or under deck, units loaded with marine pollutants should preferably be stowed under deck, except when a weather deck provides equivalent protection. 17.6.2.2 Where stowage on deck only is required, preference should be given to the stowage of units loaded with marine pollutants on well-protected decks or to stowage inboard in sheltered areas of exposed decks. 17.6.3 Segregation of dangerous goods within units.
17.6.3.1 Dangerous goods which have to be segregated from each other should not be loaded into the same unit. However, dangerous goods which should be separated AWAY FROM each other may be loaded into the same unit with the approval of the competent authority concerned In such cases an equivalent standard of safety should be maintained. 17.6.4 Segregation of units on board roll-on roll-off ships.
17.6.4.1 Requirements in this respect are laid down in section 15 of this General Introduction. 17.6.5 Securing of cargo transport units*.
17.6.5.1 On roll-on roll-off ships carrying dangerous goods, all units should be secured in accordance with SOLAS Chapter VII, regulation 6.6 (Cargo Securing Manual) and all securing should be completed before the ship leaves the berth. 17.7 17.7.1 Packing or loading of dangerous goods into a unit The load carrying portion of a unit into which dangerous goods are to be loaded should be examined visually for damage and, if there is evidence of damage, the unit should not be used. Irrelevant labels, placards and marine pollutant marks should be removed or masked before loading dangerous goods into a unit. When dangerous goods form only part of the contents of a unit, they should preferably be loaded into the unit so as to be accessible.
17.7.2 17.7.3
* See also MSC/Circ. 745 on the Guidelines for the Preparation of the Cargo Securing Manual in the Supplement to this Code
18 DANGEROUS GOODS IN LIMITED QUANTITIES 18.1 The requirements of this section concern the transport of dangerous goods of certain classes packed in limited quantities. The quantity limitations are specified in 18.3, but are subject to the exemptions provided elsewhere in this section. The full requirements of this Code apply equally to limited quantities except as provided elsewhere in this section. 18.2 The requirements contained in this section do not apply to: 1 2 3 4 5 6 7 8 9 Explosives of Gases of (with exception of AEROSOLS, UN No. 1950) which exhibit a flammable corrosive, oxidizing or toxic risk; Self-reactive and related substances and desensitized explosives of class 4.1; Substances of class 4.2 which are liable to spontaneous combustion; Organic peroxides of class 5.2 requiring temperature control; Infectious substances of class 6.2; Radioactive materials of class 7; Dangerous goods in packaging group I, and; ASBESTOS, UN Nos. 2212 and 2590, POLYCHLORINATED BIPHENYLS, UN No. 2315, POLYHALOGENATED BIPHENYLS and POLYHALOGENATED TERPHENYLS, UN Nos. 3151 and 3152 c class 9.
18.3 Quantity limitations Class Packaging group State Maximum quantity per inner packaging 120 ml (maximum inner volume in metal, plastics or glass packaging) or 1000 ml b (AEROSOLS) 1l b 5lb 500 g 3kg d 500 g 1 kg d 500 g 1 kg d 100 g 25 ml 500 g 125 ml
2a 3 3 4.1
c
Gas II III II III II III II III II II II II Liquid Liquid Solid Solid Liquid or solid Liquid or solid Liquid or solid Liquid or solid Solid Liquid Solid Liquid
4.1 c 4.3 4.3 5.1 5.1 5.2 e 5.2 e 5.2 f 5.2 f
N.B. See footnotes on next page
Class 6.1 6.1 6.1 6.1 8 8 8 8 9 9 9 9
a h h h h
Packaging group II II III III II II III III II II III III
State Solid Liquid Solid Liquid Solid Liquid Solid Liquid Solid Liquid Solid Liquid
Maximum quantity per inner packaging 500 g 100 ml 3 kg d 1/b 1 kg d 500 ml g 2 kg d 1/b 3 kg d 1/b 5 kg d 5/b
Excluding gases (with the exception of AEROSOLS UN No.1950) which exhibit a flammable, corrosive, oxidizing or toxic risk. 500 ml for severe marine pollutants.
b c
Excluding self reactive and related substances and desensitized explosives. d 500 g for severe marine pollutants. e The organic peroxide should be of type B or C and should not require temperature control. See introduction to class 5.2. f The organic peroxide should be of type D,E or F and should not require temperature control See sections 3 and 10.1 of the introduction to class 5.2.
g Glass porcelain or stoneware inner packagings should be enclosed in a compatible and rigid intermediate packaging. h Excluding ASBESTOS UN Nos. 2212 and 2590 POLYCHLORINATED BIPHENYLS, UN No. 2315 and POLYHALOGENATED BIPHENYLS AND POLYHALOGENATED TERPHENYLS, UN Nos. 3151 and 3152.
18.4
Packing
18.4.1 Dangerous goods transported according to these special requirements should be packaged only in inner packagings placed in a suitable outer packaging. The packagings should meet the requirements of Annex I, sections 3132 and 3.4 to 3.8 and be so designed that they meet the construction requirements of Annex I, section 7. The total gross mass of a package should not exceed 30 kg and should, in no case exceed that permitted in the individual schedules for the substances concerned. 18.4.2 Shrink- or stretch-wrapped trays meeting the conditions of Annex I, sections 3.1, 3.2 and 3.4 to 3.8 are acceptable as outer packagings for articles or inner packagings containing dangerous goods transported in accordance with these special requirements, except that inner packagings that are liable to break or be easily punctured, such as those made of glass, porcelain, stoneware or certain plastics, materials, etc. should not be transported in such packagings. The total gross mass of the package should not exceed 20 kg.
18.5 Stowage
18.5.1 Notwithstanding the stowage requirements given in the schedules, dangerous goods carried under the provisions of this section are allocated to stowage category A. 18.6 Segregation
18.6.1 Different dangerous goods in limited quantities may be packaged in the same outer packaging, provided the segregation requirements of section 15 are taken into account and the goods will not interact dangerously in the event of leakage. 18.6.2 The segregation requirements of section 15 of this General Introduction are not applicable for packagings containing dangerous goods in limited quantities or in relation to other dangerous goods.
18.7
Marking and labelling
18.7.1 Packages of dangerous goods transported in accordance with the special requirements of this section: .1 need not be labelled nor bear the MARINE POLLUTANT mark; .2 should, unless otherwise provided, be marked with either; .2.1 the proper shipping name together with the UN number; or .2.2 the words "dangerous goods in limited quantities of class/classes......" which should be regarded as the proper shipping name, in which case no UN Number need be marked on the packaging. 18.7.2 Cargo transport units containing dangerous goods in only limited quantities need not be placarded. They should, however, be suitably marked on the exterior as "LIMITED QUANTITIES". 18.8 Documentation
18.8.1 In addition to the requirements for documentation specified in section 9 of this Genera] Introduction, the words "limited quantity" should be included on the dangerous goods declaration together with the description of the shipment.
18.8.2 For AEROSOLS (UN No. 1950) no division is assigned and the class to be shown on the dangerous goods declaration is "2" (see 9.3.2). 18.9 Exemptions
18.9.1 Limited quantities of dangerous goods for personal or household use that are packaged and distributed in a form intended or suitable for safe through retail agencies may be exempted from marking of the proper shipping name and UN Number on the packaging.
19 CARRIAGE OF DANGEROUS GOODS IN SHIPBORNE BARGES ON BARGE-CARRYING SHIPS 19.1 General
19.1.1 Because of the structural differences of barge-carrying ships from conventional ships, this section contains alternative and special or additional provisions for the transport of packaged dangerous goods or solid bulk materials possessing chemical hazards on these ships. 19.2 Applicability
19.2.1 The provisions of this section are applicable to shipborne barges in which packaged dangerous goods or solid bulk materials possessing chemical hazards are carried while aboard barge-carrying ships or barge feeder vessels. 19.2.2 The provisions of this section are not intended to apply to shipborne barges designed for carriage aboard bargecarrying ships while the shipborne barges are operating independently of the barge-carrying ship. 19.2.3 Barges used for the shipborne carriage of packaged dangerous goods or solid bulk materials possessing chemical hazards should be of proper design and adequate strength to resist the stresses imposed by the conditions of the services in which they are employed and they should be adequately maintained. Shipborne barges should be approved in accordance with requirements for certification of a recognized classification society, or any organization approved by and acting on behalf of the competent authority of the countries concerned. 19.2.4 Except as otherwise specified in this section, all the provisions laid down for each substance in this Code should apply to the carriage of packaged dangerous goods or solid bulk materials possessing chemical hazards in shipborne barges on barge-carrying ships. 19.2.5 The provisions of this section apply only to shipborne barges of steel construction. Packaged dangerous goods or solid bulk materials possessing chemical hazards should only be carried in shipborne barges constructed of other materials, including the hatch covers, under conditions specified by the competent authority concerned. 19.3 Definitions
19.3.1 Shipborne barge or barge means, for the purposes of this section, an independent, non-self-propelled vessel, specially designed and equipped to be lifted in a loaded condition and stowed aboard a barge-carrying ship or barge feeder vessel. 19.3.2 Barge-carrying ship means a ship specially designed and equipped to carry shipborne barges. 19.3.3 Barge feeder vessel means a vessel specially designed and equipped to transfer shipborne barges to or from a barge-carrying ship. 19.3.4 Loading and unloading means the placement or removal of cargo into or out of a shipborne barge. 19.3.5 Stowage means, for the purposes of this section, the placement of a shipborne barge aboard the barge-carrying ship or barge feeder vessel.
21 CONTROLLED TEMPERATURE REQUIREMENTS 21.1 21.1.1 Preamble If the temperature of certain substances (e.g. organic peroxides and self-reactive and related substances) exceeds a value which is typical of the substance as packaged for transport, a self-accelerating decomposition, possibly of explosive violence, may result. To prevent such decomposition, it is necessary to control the temperature of the substance during transport. Other substances not requiring temperature control for safety reasons may be transported under controlled temperature conditions for commercial reasons. The requirements for the temperature control of certain specified substances are based on the assumption that the temperature in the immediate surroundings of the cargo does not exceed 55C during transport and attains this value for a relatively short time only during each period of 24 hours. If a substance which is not normally temperature-controlled is transported under conditions where the temperature may exceed 55C, it may require temperature control; in such cases adequate measures should be taken. Definitions Control temperature is the maximum temperature at which certain substances (e.g. organic peroxides and selfreactive and related substances) can be safely transported during a prolonged period of time. Emergency temperature is the temperature at which emergency procedures should be implemented. Self-accelerating decomposition temperature (SADT)* is the lowest temperature at which self-accelerating decomposition may occur for a substance in the packaging as used in transport.
21.1.2
21.1.3 21.2 21.2.1 21.2.2 21.2.3
21.2.3.1 The relationship between SADT, the control temperature and the emergency temperature is as follows: SADT 20C or less over 20C to 35C over 35C 21.3 21.3.1 General requirements The substances for which a control temperature and an emergency temperature are indicated in the individual schedules should be transported under conditions of temperature control such that the temperature of the immediate surroundings of the cargo does not exceed the control temperature. Control temperature 20C below SADT 15C below SADT 10C below SADT Emergency temperature 10C below SADT 10C below SADT 5C below SADT
* The self-accelerating decomposition temperature (SADT) should be determined in accordance with the latest version of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria. Test methods for determining flammability are given In Part III, section 32.4 of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria. Because organic peroxides may react vigorously when heated, it is recommended to determine their flashpoint using small sample sizes such as described in ISO 3679.
21.3.2 The actual transport temperature may be lower than the control temperature but should be selected so as to avoid dangerous separation of phases. 21.3.3 If, during transport the control temperature is exceeded, an alerting procedure should be initiated involving either repair of the refrigeration machinery or an increase in the cooling capacity (e.g. by adding liquid or solid refrigerants). If an adequate cooling capacity is not restored, emergency procedures, including preparation for disposal of the cargo, together with temperature checks at frequent intervals, should be started. 21.4 Methods of temperature control.
21.4.1 The suitability of a particular means of temperature control for transport depends on a number of factors. Among those to be considered are: 1 2 3 4 the control temperature (s) of the substance (s) to be transported; the difference between the control temperature and the anticipated ambient temperature conditions; the effectiveness of the thermal insulation of the cargo transport unit. The overall heat-transfer coefficient should not be more than 0.4 W/m2* K for freight containers and 0.6 W/m2* K for tanks; the duration of the voyage.
21.4.2 Suitable methods for preventing the control temperature from being exceeded are in order of increasing capability: 1 2 thermal insulation, provided that the initial temperature of the substance is sufficiently below the control temperature; thermal insulation and coolant system, provided that:
2.1 an adequate quantity of non-flammable coolant (e.g. liquid nitrogen or solid carbon dioxide) allowing a reasonable margin for delay, is carried; 2.2 liquid oxygen or air is not used as coolant. 2.3 there is a uniform cooling effect even when most of the coolant has been consumed; and 2.4 the need to ventilate the transport unit before entering is clearly indicated by a warning on the door (s). 3 single mechanical refrigeration provided that the unit is thermally insulated and for substances with a flashpoint lower than the sum of the emergency temperature plus 5C explosion-proof electrical fittings are used within the coolant compartment to prevent ignition of flammable vapours from the substances; combined mechanical refrigeration system and coolant system, provided that:
4.1 the two systems are independent of one another; and 4.2 the requirements of 21.4.2.2 and 21.4.2.3 are met. 5 dual mechanical refrigeration system, provided that: 5.1 apart from the integral power supply unit, the two systems are independent of one another; 5.2 each system alone is capable of maintaining adequate temperature control; and 5.3 for substances with a flashpoint lower than the sum of the emergency temperature plus 5C explosion proof electrical fittings are used within the coolant compartment to prevent ignition of flammable vapours from the substances.
Survey Manager Australian Maritime Safety Authority 3rd Floor 22 Queen Street Fremantle WA6160 Tel.+ 61 9 430 2100 Marine Surveyor Australian Maritime Safety Authority Suite 4 Ansett Building Wedge Street Port Hedland WA 6721 Tel.+ 61 91 73 2598 Senior Marine Surveyor Australian Maritime Safety Authority P.O. Box 860 Karratha WA 6714 Tel.+ 61 91 85 2640 BAHAMAS Bahamas Maritime Authority Bahamas House 10 Chesterfield Street London W1X 8AH United Kingdom Tel.+ 44 171 290 1500 Telefax+ 61 91 44 2023 P.O. Box 1 79 Port Hedland WA 6721
AUSTRALIA continued
P.O. Box 1332 Fremantie WA 6160 Telefax+ 619 430 4757
Telefax+ 61 91 73 2887
Telefax+ 44 171 290 1540 Telex 892617 BAHREG G
BELGIUM
Head Office Dutch Ministerie van Verkeer en Infrastructuur Bestuur van de Maritieme Zaken en van de Scheepvaart Aarlenstraat 104 1040 Brussel Tel+ 32 2 233 1211
Telefax+ 32 2 230 30 02 Telex 61880 VERTRA B
French Ministere des Communications et de I' Infrastructure Administration des Affaires Maritimes et de la Navigation rue d' Arlon 104 1040 Bruxelles Tel.+ 32 2 233 12 11 Telefax+ 32 2 230 30 02 Telex 61880 VERTRA B
BELGIUM continued Antwerp Office Ministerie van Verkeer en Infrastructuur Bestuur van de Maritieme Zaken en van de Scheepvaart Zeevaartinspektie Tavernierkaai 3 Loodsgebouw 2000 Antwerpen Tel.+ 32 3 222 08 11 Ostend Office Ministerie van Verkeer en Infrastructuur Bestuur van de Maritieme Zaken en van de Scheepvaart Zeevaartinspektie Sir Winston Churchillkaal 2 8400 Oostende Tel. + 32 59 55 28 11 BRAZIL Directoria de Portos e Costas Departamento do Material da Marinha Mercante (DPC-20) Rua 1 de marco, 118/16 andar 20010 Rio de Janeiro RJ Tel. + 55 21 216 5203 + 55 21 216 5402
Telefax + 32 3 233 67 60 Telex 35028 MARPOL B
Telefax + 32 59 55 28 88 Telex 82125 LOODSW B
Telefax + 55 21 216 5202 + 55 21 216 5207 + 55 21 216 5217
BULGARIA
Main Office State Shipping Inspectorate Ministry of Transport Levski Str 9/11 1000 Sofia Tel. + 359 2 88 55 29 Sections 1 State Shipping Inspectorate Chervenoarmejski Blvd 1 Varna Tel. + 359 52 2 54 09 2 State Shipping Inspectorate Burgas-port Burgas Tel. + 359 56 4 31 40
IMDG CODE - PAGE 0160d (page 0160e follows) Amdt. 28-96
CANADA The Chairman Canada Building 344 Slater Street Ottawa Ontario K1A 0N7 Tel.+ 1 613 991 3143 The Chairman Board of Steamship Inspection Transport Canada - Marine Safety Tower C Place de Ville 330 Sparks Street 11th floor Ottawa Ontario K1A ON8 Tel.+ 1 613991 3132 + 1 613 991 3143 + 1 613 991 3140 CHILE Direccion General del Territorio Maritime y de Marina Mercante Direccion de Seguridad y Operaciones Maritimas Depto Prevencion de Riesgos Errazuriz 537 Valparaiso Tel.+ 56 32 208256 Telefax +1 613 993 8196 Telefax + 1 613 993 8196 Telex 0533128 COASTGUARD OTT
Telefax + 56 32 208262 Telex 230602 DGTM CL 330461 DGTM CK
CHINA
The Bureau of Harbour Superintendency of the Peoples Republic of China 10 Fu Xing Road Beijing 100 845 Tel:+ 86 1 3260674
Telefax + 86 1 3264025 Telex 222258 CMSAR CN
CROATIA
Ministry of Maritime Affairs Transport and Communication Marine Safety Division Prisavlje 14 1000 Zagreb Tel:+ 385 1 611 5966
Telefax + 385 1 611 5968 E mail pomorski promet@29 Tel:hr
Testing and certification of packagings Adriainspekt Ciottina 17/b 51000 Rijeka Tel:+ 385 51 511 133
Telefax + 385 51 36 176
IMDG CODE - PAGE 0160e (page 0160f follows) Amdt. 29-98
CROATIA continued Classification society for CSC Containers (including IMO tanks) Croation Register of Shipping Marasoviceva 67 21000 Split Tel:+ 385 21 358 933 Telefax + 385 21 358 159 Department of Merchant Shipping Ministry of Communications and Works Kyliinis Street Mesa Geltonia CY-4007 Lemesos PO Box 6193 CY 3305 Lemesos Tel:+ 357 5 848100 Implementation Ministry of Transport of the Czech Republic Navigation and Waterways Division Nabrezi L Svobody 12 11015 Praha 1 Tel:+ 42 2 230 312 25 Packaging testing and certification institute CIMTO sp U Michelskeho lesa 336 146 23 Praha 4 Tel:+ 42 2 472 94 64 IMET s ro Bazantni 697 165 00 Praha 6 Tel:+ 42 2 39 32 96 Classification of dangerous goods of all classes except class 7 - radioactive materials Cesky lodni a prumyslovy registr s.r.o. (Czech Shipping and Industry Register Ltd. ) Jankovcova 10 1 70 00 Praha 7 Tel:+ 42 2 667 100 01
CYPRUS
Telefax + 357 5 848200 Telex 2004
CZECH REPUBLIC
Telefax + 42 2 248 105 96 Telex 42 2 12 10 96 DOMI C
Telefax + 42 2 472 36 76
Telefax + 42 2 29 23 70
Telefax + 42 2 808 984 Telex 422 122 874 CSLR C
IMDG CODE - PAGE 0160f (page 0160g follows) Amdt. 29-98
DENMARK Danish Maritime Authority P.O. Box 2605 Vermundsgade 38C 2100 Copenhagen 0 Tel:+ 45 39 271515 Teletex 119204 SOEFART DK Telegrams Soefart Packaging, testing and certification institute Emballage og Transportinstrtuttet (E T i ) Dansk Teknologisk Instrtut Emballage og Transportinstituttet Gregersensve) 2630 Tastrup Direccion General de la Marina Mercante y del Litoral P.O. Box 7412 Guayaquil Tel:+ 593 4 526 760
Telefax + 45 39 271516 Telex 31141 SOEFART DK
ECUADOR
Telefax + 593 4 324 246 Telex 04 3325 DIGMER ED
ESTONIA
Estonian National Maritime Board 13 Tartu Road Tallinn EE 0001 Tel:+ 372 2 430202
Telefax + 3726 312303 Telex 173027 EVA EE
FINLAND
Finnish Maritime Administration P.O. Box 171 00181 Helsinki Tel:+ 358 2044840
Telefax + 358 204484500 + 358 204484336 Telex 121471 MKH FI
Packaging and certification institute Safety Technology Authority P 0 Box 123 00181 Helsinki Tel:+ 358 9 61671 FRANCE Ministere de I'equipement, des transports et du tourisme Direction des ports et de la navigation maritimes Bureau du controle des navires 3, Place de Fontenoy 75700 Pans Tel:+ 33 1 44 49 86 49
Telefax 358 9 6167466
Telefax + 33 1 44 49 86 40 Telex 250823 F MIMER
GAMBIA The Managing Director Gambia Ports Authority Banjul Tel: + 220 27266
Telefax: + 220 27268 Telex: 2235 GAMPORTS GV
GERMANY
Ministry of Transport Postfach 20 01 00 Robert-Schuman-Platz 1 53175 Bonn Tel: + 49 228 300 0 or 300 Extension + 49 228 300 2632 + 49 228 300 2435
Telefax: + 49 228 300 2409 + 49 228 300 3428 + 49 228 300 3429 Telex: 885700 BMV D
Federal Institute for Materials Research and Testing for dangerous goods and packagings, IBCs and multi-modal tank containers: Bundesanstalt fur Materialforschung und -prufung (BAM) Unter den Eichen 87 12205 Berlin Tel: + 49 30 81 04 0 or Extension Telefax: + 49 30 81 04 12 01 + 49 30 81 04 1310 GREECE Ministry of Mercantile Marine Safety of Navigation Division (Section B) 150 Gr. Lambraki Av. 185 18 Piraeus Tel: + 30 1 4174480
Telefax: + 30 1 4112500 Telex: 212022 212239 YEN GR
ICELAND
Iceland Maritime Administration Vesturvor 2 IS-202 Kopavogur Tel: + 354 560 0000 Directorate of Shipping Hringbraut 121 P.O. Box 7200 127 Reykjavik Tel: + 354 1 25844
Telefax: + 354 560 0060 E-mail: skrifstofa@vh.is
Telefax: + 354 1 29835 Telex: 2307 ISINFO
INDIA The Directorate General of Shipping Jahaz Bhawan Walchanc Hirachand Marg Bombay 400 001 Tel:+ 91 22 263651 Packaging, testing and certification institute Indian Institute of Packaging Bombay Madras Calcutta IRAN Ports and Shipping Organization 751 Enghelab Avenue Tehran Tel:+ 98 21 837041 to 49 The Chief Surveyor Marine Survey Office Department of the Marine 26/27 Eden Quay Dublin 1 Tel:+ 353 18744900 + 353 18722045 + 353 18743325 Technical Services Department Shipping and Ports Administration 102 Haatzmaut Rd Haifa Tel:+ 972 4 535640
Telex DEGESHIP 2813-BOMBAY
Telex 212271 BNDR-IR
IRELAND
Telefax + 353 872 4491 Telex 33358 MSO EI
ISRAEL
Telex 46632
ITALY
Ministero della Marina Mercantile Viale Asia-eur 00144 Roma Tel:+ 39 6 5908 Ministero del Transporti e della Navigazione Comando Generale del Corpo delle Capitanerie di Porto Direzione Servizi Sicurezza delta Navigazione Ponte del Mille 16100 - Geneva Tel:+ 39 1024 12 443 Genera! Manager Comte A Verani IMDG Dept Compte F Carpinteri
Telex 612153 MIMERC I
Telefax + 39 10 24 12 797
JAMAICA Testing and certifying authority The Bureau of Standards 6 Winchester Road PO Box 113 Kingston Tel:+ 1 809 92 63140 7 Cable STANBUREAU Inspection and Measurement Division Marine Technology and Safety Bureau Ministry of Transport 2-1-3 Kasumigaseki, Chiyoda-ku Tokyo Tel:+813 3580 6398 Packaging, testing and certification institute Nippon Hakuyohin KenTel:Kyokal (HK) (The Ship Equipment Inspection Society of Japan) 3-32, KiOi-Cho, Chiyoda-ku Tokyo Tel:+ 81 3 3261 6611 LATVIA Maritime Administration of Latvia 5 Trijadibas iela LV 1048 Riga Tel:+ 371 7 86 00 81
Telex 2291 STANBUR Jamaica
JAPAN
Telefax + 81 3 3580 7960 Tetex 222 7381
Telefax +813 3261 6979
Telefax + 371 7 86 00 82
LIBERIA
National Port Authority Monrovia Liberia Tel:+ 231 221 306 Telex 44275 NPA LBR Office of the Commissioner of Maritime Affairs, R L Bureau of Maritime Affairs Providence Building Monrovia, Liberia Tel:+ 231 224 604/908 Telefax + 231 226 069 Office of the Deputy Commissioner of Maritime Affairs, R L Technical Division Marine Operations Department c/o Liberian Services Inc 11495 Commerce Park Drive Reston, Virginia, 22091-15007 USA Tel:+ 703 620 4880 Telefax + 703 476 8522 Telex 248403 IRI UR
IMDG CODE - PAGE 0160j (page 0160k follows) Amdt. 29-98
MALAYSIA Director Marine Department Peninsular Malaysia P 0 Box 12 42009 Port Kelang Selangor Director Marine Department, Sabah P 0 Box 5 87007 Labuan Sabah Director Marine Department, Sarawak P 0 Box 530 93619 Kuching Sarawak MEXICO Stowage, segregation labelling and documentation of goods Coordinacion General de Puertos y Marina Mercante Secretaria de Comunicaciones y Transportes Av MuniCipio Libre No 377 Piso 12, Ala B Col Santa Cruz Atoyac 03010, Mexico D F Tel:6 04 42 49 6 04 38 29 Coordinador General Lie Pedro Pablo Zepeda Bermudez Reporting procedures in the case of packages lost overboard Secretaria de Marina Eje 2 oriente tramo H Escuela Naval Militar No 861 04830, Mexico D F Tel:6 84 81 88 Telefax ext 3201 Subsecretario de Marina Almirante CG D E M Felix Jaime Perez y Elias Laboratory tests for packages containing dangerous goods Direccion General de la Sociedad Mexicana de Normalizacion y Certificacion S C (NORMEX) Alfredo Novel No 21, Centro Industrial Puente de Vigas 54070, TIalnepantIa Estado de Mexico Tel:5 65 72 72 Director General Lie Carlos Sauceda Alvarez MOROCCO Direction de la Marine Marchande et des Peches Maritimes Boulevard EI Hansali Casablanca Tel:+ 212 2 278 092 Telex 24613 MARIMAR M + 212 2 221 931 22824
Telex MA 39748
IMDG CODE - PAGE 0160k (page 01601 follows) Amdt 28-96
NETHERLANDS Ministry of Transport, Public Works and Water Management State Traffic Inspectorate Transpprt Information Centre P.O. Box 11063 3004 EB Rotterdam Tel: + 31 10 4370888 Ministry of Transport, Public Works and Water Management Directorate-General for Freight Transport P.O. Box 20904 2500 EX The Hague Tel:+ 31 70351 6171 P.O. Box 20904 2500 EX Den Haag Bezoekadres Willem Witsenplein, 6 2596 BK Den Haag Tel:+ 31 70 351 6171 P.O. Box 5817 2280 HV Rijswijk Tel:+ 31 7039 5S 555
Telefax:+ 31 104370437
Telefax:+ 31 70 351 1479
Telefax:+ 31 70 351 7895
Telefax:+ 31 7039 96 274 Telex: 31040 DGSMNL
Packaging, Testing and Certification Institute TNO Centrum voor Verpakking P.O. Box 6034 2600 JA Delft Classification societies have been designated as competent inspector agencies for the approval, acceptance and all consequential activities connected with portable tanks, tank containers and road tank vehicles to be registered in the Netherlands: Lloyd's Register of Shipping Bureau Veritas Germanischer Lloyd Det norske Veritas American Bureau of Shipping Registro Italiano Navale Nippon Kaiji Kyokai RDW, Dienst Wegverkeer* S.G.S, Redwood Nederland B.V.** * roadtank vehicles only ** 2.5 year (midway) inspections' of IMO type 1 or 2 only
IMDG CODE - PAGE 01601 (page 0160m follows) Amdt. 29-98
NEW ZEALAND Director of Maritime Safety Maritime Safety Authority of New Zealand Level 8 AMP House 109 Featherstone Street P.O. Box 27006 Wellington Tel+ 6444730111 + 64 4 472 7367*
Telefax+ 64 4 473 0999
* This number is for the Marine Duty Officer who is available 24 hours a day Competent inspection agencies for the approval, inspection and testing of all portable tanks tank containers and freight containers in New Zealand American Bureau of Shipping Bureau Veritas Det. Norske Veritas Lloyd's Register of Shipping NORWAY Norwegian Maritime Directorate Stensberggt 27 P.O. Box 8123 Dep. 0032 Oslo Tel+ 47 22 45 45 00 Classification societies: For CSC containers Det. norske Veritas Veritasveien 1 1322 Hovik For IMO tanks Det. norske Veritas Veritasveien 1 1322 Hovik Lloyd's Register of Shipping Arbiensgt 11 0253 Oslo 2 PAKISTAN Mercantile Marine Department 70/4 Timber Hard N M Reclamation Keamari, Post Box 4534 Karachi Tel+ 92 21 270117 + 92 21 270118 + 92 21 270119 + 92 21 270289
Telefax+ 47 22 56 87 80 Telex 21557 SDIR N
Telex 2733 NSC KAR 2833 2683 2765
PANAMA Direccion General Consular y Naves Apartado Postal 5245 Panama 5 First Assistant Secretary Department of Transport Division of Marine P 0 Box 457 Konedobu Tel.+ 675 211866 Direccion General de Capitanias y Guardacostas 102 de Nieto Plaza Grao Callao 1 Tel.+ 51 14 29 7278 + 51 14 29 4692 Empresa Nacional de Puertos S. A Av. Guardia Chalaca S/N Tel.+ 51 14 654280 + 51 14 290355 Philippine Ports Authority Port of Manila Safety Staff P.O. 193, Port Area Manila, 2803 Tel.+ 63 2 47 34 41 to 49 Ministry of Transport and Maritime Economy Department of Maritime and Inland Waters Administration ul. Chalubinskiego 4/6 00-928 Warszawa Tel.+ 48 26 211 448 Telefax+ 48 26 288 515 Telex 816651 PKP PL Packaging, testing and certification institute Centralny Osrodek Badawczo-Rozwojowy Opakowan ul. Konstancinska, 11 02-942 Warszawa Tel.+ 48 22 42 20 11 Telefax+ 48 22 42 23 03 Telex 812473 Classification societies For CSC containers Polski Rejestr Statkow al Gen J. Hallera 126 80-416 Gdansk Tel.+ 48 58 41 17 64 Telefax+ 48 58 46 03 92 + 48 58 46 03 82 + 48 58 46 13 96 + 48 58 41 64 82 Telex 512952 PRS PL
PAPUA NEW GUINEA
Telex 22203
PERU
Telefax+ 51 14 653908 Telex 26071 PE DICAPI
Telefax+ 51 14 656415 Telex 26010
PHILIPPINES
POLAND
PORTUGAL Direccao-Geral de Navegacao e dos Transportes Maritimos Praca Luis de Camoes, 22 - 2 Dto. 1200 Lisboa Tel:+ 351 1 373821 Telefax:+ 351 1 373826 Telex: 16753 SEMM PO REPUBLIC OF KOREA Ship Technology Division Ship Bureau Korea Maritime and Port Administration 112-2, Inui-dong, Chongno-gu Seoul, 110-410 Tel:+ 82 2 744 4742
Telefax:+ 82 2 3672 1175 Telex: K 26523
RUSSIAN FEDERATION
Department of Shipping and Navigation Ministry of Transport Rozhdestvenka Street, 1/4 Moscow 103759 Tel:+ 7 095 228 38 82
Telex: 411197 MORFLOT
Classification society has been designated as competent inspector agency for the approval, acceptance and all consequential activities connected with IMO Type tanks, CSC containers, Intermediate Bulk Containers (IBCs) and Packaging to be registered in the Russian Federation: Russian Maritime Register of Shipping Tel:+ 781231288 78 Telefax:+ 7 812 314 1087 + 781231407 43 Telex; 121525 RSSU RU E-mail: pobox@rs-head.spb.ru Ministry of Transport of the Russian Federation Regulation of Maritime Transport Operation Department -1/4, Rozhdestvenka Street Moscow, 103759 Tel:+ 7095926 14 23 Telefax:+ 7 095 926 90 38 + 7 095 92S 18 62 + 7 095 926 91 28 Telex: 411197 MMF RU Packaging, Testing and Certification Institute Central Marine Research & Design Institute (CNIIMF) 6, Kavalergardskaja Street Saint-Petersburg, 193015 Tel:+ 7 812 275 89 47
Telefax:+ 7812 2743864 Tetex: 821483 CNIMF RU
SAUDI ARABIA Port Authority Saudi Arabia Civil Defence Riyadh Tel:+ 966 1 464 9477 Maritime and Port Authority of Singapore 18th Storey PSA Building 460 Alexandra Road Singapore 119963 PSA Building Post Office P.O. Box 313 Singapore 911141 Tel:+ 65 375 1689 Uprava Republike Solvenije za pomorstvo Ukmarjev trg. 2 66 000 Koper Tel:+ 386 66 271 216
SINGAPORE
Telefax:+ 65 275 9247
SLOVENIA
Telefax:+ 386 66 271 447 Telex: 34235 UP POM SI
SOUTH AFRICA
South African Maritime Safety Authority P.O. Box 13186 Hatfield 0028 Pretoria Tel:+ 12 342 3049 South African Maritime Safety Authority Hatfield Gardens: Block E (Ground Floor) Corner Arcadia and Grosvenor Streets Hatfield 0083 Pretoria Head Office Administrations; Chief Director Chief Directorate: Shipping Department of Transport Private Bag X193 0001 Pretoria Tel:+ 27 12 2902904 Durban, East London, Port Elizabeth and Richards Bay; Chief Ship Surveyor Eastern Zone Department of Transport Marine Division Private Bag X54309 4000 Durban Tel:+ 27 12 3071501
Telefax:+ 12 342 3160
Telefax:+ 27 12 3237009
Telefax:+ 27 12 3064983
SOUTH AFRICA continued Cape Town, Sal dan ha Bay and Mossel Bay Chief Ship Surveyor Western Zone Department of Transport Marine Division Private Bag X7025 8012 Roggebaal Tel:+ 27 21 216170 Direccion General de la Marina Mercante c/Ruiz de Alarcon, 1 28014 Madrid Tel:+ 34 1 580 1464 (Office hours) + 34 1 580 1465 (Office hours) + 34 1 521 7943 (24 hours) Swedish Maritime Administration Maritime Safety Inspectorate Ship Division 601 78 Norrkoping Tel:+ 46 11 191000 Packaging, testing and certification institute Swedish National Testing and Research Institute Materials and Mechanics Box 857 501 15 Boras SWITZERLAND Office suisse de la navigation maritime Elisabethenstrasse, 31 4002 Basel Tel:+ 41 61 287 14 44
Telefax+ 27 21 4190730
SPAIN
Telefax+ 34 1 521 9510 Telex 41210 SAMAD E 41224 SAMAD E
SWEDEN
Telefax+ 46 11 239934 Telex 64380 SHIPADMS S
Telefax+ 41 61 287 15 70 Telex 965514 SSU CH
THAILAND
Ministry of Transport and Communications Ratchadamnoen-Nok Avenue Bangkok 10 100 Tel:+ 66 2 2813422
Telefax+ 66 2 2801714 Telex 70000 MINOCOM TH
TUNISIA
Direction Generate de la Marine Marchande 24 Avenue de la Republique 1001 Tunis Tel:+ 216 1 259 117
Telefax+ 216 1 354 244 Telex
Maritime and Coastguard Agency Bay 2/25 Spring Place 105 Commercial Road Southampton SO15 1EG Tel+ 44 1703 329177 Packaging, testing and certification institute PIRA International Randalls Road Leatherhead Surrey KT22 7RU
UNITED KINGDOM
Telefax+ 44 1703 329204
UNITED STATES
Hazardous Materials Standards Branch Operating and Environmental Standards Division (G MOS-3) 2100 Second Street SW Washington, DC 20593-0001 Tel+ 1 202 267 1577 Telefax+ 1 202 267 4570 + 1 202 267 1217 Telex 892427 US Department of Transportation Research and Special Programs Administration International Standards Coordinator (DHM-5) 400 Seventh Street SW Washington, DC 20590-0001 Tel+ 1 202 366 0656 Telefax+ 1 202 366 5713 Silila Patane Harbourmaster Port Administration PagoPago American Samoa 96799 Prefectura del Puerto de Montevideo RambIa 25 de Agosto de 1825 S/N Montevideo Tel+ 598 2 960123 + 598 2 960022 Commissioner of Maritime Affairs Private Mail Bag 023 Port Vila Tel+ 678 22247
AMERICAN SAMOA
URUGUAY
Telex 23929 COMAPRE UY
VANUATU
Telefax+ 678 22242
Associate Member HONG KONG, CHINA The Director of Marine Marine Department GPO Box 4155 Tel: + 852 2852 3085 + 852 2852 4538
Telefax: + 852 2815 8596 + 852 2542 3199 Telex: 64553 MARHQ HX
IMDG CODE - PAGE 0160s (page 0167 follows) Amdt. 29-98
23 23.1 MARINE POLLUTANTS General
23.1.1 Marine pollutants should be carried under the provisions of Annex III as amended of the International Convention for the Prevention of Pollution from Ships 1973 as modified by the Protocol of 1978 relating thereto (MARPOL 73/78). These substances materials or articles are identified in the individual schedules as MARINE POLLUTANT . When a substance material or are tide is suspected to possess properties that may meet the definition of a marine pollutant or severe marine pollutant but is not identified in this Code such substance material or article may be transported as a marine pollutant or severe marine pollutant in accordance with this section. All relevant data should be submitted to GESAMP* as appropriate. 23.1.2 Substances articles or materials that are identified as marine pollutants but do not possess any other hazard are listed in the appendices to the schedules for ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. UN No. 3077 or ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. UN No. 3082 in class 9. These appendices do not list the solutions mixtures and isomers referred to in 23.2.3 and 23.2.4 23.1.3 Certain marine pollutants have an extreme pollution potential** and are identified as severe marine pollutants in the individual schedules. 23.1.4 Certain marine pollutants or severe marine pollutants are identified only in the General Index with an assignment to an appropriate N.O.S or generic entry of classes 1 to 8 although they are not listed in those schedules. 23.1.5 Certain other marine pollutants or severe marine pollutants are identified only in the General Index. These marine pollutants or severe marine pollutants have not been assigned to an N.O.S or generic entry. These marine pollutants or severe marine pollutants may possess properties of classes 1 to 8 and should be classified accordingly. A substance which does not fall within the criteria of these classes should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. UN No. 3077 or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. UN No. 3082 under these entries in class 9. 23.1.6 With the approval of the competent authority substances materials or articles that are identified as marine pollutants in this Code, but which on the basis of a revised GESAMP hazard profile no longer meet the criteria for designation, as a marine pollutant or a severe marine pollutant need not be transported in accordance with the provisions of this Code applicable to marine pollutants.
* Reference is made to the IMO/FAO/UNESCO-IOC/WMO/WHO/IAEA/UN/UNEP Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection. ** A substance is regarded to have an extreme pollution potential if it - is bioaccumulated to a significant extent and known to produce a hazard to aquatic life or human health (Hazard Rating + in column A) and is highly toxic to aquatic life (Hazard Rating 4 in column B) or has particularly high toxicity to aquatic life as defined by LC50/96 hour of 0.01 ppm or less. Refer to the guidelines for the identification of harmful substances in packaged form contained in the appendix to Annex III of MARPOL 73/78 as amended and reproduced in section 23.8 of this General Introduction.
23.2 Solutions, mixtures and isomers
23.2.1 A solution or mixture containing 10% or more of (a) marine pollutant (s) is a marine pollutant. 23.2.2 A solution or mixture containing 1 % or more of (a) severe marine pollutant (s) is a marine pollutant. 23.2.3 A solution or mixture which does not fall within the criteria of classes 1 to 8 but which meets the criteria for marine pollutants under 23.2.1 or 23.2.2 should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. under the entries in class 9 even though it is not listed by name in the appendices thereto. 23.2.4 An isomer of a substance identified as a marine pollutant and covered by a generic entry in classes 1 to 8, but which does not fall within the criteria of these classes should be offered for transport as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. or as an ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. under the entries in class 9 even though it is not listed by name in the appendices thereto. 23.3 Documentation
23.3.1 The basic items of information necessary for each substance material or article offered for transport which should be included in the transport documents to be prepared by the shipper are set out in subsection 9.3 of this General Introduction. 23.3.2 A marine pollutant should only be offered for transport under its proper shipping name given in the appropriate individual schedule It should also be identified as MARINE POLLUTANT in the transport documents When declared under an N.O.S. or generic entry a marine pollutant should always be identified by its recognized chemical name in parentheses. A pesticide or pesticide preparation which is a marine pollutant should be offered for transport under the appropriate pesticide entry supplemented with the name of the specific pesticide and percentage of active ingredient in parentheses. Examples of such a description are ACROLEIN, INHIBITED, class 6.1, UN 1092, P.G. I (3), MARINE POLLUTANT FLAMMABLE ,LIQUID, N.O.S., (ethanol and dodecylphenol) class 3.2, UN 1993, P.G. II, MARINE POLLUTANT CADMIUM, COMPOUND, (cadmium chloride) class 6.1, UN 2570, P.G. I, II or III, MARINE POLLUTANT ORGANOCHLORINE, PESTICIDE, SOLID, TOXIC, (Aldrin 19%) class 6.1, UN 2761, P.G. III MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (carbophenothion 1.5%), class 9, UN 3082, P.G. III, MARINE POLLUTANT ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., (calcium naphthenate) class 9, UN 3077, P.G. III, MARINE POLLUTANT 23.4 Packaging
23.4.1 A marine pollutant should be offered for transport only in packagings which are resistant to the adverse effects of immersion in water.
26.1.5.1.3 Examples of marking: 11A/Y/02.89/ NL/...* 007/5500/1500 For a metal IBC for solids discharged by gravity and made from steel for packaging groups II and III, manufactured in February 1989 authorized by the Netherlands manufactured by* (name of manufacturer) and of a design type to which the competent authority has allocated serial number 007, showing the stacking test load and the maximum permissible gross mass in kilograms.
13H3/Z/03.89/ F/...* 1713/0/500
For a flexible IBC for solids discharged by gravity and made from woven plastics with a liner. Not designed to be stacked.
31H1/Y/04.89/ GB/...* 9099/10800/1200
For a rigid plastics IBC for liquids made from plastics with structural equipment withstanding the stack load.
31HA1/Y/05.89/ D/...* 1683/10800/1200
For a composite IBC for liquids with a rigid plastics inner receptacle and a steel outer casing.
11C/X/01.93/ S/...* 9876/3000/910
For a wooden IBC for solids with an inner liner and authorized for packaging groups I, II or III.
11G/Z/06.89/ I/...* 962/0/500
For a fibreboard IBC Not designed to be stacked.
11D/Y/07.89/ E/...* 261/3240/600
For a plywood IBC with inner liner.
26.1.5.2
Additional marking See specific requirements shown in the relevant subsections.
26.1.5.3 Conformity to design type.
26.1.5.3.1 The marking indicates that the IBCs correspond to a successfully tested design type and that the requirements referred to in the certificate have been met. 26.1.6 26.1.6.1 Operational requirements Before being filled and handed over for transport every IBC should be inspected to ensure, that it is free from corrosion contamination or other damage, with particular regard to the proper functioning of any service equipment. Any IBC which shows signs of reduced strength as compared with the tested design type should no longer be used or should be so repaired that it is able to withstand the design type tests. When filling IBCs with liquids sufficient ullage should be left to ensure that, at the mean bulk temperature of 50C, the IBC is not filled to more than 98% of its water capacity.
26.1.6.2
Note: For a differing temperature the maximum degree of filling can be determined as follows:
Degree of filling =
98 1 + (50 t F )
per cent of the capacity of the IBC.
In this formula represents the mean coefficient of cubic expansion of the liquid substance between 15C and 50C, that is to say, for a maximum rise in the temperature of 35C, is calculated according to the formula:
=
where
d15 d 50 35 d 50
d15 and d50 are the relative densities of the liquid at 15C and 50C and tf is the mean temperature of the
liquid at the time of filling.
26.1.6.3 Where two or more closure systems are fitted in series, that nearest to the substance being transported should be closed first. 26.1.6.4 During transport, no dangerous residue should adhere to the outside of an IBC. 26.1.6.5 Empty uncleaned IBCs which have been used previously for the transport of dangerous substances should be subject to the requirements of this section for filled IBCs unless adequate measures have been taken to nullify any hazard. 26.1.6.6 When IBCs are used for the transport of liquids with a flashpoint of 61C c.c. or lower or of powders liable to dust explosion measures should be taken to prevent a dangerous electrostatic discharge. 26.1.6.7 IBCs used for solids which may become liquid at temperatures likely to be encountered during transport should also be capable of containing the substance in the liquid state. 26.1.6.8 The periodic testing and inspection requirements for IBCs are provided in 26.2, 26.4 and 26.5. An IBC should not be filled and offered for transport after the date of expiry of the last periodic test required by 26.2.6, 26.4.6 or 26.5.6, or the date of expiry of the last periodic inspection required by 26.2.7, 26.4.7 or 26.5.7. However, an IBC filled prior to the date of expiry of the last periodic test or inspection may be transported for a period not to exceed three months beyond the date of expiry of the last periodic test or inspection.
In addition an IBC may be transported after the date of expiry of the last periodic test or inspection: 1 after emptying but before cleaning for purposes of performing the required test or inspection prior to refilling; and 2 unless otherwise approved by the competent authority for a period not to exceed six months beyond the date of expiry of the last periodic test or inspection in order to allow the return of dangerous goods for proper disposal or recycling Reference to this exemption should be entered on the transport document. 26.1.7 26.1.7.1 Marking and labelling Marking the proper shipping name (correct technical name) and labelling of an IBC containing a dangerous substance should be carried out in accordance with the requirements of sections 7 and 8 of this General Introduction.
26.1.8 26.1.8.1
Stowage IBCs should be stowed in accordance with section 14 of this General Introduction and with any requirements in this respect as included in the individual schedules of the substances to be transported. During transport the IBCs should be securely fastened to or contained within the cargo transport unit so that lateral or longitudinal movement or impact is prevented and adequate external support is provided Segregation IBCs containing dangerous substances should be segregated in accordance with the requirements for the segregation of packages of section 15 of this General Introduction. Special requirements relating to IBCs for the transport of organic peroxides (class 5.2)
26.1.8.2
26.1.9 26.1.9.1 26.1.10
26.1.10.1 Each organic peroxide should have been tested and a report made available indicating that transport in IBCs would be safe. The conditions for this transport should be specifically designated by the competent authority of the country of origin. A notification including the report should be sent to the competent authority of the country of destination. The tests undertaken should include those necessary: .1 to prove that the organic peroxide complies with the principles for classification given in 3.3.6 of the introduction to class 5.2; .2 to prove the compatibility of all materials normally in contact with the substance during transport; .3 to determine when applicable the control and emergency temperatures derived from the SADT (Self Accelerating Decomposition Temperature see section 2.1 of this General Introduction). These temperatures may be lower than those indicated for packages in the appendix to the individual schedules; and
.4 to design, when applicable, pressure and emergency relief devices; and any special requirements necessary for the safe transport of the organic peroxide. 26.1.10.2 Emergencies to be taken into account are self-accelerating decomposition of the organic peroxide and fire engulfment. 26.1.10.3 To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices should be designed to vent all the decomposition products and vapours evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire engulfment calculated by the equations given in 13.1.55.8. 26.1.10.4 IBCs should be transported in a closed cargo transport unit. 26.1.10.5 Organic peroxides suitable for transport in IBCs are identified in the appendices to the individual class 5.2 schedules for UN Nos. 3109 and 3119, and in appendix 1 to this section together with the special requirements applicable for their transport. 26.1.11 Special requirements relating to IBCs for the transport of self-reactive substances of class 4.1
26.1.11.1 Self-reactive substances of class 4.1 should have been tested and a report made available indicating that the transport in IBCs would be safe. The conditions for transport should be specified by the competent authority of the country of origin. The tests undertaken should include those necessary: .1 to prove that the self-reactive substance complies with the principles for classification given in 2.2.10.6 of the introduction to class 4.1; .2 to prove the compatibility of all materials normally in contact with the substance; .3 to determine the control and emergency temperatures, if required, for transport of the substance in the IBC concerned, as derived from the self-accelerating decomposition temperature; .4 to determine, when applicable, types of emergency pressure-relief devices; and .5 to determine if any special requirements are necessary. 26.1.11.2 Emergencies to be taken into account are the ability to ignite easily from external sources such as sparks and flames and the likelihood of a strongly exothermic reaction caused by excessively high transport temperatures or by contamination. 26.1.11.3 To prevent explosive rupture of metal IBCs or composite IBCs with complete metal casing, the emergency pressure-relief devices should be designed to vent all the decomposition products and vapours evolved during selfaccelerating decomposition or during a period of not toss than one hour of fire engulfment calculated by the equations given in 13.1, 55.8. 26.1.11.4 Self-reactive substances transported in IBCs with an SADT less than 55C have to be subjected to the temperature control requirements given in section 21 of this General Introduction. 26.1.11.5 IBCs should be transported in a closed cargo transport unit. 26.1.11.6 Self-reactive substances suitable for transport in IBCs are identified in the appendices to the individual class 4.1 schedules, together with the special requirements, if any, applicable to their transport.
26.2 26.2.1 SPECIFIC REQUIREMENTS FOR METAL IBCs. Scope.
26.2.1.1 These requirements apply to metal IBCs for the transport of solids and liquids of the following types:
11A 11B 11N 21A 21B 21N 31A 31B 31N Metal IBCs for solids, which are filled and discharged at a gauge pressure greater than 10 kPa. Metal IBCs for liquids except for liquids having a vapour pressure of more than 110 kPa at 50C or 130 kPa at 55C. Metal IBCs for solids, which are filled and discharged by gravity.
26.2.2
Definitions
26.2.2.1 A metal IBC consists of a metal body together with appropriate service and structural equipment. 26.2.2.2 Body means the receptacle proper including openings and their closures, but does not include service equipment (see 26.2.2.4). 26.2.2.3 Protected means the IBC being provided with additional protection against impact, the protection taking the form of for example, a multi-layer (sandwich) or double wall construction or a frame with a metal lattice-work casing. 26.2.2.4 Service equipment means filling and discharge, pressure-relief safety heating and heat insulating devices and measuring instruments. 26.2.2.5 Structural equipment means the reinforcing fastening handling protective or stabilizing members of the body. 26.2.2.6 Maximum permissible gross mass means the mass of the body and its service equipment and structural equipment and the maximum permissible load. 26.2.3 Construction
26.2.3.1 Bodies should be made of suitable ductile metallic materials in which the weldability has been fully demonstrated Low-temperature performance should be taken into account when appropriate.
26.2.3.2 Care should be taken to avoid damage by galvanic action due to the juxtaposition of dissimilar metals. 26.2.3.3 Aluminium IBCs intended for the transport of flammable liquids should have no movable parts such as covers closures, etc., made of unprotected steel liable to rust which might cause a dangerous reaction by coming into frictional or percussive contact with the aluminium. 26.2.3.4 Metal IBCs should be made of metals which meet the following requirements: 1 For steel, the elongation at fracture, in per cent, should not be less than 10 000/Rm , with an absolute minimum of 20%, where Rm = guaranteed minimum tensile strength of the reference steel to be used, in N/mm2. 2 For aluminium and aluminium alloys, the elongation at fracture in per cent, should not be less than 10 000/6Rm , with an absolute minimum of 8%. Specimens used to determine the elongation at fracture should be taken transversely to the direction of rolling and be so secured that:
L0 = 5 d
or
L0 = 5.65 A
where
Lo d A
= = =
gauge length of the specimen before the test; diameter; and cross-sectional area of the test specimen.
26.2.3.5 Minimum wall thickness 1 For a reference steel having a product of Rm x AO = 10 000, the wall thickness should not be less than
Wall thickness in mm Capacity in m

3
IBCs of types 11A, 11B, 11N Unprotected Protected 1.5 2.0 2.5
IBCs of types 21A, 21B, 21N, 31A, 31B, 31N Unprotected 2.5 3.0 4.0 Protected 2.0 2.5 3.0
>0.25 to 1.0 > 1.0 to 2.0 >2.0 to 3.0
2.0 2.5 3.0
where AO = minimum elongation (as a percentage) of the reference steel to be used on fracture under tensile stress (see 26.2.3.4)
2 For metals other than the reference steel described in 26.2.3.5.1, the minimum wall thickness is given by the equivalence formula
e1 =
where
21.4 e 0 Rm 1 A1
e1 = required equivalent wall thickness of the metal to be used (in mm); e0 = required minimum wall thickness for the reference steel (in mm);
2 Rm1 = guaranteed minimum tensile strength of the metal to be used in (N/mm ); and
A1 = minimum elongation (as a percentage) of the metal to be used on fracture under tensile stress (see 26.2.3.4). However, in no case should the wall thickness be less than 1.5 mm 26.2.3.6 Pressure-relief requirements
26.2.3.6.1 IBCs for liquids should be capable of releasing a sufficient amount of vapour in the event of fire engulfment to ensure that no rupture of the shell will occur. This can be achieved by conventional pressure relief devices or by other constructional means. 26.2.3.6.2 The start-to-discharge pressure should not be higher than 65 kPa and no lower than the total gauge pressure experienced in the IBC (i.e. the vapour pressure of the filling substance plus the partial pressure of the air or other inert gases minus 100 kPa) at 55C determined on the basis of a maximum degree of filling as defined in 26.1.6.2. 26.2.3.6.3 The pressure-relief devices should be fitted in the vapour space. 26.2.4 Testing, certification and inspections. Metal IBCs should be subject to: 1 2 3 26.2.5 26.2.5.1 type approval and certification including design type tests in accordance with 26.2.5; initial and periodic tests in accordance with 26.2.6; and inspections in accordance with 26.2.7.
Design type tests One IBC of each design type size, wall thickness and manner of construction should be submitted to the tests in the order listed below and as set out in 26.2.8.1 to 26.2.8.5 inclusive. Another IBC of the same design may be used for the drop test as set out in 26.2.8.6. These design type tests should be carried out as required by the competent approval authority.
Tests Bottom lift Top lift Stacking Leakproofness Hydraulic pressure Drop
Refer to 26.2.8.1 26.2.8.2 26.2.8.3 26.2.8.4 26.2.8.5 26.2.8.6
IBCs of types 11A, 11B, IBCs of types 21A, 21B, 11N 21N, 31A, 31B, 31N required1 required1 required2 not required not required required required1 required1 required2 required required required
When the IBCs are designed for this method of handling at least one of these (bottom or top lift) tests should be performed. When the IBCs are designed to be stacked.
26.2.5.2 The competent authority may permit the selective testing of IBCs which differ only in minor respects from the tested type e.g. with small reductions in external dimensions. 26.2.6 Initial and periodic testing of individual IBCs.
26.2.6.1 These tests should be carried out as required by the competent authority. 26.2.6.2 Each IBC should correspond in all respects to its design type and be subjected to the leak proofness test (see 26.2.8.4). 26.2.6.3 The leakproofness test in 26.2.8.4 should be repeated at intervals of not more than two and a half years. 26.2.6.4 The results of tests should be recorded in test reports to be kept by the owner of the IBC. 26.2.7 Inspections
26.2.7.1 Every IBC should be inspected to the satisfaction of the competent authority before it is put into service and thereafter at intervals not exceeding five years with regard to: 1 2 3 conformity to the design type including marking internal and external condition and proper functioning of the service equipment
Thermal insulation need be removed only to the extent necessary for a proper examination of the body of the IBC.
IMDG CODE - PAGE 0182 Amdt. 27-94 (corrected)
Appendix 1 to section 26
LIST OF LIQUID SUBSTANCES SUITABLE FOR TRANSPORT IN INTERMEDIATE BULK CONTAINERS (IBCs)
EXPLANATION OF COLUMNS Column 1 Column 2 United Nations Number (UN No.) of substance Proper shipping name of substance
Note: Depending on their hazards, mixtures or solutions should be treated in accordance with the requirements of subsections 5.3 and 5.4 of this General Introduction. Column 3 Class and subsidiary risk label(s)
Types of IBCs Columns 4, 5, 6 and 7 26.2 Metal. 26.4 Rigid plastics. 26.5 Composite only category 31HZ1, 31HA2 and 31HH2 are permitted for maritime transport. X Allowed for transport
Not allowed for transport
General requirement Liquid substances carried in metal, rigid plastics or composite IBCs with rigid inner receptacle (31HZ1) should be provided with secondary protection. Secondary protection may be effected by placing the IBCs into freight containers or vehicles which should have rigid sides or fencing at least to the height of the IBCs. Liquid substances carried in composite IBCs with flexible inner receptacles (31HA2 and 31HH2) should always be transported in closed cargo transport units. Special requirements 1 2 3 4 5 6 7 8 9 10 11 Allowed only if the vapour pressure does not exceed 110 kPa at 50C or 130 kPa at 55C. Substances falling under packaging group I criteria not allowed. Substances falling under packaging group III criteria only. Hermetically sealed as defined in 10.9.1 of this General Introduction and in the introductions to the various classes. Only with competent authority approval. IBCs to be provided with a device or vent to allow venting during transport and to be stowed with the vent uppermost. No bottom openings allowed. Only for substances with a flashpoint of 0C c.c. or above and with competent authority approval. Accessible stowage of closed cargo transport units; see 21.4.3 of this General Introduction. Only type 31HA1 is allowed. To prevent the IBC bursting in any event, including fire engulfment, it should be provided with pressure-relief devices which are adequate in relation to the capacity of the IBC and the nature of the substance carried. The device should also be compatible with the substance. Control temperature+ 30C; emergency temperature+ 35C. The temperature indicated is based on a non-insulated IBC. Control temperature+ 10C; emergency temperature + 15C. The temperature indicated is based on a non-insulated IBC. Control temperature+ 15C; emergency temperature+ 25C. The temperature indicated is based on a non-insulated IBC. Maximum capacity 1000 litres. Maximum capacity 1250 litres. Maximum capacity 1500 litres. When consigning an organic peroxide in an IBC in accordance with these requirements, it is the responsibility of the consignor to ensure that: .1 the pressure and emergency relief devices installed on the IBC are designed to take appropriate account of the selfaccelerating decomposition of the organic peroxide and of fire engulfment; and .2 when applicable, the control and emergency temperatures indicated are appropriate, taking into account the design (e.g. insulation) of the IBC to be used.
12 13 14 15 16 17 18
Types of IBCs
UN No.
Proper shipping name
Class + Subsidiary risk (s)

3 3.1 3.2 3.1 3.2 3.2 3.3 3.2 3.3 3.2+ 8 3.3+ 8 3.2 3.3 3.3 3.2 3.3 3.1 3.2 3.2 3.2 3.3 3.2 3.3 3.2+ 8 3.2 3.1 3.2 3.2 3.2 3.3 3.1
26.2 Metal
4 X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X
4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 1,4 4 4 4
26.4 Rigid plastics

5 X
4,8
26.5 Composite (31HZ1)

6 X
4,8
26.5 Composite (31HA2 and 31HH2)

7 X
4
1 1088 1088 1090 1090 1091 1104 1105 1105 1106 1106 1107 1109 1110 1111 1112 1113 1113 1114 1120 1120 1123 1123 1125 1126 1127 1127 1128 1129 1130 1133 ACETAL ACETAL ACETONE
X X
4,8 4,8 4
X X
4,8 4,8 4
ACETONE SOLUTIONS ACETONE OILS AMYL ACETATES AMYL ALCOHOLS PENTANOLS AMYLAMINES AMYLAMINES AMYL CHLORIDES AMYL FORMATES normal-AMYL METHYL KETONE AMYL MERCAPTANS AMYL NITRATES AMYL NITRITE AMYL NITRITE BENZENE BUTANOLS BUTANOLS BUTYL ACETATES BUTYL ACETATES normal-BUTYLAMINE 1-BROMOBUTANE CHLOROBUTANES CHLOROBUTANES normal-BUTYL FORMATE BUTYRALDEHYDE CAMPHOR OIL ADHESIVES containing a flammable liquid
X X
X X
4,5 4
4,5 4
X
4
X X
X X
4,5 4
4,5 4
X X
4 4
X X
X X
4,5 4 4
4,5 4 4
X X X
X X X
4,5 4
4,5 4
X
4
X
4,8
X
4,8
X
4
X
4,5 4
X
4,8 4
X X
X X
4,5 4
4,5 4
X
4
X
4,5
X
4,5
X
4
X
4,5
X
4,5
X
4
X
4
1,2,4
1133
ADHESIVES containing a flammable liquid
3.2
1,2,4
1,2,4,8
2,4,8
IMDG CODE - PAGE 0223 (first of thirty pages) Amdt. 29-98
Types of IBCs
UN No.

3 3.3 3.3 3.2 3.3 3.1 3.2 3.3 3.1 3.1 3.3 3.2 3.3 3.3 3.2 3.3 3.3 3.1+ 8 3.2 3.3 3.2+ 8 3.1 3.1+ 8 3.2+ 8 3.2 3.2 3.2 3.3
26.2 Metal
4 X
1,4
26.4 Rigid plastics

5 X
1,4

6 X
1,4

7 X
1,4
1 1133 1134 1136 1136 1139 1139 1139 1145 1146 1147 1148 1148 1149 1150 1152 1153 1154 1156 1157 1158 1159 1160 1160 1161 1165 1169 1169
2 ADHESIVES containing a flammable liquid CHLOROBENZENE COAL TAR DISTILLATES, FLAMMABLE COAL TAR DISTILLATES, FLAMMABLE COATING SOLUTION COATING SOLUTION COATING SOLUTION CYCLOHEXANE CYCLOPENTANE DECAHYDRONAPHTHALENES (cis-, trans-) DIACETONE ALCOHOL DIACETONE ALCOHOL DIBUTYL ETHERS 1, 2 DICHLOROETHYLENE DICHLOROPENTANES ETHYLENE GLYCOL DIETHYL ETHER DIETHYLAMINE DIETHYL KETONE DIISOBUTYL KETONE DIISOPROPYLAMINE DIISOPROPYL ETHER DIMETHYLAMINE, AQUEOUS SOLUTION DIMETHYLAMINE, AQUEOUS SOLUTION DIMETHYL CARBONATE DIOXANE EXTRACTS, AROMATIC LIQUID EXTRACTS, AROMATIC, LIQUID
X X X X X
X X
X X
4,8
4,8
X
4
1,2,4 2,4 4 4 4
X
2,4,8 4
X
2,4,8 4
X
4
X X X X X X X X X X X X X X X X
X X
4
X X
4
X
4
4 4 4 4 4
4,8 4 4
4,8 4 4
X X
4 4
X X X
X X X
4,5 4
4,5 4
X X
4
X X
X X
4 4 4 4 4
X
4,5 4
X
4,5 4
X
4
X X X X
4,8
X X X X
4,8
X
4
1,4
X X X X X
4 4
4,5 4,5
4,5 4,5
4,8
4,8
Types of IBCs
UN No.

3 8 8 8+ 5.1 8 8 8+ 6.1 6.1 8 8 8 8 8 8 8 8 6.1 6.1 8 8 3.2 3.1 3.2 3.3 3.1 3.2 3.3 6.1 6.1 6.1
26.2 Metal
4
26.4 Rigid plastics

5

6

7
1 1793 1800 1802 1803 1805 1811 1812 1814 1819 1824 1830 1833 1835 1837 1840 1843 1846 1848 1849 1862 1863 1863 1863 1866 1866 1866 1886 1887 1888
2 ISOPROPYL ACID PHOSPHATE OCTADECYLTRICHLOROSILANE PERCHLORIC ACID with not more than 50% acid, by mass PHENOLSULPHONIC ACID LIQUID PHOSPHORIC ACID, LIQUID POTASSIUM HYDROGENDIFLUORIDE, SOLUTION POTASSIUM FLUORIDE, SOLUTION POTASSIUM HYDROXIDE, SOLUTION SODIUM ALUMINATE, SOLUTION SODIUM HYDROXIDE, SOLUTION SULPHURIC ACID with more than 51% acid SULPHUROUS ACID TETRAMETHYLAMMONIUM HYDROXIDE, SOLUTION THIOPHOSPHORYL CHLORIDE ZINC CHLORIDE, SOLUTION AMMONIUM DINITRO-ortho-CRESOLATE aqueous SOLUTION CARBON TETRACHLORIDE PROPIONIC ACID SODIUM SULPHIDE, HYDRATED with at least 30% water (liquid) ETHYL CROTONATE FUEL, AVIATION, TURBINE ENGINE FUEL AVIATION, TURBINE ENGINE FUEL, AVIATION, TURBINE ENGINE RESIN SOLUTION flammable RESIN SOLUTION, flammable RESIN SOLUTION flammable BENZYLIDENE CHLORIDE BROMOCHLOROMETHANE CHLOROFORM
X X X
4
X X
4
X X
4
X X X X3 X8 X3 X X
5,7
X X X4 X X X X X X X X X X X X X4,5 X
2,4,8 4
X X X4 X X X X X X X X X X X X X4,5 X
2,4,8
X X X4 X X X X X X X4,5,7 X X X X X X4 X
1,2,4 2,4 4
X4
X4,8
X1,2,4 X
2,4 4
2,4,8 4
X2,4,8 X
4
X4 X X
X4 X X
X4 X X
X4 X X
Types of IBCs
UN No.
Class + Subsidiary risk(s)

3 6.1 8 8 8 8 33 33 6.1+3 3.2 3.3 3.2 3.3 3.2+8 8 8 3.1+6.1 3.2+6.1 3.3+6.1 3.2 3.3 3.1+6.1 3.2+6.1 3.3+6.1 3.1 3.2
26.2 Metal
4
26.4 Rigid plastics

5

6

7
1 1897 1898 1902 1903 1908 1914 1915 1916 1917 1918 1919 1920 1922 1938 1940 1986 1986 1986 1987 1987 1988 1988 1988 1989 1989
2 TETRACHLOROETHYLENE ACETYL IODIDE DIISOOCTYL ACID PHOSPHATE DISINFECTANT, LIQUID, CORROSIVE,
X X
4,5
X X X2 X X4 X4 X4 X
4 5 4
X X X2 X X4 X4 X4 X
4 5 4
X X X3 X3 X4 X4 X4 X4
X X2 X X4 X4 X4 X X
4 4
N.O.S.
CHLORITE SOLUTION BUTYL PROPIONATES CYCLOHEXANONE 2,2-DICHLORODIETHYL ETHER ETHYL ACRYLATE, INHIBITED ISOPROPYLBENZENE METHYL ACRYLATE, INHIBITED NONANES PYRROLIDINE BROMOACETIC ACID, SOLUTION THIOGLYCOLIC ACID ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLS, FLAMMABLE, TOXIC, N.O.S. ALCOHOLS, N.O.S. ALCOHOLS, N.O.S. ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. ALDEHYDES, FLAMMABLE, TOXIC, N.O.S. ALDEHYDES, N.O.S. ALDEHYDES, N.O.S.
X4 X4 X X
4
X4 X
4,5
X4 X
4,5
2,7
X X1,2,4,8 X X
1,4,5 1,4,8
X X1,2,4,8 X X
1,4,5 1,4,8
X X1,2,4,5 X1,2,4,5 X
1,2,4,5
X1,4
1,4
X1,4 X 1,2,4,5 X
1,2,4,5 1,4,5
X1,4 X
1,2,4,8 1,4,5
X1,4 X
1,2,4,8 1,4,5
X1,2,4 X
1,2,4
X
1,2,4,8
X
1,2,4,8
Types of IBCs
UN No.

3 3.1 3.3 3.3 8 6.1 6.1 3.2 3.3+ 6.1 6.1 3.3+ 8 9 3.3 8 6.1 6.1 3.3 3.3 3.3 8 8 6.1 3.3 3.3 3.3 3.2+ 6.1 3.2+ 6.1 3.2 3.2
26.2 Metal
4
26.4 Rigid plastics

5
26.5 Com26.5 Composite posite (31HA2 and (31HZ1) 31HH2)

6 7
1 2301 2302 2303 2305 2306 2307 2309 2310 2311 2313 2315 2319 2320 2321 2322 2323 2324 2325 2326 2327 2328 2329 2330 2332 2333 2335 2338 2339 2-METHYLFURAN
X4 X
4
X4 X
4
5-METHYLHEXAN-2-ONE ISOPROPENYLBENZENE NITROBENZENESULPHONIC ACIDS (ortho-, meta-, para-) NITROBENZOTRIFLUORIDES, LIQUID 3-NITRO-4-CHLOROBENZO-TRIFLUORIDE OCTADIENE PENTANE-2-4-DIONE PHENETIDINES PICOLINES POLYCHLORINATED BIPHENYLS TERPENE HYDROCARBONS, N.O.S. TETRAETHYLENEPENTAMINE TRICHLOROBENZENES, LIQUID TRICHLOROBUTENE TRIETHYL PHOSPHITE TRIISOBUTYLENE 1,3,5-TRIMETHYLBENZENE TRIMETHYLCYCLOHEXYLAMINE TRIMETHYLHEXAMETHYLENEDIAMINES TRIMETHYLHEXAMETHYLENE DIISOCYANATE TRIMETHYL PHOSPHITE normal-UNDECANE beta-ACETALDEHYDE OXIME ALLYL ACETATE ALLYL ETHYL ETHER BENZOTRIFLUORIDE 2-BROMOBUTANE
X4 X
4
X4 X4 X X4 X X X4 X4 X4 X X X X4 X4 X4
X X X X4 X
4
X X X X4,5 X
4
X X X X4,5 X
4
X X
4
X X
4
X X
4
X4 X
4
X4 X
4
X4 X
4
X X X4 X4 X4 X4 X X X X
4
X X X4 X4 X4 X4 X X X X
4
X X X4 X4 X4 X X X X X
4
X4 X4 X X X
4 4 4
X4 X4 X
4,5
X4 X4 X
4,5
X
4,5
X
4,5
X4
X4,5
X4,5
Types of IBCs
UN No.

3 3.2 3.3 3.2 3.2 3.2 3.3 3.2 3.2 3.1 3.2 3.3 3.2 3.2 3.3 3.2 3.2+6.1 3.2 3.2+6.1+8 3.2+6.1 3.3+8 3.2 3.3 3.3 3.2 3.3 3.1 3.2 3.1 3.2 3.2 3.2
26.2 Metal
4 X X X X X X X X X X X X X X X X X X
4
26.4 Rigid plastics

5 X
4,8

6 X
4,8
26.5 Composite (31HA2and 31HH2)

7
1 2340 2341 2342 2343 2344 2344 2345 2346 2347 2347 2348 2350 2351 2351 2352 2354 2358 2359 2360 2361 2362 2364 2366 2367 2368 2370 2372 2373 2373 2374 2375
2 2-BROMOETHYL ETHYL ETHER 1-BROMO-3-METHYLBUTANE BROMOMETHYLPROPANES 2-BROMOPENTANE BROMOPROPANES BROMOPROPANES 3-BROMOPROPYNE BUTANEDIONE BUTYL MERCAPTANS BUTYL MERCAPTANS BUTYL ACRYLATES, INHIBITED normal-BUTYL METHYL ETHER BUTYL NITRITES BUTYL NITRITES BUTYL VINYL ETHER, INHIBITED CHLOROMETHYL ETHYL ETHER CYCLOOCTATETRAENE DIALLYLAMINE DIALLYL ETHER DIISOBUTYLAMINE 1,1-DICHLOROETHANE normal-PROPYLBENZENE DIETHYL CARBONATE alpha-METHYLVALERALDEHYDE alpha-PINENE 1-HEXENE 1,2-DI-(DIMETHYLAMINO)ETHANE DIETHOXYMETHANE DIETHOXYMETHANE 3,3-DIETHOXYPROPENE DIETHYL SULPHIDE
X X X X
X X X X
4,8
4,8
4,5
4,5
4,5
4,5
X X X
X X X
4,5
4,5
4,5
4,5
X
4,8
X
4,8
X X X
X X X
4,8
*,8
4,8
4,8
X X X
4,8
X X X
4,8
4,8
4,8
,4
4,5
4,5
X X X X X X X X X X X X X
X
4
X
4
X X X
4
X X X
4
X X
<
4,5
4,5
X
<,5
X
4,5
X
4,5
X
4,5
Types of IBCs
UN No.

3 3.2 3.1 3.2 3.3+6.1 3.2+8 3.2 3.2 3.2+8 3.1 3.2 3.2 3.2+8 3.2 3.2 3.2 3.2 3.3 3.2 3.2 3.2+6.1 3.2 3.1 3.2+8 3.2 8+3 3.1 3.2 3.2+6.1 3.3 3.2 3.2
26.2 Metal
4
26.4 Rigid plastics

5

6

7
1 2376 2377 2377 2378 2379 2380 2381 2383 2384 2384 2385 2386 2387 2388 2390 2391 2392 2393 2394 2396 2397 2398 2399 2400 2401 2402 2403 2404 2405 2406 2409 2,3-DIHYDROPYRAN
X X
4 4
X4,8 X X X
4
X4,8 X X X
4
X4 X4
1,1- DIMETHOXYETHANE 1,1-DIMETHOXYETHANE 2- DIMETHYLAMINOACETONITRILE 1,3-DIMETHYLBUTYLAMINE DIMETHYLDIETHOXYSILANE DIMETHYL DISULPHIDE DIPROPYLAMINE DI-normal-PROPYL ETHER DI-normal-PROPYL ETHER ETHYL ISOBUTYRATE 1-ETHYLPIPERIDINE FLUOROBENZENE FLUOROTOLUENES (ortho-, meta-, para-) 2-IODOBUTANE IODOMETHYLPROPANES IODOPROPANES ISOBUTYL FORMATE ISOBUTYL PROPIONATE METHACRYLALDEHYDE, INHIBITED 3-METHYLBUTAN-2-ONE METHYL-tertiary-BUTYL ETHER 1-METHYLPIPERIDINE METHYL ISOVALERATE PIPERIDINE PROPANETHIOLS ISOPROPENYL ACETATE PROPIONITRILE ISOPROPYL BUTYRATE ISOPROPYL ISOBUTYRATE ISOPROPYL PROPIONATE
X4 X X X
4 4 4
4,5 4,5
4,5 4,5
X4 X X X
4 4 4
X4,5 X
4,5
X4,5 X
4,5
X
4,8
X
4,8
X4 X X X
4 4 4
X4,5 X
4,5
X4,5 X
4,5
X
4,5
X
4,5
X4 X X
4 4
X4,5 X
4,8 4
X4,5 X
4,8 4
X4 X4 X X X
4 4 4
X4,5 X4,5 X
4,5
X4,5 X4,5 X
4,5
X4,5 X X
4,8 4,5
X4,5 X X
4,8 4,5
X4 X X X
4 4 4
X4,5 X
4,5 4
X4,5 X
4,5 4
X4 X X
4 4
X4 X4
X4,5 X4,5
X4,5 X4,5
Types of IBCs
UN No.

3 3.2 3.2+6.1 3.2 3.3 3.2 3.2 5.1 5.1 5.1 6.1 6.1 6.1 3.2 3.1 3.1 3.2 3.1 6.1 6.1 3.2+6.1
26.2 Metal
4 X X X X X X
4 4 4 4 4 4
26.4 Rigid plastics

5 X X X
4,5 4,5 4,5 4

6 X X X
4,5 4,5 4,5 4

7
1 2410 2411 2412 2413 2414 2416 2427 2428 2429 2431 2432 2433 2436 2457 2458 2458 2461 2470 2474 2478
2 1,2,3,6-TETRAHYDROPYRIDINE BUTYRONITRILE TETRAHYDROTHIOPHENE TETRAPROPYL ORTHOTITANATE THIOPHENE TRIMETHYL BORATE POTASSIUM CHLORATE, AQUEOUS SOLUTION SODIUM CHLORATE AQUEOUS SOLUTION CALCIUM CHLORATE, AQUEOUS SOLUTION ortho-ANISIDINE N,N-DIETHYLANILINE CHLORO ortho-NITROTOLUENE THIOACETIC ACID 2,3-DIMETHYLBUTANE HEXADIENES HEXADIENES METHYLPENTADIENES PHENYLACETONITRILE, LIQUID THIOPHOSGENE ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC,

X
4
X
4,8
X
4,8
X X X X X X X X X X X
4 4 4 4 4
X X X X
4,8
X X X X
4,8

X X
X
4,8
X
4,8
X X X
4
X X
4
X X
4
4,5,7
N.O.S.
2478 2485 2486 2490 2491 2493 ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, 3.3+6.1 6.1+3 3.2+6.1 6.1 8 3.2+8 X X X
4,5
X X X
4,5
X X X
4,5
N.O.S.
normal - BUTYL ISOCYANATE ISOBUTYL ISOCYANATE DICHLOROISOPROPYL ETHER ETHANOLAMINE or ETHANOLAMINE SOLUTION HEXAMETHYLENEIMINE
4,5,7 4,5,7
X X X
4
Types of IBCs
UN No.

3 6.1 6.1 6.1 6.1 6.1+3 6.1
26.2 Metal 4 X X X X X
4
26.5 Compos26.4 26.5 Composite (31HA2 ite (31HZ1) Rigid plastics and 31HH2) 5 X X X X X
4,5
1 2656 2662 2664 2667 2668 2669 QUINOLINE
6 X X X X X
4,5
7 X X X X
HYDROQUINONE LIQUID DIBROMOMETHANE BUTYLTOLUENES CHLOROACETONITRILE CHLOROCRESOLS, LIQUID AMMONIA aqueous SOLUTION, (relative density between 0.880 and 0.957 at 15C) with more than 10% but not more than 35% ammonia, by mass RUBIDIUM HYDROXIDE SOLUTION LITHIUM HYDROXIDE SOLUTION CAESIUM HYDROXIDE, SOLUTION AMMONIUM SULPHIDE SOLUTION 3-(DIETHYLAMINO)PROPYLAMINE N,N-DIETHYLETHYLENEDIAMINE 2-DIETHYLAMINOETHANOL 1-CHLORO-3-BROMOPROPANE GLYCEROL-alpha-MONOCHLORO-HYDRIN N-normal-BUTYLIMIDAZOLE BISULPHITES AQUEOUS SOLUTION N O S 1-PENTOL DIMETHYLDIOXANES BUTYLBENZENES DIPROPYL KETONE NITROANISOLES, LIQUID NITROBROMOBENZENES LIQUID
2672
2677 2679 2681 2683 2684 2685 2686 2688 2689 2690 2693 2705 2707 2709 2710 2730 2732
8 8 8 8 + 6.1 + 3* 3.3+8 8+3 8+3 6.1 6.1 6.1 8 8 3.3 3.3 3.3 6.1 6.1
X X X X
4,5 4 4 4
X X X
X X X
X X X
3 3 3
X X X
X X X
4 4 4
X X X
4 4 4

X X
X X X X X X X X
4 4 4
X X X X X X X X
4 4 4
X X X X X X X X
4 4 4
X X X
4 4 4
X X
X X
X X
X X
* If flashpoint 61C c.c. or below
IMDG CODE - PAGE 0223t (page 0223u follows) Amdt. 29-98
Types of IBCs
UN No.

3
26.2, Metal 4
26.5 Compos26.4 26.5 Composite (31HA2 Rigid plastics ite (31HZ1) and 31HH2) 5 6 7
1 2733
2 AMINES, FLAMMABLE, CORROSIVE N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE,
N.O.S.
2733 AMINES, FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE,
3.1+8
X1,2,4
N.O.S.
2733 AMINES FLAMMABLE, CORROSIVE, N.O.S. or POLYAMINES, FLAMMABLE, CORROSIVE,
3.2+8
X1,2,4
X1,2,4,8
X1,2,4,8
N.O.S.
2734 AMINES LIQUID, CORROSIVE, FLAMMABLE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. AMINES, LIQUID, CORROSIVE, N.O.S. or POLYAMINES, LIQUID, CORROSIVE, N.O.S. N-normal-BUTYLANILINE BUTYRIC ANHYDRIDE CHLOROFORMATES, TOXIC, CORROSIVE, FLAMMABLE, N.O.S. normal-BUTYL CHLOROFORMATE CYCLOBUTYL CHLOROFORMATE CHLOROMETHYL CHLOROFORMATE PHENYL CHLOROFORMATE tertiary-BUTYLCYCLOHEXYL CHLOROFORMATE 2-ETHYLHEXYL CHLOROFORMATE 1,3-DICHLOROPROPANOL-2 DIETHYLTHIOPHOSPHORYL CHLORIDE 1,2-EPOXY-3-ETHOXYPROPANE
3.3+8
X4
X4
X4
8+3
X2,4 X2 X X X
4,5,7
X2,4 X2 X X X X X X4
X2,4 X2 X X X X X X4
X2,3
2735 2738 2739 2742 2743 2744 2745 2746 2747 2748 2750 2751 2752
8 6.1 8 6.1+8 + 3* 6.1+8+3 6.1+8+3 6.1+8 6.1+8 6.1 6 1+8 6.1 8 3.3
X X X4
X4,5,7 X4,5,7 X4,5,7 X4,5,7 X X

4,5,7
X X X4
* If flashpoint 61C c. c. or below
IMDG CODE - PAGE 0223u (page 0223v follows) Amdt. 28-96
Types of IBCs
UN No.

3
26.2 Metal
26.4 Rigid plastics 5
26.5 Composite (31HZ1) 6
26.5 Composite (31HA2 and 31HH2) 7
1 2753 2754 2758
2 N-ETHYL-N-BENZYLTOLUIDINES, LIQUID (ortho-, meta-, para- ) N-ETHYLTOLUIDINES CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC COPPER BASED, PESTICIDE, LIQUID, FLAMMABLE, TOXIC MERCURY BASED, PESTICIDE, LIQUID, FLAMMABLE, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC 4-THIAPENTANAL ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC
6.1 6.1+3* 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 3.2+6.1 6.1 3.2+6.1 X
X X
4
X X X
4,5
X X X
4,5
2,4,5,7
2,4,7,8
2,4,7,8
2760
X2,4,5,7 X2,4,5,7 X2,4,5,7 X2,4,5,7 X2,4,5,7 X2,4,5,7 X2,4,5,7 X2,4,5,7 X2,4,5,7 X

4,5
X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8
X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8 X2,4,7,8
2762
2764
2772
2776
2778
2780
2782
2784 2785 2787
X2,4,5,7
* if flashpoint 61C c.c. or below
IMDG CODE - PAGE 0223v (page 0223w follows) Amdt. 29-98
Types of IBCs
UN No.

3 6.1 8+3
26.2 Metal
26.4 Rigid plastics 5 X

2,4
26.5 Composite (31HZ1) 6 X

2,4
26.5 Composite (31HA2 and 31HH2) 7 X

3,4
1 2788 2789
2 ORGANOTIN COMPOUND LIQUID N O S ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass ACETIC ACID SOLUTION, not less than 10% but not more than 80% acid , by mass SULPHURIC ACID with not more than 51% acid BATTERY FLUID, ALKALI DYE, LIQUID, CORROSIVE N.O.S. or DYE INTERMEDIATE, LIQUID, CORROSIVE
4 X
2,4
2790
2796 2797 2801 2810 2815 2817 2818 2819 2820 2821 2822 2826 2829 2831 2834 2838 2839 2840 2841 2842 2849 2850 2872
8 8 8 6.1 8 8+6.1 8+6.1 8 8 6.1 6.1 8+3 8 6.1 8 3.2 6.1 3.3 3.3+6.1 3.3 6.1 3.3 6.1 X X X
X X X X
2,4,5
X X X X
2,4,5
X X
3,4,5
X
2,4,5
N.O.S.
TOXIC LIQUID, ORGANIC, N.O.S. N-AMINOETHYLPIPERAZINE AMMONIUM HYDROGEN-DIFLUORIDE SOLUTION AMMONIUM POLYSULPHIDE, SOLUTION AMYL ACID PHOSPHATE normal-BUTYRIC ACID PHENOL SOLUTION 2-CHLOROPYRIDINE ETHYL CHLOROTHIOFORMATE CAPROIC ACID 1,1,1-TRICHLOROETHANE PHOSPHOROUS ACID solution VINYL BUTYRATE, INHIBITED ALDOL BUTYRALDOXIME DI-normal-AMYLAMINE NITROETHANE 3-CHLOROPROPANOL-1 PROPYLENE TETRAMER DIBROMOCHLOROPROPANES
2,4,5 2,4,5 2,4,5 3,4,5
X
4,5,7
X X
4,5,7
X X
4,5,7
X X X X X X X X
4
4,5
4,5
4,5
X X X X X
4 4
X X X X X
4 4
X X X X X
4 4
X X X X
4
X X X X
4,5
X X X X
4,5
X X X X
4 4 4
X X
4
X X
4
X X
4
X X
4
X
4
X X
4
X X
4
X X
4
X X X
4 3
IMDG CODE - PAGE 0223w (page 0223x follows) Amdt. 29-98
Types of IBCs
UN No.

3 6.1 6.1 6.1 6.1+3
26.2 Metal
26.4 Rigid plastics 5 X X X X

2,4,5
26.5 Composite (31HZ1) 6 X X X X

2,4,5
26.5 Composite (31HA2 and 31HH2) 7 X X X

3,4,5
1 2873 2874 2902 2903
2 N,N-DI-normal-BUTYLAMINO ETHANOL FURFURYL ALCOHOL PESTICIDE LIQUID, TOXIC, N.O.S. PESTICIDE LIQUID, TOXIC, FLAMMABLE,
4 X X X X
2,4,5
N.O.S.
CHLOROPHENOLATES, LIQUID or PHENOLATES, LIQUID CORROSIVE LIQUID FLAMMABLE N O S CORROSIVE LIQUID TOXIC N O S FLAMMABLE LIQUID CORROSIVE N O S FLAMMABLE LIQUID CORROSIVE N O S TOXIC LIQUID, CORROSIVE, ORGANIC
2,4,5
2,4,5
2,4,5
2904 2920 2922 2924 2924 2927
8 8+3 8+6.1 3.2+8 3.3+8 6.1+8 X
,5
X X
X X
1,2,4,5 2,4,5
l,2,4,5 2,4,5
1,2,4,5 2,4,5
X X
X X
X X
I,24,57 1,4,5
1,2,4,7,8 1,4,5
,1,2478 l,4,5
X X
X X
X X
N.O.S.
TOXIC LIQUID, FLAMMABLE, ORGANIC,
2,4,5
2,4,5
2,4,5
2929 2933 2934 2935 2936 2937 2941 2942 2943 2945 2946 2947 2948
N.O.S.
METHYL-2-CHLOROPROPIONATE ISOPROPYL-2-CHLOROPROPIONATE ETHYL-2-CHLOROPROPIONATE THIOLACTIC ACID alpha-METHYLBENZYL ALCOHOL LIQUID FLUOROANILINES 2-TRIFLUOROMETHYLANILINE TETRAHYDROFURFURYLAMINE N-METHYLBUTYLAMINE 2-AMINO-5-DIETHYLAMINO-PENTANE ISOPROPYL CHLOROACETATE 3-TRIFLUOROMETHYLANILINE
6.1+3 3.3 3.3 3.3 6.1 6.1 6.1 6.1 3.3 3.2+8 6.1 3.3 6.1
2,4,5
2,4,5
2,4,5
X X X
4 4 4
X X X
4 4 4
X X X
4 4 4
X X X
4 4 4
X X X X X X
4 4
X X X X X
4
X X X X X
4
X X X X
4
X X
4
X X
4
X X
4
X X
4
IMDG CODE - PAGE 0223x (page 0223y follows) Amdt. 28-96
Types of IBCs
UN No.

3 8 6.1 5.1
26.2 Metal
26.4 Rigid plastics 5 X X X

4 4
26.5 Composite (31HZ1) 6 X X X

4 4
1 2949 2966 2984
2 SODIUM HYDROSULPHIDE, SOLUTION THIOGLYCOL HYDROGEN PEROXIDE, AQUEOUS SOLUTION, with not less than 8% but less than 20% hydrogen peroxide CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE CARBAMATE PESTICIDE, LIQUID, TOXIC ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE ARSENICAL PESTICIDE, LIQUID, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE TRIAZINE PESTICIDE, LIQUID, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE
4 X X X
4 4
2991 2992 2993 2994 2995
6.1+3 6.1 6.1+3 6.1 6.1+3
2,4,5
2,4,5
2,4,5
X
3,5
X X
X X
2,5
X X
2,5
2,4,5
2,4,5
2,4,5
X
3,5
X X
X X
2,5
X X
2,5
2,4,5
2,4,5
2,4,5
3,5
2996
6.1
2,5
2,5
2997 2998 3005
6.1+3 6.1 6.1+3
2,4,5
2,4,5
2,4,5
X
3,5
X X
X X
2,5
X X
2,5
2,4,5
2,4,5
2,4,5
IMDG CODE - PAGE 0223y (page 0223z follows) Amdt. 29-98
Types of IBCs
UN No.

3 6.1
26.2 Metal

2,5

2,5
26.5 Composite (31HA2 and 31HH2) 7 X

3,5
1 3006
2 THIOCARBAMATE PESTICIDE, LIQUID, TOXIC COPPER-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE COPPER-BASED PESTICIDE LIQUID, TOXIC MERCURY-BASED PESTICIDE, LIQUID, TOXIC FLAMMABLE MERCURY-BASED PESTICIDE, LIQUID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE BIPYRIDILIUM PESTICIDE, LIQUID TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC ORGANOTIN PESTICIDE, LIQUID TOXIC, FLAMMABLE ORGANOTIN PESTICIDE, LIQUID, TOXIC PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S 1,2-BUTYLENE OXIDE, STABILIZED
4 X
2
3009 3010 3011
6.1+3 6.1 6.1+3
2,4,5
2,4,5
2,4,5
X
3,5
X X
X X
2,5
X X
2,5
2,4,5
2,4,5
2,4,5
3,5
3012
6.1
2,5
2,5
3013
6.1+3
2,4,5
2,4,5
2,4,5
3,5
3014
6.1
2,5
2,5
3015 3016 3017
6.1+3 6.1 6.1+3
2,4,5
2,4,5
2,4,5
X
3,5
X X
X X
2,5
X X
2,5
2,4,5
2,4,5
2,4,5
3,5
3018
6.1
2,5
2,5
3019 3020 3021
6.1+3 6.1 3.2+6.1
2,4,5
2,4,5
2,4,5
X
3,5
X X
X X
2,5
X X
2,5
2,4,5,7
2,4,7,8
2,4,7,8
3022
3.2
IMDG CODE - PAGE 0223z (page 0223a1 follows) Amdt. 29-98
Types of IBCs
UN No.

3 3.2+6.1
26.2 Metal

2,4,7,8

2,4,7,8
26.5 Composite (31HA2and 31HH2) 7
1 3024
2 COUMARIN DERIVATIVE, PESTICIDE, LIQUID, FLAMMABLE, TOXIC COUMARIN DERIVATIVE, PESTICIDE, LIQUID, TOXIC, FLAMMABLE COUMARIN DERIVATIVE, PESTICIDE, LIQUID, TOXIC CYCLOHEXYL MERCAPTAN 2-(2-AMINOETHOXY)ETHANOL normal-HEPTALDEHYDE ALCOHOLIC BEVERAGES ALCOHOLIC BEVERAGES ISOCYANATES TOXIC, FLAMMABLE N.O.S. or ISOCYANATES, SOLUTION, TOXIC, FLAMMABLE N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. ORGANIC PEROXIDE TYPE F LIQUID - tert-BUTYL PEROXYACETATE not more than 32% in diluent type A - tert-BUTYL-PEROXY-3,5,5TRIMETHYLHEXANOATE not more than 32% in diluent type A - CUMYL HYDROPEROXIDE not more than 90% in diluent type A - DIBENZOYL PEROXIDE not more than 42% as a stable dispersion in water - DI-tert-BUTYL PEROXIDE not more than 32% in diluent type A - 1,1-DI-(tert-BUTYL-PEROXY) CYCLOHEXANE not more than 42% in diluent type A - DILAUROYL PEROXIDE not more than 42% as a stable dispersion in water - ISOPROPYL CUMYL HYDROPEROXIDE not more than 72% in diluent type A
4 X
2,4,5,7
3025
6.1+3
2,4,5
2,4,5
2,4,5
3,5
3026 3054 3055 3056 3065 3065 3080
6.1 3.3 8 3.3 3.2 3.3 6.1+3
2,5
2,5
2,5
X X X X X
4 4 4
X X X X
4 4 4
X X X X
4 4 4
X X
4
4,5,7
3082 3109
9 5.2 5.2 X
5,6,16,18
5,6,10,15,18
5.2
5,6,16,18
5,6,10,15,18
5.2
5,6,10,16,18
5.2 5.2 X
5,6,16,18
5,6,15,18
X
5,6,10,15,18
5.2
5,6,15,18
5.2
5,6,10,15,18
5.2
5,6,10,16,18
IMDG CODE - PAGE 0223a1 (page 0223b1 follows) Amdt. 29-98
Types of IBCs
UN No.

3
26.2 Metal

5,6,10,16,18
26 5 Composite (31HA2 and 31HH2) 7
2 - p-MENTHYL HYDROPEROXIDE not more than 72% in diluent type A - PEROXYACETIC ACID, TYPE F stabilized, not more than 17% ORGANIC PEROXIDE, TYPE F, LIQUID TEMPERATURE CONTROLLED - tert-BUTYL PEROXY-2-ETHYLHEXANOATE not more than 32% in diluent type B - tert-BUTYL PEROXYPIVALATE not more than 27% in diluent type B
5.2
X
5,6,17,18
X
5,6,17,18
5.2
5,6,10,17,18
3119
5.2
5,6,9,16,,18
5,6,9,10,12,15,18
5.2
5.2
5,6,9,16,18
5,6,9,10,13,15,18
- DI-(4-tert-BUTYLCYCLOHEXYL) PEROXYDICARBONATE not more than 42% as a stable dispersion in water
5.2
5,6,9,10,12,,15,18
- DICETYL PEROXYDICARBONATE not more than 42% as a stable dispersion in water - DIMYRISTYL PEROXYDICARBONATE not more than 42% as a stable dispersion in water
5.2
5,6,9,10,12,15,,18
5.2
5,6,9,10,14,15,18
- DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE, not more than 38% in diluent type A OXIDIZING LIQUID, N.O.S. ANTIMONY COMPOUND INORGANIC, LIQUID, N.O.S. DISINFECTANT, LIQUID, TOXIC N.O.S.
5.2
5,6,9,16,18

X
2,5
5,6,9,10,13,15,18

X
3,5
3139 3141
5.1 6.1
X X
2,5
X
2,5
2,5
3142
6.1
3,5
3144
NICOTINE COMPOUND LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID, NOS ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues)
6.1
3145
IMDG CODE - PAGE 0223b1 (page 0223c1 follows) Amdt. 29-98
Types of IBCs
UN No.

3
26.2 Metal
2 HYDROGEN PEROXIDE AND PEROXYACETIC ACID, MIXTURE, with acid(s), water and not more than 5% peroxyacetic acid, STABILIZED POLYHALOGENATED BIPHENYLS, LIQUID and POLYHALOGENATED TERPHENYLS, LIQUID CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERCHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. BROMATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERMANGANATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRITES, INORGANIC, AQUEOUS SOLUTION, N.O.S. CORROSIVE LIQUID, ACIDIC, INORGANIC,
3149
5.1+8
6,11
6,11
,6,10,11
3151
3210 3211
5.1 5.1
X X
,5
3213
5.1
3214
5.1
3216 3218
5.1 5.1
X X
3219 3264
5.1 8
X X
X
2,4,5
X
2,4,5
X
3,4,5
N.O.S.
CORROSIVE LIQUID, ACIDIC ORGANIC,
2,4,5
3265 3266
N.O.S.
CORROSIVE LIQUID, BASIC INORGANIC,
8 8
X X
2,4,5
X X
2,4,5
X X
2,4,5
X X
3,4,5
N.O.S.
CORROSIVE LIQUID, BASIC, ORGANIC,
2,4,5
2,4,5
2,4,5
3,4,5
3267 3276 3287 3289
N.O.S.
NITRILES, TOXIC, N.O.S. TOXIC LIQUID, INORGANIC, N.O.S. TOXIC LIQUID, CORROSIVE, INORGANIC,
8 6.1 6.1 6.1+8
X X X X
2,4,5
X X X X
2,4,5
X X X X
2,4,5
X X X
3,4,5
2,4,5 2,4,5
2,4,5 2,4,5
2,4,5 2,4,5
3,4,5 3,4,5
N.O.S.
HYDRAZINE, AQUEOUS SOLUTION, with not more than 37% hydrazine, by mass MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S
2,4,5
2,4,5
2,4,5
3293
6.1
4,5,7
2,5,7
4,5,7
4,5,7
3336
3.1
1,2,4,5
IMDG CODE - PAGE 0223d (page 0223d1 follows) Amdt. 29-98
Types of IBCs
UN No.

3
26.2 Metal
2 MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN, MIXTURE, LIQUID, FLAMMABLE, N.O.S. PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE PYRETHROID PESTICIDE, LIQUID, TOXIC
3336
3.2
1,2,4,8
1,2,4,8
1,2,4,8
3336
3.3
4,5
4,5
4,6
3346
3.2+ 6.1
2,4,5,7
2,4,7,8
2,4,7,8

X
3,5
3347
6.1+ 3
2,4,5
2,4,5
2,4,5
3348
6.1
2,5
2,5
3350 3351 3352
3.2+ 6.1 6.1+ 3 6.1
2,4,5,7
2,4,7,8
2,4,7,8

X
3,5
2,4,5
2,4,5
2,4,5
2,5
2,5
IMDG CODE - PAGE 0223d1 (page 0224 follows) Amdt. 29-98
(This page is intentionally blank)
Appendix 2 to section 26
LIST OF SOLID SUBSTANCES SUITABLE FOR TRANSPORT IN INTERMEDIATE BULK CONTAINERS (IBCs)
EXPLANATION OF COLUMNS Column 1 Column 2 United Nations Number (UN No.) of substance Proper shipping name of substance
Note: Depending on their hazards, mixtures or solutions should be treated in accordance with the requirements of subsections 5.3 and 5.4 of this General Introduction. Column 3 Class and subsidiary risk label(s) Columns 4, Types of IBCs 5, 6, 7, 8 26.2 Metal and 9 26.3 26.4 26 5 26.6 26.7 X Flexible Rigid plastics Composite Fibreboard Wooden
Allowed for transport;
Not allowed for transport.
General requirements For packaging group I solids Secondary protection is required for all IBCs except composite IBCs, which should be carried in closed cargo transport units. Secondary protection may be effected by placing the IBCs into freight containers or vehicles, which should have rigid sides or fencing at least to the height of the IBCs. For packaging group II solids Secondary protection should be provided for packaging group II solid substances and materials carried in flexible fibreboard composite or wooden IBCs. Special requirements 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 Only packed in closed cargo transport units; Substances falling under packaging group I criteria not allowed; Only flexible IBCs or fibreboard IBCs fitted with a sift proof liner unless the IBC itself is made fully sift proof such as by application of a coating to the body of the IBC use of welded seams and sift proof closures etc.; If textile IBCs are used only those with inner coating or inner liner should be used; Hermetically sealed as defined in 10.9.1 of this General Introduction and in the introductions to the various classes; Substances falling under packaging groups I or II criteria should be provided with secondary protection; Only with competent authority approval; Sift proof water resistant flexible fibreboard or wooden IBCs packed in closed cargo transport units; Flexible fibreboard or wooden IBCs are intended for the transport of solids only and they should not be used when the contents are likely to melt or become liquid during the intended voyage; Only water resistant flexible fibreboard or wooden IBCs; May be transported without secondary protection subject to special requirements agreed between the competent authority of the country of loading and the flag State administration; IBCs should be equipped with a self sealing venting device approved by the competent authority; Substances falling under packaging group III criteria only; Only water resistant wooden IBCs fitted with a sift proof liner; Accessible stowage of closed cargo transport units see 21.4.3 of this General Introduction; For packaging group I solid substances composite IBCs fitted with a flexible plastics inner receptacle (11HZ2 and 21HZ2) are not permitted; Only 13H2,13H3,13H4,13L2,13L3 and 13L4 are permitted; This is a wooden IBC containing a hermetically sealed flexible IBC with a liner. This flexible IBC should be approved in accordance with the requirements of 26.1 and 26.3. The assembled IBC should meet the standards of a composite IBC and should be approved by the competent authority.
Class + subsidiary risk(s)
3 4.3 4.3 4.3 4.3 4.3 + 6.1 4.3 4.3 4,3 4.3 4.3 4.3 + 4.2 5.1 5.1 5.1 5.1 5.1 + 6.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 + 8
UN No.
1 1398 1402 1403 1405 1408 1415 1417 1420 1428 1435 1436 1438 1439 1444 1445 1446 1451 1452 1453 1454 1458 1459 1461 1462 1463
Substance
2
26.2 Metal
4
26.4 26.3 FlexiRigid plasble tics

5 6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
ALUMINIUM SILICON POWDER, UNCOATED CALCIUM CARBIDE CALCIUM CYANAMIDE, with more than 0.1% calcium carbide CALCIUM SILICIDE FERROSILICON, (with 30% or more but less than 90% silicon) LITHIUM, solid fused only LITHIUM SILICON POTASSIUM METAL ALLOY, solid fused only SODIUM, solid fused only ZINC ASHES ZINC POWDER, or ZINC DUST ALUMINIUM NITRATE AMMONIUM DICHROMATE AMMONIUM PERSULPHATE BARIUM CHLORATE, SOLID BARIUM NITRATE CAESIUM NITRATE CALCIUM CHLORATE CALCIUM CHLORITE CALCIUM NITRATE CHLORATE AND BORATE, MIXTURE CHLORATE AND MAGNESIUM CHLORIDE, MIXCHLORATES, INORGANIC, N.O.S, CHLORITES, INORGANIC, N.O.S. CHROMIUM TRIOXIDE, ANHYDROUS
X X
5,6

X
5,8,13
X X
5
X X
5

X
5,8,13

X
5,8,13
X X
5
X X X X
5,6 5
5,6 5,6

X
6
X
s
X
5

7 7 5

7 7 5

X X X X
8 6,8

X X
8 6,8
7 7 5
X X
3,4,6 3,4
X
3,6 3
X X X
6
X X X X X X
X X X X X X
X
6,9 6 9
3,4,6 3,4,9
3,6,9 3,6 3,9
X X X X X X
3,4,6,9,11 3,4,6,9
3,6,9 3,6,9
6,9 6,9
X
3,4,6,9 1,4,6
X
3,6,9 1,6
X
6,9 1,6
3 5.1 5.1 5.1 5.1+6.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1 5.1+6.1 5.1 5.1 5.1 5.1
UN No.
1 1465 1466 1467 1469 1471 1474 1477 1479 1479 1485 1486 1487 1488 1491 1492 1493 1495 1496 1498 1499 1500 1504 1505 1506 1507
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Com26.6 posite Fibreboard

7 8
26.7 Wooden
9
DIDYMIUM NITRATE FERRIC NITRATE GUANIDINE NITRATE LEAD NITRATE LITHIUM HYPOCHLORITE DRY or LITHIUM HYPOCHLORITE MIXTURE DRY MAGNESIUM NITRATE NITRATES INORGANIC, N.O.S. OXIDIZING SOLID N O S (Packaging group I) OXIDIZING SOLID, N.O.S. (Packaging groups II and III) POTASSIUM CHLORATE POTASSIUM NITRATE POTASSIUM NITRATE AND SODIUM NITRITE MIXTURE POTASSIUM NITRITE POTASSIUM PEROXIDE POTASSIUM PERSULPHATE SILVER NITRATE SODIUM CHLORATE SODIUM CHLORITE SODIUM NITRATE SODIUM NITRATE AND POTASSIUM NITRATE, MIXTURE SODIUM NITRITE SODIUM PEROXIDE SODIUM PERSULPHATE STRONTIUM CHLORATE STRONTIUM NITRATE
X X X X X X X7 X6,7 X
7
X3,4,9 X3,4,9 X
3,4
X X X X X X X7 X6,7
X X X X X X X7 X1,7,16 X
6,7
X3,9 X3,9 X
3
X9 X9 X X
X X3,4,6,7
X X3,6,7,
X X6,7
3,4,6,7
3,6,7
X6,7 X6,9 X X6,9 X6,9
X X X X X
6,7
X3,4,6,9,11 X X3,4,6,9, X3,4,6,9
X X X X X
6,7
X X X X X
6,7,16
X3,6,9 X X3,6,9 X3,6,9
X X X X X X X X
6,7
3,4
X X X X X X X X
6,7
X X X X X X X X
6,7,16
X X6 X6,,9 X6,9 X X X9
X3,1,6 X3,4,6,9,11 X
3,4,6,9
X3,6 X3,6,9 X
3,6,9
X X X
3,4
X X X
3
3,4,9
3,9
X X X
X3,4 X3,4,6,9,11 X
3,4
X X X
X X X
X3 X3,6,9 X
3
X X6,9 X
3 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 8 8 8 8 5.1 6.1+8 8 8 8 8 8 8 8 8 8
UN No.
1 1697 1707 1708 1709 1711 1712 1713 1725 1726 1727 1733 1740 1748 1751 1756 1759 1759 1770 1773 1794 1805 1806 1807
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
CHLOROACETOPHENONE, SOLID THALLIUM COMPOUND, N.O.S. TOLUIDINE (para-), SOLID 2,4-TOLUYLENEDIAMINE, SOLID 3,4-DIMETHYLANILINE, SOLID ZINC ARSENATE or ZINC ARSENITE or ZINC ARSENATE AND ZINC ARSENITE, MIXTURE ZINC CYANIDE ALUMINIUM BROMIDE, ANHYDROUS ALUMINIUM CHLORIDE, ANHYDROUS AMMONIUM HYDROGENDIFLUORIDE, SOLID ANTIMONY TRICHLORIDE, SOLID HYDROGENDIFLUORIDES, N.O.S.
CALCIUM HYPOCHLORITE, DRY or CALCIUM HYPOCHLORITE, MIXTURE, DRY (more than 39% available chlorine)
X X X X X X X5,6 X5 X5 X
5
X X X X X X X5,6 X5 X5 X
5
X X X X X X X1,5,16 X5 X5 X
5
X3,6
X3,6
X6
X3
X3
X3,6
X3,6
X6 X1,5,14
X3,5,6,9,10
y,3,5,6,9,10
X3,5,6,9,10 X3,5,6,9,10 X
3,5,6,9,10
X5,6,9,10 X5,6,9,10 X5,6,9,10 X5,6,9,10 X5,6,7,10
3,5,6,9,10
X5 X5 X X X X
6,7
X3,5,6,9,10 X3,5,6,7,10
X5 X5 X X X X
6,7
X5 X5 X X X X
1,7
X3,5,6,9,10 X3,5,6,7,10
CHLOROACETIC ACID, SOLID CHROMIC FLUORIDE, SOLID CORROSIVE SOLID N O S (Packaging group I) CORROSIVE SOLID, N.O.S. (Packaging groups II and III) DIPHENYLMETHYL BROMIDE FERRIC CHLORIDE, ANHYDROUS LEAD SULPHATE with more than 3% free acid PHOSPHORIC ACID, SOLID PHOSPHORUS PENTACHLORIDE PHOSPHORUS PENTOXIDE
X3,6,9,10 X
3,6,10
X3,6,9,10
y,3,6,10
X6,9,10 X6,10 X6,7 X5,6,7,9,10
X5,7 X X X X X5 X
X3,5,6,7,9,10
X5,7 X X X X X5 X
X5,6,7 X X X X X5 X
X3,5,6,7,9,10
X3,10

X3,10

X10

X3,5,6,10 X3,6,9,10
X3,5,6,10 X3,6,9,10
X5,6,10 X6,9,10
Class+ subsidiary risk (s)
3
UN No.
1 1811 1812 1813 1823 1825 1830 1835 1839 1841 1843 1847 1849 1856 1868 1869 1871 1872 1884 1885 1894 1895 1905 1907 1923 1929 1931 1938 1939
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
POTASSIUM HYDROGENDIFLUORIDE, SOLID POTASSIUM FLUORIDE, SOLID POTASSIUM HYDROXIDE, SOLID SODIUM HYDROXIDE, SOLID SODIUM MONOXIDE SULPHURIC ACID with more than 51% acid TETRAMETHYLAMMONIUM HYDROXIDE TRICHLOROACETIC ACID SOLID ACETALDEHYDE AMMONIA AMMONIUM DINITRO-ortho-CRESOL ATE, POTASSIUM SULPHIDE, HYDRATED SODIUM SULPHIDE, HYDRATED RAGS, OILY DECABORANE MAGNESIUM or MAGNESIUM ALLOYS TITANIUM HYDRIDE LEAD DIOXIDE BARIUM OXIDE BENZIDINE PHENYLMERCURIC HYDROXIDE PHENYLMERCURIC NITRATE SELENIC ACID SODA LIME CALCIUM DITHIONITE POTASSIUM DITHIONITE ZINC DITHIONITE BROMOACETIC ACID, SOLID PHOSPHORUS OXYBROMIDE, SOLID
8+ 6.1 6.1 8 8 8 8 8 8 9 6.1 8 8 4.2 4.1+ 6.1 4.1 4.1 5.1 6.1 6.1 6.1 6.1 8 8 4.2 4.2 9 8 8
X5 X X X X X X X X X X X X5 X X5 X X X X X X6 X X5 X5 X X X5
X3,5,6,9,10 X3,9 X3,6,9,10 X3,6,9,10 X3,6,9,10 X

3,6,9,10
X5 X X X X X X X X X X X
X5 X X X X X X X X X X X
X3,5,6,9,10 X3,9 X3,6,9,10 X3,6,9,10 X3,6,9,10 X

3,6,9,10
X5,6,9,10 X9 X6,9,10 X6,9,10 X6,9,10 X6,9,10 X6,9,10 X6,9,10 X X6,9 X6,9,10 X6,9,10 X X X10 X6 X6 X6 X6 X9,10
X3,6,9,10 X3,6,9,10 X3 X3,6,9 X3,6,9,10 X3,6,9,10 X
X3,6,9,10 X3,6,9,10 X3 X3,6,9 X3,6,9,10 X3,6,9,10

X5 X
X5 X X X X X X X1 X X5 X5 X X X5
X3
X3
X3,4 X3,10 X3,6 X3,6 X3,6 X3,9,10
X X X X X X6 X X5 X5 X X X5
X3 X3,10 X3,6 X3,6 X3,6
X3,9,10
X3 X3,6,9,10 X3,5,6,9,10
X3 X3,6,9,10 X3,5,6,9,10
X X6,9,10 X5,6,9,10
3
UN No.
1 2305 2306 2315 2316 2318 2331 2430
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
NITROBENZENESULPHONIC ACID, (ortho-, meta, para-) NITROBENZOTRIFLUORIDES, SOLID POLYCHLORINATED BIPHENYLS SODIUM CUPROCYANIDE, SOLID SODIUM HYDROSULPHIDE with less than 25% water of crystallization ZINC CHLORIDE, ANHYDROUS ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) (Packaging group I) ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) (Packaging groups II and III) CHLORONITROTOLUENES SODIUM HYDROGENDIFLUORIDE STANNIC CHLORIDE PENTAHYDRATE NITROCRESOLS BERYLLIUM NITRATE DICHLOROISOCYANURIC ACID, DRY or DICHLOROISOCYANURIC ACID, SALTS POTASSIUM SUPEROXIDE TRICHLOROISOCYANURIC ACID, DRY SODIUM ARSANILATE VANADIUM TRICHLORIDE ZIRCONIUM TETRACHLORIDE AMMONIUM FLUORIDE AMMONIUM HYDROGEN SULPHATE CHLOROPLATINIC ACID, SOLID
8 6.1 9 6.1 4.2 8 8 8 6.1 8 8 6.1 5.1+ 6.1 5.1 5.1 5.1 6.1 8 8 6.1 8 8
X X X X
5,6
3,6,10
X X X X
5,6
X X X X
1,5,16
3,6,10
X6,10
-
3,6 -
3,6 -
X6 X
1,5,14
X5 X X6 X X X5 X X X X X6,7 X X X X X X X X
X5 X X6 X X X5 X X X X X6,7 X X X X X X X
3
X5 X X1 X6 X X5 X X X X X6,7,16 X X X X X X X
X3,9,10
X3,9,10
X9,10 X6 X6,9
-
2430 2433 2439 2440 2446 2464 2465 2466 2468 2473 2475 2503 2505 2506 2507
X3,6,9
-
X3,6,9
-
X3,5,6,10 X3,9,10
-
X3,5,6,10 X3,9,10
-
X5,6,10 X9,10
-
X3,4,6 X3,4,6,9
3,4,6
X3,6 X3,6,9
-
X6 X6,9
3,6 3
X6 X X9,10 X9,10 X X6,10 X9,10
X3,9,10 X3,9,10 X
3
X3,9,10 X3,9,10 X
3
X3,6,10 X3,9,10
X3,6,10 X3,9,10
IMDG CODE - PAGE 0226l (page 0226m follows) Amdt. 29-98
3
UN No.
1 2508 2509 2511 2512 2516 2538 2547 2567 2570 2570 2573 2578 2579 2583
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
MOLYBDENUM PENTACHLORIDE POTASSIUM HYDROGEN SULPHATE 2-CHLOROPROPIONIC ACID, solid AMINOPHENOLS (-ortho,-meta,-para) CARBON TETRABROMIDE NITRONAPHTHALENE SODIUM SUPEROXIDE SODIUM PENTACHLOROPHENATE CADMIUM COMPOUND (Packaging group I) CADMIUM COMPOUND (Packaging groups II and THALLIUM CHLORATE PHOSPHORUS TRIOXIDE PIPERAZINE SOLID ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, SOLID or ARYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid BENZOQUINONE PESTICIDE SOLID TOXIC N O S (Packaging PESTICIDE, SOLID, TOXIC, N.O.S. (Packaging groups II and III) ASBESTOS WHITE FIRELIGHTERS, SOLID MAGNESIUM SILICIDE
8 8 8 6.1 6.1 4.1 5.1 6.1 6.1 6.1 5.1+ 6.1 8 8 8
X5 X X X X X X6,7 X X6 X X X X X
X3,5,9,10 X3,6,10 X3,9,10 X3 X3,9 X3
X5 X X X X X X6,7 X X6 X X X X X
X5 X X X X X X6,7,16 X X1,16 X6 X X X X
X3,5,9,10 X3,6,10 X3,9,10 X3 X3,9 X3
X5,9,10 X6,10 X9,10 X X9 X X6 X6,14 X6 X6,9
X3,6
X3,6
X3,6 X3,4,6,9
X3,6 X3,6,9 X3,9,10 X3,6,10
X3,9,10 X3,6,10
X9,10 X6,10
2585 2587 2588 2588 2590 2623 2624
8 6.1 6.1 6.1 9 4.1 4.3
X X X
6
X3,6,10 X3,6
X X X
6
X X X
1
X3,6,10 X3,6
X6,10 X6 X6 X6 X X6
X X X X5
X3,6 X3
X X X X5
X6 X X X
X.3,6 X3 X6
3
UN No.
1 2763
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard 8
26.7 Wooden
9
TRIAZINE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) THIOCARBAMATE PESTICIDE, SOLID, TOXIC (Packaging group I) THIOCARBAMATE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) COPPER BASED PESTICIDE, SOLID, TOXIC (Packaging group I) COPPER BASED PESTICIDE, SOLID, TOXIC (Packaging groups II and III) MERCURY-BASED PESTICIDE, SOLID, TOXIC (Packaging group I) MERCURY-BASED PESTICIDE, SOLID, TOXIC (Packaging groups II and III) SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC (Packaging group I)
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1
X X6 X X6 X X6 X X6
X3,6
X X6 X X6 X X6 X X6
X6 X1 X6 X1 X6 X1,16 X6 X1
X3,6
X6 X6 X6 X6 X6 X6,14 X6 X6
2771
2771
X3,6
X3,6
2775
2775
X3,6
X3,6
2777
2777
X3,6
X3,6
2779
3
UN No.
1 2779
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
SUBSTITUTED NITROPHENOL, PESTICIDE, SOLID, TOXIC (Packaging groups II and III) BIPYRIDILIUM PESTICIDE, SOLID TOXIC (Packaging group I) BIPYRIDILIUM PESTICIDE, SOLID TOXIC (Packaging groups II and III) ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (Packaging group I) ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC (Packaging groups II and III) ORGANOTIN PESTICIDE, SOLID, TOXIC (Packaging group I) ORGANOTIN PESTICIDE, SOLID, TOXIC (Packaging groups II and III) FERROUS METAL BORINGS, SHAVINGS, TURNINGS or CUTTINGS in a form liable to self-heating SULPHURIC ACID with not more than 51% acid COPPER CHLORIDE LITHIUM HYDRIDE, FUSED SOLID LITHIUM NITRIDE TOXIC SOLID, ORGANIC N.O.S. (Packaging group I) TOXIC SOLID, ORGANIC N.O.S. (Packaging groups II and III) WATER REACTIVE SOLID, N.O.S. CROTONIC ACID LITHIUM FERROSILICON PHOSPHOROUS ACID, solid CALCIUM MANGANESE SILICON
6.1 6.1 6.1 6.1 6.1 6.1 6.1
X X6 X X6 X X6 X
3,6
X X6 X X6 X X6 X
3,6
X6 X6 X6 X6 X6 X6,14 X6
2781
X1 X6 X1 X6 X1,16 X6
2781
X3,6
X3,6
2783
2783
X3,6
X3,6
2786
2786
X3,6
X3,6,
2793
4.2 8 8 4.3 4.3 6.1 6.1 4.3 8 4.3 8 4.3
X X X X
5
2796 2802 2805 2806 2811 2811 2813 2823 2830 2834 2844
X3,6,9,10 X3,9,10

X X

X X

X3,6,9,10 X3,9,10

X6,9,10 X9,10

X5,6 X
6,7
6,7
1,7
X6,7 X6
X X5,6,7 X X5 X X
5
X3,6
X6
X3,6
X3,10
X X5 X X
5
X X5 X X
5
X3,10
X10
X3,9,10
X3,9,10
X9,10
3
UN No.
1 2853 2854 2855 2856 2859 2861 2862 2863 2864 2865 2869 2871 2875 2876 2878
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Composite
7
26.6 Fibreboard
8
26.7 Wooden
9
MAGNESIUM FLUOROSILICATE AMMONIUM FLUOROSILICATE ZINC FLUOROSILICATE FLUOROSILICATES, N.O.S. AMMONIUM METAVANADATE AMMONIUM POLYVANADATE VANADIUM PENTOXIDE, non-fused form SODIUM AMMONIUM VANADATE POTASSIUM METAVANADATE HYDROXYLAMINE SULPHATE TITANIUM TRICHLORIDE MIXTURE, nonpyrophoric ANTIMONY POWDER HEXACHLOROPHENE RESORCINOL TITANIUM, SPONGE GRANULES, or TITANIUM, SPONGE POWDERS CALCIUM HYPOCHLORITE, HYDRATED, or CALCIUM HYPOCHLORITE, HYDRATED MIXTURE, with more than 5.5% but not more than 10% water CHLOROPHENOLATES, SOLID or PHENOLATES, SOLID CORROSIVE SOLID FLAMMABLE, N.O.S. (Packaging group I) CORROSIVE SOLID, FLAMMABLE, N.O.S. (Packaging group II) CORROSIVE SOLID, TOXIC, N.O.S. (Packaging group I) CORROSIVE SOLID, TOXIC, N.O.S. (Packaging groups II and III) FLAMMABLE SOLID, CORROSIVE, ORGANIC,
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 8 6.1 6.1 6.1 4.1
X X X X X X X X X X X5 X X X X
X3 X3 X X
3 3
X3 X3 X3 X
3
X X X X X6 X6 X X6,9 X6 X10 X5,6,10 X X X X
X3,6 X3,6 X X
3
X3,6 X3,6 X X
3
3,6,9 3,6
3,6,9 3,6
X3,10 X3,5,6,10 X3 X X
3 3
X3,10 X3,5,6,10 X3 X3 X
3
X3
2880
5.1
2905
8 8+ 4.1 8+ 4.1 8+ 6.1 8+ 6.1 4.1+ 8
X X6,7 X5,7 X6,7 X5,7 X2,5,7
X3,10

X X6,7 X5,7 X6,7 X3,7 X2,5,7
X X1,7,16 X5,6,7 X',7 X5,6,7 X2,5,7
X3,10

X10

2921
2921 2923
2923 2925
N.O.S.
3
UN No.
1 2926 2928
Substance
2
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5 Com26.6 posite Fibreboard

7 8
26.7 Wooden
9
FLAMMABLE SOLID, TOXIC, ORGANIC, N.O.S. TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (Packaging group I) TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (Packaging group II) TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. (Packaging group I) TOXIC SOLID, FLAMMABLE, ORGANIC, N.O.S. (Packaging group II) VANADYL SULPHATE alpha -METHYLBENZYL ALCOHOL, SOLID 9-PHOSPHABICYCLONONANES SODIUM HYDROSULPHIDE, SOLID with not less than 25% water of crystallization MAGNESIUM GRANULES, COATED containing more than 50% magnesium SULPHAMIC ACID MANEB or MANEB PREPARATIONS STABILIZED against self heating CASTOR BEANS or CASTOR MEAL or CASTOR POMACE or CASTOR FLAKE LEAD PHOSPHITE DIBASIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging group I) COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) ENVIRONMENTALLY HAZARDOUS, SUBSTANCE, SOLID, N.O.S. CERIUM turnings or gritty powder
4.1+ 6.1 6.1+ 8 6.1+ 8 6.1+ 4.1 6.1+ 4.1 6.1 6.1 4.2 8 4.3 8 4.3 9 4.1 6.1 6.1 9 4.3
2,5,7
2,5,7
2,5,7
6,7
6,7
1,7
2928
X6,7 X6,7 X5 X X X
5
X5,7 X6,7 X5,7 X X X

5
X5,6,7 X1,7,16 X5,6,7 X X X

5
2930
2930 2931 2937 2940 2949
3,6
3,6
X6
X X X X X X X6 X X X5
X3,6,9,10 X8 X3,10 X8 X3,6 X3,6
X X X X X X X6 X X X5
X X X X X X X1 X6 X X5
X3,6,9,10 X8 X3,10 X8 X3,6 X3,6
X6,9,10 X8 X10 X8 X6 X6 X6 X6 X X5,6
2950 2967 2968 2969 2989 3027
3027 3077 3078
X3,6 X3
X3,6 X3 X3,5,6
IMDG CODE - PAGE 0226s (page 0226t follows) Amdt. 28-96
3
26.2 Metal
4
26.3 Flexible
5
26.4 Rigid plastics

6
26.5
26.6
26.7 Wooden
9
UN No.
1 3088 3096 3110 3120 3131 3132 3134
Substance
2
Composite Fibreboard
7 8
SELF HEATING SOLID, ORGANIC, N.O.S. CORROSIVE SOLID, WATER REACTIVE, N.O.S. ORGANIC PEROXIDE, TYPE F, SOLID ORGANIC PEROXIDE TYPE F, SOLID, TEMPERATURE CONTROLLED WATER REACTIVE SOLID, CORROSIVE, N.O.S. WATER REACTIVE SOLID, FLAMMABLE, N.O.S. WATER REACTIVE SOLID, TOXIC, N.O.S. DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. (Packaging group I) DYE, SOLID, TOXIC, N.O.S. or DYE INTERMEDIATE, SOLID, TOXIC, N.O.S. (Packaging groups II and III) ORGANOTIN COMPOUND, SOLID, N.O.S. (Packaging group I) ORGANOTIN COMPOUND, SOLID, N.O.S. (Packaging groups II and III) DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. (Packaging group I) DYE, SOLID, CORROSIVE, N.O.S. or DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. (Packaging groups II and III) POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID TITANIUM DISULPHIDE FLAMMABLE SOLID, INORGANIC, N.O.S. FLAMMABLE SOLID, TOXIC, INORGANIC, N.O.S. FLAMMABLE SOLID, CORROSIVE, INORGANIC,
4.2 8+ 4.3 5.2 5.2 4.3+ 8 4.3+ 4.1 4.3+ 6.1 6.1
X5 X5,6,7 X
7,12
X5 X2,6,7 X
7,12
X5 X1,5,7,16 X
7,12,15
3,6,7,9,10,12
3,6,7,9,10,12
X7,12,5 X5,6,7 X2,5,6,7 X

2,6,7
X3,6,9,10,12,15

X7,12

X7,12,15

X3,6,7,10,12,15

3143
X6,7
X6
X1,7
X6,7
3143
6.1
X3,6,9
X6
X3,6,9
X6,9
3146
6.1 6.1
X6 X
X6 X
X1,16 X6
X6,14 X6
3146
X3,6
X3,6
3147
X6,7
X6,7
X1,7
X6,7,9,10
3147
X3,6,9,10
X3,6,9,10
X6,9,9
3152 3174 3178 3179 3180
9 4.2 4.1 4.1+ 6.1 4.1+ 8
X X5,7 X2,5 X
2,5,7
X3,6 X5,7 X2,5,6,7

X X5,7 X2,5,7 X
2,5,7
X X5,7 X2,5,7 X
2,5
X3,6 X5,7 X2,5,6,7,

X6 X5,7 X2,5,6,7

N.O.S.
X2,5,7
X2,5,7
X2,5,7
IMDG CODE - PAGE 0226t (page 0226u follows) Amdt. 29-98
Class+ subsidiary risk (s) 3
26.2
Metal 4
26.3
Flexible 5

26.4
Rigid plastics 6

26.5
Composite 7

26.6
Fibreboard 8

26.7
Wooden 9

UN No.
1 3190 3208 3212 3215 3247 3253
Substance
2
SELF-HEATING SOLID, INORGANIC, N.O.S. METALLIC SUBSTANCE, WATER REACTIVE, N.O.S. HYPOCHLORITES, INORGANIC, N.O.S. PERSULPHATES, INORGANIC, N.O.S. SODIUM PEROXOBORATE, ANHYDROUS DISODIUM TRIOXOSILICATE AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES, SOLID, CORROSIVE, N.O.S. (Packaging group I) AMINES, SOLID, CORROSIVE, N.O.S. or POLYAMINES SOLID, CORROSIVE, N.O.S. (Packaging groups II and III) CORROSIVE SOLID ACIDIC, INORGANIC N.O.S. (Packaging group I) CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. (Packaging groups II and III) CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. (Packaging group I) CORROSIVE SOLID ACIDIC, ORGANIC, N.O.S. (Packaging groups II and III) CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Packaging group I) CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. (Packaging groups II and III)
4.2 4.3 5.1 5.1 5.1 8 8
X5,7 X5,6,7 X
7
X7 X X X6,7 X
3,4,6,9
X7 X X X6,7
X7 X X XI,7 X
3,6,9
X6,9 X10 X6,7
X3,10
X3,10
3259
3259
X5,7
X3,5,6,7,9,10
X5,7
X5,6,7
X3,5,6,7,9,10
X5,6,7,9,10
3260
8 8 8 8 8 8
X6,7 X5,7 X6,7 X5,7 X6,7 X5,7
X6,7 X5,7 X6,7 X5,7 X6,7 X5,7
X1,7 X5,6,7 XI,7 X5,6,7 X1,7 X5,6,7
X6,7 X5,6,7,9,10 X6,7 X5,6,7,9,10 X6,7 X5,6,7,9,10
3260
X3,5,6,7,9,10
X3,5,6,7,9,10
3261
3261
X3,5,6,7,9,10
X3,5,6,7,9,10
3262
3262
X3,5,6,7,9,10
X3,5,6,7,9,10
IMDG CODE - PAGE 0226u (page 0226v follows) Amdt. 28-96
Class+ subsidiary risk (s) 3
26.2
Metal 4
26.3
Flexible 5
26.4
Rigid plastics 6
26.5
Composite 7
26.6
Fibreboard 8
26.7
Wooden 9
UN No.
1 3263
Substance
2
CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Packaging group I) CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. (Packaging groups II and III) NITRILES, TOXIC, N.O.S. (Packaging group I) ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S. ORGANOARSENIC COMPOUND, N.O.S. METAL CARBONYLS, N.O.S. (Packaging group I) METAL CARBONYLS, N.O.S. (Packaging groups II and III) ORGANOMETALLIC COMPOUND, TOXIC, N.O.S. (Packaging group I) ORGANOMETALLIC COMPOUND, TOXIC, N.O.S. (Packaging groups II and III) SELENIUM COMPOUND, N.O.S. (Packaging group I) SELENIUM COMPOUND, N.O.S. (Packaging groups II and III) TELLURIUM COMPOUND, N.O.S. (Packaging group I) TELLURIUM COMPOUND, N.O.S. (Packaging groups II and III) VANADIUM COMPOUND, N.O.S. (Packaging group I) VANADIUM COMPOUND, N.O.S. (Packaging groups II and III)
8 8 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1
X6,7 X5,7 X6,7 X

6
X6,7 X5,7 X6 X
6
X1,7 X5,6,7 X1,7 X

1
X6,7 X5,6,7,9,10 X6,7 X6 X6 X6,7 X6 X6,7 X6 X6,7 X6 X6,7 X6 X6,7 X6
3263 3276 3278 3280 3281 3281
X3,5,6,7,9,10

X3,5,6,7,9,10

X6 X
6,7
X6 X
6,7
X1 X
1,7
X X6,7 X X6,7 X X6,7 X X6,7 X
X3,6
X X6,7 X X6 X X6 X X6 X
X6 X1,7 X6 X1,7 X6 X1,7 X6 X1,7 X6
X3,6
3282
3282 3283 3283 3284 3284 3285 3285
X3,6
X3,6
X3,6
X3,6
X3,6
X3,6
X3,6,
X3,6
IMDG CODE - PAGE 0226v (page 0226w follows) Amdt. 29-98
Class + subsidiary risk(s) 3
26.2
Metal 4
26.3
Flexible 5
26.4
Rigid plastics 6
26.5
26.6
26.7
Wooden 9
UN No.
1 3288 3288 3290 3313 3341 3342 3345
Substance
2
Composite Fibreboard 7 8
TOXIC SOLID, INORGANIC, N.O.S. (Packaging group I) TOXIC SOLID, INORGANIC, N.O.S. (Packaging groups II and III) TOXIC SOLID, CORROSIVE, INORGANIC, N.O.S. ORGANIC PIGMENTS, SELF-HEATING THIOUREA DIOXIDE XANTHATES PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging group I) PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC (Packaging groups II and III) PYRETHROID PESTICIDE SOLID, TOXIC (Packaging group I) PYRETHROID PESTICIDE, SOLID, TOXIC (Packaging groups II and III)
6.1 6.1 6.1+8 4.2 4.2 4.2 6.1 6.1 6.1 6.1
X6,7 X X
6,7
X6,7 X X
6,7
X1,7 X6 X
1,7
X6,7 X6
X3,6
X3,6
1,5,17
X5,7 XI,5 X6 X X6 X
X5,7
X5,7 X1,5 X6 X X6 X
X5,7 X1,5,7 X1 X6 X1 X6
X5,7
X5,7 X1,7,18 X6 X6 X6 X6
3345 3349 3349
X3,6
X3,6
X3,6
X3,,6
IMDG CODE - PAGE 0226w (page 0227 follows) Amdt. 29-98
ANNEX
Packagings are receptacles and any other components or materials necessary for the receptacle to perform its containment function. Receptacles are containment vessels for receiving and holding substances or articles including any means of closing. Reconditioned packagings include: (a) metal drums, that 1 2 3 are cleaned to original materials of construction with all former contents, internal and external corrosion and external coatings and labels removed; are restored to original shape and contour with chimes (if any) straightened and sealed and all non-integral gaskets replaced; and are inspected after cleaning but before painting with rejection of packagings with visible pitting significant reduction in material thickness metal fatigue, damaged threads or closures, or other significant defects.
(b) plastics drums and jerricans, that 1 are cleaned to original materials of construction, with all former contents, external coating and labels removed; 2 have all non-integral gaskets replaced; and 3 are inspected after cleaning with rejection of packagings with visible damage such as tears creases or cracks, or damaged threads or closures. Recycled plastics material means material recovered from used industrial packagings that has been cleaned and prepared for processing into new packagings. The specific properties of the recycled material used for production of new packagings should be assured and documented regularly as part of a quality assurance programme recognized by the competent authority. The quality assurance programme should include a record of proper pre-sorting and verification, that each batch or recycled plastics material has the proper melt flow rate, density and tensile yield strength, consistent with that of the design type manufactured from such recycled material. This necessarily includes knowledge about the packaging material from which the recycled plastics have been derived, as well as awareness of the prior contents of those packagings, if those prior contents might reduce the capability of new packagings produced using that material In addition, the packaging manufacturer's quality assurance programme under 3.15 should include performance of the mechanical design type test in section 8 of this Annex on packagings manufactured from each batch of recycled plastics material. In this testing stacking performance may be verified by appropriate dynamic compression testing rather than static load testing. Remanufactured packagings include: (a) metal drums, that: 1 are produced as a UN type from a non UN type; 2 are converted from one UN type to another UN type; or 3 undergo the replacement of integral structural components (such as non-removable heads).
ANNEX I
(b) plastics drums, that: .1 are converted from one UN type to another UN type (e.g. 1H1 to 1H2), or .2 undergo the replacement of integral structural components. Remanufactured drums are subject to the same requirements of this Annex as those that apply to a new drum of the same type. Reused packagings are packagings to be refilled which have been examined and found free of defects affecting their ability to withstand the performance tests the term includes those, which are refilled with the same or similar compatible contents and are transported within distribution chains controlled by the consignor of the product. Salvage packagings are special packagings conforming to the applicable requirements of this Annex, into which, damaged, defective or leaking dangerous goods packages, or dangerous goods that have spilled or leaked are placed, for the purposes of transport, recovery or disposal. Siftproof packagings are packagings impermeable to dry contents, including fine solid material produced during transport. Wooden barrels are packagings made of natural wood, of round cross-section, having convex walls, consisting of staves and heads and fitted with hoops. The following explanations and examples are meant to assist in clarifying the use of the terms defined in 2.1 The definitions in 2.1 are consistent with the use of the defined terms throughout this Annex. However, other parts of this Code currently use some of the defined terms in other ways. This is particularly evident in respect of the term "inner receptacle", which is often used to describe the "inners" of a combination packaging. In this Annex the "inners" of "combination packagings are always termed inner packagings", not "inner receptacles". A glass carboy is an example of such an "inner packaging".
ANNEX I
ANNEX I
2.2.3 In this Annex the inners of composite packagings are termed inner receptacles. For example the inner of a 6HA1 composite packaging (plastics material) is such an inner receptacle since it is normally not designed to perform a containment function without its outer packaging and is not, therefore, an inner packaging.
3 GENERAL PACKING REQUIREMENTS 3.1 Dangerous goods should be packaged in packagings of good quality which should be constructed and closed so as to prevent the package as prepared for transport from any leakage, which might be caused by vibration or by changes in temperature, humidity or pressure. No harmful quantity of a dangerous substance should adhere to the outside of a package. These provisions apply both to new and to reused packagings. Parts of packagings which are in direct contact with dangerous substances should not be affected by chemical or other action of those substances. Where necessary they should be provided with a suitable inner coating or treatment. Such parts of packagings should not incorporate constituents liable to react dangerously with the contents so as to form hazardous products or to weaken them significantly. Each packaging except inner packagings of combination packagings should conform to a design type successfully tested in accordance with the requirements laid down in section 8. When filling packagings with liquids* sufficient ullage (outage) should be left to ensure that neither leakage nor permanent distortion of the packaging occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific requirements are prescribed in national or international rules agreements or recommendations liquids should not completely fill a packaging at a temperature of 55C. Inner packagings should be packaged in an outer packaging in such a way that under normal conditions of transport they cannot break be punctured or leak their contents into the outer packaging Inner packagings that are liable to break or be punctured easily such as those made of glass porcelain or stoneware or of certain plastics materials etc should be secured in outer packagings with suitable cushioning material Any leakage of the contents should not substantially impair the protective properties of the cushioning material or of the outer packaging. Dangerous goods should not be packed together in the same outer packaging with dangerous or other goods if they react dangerously with each other and cause 1. combustion and/or evolution of considerable heat; 2. evolution of flammable poisonous or asphyxiant gases; 3. the formation of corrosive substances; or 4. the formation of unstable substances.
3.2
3.3 3.4
3.5
3.6
* With respect to ullage limits only viscous substances with an outflow time via a DIN cup with a 4 mm diameter outlet exceeding 10 minutes at 20C (corresponding to an outflow time via a Ford cup 4 of more than 690 seconds at 20C or to a viscosity of more than 2.680 cent stokes at 20C) should be subject to the provisions applicable for packagings destined for solid substances.
ANNEX I
7.3.3 Openings in jerricans (3A1 and 3B1) should not exceed 7 cm in diameter Jerricans with larger openings are considered to be of the removable head type (3A2 and 3B2). Closures should be so designed that they will remain secure and leakproof under normal conditions of transport. Gaskets or other sealing elements should be used with closures unless the closure is inherently leakproof. If materials used for body heads, closures and fittings are not in themselves compatible with the contents to be transported, suitable internal protective coatings or treatments should be applied. These coatings or treatments should retain their protective properties under normal conditions of transport. Maximum capacity of jerrican 60 litres. Maximum net mass 120 kg. Plywood drums 1D 7.4.1 The wood used should be well seasoned commercially dry and free from any defect likely to lessen the effectiveness of the drum for the purpose intended. If a material other than plywood is used for the manufacture of the heads, it should be of a quality equivalent to the plywood. At least two-ply plywood should be used for the body and at least three ply plywood for the heads the plies should be firmly glued together by a water-resistant adhesive with their grain crosswise. The body and heads of the drum and their joins should be of a design appropriate to the capacity of the drum and intended use. In order to prevent sifting of the contents lids should be lined with kraft paper or some other equivalent material, which should be securely fastened to the lid and extend to the outside along its full circumference. Maximum capacity of drum 250 litres. Maximum net mass 400 kg. Wooden barrels 2C1 bung type 2C2 slack type (removable head) 7.5.1 The wood used should be of good quality straight grained, well seasoned and free from knots bark, rotten wood, sapwood or other defects likely to lessen the effectiveness of the barrel for the purpose intended. The body and heads should be of a design appropriate to the capacity of the barrel and intended use. Staves and heads should be sawn or cleft with the grain so that no annual ring extends over more than half the thickness of a stave or head.
7.3.4
7.3.5 7.3.6 7.4
7.4.2
7.4.3
7.4.4 7.4.5 7.4.6 7.5
7.5.2 7.5.3
ANNEX I
7.5.4 7.5.5 7.5.6 7.5.7 7.5.8 7.6 Barrel hoops should be of steel or iron of good quality. The hoops of 2C2 barrels may be of a suitable hardwood. Wooden barrels 2C1: the diameter of the bunghole should not exceed half the width of the stave in which it is placed. Wooden barrels 2C2: heads should fit tightly into the crozes. Maximum capacity of barrel: 250 litres. Maximum net mass: 400 kg. Fibre drums 1G The body of the drum should consist of multiple plies of heavy paper or fibreboard (without corrugations) firmly glued or laminated together and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc. Heads should be of natural wood, fibreboard, metal, plywood, plastics or other suitable material and may include one or more protective layers of bitumen, waxed kraft paper, metal foil, plastics material, etc. The body and heads of the drum and their joins should be of a design appropriate to the capacity of the drum and intended use. The assembled packaging should be sufficiently water-resistant so as not to delaminate under normal conditions of transport. Maximum capacity of drum: 450 litres. Maximum net mass: 400 kg. Plastics drums and jerricans 1H1 drums, non-removable head 1H2 drums, removable head 3H1 jerricans, non-removable head 3H2 jerricans, removable head 7.7.1 The packaging should be manufactured from suitable plastics material and be of adequate strength in relation to its capacity and intended use. Except for Recycled plastics material as defined in 2.1, no used material other than production residues or regrind from the same manufacturing process may be used. Packaging manufactured with such recycled plastics material should be marked "REC" near the marks prescribed in 6.2. The packaging should be adequately resistant to ageing and to degradation caused either by the substance contained or by ultraviolet radiation. Any permeation of the substance contained should not constitute a danger under normal conditions of transport. Unless otherwise approved by the competent authority, the period of use permitted for the transport of dangerous substances should be five years from the date of manufacture of the packaging, except where a shorter period of use is prescribed because of the nature of the substance to be transported.
7.6.1
7.6.2
7.6.3 7.6.4 7.6.5 7.6.6 7.7
7.7.2
ANNEX I
(b) not less than 1.75 times the vapour pressure at 50C of the substance to be transported minus 100 kPa, but with a minimum test pressure of 100 kPa; (c) not less than 1.5 times the vapour pressure at 55C of the substance to be transported minus 100 kPa but with a minimum test pressure of 100 kPa. 8.6.5 In addition packagings intended to contain substances of packaging group I should be tested to a minimum test pressure of 250 kPa (gauge) for a test period of 5 or 30 minutes depending upon the material of construction of the packaging. Criterion for passing the test no packaging should leak. Stacking test All design types of packagings other than bags should be subjected to a stacking test. 8.7.1 8.7.2 Number of test samples three test samples per design type and manufacturer. Test method the test sample should be subjected to a force applied to the top surface of the test sample equivalent to the total weight of identical packages, which might be stacked on it during transport where the contents of the test sample are non-dangerous liquids with relative density different from that of the liquid to be transported the force should be calculated in relation to the latter. The minimum height of the stack including the test sample should be 3 metres. The duration of the test should be 24 hours except that plastics drums, jerricans, and composite packagings 6HH1 and 6HH2 intended for liquids should be subjected to the stacking test for a period of 28 days at a temperature of not less than 40C.
8.6.6 8.7
8.7.3
Criteria for passing the test no test sample should leak In composite packagings or combination packagings there should be no leakage of the filling substance from the inner receptacle or inner packaging. No test sample should show any deterioration which could adversely affect transport safety or any distortion liable to reduce its strength or cause instability in stacks of packages. Plastics packagings should be cooled to ambient temperature before the assessment.
8.8 8.8.1 8.8.2 8.8.3
Cooperage test for bung-type wooden barrels Number of samples one barrel. Method of testing remove all hoops above the bilge of an empty barrel at least two days old. Criterion for passing the test the diameter of the cross section of the upper part of the barrel should not increase by more than 10%. Test report A test report containing at least the following particulars should be drawn up and should be available to the users of the packaging. 1 name and address of the test facility;
8.9 8.9.1
ANNEX I
2 3 4 5 6 7 8 9 10 8.9.2 name and address of the applicant (where applicable); a unique test report identification; date of the test report; manufacturer of the packaging; description of the packaging design type (e.g. dimensions materials, closures, thickness, etc.) including method of manufacture (e.g. blow moulding) and which may include drawing(s) and/or photograph(s); maximum capacity; characteristics of test contents, e.g., viscosity and relative density for liquids and particle size for solids; test descriptions and results; signature, with the name and status of the signatory.
The test report should contain statements that the packaging prepared as for transport was tested in accordance with the appropriate provisions of Annex I to the IMDG Code and that the use of other packaging methods or components may render it invalid. A copy of the test report should be available to the competent authority. Leakproofness test for aerosol dispensers and small receptacles for gas. Each receptacle should be subjected to a test performed in a hot water bath. The temperature of the bath and the duration of the test should be such that the internal pressure reaches that which would be reached at 55C (50C if the liquid phase does not exceed 95% of the capacity of the receptacle at 50C). If the contents are sensitive to heat or if the receptacles are made of plastics material which softens at this test temperature, the temperature of the bath should be set at between 20C and 30C but in addition one receptacle in 2.000 should be tested at the higher temperature. No leakage or permanent deformation of a receptacle should occur, except that a plastics receptacle may be deformed through softening provided that it does not leak.
8.10 8.10.1
8.10.2
IMDG CODE - PAGE 0539 27-94
(pages 0540 to 9999 have been Amdt. reserved for future amendments)
GENERAL INDEX
SUBSTANCE or ARTICLE ACETALP - ditto ACETALDEHYDEP para-ACETALDEHYDE ACETALDEHYDE AMMONIA ACETALDEHYDE DIETHYL ACETAL - ditto beta-ACETALDEHYDE OXIME ACETALDOL beta-ACETALDOXIME ACETIC ACID, GLACIAL ACETIC ACID SOLUTION more than 80% acid , by mass ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass ACETIC ALDEHYDEP ACETIC ANHYDRIDE
P
IMDG CODE PAGE 3101 3171 3101 see 3372 9021 see 3101 see 3171 3301 see 6055 see 3301 8100
UN No. 1088 1088 1089
CLASS
Packaging Group II II I III III II II III II III II
Subsidiary Risk Label (s) Flammable liquid Flammable liquid
EmS No.
MFAG Table No. 330 330 300 300 320 330 330 320 300 320 700
3.1 3.2 3.1 3.3 9 3.1 3.2 3.3 6.1 3.3 8
3-06 3-06 3-06 3-06 8-07 3-06 3-06 3-06 6.1-02 3-06 8-04
1264
1841 1088 1088 2332 2839 2332 2789 2789
8100
II
8-04
700
8100 see 3101 8101
2790
1089 1715
8 3.1 8
II* I II
Flammable liquid Flammable liquid Corrosive
8-05 3-06 8-04
700 300 700
ACETIC OXIDE ACETOIN ACETONE ACETONE CYANOHYDRIN STABILIZEDP ACETONE HEXAFLUORIDE ACETONE OILS ACETONE SOLUTIONS
see 8101 see 3301 3102 6051 see 2145 3171 3172
1715 2621 1090 1541 2420 1091 1090
8 3.3 3.1 6.1 2 (2.3) 3.2 3.2
II III II I II II
8-04 3-06 3-06 6.1-02 2-08 3-07 3-06
700 305 300 215 750 300 300
* Packaging group III for solutions with more than 10% but less than 50% acid, by mass
P, PP
or
see explanatory notes in the introduction to this index

GENERAL INDEX
SUBSTANCE or ARTICLE ACETONITRILE 3-ACETOXYPROPENE ACETYLACETONE ACETYL ACETONE PEROXIDE (concentration 42%, with diluent type A and water available oxygen 4.7%) ACETYL ACETONE PEROXIDE (concentration 32%, as a paste, with diluent type A with or without water) ACETYL BENZOYL PEROXIDE (concentration 45% with diluent type A) ACETYL BROMIDE ACETYL CHLORIDE ACETYL CYCLOHEXANE-SULPHONYL PEROXIDE (concentration 82%, with water) ACETYL CYCLOHEXANE-SULPHONYL PEROXIDE (concentration 32%, with diluent type B) ACETYLENE, DISSOLVED ACETYLENE, ETHYLENE AND PROPYLENE MIXTURES, REFRIGERATED LIQUID ACETYLENE DICHLORIDE ACETYLENE TETRABROMIDE
P P
IMDG CODE PAGE 3173 see 3180 see 3373
UN No. 1648 2333 2310
CLASS 3.2 3.2 3.3
Packaging Group II II III
Subsidiary Risk Label (s) Toxic Toxic
EmS No. 3-06 3-02 3-06
MFAG Table No. 215 330 300
see ORGANIC PEROXIDE TYPE D, LIQUID
see ORGANIC PEROXIDE TYPE D, SOLID
see ORGANIC PEROXIDE TYPE D, LIQUID 8101 3172 1716 1717 8 3.2 II II Corrosive 8-02 3-04 700 700
see ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 2101 1001 2 (2.1) 2-07 310
see ETHYLENE ACETYLENE AND PROPYLENE MIXTURES, REFRIGERATED LIQUID see 3205 see 6263 see 6263 8102 see 61301 3301 1150 2504 1702 1898 2521 2621 3.2 6.1 6.1 8 6.1 3.3 II III II II I III Flammable liquid 3-07 6.1-02 6.1-02 8-02 6.1-01 3-06 340 345 340 700 300 305
ACETYLENE TETRACHLORIDE ACETYL IODIDE ACETYL KETENE INHIBITED ACETYL METHYL CARBINOL
P, PP
or
see explanatory notes in the introduction to this index

GENERAL INDEX
SUBSTANCE or ARTICLE
IMDG CODE PAGE see 8101 see 8132 see 8184 see 8194 see 8194 see 6053 6052 see 8102 6053 see 3208 3302 6054 6054 8102 see 3354 see 6053 3173 see 9024
UN No.
CLASS
Packaging Group II III I I/II I/II I III II I II III III III II III I I III
Subsidiary Risk Label (s) Flammable liquid Toxic Oxidizing agent* Oxidizing agent* Flammable liquid Flammable liquid Flammable liquid Flammable liquid Flammable liquid Toxic
EmS No.
MFAG Table No. 700 700 750 700 700 300 325 700 300 330 300 323 323 700 330 300 215 none
ACETYL OXIDE ACID BUTYL PHOSPHATE ACID MIXTURE, HYDROFLUORIC AND SULPHURIC ACID MIXTURE, NITRATING ACID ACID MIXTURE, SPENT, NITRATING ACID ACRALDEHYDE, INHIBITEDP ACRIDINE ACROLEIC ACID, INHIBITED ACROLEIN, INHIBITEDP ACROLEIN DIETHYL ACETAL ACROLEIN DIMER, STABILIZED ACRYLAMIDE, SOLID ACRYLAMIDE, SOLUTION ACRYLIC ACID, INHIBITED ACRYLIC ACID ISOBUTYL ESTER, INHIBITED ACRYLIC ALDEHYDE, INHIBITEDP ACRYLONITRILE, INHIBITED ACTINOLITE ACTIVATED CARBON ACTIVATED CHARCOAL
1715 1718 1786
8 8 8 8 8 6.1 6.1 8 6.1 3.2 3.3 6.1 6.1 8 3.3 6.1 3.2 9
8-04 8-05 8-03 8-03 8-03 6.1-01 6.1-03 8-01 6.1-01 3-06 3-06 6.1-04 6.1-02 8-01 3-03 6.1-01 3-02 6.1-04
1796
1826
1092 2713 2218
1092 2374 2607 2074 2074 2218
2527
1092 1093 2590
see CARBON, ACTIVATED see CHARCOAL, ACTIVATED
* Not required if nitric acid content is not more than 50%

p pp
or
see explanatory notes in the introduction to this index.

GENERAL INDEX
SUBSTANCE or ARTICLE ADHESIVES, containing a flammable liquid - ditto - - ditto - ADIPONITRILE Aeroplane flares AEROSOLS AGENTS, BLASTING TYPE B AGENTS BLASTING, TYPE E AIR, COMPRESSED AIR, REFRIGERATED LIQUID AIR BAG INFLATORS, pyrotechnic AIR BAG INFLATORS, COMPRESSED GAS AIR BAG MODULES, pyrotechnic AIR BAG MODULES, COMPRESSED GAS AIRCRAFT HYDRAULIC POWER, UNIT FUEL TANK (containing a mixture of anhydrous hydrazine and methylhydrazine) ALCOHOL ALCOHOL, DENATURED ALCOHOL, DENATURED SOLUTIONS ALCOHOL, INDUSTRIAL
IMDG CODE PAGE 3102 3174 3302 6054
UN No.
1133 1133 1133 2205
CLASS
Packaging Group I/II* I/II* III III
Subsidiary Risk Label (s)
EmS No.
MFAG Table No. 330 330 330 215
3.1 3.2 3.3 6.1
3 05 3-05 305 6.1-02
see FLARES AERIAL 2102 see 111 7 see 1120 2103 2103 9022-1 2102-1 9022-1 2102-1 3174-2 see 3219 see 3219 see 3337-1 see 3219
1950 0331 0332 1002 1003 3268 3353 3268 3353
2 () 1.5 D 1.5 D 2 (2.2) 2 (2.2) 9 2.2 9 2.2 3.2 3.2 3.2 3.3 3.2
III Ill I II II III II
2-13 1-05 1-05 2-04 2-11

620 ** ** none 620 none none none none 720 305 305, 306 305, 306 305, 306
Oxidizing agent Toxic, Corrosive
3165
3-02 3-06 3-06 3-06 3-06
1170 1170
1170
1170
* Packaging group III under certain conditions

Label as approved by the competent authority of the country concerned. 3 MFAG Table No 620 for classes 2.1 and 2.2 only For substances in class 2.3 and aerosols with a capacity of 1000 cm or less, if an MFAG table number is not supplied by the shipper refer to subsection 4.2 of the MFAG ** Explosive substance or article, refer to subsection 7.3 of the MFAG. To be declared by the shipper.
p pp
or

GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group III II II
Subsidiary Risk Label (s) Corrosive Corrosive
EmS No.
MFAG Table No. 305, 306 * *
ALCOHOL INDUSTRIAL, SOLUTIONS ALCOHOLATES, SOLUTION N.O.S. in alcohol - ditto - ALCOHOL C6-C17 (SECONDARY) POLY (36) ETHOXYLATE p ALCOHOL C12-C16 POLY(16)ETHOXYLATE ALCOHOL C13-C15 POLY(16)ETHOXYLATE p ALCOHOLIC BEVERAGES - ditto ALCOHOLS, N.O.S. - ditto - ALCOHOLS, FLAMMABLE, TOXIC,
see 3337-1 3102-1 3174-2
1170 3274 3274
3.3 3.1 3.2
3-06 3-06 3-06
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 3174-3 3304 3175 3303 3104 3176 3303 see 3337-1 3105 3177 3305 3105 3178 3305 3065 3065 1987 1987 1986 1986 1986 1170 1989 1989 1989 1988 1988 1988 3.2 3.3 3.2 3.3 3.1 3.2 3.3 3.3 3.1 3.2 3.3 3.1 3.2 3.3 II III II III I/II I/II III III I/II I/II III I/II I/II III Toxic Toxic Toxic Toxic Toxic Toxic 3-06 3-06 3-06 3-06 3-07 3-07 3-07 3-06 3-07 3-07 3-07 3-07 3-07 3-07 305 305 305 305 305 305 305 305 300 300 300 300 300 300
N.O.S.
- ditto - - ditto - ALCOHOL SOLUTIONS ALDEHYDES, N.O.S. - ditto - - ditto - ALDEHYDES FLAMMABLE TOXIC
NOS
- ditto - - ditto - Aldicarb ALDOL Aldrin
pp
see CARBAMATE PESTICIDE 6055 2839 6.1 II 6.1-02 300
see ORGANOCHLORINE PESTICIDE 4220-1 3206 4.2 II/III Corrosive 4.2-08 705
ALKALI METAL ALCOHOLATES, SELFHEATING, CORROSIVE, N.O.S.
* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE ALKALI METAL ALLOY, LIQUID, N.O.S. ALKALI METAL AMALGAM ALKALI METAL AMIDE ALKALI METAL DISPERSION ALKALINE CAUSTIC LIQUID, N.O.S. ALKALINE EARTH METAL, ALCOHOLATES,
IMDG CODE PAGE 4321 4322 4323 4324 see 8136 4220-1 4325 4326 4324 6056 6056 6056 6056
UN No. 1421 1389 1390 1391 1719 3205 1393 1392 1391 3140 1544 3140 1544
CLASS 4.3 4.3 4.3 4.3 8 4.2 4.3 4.3 4.3 6.1 6.1 6.1 6.1
Packaging Group I I II I II/III II/III II I I I/II/III I/II/III I/II/III I/II/III
Subsidiary EmS No. Risk Label(s) Flammable liquid* Flammable liquid* 4.3-01 4.3-04 4.3-05 4.3-01 8-06 4.2-08 4.3-04 4.3-04 4.3-01 6.1-02 6.1-04 6.1-02 6.1-04
MFAG Table No. 705 705 705 705 705 705 705 705 705 805 805 805 805
N.O.S.
ALKALINE EARTH METAL ALLOY, N.O.S. ALKALINE EARTH METAL, AMALGAM ALKALINE EARTH METAL, DISPERSION ALKALOIDS, LIQUID, N.O.S. ALKALOIDS, SOLID, N.O.S. ALKALOID SALTS, LIQUID, N.O.S. ALKALOID SALTS, SOLID, N.O.S. Alkaloids and alkaloid salts (pesticides) ALKYLALUMINIUM ALKYLBENZENE SULPHONATES, branched and straight chain p ALKYL(C12-C14)DIMETHYLAMINE p ALKYL (C7-C9) NITRATES
p
see PESTICIDE, N.O.S. see ALUMINIUM ALKYLS see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see .1.5 of the General Introduction see Section 23.1.5 of the General Introduction 8103 8103 3145 2430 8 8 I/II/III I/II/III 8-15 8-15 710 710
ALKYLPHENOLS, LIQUID, N.O.S. (including C2-C12 homologues) p ALKYLPHENOLS, SOLID, N.O.S. (including C2-C12 homologues) p
* If flashpoint 61C c.c. or below ,
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
PackSubsidiary aging EmS No. Risk Label(s) Group II III II III II

-
MFAG Table No. 700 700 700 700 700 310
ALKYLSULPHONIC ACIDS, LIQUID with more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, LIQUID with not more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, SOLID with more than 5% free sulphuric acid ALKYLSULPHONIC ACIDS, SOLID with not more than 5% free sulphuric acid ALKYLSULPHURIC ACIDS ALLENE, INHIBITED Allidochlor ALLYL ACETATE ALLYL ALCOHOL ALLYLAMINE ALLYL BROMIDE p ALLYL CHLORIDE ALLYL CHLOROCARBONATE
8105 8105 8106 8106 8104 see 2173
2584 2586 2583 2585 2571 2200
8 8 8 8 8 2(2.1)
8-06 8-06 8-06 8-06 8-06 2-07
see PESTICIDE, N.O.S. 3180 6058 6059 3180 3105-1 see 6060 2333 1098 2334 1099 1100 1722 3.2 6.1 6.1 3.2 3.1 6.1 II I I I I I Toxic Flammable liquid Flammable liquid Toxic Toxic Flammable liquid, Corrosive Flammable liquid, Corrosive Toxic Toxic Corrosive Flammable liquid 3-02 6.1-01 6.1-01 3-03 3-03 6.1-01 330 307 320 345 340 740
ALLYL CHLOROFORMATE ALLYL ETHYL ETHER ALLYL FORMATE ALLYL GLYCIDYL ETHER ALLYL IODIDE ALLYL ISOTHIOCYANATE, STABILIZED
6060 3181 3181 3305-1 3182 6060
1722 2335 2336 2219 1723 1545
6.1 3.2 3.2 3.3 3.2 6.1
I II I III II II
6.1-01 3-03 3-03 3-02 3-03 6.1-01
740 330 330 330 345 740
p pp
or

GENERAL INDEX
IMDG CODE PAGE see 6060 8107
UN No. 1545 1724
CLASS
Packaging Group II II
Subsidiary Risk Label (s) Flammable liquid Flammable liquid
EmS No.
MFAG Table No. 740 700
ALLYL MUSTARD OIL, STABILIZED ALLYLTRICHLOROSILANE, STABILIZED alpha (or -) ALUMINIUM, powder ALUMINIUM ALKYL BROMIDES ALUMINIUM ALKYL CHLORIDES ALUMINIUM ALKYL HALIDES ALUMINIUM ALKYL HYDRIDES ALUMINIUM ALKYLS ALUMINIUM BOROHYDRIDE ALUMINIUM BOROHYDRIDE IN DEVICES ALUMINIUM BROMIDE ANHYDROUS ALUMINIUM BROMIDE, SOLUTION ALUMINIUM CARBIDE ALUMINIUM CHLORIDE, ANHYDROUS ALUMINIUM CHLORIDE, SOLUTION Aluminium dross ALUMINIUM FERROSILICON, POWDER ALUMINIUM HYDRIDE ALUMINIUM NITRATE ALUMINIUM PHOSPHIDE
6.1 8
6.1-01 8-01
This prefix is not taken into account in determining the alphabetical order of entries see under the next part of the name shown in capital letters see ALUMINIUM, POWDER see 4221 see 4221 4221 4222 4221 4222 4222 8108 8108 4327 8109 8109 3052 3052 3052 3076 3051 2870 2870 1725 2580 1394 1726 2581 4.2 4.2 4.2 4.2 4.2 4.2 4.2 8 8 4.3 8 8 I I I I I I I II III II II III Dangerous when wet Dangerous when wet Dangerous when wet Dangerous when wet Dangerous when wet Dangerous when wet Dangerous when wet 4.2-01 4.2-01 4.2-01 4.2-01 4.2-01 4.2-01 4.2-01 8-06 8-06 4.3-03 8-06 8-06 170 170 170 170 170 245 245 700 700 none 700 700
see ALUMINIUM PROCESSING BYPRODUCTS 4327 4328 5121 4329 1395 2463 1438 1397 4.3 4.3 5.1 4.3 II I III I Toxic 4.3-03 4.3-04 5.1-06 4.3-02 601, 605 none 235 205
GENERAL INDEX
IMDG CODE PAGE 6061 4121 see 4255 4330 4330-1 4330-1
UN No. 3048 1309 1383 1396 3170 3170
CLASS
Packaging Group I II/III I II/III II/III II/III
EmS No.
MFAG Table No. 205 none none none 725 725
ALUMINIUM PHOSPHIDE PESTICIDE ALUMINIUM POWDER, COATED ALUMINIUM POWDER, PYROPHORIC ALUMINIUM POWDER, UNCOATED, nonpyrophoric ALUMINIUM REMELTING BY-PRODUCTS ALUMINIUM SMELTING BY-PRODUCTS Aluminium residues ALUMINIUM RESINATE ALUMINIUM SILICON POWDER, UNCOATED Aluminium skimmings Amatols AMINES FLAMMABLE, CORROSIVE, N.O.S. - ditto - - ditto - AMINES LIQUID CORROSIVE, N.O.S. AMINES LIQUID CORROSIVE FLAMMABLE N.O.S. AMINES, SOLID, CORROSIVE, N.O.S. 1-AMINO-3-AMINOMETHYL-3, 5, 5TRIMETHYLCYCLOHEXANE ortho-AMINOANISOLE AMINOBENZENE 2-AMINOBENZOTRIFLUORlDE 3-AMINOBENZOTRIFLUORIDE 1-AMINOBUTANE
6.1 4.1 4.2 4.3 4.3 4.3
6.1-04 4.1-02 4.2 02 4.3-06 4.3-04 4.3-04
see ALUMINIUM PROCESSING BY-PRODUCTS 4121 4331 2715 1398 4.1 4.3 III III 4.1-06 4.3-03 none none
see ALUMINIUM PROCESSING BY-PRODUCTS see EXPLOSIVE BLASTING TYPE B 3106 3182-1 3306 8109-2 8109-1 8109 2 see 8188 see 6069 see 6068 see 6275 see 6275 see 3192 2733 2733 2733 2735 2734 3259 2289 2431 1547 2942 2948 1125 3.1 3.2 3.3 8 8 8 8 6.1 6.1 6.1 6.1 3.2 I/II I/II III I/II/III I/II I/II/III III III II III II II Corrosive Corrosive Corrosive Flammable liquid Corrosive 3-02 3-02 3-02 8-05 8-04 8-15 8-05 6.1-02 6.1-02 6.1-02 6.1 02 3-02 320 320 320 320 320 760 320 335 335 335 335 320
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE Aminocarb p 2-AMINO-4-CHLOROPHENOL AMINOCYCLOHEXANE 2-AMINO-5-DIETHYLAMINO-PENTANE AMINODIMETHYLBENZENES, SOLID or LIQUID 2-AMINO-4, 6-DINITROPHENOL, WETTED, with not less than 20% water , by mass AMINOETHANE AMINOETHANE, AQUEOUS SOLUTION - ditto 1-AMINOETHANOL 2-AMINOETHANOL 2-(2-AMINOETHOXY) ETHANOL N-AMINOETHYLPIPERAZINE AMINOMETHANE, ANHYDROUS AMINOMETHANE, AQUEOUS SOLUTION 1-AMINO-2-METHYLPROPANE 3-AMINOMETHYL-3, 5, 5TRIMETHYLCYCLOHEXYLAMINE 1-AMINO-2-NITROBENZENE 1-AMINO-3-NITROBENZENE 1-AMINO-4-NITROBENZENE AMINOPHENETOLES AMINOPHENOLS (ortho-, meta-, para-)
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see CARBAMATE PESTICIDE 6062 see 8156 6062 see 6280 4121 1 see 2136 see 3121 see 3221 see 9021 see 8169 8110 8110 see 2157 see 3253 see 3239 see 8188 see 6207 see 6207 see 6207 see 6223 6063 2673 2357 2946 1711 3317 1036 2270 2270 1841 2491 3055 2815 1061 1235 1214 2289 1661 1661 1661 2311 2512 6.1 8 6.1 6.1 4.1 2 (21) 3.1 3.2 9 8 8 8 2 (2.1) 3.2 3.2 8 6.1 6.1 6.1 6.1 6.1 II II III II I II II III III III III II II III II II II III III Flammable liquid Corrosive Corrosive Corrosive Corrosive 6.1-04 8-04 6.1-02 6.1-02 4.1-01 2-07 3-02 3-02 8-07 8-05 8-07 8-05 2-06 3-02 3-02 8-05 6.1-03 6.1-03 6.1-03 6.1-02 6.1-04 710 320 320 335 335 320 320 320 320 320 320 325 320 320 320 320 335 335 335 335 335
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group I II/III II III II II
Subsidiary Risk Label (s) Toxic Toxic, Flammable liquid*
EmS No.
MFAG Table No. 710 225 135 750 225 135
AMMONIUM PICRATE WETTED, with not less than 10% water by mass AMMONIUM POLYSULPHIDE, SOLUTION AMMONIUM POLYVANADATE AMMONIUM SILICOFLUORIDE AMMONIUM SULPHIDE, SOLUTION AMMONIUM VANADATE Ammunition blank Ammunition fixed, semi-fixed or separateloading AMMUNITION, ILLUMINATING with or without burster, expelling charge or propelling charge AMMUNITION, INCENDIARY, liquid or gel, with burster, expelling charge or propelling charge Ammunition incendiary (water-activated contrivances) AMMUNITION, INCENDIARY, with or without burster, expelling charge or propelling charge AMMUNITION INCENDIARY, WHITE PHOSPHORUS, with burster, expelling charge or propelling charge Ammunition, industrial Ammunition lachrymatory
4122 8113 6066 see 6250 8114 see 6066
1310 2818 2861 2854 2683 2859
4.1 8 6.1 6.1 8 6.1
4.1-01 8-05 6.1-04 6.1-04 8-04 6.1-04
see CARTRIDGES FOR WEAPONS, BLANK see CARTRIDGES FOR WEAPONS, with bursting charge and CARTRIDGES FOR WEAPONS, INERT PROJECTILE 1202 0171 0254 0297 1204 0247 1.2 G 1.3 G 1.4 G 1.3 J
1-02 1-03 1-04 1-03
see CONTRIVANCES WATER-ACTIVATED 1203 0009 0010 0300 1205 0243 0244 1.2 G 1.3 G 1.4 G 1.2 H 1.3 H 1-02 1-03 1-04 1-02 1-03

see CARTRIDGES, OIL WELL and CARTRIDGES, POWER DEVICE see AMMUNITION, TEAR-PRODUCING
Explosive substance or article, refer to subsection 7.3 of the MFAG.
GENERAL INDEX
IMDG CODE PAGE 1206
UN No. 0362 0488
CLASS 1.4 G 1.3 G 1.4 G
Packaging Group
EmS No. 1.04 1.03 1.04
MFAG Table No. * * *
AMMUNITION, PRACTICE AMMUNITION, PROOF Ammunition smoke (water activated contrivances) AMMUNITION, SMOKE with or without burster expelling charge or propelling charge AMMUNITION, SMOKE WHITE PHOSPHORUS with burster expelling charge or propelling charge Ammunition sporting 1207 1206 0363
see CONTRIVANCES WATER activated 0015 0016 0303 1208 0245 0246 1.2 G 1.3 G 1.4 G 1.2 H 1.3 H Corrosive Corrosive Corrosive 1.02 1.03 1.04 1.02 1.03 * * * * *
see CARTRIDGES FOR WEAPONS INERT PROJECTILES 1209 0018 0019 0301 1.2 G 1.3 G 1.4 G Toxic Corrosive Toxic Corrosive Toxic Corrosive Corrosive 1.02 1.03 1.04 740* 740* 740*
AMMUNITION, TEAR PRODUCING with burster expelling charge or propelling charge
AMMUNITION, TEAR PRODUCING NONEXPLOSIVE with neithei burster nor expelling charge non-fuzed
6067
2017
6.1
II
6.1-02
740
1210 AMMUNITION, TOXIC, with burster expelling charge or propelling charge
0020 0021
1.2 K 1.3 K
Toxic Toxic
* *
AMMUNITION, TOXIC, NON-EXPLOSIVE with neither burster nor expelling charge non-fuzed Amorces normal-AMYL ACETATE secondary- AMYL ACETATE AMYL ACETATES
6067
2016
6.1
II
6.1-02
740
see FIREWORKS see 3307 see 3307 3307 1104 1104 1104 3.3 3.3 3.3 III III III 3.07 3.07 3.07 330 330 330
* Explosive substance or article, refer to subsection 7.3 of the MFAG. Except for articles containing hexachloroethane or red phosphorus. To be declared by the shipper after assignment by the competent authority who should allocate a schedule or develop a new schedule in a similar format to the existing schedules.
GENERAL INDEX
SUBSTANCE or ARTICLE AMYL ACID PHOSPHATE AMYL ALCOHOLS - ditto AMYL ALDEHYDES 2-AMYLAMINE normal-AMYLAMINE tertiary -AMYLAMINE AMYLAMINES - ditto n-AMYLBENZENE p secondary -AMYL BROMIDE AMYL BUTYRATES AMYL CARBINOL normal-AMYL CHLORIDE AMYL CHLORIDES normal-AMYLENE normal-AMYL FORMATE AMYL FORMATES tert-AMYL HYDROPEROXIDE (concentration - 88%, with diluent type A and water) normal-AMYL MERCAPTAN p tertiary -AMYL MERCAPTAN p AMYL MERCAPTANS p normal-AMYL METHYL KETONE normal-AMYL NITRATE AMYL NITRATES AMYL NITRITE - ditto -
IMDG CODE PAGE 8114 see 3269-1 see 3373-1 see 3288 see 3308 see 3183 see 3183 3183 3308
UN No. 2819 1105 1105 2058 1106 1106 1106 1106 1106
CLASS 8 3.2 3.3 3.2 3.3 3.2 3.2 3.2 3.3
Packaging Group III II III II III II II II III
Subsidiary Risk Label (s) Corrosive Corrosive Corrosive Corrosive Corrosive
EmS No. 8-05 3-06 3-06 3-06 3-02 3-02 3-02 3-02 3-02
MFAG Table No. 700 305 305 300 320 320 320 320 320
see Section 23.1.5 of the General Introduction see 3189 3309 see 3351 see 3183 3183 3140 see 3309 3309 2343 2620 2282 1107 1107 1108 1109 1109 3.2 3.3 3.3 3.2 3.2 3.1 3.3 3.3 II III III II II I III III 3-07 3-06 3-06 3-07 3-07 3-07 3-07 3-07 345 330 305 340 340 310 330 330
see ORGANIC PEROXIDE TYPE E, LIQUID see 3184 see 3184 3184 3310 see 3310 3310 3107 3184 1111 1111 1111 1110 1112 1112 1113 1113 3.2 3.2 3.2 3.3 3.3 3.3 3.1 3.2 II II II III III III || II 3-07 3-07 3-07 3-07 3-07 3-07 3-07 3-07 375 375 375 300 235 235 235 235
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE normal-AMYL NITRITE tert-AMYL PEROXYACETATE (concentration - 62%, with diluent type A) tert-AMYL PEROXYBENZOATE, (concentration - 96%, with diluent type A) tert-AMYL PEROXY-2-ETHYLHEXANOATE (concentration - 100%) tert-AMYL PEROXY-2-ETHYLHEXYL CARBONATE (concentration - 100%) tert-AMYL PEROXYNEODECAN-OATE (concentration - 77% with diluent type B) tert-AMYL PEROXYPIVALATE, (concentration - 77%, with diluent type B) tert-AMYL PEROXY-3, 5, 5-TRIMETHYLHEXANOATE (concentration 100%) AMYLTRICHLOROSILANE ANILINE ANILINE CHLORIDE ANILINE HYDROCHLORIDE ANILINE OIL ANILINE SALT ANIMAL FABRICS, oily ANIMAL FIBRES, burnt, wet or damp ANIMAL FIBRES, oily ortho-ANISIDINE
IMDG CODE PAGE see 3184
UN No. 1113
CLASS 3.2
Packaging Group II
EmS No. 3-07
MFAG Table No. 235
see ORGANIC PEROXIDE TYPE E, LIQUID see ORGANIC PEROXIDE TYPE D, LIQUID see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE D, LIQUID see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE B, LIQUID 8115 6068 see 6068 6068 see 6068 see 6068 see 4233 see 4233 see 4233 6069 1728 1547 1548 1548 1547 1548 1373 1373 2431 8 6.1 6.1 6.1 6.1 6.1 4.2 4.2 4.2 6.1 II II III III II III III III III III 8-01 6.1-02 6.1-04 6.1-04 6.1-02 6.1-04 4.2-05 4.2-05 4.2-05 6.1-02 700 335 335 335 335 335 none none none 335
p pp
or
GENERAL INDEX
BENZENE PHOSPHORUS, DICHLORIDE
IMDG CODE PAGE

see 8202
UN No.
2798
CLASS
8
Packaging Group
II

-
EmS No.
8-05
MFAG Table No.

700
BENZENE PHOSPHORUS, THIOCHLORIDE
see 8202
2799
II
8-05
700
BENZENESULPHONYL CHLORIDE BENZENE SULPHONYLHYDR-AZIDE (concentration 100%) BENZENETHIOL
8122
2225
III
8-05
700
see SELF-REACTIVE, SOLID, TYPE D
see 6228
2337
6.1
Flammable liquid -
6.1-01
375
BENZHYDRYL BROMIDE BENZIDINE
see 8166 6081
1770 1885
8 6.1
II II
8-02 6.1-04
345 335
BENZOL
see 3185
1114
3.2
II
3-03
312
BENZOLENE
see PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S.
BENZONITRILE BENZOQUINONE BENZOSULPHOCHLORIDE BENZOTRICHLORIDE BENZOTRIFLUORIDE BENZOYL CHLORIDE BENZYL BROMIDE
6082 6082 see 8122 8122 3185 8123 6083
2224 2587 2225 2226 2338 1736 1737
6.1 6.1 8 8 3.2 8 6.1
II II III II II II II
Corrosive
6.1-02 6.1-04 8-05 8-05 3-07 8-02 6.1-02
215 300 700 340 345 700 740
GENERAL INDEX
SUBSTANCE or ARTICLE BENZYL CHLORIDE BENZYL CHLOROCARBONATE BENZYL CHLOROFORMATE p BENZYL CYANIDE BENZYL DICHLORIDE BENZYLDIMETHYLAMINE 4-[BENZYL (ETHYL) AMINO]-3ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE (concentration 100%) BENZYLIDENE CHLORIDE BENZYL IODIDE 4-[BENZYL (METHYL) AMINO]-3ETHOXYBENZENEDIAZONIUM ZINC CHLORIDE (concentration 100%) BERYLLIUM COMPOUND, N.O.S. BERYLLIUM NITRATE BERYLLIUM POWDER beta (or ) -BHC pp BHUSA BICHLOROACETIC ACID BICYCLO [2-2-1] HEPTA-2,5-DIENE, INHIBITED - ditto p
IMDG CODE PAGE 6083 see 8124 8124 see 6226 see 6084 8124
UN No. 1738 1739 1739 2470 1886 2619
CLASS 6.1 8 8 61 6.1 8
Packaging Group II I I III II II
Subsidiary Risk Label (s) Corrosive Flammable liquid
EmS No. 6.1-02 8-03 8-03 6.1-02 6.1-02 8-04
MFAG Table No. 740 740 740 215 340 320
see SELF-REACTIVE SOLID TYPE D 6084 6084 1886 2653 6.1 6.1 II II 6.1-02 6.1-02 340 345
see SELF-REACTIVE SOLID TYPE D TEMPERATURE CONTROLLED 6085 5130 6085 1566 2464 1567 6.1 5.1 6.1 II/III II II Toxic Flammable solid 6.1-04 5.1-05 6.1-03 125 125 125
This prefix is not taken into account in determining the alphabetical order of entries, see under the next part of the name shown in capital letters see ORGANOCHLORINE PESTICIDE 4149 see 8158 3108 3186 1327 1764 2251 2251 4.1* 8 3.1 3.2 II II II 4.1-06 8-05 3-07 3-07 none 700 310 310
* No label required
p pp
or

Amdt. 29-98
GENERAL INDEX
IMDG CODE PAGE 2107 2107 8128 8128 8128 8129 4333
UN No. 1741 1008 1742 1742 2604 2851 2965
CLASS
Pack aging Group II II II I
Subsidiary Risk Label (s) Corrosive Corrosive Flammable liquid Corrosive, Flammable liquid
EmS No.
MFAG Table No. 700 750 750 750 750 750 750
BORON TRICHLORIDE BORON TRIFLUORIDE, COMPRESSED BORON TRIFLUORIDE ACETIC ACID COMPLEX, LIQUID BORON TRIFLUORIDE ACETIC ACID COMPLEX SOLID BORON TRIFLUORIDE DIETHYL ETHE RATE BORON TRIFLUORIDE DIHYDRATE BORON TRIFLUORIDE DIMETHYL ETHERATE BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, LIQUID BORON TRIFLUORIDE PROPIONIC ACID COMPLEX, SOLID Brodifacoum p p BROMATES, INORGANIC, N.O.S. BROMATES, INORGANIC, AQUEOUS, SOLUTION, N.O.S. BROMINE BROMINE CHLORIDE BROMINE CYANIDE p BROMINE PENTAFLUORIDE BROMINE SOLUTION BROMINE TRIFLUORIDE BROMOACETIC ACID, SOLID
2 (2.3) 2 (2.3) 8 8 8 8 4.3
2-08 2-03 8-05 8-05 8-01 8-06 4.3-05
8129 8129
1743 1743
8 8
II II
8-05 8-05
750 750
see COUMARIN DERIVATIVE PESTICIDE 5131 5131 8130 2108 see 6117 5132 8130 5133 8131 1450 3213 1744 2901 1889 1745 1744 1746 1938 5.1 5.1 8 2 (2.3) 6.1 5.1 8 5.1 8 II II/III I I I I I II Toxic Oxidizing agent Corrosive Corrosive Toxic Corrosive Toxic Toxic, Corrosive 5.1-05 5.1-02 8-03 2.08 6.1-04 5.1-01 8-03 5.1-01 8-05 745 745 740 740 645 750 740 750 700
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE BROMOACETIC ACID, SOLUTION BROMOACETONE

p
IMDG CODE PAGE 8131 6086 see 6223 8132 see 3180 3312 6087 3187 3187 see 6191 see 2117 6088 see 6117 see 8166 see 6143 see 6146 3188 6088 see 2158 3313 see 6191 3188 see 6209
UN No. 2645 1569 2645 2513 1099 2514 1694 1126 2339
CLASS 8 6.1 6.1 8 3.2 3.3 6.1 3.2 3.2 6.1
Packaging Group II II II II I III II II II Ill I II I II II III Ill II II III
Subsidiary Risk Label(s) Flammable liquid Toxic
EmS No. 8-06 6.1-01 6.1-04 8-03 3-03 3-07 6.1-02 3-07 3-07 6.1-02
MFAG Table No. 700 740 740 700 345 345 215 345 345 740 350 345 645 345 740 345 345 345 345 345 740 345 335
omega-BROMOACETOPHENONE BROMOACETYL BROMIDE BROMOALLYLENE BROMOBENZENE p BROMOBENZYL CYANIDES, LIQUID or SOLID* 1-BROMOBUTANE 2-BROMOBUTANE 1-BROMO-2-BUTANONE BROMOCHLORODIFLUORO-METHANE BROMOCHLOROMETHANE BROMOCYANE
p p
2340 1887 1889 1770 2558 1891 2340 2515 1062 2341 2342 2732
2(2.2) 6.1 6.1 8 6.1 6.1 3.2 6.1 2(2.3) 3.3 6.1 3.2 6.1
Corrosive Flammable liquid Flammable gas
2-09 6.1-02 6.1-04 8-02 6.1-01 6.1-01 3-06 6.1-02 2-06 3-06 6.1-02
BROMODIPHENYLMETHANE 1-BROMO-2,3-EPOXYPROPANEP BROMOETHANE 2-BROMOETHYL ETHYL ETHER BROMOFORM p BROMOMETHANE 1-BROMO-3-METHYLBUTANE BROMOMETHYL ETHYL KETONE BROMOMETHYLPROPANES BROMONITROBENZENES, LIQUID
3-07 6.1-02
* only ortho-BROMOBENZYL CYANIDE is a MARINE POLLUTANT

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE BROMONITROBENZENES, SOLID 2-BROMO-2-NITROPROPANE-1,3-DIOL 2-BROMOPENTANE Bromophos-ethyl pp BROMOPROPANES - ditto 3-BROMOPROPENE 3-BROMOPROPYNE 3-BROMO-1-PROPYNE alpha-BROMOTOLUENE BROMOTRIFLUOROETHYLENE BROMOTRIFLUOROMETHANE Bromoxynil
p p
IMDG CODE PAGE see 6209 4131 3189
UN No. 2343 3241 2343
CLASS 6.1 4.1 3.2
Packaging Group III III II
Subsidiary Risk Label(s)
EmS No. 6.1-04 4.1-05 3-07
see ORGANOPHOSPHORUS PESTICIDE 3189 3313 see 3180 3190 see 3190 see 6083 2109 2109 2344 2344 1099 2345 2345 1737 2419 1009 3.2 3.3 3.2 3,2 3.2 6.1 2(2.1) 2(2.2) II III I II II II Toxic Corrosive 3-07 3-07 3-03 3-07 3-07 6.1-02 2-07 2-09 345 345 345 345 345 740 350 350
see PESTICIDE, N.O.S. see 4131 6089 1229 2110 see 3196 see 3317 2147
p
BRONOPOL BRUCINE BURSTERS, explosive BUTADIENES, INHIBITED normal-BUTANAL p BUTANAL OXIME BUTANE BUTANEDIONE
1570 1570 0043 1010 1129 2840 1011 2346 2347 2347 2347 2820 2739
4.1 6.1 1.1 D 2(2.1) 3.2 3.3 2(2.1) 3.2 3.2 3.1 3.2 8 8
Ill I II III II II || II III III
4.1-05 6.1-04 1-01 2-07 3-07 3-07 2-07 3-06 3-07 3-07 3-07 8-05 8-05
335 805 * 310 300 300 310 300 375 375 375 700 700
3190 see 3194 see 3108 see 3194 see 8133 see 8134
1-BUTANETHIOL p BUTANETHIOLS p - ditto p
BUTANOIC ACID BUTANOIC ANHYDRIDE
* Explosive substance or article, refer to subsection 7.3 of the MFAG

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 1-BUTANOL BUTAN-2-OL normal-BUTANOL secondary -BUTANOL tertiary -BUTANOL 3-BUTANOLAL BUTANOLS - ditto 2-BUTANONE BUTANOYL CHLORIDE 2-BUTENAL, STABILIZED p BUTENE 3-BUTENE-2-ONE, STABILIZED 1,2-BUTENE OXIDE, STABILIZED 2-BUTENOIC ACID 2-BUTEN-1-OL Butocarboxim BUTYL ACETATES - ditto BUTYL ACID PHOSPHATE BUTYL ACRYLATES, INHIBITED normal-BUTYL ALCOHOL secondary -BUTYL ALCOHOL tertiary -BUTYL ALCOHOL normal-BUTYL ALDEHYDE p
IMDG CODE PAGE see 3314 see 3191 see 3314 see 3191 see 3191 see 6055 3191 3314 see 3226 see 3197 see 6114-1 see 2147 see 6198-2 see 3192 see 8154 see 3362
UN No. 1120 1120 1120 1120 1120 2839 1120 1120 1193 2353 1143 1012 1251 3022 2823 2614
CLASS 3.3 3.2 3.3 3.2 3.2 6.1 3.2 3.3 3.2 3.2 6.1 2(2.1) 6.1 3.2 8 3.3
Packaging Group III II III II II II II III II II I I II III III
Subsidiary Risk Label(s) Corrosive Flammable liquid Flammable liquid Corrosive
EmS No. 3-06 3-06 3-06 3-06 3-06 6.1-02 3-06 3-06 3-06 3-04 6.1-01 2-07 6.1-01 3-06 8-05 3-06
MFAG Table No. 305 305 305 305 305 300 305 305 300 700 300 310 300 365 700 305
see CARBAMATE PESTICIDE 3191 3314 8132 3315 see 3314 see 3191 see 3191 see 3196 1123 1123 1718 2348 1120 1120 1120 1129 3.2 3.3 8 3.3 3.3 3.2 3.2 3.2 || III III III III II II II 3-07 3-07 8-05 3-03 3-06 3-06 3-06 3-07 330 330 700 330 305 305 305 300
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
Charcoal CHARCOAL, ACTIVATED CHARCOAL, non-activated see 4224 see 4224 1240 CHARGES. BURSTING, PLASTICSBONDED
MATERIAL HAZARDOUS ONLY IN BULK* 1362 1361 0457 0458 0459 0460 4.2 4.2 1.1 D 1.2 D 1.4 D 1.4 S 1.1 D 1. 1 D 1.1 D 1.2 D 1.4 D 1.4 S 1.1 C 1.2 C 1.3 C 1.4 C 1.1 C 1.2 C 1.3 C 1.1 D 1.2 D 1.4 D 1.4 S 1.1 D 1.4 D 1.1 D 9 6.1 6.1 II/III I I III II/III 4.2-05 4.2 05 1-01 1-02 1-04 1-04 1-01 1-01 1-01 1 02 1-04 1-04 1-01 1 02 1-03 1-04 1-01 1-02 1-03 1-01 1-02 1-04 1-04 1-01 1-04 1-01
none none

CHARGES, DEMOLITION CHARGES, DEPTH
1241 1242 1243
0048 0056 0442 0443 0444 0445
CHARGES, EXPLOSIVE, COMMERCIAL, without detonator
1245 CHARGES, PROPELLING
0271 0415 0272 0491
1244 CHARGES, PROPELLING, FOR CANNON
0279 0414 0242
1246 CHARGES, SHAPED, without detonator
0059 0439 0440 0441
1247 CHARGES, SHAPED, FLEXIBLE, LINEAR CHARGES, SUPPLEMENTARY, EXPLOSIVE CHEMICAL KIT CHEMICAL SAMPLE, TOXIC, liquid CHEMICAL SAMPLE, TOXIC, solid 1248 9026-1 6096-1 6096-1
0288 0237 0060 3316 3315 3315
6.1-02 6.1-04
* See section 24 of the General Introduction. Explosive substance or article, refer to subsection 7.3 of the MFAG. To be declared by the shipper. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
GENERAL INDEX
SUBSTANCE or ARTICLE CHILE SALTPETRE Chinomethionat CHLORAL, ANHYDROUS, INHIBITED CHLORATE AND BORATE MIXTURE CHLORATE AND MAGNESIUM CHLORIDE MIXTURE CHLORATES, INORGANIC, N.O.S. CHLORATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. Chlordane
pp
UN No. 1498
CLASS 5.1
Packaging Group III
EmS No. 5.1-06
MFAG Table No. 235
see PESTICIDE, N.O.S. 6097 5141 5141 5142 5142 2075 1458 1459 1461 3210 6.1 5.1 5.1 5.1 5.1 II II/III II/III II II/III 6.1-02 5.1 06 5.1-06 5.1-05 5.1-02 300 745 745 745 745
see ORGANOCHLORINE PESTICIDE see ORGANOCHLORINE PESTICIDE see ORGANOCHLORINE PESTICIDE see ORGANOPHOSPHORUS PESTICIDE 5143 2626 5.1 II
Chlordimeform Chlordimeform hydrochloride Chlorfenvinphos

p
CHLORIC ACID, AQUEOUS SOLUTION with not more than 10% chloric acid CHLORINATED PARAFFINS (C 10 C 17) pp CHLORINE p CHLORINE BROMIDE CHLORINE CYANIDE, INHIBITED p CHLORINE PENTAFLUORIDE
5.1-02
700
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID or SOLID N.O.S. 2116 see 2108 see 2126 2116 1017 2901 1589 2548 2(2.3) 2(2.3) 2(2.3) 2(2.3) Corrosive Oxidizing agent, Corrosive Corrosive Oxidizing agent, Corrosive 2-08 2-08 2-08 2-08 740 740 645 750
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
Copper (II) chlorate COPPER CHLORIDE

p
see COPPER CHLORATE 8147

pp
2802 2802
8 8
III III
8-08 8-08
740 740
COPPER CHLORIDE (solution) Copper compounds COPPER CYANIDE p p COPPER METAL POWDER
pp
see 8147
see COPPER BASED PESTICIDE 6113 1587 6.1 II 6.1-04 215
see Section 23.1.5 of the General Introduction see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O. S 4227 1251 1363 0065 0289 1252 0290 0102 1253 1254 0104 0066 4.2* 1.1 D 1.4 D 1.1 D 1.2 D 1.4 D 1.4 G 4.2-05 1-01 1-04 1-01 1-02 1-04 1-04 none

COPPER SULPHATE ANHYDROUS/HYDRATES pp COPRA CORD DETONATING, flexible
CORD, DETONATING, metal-clad CORD, DETONATING, MILD EFFECT, metal clad CORD, IGNITER Cordite CORROSIVE LIQUID, N.O.S. CORROSIVE LIQUID, ACIDIC, INO RGANIC, N.O.S. CORROSIVE LIQUID ACIDIC ORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. CORROSIVE LIQUID, BASIC, ORGANIC, N.O.S. CORROSIVE LIQUID, FLAMMABLE, N.O.S. 8147 8147-1 8147-1 8147-1 8147-1 8148
see POWDER, SMOKELESS 1760 3264 3265 3266 3267 2920 8 8 8 8 8 8 I/II/III I/II/III I/II/III I/II/III I/II/III I/II Flammable liquid 8-15 8-15 8-15 8-15 8-15 8-15 760, 760 760 760 760 760,
No label required. Explosive substance or article, refer to subsection 7.3 of the MFAG. In addition refer to subsection 4.3 of the MFAG.
p pp
or
GENERAL INDEX
IMDG CODE PAGE 8153 8147-2 8149 8150 8151 8150-1 8150-1 8150-1 8150 1 8151 8153 8150 8152
UN No. 3093 3301 2922 3094 1759 3260 3261 3262 3263 2921 3084 3095 2923
CLASS
Packaging Group I/II I/II I/II/III I/II I/II/III I/II/III I/II/III I/II/III I/II/III I/II I/II I/II I/II/III
Subsidiary Risk Label(s) Oxidizing agent Spontaneously combustible Toxic Dangerous when wet Flammable solid Oxidizing agent Spontaneously combustible Toxic Dangerous when wet
EmS No. 8-03 8-02 8-15 8-15 8-15 8-15 8-15 8-15 8-15 8-15 8-15 8-15 8-15
MFAG Table No. 760,* 760, * 760, * 760, * 760, * 760 760 760 760 760,* 760 * 760,* 760, *
CORROSIVE LIQUID, OXIDIZING, N.O.S. CORROSIVE LIQUID, SELF-HEATING, N.O.S. CORROSIVE LIQUID, TOXIC, N.O.S. CORROSIVE LIQUID, WATER REACTIVE, N.O.S. CORROSIVE SOLID, N.O.S. CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S. CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S. CORROSIVE SOLID, BASIC, INORGANIC, N.O.S. CORROSIVE SOLID, BASIC, ORGANIC, N.O.S. CORROSIVE SOLID, FLAMMABLE, N.O.S. CORROSIVE SOLID, OXIDIZING, N.O.S. CORROSIVE SOLID, SELF-HEATING, N.O.S. CORROSIVE SOLID, TOXIC, N.O.S. CORROSIVE SOLID, WATER-REACTIVE, N.O.S. COSMETICS - ditto - COTTON, DRY
8 8 8 8 8 8 8 8 8 8 8 8 8
8150 see 3269 see 3374 see 4144
3096 1266 1266 -
8 3.2 3.3 4.1
I/II II III
8-15 3-05 3-05 4.1-06
760, * 305 305 none
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 1,1-DIETHOXYETHANE p - ditto - p 1,2-DIETHOXYETHANE DIETHOXYMETHANE - ditto 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE (concentration 67-100%) 2,5 DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM ZINC CHLORIDE (concentration 66%) 2,5-DIETHOXY-4-MORPHOLINOBENZENEDIAZONIUM TETRA FLUOROBORATE (concentration 100%) 2,5-DIETHOXY-4-(PHENYLSULPHONYL)BENZENEDIAZONIUM ZINC CHLORIDE (concentration 67%) 3,3-DIETHOXYPROPENE DIETHYLACETALDEHYDE
p
IMDG CODE PAGE see 3101 see 3171 see 3340 3116 3207
UN No. 1088 1088 1153 2373 2373
CLASS
Packaging Group II II III II II
EmS No.
MFAG Table No. 330 330 330 330 330
3.1 3.2 3.3 3.1 3.2
3-06 3-06 3-07 3-06 3-06
see SELF-REACTIVE, SOLID, TYPE D, TEMPERATURE CONTROLLED
see SELF-REACTIVE, SOLID, TYPE D, TEMPERATURE CONTROLLED 3208 see 3223 see 4221 3116 see 6062 see 8160 8160 3331 6130 3331-1 2374 1178 3052 1154 2946 2686 2686 2684 2432 2049 3.2 3.2 4.2 3.1 6.1 8 8 3.3 6.1 3.3 II II I II III II II III III III Dangerous when wet Corrosive Flammable liquid Flammable liquid Corrosive 3-06 3-07 4.2-01 3-02 6.1-02 8-04 8-04 3-02 6.1-02 3-07 330 300 170 320 320 320 320 320 335 310
DIETHYLALUMINIUM CHLORIDE DIETHYLAMINE 1-DIETHYLAMINO-4-AMINOPENTANE DIETHYLAMINOETHANOL 2-DIETHYLAMINOETHANOL 3-(DIETHYLAMINO)-PROPYLAMINE N,N-DIETHYLANILINE DIETHYLBENZENES (ortho-, meta-, para-)p
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE DIETHYL CARBINOL DIETHYL CARBONATE DIETHYLDICHLOROSILANE DIETHYLENEDIAMINE, SOLID or SOLUTION 1,4-DIETHYLENE DIOXIDE DIETHYLENEGLYCOL BIS(ALLYL CARBONATE) +DI-ISOPROPYL PEROXYDICARBONATE (concentration - 88% + -12%) DIETHYLENEGLYCOL DINITRATE DESENSITIZED with not less than 25% nonvolatile water-insoluble phlegmatizer, by mass DIETHYLENE OXIDE DIETHYLENETRIAMINE N,N-DIETHYLETHANOLAMINE DIETHYL ETHER N,N-DIETHYLETHYLENEDIAMINE DIETHYL FORMAL - ditto DI-(2-ETHYLHEXYL) PEROXYDICARBONATE (concentration > 77-100%) DI-(2-ETHYLHEXYL) PEROXYDICARBONATE (concentration -77%) DI-(2-ETHYLHEXYL) PEROXYDICARBONATE (concentration -52%, as a stable dispersion in water)
IMDG CODE PAGE see 3373-1 3332 8161 see 8211 see 3217
UN No. 1105 2366 1767 2579 1165
CLASS 3.3 3.3 8 8 3.2
Packaging Group III III II III II
Subsidiary Risk Label(s) Flammable liquid
EmS No. 3-06 3-07 8-01 8-05 3-06
MFAG Table No. 305 330 700 320 330
see SELF-REACTIVE LIQUID TYPE E, TEMPERATURE CONTROLLED
1108
0075
1.1 D
1-01
see 3217 8161 see 8160 3117 8162 see 3116 see 3207
1165 2079 2686 1155 2685 2373 2373
3.2 8 8 3.1 8 3.1 3.2
II II II I II II II
Flammable liquid Flammable liquid
3-06 8-05 8-04 3-07 8-04 3-06 3-06
330 320 320 330 320 330 330
see ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED
* Explosive substance or article, refer to subsection 7.3 of the MFAG.
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
Subsidiary EmS No. Risk Label(s)
MFAG Table No.
DI-(2-ETHYLHEXYL) PEROXYDICARBONATE (concentration 42%, as a stable dispersion in water (frozen)) DI-(2-ETHYLHEXYL)PHOSPHORIC ACID DIETHYL KETONE DIETHYLMAGNESIUM para-DIETHYLNITROSOANILINE DIETHYL OXALATE DIETHYL PEROXYDICARBONATE (concentration 27%, with diluent type B) N,N-DIETHYL-1,3-PROPANE-DIAMINE DIETHYL SULPHATE DIETHYL SULPHIDE DIETHYLTHIOPHOSPHORYL CHLORIDE DIETHYLZINC Difenacoum Difenzoquat DIFLUOROCHLOROETHANE DIFLUORODIBROMOMETHANE 1,1-DIFLUOROETHANE DIFLUOROETHANE AND DICHLORODIFLUOROMETHANE, AZEOTROPIC MIXTURE, with approximately 74% dichlorodifluoromethane 1,1-DIFLUOROETHYLENE
see ORGANIC PEROXIDE TYPE E, SOLID TEMPERATURE CONTROLLED see 8163 3208 see 4240 4247 see 6152 1902 1156 3053 2525 8 3.2 4.2 4.2 6.1 III II I II III Dangerous when wet 8-05 3-07 4.2-01 4.2-04 6.1-02 700 300 170 335 230
see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED see 3331 6130 3209 8162 4230 2684 1594 2375 2751 1366 3.3 6.1 3.2 8 4.2 III II II II I Corrosive Dangerous when wet 3-02 6.1-02 3-07 8-05 4.2-01 320 315 375 700 170
see COUMARIN DERIVATIVE PESTICIDE see PESTICIDE, N.O.S. see 2118 see 9027 2132 2517 1941 1030 2(2.1) 9 2(2.1) Ill 2-07 6.1-02 2-07 350 350 350
see DICHLORODIFLUOROMETHANE AND DIFLUOROETHANE, AZEOTROPIC MIXTURE
2132
1959
2(2.1)
2-07
350
GENERAL INDEX
IMDG CODE PAGE 2132-1
UN No. 3252
CLASS
Packaging Group
EmS No.
MFAG Table No. 350
DIFLUOROMETHANE DIFLUOROMETHANE, PENTAFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MI XTURE WITH APPROXIMATELY 10% DIFLUOROMETHANE AND 70% PENTAFLUOROETHANE DIFLUOROMETHANE, PENTAFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MI XTURE WITH APPROXIMATELY 20% DIFLUOROMETHANE AND 40% PENTAFLUOROETHANE DIFLUOROMETHANE, PENTAFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MI XTURE WITH APPROXIMATELY 23% DIFLUOROMETHANE AND 25% PENTAFLUOROETHANE DIFLUOROPHOSPHORIC ACID, ANHYDROUS 2,2-DIHYDROPEROXYPROPANE (concentration -27%, with inert solid) 2,3-DIHYDROPYRAN meta-DIHYDROXYBENZENE para-DIHYDROXYBENZENE, LIQUID para-DIHYDROXYBENZENE, SOLID DI-(1-HYDROXYCYCLOHEXYL) PEROXIDE (concentration -100%) DIISOBUTYLAMINE DIISOBUTYLENES, ISOMERIC COMPOUNDS alpha-DIISOBUTYLENE beta-DIISOBUTYLENE DIISOBUTYL KETONE
2(2.1)
2-07
see 2176-2
3339
2(2.2)
2-09
620
see 2176-1
3338
2(2.2)
2-09
620
see 2176-2
3340
2(2.2)
2-09
620
8163
1768
II
8-06
700
see ORGANIC PEROXIDE TYPE B, SOLID 3209 see 6248 see 6164 see 6164 2376 2876 2662 2662 3.2 6.1 6.1 6.1 II III III III 3-06 6.1-04 6.1-02 6.1-04 310 710 710 710
see ORGANIC PEROXIDE TYPE D, SOLID 3332 3210 see 3210 see 3210 3333 2361 2050 2050 2050 1157 3.3 3.2 3.2 3.2 3.3 III II II II III Corrosive 3-03 3-07 3-07 3-07 3-07 320 310 310 310 300
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
DIISOBUTYRYL PEROXIDE (concentration > 32-52%, with diluent type A or B) DIISOBUTYRYL PEROXIDE (concentration 32%, with diluent type B) DIISOOCTYL ACID PHOSPHATE DIISOPROPYL DIISOPROPYLAMINE DIISOPROPYLBENZENE DIHYDROPEROXIDE (concentration 82%, with diluent type A and water) DIISOPROPYLBENZENES p DIISOPROPYL ETHER DIISOPROPYLNAPHTHALENE
p
see ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 8163 see 3119 3210 1902 2457 1158 8 3.1 3.2 III II II Corrosive 8-05 3-07 3-02 700 310 320
see ORGANIC PEROXIDE TYPE D, SOLID see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 3117 1159 3.1 II 3-02 330
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 6130-1 2521 6.1 I Flammable liquid 6.1-01 300
DIISOPROPYL PEROXYDICARBONATE (concentration >52-100%) DIISOPROPYL PEROXYDICARBON ATE (concentration 52%, with diluent type B) DIISOTRIDECYL PEROXYDICARBONATE (concentration 100%) DIKETENE, INHIBITED DILAUROYL PEROXIDE (concentration 100%) DILAUROYL PEROXIDE (concentration 42% as a stable dispersion in water) Dimefox
see ORGANIC PEROXIDE TYPE D, SOLID see ORGANIC PEROXIDE TYPE F, LIQUID see ORGANOPHOSPHORUS PESTICIDE
p pp
or

GENERAL INDEX
SUBSTANCE or ARTICLE Dimetan Dimethoate pp 1,1-DIMETHOXYETHANE - ditto 1,2-DIMETHOXYETHANE DIMETHOXYMETHANE 2,5-DIMETHOXY-4-(4-METHYLPHENYLSULPHONYL)BENZENEDIAZONIUM ZINC CHLORIDE (concentration 79%) DIMETHOXYSTRYCHNINE DIMETHYL ACETAL - ditto 1,1-DIMETHYLACETONE DIMETHYLACETYLENE DIMETHYLAMINE, ANHYDROUS DIMETHYLAMINE, AQUEOUS SOLUTION - ditto 2-DIMETHYLAMINOACETONITRILE 4-DIMETHYLAMINO-6-(2-DIMETHYLAMINOETHOXY'TOLUENE-2-DIAZONIUM ZINC CHLORIDE (concentration 100%) 2-DIMETHYLAMINOETHANOL 2-DIMETHYLAMINOETHYL ACRYLATE 2-DIMETHYLAMINOETHYL METHACRYLATE 3,4-DIMETHYLANILINE N,N-DIMETHYLANILINE
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see CARBAMATE PESTICIDE see ORGANOPHOSPHORUS PESTICIDE 3118 3211 3211 see 3136 2377 2377 2252 1234 3.1 3.2 3.2 3.1 II II II II 3-06 3-06 3-06 3-06 330 330 330 330
see SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED
see 6089 see 3118 see 3211 see 3254 see 3113 2133 3118 3212 3334
1570 2377 2377 2397 1144 1032 1160 1160 2378
6.1 3.1 3.2 3.2 3.1 2(2.1) 3.1 3.2 3.3
I II II II I II II II
Corrosive Corrosive Toxic
6.1-04 3-06 3-06 3-07 3-07 2-07 3-02 3-02 3-02
805 330 330 300 310 320 320 320 215
see SELF-REACTIVE SOLID TYPE D, TEMPERATURE CONTROLLED Flammable liquid
8164 6130-1 6131 see 6280 6131
2051 3302 2522 1711 2253
8 6.1 6.1 6.1 6.1
II II II II II
8-04 6.1-02 6.1-02 6.1-02 6.1-02
320 330 330 335 335
p pp
or
GENERAL INDEX
IMDG CODE PAGE see 6093 see 3292 see 3394
UN No. 1572 1307 1307
CLASS
Packaging Group II II III
Subsidiary EmS No. Risk Label(s) 6.1-04 3-07 3-07
DIMETHYLARSINIC ACID DIMETHYLBENZENES - ditto DI-(2-METHYLBENZOYL) PEROXIDE (concentration 87%, with water) DI-(4-METHYLBENZOYL) PEROXIDE (concentration 52% as a paste with silicon oil) DIMETHYLBENZYLAMINE N,N-DIMETHYLBENZYLAMINE 2,3-DIMETHYLBUTANE 1,3-DIMETHYLBUTYLAMINE N,N-DIMETHYLCARBAMOYL CHLORIDE DIMETHYL CARBINOL DIMETHYL CARBONATE DIMETHYLCYCLOHEXANES N,N-DIMETHYLCYCLOHEXYLAMINE 2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE (concentration > 82100%) 2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE (concentration 82%, with inert solid) 2,5-DIMETHYL-2,5-DI-(BENZOYLPEROXY)HEXANE (concentration 82%, with water) 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXANE (concentration > 52100%)
6.1 3.2 3.3
see ORGANIC PEROXIDE TYPE B, SOLID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE D, SOLID Flammable liquid Flammable liquid Corrosive Flammable liquid
see 8124 see 8124 3119 3212 8164 see 3244 3213 3213 8165
2619 2619 2457 2379 2262 1219 1161 2263 2264
8 8 3.1 3.2 8 3.2 3.2 3.2 8
II II II II II II II
8-04 8-04 3-07 3-03 8-05 3-06 3-07 3-07 8-04
320 320 310 320 700 305 330 310 320
see ORGANIC PEROXIDE TYPE B, SOLID
see ORGANIC PEROXIDE TYPE C, SOLID
GENERAL INDEX
SUBSTANCE or ARTICLE 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXANE (concentration 47% as a paste) 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXANE (concentration 52%, with diluent type A) 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXANE (concentration 52%, with inert solid) 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXYNE-3 (concentration > 5286%, with diluent type A) 2,5-DIMETHYL-2,5-DI-(tert-BUTYLPEROXY)HEXYNE-3 (concentration 52%, with inert solid) DIMETHYLDICHLOROSILANE DIMETHYLDIETHOXYSILANE 2,5-DIMETHYL-2,5-DI-(2-ETHYL HEXANOYLPEROXY)HEXANE (concentration 100%) 2,5-DIMETHYL-2,5DIHYDROPEROXYHEXANE (concentration 82%, with water) 4,4-DIMETHYLDIOXANE-1,3DIMETHYLDIOXANES - ditto DIMETHYL DISULPHIDE p 2,5 DIMETHYL-2,5-DI (3,5,5TRIMETHYLHEXANOYLPEROXY)HEXANE (concentration 77%, with diluent type A) DIMETHYLENEIMINE, INHIBITED
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
see ORGANIC PEROXIDE TYPE E, SOLID
see ORGANIC PEROXIDE TYPE F, LIQUID
see ORGANIC PEROXIDE TYPE C, LIQUID
see ORGANIC PEROXIDE TYPE D, SOLID 3214 3214 1162 2380 3.2 3.2 II II Corrosive 3-04 3-06 700 none
see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE C, SOLID see 3334 3215 3334 3215 2707 2707 2707 2381 3.3 3.2 3.3 3.2 III II III II 3-06 3-06 3-06 3-07 330 330 330 225
see 6151
1185
6.1
Flammable liquid
6.1-01
320
p pp
or

GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group II III II II III I
Subsidiary Risk Label(s) Flammable liquid Toxic Flammable liquid, Corrosive Flammable liquid Flammable liquid Flammable liquid, Corrosive
EmS No.
MFAG Table No. 320 330 321 215 300 300 720
DIMETHYLETHANOLAMINE DIMETHYL ETHER N,N-DIMETHYLFORMAMIDE N,N-DIMETHYLGLYCINONITRILE DIMETHYLGLYOXAL

p
see 8164 2133 3335 see 3334 see 3190 see 3333 see 6132
2051 1033 2265 2378 2346 1157 1163
8 2(2.1) 3.3 3.3 3.2 3.3 6.1
8-04 2-07 3-06 3-02 3-06 3-07 6.1-01
2,6-DIMETHYL-4-HEPTANONE 1,1-DIMETHYLHYDRAZINE
p
1,2-DIMETHYLHYDRAZINE
see 6131-1 6131-1
2382 2382
6.1 6.1
I I
6.1-01 6.1-01
720 720
DIMETHYLHYDRAZINE, SYMMETRICAL p
DIMETHYLHYDRAZINE, UNSYMMETRICAL p 1,1-DIMETHYL-3-HYDROXYBUTYL PEROXYNEOHEPTANOATE (concentration 52%, with diluent type A) DIMETHYL KETONE DIMETHYL KETONE SOLUTIONS DIMETHYLMAGNESIUM N,N-DIMETHYL-4-NITROSO-ANILINE para-DIMETHYLNITROSOANILINE DIMETHYLPHENOLS, SOLID DIMETHYLPHENOLS LIQUID
p
6132
1163
6.1
6.1-01
720
see ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED see 3102 see 3172 see 4240 see 4247 see 4247 see 6280 see 6280 see 6133-1 2147 1090 1090 3053 1369 1369 2261 2261 2267 2044 3.1 3.2 4.2 4.2 4.2 6.1 6.1 6.1 2(2.1) II II I II II II II II Dangerous when wet Corrosive 3-06 3-06 4.2-01 4.2-04 4.2-04 6.1-04 6.1-02 6.1-02 2-07 300 300 170 335 335 710 710 700 310
DIMETHYL PHOSPHOROCHLORIDOTHIONATE 2,2-DIMETHYLPROPANE
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE DIMETHYL-N-PROPYLAMINE N,N-DIMETHYLPROPYLAMINE DIMETHYL-normal-PROPYL CARBINOL DIMETHYL SULPHATE DIMETHYL SULPHIDE
p
IMDG CODE PAGE see 3216 3216 see 3367 6133 3119 6133-1 4231
UN No. 2266 2266 2560 1595 1164 2267 1370
CLASS 3.2 3.2 3.3 6.1 3.1 6.1 4.2
Packaging Group II II III I II II I
Subsidiary Risk Label(s) Corrosive Corrosive Corrosive Corrosive Dangerous when wet
EmS No. 3-02 3-02 3-06 6.1-02 3-07 6.1-02 4.2-01
MFAG Table No. 320 320 305 315 225 700 170
DIMETHYLTHIOPHOSPHORYL CHL ORIDE DIMETHYLZINC Dimetilan Dimexano DIMYRISTYL PEROXYDICARBONATE (concentration -100%) DIMYRISTYL PEROXYDICARBONATE (concentration -42%, as a stable dispersion in water) DI-(2-NEODECANOYLPEROXYISOPROPYL)BENZENE (concentration -52%, with diluent type A) DINGU DINITROANILINES DINITROBENZENES, LIQUID ( ortho-, meta, para-) or (1,2-, 1,3-, 1,4-) DINITROBENZENES, SOLID (ortho-, meta-, para-) or (1,2-, 1,3-, 1 4-) DINITROCHLOROBENZENES, LIQUID or SOLID p DINITRO-ortho-CRESOL DINITROGEN OXIDE
p
see CARBAMATE PESTICIDE see PESTICIDE, N.O.S. see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE F, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 1104 6134 6134 6134 see 6103 6135 see 2166 0489 1596 1597 1597 1577 1598 1070 1.1 D 6.1 6.1 6.1 6.1 6.1 2(2.2) II II II II II Oxidizing agent 1-01 6.1-03 6.1-01 6.1-03 6.1-01 6 1-04 2-08 * 335 335 335 335 710 none

p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
Subsidiary Risk Label(s) Oxidizing agent
EmS No.
MFAG Table No. 620
DINITROGEN OXIDE, REFRIGERATED, LIQUID DINITROGEN TETROXIDE AND NITRIC OXIDE, MIXTURES DINITROGEN TETROXIDE
see 2166
2201
2(2.2)
2-11
see NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURES Oxidizing agent, Corrosive Oxidizing agent, Corrosive
2134
1067
2(2.3)
2-08
610
DINITROGEN TRIOXIDE DINITROGLYCOLURIL Dinitrophenates ( class 1) DINITROPHENATES, WETTED p DINITROPHENOL, dry or wetted with less than 15% water, by mass p DINITROPHENOL WETTED with not less than 15% water, by mass p DINITROPHENOLATES alkali metals, dry or wetted with less than 15% water, by mass p DINITROPHENOLATES, WETTED with not less than 15% water, by mass p DINITROPHENOL SOLUTION
p
see 2164 1104
2421 0489
2(2.3) 1.1 D
2-08 1-01
610 *
see DINITROPHENOLATES ( class 1) see 4139 1109 4140 1321 0076 1320 4.1 1.1 D 4.1 I I Toxic Toxic Toxic 4.1-01 1-01 4.1-01 710 710,* 710
1107
0077
1.3 C
Toxic
1-03
710,*
4139 6136 1109 4141 1115
1321 1599 0078 1322 0406
4.1 6.1 1.1 D 4.1 1.3 C
I II/III I
Toxic
4.1-01 6.1-01 1-01 4.1-01 1-03
710 710 710,* 710 335,*
DINITRORESORCINOL, dry or wetted with less than 15% water, by mass DINITRORESORCINOL, WETTED with not less than 15% water, by mass DINITROSOBENZENE N,N' -DINITROSO-N,N -DIMETHYLTEREPHTHALAMIDE, as a paste (concentration 72%)
see SELF-REACTIVE SOLID TYPE C

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE N,N'-DINITROSOPENTAMETHYLENETETRAMINE (concentration 82%) DINITROTOLUENES, LIQUID DINITROTOLUENES, MOLTEN DINITROTOLUENES, SOLID Dinobuton p DI-n-NONANOYL PEROXIDE (concentration 100%) Dinoseb
p p
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
see SELF-REACTIVE SOLID TYPE C 6137 6137 6137 2038 1600 2038 6.1 6.1 6.1 II II II 6.1-01 6.1-01 6.1-03 335 335 335
see SUBSITUTED NITROPHENOL PESTICIDE see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED see SUBSTITUTED NITROPHENOL PESTICIDE see SUBSTITUTED NITROPHENOL PESTICIDE see SUBSTITUTED NITROPHENOL PESTICIDE see SUBSTITUTED NITROPHENOL PESTICIDE see ORGANIC PEROXIDE TYPE C, SOLID, TEMPERATURE CONTROLLED see CARBAMATE PESTICIDE 3217 1165 3.2 II 3-06 330
Dinoseb acetate Dinoterb Dinoterb acetate
DI-n-OCTANOYL PEROXIDE (concentration 100%) Dioxacarb p DIOXANE Dioxathion

p
see ORGANOPHOSPHORUS PESTICIDE 3217

p
DIOXOLANE DIPENTENE
1166 2052 2841
3.2 3.3 3.3
II III III
Toxic
3-06 3-07 3-03
330 310 320
3336 see 3327
DI-normal-PENTYLAMINE DIPEROXYAZELAIC ACID (concentration 27%, with inert solid) DIPEROXYDODECANE DIACID (concentration > 13-42%, with inert solid) Diphacinone p
see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED see ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED see PESTICIDE, N.O.S.
p pp
or

GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
DI-(2-PHENOXYETHYL) PEROXYDICA RBONATE (concentration >85-100%) DI-(2-PHENOXYETHYL) PEROXYDICA RBONATE (concentration -85%, with water) DIPHENYL p DIPHENYLAMINE CHLORO-ARSINE DIPHENYLBROMOMETHANE DIPHENYLCHLOROARSINE, LIQUID pp DIPHENYLCHLOROARSINE SOLID DIPHENYLDICHLOROSILANE DIPHENYL ETHER/BIPHENYL PHENYL ETHER MIXTURES p DIPHENYL(DIPHENYL) ETHER (MI XTURES) p DIPHENYLMAGNESIUM DIPHENYLMETHYL BROMIDE DIPHENYLOXIDE-4,4'-DISULPHONYLHYDRAZIDE (concentration 100%) DIPICRYLAMINE DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass DIPICRYL SULPHIDE, WETTED with not less than 10% water, by ma ss DI-2-PROPENYLAMINE 1122 1104 4143 see 3204
pp pp
see ORGANIC PEROXIDE TYPE D, SOLID see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 6138 see 8166 6139 6139 8166 1698 1770 1699 1699 1769 6.1 8 6.1 6.1 8 I II I I II 6.1-04 8-02 6.1-02 6.1-02 8-02 101 345 101 101 700
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see 4241 8166 2005 1770 4.2 8 I II 4.2-01 8-02 170 345
see SELF-REACTIVE SOLID TYPE D 0079 0401 2852 2359 1.1 D 1.1 D 4.1 3.2 I II Toxic, Corrosive 1-01 1-01 4.1-01 3-02 * 375,* 375 320

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE DIPROPIONYL PEROXIDE (concentration 27%, with diluent type A or B) DIPROPYLAMINE DI-normal-PROPYLAMINE 4-DIPROPYLAMINOBENZENE-DIAZONIUM ZINC CHLORIDE (concentration 100%) DIPROPYLENETRIAMINE DI-normal-PROPYL ETHER - ditto DIPROPYL KETONE DI-n-PROPYL PEROXYDICARBONATE (concentration 100%) Diquat Direct reduced iron DISINFECTANT, LIQUID, CORROSIVE, N.O.S DISINFECTANT, LIQUID, TOXIC, N.O.S. DISINFECTANT, SOLID, TOXIC, N.O.S. DISODIUM TRIOXOSILICATE DISODIUM TRIOXOSILICATE, PENTAHYDRATE DISTEARYL PEROXYDICARBONATE (concentration 87%, with inert solid) DISUCCINIC ACID PEROXIDE (concentration > 72-100%) DISUCCINIC ACID PEROXIDE (concentration 72%, with water)
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
see ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED 3218 see 3218 2383 2383 3.2 3.2 II II Corrosive Corrosive 3-02 3-02 320 320
see SELF-REACTIVE SOLID TYPE D see 8187 3120 3218 3336 2269 2384 2384 2710 8 3.1 3.2 3.3 III II II III 8-05 3-06 3-06 3-07 320 330 330 300
see ORGANIC PEROXIDE TYPE C, LIQUID, TEMPERATURE CONTROLLED see BIPYRIDILIUM PESTICIDE MATERIAL HAZARDOUS ONLY IN BULK * 8167 6141 6141 8166-1 1903 3142 1601 3253 8 6.1 6.1 8 I/II/III I/II/III I/II/III III 8-06 6.1-02 6.1-04 8-06 760,

705
see DISODIUM TRIOXOSILICATE see ORGANIC PEROXIDE TYPE D, SOLID see ORGANIC PEROXIDE TYPE B, SOLID see ORGANIC PEROXIDE TYPE D, SOLID TEMPERATURE CONTROLLED
p pp
or

GENERAL INDEX
SUBSTANCE or ARTICLE Disulfoton p DISULPHURIC ACID DISULPHURYL CHLORIDE DI-(3,5,5-TRIMETHYL-1,2-DIOX OLANYL3) PEROXIDE (concentration -52%, as a paste, with diluent type A, with or without water) DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE (concentration -52%, as a stable dispersion in water) DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE (concentration > 38-82%, with diluent type A) DI-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE (concentration -38%, with diluent type B) DIVINYL, INHIBITED DIVINYL ETHER, INHIBITED DIVINYL OXIDE, INHIBITED DNOC p DNOC (pesticide)
p
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see ORGANOPHOSPHORUS PESTICIDE see 8231 see 8218 1831 1817 8 8 I II Toxic 8-06 8-03 700 700
see ORGANIC PEROXIDE TYPE 0, SOLID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE E, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED see 2110 3120 see 3120 see 6135 1010 1167 1167 1598 2(2.1) 3.1 3.1 6.1 I I II 2-07 3-02 3-02 6.1-04 310 330 330 710
see SUBSTITUTED NITROPHENOL PESTICIDE see 8160 see 3378 2565 2850 8 3.3 III III 8-05 3-07 320 310
DODECAHYDRODIPHENYLAMINE DODECENE
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 1-DODECYLAMINE p DODECYL DIPHENYL OXIDE DISULPHONATE p DODECYL HYDROXYPROPYL SULPHIDEp DODECYLPHENOL pp DODECYLTRICHLOROSILANE Dolomitic quicklime Drazoxolon p DRI DRY ICE DYE, LIQUID, CORROSIVE, N.O.S. DYE, LIQUID, TOXIC, N.O.S. DYE, SOLID, CORROSIVE, N.O.S. DYE, SOLID TOXIC, N.O.S. DYE INTERMEDIATE LIQUID, CORROSIVE, N.O.S DYE INTERMEDIATE, LIQUID, TOXIC,
IMDG CODE PAGE
UN No.
CLASS
Pack Subsidiary EmS No. aging Risk Label(s) Group
MFAG Table No.
see Section 23.1.5 of the General Introduction see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID N.O.S. see Section 23.1.5 of the General Introduction see 8103 8167 3145 1771 8 8 I/II/III II 8-15 8-02 710 700
MATERIAL HAZARDOUS ONLY IN BULK* see PESTICIDE, N.O.S. see MATERIAL HAZARDOUS ONLY IN BULK* 9025 8168 6142 8168 6142 8168 6142 8168 6142
1845
2801 1602 3147 3143 2801 1602 3147 3143
9 8 6.1 8 6.1 8 6.1 8 6.1
III I/II/III I/II/III I/II/III I/II/III I/II/III I/II/III I/II/III I/II/III
8-08 8-04 6.1-02 8-05 6.1-04 8-04 6.1-02 8-05 6.1-04
615 760,
760,
760,
N.O.S.
DYE INTERMEDIATE, SOLID, CORROSIVE, N.O.S. DYE INTERMEDIATE, SOLID, TOXIC,
760,
N.O.S.
Dynamite
see EXPLOSIVE, BLASTING, TYPE A
See section 24 of the General Introduction In addition, refer to subsection 4.3 of the MFAG If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG
p pp
or

GENERAL INDEX
IMDG CODE PAGE 3338 3339 see 3338 3223 3223 3339 see 3332 2137 6147
UN No. 2275 1177 2275 1179 1178 1180 2366 1037 1181
CLASS
Packaging Group III III III II II III III II
Subsidiary EmS No. Risk Label(s) Flammable liquid Flammable liquid Corrosive Flammable liquid Flammable liquid, Corrosive Flammable liquid Toxic 3-06 3-07 3-06 3-07 3-07 3-07 3-07 2-07 6.1-01
MFAG Table No. 305 330 305 330 300 330 330 340 540
2-ETHYLBUTANOL 2-ETHYLBUTYL ACETATE 2-ETHYLBUTYL ALCOHOL ETHYL BUTYL ETHER 2-ETHYLBUTYRALDEHYDE p ETHYL BUTYRATE ETHYL CARBONATE ETHYL CHLORIDE ETHYL CHLOROACETATE
3.3 3.3 3.3 3.2 3.2 3.3 3.3 2(2.1) 6.1
ETHYL CHLOROCARBONATE
see 6148
1182
6.1
6.1-01
740
ETHYL CHLOROETHANOATE
see 6147
1181
6.1
II
6.1-01
540
ETHYL CHLOROFORMATE ETHYL-2-CHLOROPROPIONATE ETHYL CHLOROTHIOFORMATE p ETHYL CROTONATE ETHYL CYANIDE ETHYL-3,3-DI-(tert-AMYLPEROXY)BUTYRATE (concentration 67%, with diluent type A) ETHYL-3,3-Dl-(tert-BUTYLPEROXY) BUTYRATE (concentration > 77-100%)
6148 3340 8169 3224 see 3273
1182 2935 2826 1862 2404
6.1 3.3 8 3.2 3.2
I III I] II II
6.1-01 3-07 8-04 3-07 3-02
740 740 740 300 215
see ORGANIC PEROXIDE TYPE C, LIQUID
p pp
or

GENERAL INDEX
SUBSTANCE or ARTICLE ETHYL-3,3-DI-(tert-BUTYLPEROXY)BUTYRATE (concentration - 77%, with diluent type A) ETHYL-3,3-DI-(tert-BUTYLPEROXY) B UTYRATE (concentration -52% with inert solid) ETHYLDICHLOROARSINE ETHYLDICHLOROSILANE
p
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see ORGANIC PEROXIDE TYPE D, SOLID 6149 4342 1892 1183 6.1 4.3 I I Flammable liquid, Corrosive 6.1-02 4.3-05 101 700
ETHYLENE ACETYLENE AND PROPY LENE MIXTURE, REFRIGERATED LIQUID, containing at least 71.5% ethylene, with not more than 22.5% acetylene and not more than 6% propylene ETHYLENE, COMPRESSED ETHYLENE, REFRIGERATED LIQUID ETHYLENE CHLORIDE ETHYLENE CHLOROHYDRIN ETHYLENEDIAMINE ETHYLENE DIBROMIDE ETHYLENE DIBROMIDE AND METHYL BROMIDE MIXTURE LIQUID ETHYLENE DICHLORIDE ETHYLENE FLUORIDE ETHYLENE GLYCOL DIETHYL ETHER ETHYLENE GLYCOL DIMETHYL ETHER
2137
3138
2(2.1)
2-10
310, 620
2138 2138 see 3224 6150 8170 6150 see 6190 3224 see 2132 3340 see 3211
1962 1038 1184 1135 1604 1605 1647 1184 1030 1153 2252
2(2.1) 2(2.1) 3.2 6.1 8 6.1 6.1 3.2 2(2.1) 3.3 3.2
II I II I I II Ill II
Toxic Flammable liquid Flammable liquid Toxic
2-07 2-10 3-03 6.1-01 8-04 6.1-02 6.1-02 3-03 2-07 3-07 3-06
310 310, 620 340 740 320 345 345 340 350 330 330
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
Fluoroacetamide FLUOROACETIC ACID 2-FLUOROANILINE 4-FLUOROANILINE ortho-FLUOROANILINE para-FLUOROANILINE FLUOROANILINES FLUOROBENZENE FLUOROBORIC ACID FLUOROETHANE FLUOROETHANOIC ACID FLUOROFORMYL FLUORIDE, COMPRESSED FLUOROMETHANE FLUOROPHOSPHORIC ACID, ANHYDROUS FLUOROSILICATES, N.O.S. FLUOROSILICIC ACID FLUOROSULPHONIC ACID 2-FLUOROTOLUENE 3-FLUOROTOLUENE 4-FLUOROTOLUENE FLUOROTOLUENES (ortho-, meta-, para- ) Fluorspar Fly ash 6154 see 6155 see 6155 see 6155 see 6155 6155 3233 8175 see 2140 see 6154 see 2115 see 2160 8175 6250 8176 8176 see 3233 see 3233 see 3233 3233 2642 2941 2941 2941 2941 2941 2387 1775 2453 2642 2417 2454 1776 2856 1778 1777 2388 2388 2388 2388
see PESTICIDE N.O.S. 6.1 6.1 6.1 6.1 6.1 6.1 3.2 8 2(2.1) 6.1 2(2.3) 2(2.1) 8 6.1 8 8 3.2 3.2 3.2 3.2 I III III III III III II II I II III II I II II II II Corrosive 6.1-02 6.1-02 6.1-02 6.1-02 6.1-02 6.1-02 3-07 8-06 2-07 6.1-02 2-08 2-07 8-06 6.1-04 8-06 8-03 3-07 3-07 3-07 3-07 540 335 335 335 335 335 345 750 345 540 750 345 700 750 750 750 345 345 345 345
MATERIAL HAZARDOUS ONLY IN BULK * MATERIAL HAZARDOUS ONLY IN BULK *
* See section 24 of the General Introduction

p pp
, or see explanatory notes in the introduction to this index.
GENERAL INDEX
SUBSTANCE or ARTICLE Fonofos pp FORMAL FORMALDEHYDE SOLUTION, FLAMMABLE FORMALDEHYDE SOLUTION, with not less than 25% formaldehyde FORMALDEHYDE DIMETHYL ACETAL FORMALIN SOLUTION, FLAMMABLE FORMALIN SOLUTION with not less than 25% formaldehyde FORMAMIDINE SULPHINIC ACID Formetanate
p
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
see ORGANOPHOSPHORUS PESTICIDE see 3136 3347 8176-1 see 3136 see 3347 see 8176-1 see 4264 1234 1198 2209 1234 1198 2209 3341 3.1 3.3 8 3.1 3.3 8 4.2 II III III II III III II/III Corrosive Corrosive 3-06 3-06 8-07 3-06 3-06 8-07 4.2-04 330 300 300 330 300 300
see CARBAMATE PESTICIDE 8177 see 3123 see 3347 see 8176 1 1779 1190 1198 2209 8 3.1 3.3 8 II II III III Corrosive 8-05 3-07 3-06 8-07 700 330 300 300
FORMIC ACID FORMIC ACID ETHYL ESTER FORMIC ALDEHYDE SOLUTION, FLAMMABLE FORMIC ALDEHYDE SOLUTION, with not less than 25% formaldehyde Formothion 2-FORMYL-3,4-DIHYDRO-2H-PYRAN, STABILIZED N-FORMYL-2-(NITROMETHYLENE)PERHYDRO-1,3-THIAZINE (concentration 100%) FRACTURING DEVICES, EXPLOSIVE, for oil wells without detonator
see ORGANOPHORUS PESTICIDE see 3302 2607 3.3 III 3-06 300
1264
0099
1.1 D
1-01
* Explosive substance or article, refer to subsection 7.3 of the MFAG. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
p pp
or

GENERAL INDEX
IMDG CODE PAGE 8178
UN No. 2803
CLASS
Packaging Group III
Subsidiary EmS No. Risk Label(s) 8 12
MFAG Table No. none
GALLIUM
gamma- (or -)
This prefix is not taken into account in determining the alphabetical order of entries, see under the next part of the name shown in capital letters
GAS CARTRIDGES without a release device non-refillable GAS DRIPS hydrocarbon GAS OIL GASOLINE GASOLINE, CASINGHEAD GAS REFRIGERATED LIQUID, N.O.S. GAS, REFRIGERATED LIQUID, FLAMMABLE, N.O.S. GAS, REFRIGERATED LIQUID, OXIDIZING, N.O.S. GAS SAMPLE, NON-PRESSURIZED FLAMMABLE, N.O.S. , not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED, TOXIC, N.O.S. , not refrigerated liquid GAS SAMPLE, NON-PRESSURIZED TOXIC FLAMMABLE, N.O.S., not refrigerated liquid Gelatine, blasting Gelatine dynamite
2175
2037
2(*)
2-13
see HYDROCARBONS, LIQUID, N.O.S. 3375 3141 1202 1203 3.3 3.1 III II 3-07 3-07 311 311
see CASINGHEAD GASOLINE 2142-1 2142-1 3158 3312 2(2.2) 2(2.1) Oxidizing agent 2-12 2-10 620 620
2142-2
3311
2(2.2)
2-11
620
2142-2
3167
2(2.1)
2-02
2142-3
3169
2(2.3)
2-03
2142-3
3168
2(2.3)
Flammable gas
2-01
see EXPLOSIVE, BLASTING TYPE A see EXPLOSIVE, BLASTING TYPE A
* According to properties. MFAG Table No. 620 for classes 2.1 and 2.2. For substances in class 2.3, if an MFAG table number is not supplied by the shipper refer to subsection 4.2 of the MFAG. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG.
p pp
or

GENERAL INDEX
SUBSTANCE or ARTICLE GENETICALLY MODIFIED MICROORGANISMS GERMANE GERMANIUM HYDRIDE GLYCEROL-1,3-DICHLOROHYDRIN GLYCEROL-alpha -MONOCHLOROHYDRIN Glycerol trinitrate ( class 1) Glyceryl trinitrate ( class 1) GLYCERYL TRINITRATE - ditto GLYCIDAL GLYCIDALDEHYDE GLYCOL CHLOROHYDRIN GLYCOL DIMETHYL ETHER GRENADES hand or rifle, with bursting charge - ditto Grenades, illuminating
IMDG CODE PAGE 9031 2143 see 2143 see 6129 6156
UN No. 3245 2192 2192 2750 2689
CLASS
Packaging Group II III
Subsidiary Risk Label(s) Flammable gas Flammable gas
EmS No.
MFAG Table No. n/a 606 606 740 740
9 2(2.3) 2(2.3) 6.1 6.1
* 2-05 2-05 6.1-02 6.1-02
see NITROGLYCERIN ( class 1) see NITROGLYCERIN ( class 1) see 3265-2 see 3266 see 3349 3349 see 6150 see 3211 1271 1204 3064 2622 2622 1135 2252 0284 0285 1272 0292 0293 3.2 3.2 3.3 3.3 6.1 3.2 1.1 D 1.2 D 1.1 F 1.2 F II II II II II Toxic Toxic Flammable liquid 3-06 3-06 3-02 3-02 6.1-01 3-06 1-01 1-02 1-01 1-02 235 235 300 300 740 330

see AMMUNITION, ILLUMINATING 1273 0372 0318 0452 0110 1.2 G 1.3 G 1.4 G 1.4 S 1-02 1-03 1-04 1-04

GRENADES, PRACTICE, hand or rifle
Grenades, smoke
see AMMUNITION, SMOKE
To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to, or leakage from, a package containing infectious substances refer to section 9 of the introduction to class 6.2. Explosive substance or article, refer to subsection 7.3 of the MFAG. n/a - not applicable
GENERAL INDEX
SUBSTANCE or ARTICLE normal-HEPTYL ALDEHYDE p normal-HEPTYLBENZENE

p
UN No. 3056
CLASS
Packaging Group III
Subsidiary EmS No. Risk Label(s) 3-06
MFAG Table No. 300
3.3
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see 3319 3.3 III 3-07 340
normal-HEPTYL CHLORIDE p H.E.T.P.

p
see HEXAETHYL TETRAPHOSPHATE see 2145 6158 6158 6159 see 6159 see 6159 6159 see 6160 6160 see 6158 8179 see 3236 see 3128 see 3128 see 3236
p
H.E.T.P. (and compressed gas, mixtures) HEXACHLOROACETONE HEXACHLOROBENZENE HEXACHLOROBUTADIENE pp HEXACHLORO-1,3-BUTADIENE pp 1,3-HEXACHLOROBUTADIENE
pp
1612 2661 2729 2279 2279 2279 2646 2875 2875 2661 1781 2458 2458 2458 2458
2(2.3) 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 8 3.2 3.1 3.1 3.2
Ill III III III III I III III III II II II II II
2-08 6.1-02 6.1-04 6.1-02 6.1-02 6.1-02 6.1-02 6.1-04 6.1-04 6.1-02 8-02 3-07 3-07 3-07 3-07
505 740 500 340 340 340 340 711 711 740 700 310 310 310 310
HEXACHLOROCYCLOPENTADIENE HEXACHLOROPHANE HEXACHLOROPHENE HEXACHLORO-2-PROPANONE HEXADECYLTRICHLOROSILANE 1,3-HEXADIENE 1,4-HEXADIENE 1,5-HEXADIENE 2,4-HEXADIENE 2,4-HEXADIENE ALDEHYDE HEXADIENES - ditto HEXAETHYL TETRAPHOSPHATE p HEXAETHYL TETRAPHOSPHATE AND COMPRESSED GAS, MIXTURE
p pp
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 3128 3236 6160 2145 2458 2458 1611 1612 3.1 3.2 6.1 2(2.3) II II II 3-07 3-07 6.1-02 2-08 310 310 505 505
or

GENERAL INDEX
SUBSTANCE or ARTICLE HEXAFLUOROACETONE HEXAFLUOROACETONE HYDRATE HEXAFLUOROETHANE, COMPRESSED HEXAFLUOROPHOSPHORIC ACID HEXAFLUORO-2-PROPANONE HEXAFLUOROPROPYLENE HEXAHYDROBENZENE HEXAHYDROPYRIDINE HEXAHYDROTHIOPHENOL HEXAHYDROTOLUENE normal-HEXALDEHYDE HEXAMETHYLENE HEXAMETHYLENEDIAMINE, SOLID HEXAMETHYLENEDIAMINE, SOLUTION HEXAMETHYLENE DIISOCYANATE HEXAMETHYLENEIMINE HEXAMETHYLENETETRAMINE 3,3,6,6,9,9-HEXAMETHYL-1,2,4,5TETRAOXACYCLONONANE (concentration >52-100%) 3,3,6,6,9,9-HEXAMETHYL-1,2,4,5TETRAOXACYCLONONANE (concentration -52%, with diluent type A) 3,3,6,6,9,9-HEXAMETHYL-1,2,4,5TETRAOXACYCLONONANE (concentration -52%, with inert solid) HEXAMINE
p
IMDG CODE PAGE 2145 6161 2146 8179 see 2145 2146 see 3114 see 8211-1 see 3323 see 3256 3350 see 3114 8180 8180 6161 3236 4150
UN No. 2420 2552 2193 1782 2420 1858 1145 2401 3054 2296 1207 1145 2280 1783 2281 2493 1328
CLASS 2(2.3) 6.1 2(2.2) 8 2(2.3) 2(2.2) 3.1 8 3.3 3.2 3.3 3.1 8 8 6.1 3.2 4.1
Packaging Group II II II I III II III II III II/III II II III
Subsidiary Risk Label(s) Corrosive Corrosive Flammable Corrosive
EmS No. 208 6.1-02 2-09 8-06 2-08 2-09 3-07 8-01 3-03 3-07 3-07 3-07 8-05* 8-05 6.1-02 3-02 4.1-06
MFAG Table No. 750 750 350 750 750 345 310 325 375 310 300 310 320 320 370 320 320
see ORGANIC PEROXIDE TYPE D, SOLID see 4150 1328 4.1 III 4.1-06 320
8-13 when in the molten state
p pp
or
GENERAL INDEX
UN No. 2876 3212 1791
CLASS
Packaging Group III II II/III
Subsidiary EmS No. Risk Label(s) 6.1 04 5.1-06 8-08
3-HYDROXYPHENOL HYPOCHLORITES, INORGANIC, N.O.S. HYPOCHLORITE SOLUTION
6.1 5.1 8
5152-1 8186
p pp
or

GENERAL INDEX
IMDG CODE PAGE 1274
UN No. 0121 0314
CLASS 1.1 G 1.2 G 1.3 G 1.4 G 1.4 S
Packaging Group
EmS No. 1-01 1-02 1-03 1-04 1-04
MFAG Table No. * * * * *
IGNITERS
0315 0325 0454
Imazalil 3,3-IMINODIPROPYLAMINE INFECTIOUS SUBSTANCES, AFFECTING ANIMALS only INFECTIOUS SUBSTANCES, AFFECTING HUMANS INFLAMMABLE INSECTICIDE GAS, N.O.S. INSECTICIDE GAS, FLAMMABLE, N.O.S. INSECTICIDE GAS TOXIC, N.O.S. INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. IODINE MONOCHLORIDE IODINE PENTAFLUORIDE 2-IODOBUTANE IODOMETHANE IODOMETHYLPROPANES 1-IODOPROPANE 2-IODOPROPANE 2152 2152-1 2152 2152-1 8187 5153 3238 see 6197 3238 see 3353 see 3353 1968 3354 1967 3355 1792 2495 2390 2644 2391 2392 2392 8187 6322 6321 2269 2900 2814
see PESTICIDE, N.O.S. 8 6.2 6.2 Ill 8-05
320 n/a n/a
see FLAMMABLE 2() 2(2.1) 2(2.3) 2(2.3) 8 5.1 3.2 6.1 3.2 3.3 3.3 II I II I II III III Flammable gas Toxic Corrosive 2-09 2-07 2-06 2-06 8-03 5.1-01 3-07 6.1-02 3-07 3-07 3-07 none none
none 740 750 345 345 345 345 345
Explosive substance or article, refer to subsection 7.3 of the MFAG. Emergency procedure to be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from a package containing infectious substances, refer to section 9 of the introduction to class 6.2. Label according to properties. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. n/a - Not applicable.
p pp
or
GENERAL INDEX
IMDG CODE PAGE 3353 see 6084
UN No. 2392 2653
CLASS
Packaging Group III II
EmS No.
IODOPROPANES alpha-IODOTOLUENE loxynil

p
3.3 6.1
3-07 6.1-02
see PESTICIDE, N.O.S. see ORGANOPHOSPHORUS PESTICIDE see IRON POWDER see 6165 see 8173 1994 1773 6.1 8 III Flammable liquid 6.1-01 8-06 165 700
Iprobenfos IRON, powder IRON CARBONYL IRON CHLORIDE, ANHYDROUS Iron (III) chloride, anhydrous IRON CHLORIDE SOLUTION IRON OXIDE, SPENT
p
see FERRIC CHLORIDE, ANHYDROUS see 8173 4238 6165 see 8173 see 8173 see 4255 4238 see 4232 see 8173 see 8173 see 3307 see 3373-1 see 3313 see 3309 see 3132 see 3309 2582 1376 1994 1773 2582 1383 1376 2793 1773 2582 1104 1105 2341 2620 2561 1109 1111 1112 8 4.2 6.1 8 8 4.2 4.2 4.2 8 8 3.3 3.3 3.3 3.3 3.1 3.3 3.2 3.3 III III I III III I III Ill III III III III III I III II III Flammable liquid 8-08 4.2-04 6.1-01 8-06 8-08 4.2-02 4.2-04 4.2-05 8-06 8-08 3-07 3-06 3-06 3-06 3-07 3-07 3-07 3-07 700 none 165 700 700 none none none 700 700 330 305 345 330 310 330 375 235
IRON PENTACARBONYL IRON PERCHLORIDE, ANHYDROUS IRON PERCHLORIDE, SOLUTION IRON POWDER, PYROPHORIC IRON SPONGE, SPENT IRON SWARF IRON TRICHLORIDE ANHYDROUS IRON TRICHLORIDE, SOLUTION ISOAMYL ACETATE ISOAMYL ALCOHOL ISOAMYL BROMIDE ISOAMYL BUTYRATE alpha-ISOAMYLENE ISOAMYL FORMATE ISOAMYL MERCAPTAN ISOAMYL NITRATE
p p
see 3184 see 3310
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE ISOAMYL NITRITE Isobenzan

p
UN No. 1113
CLASS 3.1
Packaging Group II
Subsidiary EmS No. Risk Label(s) 3-07
MFAG Table No. 235
see ORGANOCHLORINE PESTICIDE see 3130 2147 3354 see 2147 see 3362 see 3253 3239 3354 3354
p
ISOBUTANAL p ISOBUTANE ISOBUTANOL ISOBUTENE ISOBUTENOL ISOBUTENYL CHLORIDE ISOBUTYL ACETATE ISOBUTYL ACRYLATE, INHIBITED ISOBUTYL ALCOHOL ISOBUTYL ALDEHYDE ISOBUTYLAMINE ISOBUTYLBENZENE p ISOBUTYL BROMIDE ISOBUTYL BUTYRATE ISOBUTYLENE ISOBUTYL FORMATE ISOBUTYL IODIDE ISOBUTYL ISOBUTYRATE ISOBUTYL ISOCYANATE ISOBUTYL MERCAPTAN
p p p
2045 1969 1212 1055 2614 2554 1213 2527 1212 2045 1214 2709 2342
3.1 2(2.1) 3.3 2(2.1) 3.3 3.2 3.2 3.3 3.3 3.1 3.2 3.3 3.2
II III III II II III III II II III II
Corrosive
307 2-07 3-06 2-07 3-06 3-06 3-07 3-03 3-06 3-07 3-02 3-07 3-07
300 310 305 310 305 340 330 330 305 300 320 310 345
3130 3239 see 3315 see 3188
see Section 23.1.5 of the General Introduction 2147 3240 see 3238 3355 3240 see 3194 3355 3241 see 3290 3130 1055 2393 2391 2528 2486 2347 2283 2394 1304 2045 2(2.1) 3.2 3.2 3.3 3.2 3.2 3.3 3.2 3.2 3.1 II II III II II III II II II Toxic 2-07 3-07 3-07 3-07 3-04 3-07 3-07 3-07 3-06 3-07 310 330 345 330 370 375 330 330 330 300
ISOBUTYL METHACRYLATE, INHIBITED ISOBUTYL PROPIONATE p ISOBUTYL VINYL ETHER ISOBUTYRALDEHYDE p
p pp
or

GENERAL INDEX
IMDG CODE PAGE see 3112 see 3117 3245 8188 3244 3133
UN No. 2456 1159 1220 1793 1219 1221 1918 2344 2344
CLASS
Packaging Group I II II III II I III II III
Subsidiary Risk Label(s) Corrosive
EmS No.
MFAG Table No. 340 330 330 700 305 320 310 345 345
ISOPROPENYL CHLORIDE 2-ISOPROPOXYPROPANE ISOPROPYL ACETATE ISOPROPYL ACID PHOSPHATE ISOPROPYL ALCOHOL ISOPROPYLAMINE ISOPROPYLBENZENE
p
3.1 3.1 3.2 8 3.2 3.1 3.3 3.2 3.3
3-07 3-02 3-07 8-05 3-06 3-02 3-07 3-07
3357 see 3189 see 3313
ISOPROPYL BROMIDE - ditto ISOPROPYL-sec -BUTYL PEROXYDICA RBONATE + DI-sec-BUTYL PEROXYDICARBONATE + DI-ISOPROPYL PEROXYDICARBONATE (concentration -52% + -28% + - 22%) ISOPROPYL-sec -BUTYL PEROXYDICA RBONATE + DI-sec-BUTYL PEROXYDICARBONATE + DI-ISOPROPYL PEROXYDICARBONATE (concentration -32%+ - 15-18% + -12-15%) ISOPROPYL BUTYRATE ISOPROPYL CARBINOL ISOPROPYL CHLORIDE ISOPROPYL CHLOROACETATE ISOPROPYL CHLOROCARBONATE
3-07
see ORGANIC PEROXIDE TYPE B, LIQUID, TEMPERATURE CONTROLLED
3358 see 3354 see 3111 3358 see 6168-1
2405 1212 2356 2947 2407
3.3 3.3 3.1 3.3 6.1
III III I III I
Corrosive, Flammable liquid Flammable liquid, Corrosive Corrosive, Flammable liquid
3-07 3-06 3-07 3-02 6.1-01
330 305 340 740 740
ISOPROPYL CHLOROFORMATE
6168-1
2407
6.1
6.1-01
740
ISOPROPYL CHLOROMETHANOATE
see 6168-1
2407
6.1
6.1-01
740
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE ISOPROPYL-2-CHLOROPROPIONATE ISOPROPYL-alpha-CHLOROPROPIONATE ISOPROPYL CUMYL HYDROPER OXIDE (concentration 72% with diluent type A) ISOPROPYL CYANIDE ISOPROPYL ETHER ISOPROPYL FORMATE ISOPROPYLIDENEACETONE ISOPROPYL ISOBUTYRATE ISOPROPYL ISOCYANATE ISOPROPYL MERCAPTAN p ISOPROPYL METHANOATE ISOPROPYL NITRATE ISOPROPYL PROPIONATE ISOPROPYLTOLUENE pp ISOPROPYLTOLUOL pp ISOSORBIDE DINITRATE MIXTURE with hot less than 60% lactose, mannose, starch or calcium hydrogen phosphate ISOSORBIDE-5-MONONITRATE ISOTETRAMETHYLBENZENE Isothioate ISOVALERALDEHYDE ISOVALERONE Isoxathion pp
p p
UN No. 2934 2934
CLASS 3.3 3.3
Packaging Group III III
Subsidiary EmS No. Risk Label(s) 3-07 3-07
see ORGANIC PEROXIDE TYPE F, LIQUID see 3241 see 3117 see 3275 see 3362 3246 3246 see 3142 see 3275 3247 3247 see 3325 see 3325 4151 4151-1 2284 1159 1281 1229 2406 2483 2402 1281 1222 2409 2046 2046 2907 3251 3.2 3.1 3.2 3.3 3.2 3.2 3.1 3.2 3.2 3.2 3.3 3.3 4.1 4.1 III II II II III II II II II II II III III Toxic Toxic 3-03 3-02 3-06 3-06 3-07 3-04 3-07 3-06 3-07 3-07 3-07 3-07 4.1-06 4.1-10 215 330 330 300 330 370 375 330 235 330 310 310 320 235
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID, N.O.S. see ORGANOPHOSPHORUS PESTICIDE see 3288 see 3333 2058 1157 3.2 3.3 II III 3-06 3-07 300 300
see ORGANOPHOSPHORUS PESTICIDE
p pp
or

GENERAL INDEX
IMDG CODE PAGE 9033 9033 9033 4347
UN No. 3090 3091 3091 1413
CLASS
Packaging Group II II II I
EmS No.
MFAG Table No. none none none 245
LITHIUM BATTERIES LITHIUM BATTERIES CONTAINED IN EQUIPMENT LITHIUM BATTERIES PACKED WITH EQUIPMENT LITHIUM BOROHYDRIDE Lithium dispersions LITHIUM FERROSILICON LITHIUM HYDRIDE LITHIUM HYDRIDE FUSED SOLID LITHIUM HYDROXIDE SOLID LITHIUM HYDROXIDE SOLUTION LITHIUM HYDROXIDE MONOHYDRATE LITHIUM HYPOCHLORITE DRY with more than 39% available chlorine (8.8% available oxygen) LITHIUM HYPOCHLORITE MIX TURE DRY with more than 39% available chlorine (8.8% available oxygen) LITHIUM NITRATE LITHIUM NITRIDE LITHIUM PEROXIDE LITHIUM SILICON L.N.G. LONDON PURPLE p L.P.G.
9 9 9 4.3
4.1-06 4.1-06 4.1-06 4.3-04
see ALKALI METAL DISPERSION 4347-1 4348 4348 see 8190 8190 8190 5156 2830 1414 2805 2680 2679 2680 1471 4.3 4.3 4.3 8 8 8 5.1 II I II II II/III II II 4.3-03 4.3-01 4.3-01 8-06 8-06 8-06 5.1-06 160, 605 160 160 160 160 160 160, 741 160, 741 160 160, 725 160, 735 160
5156 5157 4349 5157 4349
1471 2722 2806 1472 1417
5.1 5.1 4.3 5.1 4.3
II III I II II
5.1 06 5.1-06 4.3-05 5.1 04 4.3-03
see NATURAL GAS, REFRIGERATED LIQUID 6171 1621 6.1 II 6.1 04 100
see PETROLEUM GASES LIQUEFIED
p pp
or
IMDG CODE - PAGE 10145 Amdt 28 96
GENERAL INDEX
SUBSTANCE or ARTICLE m M86 fuel Magnesia (unslaked) MAGNESIUM granules coated MAGNESIUM powder MAGNESIUM with more than 50% magnesium in pellets, turnings or ribbons MAGNESIUM ALKYLS Magnesium alloys MAGNESIUM ALLOYS, POWDER containing more than 50% magnesium nonpyrophoric MAGNESIUM ALLOYS, with more than 50% magnesium in pellets turnings or ribbons MAGNESIUM ALUMINIUM PHOSPHIDE Magnesium amalgams MAGNESIUM ARSENATE
p
IMDG CODE PAGE see metasee 3174-1
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
3165
3.2
Toxic Corrosive
3-02
720
MATERIAL HAZARDOUS ONLY IN BULK * see MAGNESIUM GRANULES, COATED see MAGNESIUM POWDER 4153 4240 1869 3053 4.1 4.2 III I
4.1-02 4.2-01
none 170
Dangerous when wet
see also ALKALINE EARTH METAL ALLOY, N.O.S. 4353 1418 4.3 I/II/III Spontaneously combustible Toxic 4.3-06 none
4153 4350
1869 1419
4.1 4.3
III I
4.1-02 4.3-02
none 205
see ALKALINE EARTH METAL AMALGAM 6172 see 8126 5158 5158 1622 2693 1473 2723 6.1 8 5.1 5.1 II III II II 6.1-04 8-08 5.1-06 5.1-06 100 635 745 745
MAGNESIUM BISULPHITE SOLUTION MAGNESIUM BROMATE MAGNESIUM CHLORATE Magnesium chloride and chlorate, mixture MAGNESIUM DIAMIDE MAGNESIUM DIPHENYL Magnesium dispersions
4240 4241
see CHLORATE AND MAGNESIUM CHLORIDE MIXTURE 2004 2005 4.2 4.2 II I 4.2-01 4.2-01 725 170
see ALKALINE EARTH METAL DISPERSION
See section 24 of the General Introduction.
p pp
or
see explanatory notes in the intr oduction to this index.
GENERAL INDEX
IMDG CODE PAGE 6250 4351 see 6250 4351 5159 5159 5160 4352 4353 4353 see 6250 see 4353
UN No. 2853 2950 2853 2010 1474 1475 1476 2011 1418 2624 2853 2624
CLASS
Packaging Group III III III I III II II I I/II/III II III II
Subsidiary Risk Label(s) Toxic Spontaneously combustible
EmS No. 6.1-04 4.3-06 6.1-04 4.3-01 5.1-06 5.1-06 5.1-04 4.3-02 4.3-06 4.3-05 6.1-04 4.3-05
MFAG Table No. 750 none 750 none 235 745 735 205 none none 750 none
MAGNESIUM FLUOROSILICATE MAGNESIUM GRANULES, COATED, containing more than 50% magnesium particle size not less than 149 microns MAGNESIUM HEXAFLUOROSILICATE MAGNESIUM HYDRIDE MAGNESIUM NITRATE MAGNESIUM PERCHLORATE MAGNESIUM PEROXIDE MAGNESIUM PHOSPHIDE MAGNESIUM POWDER containing more than 50% magnesium non-pyrophoric MAGNESIUM SILICIDE MAGNESIUM SILICOFLUORIDE MAGNESIUM SILICON MALATHION p MALEIC ANHYDRIDE (a) solid (b) molten MALONODINITRILE MALONONITRILE MANCOZEB p (ISO) MANEB p MANEB STABILIZED against self-heating
p
6.1 4.3 6.1 4.3 5.1 5.1 5.1 4.3 4.3 4.3 6.1 4.3
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 8191 see 6172 6172 2215 2647 2647 8 6.1 6.1 III II II (a) 8-05 (b) 8-13 6.1-02 6.1-02 700 215 215
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 4242 4354 2210 2968 4.2 4.3 III III Dangerous when wet 4.2-04 4.3-05 506 506
p pp
or

GENERAL INDEX
SUBSTANCE or ARTICLE MANEB PREPARATION, STABILIZED against self-heating p MANEB PREPARATION with not less than 60% maneb p MANGANESE ETHYLENE-BISDITHIOCARBAMATE p MANGANESE ETHYLENE-1,2-BISDITHIOCARBAMATE p MANGANESE ETHYLENE-BISDITHIOCARBAMATE, STABILIZED p MANGANESE ETHYLENE-1,2-BISDITHIOCARBAMATE, STABILIZED p MANGANESE NITRATE Manganese (II) nitrate MANGANESE RESINATE MANGANOUS NITRATE MANNITOL HEXANITRATE, WETTED with not less than 40% water, or mixture of alcohol and water, by mass MATCHES, FUSEE MATCHES, SAFETY (book card or strike on box) MATCHES, "STRIKE ANYWHERE" MATCHES, WAX "VESTA" MEAL, oily - ditto - ditto Mecarbam
p
IMDG CODE PAGE 4354 4242 see 4242 see 4242 see 4354 see 4354 5160
UN No. 2968 2210 2210 2210 2968 2968 2724
CLASS
Packaging Group III III III III III III III
Subsidiary Risk Label(s) Dangerous when wet Dangerous when wet Dangerous when wet
EmS No.
MFAG Table No. 506 506 506 506 506 506 none
4.3 4.2 4.2 4.2 4.3 4.3 5.1
4.3-05 4.2-04 4.2-04 4.2-04 4.3-05 4.3-05 5.1-06
see MANGANESE NITRATE 4153 see 5160 1123 4154 4155 4155 4156 see 4257 see 4258 see 4259 1330 2724 0133 2254 1944 1331 1945 1386 1386 2217 4.1 5.1 1.1 D 4.1 4.1 4.1 4.1 4.2 4.2 4.2
III III
4.1-06 5.1-06 1-01 4.1-06 4.1-06 4.1-06 4.1-06 4.2-05 4.2-05
none none
III III III III
none none 200 none none none none
4.2-05
see ORGANOPHOSPHORUS PESTICIDE
No label required.
p pp
or
GENERAL INDEX
IMDG CODE PAGE 6320 3134-1 3248-1 3360-1 6172-1 6172-1
UN No. 3291 3248 3248 3248 1851 3249
CLASS
Packaging Group II II II III II/III II/III
Subsidiary Risk Label(s) Toxic Toxic Toxic
EmS No.
MFAG Table No. n/a

MEDICAL WASTE, N.O.S MEDICINE, LIQUID, FLAMMABLE TOXIC, N.O.S. - ditto - - ditto - MEDICINE, LIQUID, TOXIC, N.O.S MEDICINE SOLID, TOXIC, N.O.S. Medinoterb p-MENTHYL HYDROPEROXIDE (concentration > 72-100%) p-MENTHYL HYDROPEROXIDE (concentration -72% with diluent type A) Mephosfolan p MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, N.O.S. - ditto - - ditto - MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S. - ditto - - ditto - MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. MERCAPTANS, LIQUID, FLAMMABLE, N.O.S.* - ditto - - ditto - MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. - ditto - - ditto -
6.2 3.1 3.2 3.3 6.1 6.1
* 3-07 3-07 3-07 6.1-02 6.1-04
see SUBSTITUTED NITROPHENOL PESTICIDE see ORGANIC PEROXIDE TYPE D LIQUID see ORGANIC PEROXIDE TYPE F, LIQUID see ORGANOPHOSPHORUS PESTICIDE 3134-2 3248-2 3360-2 3135 3249 3361 6173 3134-2 3248-2 3360-2 3135 3249 3361 3336 3336 3336 1228 1228 1228 3071 3336 3336 3336 1228 1228 1228 3.1 3.2 3.3 3.1 3.2 3.3 6.1 3.1 3.2 3.3 3.1 3.2 3.3 I/II l/ll III II II III II I/II I/II III II II III Toxic Toxic Toxic Flammable liquid Toxic Toxic Toxic 3-07 3-07 3-07 3-03 3-03 3-07 6.1-01 3-07 3-07 3-07 3-03 3-03 3-07

375 375 375 375
375 375 375
* To be declared by the shipper after agreement with the competent authority of the country concerned. For action to
be taken in the event of damage to, or leakage from, a package containing infectious substances, refer to section 9 of the introduction to class 6.2. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. n/a - not applicable
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE MERCAPTANS LIQUID, TOXIC, FLAMMABLE, N.O.S. MERCAPTOACETIC ACID Mercaptodimethur
p
UN No. 3071 1940
CLASS
Subsidiary Risk Label(s) Flammable liquid
EmS No.
61 8
6.1-01 8-05
see CARBAMATE PESTICIDE see 6267 see 6267 1141 see 6178 see 6178 6174 see 6179
pp
2-MERCAPTOETHANOL 2-MERCAPTOPROPIONIC ACID 5-MERCAPTOTETRAZOL-1-ACETIC ACID MERCURIC ACETATE pp MERCURIC AMMONIUM CHLORIDE pp MERCURIC ARSENATE MERCURIC BENZOATE
pp
2966 2936 0448 1629 1630 1623 1631 1645 1634 1624 1636 1637 1638 1625 1640 1641 1642 1626 1645 1646 1639 1629
6.1 6.1 1.4 C 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1
II II II II II II II II II II II II II II II II I II II II II
6.1-02 6.1-02 1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04
375 375 700 * 105 105 100, 105 105 105 105 105 215 105 105 105 105 105 215 105, 215 105 105 105 105
pp
MERCURIC BISULPHATE MERCURIC BROMIDE

pp
see 6187 see 6179 6175 see 6182
MERCURIC CHLORIDE MERCURIC CYANIDE p p
pp
MERCURIC GLUCONATE MERCURIC IODIDE

p
pp
see 6182 see 6183 6175 see 6184 see 6184 see 6185 6176 see 6187
pp
6.1-04 6.1-04
MERCURIC NITRATE pp MERCURIC OLEATE pp MERCURIC OXIDE pp MERCURIC OXYCYANIDE, DESENSITIZED pp MERCURIC POTASSIUM CYANIDE pp MERCURIC SULPHATE
pp
6.1-02 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04
MERCURIC THIOCYANATE MERCUROL p p MERCUROUS ACETATE

pp
see 6187 see 6183 see 6178
* Explosive substance or article, refer to subsection 7.3 of the MFAG. p pp , or see explanatory notes in the introduction to this index.
GENERAL INDEX
SUBSTANCE or ARTICLE MERCUROUS BISULPHATE pp MERCUROUS BROMIDE

pp
IMDG CODE PAGE see 6187 see 6179
UN No. 1645 1634
CLASS
EmS No.
6.1 6.1
6.1-04 6.1-04
MERCUROUS CHLORIDE MERCUROUS NITRATE pp
pp
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 6177

pp
1627 1644 1645 2809 1629 1630 2778
6.1 6.1 6.1 8 6.1 6.1 3.2
II II II III II II I/II
Toxic
6.1-04 6.1-04 6.1-04 8-12 6.1-04 6.1-04 3-03
105 105 105 none 105 105 105
MERCUROUS SALICYLATE MERCUROUS SULPHATE MERCURY metal MERCURY ACETATE pp

pp
see 6186 see 6187 8191 6178

pp
MERCURY AMMONIUM CHLORIDE
6178 3270
MERCURY BASED PESTICIDE LIQUID, FLAMMABLE TOXIC, flashpoint less than 23C c.c. pp MERCURY-BASED PESTICIDE, LIQUID TOXIC pp MERCURY-BASED PESTICIDE LIQUID, TOXIC, FLAMMABLE, flashpoint between 23C and 61C c.c. pp MERCURY-BASED PESTICIDE, SOLID, TOXIC pp MERCURY BENZOATE
pp
6219
3012
6.1
I/II/III
6.1-02
105
6220
3011
6.1
I/II/III
Flammable liquid
6.1-01
105
6221 6179
2777 1631 1624 1645 1634 2024 2025
6.1 6.1 6.1 6.1 6.1 6.1 6.1
I/II/III II II II II I/II/III I/II/III
6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-02 6.1-04
105 105 105 105 105 105 105
MERCURY BICHLORIDE
pp
see 6175 see 6187 6179 6180 6181
MERCURY BISULPHATE pp MERCURY BROMIDES pp MERCURY COMPOUND, LIQUID, N.O.S. p p MERCURY COMPOUND SOLID, N.O.S. pp * Mercury (II) (mercuric) compounds or Mercury (l) (mercurous) compounds p p
pp
see also MERCURY-BASED PESTICIDE
* p
for mercuric sulphide.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE MERCURY CYANIDE

pp
IMDG CODE PAGE 6182 1105 6182 6183 6183 6184 6184 6185 see 6176 6185 6186 6187
UN No. 1636 0135 1637 1638 1639 1640 1641 1642 1626 1643 1644 1645 1646 2325 1229 3246
CLASS 6.1 1.1 A 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3.3 3.3 6.1
Packaging Group II
Subsidiary Risk Label(s) Corrosive
EmS No. 6.1-04 1-01 6.1-04 6.1-04 6.1-04 6.1-02 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 6.1-04 3-03 3-06 6.1-02
MFAG Table No. 215
MERCURY FULMINATE, WETTED with not less than 20% water or mixture of alcohol and water, by mass MERCURY GLUCONATE pp MERCURY IODIDE
pp
II II II II II II I II II II II III III I
105 105 105 105 105 215 105,21 5 105 105 105 105 310 300 700
MERCURY NUCLEATE pp MERCURY OLEATE MERCURY OXIDE pp MERCURY OXYCYANIDE, DESENSITIZED

pp pp
MERCURY POTASSIUM CYANIDE pp MERCURY POTASSIUM IODIDE MERCURY SALICYLATE MERCURY SULPHATE
pp pp pp
MERCURY THIOCYANATE MESITYLENE

p
pp
6187 see 3389-1 3362 see 6188
MESITYL OXIDE MESYL CHLORIDE meta- (or m-) METAARSENIC ACID METACETONE METAL ALKYL HALIDES, WATERREACTIVE, N.O.S. METAL ALKYL HYDRIDES, WATERREACTIVE, N.O.S. METAL ALKYLS, WATER-REACTIVE, N.O.S.
This prefix is not taken into account in determining the alphabetical order of entries; see under the next part of the name shown in CAPITAL letters. see 6072 see 3208 4243 4244 4243 1554 1156 3049 3050 2003 6.1 3.2 4.2 4.2 4.2 II II I I I Dangerous when wet Dangerous when wet Dangerous when wet 6.1-04 3-07 4.2-01 4.2-01 4.2-01 100 300 170 170 170
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE METAL ARYL HALIDES, WATER REACTIVE, N.O.S. METAL ARYL HYDRIDES WATER-REACTIVE, N.O.S. METAL ARYLS, WATER REACTIVE, N.O.S. METAL CARBONYLS, N.O.S. METAL CATALYST, DRY METAL CATALYST, WETTED with a visible excess of liquid METALDEHYDE METAL HYDRIDES FLAMMABLE, N.O.S. METAL HYDRIDES WATER REACTIVE N.O.S. METALLIC SUBSTANCE WATER REACTIVE N.O.S. METALLIC SUBSTANCE, WATER-REACTIVE, SELF-HEATING, N.O.S. METAL POWDER, FLAMMABLE, N.O.S. METAL POWDER SELF-HEATING, N.O.S. METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S. Metal sulphide concentrates Metam-sodium
p
IMDG CODE PAGE 4243 4244 4243 6187-1 4245 4246 4157 4157-1 4354-1 4354-2 4354-3 4157 4260 4157-1
UN No. 3049 3050 2003 3281 2881 1378 1332 3182 1409 3208 3209 3089 3189 3181
CLASS
Packaging Group I I I I/II/III I/II/III II III II/III I/II I/II/III I/II/III II/III II/III II/III
Subsidiary Risk Label(s) Dangerous when wet Dangerous when wet Dangerous when wet Spontaneously combustible
EmS No. 4.2-01 4.2-01 4.2-01 6.1-02 4.2-02 4.2-05 4.1-03 4.1 06 4.3-01 4.3-08 4.3-08 4.1-02 4.2-04 4.1-06
MFAG Table No. 170 170 170 165 none none 300 * 760 * * *
4.2 4.2 4.2 6.1 4.2 4.2 4.1 4.1 4.3 4.3 4.3 4.1 4.2 4.1
MATERIAL HAZARDOUS ONLY IN BULKS see DITHIOCARBAMATE PESTICIDE see 3250 3250 2396 2396 3.2 3.2 II II Toxic Toxic 3-02 3-02 300 300
MFTHACRALDEHYDE, INHIBITED MFTHACRYLALDEHYDE, INHIBITED
If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. In addition refer to subsection 4.3 of the MFAG. COPPER METAL POWDER carried under this entry is a severe marine pollutant. See section 24 of the General Introduction.

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 3-METHACRYLIC ACID METHACRYLIC ACID, INHIBITED METHACRYLONITRILE INHIBITED METHALLYL ALCOHOL Methamidophos
p
IMDG CODE PAGE see 8154 8192 3250 3362
UN No. 2823 2531 3079 2614
CLASS 8 8 3.2 3.3
Packaging Group III III I III
Subsidiary Risk Label(s) Toxic
EmS No. 8-05 8-02 3-06 3-06
MFAG Table No. 700 700 215 305
see ORGANOPHOSPHORUS PESTICIDE 2156 2156 1971 1972 2(2.1) 2(2.1) 2-02 2-10 620 620
METHANE COMPRESSED METHANE, REFRIGERATED LIQUID METHANE AND HYDROGEN, MIXTURES, COMPRESSED METHANESULPHONYL CHLORIDE METHANETHIOL METHANOL Methasulfocarb Methidathion Methomyl p ortho-METHOXYANILINE METHOXYBENZENE p 1-METHOXYBUTANE METHOXYETHANE 2-METHOXYETHANOL 2-METHOXYETHYL ACETATE METHOXYMETHYL ISOCYANATE 4-METHOXY-4-METHYLPENTAN-2-ONE
p p
see HYDROGEN AND METHANE MIXTURES, COMPRESSED 6188 see 2160 3251 3246 1064 1230 6.1 2(2.3) 3.2 I II Corrosive Flammable gas Toxic 6.1-02 2-06 3-06 700 375 306
see CARBAMATE PESTICIDE see ORGANOPHOSPHORUS PESTICIDE see CARBAMATE PESTICIDE see 6069 see 3311 see 3195 see 2140 see 3342 see 3342 3251 3363 2431 2222 2350 1039 1188 1189 2605 2293 6.1 3.3 3.2 2(2.1) 3.3 3.3 3.2 3.3 III III II III III I III Toxic 6.1-02 3-07 3-07 2-06 3-06 3-06 3-04 3-07 335 330 330 330 330 330 370 300
p pp
or
GENERAL INDEX
IMDG CODE PAGE see 3363 see 6207 see 3138 3363 3252 see 8216 2157 see 3250 see 6114-1 3252 3136 see 3362 3253 see 4221 see 4221 2157 3253
UN No. 2293 2730 2612 3092 1231 1848 1060 2396 1143 1919 1234 2614 2554 3052 3052 1061 1235
CLASS
Packaging Group III III II III II III II I II II III II I I II
Subsidiary Risk Label(s) Flammable liquid* Toxic Flammable liquid Dangerous when wet Corrosive
EmS No.
MFAG Table No. 300 335 330 330 330 700 310 300 300 330 330 305 340 170 170 320 320
4-METHOXY-4-METHYL-2-PENTANONE METHOXYNITROBENZENES SOLID or LIQUID 1-METHOXYPROPANE 1-METHOXY-2-PROPANOL METHYL ACETATE METHYLACETIC ACID METHYLACETYLENE AND PROPADIENE MIXTURE, STABILIZED 2-METHYLACROLEIN, INHIBITED 3-METHYLACROLEIN STABILIZED p METHYL ACRYLATE, INHIBITED METHYLAL METHYL ALLYL ALCOHOL METHYL ALLYL CHLORIDE METHYLALUMINIUM SESQUIBROMIDE METHYLALUMINIUM SESQUICHLORIDE METHYLAMINE, ANHYDROUS METHYLAMINE, AQUEOUS SOLUTION 2-(N,NMETHYLAMINOETHYLCARBONYL)-4(3,4- DIMETHYLPHENYLSULPHONYL)BENZENEDIAZONIUM HYDROGEN SULPHATE (concentration 96%)
3.3 6.1 3.1 3.3 3.2 8 2(2.1) 3.2 6.1 3.2 3.1 3.3 3.2 4.2 4.2 2(2.1) 3.2
3-07 6.1-02 3-06 3-06 3-06 8-04 2-07 3-02 6.1-01 3-03 3-06 3-06 3-06 4.2-01 4.2-01 2-06 3-02

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE METHYLAMYL ACETATE METHYLAMYL ALCOHOL METHYL-normal-AMYL KETONE N-METHYLANILINE METHYLATED SPIRITS METHYLBENZENE 4-METHYLBENZENESULPHONYLHYDRAZIDE (concentration 100%) METHYLBENZOL alpha-METHYLBENZYL ALCOHOL, SOLID or LIQUID METHYL BORATE METHYL BROMIDE METHYL BROMIDE AND CHLOROPICRIN, MIXTURE METHYL BROMIDE AND ETHYLENE DIBROMIDE, MIXTURE, LIQUID p METHYL BROMOACETATE METHYLBROMOACETONE 2-METHYL-1,3-BUTADIENE, INHIBITED 2-METHYLBUTANE METHYLBUTANOLS - ditto 3-METHYLBUTAN -2-ONE 3-METHYL-2-BUTANONE 2-METHYL-1-BUTENE
IMDG CODE PAGE 3364 see 3366 see 3310 6188 see 3219 see 3285
UN No. 1233 2053 1110 2294 1170 1294
CLASS 3.3 3.3 3.3 6.1 3.2 3.2
Packaging Group III III III III II II
EmS No. 3-07 3-02 3-07 6.1-02 3-06 3-07
MFAG Table No. 330 305 300 335 305, 306 310
see SELF-REACTIVE SOLID TYPE D see 3285 6189 see 3287 2158 see 2120 6190 6191 6191 see 3133 see 3140 see 3269-1 see 3373-1 3254 see 3254 3132 1294 2937 2416 1062 1581 1647 2643 1218 1265 1105 1105 2397 2397 2459 3.2 6.1 3.2 2(2.3) 2(2.3) 6.1 6.1 6.1 3.1 3.1 3.2 3.3 3.2 3.2 3.1 II III II I II II I I II III II II I Flammable gas 3-07 6.1-02 3-06 2-06 2-08 6.1-02 6.1-02 6.1-02 3-07 3-07 3-06 3-06 3-07 3-07 3-07 310 305 240 345 345 345 740 740 310 310 305 305 300 300 310
p pp
or
GENERAL INDEX
UN No. 1593
CLASS
Packaging Group III
EmS No.
MFAG Table No. 340
METHYLENE CHLORIDE METHYLENE CHLORIDE AND METHYL CHLORIDE, MIXTURE METHYLENE CHLOROBROMIDE METHYLENE CYANIDE p.p'-METHYLENEDIANILINE METHYLENE DIBROMIDE METHYL ETHER 1-METHYL-2-ETHYLBEN2ENE
p p
6.1
6.1-02
see METHYL CHLORIDE AND METHYLENE CHLORIDE, MIXTURE see 6088 see 6172 see 6119 see 6122 see 2133 1887 2647 2651 2664 1033 6.1 6.1 6.1 6.1 2(2.1) III II III III 6.1-02 6.1-02 6.1-04 6.1-02 2-07 345 215 335 345 330
see Section 23.1.5 of the General Introduction see ENVIRONMENTALLY HAZARDOUS SUBSTANCE LIQUID N.O.S. see 3191 see 3314 see 2140 3226 1120 1120 1039 1193 3.2 3.3 2(2.1) 3.2 || III II 3-06 3-06 2-06 3-06 305 305 330 300
1-METHYL-4-ETHYLBENZENE p METHYL ETHYL CARBINOL - ditto METHYL ETHYL ETHER METHYL ETHYL KETONE METHYL ETHYL KETONE PEROXIDE(S) (concentration -52%, with diluent type A, available oxygen >10%) METHYL ETHYL KETONE PEROXIDE(S) (concentration -45%, with diluent type A available oxygen - 10%) METHYL ETHYL KETONE PEROXIDE(S) (concentration -40%, with diluent type A available oxygen -82%) 2-METHYL-5-ETHYLPYRIDINE p METHYL FLUORIDE METHYLFLUOROBENZENES (ortho-, meta-, para-) METHYL FORMATE
see ORGANIC PEROXIDE TYPE B, LIQUID
see ORGANIC PEROXIDE TYPE E LIQUID 6195 2160 see 3233 3137 2300 2454 2388 1243 6.1 2(2.1) 3.2 3.1 III II I 6.1-02 2-07 3-07 3-06 325 345 345 330
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 2-METHYLFURAN METHYL GLYCOL METHYL GLYCOL ACETATE 2-METHYLHEPTANE 2-METHYL-2-HEPTANETHIOL 5-METHYL-2-HEXANONE 5-METHYLHEXAN-2-ONE METHYLHYDRAZINE METHYL IODIDE METHYL ISOBUTENYL KETONE METHYL ISOBUTYL CARBINOL METHYL ISOBUTYL CARBINOL ACETATE METHYL ISOBUTYL KETONE METHYL ISOBUTYL KETONE PEROXIDES (concentration 62% with diluent types A and B) METHYL ISOCYANATE METHYL ISOCYANATE SOLUTION METHYL ISONITRILE METHYL ISOPROPENYL KETONE, INHIBITED METHYL ISOPROPYL KETONE METHYL ISOTHIOCYANATE
IMDG CODE PAGE 3137-1 see 3342 see 3342 see 3267 6213 see 3366 3366 6196 6197 see 3362 3366 see 3364 3257
UN No. 2301 1188 1189 1262 3023 2302 2302 1244 2644 1229 2053 1233 1245
CLASS 3.1 3.3 3.3 3.2 6.1 3.3 3.3 6.1 6.1 3.3 3.3 3.3 3.2
Packaging Group II III III II I III III I I III III III II
Subsidiary EmS No. Risk Label(s) Flammable liquid Flammable liquid, Corrosive 3-07 3-06 3-06 3-07 6.1-01 3-07 3-07 6.1-01 6.1-02 3-06 3-02 3-07 3-07
MFAG Table No. 330 330 330 310 375 300 300 720 345 300 305 330 300
see ORGANIC PEROXIDE TYPE D, LIQUID Flammable liquid Flammable liquid Flammable liquid Flammable liquid*
6197-1 6197-1 see 6197-1 3258 see 3254 6198
2480 2480 2480 1246 2397 2477
6.1 6.1 6.1 3.2 3.2 6.1
I I I II II I
6.1-01 6.1-01 6.1-01 3-07 3-07 6.1-01
370 370 370 300 300 370
* If shipped as a liquid.
p pp
or

GENERAL INDEX
IMDG CODE PAGE 3258 4355-1 2160

p
UN No. 2400 1928
CLASS
Pack aging Group II I III II II II
EmS No. 3-07
MFAG Table No. 330
METHYL ISOVALERATE METHYLMAGNESIUM BROMIDE IN ETHYL ETHER METHYL MERCAPTAN

p
3.2 4.3
Flammable liquid 4.3-01 170, 330 Flammable gas Corrosive Corrosive 2-06 6.1-01 3-07 3-02 3-02 375 300 330 322 322
1064 2(2.3) 2785 1247 2535 2535 6.1 3.2 3.2 3.2
METHYLMERCAPTOPROPIONALDEHYDE
see 6266 3259 3259 3259
METHYL METHACRYLATE, MONOMER, INHIBITED 4-METHYLMORPHOLINE N-METHYLMORPHOLINE METHYLNAPHTHALENES METHYL NITRITE METHYLNITROPHENOLS p METHYL ORTHOSILICATE METHYLPENTADIENES 2-METHYLPENTANE 3-METHYLPENTANE 2-METHYLPENTAN -2-OL 4-METHYLPENTAN-2-OL 4-METHYL-2-PENTANONE 4-METHYL-3-PENTEN-2-ONE 3-METHYL-2-PENTEN-4-YN OL METHYLPHENYLDICHLOROSILANE METHYL PHENYL ETHER
p p
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE. LIQUID or SOLID, N.O.S. see 6210 6198-1 3138 see 3129 see 3129 3367 see 3366 see 3257 see 3362 see 8200 8192 see 3311 see 3315 2455 2446 2606 2461 1208 1208 2560 2053 1245 1229 2705 2437 2222 2709 6.1 6.1 3.1 3.1 3.1 3.3 3.3 3.2 3.3 8 8 3.3 3.3 III I II II II III III II III II II III III CARRIAGE PROHIBITED 6.1-02 710 360 310 310 310 305 305 300 300 305 700 330 310
Flammable liquid 6.1-01 3-07 3-07 3-07 3-06 3-02 3-07 3-06 8-05 8-02 3-07 3-07
2-METHYL-2-PHENYLPROPANE p
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 1-METHYLPIPERIDINE N-METHYLPIPERIDINE 2-METHYLPROPANOL-1 2-METHYL-2-PROPANOL 2-METHYLPROPANOYL CHLORIDE 2-METHYL-2-PROPEN-1-OL METHYL PROPIONATE 2-METHYLPROPIONIC ACID METHYLPROPYL ACRYLATE, INHIBITED METHYLPROPYLBENZENES METHYL PROPYL ETHER 2-METHYLPROPYL ISOBUTYRATE METHYL PROPYL KETONE METHYLPYRIDINES (2-, 3-, 4 ) 3-METHYL-4-(PYRROLIDIN-1-YL)BENZENEDIAZONIUM TETRAFLUOROBORATE (concentration 95%) METHYL SALICYLATE p METHYLSTYRENES, INHIBITED alpha-METHYLSTYRENE p METHYL SULPHATE METHYL SULPHIDE
p p p pp
IMDG CODE PAGE 3260 see 3260 see 3354 see 3191 see 3242 see 3362 3261 see 3356 see 3354 see 3325 3138 see 3355 3261 see 3376
UN No. 2399 2399 1212 1120 2395 2614 1248 2529 2527 2046 2612 2528 1249 2313
CLASS 3.2 3.2 3.3 3.2 3.2 3.3 3.2 3.3 3.3 3.3 3.1 3.3 3.2 3.3
Packaging Group II II III II II III II III III III II III II III
Subsidiary Risk Label(s) Corrosive Corrosive Corrosive Corrosive Corrosive
EmS No. 3-02 3-02 3-06 3-06 3-04 3-06 3-07 3-02 3-03 3-07 3-06 3-07 3-07 3-02
MFAG Table No. 325 325 305 305 700 305 330 700 330 310 330 330 300 325
see SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see 3392 see 3357 see 6133 see 3119 3262 6198-1 3262 2618 2303 1595 1164 2536 2533 1250 3.3 3.3 6.1 3.1 3.2 6.1 3.2 III III I II II III I Corrosive Corrosive 3-02 3-07 6.1-02 3-07 3-07 6.1-02 3-04 310 310 315 225 330 540 700
METHYLTETRAHYDROFURAN METHYL TRICHLOROACETATE METHYLTRICHLOROSILANE
p pp
or
GENERAL INDEX
IMDG CODE PAGE 3258 4355-1 2160 see 6266 3259 3259 3259
UN No. 2400 1928 1064 2785 1247 2535 2535
CLASS
Packaging Group II I III II II II
Subsidiary Risk Label(s) Flammable liquid Flammable gas Corrosive Corrosive
EmS No.
MFAG Table No. 330 170, 330 375 300 330 322 322
METHYL ISOVALERATE METHYLMAGNESIUM BROMIDE IN ETHYL ETHER METHYL MERCAPTAN

p
3.2 4.3 2(2.3) 6.1 3.2 3.2 3.2
3-07 4.3-01 2-06 6.1-01 3-07 3-02 3-02
METHYLMERCAPTOPROPION ALDEHYDE p METHYL METHACRYLATE, MONOMER, INHIBITED 4-METHYLMORPHOLINE N-METHYLMORPHOLINE METHYLNAPHTHALENES METHYL NITRITE METHYLNITROPHENOLS
p p
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE. LIQUID or SOLID, N.O.S. see 6210 6198-1 3138 see 3129 see 3129 3367 see 3366 see 3257 see 3362 see 8200 8192 see 3311
p
2455 2446 2606 2461 1208 1208 2560 2053 1245 1229 2705 2437 2222 2709 6.1 6.1 3.1 3.1 3.1 3.3 3.3 3.2 3.3 8 8 3.3 3.3
CARRIAGE PROHIBITED III I II II II III III II III II II III III Flammable liquid 6.1-02 6.1-01 3-07 3-07 3-07 3-06 3-02 3-07 3-06 8-05 8-02 3-07 3-07 710 360 310 310 310 305 305 300 300 305 700 330 310
METHYL ORTHOSILICATE METHYLPENTADIENES 2-METHYLPENTANE 3-METHYLPENTANE 2-METHYLPENTAN-2-OL 4-METHYLPENTAN -2-OL 4-METHYL-2-PENTANONE 4-METHYL-3-PENTEN-2-ONE 3-METHYL-2-PENTEN-4-YN OL METHYLPHENYLDICHLOROSILANE METHYL PHENYL ETHER
p
2-METHYL-2-PHENYLPROPANE
see 3315
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 1-METHYLPIPERIDINE N-METHYLPIPERIDINE 2-METHYLPROPANOL-1 2-METHYL-2-PROPANOL 2-METHYLPROPANOYL CHLORIDE 2-METHYL-2-PROPEN-1-OL METHYL PROPIONATE 2-METHYLPROPIONIC ACID METHYLPROPYL ACRYLATE, INHIBITED METHYLPROPYLBENZENES METHYL PROPYL ETHER 2-METHYLPROPYL, ISOBUTYRATE METHYL PROPYL KETONE METHYLPYRIDINES (2-, 3 , 4-) 3-METHYL-4-(PYRROLIDIN-1YL)BENZENEDIAZONIUM TETR AFLUOROBORATE (concentration 95%) METHYL SALICYLATE p METHYLSTYRENES, INHIBITED alpha-METHYLSTYRENE p METHYL SULPHATE METHYL SULPHIDE
p p p pp
IMDG CODE PAGE 3260 see 3260 see 3354 see 3191 see 3242 see 3362 3261 see 3356 see 3354 see 3325 3138 see 3355 3261 see 3376
UN No. 2399 2399 1212 1120 2395 2614 1248 2529 2527 2046 2612 2528 1249 2313
CLASS 3.2 3.2 3.3 3.2 3.2 3.3 3.2 3.3 3.3 3.3 3.1 3.3 3.2 3.3
Packaging Group II II III II II III II III III III II III II III
Subsidiary Risk Label(s) Corrosive Corrosive Corrosive Corrosive Corrosive
EmS No. 3-02 3-02 3-06 3-06 3-04 3-06 3-07 3-02 3-03 3-07 3-06 3-07 3-07 3-02
MFAG Table No. 325 325 305 305 700 305 330 700 330 310 330 330 300 325
see SELF-REACTIVE SOLID TYPE C, TEMPERATURE CONTROLLED
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID N.O.S. see 3392 see 3357 see 6133 see 3119 3262 6198-1 3262 2618 2303 1595 1164 2536 2533 1250 3.3 3.3 6.1 3.1 3.2 6.1 3.2 III III I II II III I Corrosive Corrosive 3-02 3-07 6.1-02 3-07 3-07 6.1-02 3-04 310 310 315 225 330 540 700
METHYLTETRAHYDROFURAN METHYL TRICHLOROACETATE METHYLTRICHLOROSILANE
p pp
or
IMDG CODE - PAGE 10162 Amdt. 29 98
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
NATURAL GASOLINE Neodymium nitrate and praseodymium nitrate, mixture NEOHEXANE NEON, COMPRESSED NEON, REFRIGERATED LIQUID Neon and nitrogen mixtures Neon and oxygen mixtures Neon in rare gases mixtures NEOPENTANE NICKEL CARBONYL pp NICKEL CYANIDE pp Nickel (II) cyanide NICKEL NITRATE Nickel (II) nitrate NICKEL NITRITE Nickel (II) nitrite NICKELOUS NITRATE NICKELOUS NITRITE NICKEL TETRACARBONYL NICOTINE NICOTINE COMPOUND, LIQUID, N.O.S. NICOTINE COMPOUND, SOLID, N.O.S. NICOTINE HYDROCHLORIDE, LIQUID
pp
see MOTOR SPIRIT or GASOLINE or PETROL see DIDYMIUM NITRATE see 3129 2161 2161 1208 1065 1913 3.1 2(2.2) 2(2.2) II 3-07 2-04 2-12 310 none 620
see RARE GASES AND NITROGEN MIXTURES see RARE GASES AND OXYGEN MIXTURE see RARE GASES MIXTURES see 2147 6202 6203 2044 1259 1653 2(2.1) 6.1 6.1 I II Flammable liquid 2-07 6.1-01 6.1-04 310 165 215
see NICKEL CYANIDE 5161 2725 5.1 III 5.1-06 none
see NICKEL NITRATE 5161 2726 5.1 III 5.1-06 235
see NICKEL NITRITE see 5161 see 5161 see 6202 6203 6204 6204 6205 2725 2726 1259 1654 3144 1655 1656 5.1 5.1 6.1 6.1 6.1 6.1 6.1 III III I II I/II/III I/II/III II Flammable liquid 5.1-06 5.1-06 6.1-01 6.1-02 6.1-02 6.1-04 6.1-02 none 235 165 800 800 800 800
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE NICOTINE HYDROCHLORIDE SOLID NICOTINE HYDROCHLORIDE SOLUTION NICOTINE PREPARATION LIQUID, N.O.S. NICOTINE PREPARATION, SOLID, N.O.S. NICOTINE SALICYLATE NICOTINE SULPHATE, SOLID NICOTINE SULPHATE, SOLUTION NICOTINE TARTRATE NITRATES, INORGANIC, N.O.S. NITRATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. NITRATING ACID, MIXTURE NITRATING ACID, MIXTURE, SPENT NITRIC ACID, other than red fuming, all concentrations NITRIC ACID, RED FUMING
IMDG CODE PAGE 6205 6205 6204 6204 6205 6206 6206 6206 5162 5162 8194 8194 8195 8196
UN No. 1656 1656 3144 1655 1657 1658 1658 1659 1477 3218 1796 1826 2031 2032
CLASS 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 5.1 5.1 8 8 8 8
Packaging Group II II I/II/III I/II/III II II II II II/III II/III I/II I/II I /ll I
Subsidiary Risk Label(s) Oxidizing agent * Oxidizing agent * Oxidizing agent Oxidizing agent. Toxic Oxidizing agent. Corrosive Oxidizing agent. Corrosive
EmS No. 6.1-04 6.1-02 6.1-02 6.1-04 6.1-04 6.1-04 6.1 02 6.1-04 5.1-05 5.1 02 8-03 8-03 8-03 8-03
MFAG Table No. 800 800 800 800 800 800 800 800 235 235 700 700 610 , 700 610, 700 610
NITRIC OXIDE, COMPRESSED
2162
1660
2(2.3)
2-03
NITRIC OXIDE AND DINITROGEN TETROXIDE, MIXTURE
2162
1975
2(2.3)
2-08
610
Not required if nitric acid content is not more than 50%. Concentrations over 70%. For packaging group I only.
p pp
or
GENERAL INDEX
IMDG CODE PAGE see 4159 see 4160 see 4161 6210 3369 2163 2163
UN No. 2556 2557 2555 2446 2842 1066 1977
CLASS
Packaging Group II II II III III
EmS No.
MFAG Table No. 610 610 610 710 335 none 620
NITROCOTTON WITH ALCOHOL NITROCOTTON WIT PLASTICIZING SUBSTANCE
4.1 4.1 4.1 6.1 3.3 2(2.2) 2(2.2)
4.1-01 4.1-01 4.1-01 6.1-02 3-06 2-04 2-12
NITROCOTTON WITH WATER NITROCRESOLS p NITROETHANE NITROGEN COMPRESSED NITROGEN, REFRIGERATED LIQUID NITROGEN DIOXIDE AND NITRIC OXIDE MIXTURES NITROGEN DIOXIDE NITROGEN MIXTURES WITH RARE GASES NITROGEN PEROXIDE
see NITRIC OXIDE AND DINITROGEN TETROXIDE MIXTURES Oxidizing agent, Corrosive
2134
1067
2(2.3)
2-08
610
see RARE GASES AND NITROGEN MIXTURES Oxidizing agent Corrosive Oxidizing agent Corrosive Oxidizing agent Oxidizing agent Corrosive
see 2134
1067
2(2.3)
2-08
610
NITROGEN SESQUIOXIDE
see 2164
2421
2(2.3)
2-08
610
NITROGEN TRIFLUORIDE, COMPRESSED
2164
2451
2(2.2)
2-03
750
NITROGEN TRIOXIDE
2164
2421
2(2.3)
2-08
610
NITROGLYCERIN DESENSITIZED with not less than 40% non-volatile water-insoluble phlegmatizer by mass
1108
0143
1.1 D
Toxic
1-01
Amdt. 29 98
GENERAL INDEX
SUBSTANCE or ARTICLE NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. , with not more than 30% nitroglycerin, by mass - ditto - - ditto - NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S. , with more than 2% but not more than 10% nitroglycerin, by mass NITROGLYCERIN SOLUTION IN ALC OHOL, with more than 1% but not more than 10% nitroglycerin NITROGLYCERIN SOLUTION IN ALC OHOL, with more than 1% but not more than 5% nitroglycerin NITROGLYCERIN SOLUTION IN ALC OHOL, with not more than 1% nitroglycerin NITROGUANIDINE, dry or wetted with less than 20% water, by ma ss NITROGUANIDINE, WETTED with not less than 20% water, by mass NITROHYDROCHLORIC ACID NITROMANNITE, WETTED with not less than 40% water, or mixture of alcohol and water, by ma ss NITROMETHANE NITRONAPHTHALENE NITROPHENOLS (ortho-, meta-, para-) 1-NITROPROPANE 2-NITROPROPANE
IMDG CODE PAGE
UN No.
CLASS
Pack Subsidiary aging Risk Label(s) Group
EmS No.
MFAG Table No.
3138-3
3343
3.1
3265-1 3369-1
3343 3343
3.2 3.3
4161-2
3319
4.1
4.1-01
235
1126
0144
1.1 D
1-01
3266
3064
3.2
II
3-06
235
3265-2
1204
3.2
II
3-06
235
1127 4162 8197 see 1123 3370 4163 6210 see 3370 see 3370
0282 1336 1798 0133 1261 2538 1663 2608 2608
1.1 D 4.1 8 1.1 D 3.3 4.1 6.1 3.3 3.3
I I II III III III III
1-01 4.1-01 8-03 1-01 3-06 4.1-05 6.1-04 3-06 3-06
610 * 610 700
335 335 710 335 335
Explosive substance or article, refer to subsection 7.3 of the MFAG. Packaging group as assigned by the competent authority on the basis of the criteria set out in paragraph 3.1.2 of the Introduction to class 3. As approved by the competent authority.
p pp
or
GENERAL INDEX
IMDG CODE PAGE 3370 4247 4247
UN No. 2608
CLASS
Packaging Group III II II
EmS No.
NITROPROPANES para-NITROSODIETHYLANILINE para-NITROSODIMETHYLANILINE 4-NITROSOPHENOL NITROSTARCH dry or wetted with less than 20% water, by mass NITROSTARCH, WETTED with not less than 20% water , by ma ss NITROSYL CHLORIDE NITROSYLSULPHURIC ACID, SOLID or LIQUID NITROTOLUENES (ortho-, meta-, para-), LIQUID p NITROTOLUENES (ortho-, meta-, para-), SOLID p NITROTOLUIDINES NITROTRIAZOLONE NITROTRICHLOROMETHANE NITRO-UREA NITROUS ETHER, SOLUTION - ditto NITROUS OXIDE NITROUS OXIDE, REFRIGERATED LIQUID NITROUS OXIDE AND CARBON, DIOXIDE MIXTURES NITROXYLENES, LIQUID or SOLID p N,N-
3.3 4.2
3-06 4.2-04 4.2-04
1369
4.2
see SELF-REACTIVE SOLID, TYPE D, TEMPERATURE CONTROLLED 1128 4163-1 2165 8198 6211 0146 1337 1069 2308 1664 1.1 D 4.1 2(2.3) 8 6.1 I II II Corrosive 1-01 4.1-01 2-08 8-03 6.1-02 * 610 740 700 335
6211 6211 1104 see 6108 1129 see 3124 see 3227 2166 2166
1664 2660 0490 1580 0147 1194 1194 1070 2201
6.1 6.1 1.1 D 6.1 1.1 D 3.1 3.2 2(2.2) 2(2.2)
II III I I I
Toxic Toxic Oxidizing agent Oxidizing agent
6.1-02 6.1-04 1-01 6.1-02 1-01 3-02 3-02 2-08 2-11
335 335 * 740 * 235 235 none 620
see CARBON DIOXIDE AND NITROUS OXIDE, MIXTURES 6212 see N1665 6.1 II 6.1-02 335
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE 1-NONANAL p NONANES 1-NONANAL p NONYLPHENOL p NONYLTRICHLOROSILANE Norbormide 2,5-NORBORNADIENE, INHIBITED - ditto - normal NTO
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 3371 1920 3.3 III 3-07 310
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see 8103 8198 3145 1799 8 8 I/II/III II 8-15 8-02 710 700
see PESTICIDE, N.O.S. 3108 3186 2251 2251 3.1 3.2 II II 3-07 3-07 310 310
This prefix is not taken into account in determining the alphabetical order of entries, see under the next part of the name shown in capital letters 1104 0490 1.1 D 1-01 *
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
Subsidiary EmS No. Risk Label(s) Oxidizing agent
MFAG Table No. 615
OXYGEN AND CARBON DIOXIDE, MIXTURE, COMPRESSED OXYGEN AND RARE GASES, MIXTURES OXYGEN DIFLUORIDE, COMPRESSED
see 2113
1014
2(2.2)
2-04
see RARE GASES AND OXYGEN, MIXTURE 2170 2190 2(2.3) Oxidizing agent. Corrosive Oxidizing agent, Corrosive 2-03 750
OXYGEN FLUORIDE, COMPRESSED OXYGEN GENERATOR, CHEMICAL
see 2170 5165-1
2190 3356
2(2.3) 5.1
II
2-03 5.1-11
750 *
GENERAL INDEX
SUBSTANCE or ARTICLE p PAINT (including paint, lacquer, enamel, stain, shellac solutions varnish polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound)*
IMDG CODE PAGE see para
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
3139
1263
3.1
I/II *
305
310,313
ditto ditto PAPER, UNSATURATED OIL TREATED, incompletely dried para (or p) PARAFFIN PARAFORMALDEHYDE PARALDEHYDE Paraoxon p Paraquat Parathion pp Parathionmethyil p PCB's p p PENTABORANE PENTACHLOROETHANE p PENTACHLOROPHENOL Pentachlorophenol pp
pp
3268 3372 4248
1263 1263 1379
3.2 3.3 4.2
l/ll * III III
305 305 4.205
310, 313 310, 313 none
This prefix is not taken into account in determining the alphabetical order of entries, see under the next part of the name shown in CAPITAL letters see 3375 4164 3372 1223 2213 1264 3.3 4.1 3.3 III Ill 307 4.103 306 311 300 300
see ORGANOPHOSPHORUS PESTICIDE see BIPYRIDILIUM PESTICIDE see ORGANOPHOSPHORUS PESTICIDE see ORGANOPHOSPHORUS PESTICIDE see 9034 42481 6217 6217 2315 1380 1669 3155 9 4.2 6.1 6.1 II I II II Toxic 6.102 4.201 6.102 6.104 none 245 340 711
see also ORGANOCHLORINE PESTICIDE
Packaging group III under certain conditions. No label required.
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
PENTAERYTHRITE TETRANITRATE, DESENSITIZED with not less than 15% phlegmatizer, by ma ss PENTAERYTHRITE TETRANITRATE, MIXTURE, DESENSITIZED, SOLID, N.O.S., with more than 10% but not more than 20% PETN, by mass PENTAERYTHRITE TETRANITRATE, WETTED with not less than 25% water, by mass PENTAERYTHRITE TETRANITRATE with not less than 7% wax, by mass PENTAERYTHRITOL TETRANITRATE, DESENSITIZED, with not less than 15% phlegmatizer, by mass PENTAERYTHRITOL TETRANITRATE, WETTED with not less than 25% water, by mass PENTAERYTHRITOL TETRANITRATE with not less than 7% wax, by mass PENTAFLUOROETHANE PENTAFLUOROETHANE,1,1,1TRIFLUOROETHANE AND 1,1,1,2TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH APPROXIMATELY 44% PENTAFLUOROETHANE AND 52% 1,1,1TRIFLUOROETHANE PENTAFLUOROETHYL, TRIFLUOROVINYL ETHER PENTAFLUOROETHOXYTRIFLUOROETHYLENE PENTALIN p PENTAMETHYLENE PENTAMETHYLHEPTANE
1106
0150
1.1 D
1-01
4164
3344
4.1
Ill
1106
0150
1.1 D
1-01
1130
0411
1.1 D
1-01
1106
0150
1.1 D
1-01
1106
0150
1.1 D
1-01
1130 2170 1
0411 3220
1.1 D 2(2.2)
1-01 2-09
350
see 2176-1
3337
2(2.2)
2-09
620
see 2171 see 2171 see 6217 see 3115 3373
3154 3154 1669 1146 2286
2(2.1) 2(2.1) 6.1 3.1 3.3
II II III
2-07 2-07 6.1-02 3-07 3-07
620, 615 620, 615 340 310 310
* Explosive substance or article, refer to subsection 7.3 of the MFAG. As approved by the competent Authority.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE PENTANALS normal-PENTANE PENTANE-2,4-DIONE 2,4-PENTANEDIONE PENTANES, liquid PENTANETHIOLS PENTANOLS - ditto 2-PENTANONE 3-PENTANONE 1-PENTENE 1-PENTOL PENTOLITE, dry or wetted with less than 15% water, by mass 1-PENTYLAMINE 2-PENTYLAMINE 3-PENTYLAMINE PENTYLAMINES - ditto n-PENTYLBENZENE p PENTYL BUTANOATES PENTYL BUTYRATES PENTYL FORMATES PENTYL NITRATES PERCHLORATES, INORGANIC, N.O.S. PERCHLORATES, INORGANIC, AQU EOUS SOLUTION, N.O.S. PERCHLORIC ACID, with more than 50% but not more than 72% acid , by ma ss
p
IMDG CODE PAGE see 3288 see 3140 3373 see 3373 3140 see 3184 see 3269-1 see 3373-1 see 3261 see 3208 3140 8200 1110 see 3183 see 3308 see 3183 see 3183 see 3308
UN No. 2058 1265 2310 2310 1265 1111 1105 1105 1249 1156 1108 2705 0151 1106 1106 1 106 1106 1106
CLASS 3.2 3.1 3.3 3.3 3.1 3.2 3.2 3.3 3.2 3.2 3.1 8 1.1 D 3.2 3.3 3.2 3.2 3.3
Packaging Group II II III III I/II II II III II II I II II III II II III
Subsidiary Risk Label(s) Toxic Toxic Corrosive Corrosive Corrosive Corrosive Corrosive
EmS No. 3-06 3-07 3-06 3-06 3-07 3-07 3-06 3-06 3-07 3-07 3-07 8-05 1-01 3-02 3-02 3-02 3-02 3-02
MFAG Table No. 300 310 300 300 310 375 305 305 300 300 310 305 * 320 320 320 320 320
see Section 23.1.5 of the General Introduction see 3309 see 3309 see 3309 see 3310 5166 5166 5167 2620 2620 1109 1112 1481 321 I 1873 3.3 3.3 3.3 3.3 5.1 5.1 5.1 III III III III II/III II/III I Corrosive 3-06 3-06 3-07 3-07 5.1-05 5.1-02 5.1-02 330 330 330 235 745 745 700
p pp
or
GENERAL INDEX
IMDG CODE PAGE 8200 see 6158 see 6159 see 6264
p
UN No. 1802 2729 2646 1897 1670 3083 3057 2422 3154 3153 2424 1266 1266 1482 3214 1483
CLASS
Packaging Group II III I III I II III II/III II II/III
Subsidiary Risk Label(s) Oxidizing agent Oxidizing agent Corrosive
EmS No.
MFAG Table No. 700 500 340 340 376 750 700 350 620, 615 620, 615 350 305 305 715 715 735
PERCHLORIC ACID with not more than 50% acid , by ma ss PERCHLOROBENZENE PERCHLOROCYCLOPENTADIENE PERCHLOROETHYLENE
p
8 6.1 6.1 6.1 6.1 2(2.3) 2(2.3) 2(2.2) 2(2.1) 2(2.1) 2(2.2) 3.2 3.3 5.1 5.1 5.1
8-03 6.1-04 6.1-02 6.1-02 6.1-02 2-08 2-08 2-09 2-07 2-07 2-09 3-05 3-05 5.1-05 5.1-02 5.1-04
PERCHLOROMETHYL MERCAPTAN PERCHLORYL FLUORIDE PERFLUOROACETYL CHLORIDE PERFLUORO-2-BUTENE PERFLUORO(ETHYL VINYL ETHER)
6218 2170-1 see 2183 see 2167 2171 2171 see 2168 3269 3374 5167-1 5167-1 5168
PERFLUORO(METHYL VINYL ETHER) PERFLUOROPROPANE PERFUMERY PRODUCTS with flammable liquid - ditto - PERMANGANATES, INORGANIC, N.O.S. PERMANGANATES, INORGANIC, AQU EOUS SOLUTION, N.O.S. PEROXIDES, INORGANIC, N.O.S. PEROXYACETIC ACID, TYPE D (concentration -43%) stabilized PEROXYACETIC ACID, TYPE E (concentration -43%) stabilized PEROXYACETIC ACID, TYPE F (concentration -43%) stabilized PEROXYACETIC ACID AND HYDROGEN PEROXIDE MIXTURE PERSULPHATES, INORGANIC, N.O.S.
see ORGANIC PEROXIDE, TYPE D, LIQUID see ORGANIC PEROXIDE, TYPE E, LIQUID see ORGANIC PEROXIDE, TYPE F, LIQUID see HYDROGEN PEROXIDE AND PEROXYACETIC ACID, MIXTURE 5168-1 3215 5.1 III 5.1-05 700
* Packaging group III under certain conditions

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE PERSULPHATES, INORGANIC, AQUEOUS SOLUTION, N.O.S. PESTICIDE, LIQUID, FLAMMABLE, TOXIC, N.O.S., flashpoint less than 23 C c.c. PESTICIDE, LIQUID, TOXIC, N.O.S. PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., flashpoint between 23 C and 61 C c.c.
IMDG CODE PAGE 51681
UN No. 3216
CLASS
Packaging Group III
EmS No.
MFAG Table No. 700
5.1
5.102
3270 6219 6220 6221 1106 1106 1130
3021 2902 2903 2588 0150 0150 0411
3.2 6.1 6.1 6.1 1.1 D 1.1 D 1.1 D
I/II I/II/III I/II/III I/II/III
Toxic Flammable liquid
303 6.102 6.101 6.104 101 101 101
PESTICIDE, SOLID, TOXIC, N.O.S. PETN, DESENSITIZED with not less than 15% phlegmatizer, by mass PETN, WETTED, with not less than 25% water , by ma ss PETN, with not less than 7% wax by mass PETN/TNT PETROL
* *

see PENTOLITE 3141 1203 3.1 II 307 311
Petroleum coke calcined or uncalcined PETROLEUM CRUDE OIL ditto ditto PETROLEUM DISTILLATES, N.O.S. ditto ditto PETROLEUM ETHER 3141 3271 3375 3141 3271 3375
MATERIAL HAZARDOUS ONLY IN BULK 1267 1267 1267 1268 1268 1268 3.1 3.2 3.3 3.1 3.2 3.3 I/II I/II III I/II I/II III 307 307 307 307 307 307 311 311 311 311 311 311
see PETROLEUM DISTILLATES N.O.S. or PETROLEUM PRODUCTS, N.O.S.
* If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. Explosive substance or article refers to subsection 7.3 of the MFAG. PETROL leaded is a MARINE POLLUTANT . See section 24 of the General Introduction.
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No. 1075
CLASS
Packaging Group
EmS No.
MFAG Table No. 311
PETROLEUM GASES, LIQUEFIED PETROLEUM NAPHTHA PETROLEUM OIL
2147
2(2.1)
2-07
see NAPHTHA, PETROLEUM see PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRO DUCTS, N.O.S. 3141 3271 3375 1268 1268 1268 3.1 3.2 3.3 I/II I/II 3-07 3-07 3-07 311 311 311
PETROLEUM PRODUCTS, N.O.S. - ditto - - ditto - Petroleum products PETROLEUM SPIRIT PHENACYL BROMIDE PHENARSAZINE CHLORIDE p p PHENETIDINES (ortho-; para-) Phenkapton PHENOL, MOLTEN PHENOL, SOLID PHENOL, SOLUTION PHENOLATES, LIQUID PHENOLATES, SOLID
see class 3.1 , page 3271 Class 3.3, page 3375 see PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRO DUCTS, N.O.S. 6223 see 6138 6223 2645 1698 2311 6.1 6.1 6.1 II I III 6.1-04 6.1-04 6.1-02 740 101 335
see ORGANOPHOSPHORUS PESTICIDE 6224 6225 6225 2312 1671 2821 2904 2905 1803 6.1 6.1 6.1 8 8 8 II II II/III III III II 6.1-02 6.1-04 6.1-02 8-05 8-05 8-06 710 710 710 711 711 700
8139 8139 8201
PHENOLSULPHONIC ACID, LIQUID d-PHENOTHRIN

p
see Section 23.1.5 of the General Introduction 3270 3346 3.2 I/II Toxic 3-03 510
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23C c.c. PESTICIDE, LIQUID, TOXIC
6219 3348 6.1 I/II/III Flammable liquid 6.1-02 510
PHENOXYACETIC ACID DERIVATIVE
PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, flashpoint between 23C and 61C c.c.
6220
3347
6.1
I/II/III
6.1-02
510
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE PHENOXYACETIC ACID DERIVATIVE, SOLID, TOXIC Phenthoater pp PHENYLACETONITRILE, LIQUID PHENYLACETYL CHLORIDE PHENYLAMINE PHENYL BROMIDE 1-PHENYLBUTANE
p
IMDG CODE PAGE 6221
UN No. 3345
CLASS
Packaging Group I/II/III
EmS No.
MFAG Table No. 510
6.1
61-04
see ORGANOPHOSPHORUS PESTICIDE 6226 8201 see 6068 see 3312 see 3315 see 3315 see 6228 6226 see 8122 6104 1 see 6099 see 6082
p
2470 2577 1547 2514 2709 2709 2487 1672 2226 2746 1697 2224
6.1 8 6.1 3.3 3.3 3.3 6.1 6.1 8 6.1 6.1 6.1
III II II III III III I I II II II II
Flammable liquid Corrosive
6.1-02 8-02 6.1-02 3-07 3-07 3-07 6.1-01 6.1-02 8-05 6.1-02 6.1 02 6.1-02
215 700 335 345 310 310 370 740 340 740 740 215
2-PHENYLBUTANE p PHENYL CARBIMIDE PHENYLCARBYLAMINE CHLORIDE PHENYLCHLOROFORM PHENYL CHLOROFORMATE PHENYL CHLOROMETHYL KETONE, LIQUID or SOLID PHENYL CYANIDE PHENYLCYCLOHEXANE
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID N.O.S. see 8202 see 8202 6227 see 3222 see 3381 see 3233 6227 2798 2799 1673 1175 2055 2387 2572 8 8 6.1 3.2 3.3 3.2 6.1 II II III II III II II 8-05 8-05 6.1-04 3-07 3-07 3-07 6.1-02 700 700 320 310 310 345 720
PHENYLDICHLOROPHOSPHINE PHENYLDICHLOROPHOSPHINE SU LPHIDE PHENYLENEDIAMINES (ortho-, meta-, para-) PHENYLETHANE PHENYLETHYLENE, INHIBITED p PHENYL FLUORIDE PHENYLHYDRAZINE
p pp
or
GENERAL INDEX
IMDG CODE UN PAGE No. see 6226 6228 see 6226 6228 6229
pp
CLASS
Packaging Group I I I I II I/II/III II II III III II II III II II
Subsidiary Risk Label(s) Flammable liquid Flammable liquid
EmS No.
MFAG Table No. 740 370 740 375 105 105 105 105 305 330 700 700 310 700 345
PHENYLIMINOPHOSGENE PHENYL ISOCYANATE PHENYLISOCYANODICHLORIDE PHENYL MERCAPTAN PHENYLMERCURIC ACETATE p p PHENYLMERCURIC COMPOUND, N.O.S. PHENYLMERCURIC HYDROXIDE pp PHENYLMERCURIC NITRATE
pp
1672 2487 1672 2337 1674 2026 1894 1895 2937 2222 2798 2799 2303 1804 2338
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 3.3 8 8 3.3 8 3.2
6.1-02 6.1-01 6.1-02 6.1-01 6.1 04 6.1-04 6.1-04 6.1-04 6.1-02 3-07 8-05 8-05 3-07 8-02 3-07
6229 6230 6230 see 6189 see 3311 8202 8202 see 3357 8203 see 3185
PHENYL METHYL CARBINOL, SOLID or LIQUID PHENYL METHYL ETHER

p
PHENYLPHOSPHORUS DICHLORIDE PHENYLPHOSPHORUS THIODICHLORIDE 2-PHENYLPROPENE p PHENYLTRICHLOROSILANE PHENYLTRIFLUOROMETHANE
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE Phorate pp Phosalone Phosfolan PHOSGENE Phosmet

p pp
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see ORGANOPHOSPHORUS PESTICIDE see ORGANOPHOSPHORUS PESTICIDE see ORGANOPHOSPHORUS PESTICIDE 2172 1076 2(2.3) Corrosive 2-08 600
see ORGANOPHOSPHORUS PESTICIDE 4249 2940 4.2 II 42-04 310
9-PHOSPHABICYCLONONANES Phosphamidon PHOSPHINE PHOSPHORETTED HYDROGEN PHOSPHORIC ACID, LIQUID PHOSPHORIC ACID, SOLID PHOSPHORIC ANHYDRIDE PHOSPHORIC CHLORIDE PHOSPHORIC PENTACHLORIDE PHOSPHORIC PERCHLORIDE PHOSPHOROUS ACID, solid or solution PHOSPHOROUS BROMIDE PHOSPHOROUS CHLORIDE PHOSPHORUS, AMORPHOUS PHOSPHORUS, RED PHOSPHORUS, WHITE, DRY
pp pp
see ORGANOPHOSPHORUS PESTICIDE 2172 see 2172 8204 8204 see 8208 see 8208 see 8208 see 8208 8205 see 8209 see 6231 4165 see 4165 4249 4251 2199 2199 1805 1805 1807 1806 1806 1806 2834 1808 1809 1338 1338 1381 2447 2(2.3) 2(2.3) 8 8 8 8 8 8 8 8 6.1 4.1 4.1 4.2 4.2 III III II II II II III II I III III I I Flammable gas Flammable gas Corrosive Toxic Toxic 2-05 2-05 8-08 8-08 8-06 8-03 8-03 8-03 8-08 8-03 6.1-02 4.1-06 4.1-06 4.2-04 4.2-03 601 601 700 700 700 700 700 700 700 700 700 none none 200 200
PHOSPHORUS, WHITE, MOLTEN pp
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE PHOSPHORUS, WHITE, UNDER WATER p p PHOSPHORUS, YELLOW, DRY p p PHOSPHORUS, YELLOW, MOLTEN
pp
IMDG CODE PAGE 4250 4249 4251

pp
UN No. 1381 1381 2447 1381 1339 2576 1939 1810 2691 1806 2198 1340 1807 1341
CLASS
Packaging Group I I I I II II II II II II II II II
Subsidiary Risk Label(s) Toxic Toxic Toxic Toxic Corrosive Flammable solid ~
EmS No.
MFAG Table No. 200 200 200 200 225 700 700 700 700 700 750 225 700 225
4.2 4.2 4.2 4.2 4.1 8 8 8 8 8 2(2.3) 4.3 8 4.1
4.2-04 4.2-04 4.2-03 4.2-04 4.1-03 8-13 8-03 8-03 8-06 8-03 2-08 4.3-03 8-06 4.1-03
PHOSPHORUS, YELLOW, UNDER WATER
4250 4165 8206 8206 8207 8207 8208 2173 4355-3 8208 4166
PHOSPHORUS HEPTASULPHIDE, free from yellow or white phosphorus PHOSPHORUS OXYBROMIDE, MOLTEN PHOSPHORUS OXYBROMIDE, SOLID PHOSPHORUS OXYCHLORIDE PHOSPHORUS PENTABROMIDE PHOSPHORUS PENTACHLORIDE PHOSPHORUS PENTAFLUORIDE, COMPRESSED PHOSPHORUS PENTASULPHIDE, free from yellow or white phosphorus PHOSPHORUS PENTOXIDE PHOSPHORUS SESQUISULPHIDE, free from yellow or white phosphorus Phosphorus (V) sulphide, free from yellow or white phosphorus PHOSPHORUS SULPHOCHLORIDE PHOSPHORUS TRIBROMIDE PHOSPHORUS TRICHLORIDE
see PHOSPHORUS PENTASULPHIDE see 8237 8209 6231 1837 1808 1809 8 8 6.1 II II I Corrosive 8-03 8-03 6.1-02 740 700 700
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE PHOSPHORUS TRIOXIDE PHOSPHORUS TRISULPHIDE, free from yellow or white phosphorus PHOSPHORYL BROMIDE, MOLTEN PHOSPHORYL BROMIDE, SOLID PHOSPHORYL CHLORIDE PHTHALIC ANHYDRIDE with more than 0.05% of maleic anhydride, solid or molten PICOLINES (alpha-, beta-, gamma-) PICRAMIC ACID WETTED with not less than 20% water PICRAMIDE PICRIC ACID, dry or wetted with less than 30% water, by mass PICRIC ACID, WETTED PICRITE, dry or wetted with less than 20% water, by ma ss
IMDG CODE PAGE 8210 4166 see 8206 see 8206 see 8207 8210 3376 see 4121-1 1104 1109 see 4180 1127
UN No. 2578 1343 2576 1939 1810 2214 2313 3317 0153 0154 1344 0282
CLASS 8 4.1 8 8 8 8 3.3 4.1 1.1 D 1.1 D 4.1 1.1 D
Packaging Group III II II II II III III I I
EmS No. 8-06 4.1-03 8-13 8-03 8-03 8-05 * 8-13
MFAG Table No. 700 225 700 700 700 700 325 335

Corrosive
3-02 4.1-01 1-01 1-01 4.1-01 1-01
710 610
* Solid Molten Explosive substance or articles refer to subsection 7.3 of the MFAG.
GENERAL INDEX
UN No. 1336 0155
CLASS
Packaging Group I
EmS No.
MFAG Table No. 610
PICRITE, WETTED with not less than 20% water, by ma ss PICRYL CHLORIDE PINANYL HYDROPEROXIDE (concentration 56100%) PINANYL HYDROPEROXIDE (concentration <56% with diluent type A) Pindone (and salts of) p alphaPINENE PINE OIL PIPERAZINE, SOLID or SOLUTION 1PIPERAZINEETHYLAMINE PIPERIDINE Pinmicarb
p p
4.1 1.1 D
4.101 101
see ORGANIC PEROXIDE TYPE D, LIQUID see ORGANIC PEROXIDE TYPE F, LIQUID see PESTICIDE, N.O.S. 3377 3377 8211 see 8110 82111 2368 1272 2579 2815 2401 3.3 3.3 8 8 8 Ill III III III I Flammable 303 307 805 805 801 313 313 320 325 325
see CARBAMATE PESTICIDE see ORGANOPHOSPHORUS PESTICIDE MATERIAL HAZARDOUS ONLY IN BULK see 62751 2438 6.1 I Corrosive Flammable liquid 6.101 700
Pinmiphos ethyl pp Pitch prill PIVALOYL CHLORIDE Plastic explosives PLASTICS MOULDING COMPOUND in dough sheet or extruded rope form, evolving flammable vapour PLASTICS NITROCELLULOSEBASED SELFHEATING, N.O.S. PLATINIC CHLORIDE, SOLID Polish 9036
see EXPLOSIVE, BLASTING TYPE D 3314 9 III 4.106 none
4252 see 8140
2006 2507
4.2 8
III III see PAINT
4.207 806
610 700
* Explosive substance or article, refer to subsection 7.3 of the MFAG. See section 24 of the General Introduction.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE POLYAMINES, FLAMMABLE, CORROSIVE, N.O.S. - ditto - - ditto - POLYAMINES, LIQUID, CORROSIVE, N.O.S. POLYAMINES, LIQUID, CORROSIVE, FLAMMABLE, N.O.S. POLYAMINES, SOLID, CORROSIVE, N.O.S. POLYCHLORINATED BIPHENYLS pp POLYESTER RESIN KIT - ditto - POLYHALOGENATED BIPHENYLS, LIQUID pp POLYHALOGENATED BIPHENYLS, SOLID p p POLYHALOGENATED TERPHENYLS, LIQUID p p POLYHALOGENATED TERPHENYLS, SOLID p p POLYMERIC BEADS EXPANDABLE, evolving flammable vapour Polystyrene beads, expandable POLYSTYRENE BEADS, EXPANDABLE evolving flammable vapour POTASSIUM POTASSIUM ACID FLUORIDE, SOLID POTASSIUM ACID FLUORIDE, SOLUTION
IMDG CODE PAGE 3106 3182-1 3306 8109-2 8109-1 8109-2 9034 3272 3377-1 9035 9035 9035 9035 9036
UN No. 2733 2733 2733 2735 2734 3259 2315 3269 3269 3151 3152 3151 3152 2211
CLASS
Packaging Group I/II I/I I III I/II/III I/II I/II/III II II III II II II II III
Subsidiary Risk Label(s) Corrosive Corrosive Corrosive Flammable liquid
EmS No.
MFAG Table No. 320 320 320 320 320 760 none * * none none none none none
3.1 3.2 3.3 8 8 8 9 3.2 3.3 9 9 9 9 9
3-02 3-02 3-02 8-05 8-04 8-15 6.1-02 3-07
3-07 6.1-02 6.1-04 6.1-02 6.1-04 4.1-06
see POLYMERIC BEADS EXPANDABLE see 9036 4356 see 8212 see 8212 2211 2257 1811 1811 9 4.3 8 8 III I II II Toxic Toxic 4.1-06 4.3-01 8-06 8-06 none 705 750 750
p pp
or
GENERAL INDEX
IMDG CODE PAGE see 3189 see 3313 see 3111 see 6244
UN No. 2344 2344 1278 2740
CLASS
Packaging Group II III II I
Subsidiary Risk Label(s) Flammable liquid Corrosive Flammable liquid Corrosive Toxic
EmS No.
MFAG Table No. 345 345 340 740
PROPYL BROMIDES - ditto PROPYL CHLORIDE normal-PROPYL CHLOROCARBONATE
3.2 3.3 3.1 6.1
3-07 3-07 3-07 6.1-01
normal- PROPYL CHLOROFORMATE PROPYL CYANIDE PROPYLENE PROPYLENE ACETYLENE AND ETHYLENE MIXTURE, REFRIGERATED LIQUID PROPYLENE CHLOROHYDRIN PROPYLENEDIAMINES (1,2 or 1,3 ) PROPYLENE DICHLORIDE PROPYLENEIMINE, INHIBITED PROPYLENE OXIDE PROPYLENE TETRAMER PROPYLENE TRIMER - ditto normal-PROPYL ETHER - ditto PROPYL FORMATES PROPYLFORMIC ACID PROPYLIDENE DICHLORIDE* PROPYL IODIDES
6244 see 3197 2147
2740 2411 1077
6.1 3.2 2(2.1)
I II
6.1-01 3-03 2-07
740 215 310
see ETHYLENE ACETYLENE AND PROPYLENE MIXTURE, REFRIGERATED LIQUID 6245 8217 see 3206 3274 3143 3378 see 3287 see 3391 see 3120 see 3218 3275 see 8133 see 3230 see 3353 2611 2258 1279 1921 1280 2850 2057 2057 2384 2384 1281 2820 1993 2392 6.1 8 3.2 3.2 3.1 3.3 3.2 3.3 3.1 3.2 3.2 8 3.2 3.3 II II II I I III II III II II II III II III Flammable liquid Flammable liquid Toxic 6.1-01 8-04 3-07 3-02 3-06 3-07 3-07 3-07 3-06 3-06 3-06 8-05 3-07 3-07 740 320 340 320 365 310 310 310 330 330 330 700 340 345
* PROPYLIDENE DICHLORIDE(1,1- DICHLOROPROPANE) should be shipped under the entry FLAMMABLE, LIQUID, N.O.S in class 3.2.
GENERAL INDEX
IMDG CODE PAGE 6245-1 see 3142 see 3275 3276 8218
UN No. 2482 2402 1281 1865 1816
CLASS
Packaging Group I II II II II
Subsidiary Risk Label(s) Flammable liquid Flammable liquid
EmS No.
MFAG Table No. 370 375 330 235 700
normal-PROPYL ISOCYANATE PROPYL MERCAPTAN

p
6.1 3.1 3.2 3.2 8
6.1-01 3-07 3-06 3-07 8-01
PROPYL METHANOATES normal-PROPYL NITRATE PROPYLTRICHLOROSILANE Prothoate p PRUSSIC ACID, ANHYDROUS, STABILIZED, containing less than 3% water p PRUSSIC ACID, ANHYDROUS, STABILIZED, containing less than 3% water and absorbed in a porous inert material p PRUSSIC ACID, AQUEOUS SOLUTION p PRUSSIC ACID, AQUEOUS SOLUTION with not more than 20% hydrogen cyanide p PYRAZINE HEXAHYDRIDE, SOLID or SOLUTION Pyrazophos p p Pyrazoxon PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C c.c. PYRETHROID PESTICIDE, LIQUID, TOXIC PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint between 23 C and 61 C c.c.
see ORGANOPHOSPHORUS PESTICIDE see 6163 1051 6.1 I Flammable liquid 6.1-01 645
see 6163 see 6162 see 6162 see 8211
1614 1613 1613 2579
6.1 6.1 6.1 8
I I I III
6.1-01 6.1-01 6.1-01 8-05
645 645 645 320
see ORGANOPHOSPHORUS PESTICIDE see ORGANOPHOSPHORUS PESTICIDE 3270 6219 6220 3350 3352 3351 3349 3.2 6.1 6.1 6.1 I/II I/II/III I/II/III I/II/III Toxic Flammable liquid 3-03 6.1-02 6.1-02 6.1-04 510 510 510 510

6221
PYRETHROID, PESTICIDE, SOLID, TOXIC
p pp
or
GENERAL INDEX
IMDG CODE UN PAGE No. 3277 1282
CLASS
Packaging Group II
EmS No.
MFAG Table No. 325
PYRIDINE Pyntic ash PYROPHORIC ALLOY, N.O.S. PYROPHORIC ARTICLES PYROPHORIC LIQUID, INORGANIC, N.O.S. PYROPHORIC LIQUID, ORGANIC, N.O.S. PYROPHORIC METAL, N.O.S. PYROPHORIC ORGANOMETALLIC COMPOUND (liquid), WATER-REACTIVE, N.O.S. PYROPHORIC ORGANOMETALLIC COMPOUND (solid) WATER-REACTIVE, N.O.S. PYROPHORIC SOLID, INORGANIC, N.O.S. PYROPHORIC SOLID, ORGANIC, N.O.S. PYROSULPHURIC ACID PYROSULPHURYL CHLORIDE PYROXYLIN SOLUTION - ditto - ditto PYRROLIDINE
3.2
3-02
MATERIAL HAZARDOUS ONLY IN BULK * 4255 1383 4.2 I 4.2-02 760,
see ARTICLES PYROPHORIC 4254 4254 4255 4254 3194 2845 1383 3203 4.2 4.2 4.2 4.2 I I I I Dangerous when wet Dangerous when wet Toxic Corrosive 4.2-01 4.2-01 4.2-02 4.2-01 760, 760, 760, 760,
4255 4255 4255 see 8231 8218 see 3138 2 see 3265 see 3369 3277
3203 3200 2846 1831 1817 2059 2059 2059 1922
4.2 4.2 4.2 8 8 3.1 3.2 3.3 3.2
I I I I II I/II III II
4.2-01 4.2-01 4.2-01 8-06 8-03 3-05 3-05 3-05 3-02
760, 760, 760, 700 700 610 610 610 325
* See section 24 of trie General Introduction. In addition, refer to subsection 4.3 of the MFAG.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE Quicklime, dolomitic Quinalphos

p
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
MFAG Table No.
MATERIAL HAZARDOUS ONLY IN BULK * see ORGANOPHOSPHORUS PESTICIDE see 6164 see 6164 6246 see 6082 2662 2662 2656 2587 6.1 6.1 6.1 6.1 III III III II 6.102 6.104 6.101 6.104 710 710 335,610 300
QUINOL, LIQUID QUINOL SOLID QUINOLINE QUINONE QUIZALOFOP pp QUIZALOFOPPETHYL pp
see Section 23.1.5 of the General Introduction see Section 23.1.5 of the General Introduction
* See section 24 of the General Introduction.

p pp
or

GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
RECEPTACLES, SMALL CONTAINING GAS, without a release device not refillable REFRIGERANT GAS, N.O.S. REFRIGERANT GAS R 12 REFRIGERANT GAS R 12B1 REFRIGERANT GAS R 13 REFRIGERANT GAS R 13B1 REFRIGERANT GAS R 14, COMPRESSED REFRIGERANT GAS R 21 REFRIGERANT GAS R 22 REFRIGERANT GAS R 23 REFRIGERANT GAS R 32 REFRIGERANT GAS R 40 REFRIGERANT GAS R 41 REFRIGERANT GAS R 114 REFRIGERANT GAS R 115 REFRIGERANT GAS R 116 COMPRESSED REFRIGERANT GAS R 124 REFRIGERANT GAS R 125 REFRIGERANT GAS R 133a REFRIGERANT GAS R 134a REFRIGERANT GAS R 142b REFRIGERANT GAS R 143a
2175 2176 2129 2117 2122 2109 2182 2130 2118 2184 2132-1 2158 2160 2131 2119 2146 2121 2170-1 2121 2181 2118 2184
2037 1078 1028 1974 1022 1009 1982 1029 1018 1984 3252 1063 2454 1958 1020 2193 1021 3220 1983 3159 2517 2035
2(*) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.1) 2(2.1) 2(2.1) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.1) 2(2.1)
2-13 2-06 2-09 2-09 2-09 2-09 2-09 2-09 2-09 2-09 2-07 2-07 207 2-09 2-09 2-09 2-09 2-09 2-09 2-09 2-07 2-07
350 350 350 350 350 350 350 350 350 350 340 345 350 350 350 350 350 350 350 350 350
* According to properties Class 2.1, 6.20, Class 2.2, 6.20,Class 2.3. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE REFRIGERANT GAS R 152a REFRIGERANT GAS R 161 REFRIGERANT GAS R 218 REFRIGERANT GAS R 227 REFRIGERANT GAS R 404a REFRIGERANT GAS R 407a REFRIGERANT GAS R 407b REFRIGERANT GAS R 407c REFRIGERANT GAS R 500 REFRIGERANT GAS R 502 REFRIGERANT GAS R 503 REFRIGERANT GAS R 1132a REFRIGERANT GAS R 1216 REFRIGERANT GAS R 1318 REFRIGERANT GAS RC 318 REFRIGERATING MACHINES containing non-flammable, non-toxic liquefied gas or ammonia solution (UN 2672) REGULATED MEDICAL, WASTE, N.O.S. RELEASE DEVICES EXPLOSIVE RESIN SOLUTION flammable - ditto - - ditto -
IMDG CODE PAGE 2132 2140 2168 2144-1 2176-1 2176-1 2176-2 2176-2 2129 2119 2122 2132 2146 2167 2167 2176 6320 1287 3143-1 3278 3379
UN No. 1030 2453 2424 3296 3337 3338 3339 3340 2602 1973 2599 1959 1858 2422 1976 2857 3291 0173 1866 1866 1866
CLASS 2(2.1) 2(2.1) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 2(2.1) 2(2.2) 2(2.2) 2(2.2) 2(2.2) 6.2 1.4 S 3.1 3.2 3.3
Packaging Group II I/II I/II III
EmS No. 2-07 2-07 2-09 2-09 2-09 2 09 2-09 2 09 2-09 2-09 2-09 2-07 2-09 2-09 2-09 2-13 * 1-04 3-05 3-05 3-05
MFAG Table No. 350 345 350 350 620 620 620 620 350 350 350 350 345 350 350 350 n/a
310 310 310
* To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from a package containing infectious substances, refer to section 9 of the introduction to class 6.2. Explosive substance or article, refer to subsection 7.3 of the MFAG . Packaging group III under certain conditions. n/a not applicable .
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE Sahthion p SAMPLES, EXPLOSIVE, other than initiating explosive - ditto Sawdust Schradan SEAT BELT PRETENSIONERS, pyrotechnic SEAT-BELT PRETENSIONERS, COMPRESSED GAS secondary (or sec-) SEED CAKE, containing vegetable oil mechanically expelled seeds, containing more than 10% of oil or more than 20% of oil and moisture combined SEED CAKE, containing vegetable oil solvent extractions and expelled seeds, containing not more than 10% of oil and when the amount of moisture is higher than 10%, not more than 20% of oil and moisture combined SEED CAKE, containing vegetable oil, solvent extractions containing not more than 1.5% of oil and 11% of moisture SEED EXPELLERS, oily - ditto - ditto SELENATES
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see ORGANOPHOSPHORUS PESTICIDE 1134 1298 0190 0190 1(*) 1(*)

MATERIAL HAZARDOUS ONLY IN BULKS see ORGANOPHOSPHORUS PESTICIDE 9022-1 3268 9 Ill ** none none
2102-1
3353
2.2
**
This prefix is not taken into account in determining the alphabetical order of entries see under the next part of the name shown in capital letters
4257
1386
4.2
4.2-05
none
4258
1386
4.2
4.2-05
none
4259 see 4257 see 4258 see 4259
2217 1386 1386 2217 2630
4.2 4.2 4.2 4.2 6.1
4.2-05 4.2-05 4.2-05 4.2-05 6.1-04
none none none none 175
6249
As appropriate To be declared by the shipper after assignment by the competent authority, who should allocate a schedule or develop a new schedule in a similar format to the existing schedules. Explosive substance or article, refer to subsection 7.3 of the MFAG. See section 24 of the General Introduction. No label required. ** To be declared by the shipper.
p pp
or
GENERAL INDEX
IMDG CODE PAGE 8220
UN No. 1905
CLASS
Packaging Group I I I I/II/III II
Subsidiary Risk Label(s) Toxic Corrosive Flammable gas Toxic Corrosive Corrosive
EmS No.
MFAG Table No. 175, 700 175, 700 175 175 175, 225 175, 750 175 175, 700 * * *
SELENIC ACID SELENINYL CHLORIDE SELENITES
8 8 6.1 6.1 6.1 2(2.3)
8-06 8-06 6.1-04 6.1-021 6.1-042 6.1-04 2-08
see 8220 2879 6249 6249-1 6249 2177 see 2151 8220 4259-2 4259-2 4259-1 2630 3283 2657 2194
SELENIUM COMPOUND, N.O.S. SELENIUM DISULPHIDE SELENIUM HEXAFLUORIDE
SELENIUM HYDRIDE SELENIUM OXYCHLORIDE SELF HEATING LIQUID, CORROSIVE, INO RGANIC, N.O.S. SELF-HEATING LIQUID, CORROSIVE, ORGANIC, N.O.S. SELF-HEATING LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, ORGANIC, N.O.S. SELF-HEATING LIQUID, TOXIC, INORGANIC, N.O.S. SELF-HEATING LIQUID, TOXIC, ORGANIC, N.O.S. SELF-HEATING SOLID, CORROSIVE, INO RGANIC, N.O.S. SELF-HEATING SOLID, CORROSIVE, ORGANIC, N.O.S.
2202 2879 3188 3185 3186
2(2.3) 8 4.2 4.2 4.2
I II/III II/III II/III
2-05 8-06 4.2-04 4.2-04 4.2-04
4259-1 4259-2 4259-2 4261 4261
3183 3187 3184 3192 3126
4.2 4.2 4.2 4.2 4.2
II/III II/III II/III II II
Toxic Toxic Corrosive Corrosive
4.2-04 4.2-04 4.2-04 4.2-04 4.2-04
* * 760 760
* If an MFAG Table No is not supplied by the shipper refer to subsection 4.2 of the MFAG. In addition refer to subsection 4.3 of the MFAG. For liquids. 2 For solids.
1
p pp
or
GENERAL INDEX
IMDG CODE PAGE
UN No.
CLASS
Packaging Group II III III II III III III II II II II II II II I II III I I
EmS No.
MFAG Table No. 306, 705 306, 705 540 705 235 235 235 235 100 705 711 735 745 715 735 735 700 205 710,* 710
SODIUM METHYLATE, SOLUTIONS in alcohols - ditto SODIUM MONOCHLOROACETATE SODIUM MONOXIDE SODIUM NITRATE SODIUM NITRATE AND POTASSIUM NITRATE, MIXTURE SODIUM NITRITE SODIUM NITRITE AND POTASSIUM NITRATE, MIXTURE SODIUM ORTHOARSENATE SODIUM OXIDE SODIUM PENTACHLOROPHENATE
pp
3280 3381 see 6255 8226 5180 5181 5181 see 5171 see 6253 see 8226 6259 see 5185 5182 5183 5184 5185 5185 4363 1107 4173
1289 1289 2659 1825 1498 1499 1500 1487 1685 1825 2567 3247 1502 1503 1504 3247 1505 1432 0235 1349
3.2 3.3 6.1 8 5.1 5.1 5.1 5.1 6.1 8 6.1 5.1 5.1 5.1 5.1 5.1 5.1 4.3 1.3 C 4.1
Corrosive Corrosive Toxic Toxic
3-04 3-04 6.1-04 8-06 5.1-06 5.1-06 5.1-06 5.1-06 6.1-04 8-06 6.1-04 5.1-06 5.1-06 5.1-06 5.1-04 5.1-06 5.1-06 4.3-02 1-03 4.1-01
SODIUM PERBORATE, ANHYDROUS SODIUM PERCHLORATE SODIUM PERMANGANATE SODIUM PEROXIDE SODIUM PEROXOBORATE, ANHYDROUS SODIUM PERSULPHATE SODIUM PHOSPHIDE SODIUM PICRAMATE, dry or wetted with less than 20% water , by ma ss SODIUM PICRAMATE, WETTED with not less than 20% water, by mass
* Explosive substance or articles refer to subsection 7.3 of the MFAG.

p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE SODIUM POTASSIUM ALLOYS SODIUM SILICOFLUORIDE SODIUM SULPHIDE, ANHYDROUS SODIUM SULPHIDE, HYDRATED with at least 30% water SODIUM SULPHIDE with less than 30% water of crystallization SODIUM SULPHYDRATE - ditto SODIUM SUPEROXIDE SOLIDS CONTAINING CORROSIVE LIQUID, N.O.S. SOLIDS CONTAINING FLAMMABLE, LIQUID, N.O.S. SOLIDS CONTAINING TOXIC, LIQUID, N.O.S. SOUNDING DEVICES, EXPLOSIVE
IMDG CODE PAGE see 4356 see 6250 4263 8227 4263 see 4262 see 8225 5186 8227-1 4173-1 6259-1 1303
UN No. 1422 2674 1385 1849 1385 2318 2949 2547 3244 3175 3243 0374 0375
CLASS 4.3 6.1 4.2 8 4.2 4.2 8 5.1 8 4.1 6.1 1.1 D 1.2 D 1.1 F 1.2 F
Packaging Group I III II II II II II I II II II
EmS No. 4.3-01 6.1-04 4.2-04 8-08 4.2-04 4.2-04 8-05 5.1-04 8-15 4.1-06 6.1-04 1-01 1-02 1-01 1-02
MFAG Table No. 705 750 225, 705 225 225, 705 225 225 735 760
* * * *
- ditto -
1304
0296 0204
Squibs Stain STANNIC CHLORIDE, ANHYDROUS STANNIC CHLORIDE PENTAHYDRATE STANNIC PHOSPHIDE STEEL SWARF 8228 8228 4364 see 4232
see IGNITERS, UN Nos. 0325 and 0454 see PAINT 1827 2440 1433 2793 8 8 4.3 4.2 II III I Toxic 8-03 8-06 4.3-02 4.2-05 700 700 205 none
* Explosive substance or article, refer to subsection 7.3 of the MFAG. If an MFAG number is not supplied by the shipper, refer to subsection 7.3 of the MFAG.
p pp
or
GENERAL INDEX
IMDG CODE PAGE see 3114 see 3203 3144 3282 3385 see 3262
UN No. 2256 2256 2056 2056 2943 2536
CLASS
Packaging Group II II II II III II
EmS No.
MFAG Table No. 310 310 330 330 320 330
TETRAHYDROBENZENE - ditto TETRAHYDROFURAN - ditto TETRAHYDROFURFURYLAMINE TETRAHYDROMETHYLFURAN TETRAHYDRONAPHTHYL HYDROPEROXIDE (concentration -100%) TEFRAHYDRO-1,4-OXAZINE TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% maleic anhydride 1,2,3,6-TETRAHYDROPYRIDINE 1,2,5,6-TETRAHYDROPYRIDINE TETRAHYDROTHIOPHENE TETRAMETHOXYSILANE TETRAME TURIN p TETRAMETHYLAMMONIUM HYDROXIDE, LIQUID or SOLID n-TETRAMETHYLBENZENE p 1,1,3,3-TETRAMETHYLBUTYL HYDROPEROXIDE (concentration - 100%) 1,1,3,3-TETRAMETHYLBUTYL PEROXY2-ETHYL HEXANOATE (concentration -100%) TETRAMETHYLENE TETRAMETHYLENE CYANIDE N,N,N',N'- TETRAMETHYLETHYLENEDIAMINE
3.1 3.2 3.1 3.2 3.3 3.2
3-07 3-07 3-06 3-06 3-02 3-07
see ORGANIC PEROXIDE, TYPE D, SOLID see 3367 8234 3282 3282 3283 see 6198-1 2054 2698 2410 2410 2412 2606 3.3 8* 3.2 3.2 3.2 6.1 III III II II II Flammable liquid 3-02 8-05 3-06 3-06 3-07 6.1-01 322 700 325 325 375 360
see Section 23.1.5 of the General Introduction 8235 1835 8 II 8-05 705
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. see ORGANIC PEROXIDE, TYPE D, LIQUID
see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED see 2127 see 6054 see 3207 2601 2205 2372 2(2.1) 6.1 3.2 Ill II 2-07 6.1-02 3-06 310 215 320
* No label required
p pp
or
GENERAL INDEX
UN No. 1649 2749
CLASS
Packaging Group I I
Subsidiary Risk Label(s) Flammable liquid*
EmS No.
MFAG Table No. 111 none
TETRAMETHYLLEAD p TETRAMETHYLSILANE TETRAMINE PALLADIUM (II) NITRATE (concentration 100%) TETRANITROANILINE TETRANITROMETHANE TETRAPROPYLENE TETRAPROPYL ORTHOTITANATE TETRAZENE, WETTED with not less than 30% water, or mixture of alcohol and water, by mass TETRAZOL-1-ACETIC ACID TETRYL TEXTILE WASTE, WET THALLIUM CHLORATE p Thallium (l) chlorate THALLIUM COMPOUND, N.O.S. THALLIUM NITRATE p Thallium (l) nitrate Thallium sulphate
p p
6.1 3.1
6.1-01 3-07
see SELF-REACTIVE SOLID, TYPE C, TEMPERATURE CONTROLLED 1104 5189 see 3378 3385 1105 1141 1112 4264 5190 0207 1510 2850 2413 0114 0407 0208 2573 1.1 D 5.1 3.3 3.3 1.1 A 1.4 C 1.1 D 4.2 5.1 I III III Ill II Toxic Toxic 1-01 5.1-02 3-07 3-06 1-01 1-04 1-01 4.2-05 5.1-05 335, 335 310 330
700,
none 140,74 5 140 140
see THALLIUM CHLORATE 6265 6265 1707 2727 6.1 6.1 II II Oxidizing agent 6.1-04 6.1-04
see THALLIUM NITRATE see THALLIUM COMPOUND, N.O.S. see 5190 6266 3283 3270 2573 2785 2436 2772 5.1 6.1 3.2 3.2 II III II I/II Toxic Toxic 5.1-05 6.1-01 3-06 3-03 140,74 5 300 700 506
THALLOUS CHLORATE p 4-THIAPENTANAL

p
THIOACETIC ACID THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23C c.c.
If flashpoint 61 C c. c. or below. Explosive substance or article refer to subsection 7.3 of the MFAG.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE THIOCARBAMATE PESTICIDE, LIQUID, TOXIC
IMDG CODE PAGE
UN No.
CLASS
Packaging Group I/II/III
EmS No.
MFAG Table No. 506
6219
3006
6.1
Flammable liquid
6.1-02
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flash point between 23 C and 61 C c.c. THIOCARBAMATE PESTICIDE, SOLID, TOXIC THIOCARBONYL CHLORIDE THIOCARBONYL TETRACHLORIDE THIOGLYCOL THIOGLYCOLIC ACID THIOLACETIC ACID THIOLACTIC ACID Thiometon Thionazin THIONYL CHLORIDE THIOPHENE THIOPHENOL THIOPHOSGENE THIOPHOSPHORYL CHLORIDE THIOPROPYL ALCOHOLS THIOUREA DIOXIDE THORIUM METAL PYROPHORIC - in Type A packages - in Type B(U) packages - in Type B(M) packages - under special arrangement
p p
6220
3005
6.1
I/II/III
6.1-01
506
6221 see 6268 see 6218 6267 8235 see 3283 6267
2771 2474 1670 2966 1940 2436 2936
6.1 6.1 6.1 6.1 8 3.2 6.1
I/II/III II I II II II II
6.1-04 6.1-02 6.1-02 6.1-02 8-05 3-06 6.1-02
506 600 376 375 700 700 375
see ORGANOPHOSPHORUS PESTICIDE see ORGANOPHOSPHORUS PESTICIDE 8236 3284 see 6228 6268 8237 see 3142 4264 7109 7110 7111 7113 1836 2414 2337 2474 1837 2402 3341 2975 2975 2975 2975 8 3.2 6.1 6.1 8 3.1 4.2 7 7 7 7 I II I II II II II/III Flammable liquid Spontaneously combustible Spontaneously combustible Spontaneously combustible Spontaneously combustible 8-03 3-07 6.1-01 6.1 02 8-03 3-07 4.2-04 7-03 7-03 7-03 7-03 635 700 375 375 600 740 375
* * * *
* See subsection 7.4 of the MFAG. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
p pp
or
GENERAL INDEX
SUBSTANCE or ARTICLE THORIUM METAL, PYROPHORIC - in Type A packages - in Type B(U) packages - in Type B(M) packages - under special arrangement THORIUM NITRATE, SOLID - as LSA-I - as LSA-ll - in Type A packages - in Type B(U) packages - in Type B(M) packages - under special arrangement Tin (IV) chloride, anhydrous TIN CHLORIDE, fuming Tin (IV) chloride, pentahydrate TINCTURES, MEDICINAL - ditto - TIN MONOPHOSPHIDE TIN TETRACHLORIDE TITANIC CHLORIDE TITANIUM, SPONGE GRANULES TITANIUM, SPONGE POWDERS
IMDG CODE PAGE 7109 7110 7111 7113 7105 7106 7109 7110 7111 7113
UN No. 2975 2975 2975 2975 2976 2976 2976 2976 2976 2976
CLASS
Packaging Group
Subsidiary Risk Label(s) Spontaneously combustible Spontaneously combustible Spontaneously combustible Spontaneously combustible Oxidizing agent Oxidizing agent Oxidizing agent Oxidizing agent Oxidizing agent Oxidizing agent
EmS No. 7-03 7-03 7-03 7-03 7-05 7-05 7-05 7-05 7-05 7-05
MFAG Table No. * * * * * * * * * *
7 7 7 7 7 7 7 7 7 7
see TIN TETRACHLORIDE see 8228 1827 8 II 8-03 700
see STANNIC CHLORIDE PENTAHYDRATE 3284 3386 see 4364 see 8228 see 8237 4177 4177 1293 1293 1433 1827 1838 2878 2878 3.2 3.3 4.3 8 8 4.1 4.1 II III I II II III III Toxic 3-06 3-06 4.3-02 8-03 8-03 4.1-02 4.1-02 305 305 205 700 700 none none
* See subsection 7.4 of the MFAG

p pp
or

GENERAL INDEX
IMDG CODE PAGE 4264-1 4176 4265 4176
UN No. 3174 18/1 2546 1352
CLASS
Packaging Group III II I/II/III II
Subsidiary EmS No. Risk Label(s) 4.2-05 4.1-06 4.2-02 4.1-02
MFAG Table No. * none none none
TITANIUM DISULPHIDE TITANIUM HYDRIDE TITANIUM POWDER, DRY TITANIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present) (a) mechanically produced having a particle size less than 53 microns, or (b) chemically produced having a particle size less than 840 microns TITANIUM TETRACHLORIDE TITANIUM TRICHLORIDE, PYROPHORIC TITANIUM TRICHLORIDE MIXTURE nonpyrophoric TITANIUM TRICHLORIDE MIXTURE, PYROPHORIC TITANOUS CHLORIDE, PYROPHORIC TNT, dry or wetted with less than 30% water, by mass TNT, WETTED TNT AND HEXANITROSTILBENE, MIXTURE TNT AND TRINITROBENZENE, MIXTURE TNT, MIXTURE CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE Toe puffs nitrocellulose base
4.2 4.1 4.2 4.1
8237 4266 8238 4266 see 4266 1144 see 4181 1104 1104 1104 see 4144 1
1838 2441 2869 2441 2441 0209 1356 0388 0388 0389 1353
8 4.2 8 4.2 4.2 1.1 D 4.1 1.1 D 1.1 D 1.1 D 4. 1
II I II/III I I I Ill
Corrosive Corrosive Corrosive
8-03 4.2-04 8-06 4.2-04 4.2-04 1-01 4.1-01 1.01 1.01 1-01 4.1-06
700 700 700 700 700
335

610
* If an MFAG numbei is not supplied by the shipper, refer to subsection 4.2 of the MFAG. Explosive substance or article, refer to subsection 7.3 of the MFAG.
GENERAL INDEX
BSTANCE or ARTICLE TOLUENE TOLUENE DIISOCYANATE TOLUENE TRICHLORIDE TOLUIDINES (ortho-, meta-, para- ), LIQUID or SOLID TOLUOL 2,4-TOLUYLENEDIAMINE, LIQUID 2,4-TOLUYLENEDIAMINE, SOLID TOLUYLENE DIISOCYANATE TOLYLENE DIISOCYANATE TORPEDOES, LIQUID-FUELLED, with inert head TORPEDOES, LIQUID-FUELLED, with or without bursting charge TORPEDOES with bursting charge - ditto - ditto TOXIC LIQUID, CORROSIVE, INORGANIC, N.O.S. TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S. TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. TOXIC LIQUID, INORGANIC, N.O.S. TOXIC LIQUID, ORGANIC, N.O.S. TOXIC LIQUID, OXIDIZING, N.O.S. TOXIC LIQUID, WATER-REACTIVE, N.O.S.
IMDG CODE PAGE 3285 6269 see 8122 6270 see 3285 6270 6270 see 6269 see 6269 1308 1308 1306 1305 1307 6270-2 6270-2 6270-3 6270-1 6270-1 6270-4 6270-5
UN No. 1294 2078 2226 1708 1294 1709 1709 2078 2078 0450 0449 0451 0329 0330 3289 2927 2929 3287 2810 3122 3123
CLASS 3.2 6.1 8 6.1 3.2 6.1 6.1 6.1 6.1 1.3 J 1.1 J 1.1 D 1.1 E 1.1 F 6.1 6.1 6.1 6.1 6.1 6.1 6.1
Packaging Group II II II II II III III II II I/II I/II I/II I/II/III I/II/III I/II I/II
EmS No. 3-07 6.1-02 8-05 6.1-02 3-07 6.1-02 6.1-04 6.1-02 6.1-02 1-03 1-01 1-01
MFAG Table No. 310 370 340 335 310 335 335 370 370 * *
* *
Corrosive Corrosive Flammable liquid Oxidizing agent Dangerous when wet
1-01 1-01 6.1-02 6.1-02 6.1-01 6.1-02 6.1-02 6.1-02 6.1-07
Explosive substance or article, refer to subsection 7.3 of the MFAG. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG.
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE TOXIC SOLID, CORROSIVE, INORGANIC,
IMDG CODE PAGE
UN No.
CLASS
Packaging Group I/II I/II I/II I/II/III I/II/III I/II I/II I/II I/II/III
EmS No.
MFAG Table No. * * * * * * *

+
N.O.S.
TOXIC SOLID, CORROSIVE, ORGANIC,
62707 62707 62708 62706 62706 62704 62705 62705 62709 1309
3290 2928 2930 3288 2811 3086 3124 3125 3172 0212 0306
6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 6.1 1.3 G 1.4 G
Corrosive Corrosive Flammable solid Oxidizing agent Spontaneously combustible Dangerous when wet
6.104 6.104 6.103 6.104 6.104 6.104 6.108 6.107 6.102 1 6.104 2 103 104
N.O.S.
TOXIC SOLID, FLAMMABLE, ORGANIC,
N.O.S.
TOXIC SOLID, INORGANIC, N.O.S. TOXIC SOLID, ORGANIC, N.O.S. TOXIC SOLID, OXIDIZING, N.O.S. TOXIC SOLID, SELFHEATING, N.O.S. TOXIC SOLID, WATERREACTIVE,
N.O.S.
TOXINS, EXTRACTED FROM LIVING SOURCES, N.O.S. TRACERS FOR AMMUNITION trans TREMOLITE Triadimefon TRIALLYLAMINE TRIALLYL BORATE Triamiphos TRIARYL PHOSPHATES, N.O.S. pp TRIARYL PHOSPHATES, ISOPROPYLATED p
This prefix is not taken into account in determining the alphabetical order of entries, see under the next part of the name shown in capital letters see 9024 2590 9 III 6.104 none
see PHENOXY PESTICIDE 3387 6271 2610 2609 3.3 6.1 III III Corrosive 302 6.101 320 240
see ORGANOPHOSPHORUS PESTICIDE see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. Explosive substance or article, refer to subsection 7.3 of the MFAG. For liquids. 2 For solids.
1
p pp
or

GENERAL INDEX
BSTANCE or ARTICLE TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC, flashpoint less than 23 C c.c.
IMDG CODE PAGE
UN No.
CLASS
Packaging Group I/II I/II/III I/II/III I/II/III
EmS No.
MFAG Table No. 530 530 530 530
3270 6219 6220 6221
2764 2998 2997 2763
3.2 6.1 6.1 6.1
Toxic Flammable liquid
3-03 6.1-02 6.1-01 6.1-04
TRIAZINE PESTICIDE, LIQUID, TOXIC
TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE, flashpoint between 23 and 61 C c.c. TRIAZINE PESTICIDE, SOLID, TOXIC Triazophos
p
see ORGANOPHOSPHORUS PESTICIDE see 8127

p
TRIBROMOBORANE TRIBROMOMETHANE
2692 2515 3051 2542 3254
8 6.1 4.2 6.1 4.2
I III I II I
8-03 6.1-02 4.2-01 6.1-02 4.2-04
245 345 170 320 760
see 6088 see 4221 6271 4266-1
TRIBUTYLALUMlNIUM TRIBUTYLAMINE TRIBUTYLPHOSPHANE Tributyltin compounds Tricamba Trichlorfon

p pp
see ORGANOTIN PESTICIDE see BENZOIC DERIVATIVE PESTICIDE see ORGANOPHOSPHORUS PESTICIDE see 6097 8239 8239 see 6097 8240 6271-1 6272
p
TRICHLOROACETALDEHYDE, ANHYDROUS, INHIBITED TRICHLOROACETIC ACID, SOLID TRICHLOROACETIC ACID, SOLUTION TRICHLOROACETIC ALDEHYDE, ANHYDROUS, INHIBITED TRICHLOROACETYL CHLORIDE TRICHLOROBENZENES, LIQUID TRICHLOROBUTENE p TRICHLOROBUTYLENE
p
2075 1839 2564 2075 2442 2321 2322 2322
6.1 8 8 6.1 8 6.1 6.1 6.1
II II II/III II II III II II
6.1-02 8-06 8-06 6.1-02 8-02 6.1-02 6.1-02 6.1-02
300 700 700 300 700 340 340 340
see 6272
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE 6272-1
UN No. 2831
CLASS
Packaging Group III
EmS No.
MFAG Table No. 340
1,1,1-TRICHLOROETHANE 1,1,2-TRICHLOROETHANE TRICHLOROETHYLENE TRICHLOROISOCYANURIC ACID, DRY TRICHLOROMETHANE TRICHLOROMETHANESULPHURYL CHLORIDE p TRICHLOROMETHYL SULPHOCHLORIDE p Trichloronat
p
61
6.1-02
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 6273 5190 see 6103 see 6218 see 6218 1710 2468 1888 1670 1670 6.1 5.1 6.1 6.1 6.1 III II III I I 6.1-02 5.1-05 6.1-02 6.1 02 6.1 02 340 740 340 376 376
see ORGANOPHOSPHORUS PESTICIDE see 6108 4365-1 see 8155 see 5190 1580 1295 26/-0 2468 6.1 4.3 8 5.1 I I II II Corrosive Flammable liquid 6.1-02 4.3-05 8-06 5.1-05 740 700 740 740
TRICHLORONITROMETHANE TRICHLOROSILANE 2,4,6-TRICHLORO-1,3,5-TRIAZINE 1,3,5-TRICHLORO-s -TRIAZINE 2,4,6TRIONE TRICRESYL PHOSPHATE, less than 1% ortho-isomer p TRICRESYL PHOSPHATE, not less than 1% but not more than 3% ortho-isomer pp TRICRESYL PHOSPHATE with more than 3% ortho-isomer p p TRICYANOGEN CHLORIDE TRIETHOXYBORON TRIETHOXYM ETHANE TRIETHYLALUMINIUM TRIETHYLAMINE
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 6274 see 8155 see 3222 see 3344 see 4221 3285 2574 2670 1176 2524 3051 1296 6.1 8 3.2 3.3 4.2 3.2 II II II III I || Dangerous when wet Corrosive 6.1-02 8-06 3-06 3-07 4.2-01 3-02 355 740 240 330 170 320
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE TRIETHYLBENZENE TRIETHYL BORATE TRIETHYLENEPHOSPHORAMIDE, SOLUTION TRIETHYLENETETRAMINE TRIETHYL ORTHOFORMATE TRIETHYL PHOSPHITE TRIFLUOROACETIC ACID TRIFLUOROACETYL CHLORIDE TRIFLUOROBROMOMETHANE TRIFLUOROCHLOROETHANE TRIFLUOROCHLOROETHYLENE, INHIBITED TRIFLUOROCHLOROMETHANE 1,1,1-TRIFLUOROETHANE TRIFLUOROMETHANE TRIFLUOROMETHANE, REFRIGERATED LIQUID TRIFLUOROMETHANE AND CHLOROTR IFLUOROMETHANE, AZEOTROPIC MIXTURE TRIFLUOROMETHOXYTRIFLUOROETHYLENE 2-TRIFLUOROMETHYLANILINE 3-TRIFLUOROMETHYLANILINE TRIFLUOROMETHYLBENZENE TRIFLUOROMETHYLPHENYL ISOCYANATES
p
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see 3222 see 6276 8240 see 3344 3387 8241 2183 see 2109 see 2121 2183 see 2122 2184 2184 2184-1 1176 2501 2259 2524 2323 2699 3057 1009 1983 1082 1022 2035 1984 3136 3.2 6.1 8 3.3 3.3 8 2(2.3) 2(2.2) 2(2.2) 2(2.3) 2(2.2) 2(2.1) 2(2.2) 2(2.2) II II/III II III III I Corrosive Flammable gas 3-06 6.1-02 8-05 3-07 3-07 8-05 2-08 2-09 2-09 2-07 2-09 2-07 2-09 2-12 240 205 320 330 330 750 700 350 350 350 350 350 350 620
see CHLOROTRIFLUOROMETHANE AND TRIFLUOROMETHANE, AZEOTROPIC MIXTURE see 2171 6275 6275 see 3185 see 6168 3153 2942 2948 2338 2285 2(2.1) 6.1 6.1 3.2 6.1 Ill II II II Flammable liquid * 2-07 6.1-02 6.1-02 3-07 6.1-01 * 6.1-02 620, 615 335 335 345 370
* If flashpoint 61 C c.c. or below. If flashpoint higher than 61 C c.c.

p pp
or
GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE
UN No.
CLASS
Packaging Group I III
EmS No.
MFAG Table No. 620, 615 350 170 310
TRIFLUOROMETHYL TRIFLUOROVINYL ETHER TRIFLUOROMONOCHLOROETHYLENE, INHIBITED TRIISOBUTYLALUMINIUM TRIISOBUTYLENE TRIISOPROPYLATED PHENYL, PHOSPHATES p TRIISOPROPYL BORATE - ditto TRIMETHYLACETYL CHLORIDE
see 2171 see 2183 see 4221 3388
3153 1082 3051 2324
2(2.1) 2(2.3) 4.2 3.3
Flammable gas Dangerous when wet
2-07 2-07 4.2-01 3-07
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 3286 3389 6275-1 2616 2616 2438 3.2 3.3 6.1 II III I Flammable liquid, Corrosive Dangerous when wet Corrosive Corrosive Corrosive 3-06 3-06 6.1-01 240 240 700
TRIMETHYLALUMINIUM TRIMETHYLAMINE, ANHYDROUS TRIMETHYLAMINE, AQUEOUS SOLUTION, not more than 30% trimethylamine, by mass - ditto TRIMETHYLAMINE, AQUEOUS SOLUTION, 30% to 50% trimethylamine, by mass 1,2,3-TRIMETHYLBENZENE p 1,2,4-TRIMETHYLBENZENE
p
see 4221 2185 3286 3389-1 3145
3051 1083 1297 1297 1297
4.2 2(2.1) 3.2 3.3 3.1
I I/II III I/II
4.2-01 2-06 3-02 3-02 3-02
170 320 320 320 320
see Section 23.1.5 of the General Introduction see Section 23.1.5 of the General Introduction 3389-1 3287 see 3191 3145 8242 see 6102 2325 2416 1120 1298 2326 2688 3.3 3.2 3.2 3.1 8 6.1 III II II II III III Corrosive 3-03 3-06 3-06 3-04 8-05 6.1-02 310 240 305 700 320 345
1,3,5-TRIMETHYLBENZENE p TRIMETHYL BORATE TRIMETHYL CARBINOL TRIMETHYLCHLOROSILANE TRIMETHYLCYCLOHEXYLAMINE TRIMETHYLENE CHLOROBROMIDE
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE TRIMETHYLENE CHLOROHYDRIN TRIMETHYLENE DICHLORIDE - ditto - TRIMETHYLHEXAMETHYLENEDIAMINES TRIMETHYLHEXAMETHYLENE DIISOCYANATE 2,2,4-TRIMETHYLPENTANE 2,4,4-TRIMETHYLPENTENE-1 2,4,4-TRIMETHYLPENTENE-2 2,4,4-TRIMETHYLPENTYL-2PEROXYNEODECANOATE (concentration -72%, with diluent type A) 2,4,4-TRIMETHYLPENTYL-2PEROXYNEODECANOATE (concentration -52% as a stable dispersion in water) 2,4,4-TRIMETHYLPENTYL-2PEROXYPHENOXYACETATE (concentration -37%, with diluent type B) TRIMETHYL PHOSPHITE 2,4,6-TRIMETHYL-1,3,5-TRIOXANE TRINITROANILINE TRINITROANISOLE TRINITROBENZENE, dry or wetted with less than 30% water, by mass TRINITROBENZENE, WETTED with not less than 30% water, by mass TRINITROBENZENESULPHONIC ACID
*
IMDG CODE PAGE see 6110 see 3230 see 3345 8243 6276 see 3267 see 3210 see 3210
UN No. 2849 1993 1993 2327 2328 1262 2050 2050
CLASS 6.1 3.2 3.3 8 6.1 3.2 3.2 3.2
Packaging Group III II III III III II II II
EmS No. 6.1-02 3-07 3-07 8-05 6.1-02 3-07 3-07 3-07
MFAG Table No. 740 340 340 320 370 310 310 310
see ORGANIC PEROXIDE, TYPE D, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED
see ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED 3390 see 3372 1104 1104 1104 4178 1104 2329 1264 0153 0213 0214 1354 0386 3.3 3.3 1.1 D 1.1 D 1.1 D 4.1 1.1 D III III I 3-07 3-06 1-01 1-01 1-01 4.1-01 1-01 330 300

335 700,
TRIMETHYLENE DICHLORIDE (1,3-DICHLOROPROPANE) under a flashpoint of less than 23 C should be shipped under the entry FLAMMABLE LIQUID, N.O.S.in class 3.2. TRIMETHYLENE DICHLORIDE (1,3-DICHLOROPROPANE) with a flashpoint of 23 C or higher should be shipped under the entry FLAMMABLE LIQUID, N.O.S.in class 3.3. Explosive substance or article, refer to subsection 7.3 of the MFAG.
GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE
UN No.
CLASS
Packaging Group I I
MFAG Table No. 335, 700 * 335, 700 * * * * * * 710 * *
TRINITROBENZOIC ACID, dry or wetted with less than 30% water, by mass TRINITROBENZOIC ACID, WETTED with not less than 30% water, by mass TRINITROCHLOROBENZENE TRINITRO-meta-CRESOL TRINITROFLUORENONE TRINITRONAPHTHALENE TRINITROPHENETOLE TRINITROPHENOL, dry or wetted with less than 30% water, by mass TRINITROPHENOL, WETTED with not less than 30% water, by mass TRINITROPHENYLMETHYLNITRAMINE TRINITRORESORCINOL, dry or wetted with less than 20% water or mixture of alcohol and water , by mass TRINITRORESORCINOL, WETTED with not less than 20% water or mixture of alcohol and water, by mass TRINITROTOLUENE, dry or wetted with less than 30% water, by mass TRINITROTOLUENE, WETTED with not less than 30% water, by mass TRINITROTOLUENE AND HEXANITROSTILBENE MIXTURES TRINITROTOLUENE AND TRINITROBENZENE MIXTURES TRINITROTOLUENE MIXTURES, CONTAINING TRINITROBENZENE AND HEXANITROSTILBENE
1142 4179 1104 1109 1104 1104 1104 1109 4180 1112 1109
0215 1355 0155 0216 0387 0217 0218 0154 1344 0208 0219
1.1 D 4.1 1.1 D 1.1 D 1.1 D 1.1 D 1.1 D 1.1 D 4.1 1.1 D 1.1 D
1-01 4.1-01 1-01 1-01 1 01 1-01 1-01 1 01 4.1-01 1-01 1-01
1143
0394
1.1 D
1-01
1144 4181 1104 1104
0209 1356 0388 0388
1.1 D 4.1 1.1 D 1.1 D
1-01 4.1-01 1-01 1-01
* 335 * *
1104
0389
1.1 D
1-01
GENERAL INDEX
BSTANCE or ARTICLE
UN No. 1356
CLASS
Packaging Group I
EmS No.
MFAG Table No. 335
TRINITROTOLUOL, WETTED Triphenyltin compounds (other than fentin acetate and fentin hydroxide) TRIPHENYL PHOSPHATE pp TRIPHENYL PHOSPHATE/tertBUTYLATED TRIPHENYL PHOSPHATES, MIXTURES containing 5 to 10% of TR IPHENYL PHOSPHATE p TRIPHENYL PHOSPHATE/tert BUTYLATED TRIPHENYL PHOSPHATES, MIXTURES containing 10 to 48% of TRIPHENYL PHOSPHATE p p TRIPROPYLALUMINIUM TRIPROPYLAMINE TRIPROPYLENE - ditto TRIS-(1-AZIRIDINYL)PHOSPHINE OXIDE, SOLUTION TRITOLYL PHOSPHATE pp TRITONAL TRIXYLENYL PHOSPHATE TROPILIDENE TUNGSTEN HEXAFLUORIDE TURPENTINE
p p pp
4.1
4.1-01
see ORGANOTIN PESTICIDE see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
see 4221 3390 3287 3391 6276 see 6274 1104
3051 2260 2057 2057 2501 2574 0390
4.2 3.3 3.2 3.3 6.1 6.1 1.1 D
I III II III II/III II
Dangerous when wet Corrosive
4.2-01 3-02 3-07 3-07 6.1-02 6.1-02 1-01
170 320 310 310 205 355 *
see ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. see 3202 2185 3391
2603 2196 1299 1300 1300
3.2 2(2.3) 3.3 3.2 3.3
II Ill II III
Toxic Corrosive
3-03 2-08 3-07 3-07 3-07
310 750 313 311 311
TURPENTINE SUBSTITUTE - ditto -
3271 3375
Explosive substance or article, refer to subsection 7.3 of the MFAG. WHITE SPIRIT, low aromatic (15%-20%) is a MARINE POLLUTANT
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE
p
IMDG CODE PAGE see 3288 3288 see 3288 8244
UN No. 2058 2058 2058 2502
CLASS
Packaging Group II II II II
Subsidiary Risk Label(s) Flammable liquid *
EmS No.
MFAG Table No. 300 300 300 700
normaI -VALERALDEHYDE VALERALDEHYDES VALERIC ALDEHYDES
3.2 3.2 3.2 8
3-06 3-06 3-06 8-01
normal-VALERYL CHLORIDE Vamidothion VANADIUM COMPOUND, N.O.S. Vanadium ore Vanadium (IV) oxide sulphate VANADIUM OXYSULPHATE VANADIUM OXYTRICHLORIDE VANADIUM PENTOXIDE, non-fused form VANADIUM TETRACHLORIDE VANADIUM TRICHLORIDE VANADYL SULPHATE Varnish VEGETABLE FABRICS, oily VEGETABLE FIBRES, burnt, wet or damp VEGETABLE FIBRES, DRY VEGETABLE FIBRES, oily VINYL ACETATE, INHIBITED VINYLBENZENE, INHIBITED p
see ORGANOPHOSPHORUS PESTICIDE 6276-1 3285 6.1 I/II/III 6.1-02 1 6.1-04 2 135
MATERIAL HAZARDOUS ONLY IN BULK see VANADIUM SULPHATE see 6278 8244 6277 8245 8246 6278 see PAINT see 4233 see 4233 see 4144 see 4233 3289 see 3381 2931 2443 2862 2444 2475 2931 1373 1373 1301 2055 6.1 8 6.1 8 8 6.1 4.2 4.2 4.1 4.2 3.2 3.3 II II III I III II III III Ill II III 6.1-04 8-03 6.1-04 8-03 8-06 6.1-04 4.2-05 4.2-05 4.1-06 4.2-05 3-07 3-07 135, 700 135 135 135, 700 135, 700 135, 700 none none none none 330 310
* If flashpoint between 23C and 61 C c.c. See section 24 of the General Introduction. No label required. 1 For liquids. 2 For solids.
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE 2186 see 3196 3289 2186 2186 6278 see 3173 see 3120 3146 2187 3146 see 2132 3290 2187 6279
UN No. 1085 2352 2838 1086 1086 2589 1093 1167 1302 1860 1303 1959 1304 1087 3073
CLASS
PackSubsidiary aging EmS No. Risk Label(s) Group II II II I I I I II II Flammable liquid Toxic Flammable liquid Corrosive Corrosive 2-07 3-06 307 2-07 2-07 6.1-01 3-02 3-02 3-07 2-07 3-07 2-07 3-06 2-07 6.1-01
MFAG Table No. 345 330 330 340 340 540 215 330 330 350 340 350 330 330 325
VINYL BROMIDE, INHIBITED VINYL normaI-BUTYL ETHER, INHIBITED VINYL BUTYRATE, INHIBITED VINYL CHLORIDE, INHIBITED VINYL CHLORIDE, STABILIZED VINYL CHLOROACETATE VINYL CYANIDE, INHIBITED VINYL ETHER, INHIBITED VINYL ETHYL ETHER, INHIBITED VINYL FLUORIDE, INHIBITED VINYLIDENE CHLORIDE, INHIBITED p VINYLIDENE FLUORIDE VINYL ISOBUTYL ETHER, INHIBITED VINYL METHYL ETHER, INHIBITED VINYLPYRIDINES, INHIBITED VINYLTOLUENES, INHIBITED (ortho-, meta-, para-) p VINYLTRICHLOROSILANE, INHIBITED
2(2.1) 3.2 3.2 2(2.1) 2(2.1) 6.1 3.2 3.1 3.1 2(2.1) 3.1 2(2.1) 3.2 2(2.1) 6.1
3392 3290
2618 1305
3.3 3.2
III I
3-02 3-04
310 700
p pp
or

GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
Warfarin (and salts of) p WARHEADS, ROCKET, with burster or e xpelling charge - ditto WARHEADS, ROCKET, with bursting charge - ditto WARHEADS, TORPEDO, with bursting charge Warheads for guided missiles WATER-ACTIVATED CONTRIVANCES WATER GAS, COMPRESSED Water gels WATER-REACTIVE LIQUID, N.O.S. WATER-REACTIVE LIQUID, CORROSIVE, N.O.S. WATER-REACTIVE LIQUID, TOXIC, N.O.S. WATER REACTIVE SOLID, N.O.S. WATER-REACTIVE SOLID, CORROSIVE, N.O.S. WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. WATER-REACTIVE SOLID, TOXIC, N.O.S. WHITE ARSENIC WHITE ASBESTOS WHITE PHOSPHORUS, DRY pp 4366 4367 4367 4368 4369 4369 4369 see 6078 see 9024 see 4249 see 2114 1312 1313 1310 1311 1314
see COUMARIN DERIVATIVE PESTICIDE 0370 0371 0286 0287 0369 0221 1.4 D 1.4 F 1.1 D 1.2 D 1.1 F 1.1 D 1-04 1-04 1-01 1-02 1-01 1-01 * * * *
see WARHEADS, ROCKET see CONTRIVANCES, WATER-ACTIVATED 2600 2(2.3) Flammable gas 2-01 616
see EXPLOSIVE, BLASTING, TYPE E 3148 3129 3130 2813 3131 3132 3134 1561 2590 1381 4.3 4.3 4.3 4.3 4.3 4.3 4.3 6.1 9 4.2 I/II/III I/II/III I/II/III I/II/III I/II/III I/II/III I/II/III II III I Corrosive Toxic Corrosive Flammable solid Toxic Toxic 4.3-08 4.3-08 4.3-08 4.3-08 4.3-08 4.3-08 4.3-08 6.1-04 6.1-04 4.2-04
760

760
100 none 200
* Explosive substance or article, refer to subsection 7.3 of the MFAG. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. In addition, refer to subsection 4.3 of the MFAG. p pp , or see explanatory notes in the introduction to this index.
GENERAL INDEX
BSTANCE or ARTICLE WHITE PHOSPHORUS, WET pp WHITE SPIRIT * - ditto Woodchips WOOD PRESERVATIVES, LIQUID - ditto - Wood pulp, pellets WOOL WASTE, WET
IMDG CODE PAGE see 4250 see 3271 see 3375
UN No. 1381 1300 1300
CLASS
Packaging Group I II III
Subsidiary Risk Label(s) Toxic
EmS No.
4.2 3.2 3.3
4.2-04 3-07
3-07
MATERIAL HAZARDOUS ONLY IN BULK
3291 3393
1306 1306
3.2 3.3
II III
3-05 3-05
310, 310,
MATERIAL HAZARDOUS ONLY IN BULK 4264 4.2 III 4.2-05 none
* WHITE SPIRIT, low aromatic (15%-20%) is a MARINE POLLUTANT . See section 24 of the General Introduction. In addition, refer to subsection 4.3 of the MFAG.
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE 4266-2 2188 2188
UN No. 3342 2036 2591
CLASS
Packaging Group II/III
EmS No.
MFAG Table No.
XANTHATES XENON, COMPRESSED XENON, REFRIGERATED LIQUID Xenon and nitrogen mixtures Xenon and oxygen mixture Xenon in rare gases mixtures meta-XYLENE ortho-XYLENE para-XYLENE XYLENES - ditto XYLENOLS, LIQUID XYLENOLS, SOLID p XYLIDINES, SOLID or LIQUID XYLOLS - ditto XYLYL BROMIDE YELLOW PHOSPHORUS, DRY
pp p
4.2 2(2.2) 2(2.2)
4.2-04 2-09 2-12
none 350
see RARE GASES AND NITROGEN MIXTURES see RARE GASES AND OXYGEN MIXTURE see RARE GASES MIXTURES see 3394 see 3292 see 3394 3292 3394 6280 6280 6280 see 3292 see 3394 6281 see 4249 see 4250 1307 1307 1307 1307 1307 2261 2261 1711 1307 1307 1701 1381 1381 3.3 3.2 3.3 3.2 3.3 6.1 6.1 6.1 3.2 3.3 6.1 4.2 4.2 Ill II III II III II II II II III II I I Toxic Toxic 3-07 3-07 3-07 3-07 3-07 6.1-02 6.1-04 6.1-02 3-07 3-07 6.1-02 4.2-04 4.2-04 310 310 310 310 310 710 710 335 310 310 345 200 200
YELLOW PHOSPHORUS, WET pp
p pp
or
GENERAL INDEX
BSTANCE or ARTICLE
IMDG CODE PAGE
UN No.
CLASS
Packaging Group
EmS No.
MFAG Table No.
ZINC, dust ZINC, powder ZINC AMMONIUM NITRITE ZINC ARSENATE ZINC ARSENATE AND ZINC ARSENITE MIXTURE ZINC ARSENITE ZINC ASHES ZINC BISULPHITE, SOLUTION ZINC BROMATE ZINC BROMIDE
p
see ZINC DUST see ZINC POWDER 6282 6282 6282 4371 see 8126 5192 1512 1712 1712 1712 1435 2693 2469 6.1 6.1 6.1 4.3 8 5.1 CARRIAGE PROHIBITED II II II III III III 6.1-04 6.1 04 6.1 04 4.3-06 8-08 5.1-06 100 100 100 none 635 745
see ENVIRONMENTALLY HAZARDOUS, SUBSTANCE, SOLID, N.O.S. 5192 8247 8247 6282 see 4230 see 4231 9037 4371 4373 see 4255 see 4230 1513 2331 1840 1713 1366 1370 1931 1435 1436 1383 1366 5.1 8 8 6.1 4.2 4..2 9 4.3 4.3 4.2 4.2 II III III I I I III III II/III I I Dangerous when wet Dangerous when wet Spontaneously combustible Dangerous when wet 5.1-06 8-06 8-06 6.1-04 4.2-01 4.2-01 4.2-04 4.3-06 4.3-06 4.2-02 4.2-01 745 145 145 215 170 170 635 none none none 170
ZINC CHLORATE ZINC CHLORIDE, ANHYDROUS ZINC CHLORIDE, SOLUTION ZINC CYANIDE ZINC DIETHYL ZINC DIMETHYL ZINC DITHIONITE ZINC DROSS ZINC DUST, non-pyrophoric ZINC DUST, PYROPHORIC ZINC ETHYL
p
p pp
or
UN Nos. / IMDG CODE PAGE Nos. / EmS Nos. / MFAG TABLE Nos.
UN No.
... 0
... 1
... 2
... 3
... 4
... 5 32691, 3373-1, 3-06, 3-05
... 6 3183, 3308, 3-02, 320
... 7
... 8
... 9
110...
3105-1, 3-03, 340
3184, 3-07, 375
3310, 3-07, 235
3107, 3184, 3-07, 235 3191, 3314, 3-07, 330 3102, 3174, 3302, 3-05, 330 6114-1, 6.1-01, 300
3307, 3-07, 330
3183, 3-07, 340
3140, 3-07, 310
3309, 3-07, 330
111...
3310, 3-07, 300 3191, 3314, 3-06, 3-05 3318, 3-07, 331
3185, 3-03, 312
3192, 3-02, 320
3187, 3-07, 345 3200, 3321, 3-07, 310
3110, 3198, 3-07, 340
3193, 3-06, 330
3196, 3-07, 300 3112, 3200, 3321, 3-05, 310 3328, 3-07, 330
112...
3109, 3-01, 210

3329, 3-07, 340
3318, 3-07, 340
113...
6150, 6.1-01, 740
3326, 3-07, 310
3203-1, 3327, 3-06, 3-05
114...
3205, 3-07, 340

3213, 3-07, 330
3113, 3-07, 310
3114, 3-07, 310
3115, 3-07, 310
115...
3340, 3-07, 330
3116, 3-02, 320
3117, 3-07, 330
3208, 3-07, 300
3333, 3-07, 300
3210, 3-02, 320
3117, 3-02, 330
116...
3118, 3212, 3-02, 320 3219, 3337-1, 3-06, 3-05*
3214, 3-04, 700
6132, 6.1-01, 720
3119, 3-07, 225
3217, 3-06, 330
3217, 3-06, 330
3120, 3-02, 330
3223, 3-07, 300
3229, 3344, 3-06, 3-05
117...
3341, 3-06, 330
3341, 3-06, 330
3220, 3-07, 330
3224, 3-03, 340
3222, 3-07, 310
3222, 3-06, 240
3339, 3-07, 330
3223, 3-07, 330
118...
3339, 3-07, 330
6147, 6.1-01, 540
6148, 6.1-01, 740
4342, 4.3-05, 700
6151, 6.1-01, 320
3228, 3-04, 700
3229, 3344, 3-06, 3-05
3342, 3-06, 330
3342, 3-06, 330
119...
3123, 3-07, 330
3343, 3-07, 300
3343-1, 3-06, 330
3226, 3-06, 300
3124, 3227, 3-02, 235
3228, 3-07, 330
3347, 3-06, 300
6155, 6.1-01, 300
NOTE: * 305-306 for ALCOHOL DENATURED for ALCOHOL INDUSTRIAL and for METHYLATED SPIRITS
UN No.
...0
...1 3234, 3348, 3-06, 3-05
...2
...3
...4
...5
...6
...7
...8
...9
120...
3141-1, 3272-1, 3377-1, 3-05, 311 3245,
3375, 3-07, 311
3141, 3-07, 311
3265-2, 3-06, 235

3253, 3-02, 320
3235, 3-07, 310
3350, 3-07, 300
3129, 3-07, 310
3244, 3-06, 3-05
121...
3133, 3-02, 320
3354, 3-06, 3-05
3239, 3-07, 330
3239, 3-02, 320
3243, 3-07, 310

3255, 3-07, 330
3133, 3-07, 310 3135,
3247, 3-07, 235
3375, 3-07, 311
3248, 3360, 3-07, 300
122...
3-07, 330

3258, 3-07, 300
3249, 3361, 3-03*, 375 6193, 61-01, 740
3362, 3-06, 300
3251, 123... 3-06, 3-06
3252, 3-06, 330
4355, 43-05, 700
3364, 3-07, 330
3136, 3-06, 330
6194, 61-01, 340
124...
3262, 3-04, 700
6198-2, 61-01, 300
3137, 3-06, 330
6196, 61-01, 720
3257, 3-07, 300
3259, 3-07, 330
3261, 3-07, 330
3261, 3-07, 300
125.
3267, 3-07, 310
3139, 3268, 3372, 3-05, 310, 313
3372, 3-06, 300
3140, 3-07, 310
3269, 3374, 3-05, 3-05
3141.3271, 3375, 3-07, 311
3141, 3271, 3375, 3-07, 311
6202, 6, 1-01, 165
126...

3143, 3-06, 365
3370, 3-06, 335
3206, 3-07, 340 3280,
127...
3275, 3-06, 330
3377, 3-07, 313

3284, 3386, 3-06, 3-05
3272-1, 3377-2, 3-06, 3-05
3142, 1, 3-06, 300
3274, 3-07, 330
3143, 3-02, 320
3111, 3-07, 340
3277, 3-02, 325
128...
3285, 3-07, 310
4365-1, 43-05, 700
3278, 3380, 3-07, 310
3279, 3380, 3-05, 310 3145,
3271,3375, 3-07, 311
3381, 3-04, 3-06, 705
129...
3384, 3-06, 360
3285, 3-02, 320
3286, 3389-1, 3-02, 320
3145, 3-04, 700
3391, 3-07, 313
NOTE: * 3-07 for class 3.3
UN No.
...0 3271, 3375, 3-07, 311 4122, 4.1-01, 710 4140, 4.1-01, 710 4153, 4.1-06, none 4355-3, 4.3-03, 225 4174, 4.1-06, none 4338, 4.3-02, 205 4231, 4.2-01, 170 4248-1, 4.2-01, 245 4323, 4.3-05, 705
...1
...2
...3
...4
...5
...6 3291, 3393, 3-05, 310*
...7 3292, 3394, 3-07, 310
...8 3147, 3293, 3395, 3-07, 310* 4135, 4.1-06, none 4150, 4.1-06, 320 4165, 4.1-06, none 4172, 4.1-01, 710 4184, 4.1-02, none
...9
130
3289, 3-07, 330
3146, 3-07, 330
3146, 3-07, 340
3290, 3-06, 330
3290, 3-04, 700
4121, 4.1-02, none
131
4139, 4.1-01, 710 4155, 4.1-06, 200 4166, 4.1-03, 225
4130, 4.1-06, 3-05 4141, 4.1-01, 710 4157, 4.1-03, 300
4132, 4.1-06, 705 4144, 4.1-06, none 4133, 4.1-06, none 4166, 4.1-03, 225 4144-1, 4.1-06, 610 4227, 4.2-05, none 4233, 4.2-05, none 4255, 4.2-02, 760* 4325, 4.3-04, 705
4132, 4.1-06, 705 4145, 4.1-06, 610 4158, 4.1-05, 314 4180, 4.1-01, 710 4178, 4.1-01, 335 4228, 4.2-05, none 4234,4235, 4.2-05, none 4262, 4.2-04, 635,700 4327, 4.3-03, none
4146, 4.1-05
4148, 4.1-02, none 4162, 4.1-01, 610 4170, 4.1-02, none 4181, 4.1-01, 335 4230, 4.2-01, 170 4238, 4.2-04, none 4257, 4258, 4.2-05, none 4330, 4.3-06, none
4149, 4.1-06, none 4163-1, 4.1-01, 610 4170, 4.1-01, 710 4182, 4.1-01, 610

4165, 4.1-03, 225 4173, 4.1-01, 710
132
133
4167, 4.1-06, none 4179, 4.1-01, 335, 700 4229, 4.2-05, none
134
4176, 4.1-02, none 4224, 4.2-05, none
135
4224, 4.2-05, none
4247, 4.2-04, 335 4248, 4.2-05, none 4322, 4.3-04, 705
136

4329, 4.3-02, 205
4246, 4.2-05, none
137
4249, 4250, 4.2-04, 200 4324, 4.3-01, 705
4253, 4.2-04, 225 4326, 4.3-04, 705
4263, 4.2-04, 225, 705 4327, 4.3-03, 605, 601
138
4331, 4.3-03, none
139
NOTES: * In addition, refer to subsection 4.3 of the MFAG. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
UN No.
8 4343, 4.3-03, 601, 605 4353, 4.3-06, none 4360, 4.3-01, 705 5121, 5.1-06, 235 5129, 5.1-05, 715 5141, 5.1-06, 745
4332, 140 4.3-04, 120 43451, 141 4.3-01, 160 4356, 142 4.3-01, 705
4335, 4.3-04, 705 4346, 4.3-01, 160, 330 4321, 4.3-01, 705 4263, 42-08, 705
4335, 4.3-03, 705
4336, 4.3-03, 705 4347, 4.3-04, 245 4359, 4.3-01, 705 4364, 4.3-02, 205
4337, 4.3-04, 705 4348, 4.3-01, 160
4339, 4.3-03, 705 4345, 4.3-01, 160

4361, 4.3-04, 245 4373, 4.3-06, none 5128, 5.1-05, 120 5140, 5.1-06, 715 5148, 5.1-06, 700 5160, 5.1-04, 735 5171, 5.1-06, 235 5180, 5.1-06, 741
4334, 4.3-01, 705 4349, 4.3-03, 160 4362, 4.3-01, 705 4185, 4.1-06, none 5129, 5.1-05, 120, 745 5140, 5.1-04, 735 5148, 5.1-06, 235 5162, 5.1-05, 235 5171, 5.1-06, 235
4354-1, 4.3-01, 760* 4350, 4.3-02, 205
4356, 4.3-01, 705 4363, 4.3-02, 205 5126, 5.1-09, 745 5134, 5.1-06, 745 5144, 5.1-05, 741 5157, 5.1-04, 160, 735 5167-1, 5.1-05, 715 5175, 5.1-06, 700

5126, 5.1-06, 725 5139, 5.1-06, 235
4371, 4.3-06, none 5127, 5.1-05, 120, 745 5139, 5.1-06, 745 5147, 5.1-06, none 5159, 5.1-06 745 5169, 5.1-06, 745 5178, 5.1-06, 745
5121, 5.1-06, 155 5130, 5.1-04, 120, 735 5141, 5.1-06, 745 5154, 5.1-05, 110 5163, 5111, 760* 5172, 5.1-06, 745 5181, 5.1-06, 235
143

5131, 5.1-05, 745
144
5134, 5.1-06, none 5142, 5.1-05, 745 5156, 5.1-06, 160, 741 5166, 5.1-05, 745 5174, 5.1-04, 735
5136, 5.1-06, 741 5145, 5.1-05, 700 5158, 5.1-06, 745 5168, 5.1-04, 735 5177, 5.1-06, 235
145
146
5155, 5.1-05, 110, 745
5159, 5.1-06, 235 5169, 5.1-06, 745 5178, 5.1-06, 745

5172, 5.1-06, 235 5180, 5.1-06, 235
147
148
5173, 5.1-06, 715
149
NOTES: * In addition, refer to subsection 4.3 of the MFAG. 5.1-02 for SOLUTIONS
UN No.
9 6270, 6.1-02, 6.1-04, 335 8136, 8-06, 705 8115, 8-02, 700 8124, 8-03, 740 2117, 2-08, 750 8151, 8-15, 760 8166, 8-02, 700 8177, 8-05, 700 8183, 8-03, 700 8198, 8-02, 700
6261, 170 6.1-03, 740 6273, 171 6.1-02, 340
6281, 6.1-02, 345 6280, 6.1-02, 335
6263, 6.1-02, 340 6282, 6.1-04, 100 6060, 6.1-01, 740 8117, 8-03, 130 8128, 8-05, 750 6099, 6.1-02, 700 8155, 8-02, 700 6282, 6.1-04, 215 3182, 3-03, 345 8118, 8-06, 8-03 , 130 8129, 8-05, 750 8140, 8-02 700 8156, 8-02, 700 8173, 8-06, 700 8180, 8-05, 320 8188, 8-05, 700
6264,
*
6.1-02, 505 4372, 43-02, 205 8107, 8-01, 700
8101, 8-02, 700 8109, 8-06, 700 8123, 8-02, 700 5133, 5.1-01, 750 8145, 8-06, 750 8159, 8-02, 700 8175, 8-06, 700 8184, 8-03, 750 8194, 803, 700
6265, 6.1-04, 140 3172, 3-04, 700 8112, 8-06, 750 6083, 6.1-02, 740 8133, 8-01, 700 8145, 8-06, 750 8161, 8-01, 700 8176, 8-03, 750 8182, 8-03, 700
6270, 6.1-02, 335 8132, 8-05, 700 8115, 8-01, 700 6083, 6.1-02, 740 5137, 51-06, 741 8146, 8-03, 155 8163, 8-06, 700 8176, 8-06, 750 8183, 8-03, 700 8197, 8-03, 700
8101, 8-04, 700 8108, 8-06, 700
172
8116, 8-03, 130 8184-1,
8116, 8-03, 130 2107, 2-08, 700 6097-1, 6.1-04, 540 8154, 8-06, 320 8167, 8-02, 700 8179, 8-02, 700 8186, 8-08 741
173
8130, 8-03, 740 8144, 8-03, 700 8158, 8-05, 700 8174, 8-06, 700 8181, 8-02, 700 8189, 8-08, 700
5132, 5.1-01, 750 8144, 8-03, 700 8158, 8-02, 700 8175, 8-06, 750
174
8-06, 750 6097-1,
175
6.1-02, 540 8147,
176
8-15, 760 8166,
177
8-02, 345 8177,
8179, 8-06, 750 8187, 8-03, 740
178
8-02, 700 8184,
179
8-03, 750
NOTES: * This UN number should not be used for sea transport. Use appropriate N.O.S. entry in class 2. Liquid or solutions. In addition, refer to subsection 4.3 of the MFAG.
UN No.
180
8199, 8-02, 700
8199, 8-02, 700
8200, 8-03, 700 6242, 6.1-02*, 6.1-04, 750
8201, 8-06, 700
8203, 8-02, 700
8204, 8-08, 700
8208, 8-03, 700
8208, 8-06, 700
8209, 8-03, 700
6231, 61-02, 700
181
8207, 8-03, 700
8212, 8-06, 750
8214, 8-06, 705
8214, 8-06, 705
3273, 3-04, 700
8218, 8-01, 700
8218, 8-03, 700
8221, 8-03, 700
8222, 8-06, 705
182
8230, 8-06, 700
8231, 8-06, 700
8232, 8-06, 700
8225-1, 8-06, 705
8226, 8-06, 705
8226, 8-06, 705
8194, 8-03, 700 8236, 8-03, 635, 700 6096, 6.1-02, 340
8228, 8-03, 700
8229, 8-02, 740
8233, 8-06, 700
183
8232, 8-06, 700 6064, 6.1-02*, 6.1-03, 710
8233, 8-03, 700
8235, 8-05, 705
8237, 8-03, 740
8237, 8-03, 700
8239, 8-06, 700
184
8247, 8-06, 145
9021, 8-07, 320

3224, 3-07, 300
4255, 4.2-02, 120
9025, 8-08, 615
8215, 8-07, 225
8216, 8-04, 700
8227, 8-08, 225
185
2187, 2-07, 350
6172-1, 6.1-02
3141, 3271, 3375, 3-07, 311 5167, 5.1-02, 700
4255, 4.2-02, 705
4256, 4.2-05, none 3143-1, 3278, 3379, 3-05, 310

6088, 6.1-02, 345
2146, 2-09, 345
2178, 2-08, 750
186
4176, 4.1-06, none

6081, 6.1-04, 705
3276, 3-07, 235
4136, 4.1-03, 245
4153, 4.1-02, none
187
4357, 4.3-04, 245
5154, 5.1-06 110
6081, 6.1-04, 335
6084, 6.1-02, 340
6103, 6.1-02, 340
6117, 6.1-04, 645
188
6146, 6.1-01, 345
6149, 6.1-02, 101
189
6230, 6.1-04, 105
6230, 6.1-04, 105
6264, 6.1-02, 340
8102, 8-02, 700
NOTES: * Solutions If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
UN No.
190
2128, 2-05, 245
8163, 8-05, 700
8167, 8-06, 760*
3317, 3-07, 330
8220, 8-06, 175, 700 3322, 3-07, 300
8221, 8-06, 700
8222, 8-06, 705
8137, 8-06, 741
3252, 3-03, 330 4253, 4.2-04, 635, 700 8206, 8-03, 700
191
2159, 2-07, 340
2161, 2-12, 620
6126, 6.1-01, 340
3220, 3-07, 330
3357, 3-07, 310 4355-1, 4.3-01, 170, 330 8131, 8-05, 8-06, 700
192
3371, 3-07, 310
3274, 3-02, 320
3277, 3-02, 325
4223 4.2-04, 635

4155, 4.1-06, none
6116, 6.1-02, 215

2124, 2-04, 620

2127, 2-02, none
193
8235, 8-05, 700
9037, 4.2-04, 635
4269, 4.2-02, none

2125-1 2-01
194
9027, 6.1-02, 350
5122, 5.1-06, 610
4156, 4.1-06, none
2131, 2-09, 350
2132, 2-07, 350
195
2102, 2-13, 620
2105, 2-12, 620 2135, 2-10, 310, 620 2156, 2-02, 620
2138-1, 2-08, 365
2124, 2-02, 620
2125, 2-03
196
2153, 2-12, 620
2138, 2-07, 310
2144, 2-12, 620
2147, 2-02, 310
2147, 2-07, 310
2148, 2-10, 620
2152, 2-06
2152, 2-09, none
2147, 2-07, 310
197
2156, 2-10, 620
2119, 2-09, 350
2117, 2-09, 350
2162, 2-08, 610
2167, 2-09, 350 3104, 3176, 3303, 3-07, 3-05
2163, 2-12, 620 3175, 3303, 3-06, 3-05
2147, 2-07, 310 3105, 3178, 3305, 3-07, 300
2174, 2-04, none 3105, 3177, 3305, 307, 300 3281, 3382, 3-05, 311
198
2175, 2-04, none
2174, 2-04, none
2182, 2-09, 350 3127, 3232, 3346-1, 3-07
2121, 2-09, 350
2184, 2-09, 350
199
9024-1, 6.1-02, 300
3110, 3-01, 340
3126,3230, 3345, 3-07
6165, 6.1-01, 165
NOTES: * In addition, refer to subsection 4.3 of the MFAG. Classified as hazardous for air transport only. Solution. 3 MFAG Table No. 620 for classes 2.1 and 2.2 only. For substances in class 2.3 and aerosols with a capacity of 1000 cm or less, if an MFAG table number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
UN No.
200
4133, 4.1-06, 610 4351, 4.3-01, none 6107, 6.1-04, 711 8182, 8-11, 720
4135, 4.1-06, none 4352, 4.3-02, 205 6107, 6.1-02, 711 8195, 803, 610*, 700
4226, 4.2-05, 610 4358, 4.3-02, 205 6114, 6.1-02, 710 8196, 8-03, 610, 700
4243, 4.2-01, 170 4365, 4.3-02, 205 6143, 6.1-01, 740 8215, 8-06, 705
4240, 4.2-01, 725 5151, 5.1-02, 735 6180, 6.1-02, 105 2149, 2-02, none 2147, 2-07, 310 3367, 3-02, 322
4241, 4.2-01, 170 5152, 5.1-02, 735 6181, 6.1-04, 105 2184, 2-07, 350 3130, 3-07, 300 3381, 3-07, 310
4252, 4.2-07, 610 6067, 6.1-02, 740 6229, 6.1-04, 105 2188, 2-09, none 3325, 3-07, 310 3144, 3282, 3-06, 330
6067, 6.1-02 740 6254, 6.1-04, 100
4268, 4.2-02, none 6100, 6.1-03, 335 8127, 8-05, 700 6137, 6.1-01, 6.1-03, 335 3330, 3-07, 310 3288, 3-06, 300 5123, 51-06, 610 6269, 6.1-02, 370
4267, 4.2-02, none 6100, 6.1-02, 335 8181, 801, 720
201
202
203
2175, 2-13 3206, 3330, 3-07, 340 3287, 3391, 3-07, 310 5123, 5.1-06, 610 6200, 6.1-02, 6.1-04, 320
3331-1, 3-07, 310 3138-2, 3265, 3369, 3-05, 610 5123, 5.1-06, 610 8161, 8-05, 320
204
3210, 3-07, 310
8164, 8-04, 320
3336, 3-07, 310
3366, 3-02, 3-05
205
206
5123, 5.1-06, 610
9023, 5.1-06, 610
5124, 5.1-06, 610
2104-1, 2-08, 725
6054, 6.1-02, 6.1-04, 323
6097, 6.1-02, 300
6114, 6.1-02, 710
207
208
209
NOTES: * Concentration over 70%. MFAG Table No. 620 for classes 2.1 and 2.2. For class 2.3, if an MFAG table number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. Solution or liquid.
UN No.
0 6195,
1 3137-1, 3-07, 330 6223, 6.1-02, 335 6271-1, 6.1-02, 340 8247, 8-06, 145 3313, 3-06, 345 3195, 3316, 3-06, 235 3332, 3-03, 320 3132, 3-07, 310 3215, 3-07, 225 3238, 3-07, 345
2 3366, 3-07, 300 6224, 6.1-02, 710 6272, 6.1-02, 340 3301, 3-06, 320 3188, 3-07, 345 3196, 3-06, 330 3205, 3-03, 340 3207, 3-06, 320 6131-1, 6.1-01, 720 3353, 3-07, 345
3 3357, 3-07, 310 3376, 3-02, 325 3387, 3-07, 330 3180, 3-02, 330 3189, 3-07, 345 3197, 3-04, 700 3123, 3-07, 375 3116, 3207, 3-06, 330 3218, 3-02, 320 3240, 3-07, 330
4 4158, 4.1-04, 314
5 8197, 8-05, 700 9034, 6.1-02, none 3389-1, 3-03, 310 3181, 3-03, 330 3190, 3-07, 345
6 6208, 6.1-02, 335 6256, 6.1-04, 215 8242, 8-05, 320 3181, 3-03, 330 3190, 3-06, 300 3111, 3-07, 340 3332, 3-07, 330 3209, 3-06, 310 3227, 3-02, 325 3250, 3-02, 300
7 6209, 6.1-02, 335 6256, 6.1-02, 215 8243, 8-05, 320 6228, 6.1-01, 375 3108, 3194, 3-07, 375 8156, 8-04, 320 3263, 3-07, 300 3118, 3211, 3-06, 330 3233, 3-07, 345 3254, 3-07, 300
8 8198, 803, 700 4262, 4.2-04, 225 6276, 6.1-02, 370 3185, 3-07, 345 3315, 3-03, 330 3203, 3-07, 310 3377, 3-03, 313 3334, 3-02, 215 3233, 3-07, 345 3136, 3-07, 330
9 3267, 307, 310 3383, 3-07, 310, 313 3390, 3-07, 330 3187, 3-07, 345
230
6.1-02, 325 3373,
231
3-06, 300 8234,
3388, 3-07, 310 6059, 6.1-01, 320 3189, 3313, 3-07, 345 3198, 3-02, 340 3378, 3-07, 310 3208, 3-06, 330 3120, 3218, 3-06, 330 3241, 3-07, 330
232
8-05, 320 3392,
233
307, 310 3188,
234
3-06, 345 3195,
3204, 3-02, 320
235
3-07, 330 3204,

3209, 3-07, 375 3225, 3-07, 330 3242, 3-04, 700
236
3-03, 330 3129,
3212, 3-03, 320 3127, 3-07, 300 3260, 3-02, 325
237
3-07, 310 3214,
238
3-06, none 3238,
239
3-07, 345
UN No.
3258, 240... 3-07, 330 3282, 241... 3-06, 325 2145, 242... 2-08, 750 8103, 243... 8-15, 710 8228, 244... 8-06, 700
8211-1, 8-01, 325 3197, 3-03, 215 2164, 2-08, 610 6069, 6.1-02, 335 4266, 4.2-04, 700 2164, 2-03, 750 3138, 3-07, 310
3142, 3-07, 375 3283, 3-07, 375 2167, 2-09, 350 6130, 6.1-02, 335 8240, 8-02, 700 2136, 2-07, 310
3244, 307, 330 3385, 3-06, 330
3273, 3-02, 215 3284, 3-07, 375 2168, 2-09, 350 8157, 8-02, 700 8245, 8-03, 135,, 700 2160, 2-07, 345 5130, 5.1-05, 125
3358, 3-07, 330
3246, 3-07, 330 3287, 3-06, 240 5125, 51-10, 235 3283, 3-06, 700 6210, 6.1-02, 710 3112, 3-07, 340 5176, 5.1-04, 735
6168-1, 6.1-01, 740 2115, 2-08, 750 5170, 5.1-03, 745 8192, 8-02, 700 4251, 4.2-03, 200 3119, 307, 310
2180, 2-08, 750 5179, 5.1-03, 745 6275-1, 6.1-01, 700 4175, 4.1-04, 635* 3128, 3236, 3-07, 310 5190, 5.1-05, 740 3130,
3247, 3-07, 330 2109, 207, 350 5135, 5.1-03, 745 8223, 8-06, 750

8171, 8-02, 700 4239, 4.2-01, 160, 170 Carriage,
6106, 6.1-02, 335 8244, 8-03, 135 2140, 2-07, 345 4328, 4.3-04, none
3132, 3-07, 310 5192, 5.1-06, 745
245...
3132, 3-07, 310
prohibited
246...

6245-1, 6.1-01, 370
5147, 5.1-06, 740 8246, 8-06, 135, 700 6091, 6.1-01, 370 5153, 5.1-01, 750
6198, 6.1-01, 370
6226, 247... 6.1-02, 215
6215, 6.1-04, 181
6252, 6.1-04, 100
6268, 6.1-02, 600
3240, 3-04, 370 8216, 8-05, 700
3242, 3356-1, 3-04, 370
6197-1, 248... 6.1-01, 370 6127, 249... 6.1-02, 340
3225, 3-04, 370 8169, 8-05, 320
3246, 3-04, 370 3236, 3-02, 320
6091, 6.1-01, 370
6228, 6.1-01, 370
6118, 6.1-01, 370 3384, 3-07, 300
NOTES: * Fire risk only
METHYL NITRITE
UN No.
270...
3336, 3-07, 300 5145-1,

5146, 5.1-06, 745

5157, 5.1-06, 160 6209, 6.1-02*, 6.1-04, 335
6052, 6.1-03, 325 5158, 5.1-06, 745 3106,3306, 3182-1, 3-02, 320 6104, 6.1-01, 740 6145-1, 6.1-02, 335 6221, 6.1-04, 530
4183, 4.1-06, 145 5160, 5.1-06, none 8109-1, 8-04, 320 6104, 6.1-01, 740 6152, 6.1-01, 335 3270, 3-03, 530
8200, 8-05, 305 4121, 4.1-06, none 5161, 5.1-06, none 8109-2, 8-05, 320 6104-1, 6.1-02, 740
6092, 6.1-03, 305 5161, 5.1-06, 235
3215, 3334, 3-06, 330 4132, 4.1-06, 331 6265-1, 6.1-04, 140

5194, 5.1-06, none 6089, 6.1-02, 335 6104-1, 6.1-02, 740 3270, 3-03, 505
3315-1, 3-07, 310 5127, 5.1-05, 1745 6158, 6.1-04, 500 8134, 8-05, 700 3144, 3-07, none 6221, 6.1-04, 100
271...
272...
5.1-06, 155 6207,
273...
6.1-02, 335 6244,
5128, 5.1-05, 741 8162, 8-05, 700 6221, 6.1-04, 500 6221, 6.1-04, 506 6221, 6.1-04, 525
6104-1, 6.1-02, 740
6090, 6.1-02, 740 6221, 6.1-04, 505
6104, 6.1-01, 740 3337, 3-07, 365 3270, 3-03, 500 3270, 3-03, 506 3270, 3-03, 525
274...
6.1-01, 740 6129,
275...
6.1-02, 740 3270,

6221, 6.1-04, 150 6266, 6.1-01, 300 8120, 8-10, 705

3270, 3-03, 150 6221, 6.1-04, 545 8230, 8-06, 700
276...
3-03, 100
6221, 6.1-04, 105 3270, 3-03, 545 8119, 8-06, 705
3270, 3-03, 105 6214, 6.1-02, 545 8202, 8-05, 700
6221, 6.1-03, 515 8100, 8-04, 700 8202, 8-05, 700
277...
3270, 3-03, 515 8100,
6221, 6.1-04, 505 4232, 4.2-05, none
3270, 3-03, 505 8120, 8-10, 700
278...
279...
8-05, 700
NOTE: * Liquids
UN, No.
6 4349, 4.3-05, 160, 725
280.
8121, 8-10, none 6270-1, 6.1-02 8133, 8-05, 700 4347-1, 4.3-03, 160, 605 3317, 3-07, 300 3378, 3-07, 310
8168, 8-04, 760* 6270-6 6.1-04 6225, 6.1-02, 710 6272-1, 6.1-02, 340 3327, 3-03, 320 8129, 8-06, 750 6066, 6.1-04, 135 6071, 6.1-03, 130 4245, 4.2-02, none
8147, 8-08, 740
8178, 8-12, none 4368, 4.3-08 8154, 8-05, 700
6321, not applicable
4348, 4.3-01, 160 8110, 8-05, 325
8113, 8-05, 225
8191, 8-12, none 8114, 8-05, 700 8136, 8-07, 700 6055, 6.1-02, 300 6110, 6.1-02, 740 6066, 6.1-04, 135 8238, 8-06, 700 8220, 8-06, 175, 700
281.
8169, 8-04, 740
8112, 8-06, 750
282.
6110, 6.1-02, 325
8205, 8-08, 700 4337, 4.3-03, 705 6250, 6.1-04, 750 6243, 6.1-04, 135 6156, 6.1-02, 305
4361, 4.3-01, 705 4254, 4.2-01, 760* 6250, 6.1-04, 750 8185, 8-06, none 6160, 6.1-04, 711
8125, 8-08, 700
3289, 3-07, 330
283.
3369, 3-06, 335 4143, 4.1-01, 375 6277, 6.1-04, 135 6120, 6.1-02, 345

6250, 6.1-04, 750 6252, 6.1-04, 135 6122, 6.1-02, 320
4255, 4.2-01, 760* 6250, 6.1-04, 750
284.
2176, 2-13, 350
4183, 4.1-02, none
285.
286.
4222, 4.2-01, 245 5138, 5.1-06, 741
6248, 6.1-04, 710
4177, 4.1-02, none
287.
288.
289.
NOTES: * In addition, refer to subsection 4.3 of the MFAG. Classified as hazardous for air transport only. If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. Emergency procedures to be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from, a package containing infectious substances, refer to section 9 of the introduction to class 6.2.
UN No.
290...
6322 not applicable
2108, 2-08, 740
6219, 6.1-02
6220, 6.1-01,
8139, 805, 711
8139, 8-05, 711

4147, 4.1-03
4151, 4.1-06, 320
, 7-01,
6270-7, 6.1-04

6270-3, 6.1-01
291... 7-07,
8151, 8-15 760 6278, 6.1-04, 135, 700 6155, 6.1-02, 335
7-02
7-02,
3126, 3231, 3346, 3-02, 760 3359, 3-07, 740
4146-1, 4.1-03, 760 3340, 3-07, 740 3254, 3-02, 320
6270-2, 6.1-02
292...
8148, 8-15, 760 6270-8, 6.1-03,
8149, 8-15, 760
8152, 8-15, 760 3364, 3-06, 740 3385, 3-02, 320
6267, 6.1-02, 375 6062, 6.1-02, 320 4131-1, 4.1-05, 335 6267, 6.1-02, 375
6189, 6.1-02, 305 3358, 3-02, 740
293...
6275, 6.1-02, 335
6275, 6.1-02, 335
8225, 8-05, 225
294...
4249, 4.2-04, 310 4351, 4.3-06, none
7-01,
295...
7-05
7-01,

3122, 3-02, 365 6220, 6.1-01, 100
4333, 4.3-05, 750
8229, 8-08, 700
4354, 4.3-05, 506
9026, 6.1-04, 851
296...
706,
7-03,
7-05,
7-04, 750 8142, 8-02, 700 6220, 6.1-01, 530
7-04, 750 4341, 4.3-05, 700 6219, 6.1-02, 530
7-03
297...
298...
5150, 5.1-02, 735 6219, 6.1-02, 100
3199, 3-04, 700 6220, 6.1-01, 500
8143, 8-01, 700 6219, 6.1-02, 500
4152, 4.1-03, 110, 700
299...
9032** none
6220, 6.1-01, 505
6219, 6.1-02, 505
NOTES: * Emergency procedures to be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from, a package containing infectious substances, refer to section 9 of the introduction to class 6.2. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. See section 12 of the introduction to class 7. See subsection 7.4 of the MFAG.
If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG.
In addition, refer to subsection 4.3 of the MFAG.

** EmS to be declared by the shipper.
UN, No.
300
6219, 6.1-02, 150 6219, 6.1-02, 545
6220, 6.1-01, 105 3270, * 3-03
6219, 6.1-02, 105 3192, 3-06, 365
6220, 6.1-01, 515 6213, 6.1-01, 375
6219, 6.1-02, 515 3270, 3-03, 535
6220, 6.1-01, 506 6220, 6.1-01, 525 6220, 6.1-01 535
6219, 6.1-02, 506 6219, 6.1-02, 525 6219, 6.1-02, 535
6220, 6.1-01, 505 6221, 6.1-04, 535
6219, 6.1-02, 505 8119, 8-10, 705
6220, 6.1-01, 150 6220, 6.1-01, 545
301
302

4243, 4.2-01, 170
303

4244, 4.2-01, 170

4221, 4.2-01, 170

4221, 4.2-01, 170

4240, 4.2-01, 170

3323, 3-03, 375 3266, 3-06, 235

8110, 8-07, 320 3174-3, 3304, 3-06, 305

3350, 3-06, 300

2183, 2-08, 700
6061, 6.1-04, 205
304
305

4340, 4.3-06, none 4260, 4.2-04

3250, 3-06, 215 4157, 4.1-02
306
2138-3, 2-09, 350 6167, 6.1-01, 370 9033, 4.1-06, none
6173, 6.1-01, 375
9032,

6279, 6.1-01, 305 2170-1, 2-08, 750 8153, 8-03, 760
4222, 4.2-01, 170 9029, none, none 5165, 5.1-05, 760 6270-4, 6.1-04
307
none 9028, none, none 3363, 3-06, 330
8153, 8-15, 760 8150, 8-15, 760
5164, 5.1-05, 760 8150, 8-15, 760
308
9033, 4.1-06, none
309
8150, 8-15, 760
5164, 5.1-02, 760
5165, 5.1-02, 760
NOTES: * If an MFAG number is not supplied by the shipper, refer to subsection 4.2 of the MFAG. MFAG Table No. 505 for Coumaphos. EmS to be declared by the shipper. In addition refer to subsection 4.3 of the MFAG.
UN No.
310.
5230*, 735 5240, 735
5221, 52-01, 735 5231, 5.2-02, 735
5222, 5.2-01, 735 5232, 5.2-02, 735 6270-4, 6.1-02
5223, 5.2-01, 735 5233, 5.2-02, 735 6270-5, 6.1-07
5224, 5.2-01, 735 5234, 5.2-02, 735 6270-5, 6.1-08
5225, 5.2-01, 735 5235, 5.2-02, 735 6270-5, 6.1-07
5226, 5.2-01, 735 5236, 5.2-02, 735 4261, 4.2-04, 760 2184-1, 2-12, 620 6214, 6.1-04, 545 2125, 204, 620
5227, 5.2-01, 735 5237, 5.2-02, 735
5228, 5.2-01, 735 5238, 5.2-02, 735
5229*, 735
311.
5239, 735
312.
4369, 4.3-08, 760 6070, 6.1-02, 130 9035, 6.1-02, none 2155-1, 2-07, 620

8168, 8-05, 760 2155-1, 2-08, 620 214.2-2, 202
4261, 4.2-04 2137, 2-10, 310, 620 4366, 4.3-08,
4367, 4.3-08, 760 5163, 5.1-11, 760 5149, 5.1-02, 735 2181, 209, 350 21423, 2-03
313.
4367, 4.3-08,
6141, 6.1-02 9035, 6.1-04, none 2155-2, 2-08
6142 6.1-04 2171, 2-07, 620, 615 2155, 2-09, 620
4369, 4.3-08
8103, 8-15, 710 6217, 6.1-04, 711 3174-1, 3-02, 720 4173-1, 4.1-06
314.
6056, 6.1-02, 805 2128, 2-13, none 2155-3, 2-06
6204, 6.1-02, 800 2171, 2-07, 620, 615 2106, 2-13, 620 4264-1, 4.2-05,
315.
214.2-1, 2-12, 620 214.2-3, 2-01
316.
4146-2, 4.1-04,
317.
4330-1, 4.3-04, 725 4146-1, 4.1-03, 760 4260 4.2-04,
6270-9, 6.1-021, 6.1-042
4259-1, 4.2-04,
4259-2, 4.2-04,
4146, 4.1-023, 4.1-054
4147, 4.1-03
318.
4157-1 4.1-06
4157-1, 4.1-06
4259-2, 4204,
42592, 4.2-04
4259-1, 4.2-04
4259-2, 4.2-04,
4260, 4.2-04,
319.
4261, 4.2-04
4261, 4.2-04, 760
4254, 4.2-01, 760
NOTES: *5.2-01 in packagings. 5.2-03 in IBCs. 5.2-05 in tanks. 5.2-02 in packagings. 5.2-04 in IBCs. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG. In addition, refer to subsection 4.3 of the MFAG. Classified as hazardous for air transport only 1 For liquids. 2 For solids. 3 Metals other than metal powders. 4 Other than metals.
UN, No.
320...
4255, 4.2-01, 760* 5142, 5.1-02, 745 2170-1, 2-09, 350 4168-9, 4.1-101, 4.1-122,
5166, 5.1-02, 745 4168, 4.1-10,
5152-1, 5.1-06, 741 4168-1, 4.1-10
4254,4255, 4.2-01, 760* 5131, 5.1-02, 745 4168-2, 4.1-10
5167-1, 5.1-02, 715 4168-3, 4.1-10
4220-1, 4.2-08, 705 5168-1, 5.1-05, 700 4168-4, 4.1-10
4220-1, 4.2-08, 705 5168-1, 5.1-02, 700 4168-5, 4.1-10,
4355-2, 4.3-08,
4354-2, 4.3-08,
4354-3, 4.3-08,
321...
4168-6, 4.1-10
5162, 5.1-02, 235 4168-7, 4.1-10
5162-1, 5.1-06, 235 4168-8, 4.1-101, 4.1-122,
322...
323...
4169, 4.1-11
4169-1, 4.1-11,
4169-2, 4.1-11,
4169-3, 4.1-11,
41694, 4.1-11,
4169-5, 4.1-11
4169-6, 4.1-11,
4169-7, 4.1-11,
4169-8, 4.1-111, 4.1-132
324...
4169-9, 4.1-111, 4.1-132,
4131, 4.1-05, 335 4151-1, 4.1-10, 235 8150-1, 815, 760 3120-1, 3219, 3337-1, 307
*
4122-1, 4.1-10, 240 2132-1, 2-07, 350 8150-1, 815, 760 3218-1, 3337, 307
*
6259-1, 6.1-04
8227-1, 8-15, 760 4266-1, 4.2-04, 760 8147-1, 8-15, 760 3102-1, 3174-2, 3-06
*
9031, , not applicable 4221-1, 4.2-04, 741 8147-1, 8-15, 760 6206-2, 6.1-01, 215
6188, 6.1-02, 700 3336-1, 3-07
5185, 5.1-06, 735
3134-1, 3248-1, 3360-1, 3-07
6172-1, 6.1-04
325...
6097-2, 6.1-09, 540 8150-1, 8-15, 760 4161-1, 4.1-06, none
8166-1, 8-06, 705 8150-1, 815, 760 3138-1, 3264, 3-03, 215
9027-1
9027-2
8109-2, 8-15, 760 3272, 3377-1, 3-07
326...
8147-1, 8-15, 760 6206-1, 6.1-02, 215
8147-1, 8-15, 760 6104-1, 6.1-021, 6.1-042, 740
9022-1, , none 6213-2, 6.1-021, 6.1-042, 505
327...
62132, 6.1-011, 6.1-032, 505
NOTES: 1 For self-reactive substances in packagings. 2 For self-reactive substances in IBCs. * In addition refer to subsection 4.3 of the MFAG. If an MFAG Table No is not supplied by the shipper, refer to subsection 4.2 of the MFAG. To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to or leakage from, a package containing infectious substances refer to section 9 of the introduction to class 6.2. To be declared by the shipper.
UN No.
328...
6213-1, 6.1-021, 6.1-042, 100 6270-7, 6.1-04

*
61871, 6.1-02, 165 6320, , not applicable 8147-2, 8-02, 760
62131, 6.1-021, 6.1-042

*
6249-1, 6.1-021, 6.1-042, 175 6161-1, 6.1-02, 720
6262-1, 6.1-021, 6.1-042

*
6276-1, 6.1-021, 6.1-042, 135 3129-1, 3237, 3352, 3-07, 310 2125-2, 2-01
*
3126-1, 3232-1, 3-03

*
6270-1, 6.1-02
*
62706, 6.1-04
*
6270-2, 6.1-02
*
329...
4332-1, 4.3-09, 705
6163-1, 6.1-01, 215
2144-1, 2-09, 350
2138-2, 2-09, 350
21384, 2-09, 350
2138-4, 2-09, 350
330...
2138-2, 2-06, 365
6130-1, 6.1-02, 330
2125-3, 2-03
*
2125-1, 2-03
*
2125-3, 2-03
*
21554, 2-08
*
2155-2, 2-08
*
2155-3, 2-06
*
331...
2155-4, 2-08
*
2142-2, 2-11, 620
2142-1, 2-10, 620
4247-1, 4.2-05
*
9036, 4.1-06, none
6096-1, 6.1-021, 6.1-042
9026-13
*
4121-1, 4.1-01, 335
2104, 2-083, 725
4162-2, 4.1-01, 235
332...
8222-1, 8-06, 705

4264, 4.2-04
*

4266-2, 4.2-04
*

3138-3, 3265-1, 3369-1, ,

4164

6221, 6.1-04, 510
3134-2, 3248-2, 3360-2, 3-07

*
2176-1, 2-09, 620
2176-1, 2-09, 620
2176-2, 2-09, 620
333...
2176-2, 2-09, 620
334...
3270, 3-03, 510
6219, 6.1-02, 510
6219, 6.1-02, 510
6221, 6.1-04, 510
NOTES: * If an MFAG Table No is not supplied by the shipper refer to subsection 4.2 of the MFAG. To be declared by the shipper after agreement with the competent authority of the country concerned. For action to be taken in the event of damage to, or leakage from a package containing infectious substances, refer to section 9 of the introduction to class 6.2. In addition, refer to subsection 4.3 of the MFAG.
1 2
As approved by the competent authority.
For liquids. For solids. 3 To be declared by the shipper.
UN No.
335
3270, 3-03, 510
6220, 6.1-02, 510
6219, 6.1-02 510
2102-1, none
2152-1, 2-07, none
2152-1, 2-06, none
5165-1, 5.1-11,
* To be declared by the shipper. If an MFAG number is not supplied by the shipper refer to subsection 4.2 of the MFAG.
CLASS 1 - E x p l o s i v e s
3.2 3.2.1
Introduction All packagings for goods should be so designed and constructed that: 1. they will protect the explosives prevent them escaping and cause no increase in the risk of unintended ignition or initiation when subjected to normal conditions of transport including foreseeable changes in temperature humidity and pressure; the complete package can be handled safely in normal conditions of transport; and the packages will withstand any loading imposed on them by foreseeable stacking to which they will be subject during transport so that: they do not add to the risk presented by the explosives; the containment function of the packagings is not harmed; and they are not distorted in a way or to an extent which will reduce their strength or cause instability of the stack.
2. 3.
3.2.2
Packing requirements for consist of general packing provisions which apply to all or a broad spectrum of goods in and additional requirements which only apply to specific UN (substance/article identification) Numbers. The general packing provisions are given in section 3.3 and the relevant additional requirements appear as notes to the explosive packing method tables which are found in section 3.4 of this introduction. General packing provisions The general provisions given below are in addition to those in Annex I of the General Introduction. All explosive substances and articles as prepared for transport should have been classified in accordance with the procedures given in the United Nations Recommendations on the Transport of Dangerous Goods. goods should be packed in accordance with: 1 the appropriate packing method shown on the schedules for substances and articles in this class; and 2 any relevant additional requirements for specific UN Numbers which are given as notes in the packing method tables in section 3.4 of this introduction. Note: In section 3.4 the following convention is used: Packing methods EP-01 to EP-09 - reserved for methods requiring competent authority approval. Packing methods EP-10 to EP-29 - reserved for explosive substances; and Packing methods EP-30 onwards - reserved for explosive articles.
3.3 3.3.1 3.3.2 3.3.3
3.3.4
Packages should conform to the requirements of Annex I of the General Introduction in particular to meeting the test requirements of section 8 and should be subject to the requirements of paragraphs 3.14 and 5.4. IBCs should comply with the provisions of section 26 of the General Introduction. The closure device of packagings containing liquid explosives should ensure a double protection against leakage. The closure device of metal drums should include a suitable gasket if a closure device includes a screw thread the ingress of explosive substances into the screw thread should be prevented.
3.3.5 3.3.6
IMDG CODE - PAGE 1006-1 (page 1006-2 follows) Amdt. 28-96
3.3.7 3.3.8
Packagings for water soluble substances should be water resistant. Packagings for desensitized or phlegmatized substances should be closed to prevent changes in concentration during transport. When the packaging includes a double envelope filled with water which may freeze during transport, a sufficient quantity of an antifreeze agent should be added to the water to prevent freezing. Antifreeze that could create a fire hazard because of its inherent flammability should not be used. Nails, staples and other closure devices made of metal without protective covering should not penetrate to the inside of the outer packaging unless the inner packaging adequately protects the explosives against contact with the metal. Inner packagings, fittings and cushioning materials and the placing of explosive substances or articles in packages should be accomplished in a manner which prevents the explosive substance or article from becoming loose in the outer packaging under normal conditions of transport. Metallic components of articles should be prevented from making contact with metal packagings. Articles containing explosive substances not enclosed in an outer casing should be separated from each other in order to prevent friction and impact. Padding, trays partitioning in the inner or outer packaging, mouldings or receptacles may be used for this purpose. Packagings should be made of materials compatible with, and impermeable to, the explosives contained in the package, so that neither interaction between the explosives and the packaging materials, nor leakage, causes the explosive to become unsafe for transport, or the hazard division or compatibility group to change. The ingress of explosive substances into the recesses of seamed metal packagings should be prevented. Plastics packagings should not be liable to generate or accumulate sufficient static electricity so that a discharge could cause the packaged explosive substances or articles to initiate ignite or function. Large and robust explosives articles, normally intended for military use without their means of initiation or with their means of initiation containing at least two effective protective features, may be carried unpacked. When such articles have propelling charges or are self propelled their ignition systems should be protected against stimuli encountered during normal conditions of transport. A negative result in Test Series 4 of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria on an unpacked article indicates that the article can be considered for transport unpacked. Such unpacked articles may be fixed to cradles or contained in crates or other suitable handling, storage or launching devices in such a way that they will not become loose during normal conditions of transport. Where, as part of their operational safety and suitability tests, such large explosive articles are subjected to test regimes which are at least equivalent or more stringent that the tests prescribed in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, as referred to in this Code and such tests have been successfully undertaken the competent authority may approve the transport of such articles under the requirements of this Code. Explosive substances should not be packed in inner or outer packagings where the differences in internal and external pressures, due to thermal or other effects, could cause an explosion or rupture of the package.
3.3.9
3.3.10
3.3.11
3.3.12 3.3.13
3.3.14
3.3.14.1
3.3.15
3.3.16
Whenever loose explosive substances or the explosive substances of an uncased or partly cased article may come into contact with the inner surface of metal packagings (1A2, 1B2, 4A, 4B and metal receptacles) the metal packaging should be provided with an inner liner or coating (see 3.2 of Annex I to this code). Notwithstanding the explosive packing methods listed in section 3.4 of this introduction EP-01 may be adopted for any explosive substance or article provided the package has been approved by a national competent authority. For the declaration of such goods see 2.5 of this introduction. Packing methods for explosives General Notes: (1) Whenever Boxes natural wood ordinary (4C1) are listed in the following tables a Box natural wood sift proof walls (4C2) may be used instead; (2) Leakproof packagings should correspond to a design type that has passed a leakproofness test at the Packaging Group II level; (3) The term receptacle used in the inner and intermediate packaging columns of the following tables includes boxes bottles cans drums jars and tubes including any means of closure; (4) Reels are devices made of plastics wood fibreboard metal or other suitable material comprising a central spindle with or without side walls at each end of the spindle Articles and substances can be wound onto the spindle and may be retained by side walls; (5) Trays are sheets of metal plastics wood fibreboard or other suitable material which are placed in the inner intermediate or outer packaging and achieve a close fit in such packagings. The surface of the tray may be shaped so that packagings or articles can be inserted held secure and separated from each other; (6) Some UN Numbers cover substances which may be transported dry or wetted. Where appropriate the heading of the packing method indicates whether it is suitable for the dry powder or wetted substance.
3.3.17
3.4
METHOD EP-01 Inner packagings and arrangements Intermediate packagings and arrangements Outer packagings and arrangements
As approved by the competent authority. The State's distinguishing sign for motor vehicles in international traffic of the country for which the authority acts, should be marked on the shipping documents as follows: "Packaging approved by the competent authority of " Note: For UN Nos. 0020, 0021, 0190 0349 to 0359 inclusive, 0382, 0383, 0384, 0461 to 0482 inclusive and 0485. For the purposes of documentation and package marking, the proper shipping name should be supplemented with the correct technical name (see 7.1.12 of the General Introduction)
UN No. 0059 0439 0440 0441
Division 1.1 1.2 1.4 1.4
Compatibility Group D D D S
CHARGES, SHAPED
without detonator
For UN Nos. 0059 and 0439 only Label of class
Properties or descriptions Articles consisting of a casing containing a charge of detonating explosive with a cavity lined with rigid material without means of initiation. They are designed to produce a powerful penetrating jet effect.
1
(the appropriate division number and the letter D should be placed on the label) For UN No. 0440 only Label of class
Observations
Packagings Packing Method EP-37 applies. Stowage Cargo ships.
Division 1.4 Compatibility Group D
ON DECK IN CONTAINERS OR THE LIKE UNDER DECK ORDINARY STOWAGE
Passenger ships SEE SECTION 9 OF INTRODUCTION TO THIS CLASS
For UN No. 0441 only the package should be EITHER marked
Packing, Stowage & Segregation See also General Introduction and introduction to this class.
1.4S
OR labelled with Label of class
Division 1.4 Compatibility Group S
CLASS 2 - G a s e s
AEROSOLS
UN No. 1950
Formula
Explosive limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. "AEROSOLS" meaning aerosol dispensers are any non-refillable receptacles meeting the requirements of paragraph 8.9 of Annex I, made of metal, glass or plastics and containing a gas compressed, liquefied or dissolved under pressure, with or without a liquid, paste or powder, and fitted with a release device allowing the contents to be ejected as solid or liquid particles in suspension in a gas, as a foam, paste or powder or in a liquid state or in a gaseous state. Observations The aerosols should comply with the provisions of the country in which they are filled. They should be provided with protection against inadvertent discharge They should be of a type which shows no visible leakage or loss of contents of more than 1% in mass (or 1 gram if the total contents are less than 100 grams) when stored for 18 hours at 55 C. This temperature may be reduced to 45 C for carriage solely within temperate climates (i.e. in latitudes greater than 30 North or South). A label of class 2.1 applies if the contents include more than 45%, by mass, or more than 250 g of flammable components. Flammable components are gases which are flammable in air at normal pressure or substances or preparations in liquid form which have a flashpoint less than or equal to 100 C. The provisions of this Code should not apply to aerosols with a capacity of less than 50 cm3 . The provisions of this Code should not apply to aerosols with a capacity of 1000 cm3 or less when the following conditions are met: - no flammable gas present; - internal pressure not greater than 8.4 kg/cm8 gauge at 55 C; - less than 10% , by mass of the total contents consisting of flammable liquid; - less than 1% , by mass of toxic substances present in liquid concentrate; - less than 0.2%, by mass of corrosive substances present in the liquid concentrate.
Label ACCORDING TO PROPERTIES. However for aerosols with a capacity of 1000 cm3 or less the mark "AEROSOLS" may be applied instead of a label.
MARINE POLLUTANT mark (for marine pollutants only)
IMDG CODE - PAGE 2102 (first of two pages) Amdt. 29-98
CLASS 2 - G a s e s
Packing The outer packagings should comply with the provisions of Annex 1 to this Code for packagings of packaging group II (medium danger). For AEROSOLS with a capacity of 1000 cm3 or less the following packagings* may also be used. Package gross 1 Wooden box 2 Fibreboard box 3 Shrink-wrapped or stretch-wrapped trays (meeting the conditions set out in sections 3.1, 3.2 and 3.4 to 3.8 of Annex I to this Code). 125 kg 55 kg 20 kg
* The packaging performance tests referred to in section 10 of the General Introduction and in Annex I of this Code need not apply. Stowage For AEROSOLS with a capacity above 1000 cm3 Category B. For AEROSOLS with a capacity of 1000 cm3 or less Category A. Segregation as for class 9 but "away from sources of heat and SEPARATED FROM goods of except from those in division 1.4. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
IMDG CODE - PAGE 2102a (page 2102-1 follows) Amdt. 28-96
CLASS 2 - G a s e s
AIR BAG INFLATORS, COMPRESSED GAS or AIR BAG MODULES, COMPRESSED GAS or SEAT-BELT PRETENSIONERS, COMPRESSED GAS [new schedule]
UN No. 3353
Formula
Explosive limits
Properties This entry applies to articles which are used as life-saving vehicle air bag inflators or air bag modules or seat-belt pretensioners, containing a gas or a mixture of compressed gases classified under class 2.2, with or without small quantities of pyrotechnic material. For units with pyrotechnic material, initiated explosive effects should be contained within the pressure vessel such that the unit, when tested, may be excluded from in accordance with 1.11 (b), in conjunction with 16.61.4.7 (a) (ii) of the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Part 1. Observations The provisions of this Code should not apply to air bags or seat-belts installed in vehicles or in completed vehicle components such as steering columns, door panels, seats, etc. Packing Units should be designed or packaged for transport so that when engulfed in a fire there will be no fragmentation of the pressure vessel or projection hazard. This should be determined by analysis. The pressure vessel should be in compliance with the requirements for the gas(es) contained in the pressure vessel. Stowage Category A Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.2
IMDG CODE - PAGE 2102-1 (page 2703 follows) Amdt. 29-98
CLASS 2 - G a s e s
CLASS 2 - G a s e s
UN No. 2188
ARSINE ARSENIC HYDRIDE HYDROGEN ARSENIDE
Formula AsH3
Explosive limits 3.9% to 77.8%
Label of class
2.3
Subsidiary risk label of class
2.1
ARTICLES, PRESSURIZED PNEUMATIC or HYDRAULIC (containing nonflammable gas)
Properties Flammable, toxic colourless gas with a garlic odour. Much heavier than air (2.8) Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D Clear of living quarters Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 3164
Formula
Explosive limits None
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with " P " or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Articles containing non-flammable, non-toxic gas necessary for their operation. Observations Articles intended to function as shock absorbers are not subject to the provisions of this Code provided that each article: 1. has a gas space capacity not exceeding 1 litre and a charge pressure not exceeding 50 bar; 2. has a minimum burst pressure of 4 times the charge pressure at 20 C; 3. is manufactured from material which will not fragment upon rupture; 4. when subjected to fire, is protected from rupture by means of a fire degradable seal or a pressure relief device to relieve internal pressure; and 5. is manufactured in accordance with a quality assurance standard acceptable to the competent authority. Packing The outer packagings should comply with the provisions of Annex I to this Code for packagings of packaging group III. Stowage Category A Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
2.2
MARINE POLLUTANT mark
(for marine pollutants only)
IMDG CODE PAGE 2106 Amdt. 29-98
CLASS 2 - G a s e s
UN No. 1741
BORON TRICHLORIDE
Formula BCI3
Label of class
Properties Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen chloride, and irritating and corrosive gas apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Much heavier than air. Observations Highly irritating to skin, eyes and mucous membranes. Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Shade from radiant heat. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
2.3
UN No. 1008
Formula BF3
BORON TRIFLUORIDE, COMPRESSED BORON FLUORIDE, COMPRESSED
Label of class
Properties Non-flammable, toxic and corrosive gas. Forms dense white corrosive fumes in moist air. Reacts violently with water, evolving hydrogen fluoride, an irritating and corrosive gas apparent as white fumes. Corrosive to glass and to most metals. Much heavier than air (2.35). Observations Highly irritating to skin, eyes and mucous membranes. Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
2.3
CLASS 2 - G a s e s
UN No. 2202
HYDROGEN SELENIDE, ANHYDROUS SELENIUM HYDRIDE HYDROSELENIC ACID, ANHYDROUS
Formula H2Se
Explosive limits
Properties Flammable, toxic, colourless gas with a disagreeable odour Much heavier than air (2.8). Observations Highly irritating to skin, eyes and mucous membranes. Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. Formula H2S Explosive limits 4% to 46%
Label of class
2.3
2.1
HYDROGEN SULPHIDE SULPHURETTED HYDROGEN
1053
Properties Liquefied, flammable, toxic gas with a foul odour. Heavier than air (1.2). Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.3
2.1
CLASS 2 - G a s e s
UN No.
INSECTICIDE GAS, N.O.S.
Formula
Explosive limits Variable
1968
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with " P " or 1% or more of substance(s) identified with "PP in the General Index to this Code. Mixtures of insecticides with liquefied gases. These mixtures may be flammable. Observations Packing For packing specifications see section 2 of the introduction to this class. Stowage Non-flammable gas category A. Flammable gas category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No.
INSECTICIDE GAS, TOXIC, N.O.S.
Label ACCORDING TO PROPERTIES

Formula
1967
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Toxic mixtures of insecticides with liquefied gases. These mixtures may be flammable. Observations Packing For packing specifications see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
2.3
IMDG CODE - PAGE 2152 (page 2152-1 follows) Amdt. 28-96
CLASS 2 - G a s e s
UN No. 3354
INSECTICIDE GAS, FLAMMABLE, N.O.S. [new schedule]
Formula
Properties MARINE POLLUTANT Label of class Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Flammable mixtures of insecticides with liquefied gases. Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 3355
INSECTICIDE GAS, TOXIC, FLAMMABLE, N.O.S. [new schedule]
2.1
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Toxic flammable mixtures of insecticides with liquefied gases. Label of class Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
2.3
2.1
CLASS 2 - G a s e s
CLASS 2 - G a s e s
UN No.
NITROGEN COMPRESSED
Formula N2
1066
Properties Non-flammable, odourless gas. Lighter than air (0.97). Observations Label of class
2.2
Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No.
NITROGEN, REFRIGERATED, LIQUID
Formula N2
1977
Properties Liquefied, non-flammable, odourless gas. Lighter than air (0.97) Observations The provisions of this schedule should not apply to liquid nitrogen carried on board ship for cooling purposes for certain goods shipped in closed freight containers or vehicles. Arrangements for the containment of the liquid nitrogen and fittings in use should be appropriate to the potential danger to the structure of the freight container or ship from the effect of misuse or accidental spillage of the gas. Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.2
CLASS 2 - G a s e s
UN No. 2451
NITROGEN TRIFLUORIDE, COMPRESSED
Formula NF3
Properties Non-flammable non-toxic colourless odourless stable gas. Strong oxidizing agent reacts violently with many substances e.g. grease oil etc. Much heavier than air (2.4). Observations May cause slight eye irritation. Packing For packing specifications see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2421 Formula N2O3 Explosive limits None
Label of class
2.2
5.1
NITROGEN TRIOXIDE NITROGEN SESQUIOXIDE DINITROGEN TRIOXIDE
Properties Liquefied non-flammable toxic and corrosive gas. At lower temperatures present as a blue liquid. Strong oxidizing agent. Much heavier than air (2.6). Boiling point 3.5 C. Observations Highly irritating to skin eyes and mucous membranes.
Label of class
2.3
Subsidiary risk labels of classes
Packing For packing specifications see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Segregation as for class 51, but separated from class 7. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
5.1and 8
CLASS 2 - G a s e s
UN No
PENTAFLUOROETHANE REFRIGERANT GAS R 125
Formula C2HF5
3220
Properties Liquefied non-flammable gas with a mild ethereal odour. Much heavier than air (4.2). Label of class Observations Packing For packing specifications see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
2.2
UN No. 3083
Formula ClO3F
Explosive limits
PERCHLORYL FLUORIDE
Label of class
2.3
Properties Non-flammable toxic colourless gas with a characteristic sweet odour. Strong oxidizing agent may cause fire in contact with organic materials. Reacts with water or moist air to produce toxic and corrosive fumes. Mixtures with oils or combustible materials may explode. Much heavier than air (3.6). Observations Irritating to skin eyes and mucous membranes. Packing For packing specifications see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
5.1
CLASS 2 - G a s e s
UN No.
PERFLUORO(ETHYL, VINYL ETHER) PENTAFLUOROETHYL TRIFLUOROVINYL ETHER, PENTAFLUOROETHOXYTRIFLUOROETHYLENE.
Formula CF3CF2OCF-CF2
Explosive limits 7% to 73%
3154
Properties Liquefied, flammable gas. Much heavier than air (6.4). Boiling point. 12C. Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category E. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.1
UN No.
PERFLUORO(METHYL, VINYL ETHER) TRIFLUOROMETHYL TRIFLUOROVINYL ETHER TRIFLUOROMETHOXYTRIFLUOROETHYLENE
Formula CF3OCF-CF2
3153
Properties Liquefied, flammable gas. Much heavier than air (4.8). Boiling point -27C. Observations Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category E. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.1
CLASS 2 - G a s e s
UN No. 1078
REFRIGERANT GAS, N.O.S.
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Different chloro-fluoro-hydrocarbons or other non-flammable, nontoxic gases considered as refrigerant agents. Observations Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No.
REFRIGERATING MACHINES containing non-flammable, non-toxic liquefied gas or ammonia solution (UN No. 2672)
Label of class
2.2
Formula
Explosive limits
2857
Label of class
2.2
Properties Refrigerating machines include air conditioning units and machines or other appliances which have been designed for the specific purpose of keeping food or other items at a low temperature in an internal compartment. Observations The provisions of this Code should not apply to refrigerating machines containing less than 12 kg non-flammable, non-toxic liquefied gas or if containing less than 12 l of ammonia solution. (UN No. 2672) Packing May be carried unpacked or in crates. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
CLASS 2 - G a s e s
UN No.
REFRIGERANT GAS R 404A PENTAFLUOROETHANE 1,1,1-TRIFLUOROETHANE, AND 1,1,1,2-TETRAFLUORO-ETHANE ZEOTROPIC MIXTURE WITH APPROXIMATELY 44% PENTAFLUOROETHANE AND 52% 1,1,1-TRIFLUOROETHANE [new schedule]
Formula
Explosive limits
3337
Properties Liquefied non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.06). Observations Very high exposures may cause anaesthetic effects and asphyxiation. Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.2
UN No.
REFRIGERANT GAS R 407A DIFLUOROMETHANE PENTAFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH APPROXIMATELY 20% DIFLUOROMETHANE AND 40% PENTAFLUOROETHANE (new schedule]
Formula
Explosive limits
3338
Properties Liquefied non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.1 7). Observations Very high exposures may cause anaesthetic effects and asphyxiation. Packing For packing specifications see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.2
CLASS 2 - G a s e s
UN No.
REFRIGERANT GAS R 407B
Formula
Explosive limits
3339
DIFLUOROMETHANE PENTAFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH APPROXIMATELY 10% DIFLUOROMETHANE AND 70% PENTAFLUOROETHANE [new schedule]
Properties Liquefied non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.19). Observations Very high exposures may cause anaesthetic effects and asphyxiation. Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.2
UN No.
REFRIGERANT GAS R 407C DIFLUOROMETHANE, PENTAFLUOROETHANE AND 1,1,1,2-TETRAFLUOROETHANE ZEOTROPIC MIXTURE WITH APPROXIMATELY 23% DIFLUOROMETHANE AND 25% PENTAFLUOROETHANE [new schedule]
Formula
Explosive limits
3340
Properties Liquefied, non-flammable, colourless gas with a faint ether-like odour. Heavier than air (1.16). Observations Very high exposures may cause anaesthetic effects and asphyxiation. Packing For packing specifications, see section 2 of the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.2
CLASS 2 - G a s e s
UN No.
SELENIUM HEXAFLUORIDE
Formula SeF6
Explosive limits
2194
Label of class
2.3
Properties Colourless, toxic and corrosive gas. Corrosive to glass and to most metals. Heavier than air. Observations Highly irritating to skin, eyes and mucous membranes. Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2203
Formula SiH4
SILANE, COMPRESSED HYDROGEN SILICIDE, COMPRESSED SILICON TETRAHYDRIDE, COMPRESSED
Properties Flammable, colourless gas with a foul odour. Ignites spontaneously in air. Strong reducing agent which reacts violently with oxidizing substances. Heavier than air (1.1). Observations Packing For packing specifications, see section 2 of the introduction to this class. Stowage Category E. Clear of living quarters. SEPARATED FROM bromine and chlorine. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
2.1
CLASS 3 F l a m m a b l e l i q u i d s
1.25 1.3 1.31 1.32 1.4
The substances are arranged in alphabetical order of proper shipping names within each flashpoint group, and commonly used synonyms have been included. The vapours from all substances of class 3 have a narcotic effect, and prolonged inhalation may result in unconsciousness. Deep or prolonged narcosis may lead to death. Some flammable liquids also have specific toxic or corrosive effects, and this has been indicated in the individual schedules where appropriate. A number of flammable liquids have been identified as harmful to the marine environment (MARINE POLLUTANT), and this has been indicated in the individual schedules where appropriate. Some substances in this class, under conditions incident to transport, are liable to polymerize (combine or react with themselves) so as to cause dangerous liberation of heat or gas, possibly resulting in rupture of the receptacle. These substances should not be transported unless they are properly inhibited.
1.5 1.6
Where explosive limits are given, these refer to the volume percentage of the vapour of the substance when mixed with air. The ease and extent to which different liquids mix with water varies greatly and most individual schedules have included an indication of miscibility. In these cases "miscible with water" normally means capable of being mixed with water in all proportions to form a completely homogeneous liquid.
2 STANDARDIZATION OF THE FLASHPOINT TEST METHOD 2.1 Information in this respect will be found in section 6 of the General Introduction.
3 PACKING
3.1 3.1.1
Classification and grouping criteria. Flammable liquids have for packing purposes been apportioned among three categories (packaging groups) according to the degree of danger they present great danger (packaging group I), medium danger (packaging group II) and minor danger (packaging group III). The packaging group to which a substance is assigned is given in its individual schedule.
3.1.2
The packaging group of a flammable liquid for which no specific packaging group is given in the individual schedule should be assigned in accordance with the following table. However, if the liquid possesses more than one hazard the packaging group should be determined in accordance with subsection 5.2 of the General Introduction.
Hazard grouping based on flammability Flammable liquids are grouped for packing purposes according to their flashpoint their boiling point and their viscosity. The table shows the relationship existing between two of these characteristics.
Packaging group
| II III
Flashpoint in C closed cup (c.c. ) <23 >23 to 61
Initial boiling point in C

35 >35 >35
Viscous substances having a flashpoint below 23 C c.c. may be placed in packaging group III in conformity with 3.1.3 and 3.1.4.
Substances classified as flammable liquids due to their being transported or offered for transport at elevated temperatures are included in packaging group III. 3.1.3 Determination of grouping of flammable viscous substances with a flashpoint of less than 23 C c.c. The packaging group of paints adhesives and other viscous flammable liquids with a flashpoint of less than 23 C c.c. is determined by reference to: 1 2 3 the viscosity expressed as the flow time in seconds (refer to ISO standard 2431-84); the closed cup flashpoint; and a solvent separation test.
3.1.4
Criteria for inclusion in packaging group III Viscous flammable liquids such as paints and adhesives with a flashpoint below 23 C c.c. are included in packaging group III provided that: 1 2 less than 3% of the clear solvent layer separates in the solvent separation test; the mixture does not contain any substances with a primary or a subsidiary risk of class 6.1 or class 8.
3.3.1.1
Glass receptacles packaged in an outer packaging should be surrounded by inert cushioning material so arranged as to prevent breakage and leakage from the package. For substances in class 3.1 this cushioning material should also be absorbent. This is not necessary if close-fitting parts of expanded plastics are used as cushioning material and the requirements of the second sentence of 3.3.1.5 are met when appropriate. Where glass is permitted, it should be understood to include earthenware, porcelain and other comparable materials unless stipulated otherwise. Where glass or plastics receptacles are permitted it should be understood that glass or plastics bottles or jars are included. Where wooden boxes are permitted as outer packaging it should be understood that boxes of natural wood (4C1, 4C2), plywood boxes (4D) and reconstituted wood boxes (4F) are included. Moulded expanded plastics boxes (4H1) should be constructed of a fire-resistant grade of plastics material. When the contents are not compatible with the outer packaging, each glass bottle should be enclosed in a bag made of plastics material compatible with the contents and the bag should be effectively closed.
3.3.1.2 3.3.1.3 3.3.1.4 3.3.1.5
3.3.1.6
Where for substances in the intermediate and high flashpoint groups, packaging groups I or II fibreboard boxes are specified a fibreboard box reinforced by wood or other suitable material with a maximum gross mass of 55 kg may be used provided that it is water-resistant and compatible with the substance to be carried.
3.3.2
A cylinder of the kind normally used for compressed gases, approved by the competent authority of the country concerned and with suitable valve protection may be used to contain any flammable liquid, provided that this liquid is compatible with the material of construction. Removable head packagings should not be used for the transport of liquids except that steel and aluminium removable head drums or jerricans may be used for liquids in packaging groups II and III, when these packagings successfully pass the test for liquids. Viscous flammable liquids in the low or intermediate flashpoint groups are included in packaging group III if they meet the criteria in 3.1.4. In such cases, packagings indicated in the table for liquids in the high flashpoint group, packaging group III, may be used.
3.3.3
3.3.4
IMDG CODE - PAGE 3007 (page 3009 follows) Amdt. 29-98
3.4
Packaging specifications [new table] Maximum gross mass or maximum liquid contents Packaging group I II 125 kg 125 kg 125 kg 125 kg 125 kg 120 kg 120 kg 60 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 551 kg 55 kg 250 litres 2504 litres 250 litres 2504 litres 250 litres 60 litres 604 litres 60 litres 604 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres III 125 kg 125 kg 125 kg 125 kg 125 kg 120 kg 120 kg 60 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 551 kg 55 kg 250 litres 2504 litres 250 litres 2504 litres 250 litres 60 litres 604 litres 60 litres 604 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 75 kg 75 kg 75 kg 75 kg 75 kg 60 kg 60 kg 30 kg 75 kg 75 kg 75 kg 75 kg 75kg 75 kg 401 kg 40 kg 250 litres Prohibited 250 litres Prohibited 2502 litres 60 litres Prohibited 60 litres Prohibited 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres
Inner packaging
Outer packaging
Packaging code (Annex I) 1A2 1B2 1D 1G 1H2 3A2 3B2 3H2 4A 4B 4D 4C1, 4C2 4F 4H2 4G 4H1 1A1 1A2 1B1 1B2 1H1 3A1 3A2 3B1 3B2 3H1
Receptacles, glass, porcelain and stoneware, maximum contents 10 litres or Receptacles, plastics, maximum contents 30 litres, or Receptacles, metal, maximum contents 40 litres
Drums - Steel Aluminium Plywood Fibre Plastics Jerricans - Steel Aluminium Plastics Boxes - Steel Aluminium Plywood Natural wood Reconstituted wood Solid plastics Boxes - Fibreboard Boxes - Moulded expanded plastics
Drums - Steel Steel Aluminium Aluminium Drums - Plastics Jerricans - Steel Steel Aluminium Aluminium Plastics Cylinders Plastics receptacle in a: steel crate or box aluminium crate or box wooden box plywood box fibreboard box solid plastics box
According to the design type3 6HA2 6HB2 6HC 6HD2 6HG2 6HH2
Notes:
When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging groups II and III and 75 kg for packaging group I.
2 3
Not permitted for class 3, packaging group I.
Cylinders of carbon steel, special steels, copper alloy and aluminium alloy 150 litres Receptacles of carbon steel, special steels, copper alloy and aluminium alloy 100 to 1000 litres.
4
Tested for liquids.
[new table] Maximum gross mass or maximum liquid contents Packaging group I Plastics receptacle in a plywood drum fibre drum plastics drum steel drum aluminium drum Glass receptacle in a steel drum steel crate or box aluminium drum aluminium crate or box wooden box plywood drum plywood box fibre drum fibreboard box expanded plastics drum solid plastics drum 6HD1 6HG1 6HH1 6HA1 6HB1 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 6PH2 1202 litres 1202 litres 1202 litres 250 litres 250 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres II 250 litres 250 litres 250 litres 250 litres 250 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres III 250 litres 250 litres 250 litres 250 litres 250 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
Table 3.4 (continued)
Packaging code (Annex 1)
Plastics receptacle in a
CLASS 3.1 F l a m m a b l e l i q u i d s
Low flashpoint group

MEDICINE, LIQUID, FLAMMABLE, TOXIC,
UN No. 3248
Formula
Explosive Limits
Flashpoint * below -18 C c.c.
N.O.S.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations Toxic if swallowed by skin contact or by inhalation. The technical name of only the flammable liquid component of this solution or mixture should be shown in parentheses immediately following the proper shipping name.
* Also listed in intermediate and high flashpoint groups.
Packaging group: II Label of class
3
6.1
Packing See table 3.4 in the introduction to this class. Maximum net quantity per inner receptacle 5 litres or 5 kg. Stowage Category E. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID FLAMMABLE, N.O.S. [new schedule]
UN No. 3336
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1 % or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour which may affect all odour absorbing cargoes. Immiscible with water. Observations *Also listed in intermediate and high flashpoint groups. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category E.
SEPARATED FROM foodstuffs.
Packaging group: I or II according to the grouping criteria for each hazard
Label of class
3
Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

MERCAPTANS, LIQUID, FLAMMABLE, TOXIC, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE, TOXIC, N.O.S.
UN No. 1228
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour. Immiscible with water. Observations Toxic if swallowed by skin contact or by inhalation. For MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S., UN No. 3071, see class 6.1.
3
6.1
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category E. Clear of living quarters. SEPARATED FROM foodstuffs and all other odour-absorbing cargoes. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

NITRITES, FLAMMABLE, TOXIC, N.O.S. CYANIDES, ORGANIC, FLAMMABLE, TOXIC,
UN No. 3273
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids evolving toxic vapour. React with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Observations Toxic if swallowed, by skin contact or by inhalation. For NITRILES, TOXIC, FLAMMABLE, N.O.S. , UN No. 3275, see class 6.1
* Also listed in intermediate flashpoint group.
N.O.S.
Label of class
Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category E. Clear of living quarters. SEPARATED FROM acids. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
3
6.1

NITROCELLULOSE SOLUTION, FLAMMABLE, with not more than 12 6% nitrogen, by dry mass, and not more than 55% nitrocellulose CELLULOSE NITRATE SOLUTION, COLLODION SOLUTION, LACQUER BASE SOLUTION, NITROCOTTON SOLUTION, PYROXYLIN SOLUTION
UN No. 2059
Formula
Explosive Limits
Flashpoint *below -18C c.c.
Properties When involved in a fire, evolves toxic nitrous fumes. Observations For NITROCELLULOSE WETTED with not less than 25% alcohol by mass, UN No. 0342, see . For PAINT or PAINT RELATED MATERIAL containing 20% or less nitrocellulose with not more than 12.6% nitrogen, see UN No. 1263 in this class. For PRINTING INK, flammable, containing 20% or less nitrocellulose, see UN No. 1210 in this class.
Packaging group: I or II according to the grouping criteria for flammable liquids
Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Label of class Stowage Category E. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S., with not more than 30% nitroglycerin, by mass [new schedule]
UN No. 3343
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations
* Also listed in intermediate and high flashpoint groups. These substances should not be classified and transported unless authorized by the competent authority on the basis of results from. Series 2 tests and a Series 6(c) test on packages as prepared for transport (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria).
Packaging group: as assigned by

the competent authority on the basis of the criteria set out in paragraph 3.1.2 of the introduction to this class.
Packing As approved by the competent authority who should assign the package type according to that used for the Series 6(c) test (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria). Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
3
Intermediate flashpoint group

2-BROMOETHYL, ETHYL, ETHER
UN No. 2340
Formula BrCH2CH2OC2H5
Explosive Limits
Flashpoint -18C to 23C c.c.
Properties Colourless liquid with an ethereal odour. Partially miscible with water. Packaging group: II Observations Harmful by inhalation. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
3
BROMOMETHYLPROPANES ISOBUTYL BROMIDE tertiary-BUTYL BROMIDE
UN No. 2342
Formula C4H9Br
Explosive Limits
Flashpoint -18C to 23C c.c.
Properties Colourless liquids. Immiscible with water. Observations Harmful by inhalation. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Packaging group: II
Label of class

2-BROMOPENTANE secondary-AMYL BROMIDE
UN No. 2343
Formula C5H11Br
Explosive Limits
Flashpoint 21 C c.c.
Properties Colourless or yellow liquid with a strong odour. Immiscible with water. Observations Harmful by inhalation. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Packaging group: II
Label of class
3
BROMOPROPANES ISOPROPYL BROMIDE PROPYL BROMIDES
UN No. 2344
Formula C3H7Br
Explosive Limits
Flashpoint * -18 C to 23 C c.c.
Properties Colourless liquids. Immiscible with water. When involved in a fire evolve toxic fumes. Observations Harmful by inhalation.
* Also listed in high flashpoint group.
Packaging group: II
Label of class
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

MEDICINE LIQUID, FLAMMABLE, TOXIC, N.O.S.
UN No. 3248
Formula
Explosive Limits
Flashpoint -18 C to 23 C c.c.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations Toxic if swallowed by skin contact or by inhalation. The technical name of only the flammable liquid component of this solution or mixture should be shown in parentheses immediately following the proper shipping name.
* Also listed in low and high flashpoint groups.
Packaging group: II
Label of class
3
Packing See table 3.4 in the introduction to this class. Maximum net quantity per inner receptacle 5 litres or 5 kg. Stowage Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1

MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN FLAMMABLE,
UN No. 3336
Formula
Explosive Limits
Flashpoint * -18 C c.c. to 23C c.c.
N.O.S.
[new schedule] MIXTURE, LIQUID,
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour which may affect all odour absorbing cargoes. Immiscible with water.
Packaging group: I or II according to the grouping criteria for flammable liquids.
Observations
*Also listed in low and high flashpoint groups.
Label of class
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Separated from foodstuffs. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
3

UN No. 1228
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substances identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour. Immiscible with water. Observations Toxic if swallowed by skin contact or by inhalation. For MERCAPTANS LIQUID TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S. UN No. 3071, see class 6.1.
Packaging group: II
Label of class
3
6.1
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Separated from foodstuffs and all other odour-absorbing cargoes. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

NITRILES, FLAMMABLE, TOXIC, N.O.S. CYANIDES, ORGANIC, FLAMMABLE, TOXIC, N.O.S.
UN No. 3273
Formula
Explosive Limits
Flashpoint * 18 C to 23 C c.c.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids evolving toxic vapour. React with acid or acid fumes evolving hydrogen cyanide a highly toxic and flammable gas. Observations Toxic if swallowed by skin contact or by inhalation. For NITRILES, TOXIC, FLAMMABLE, N.O.S., UN No. 3275 see class 6.1.
* Also listed in low flashpoint group.
Label of class
Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Separated from acids. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
3
6.1

NITROCELLULOSE SOLUTION, FLAMMABLE, with not more than 12.6% nitrogen by dry mass, and not more than 55% nitrocellulose. CELLULOSE NITRATE SOLUTION, COLLODION SOLUTION, LACQUER BASE SOLUTION, NITROCOTTON SOLUTION, PYROXYLIN SOLUTION.
UN No. 2059
Formula
Explosive Limits
Properties When involved in a fire, evolves toxic nitrous fumes. Observations For NITROCELLULOSE, WETTED with not less than 25% alcohol, by mass, UN No. 0342, see . For PAINT or PAINT, RELATED MATERIAL containing 20% or less nitrocellulose, with not more than 12.6% nitrogen, see UN No. 1263 in this class. For PRINTING INK, flammable, containing 20% or less nitrocellulose, see UN. No 1210 in this class.
Packaging group: I or II according to the grouping criteria for flammable liquids.
Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B.
Label of class

NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. with not more than 30% nitroglycerin, by mass [new schedule]
UN No. 3343
Formula
Explosive Limits
Flashpoint * -18 C c.c. to 23 C c.c.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations Packaging group: as assigned by the competent authority on the basis of the criteria set out in paragraph 3.1.2 of the introduction to this class.
*Also listed in low and high flashpoint groups. These substances should not be classified and transported unless authorized by the competent authority on the basis of results from. Series 2 tests and a Series 6(c) test on packages as prepared for transport (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria).
Label of class
3

NITROGLYCERIN SOLUTION IN ALCOHOL with not more than 1% nitroglycerin. GLYCERYL TRINITRATE.
UN No. 1204
Formula C3H5(NO3)3
Explosive Limits
Properties Immiscible with water. Ignites readily. When involved in a fire evolves toxic nitrous fumes. Observations Not explosive in this state but damage to or leakage from a package may allow solvent to evaporate and thus leave the nitroglycerin in an explosive state. Refuse for shipment damaged or leaking packages For NITROGLYCERIN SOLUTION IN ALCOHOL containing more than 1% but not more than 10% nitroglycerin in solution in alcohol, see UN No. 0144 . For NITROGLYCERIN, SOLUTION IN ALCOHOL with more than 1% but not more than 5% nitroglycerin, see UN No. 3064 in this class. Packing See table 3 4 in the introduction to this class. Transport in tanks p r o h i b i t e d . Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Packaging group: II
Label of class

PAINT (including paint, lacquer, enamel, stain shellac, solutions, varnish, polish liquid, filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound).
UN No. 1263
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Miscibility with water depends upon the composition Observations May contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen. A substance specifically identified by name in this Code should not be shipped under this entry.
* Also listed in low and high flashpoint groups. ** Packaging group III if the criteria set out in 3.1.4 of the introduction to this class are met.
Packaging group: I or II according to the grouping criteria for flammable liquids.**
Label of class
3
Packing See 3.2.6 and table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

PERFUMERY PRODUCTS, flammable liquid. COSMETICS.
UN No. 1266
Formula
Explosive Limits
Flashpoint *-18C to 23 C c.c.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Miscibility with water depends upon the composition. Observations
* Also listed in high flashpoint group. ** Packaging group III if the criteria set out in 3.1.4 of the introduction. to this class are met.
Packaging group: II**
Label of class
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
3

PENTANOLS. AMYL ALCOHOLS, METHYLBUTANOLS.
UN No. 1105
Formula C5H11OH
Explosive Limits 1.2% to 10.5%
Properties Colourless liquids with a strong odour. Immiscible with water. tertiary-AMYL ALCOHOL, flashpoint 19C to 21C c.c. Observations
Packaging group: II Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Label of class
Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

PESTICIDE, LIQUID, FLAMMABLE, TOXIC,
UN No. Formula 3021 2758 2760 2762 2764 2772 2776 2778 2780 2782 2784 2787 3024 3346 3350
Explosive Limits
N.O.S.
CARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC ARSENICAL PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC TRIAZINE PESTICIDE, LIQUID, FLAMMABLE, TOXIC THIOCARBAMATE PESTICIDE, LIQUID, FLAMMABLE, TOXIC COPPER BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC MERCURY-BASED PESTICIDE, LIQUID, FLAMMABLE, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, FLAMMABLE, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, FLAMMABLE, TOXIC ORGANOTIN PESTICIDE, LIQUID, FLAMMABLE, TOXIC COUMARIN DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, FLAMMABLE, TOXIC PYRETHROID PESTICIDE, LIQUID, FLAMMABLE, TOXIC
Properties MARINE POLLUTANT Pesticides frequently contain petroleum or coal tar distillates, or other flammable liquids. Miscibility with water depends upon the composition. Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active pesticide substance or substances should be mentioned in the shipping documents when a pesticide is offered for shipment. For PESTICIDE, LIQUID, TOXIC, FLAMMABLE, N.O.S., with a flashpoint between 23 C and 61 C c.c., see UN No. 2903, class 6.1. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: I or II according to grouping criteria for each hazard Label of class
6.1

AMYL ALCOHOLS
entry moved to page 3269-1

AMYLAMINES. PENTYLAMINES, normaI-AMYLAMINE, 1-PENTYLAMINE, tertiary-AMYLAMINE, 3-PENTYLAMINE.
UN No. 1106
Formula C5H11NH2
Explosive Limits 2.2% to 22%
Flashpoint * -7C to 23C c.c.
Properties Colourless, clear liquids. normal-AMYLAMINE (1-PENTYLAMINE) flashpoint 4 C c.c. tertiary-AMYLAMINE (3-PENTYLAMINE) flashpoint 2 C c.c. Miscible with water. Observations Harmful by inhalation. Cause burns to skin eyes and mucous membranes.
3
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

AMYL CHLORIDES. CHLOROPENTANES, 1-CHLORO-3-METHYLBUTANE, 2-CHLORO-2-METHYLBUTANE, normaI-AMYL CHLORIDE.
UN No. 1107
Formula C5H11CI
Explosive Limits
Flashpoint -18 C to 23C c.c.
Properties Colourless or light brown liquids with an aromatic odour. Explosive limits normal AMYL CHLORIDE 1.4% to 8.6% Immiscible with water. Observations
Packaging group: II Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Label of class
Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
CLASS 3.2 - Flammable liquids
UN No.
Formula
Explosive Limits
Petroleum products* FUEL, AVIATION, TURBINE ENGINE, AVIATION GASOLINE PETROLEUM CRUDE OIL PETROLEUM DISTILLATES, N.O.S. or PETROLEUM PRODUCTS, N.O.S. SHALE OIL TURPENTINE SUBSTITUTE, WHITE SPIRIT 1863 1267 1268 1288 1300
Properties Packaging group: I or II according to the grouping criteria for flammable liquids. MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code.
WHITE SPIRIT low aromatic (15% - 20%) is a
MARINE POLLUTANT Label of class
3
Packaging group II only. Immiscible with water. Observations

Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

POLYESTER RESIN KIT
UN No. 3269
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Polyester resin kits consist of two components a base material (flammable liquid, packaging group II) and an activator (organic peroxide), each separately packed in an inner packaging. Observations The organic peroxide should be type D, E or F, not requiring temperature control and should be limited to a quantity of 125 ml per inner packaging, if liquid, and 500 grams, if solid. The components may be placed in the same outer packaging provided they will not interact dangerously in the event of leakage.
Packaging group: II
Label of class
3
Packing Wooden box (4C1), (4D), (4F) Fibreboard box (4G) Moulded expanded plastics box (4H1) Solid plastics box (4H2)
Package gross 125 kg 40 kg 40 kg 125 kg
Stowage Category B. Packing, Stowage, Segregation and Marine Pollution Aspects See also General Introduction and introduction to this class. IMDG CODE - PAGE 3272 (page 3272-1 follows) Amdt. 29-98

PRINTING INK, flammable
UN No. 1210
Formula
Explosive Limits
Properties Fluid or viscous liquid containing colouring matter in solution or suspension. Miscibility with water depends upon the solvent. Observations May contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen. A substance specifically identified by name in this code should not be shipped under this entry.
* Also listed in low and high flashpoint groups. ** Packaging group III if the criteria set out in 3.1.4 of the introduction to this class are met.
Packaging group: I or II** according to the grouping criteria for flammable liquids Label of class
Packing See table 3.2.6 and 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

normal-PROPANOL 1-PROPANOL, normal-PROPYL ALCOHOL
UN No. 1274
Formula CH3CH2CH2OH
Explosive Limits 2% to 12%
Properties Colourless liquid. Miscible with water. Observations

Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

PROPIONITRILE. ETHYL CYANIDE.
UN No. 2404
Formula CH3CH2CN
Explosive Limits 3.1 % to
Flashpoint 2 C c.c.
Properties Colourless volatile liquid with an ethereal odour. Miscible with water. When involved in a fire, evolves highly toxic cyanide fumes. Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category E. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
3
6.1

PROPIONYL CHLORIDE. PROPANOYL CHLORIDE.
UN No. 1815
Formula CH3CH2COCI
Explosive Limits
Properties Colourless liquid. Reacts violently with water evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. In the presence of moisture, highly corrosive to most metals. Observations Causes burns to skin, eyes and mucous membranes. Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
3

normal-PROPYL ACETATE.
UN No. 1276
Formula C3H7OOCCH3
Explosive Limits 1.8% to 8%
Properties Colourless, clear liquid with a pleasant odour. Immiscible with water. Packaging group: II Label of class Observations Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class. Intermediate flashpoint group
PROPYLENEIMINE, INHIBITED.
UN No. 1921
Formula CH3CHNHCH2
Explosive Limits
Flashpoint -4 C c.c.
Properties Colourless liquid with an ammoniacal odour. Miscible with water. Packaging group: I Label of class Observations Toxic, if swallowed, by skin contact or by inhalation. Causes burns to skin and eyes. Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
3
6.1
UN No.
Formula CH3COOC5H11
Explosive Limits 1.1 % to
Flashpoint 23 C to 61 C c.c.
High flashpoint group

AMYL ACETATES. normal-AMYL ACETATE, secondary-AMYL ACETATE, ISOAMYL ACETATE.
1104
Properties Colourless liquids with a pear or banana like odour. normal AMYL ACETATE flashpoint 25 C c.c. secondary AMYL ACETATE flashpoint 32 C c.c. Immiscible with water. Observations
Packaging group: III
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class

AMYL ALCOHOLS.
entry moved to page 3373-1

UN No. 1106 Formula C5H11NH2 Explosive Limits 2.2% to 22% Flashpoint * 23 C to 61 C c.c.

AMYLAMINES. 2-PENTYLAMINE, 2-AMYLAMINE.
Properties Colourless liquids. Miscible with water.
Observations Harmful by inhalation. Irritating to skin, eyes and mucous membranes. Packaging group: III Label of class
3
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.
Stowage Category A.

1-BROMO-3-METHYLBUTANE. ISOAMYL BROMIDE.
UN No. 2341
Formula C5H11Br
Explosive Limits
Properties Colourless liquid. Immiscible with water. Observations Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2344 Formula Explosive Limits Flashpoint * 23 C to 61 C c.c.
Packaging group III Label of class

BROMOPROPANES.
Properties Colourless liquids. Immiscible with water. When involved in a fire evolve toxic fumes. Observations Harmful by inhalation.
ISOPROPYL BROMIDE, PROPYL BROMIDES [new schedule]

BUTANOLS.
UN No. 1120
Formula C4H9OH
Explosive Limits
normal-BUTANOL, normal-BUTYL ALCOHOL, 1-BUTANOL, METHYL ETHYL CARBINOL.
Properties Colourless liquids with a disagreeable odour. Explosive limits normal-BUTANOL 1.4% to 11.2%, normal-BUTANOL is immiscible with water. Observations Irritating to skin eyes and mucous membranes.
UN No. 1123 Formula C4H9OOCCH3 Explosive Limits 1.5% to 15% Flashpoint * 23 C to 61 C c.c.

BUTYL ACETATES.
Properties Colourless liquids with a pineapple-like odour normal-BUTYL ACETATE flashpoint 27 C c.c. Immiscible with water. Observations Also listed in intermediate flashpoint group. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.

ISOBUTYRIC ACID.
UN No. 2529
Formula (CH3)2CHCOOH
Explosive Limits 2% to 9.2%
2-METHYLPROPIONIC ACID
Properties Colourless liquid with a pungent odour. Miscible with water. Observations Causes burns to skin and eyes. Irritating to skin eyes and mucous membranes. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
3
8
ISOBUTYRIC ANHYDRIDE.
UN No. 2530
Formula [(CH3)2CHCO]2O
Explosive Limits 1 % to 6.2%
Properties Colourless liquid. Decomposes in water. Observations Causes burns to skin and eyes. Irritating to skin eyes and mucous membranes. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
3

ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S.
UN No. 2478
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1 % or more of substance(s) identified with "PP" in the General Index to this Code. Toxic liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide.
Observations Toxic if swallowed, by skin contact or by inhalation. For ISOCYANATES, TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION, TOXIC, FLAMMABLE, N.O.S. , UN No. 3080, see class 6.1.
* Also listed in low and intermediate flashpoint groups.
Label of class
3
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category E, If under deck, with mechanical ventilation. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1

MEDICINE, LIQUID, FLAMMABLE, TOXIC,
UN No. 3248
Formula
Explosive Limits
N.O.S.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations Toxic if swallowed, by skin contact or by inhalation. The technical name of only the flammable liquid component of this solution or mixture should be shown in parentheses immediately following the proper shipping name.
Label of class
Packing See table 3.4 in the introduction to this class. Maximum net quantity per inner receptacle 5 litres or 5 kg. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
3
6.1
IMDG CODE - PAGE 3360-1 (page 3360 2 follows) Amdt. 27-94

MERCAPTANS, LIQUID, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, FLAMMABLE,
UN No. 3336
Formula
Explosive Limits
Flashpoint * 23 C c.c. to 61 C c.c.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour which may affect all odour-absorbing cargoes. Immiscible with water.
N.O.S.
[new schedule]
Packaging group: III Observations

Label of class
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B.
3

UN No. 1228
Formula C2H5SH
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless to yellow liquids with a garlic odour. Immiscible with water. Observations Toxic, if swallowed, by skin contact or by inhalation. For MERCAPTANS, LIQUID, TOXIC, FLAMMABLE, N.O.S. or MERCAPTAN MIXTURE, LIQUID, TOXIC, FLAMMABLE, N.O.S., UN No. 3071, see class 6.1.
Packaging group III
Label of class
3
Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. SEPARATED FROM foodstuffs and all other odour absorbing cargoes. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
PAGE RESERVED

NITROCELLULOSE SOLUTION, FLAMMABLE, with not more than 12.6% nitrogen by dry mass and not more than 55% nitrocellulose.
UN No. 2059
Formula
Explosive Limits
(C6H10O5)n
Properties When involved in a fire evolves toxic nitrous fumes. Observations For NITROCELLULOSE, WETTED, with not less than 25% alcohol by mass, UN No. 0342, see . For PAINT or PAINT, RELATED MATERIAL, containing 20% or less nitrocellulose with not more than 126% nitrogen, see UN No. 1263 in this class. For PRINTING INK, flammable, containing 20% or less nitrocellulose, see UN No. 1210 in this class.
CELLULOSE NITRATE SOLUTION, COLLODION SOLUTION, LACQUER BASE SOLUTION, NITROCOTTON SOLUTION, PYROXYLIN SOLUTION.
Packing See table 3.4 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2842 Formula C2H5NO2 Explosive Limits 3.4% to Flashpoint 28 C c.c.

NITROETHANE.
Properties Colourless oily liquid. When involved in a fire evolves nitrous toxic fumes. Slightly soluble in water. Observations Irritating to skin eyes and mucous membranes.

NITROGLYCERIN MIXTURE, DESENSITIZED, LIQUID, FLAMMABLE, N.O.S. , with not more than 30% nitroglycerin, by mass [new schedule]
UN No. 3343
Formula
CH2NO3CHNO3CH2NO3
Explosive Limits
Flashpoint * 23C c.c. to 61 C c.c.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Packaging group: as assigned by Observations the competent authority on the ba* Also listed in low and intermediate flashpoint groups. These substances should not be sis of the criteria set out in paraclassified and transported unless authorized by the competent authority on the basis of graph 3.1.2 of the introduction to this results from Series 2 tests and a Series 6(c) test on packages as prepared for transport (see the United Nations Recommendations on the Transport of Dangerous Goods, Manual of class.
Tests and Criteria).
Label of class
3

PAINT (including paint, lacquer, enamel, stain, shellac solution, varnish, polish, liquid filler and liquid lacquer base) or PAINT RELATED MATERIAL (including paint thinning or reducing compound).
UN No. 1263
Formula
Explosive Limits
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Miscibility with water depends upon the composition. Observations May contain 20% or less nitrocellulose provided the nitrocellulose contains not more than 12.6% nitrogen. A substance specifically identified by name in this Code should not be shipped under this entry.
Packaging group: Ill Label of class
3
Packing See 3.2.6 and table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.

PARALDEHYDE. para-ACETALDEHYDE-2,4,6-TRIMETHYL1,3,5-TRIOXANE
UN No. 1264
Formula C6H12O3
Explosive Limits 1.3% to
Properties Colourless liquid. Miscible with water. Observations Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2286
Formula
Explosive Limits
C12H26

PENTAMETHYLHEPTANE. ISODODECANE.
Properties Colourless liquid. Immiscible with water. Observations
UN No. 2310
Formula CH3COCH2COCH3
Explosive Limits 1.7% to

PENTANE-2,4-DIONE. 2,4-PENTANEDIONE ACETYLACETONE
Properties Colourless liquid. Miscible with water. Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 3.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
3
6.1
UN No. 1105
Formula C5H11OH
Explosive Limits 1.2% to 10.5%

PENTANOLS. AMYL ALCOHOLS, DIETHYL CARBINOL, ISOAMYL ALCOHOL, METHYLBUTANOLS.
Properties Colourless liquids with a strong odour. Immiscible with water. Observations
Label of class
CLASS 4.1 F l a m m a b l e s o l i d s
UN No. 3317
2-AMINO-4,6-DINITROPHENOL, WETTED, with not less than 20% water, by mass. PICRAMIC ACID, WETTED.
Formula C6H2(NO2)2(NH2)OH
Properties Desensitized explosive. Red crystals. Insoluble in water. Explosive in the dry state. May form extremely sensitive compounds with heavy metals or their salts. When involved in a fire, evolves toxic fumes, in closed compartments these fumes may form an explosive mixture with air. Observations Harmful if swallowed or by skin contact. Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport.
Packing Hermetically sealed: 1 Glass or plastics inner packagings, packed together in a wooden box (4C1), (4D), (4F) fibreboard box (4G) fibre drum (1G) 2 Liner in a wooden box (4C2, 4D, 4F) fibre drum (1G) 3 Drum, plastics (1H2) Receptacle net kg Package gross kg
Packaging group: I
Label of class
50 30 50 125 50 90
4.1
Stowage Category E. AWAY FROM class 3 and lead and its compounds. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
AMMONIUM PICRATE, WETTED with not less than 10% water, by mass
UN No. 1310
Formula NH4C6H2(NO2)3O
Properties Desensitized explosive. Substance in pure form consists of yellow crystals. Explosive and sensitive to friction in the dry state. May form extremely sensitive compounds with heavy metals or their salts. Observations Harmful if swallowed or by skin contact. Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For AMMONIUM PICRATE, dry or wetted with less than 10% water, by mass, UN No. 0004, see .
Packing Hermetically sealed: 1 Glass or plastics inner packagings, packed together in a wooden box (4C1), (4D), (4F) fibreboard box (4G) fibre drum (1G) 2 Liner in a wooden barrel (2C2) or fibre drum (1G) Receptacle net / Package gross kg
Packaging group: I
50 30 50 50
Note: Packagings should be lead-free.
Stowage Category D. AWAY FROM class 3 and lead and its compounds. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
DIPICRYL SULPHIDE, WETTED, with not less than 10% water, by mass. HEXANITRODIPHENYL SULPHIDE, WETTED.
UN No. 2852
Formula [(NO2)3C6H2]2S
Properties Desensitized explosive. Golden-yellow, crystalline leaflets. Explosive and sensitive to shock and heat in the dry state. Observations Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For DIPICRYL SULPHIDE, dry or wetted with less than 10% water, by mass, UN No. 0401, see Packing Hermetically sealed. Glass receptade(s), sealed with soft stopper(s) compatible with the substance enclosed, packed in a wooden box (4C1), (4D), (4F). Stowage Category D. AWAY FROM class 3. Package net
Packaging group: I
500 g
UN No. 1323
FERROCERIUM.
Formula
4.1
FIBRES, VEGETABLE, DRY. COTTON, DRY FLAX, DRY HEMP, DRY JUTE, DRY KAPOK, DRY SISAL, DRY VEGETABLE FIBRES, DRY
Properties Alloy derived from cerium or misch metal with the addition of 10% to 65% iron. Emits sparks when struck. Observations The provisions of this Code should not apply to Ferrocerium stabilized against corrosion with a minimum iron content of 10%. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class. UN No. Formula
Label NO LABEL REQUIRED
Properties Ignite readily. Observations The packaging performance tests referred to in section 10 of the General Introduction and in Annex I to this Code should not apply to these materials. For COTTON, WET, UN No. 1365, FIBRES, VEGETABLE, N.O.S., with animal or vegetable oil, UN No. 1373, and FIBRES, VEGETABLE, burnt, wet or damp, see class 4.2. The provisions of this Code should not apply to consignments of COTTON DRY having a density of not less than 360 kg/m3 (according to ISO Standard 8115 (1986)) and carried in closed cargo transport units (CTUs). Packing Tightly secured bales. Stowage Category A. AWAY FROM animal or vegetable oils. Unless carried in closed cargo transport units bales should be properly covered by tarpaulins or the like Cargo spaces should be clean dry and free from oil or grease. Ventilator cowls leading into the cargo space should have spark preventing screens. All other openings entrances and hatches leading to the cargo space should be securely closed. During temporary interruption of loading when the hatch remains uncovered a fire watch should be kept. During loading or discharge smoking in the vicinity should be prohibited and firefighting appliances kept ready for immediate operation. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
HAFNIUM POWDER, WETTED with not less than 25% water (a visible excess of water must be present), (a) mechanically produced having a particle size less than 53 microns; or (b) chemically produced having a particle size less than 840 microns.
UN No. 1326
Formula Hf
Properties Insoluble in water. Liable to spontaneous combustion when dry. Forms explosive mixtures with most oxidizing substances such as chlorates nitrates perchlorates and permanganates. Observations Refuse for shipment damaged or leaking receptacles. For HAFNIUM POWDER, DRY, UN No. 2545, see class 4.2. The provisions of this Code should not apply to this substance: (a) mechanically produced having a particle size of 53 microns or greater; or (b) chemically produced having a particle size of 840 microns or greater. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
BAGS ARE NOT ALLOWED.
Packaging group: II
Label of class
4.1
For IBCs see section 26 of the General Introduction. Stowage Category E. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1327
HAY STRAW BHUSA
Formula
Properties Ignites readily. Liable to spontaneous combustion when wet, damp or contaminated with oil. Observations Refuse for shipment when loose, damp, wet or contaminated with oil. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to Its low degree of danger. The provisions of this Code should not apply to consignments of compressed baled hay with a moisture content of less than 14% shipped in closed cargo transport units and accompanied by a certificate from the shipper stating that the product does not present any Class 4.1, UN No. 1327 hazard in transport and that its moisture content is less than 14%. Packing Tightly secured bales. For IBCs see section 26 of the General Introduction.
Stowage Category A. AWAY FROM animal or vegetable oils. Unless carried in closed cargo transport units, bales should be properly covered by tarpaulins or the like. Cargo spaces should be clean, dry and free from oil or grease. Ventilator cowls leading into the cargo space should have spark-preventing screens. All other openings, entrances and hatches leading to the cargo space should be securely closed. During temporary interruption of loading, when the hatch remains uncovered, a fire-watch should be kept. During loading or discharge, smoking In the vicinity should be prohibited and fire-fighting appliances kept ready for immediate operation. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
NITROCELLULOSE with not more than 12.6% nitrogen, by dry mass, MIXTURE WITH or WITHOUT PLASTICIZER, WITH or WITHOUT PIGMENT. CELLULOSE NITRATE WITH PLASTICIZING SUBSTANCE COLLODION COTTON WITH PLASTICIZING SUBSTANCE NITROCOTTON WITH PLASTICIZING SUBSTANCE
UN No. 2557
Formula
[C6H7O2(OH)3-(ONO2)X]n
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Nitrocellulose may be in granular form or in flakes. This product may also contain added pigments. When involved in a fire evolves toxic fumes, in closed compartments, these fumes may form an explosive mixture with air Burns extremely rapidly with intense heat radiation. Observations
The formulation should be prepared so that it remains homogeneous and does not separate during transport. The provisions of this Code do not apply to formulations with low nitrocellulose contents which, 1. do not show dangerous properties when tested for their liability to detonate deflagrate or explode when heated under defined confinement in tests of Test Series 1(a), 2(b) and 2(c) respectively in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Part I; and 2. are not shown to be flammable solids when tested in accordance with chapter 14 of the United Nations Recommendations on the Transport of Dangerous Goods, or test N1 in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria Part III, sub-section 33.2.1.4 (chips, if necessary crushed and sieved to a particle size of less than 1.25 mm). Refuse for shipment damaged or leaking receptacles. For NITROCELLULOSE, unmodified or plasticized with less than 18% plasticizing substance, by mass, UN No. 0341, see . For NITROCELLULOSE, PLASTICIZED with not less than 18% plasticizing substance by mass, UN No. 0343, see .
Packaging group: II
Label of class
4.1
Packing Hermetically sealed 1 Cans, packed together in a wooden box (4C1),(4D),(4F) f ibreboard box (4G) fibre drum (1G) 2 Plastics receptacles or bags, packed together in a wooden box (4C2), (4D), (4F) fibreboard box (4G) 3 Liner in a wooden box (4C1), (4D), (4F) 4 Plastics bag packed in a fibre drum (1G) 5 Water-resistant fibre drum with vapour barrier (1G) 6 Drum, steel (1A2) 7 Paper bag (5M2) should be carried in cargo transport units (CTUs)
Receptacle net l 20 20 20
Package gross kg 125 40 125
125 40 125 225 225
225 55
Note: Receptacles should be so constructed that explosion is not possible by reason of increased internal pressure
Stowage Category D. AWAY FROM class 3. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class IMDG CODE - PAGE 4160 Amdt. 29-98
NITROCELLULOSE WITH not less than 25% WATER, by mass CELLULOSE NITRATE WITH WATER COLLODION COTTON WITH WATER NITROCOTTON WITH WATER
UN No. 2555
Formula
Properties Desensitized explosive. Nitrocellulose may be granular or in flakes blocks or fibrous form. When involved in a fire, evolves toxic fumes in closed compartments these fumes may form an explosive mixture with air. Observations Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For NITROCELLULOSE, dry or wetted with less than 25% water, by mass, UN No. 0340, see .
Packing Hermetically sealed: 1 Cans, packed together in a wooden box (4C1), (4D), (4F) 2 Plastics receptacles or bags packed together in a wooden box (4C1), (4D), (4F) fibreboard box (4G) 3 Liner in a wooden box (4C1), (4D), (4F) 4 Plastics bag, packed in a fibre drum (1G) 5 Water resistant fibre drum with vapour barrier (1G) 6 Drum steel (1A2) Receptacle net l 20 Package gross kg 125
Packaging group: II
Label of class
4.1
125 40 125 225 225 225
Note: Receptacles should be so constructed that explosion is not possible by reason of increased internal pressure.
Stowage Category E. AWAY FROM class 3. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 3270
NITROCELLULOSE, MEMBRANE FILTERS
Formula
Properties Filters may be small round pieces or large sheets. When involved in a fire, evolves toxic fumes in closed compartments these fumes may form an explosive mixture with air. Burns rapidly with intense heat radiation. Observations The nitrogen content of the nitrocellulose should not exceed 11.5%. Packing Each single filter sheet should be packed between sheets of glazed paper. The proportion of glazed paper between the filter sheets should be not less than 65%, by mass. The membrane filters/paper arrangement should not be liable to propagate a detonation as tested by one of the tests described in the United Nations Recommendations on the Transport of Dangerous Goods, Tests and Criteria, Part I, Test Series I (a), Receptacle net kg Package gross kg
Packaging group: II
Label of class
4.1
Suitable small quantities in fibreboard boxes, plastics packagings or wrapped in paper, in a fibreboard box (4G) 30
Note: Packagings should be so constructed that explosion is not possible by reason of increased internal pressure.
Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
NITROGLYCERIN MIXTURE, DESENSITIZED, SOLID, N.O.S., with more than 2% but not more than 10% nitroglycerin, by mass.
UN No. 3319
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Desensitized explosive with lactose, glucose or cellulose. White solid Soluble in water. When involved in a fire the nitroglycerin may accumulate and may produce an explosion. Contact with water may dissolve the desensitizer (lactose or glucose) causing migration and accumulation of the nitroglycerin which may explode. Nitroglycerin is more dense than water. When involved in a fire, evolves toxic fumes, in closed compartments these fumes may form an explosive mixture with air Inhalation of vapours may cause headaches, dizziness and fainting. Observations This substances should not be transported under the provisions of this class unless specifically authorized by the competent authority. Packing As approved by the competent authority. Stowage Category E. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Packaging group:
Label of class
4.1
NITROSTARCH, WETTED, with not less than 20% water, by mass.
UN No. 1337
12
Formula C H (NO ) O
12 2 8 10
Properties Desensitized explosive. Orange powder. Explosive and sensitive to friction in the dry state. When involved in a fire evolves toxic fumes in closed compartments these fumes may form an explosive mixture with air. Packaging group I Observations Refuse for shipment damaged or leaking receptacles. This substance may be carried under the provisions of this class only if it is so packaged that the percentage of water will not fall below that stated above at any time during transport. For NITROSTARCH, dry or wetted with less than 20% water, by mass, UN No. 0146, see .
Packing
Receptacle net l 20 -
Package kg 125 125 75 225
Label of class
Hermetically sealed 1 Cans packed together in a wooden box (4C1), (4D), (4F) 2 Liner in a wooden box (4C2), (4D), (4F)
4.1
3 Plastics bag packed individually in a fibre drum (1G) 4 Drum steel (1A2)
Stowage Category D. AWAY FROM class 3. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2213
PARAFORMALDEHYDE
Formula [HCHO] n or HO [CH2O] H
Label NO LABEL REQUIRED. Package to be marked CLASS
4.1
Properties White powder with a pungent odour. Evolves formaldehyde particularly when heated which is irritating to eyes and mucous membranes. Observations Refuse for shipment damaged or leaking receptacles. Harmful if swallowed by skin contact or by inhalation. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 4.1. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Any sift proof tear proof receptacles. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks see section 25 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
PENTAERYTHRITE, TETRANITRATE MIXTURE, DESENSITIZED, SOLID, N.O.S., with more than 10% but not more than 20% PETN, by mass [new schedule]
UN No. 3344
Formula
Packaging group: III Label of class
Properties MARINE POLLUTANT

Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code.
4.1
Observations This substance should not be transported under the provisions of this class unless specifically authorized by the competent authority. Packing Unless otherwise approved by the competent authority based on a Series 6(c) test (see United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria) the packaging should be:
Receptacle net kg Plastics liner in a fibre drum (1G) Package gross kg 20
Stowage Category E. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
PHOSPHORUS, AMORPHOUS PHOSPHORUS, RED
UN No. 1338
Formula P
Properties Reddish-brown powder. Insoluble in water. Ignites readily by friction. When involved in a fire, evolves irritating fumes. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful, if swallowed, or by dust inhalation Packing See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction. Stowage Category A.
SEPARATED FROM class 5.1.
Label of class
4.1
PHOSPHORUS HEPTASULPHIDE, free from yellow or white phosphorus
UN No. 1339 Formula P4S7
Packaging group: II
Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
Label of class
4.1
For IBCs see section 26 of the General Introduction. Stowage Category B.

PHOSPHORUS SESQUISULPHIDE, free from yellow or white phosphorus
UN No. 1341
Formula P4S3
Packaging group: II
Label of class
Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
4.1
PHOSPHORUS TRISULPHIDE, free from yellow or white phosphorus

SEPARATED FROM class 5.1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1343
Formula P2S3 or P4S6
Packaging group: II
Label of class
4.1
Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air, evolving toxic and flammable gases. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.

SEPARATED FROM class 5.1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
CLASS 4.2 S p o n t a n e o u s l y c o m b u t i b l e
UN No. 3051
ALUMINIUM ALKYLS TRIBUTYLALUMlNIUM TRIETHYLALUMINIUM TRIISOBUTYLALUMINIUM TRIMETHYLALUMINIUM TRIPROPYLALUMINIUM
Formula
Packaging group: I Label of class
Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas. Observations Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.2
4.3
ALUMINIUM ALKYL HALIDES ALUMINIUM ALKYL BROMIDES METHYLALUMINIUM SESQUIBROMIDE ALUMINIUM ALKYL CHLORIDES DIETHYLALUMINIUM CHLORIDE ETHYLALUMINIUM CHLORIDE ETHYLALUMINIUM SESQUICHLORIDE METHYLALUMINIUM SESQUICHLORIDE
UN No. 3052
Formula
Properties Liquids or solids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas. Observations Packing Hermetically sealed. For liquids see table 1 in the introduction to this class.
For solids Hermetically sealed:
Receptacle net Package gross
Packaging group: I
kg
kg
Label of class
1 Glass receptacles, packed with inert cushioning material together in a wooden box (4C1), (4D), (4F) 1 1 75 40 75 40 250
4.2
fibreboard box (4G) 2 Cans, packed together in a wooden box (4C2), (4D), (4F) fibreboard box (4G) 3 Drum, metal (1A2), (1B2)
4.3
For tanks see section
13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
ALUMINIUM ALKYL HYDRIDES
UN No. 3076
Formula
Packaging group: I
Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water acids halogens alcohols and amines evolving flammable gas. Observations Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
4.2
4.3
ALUMINIUM BOROHYDRIDE or ALUMINIUM BOROHYDRIDE IN DEVICES
UN No. 2870
Formula AI(BH4)3
Packaging group: I
Properties Liquid. Ignites spontaneously in air. Reacts with water or steam to produce heat or hydrogen which may form explosive mixtures with air. Observations
Label of class
4.2
Packing Hermetically sealed. See table 1 in the introduction to this class.

Note: The number of inner packagings should be restricted to 8 (eight) receptacles of maximum 1 litre each.
4.3
CARBON, animal or vegetable origin CHARCOAL, non-activated CARBON BLACK
UN No. 1361
Formula
Packaging group: II or III according to the grouping criteria. Label of class
4.2
Properties Black powder or granules. Liable to heat slowly and ignite spontaneously in air. Observations The material as offered for shipment should have been sufficiently heat-treated and cooled down before packing. The provisions of this Code should not apply to non-activated carbon blacks of mineral origin. The provisions of this Code should not apply to a consignment of carbon or charcoal if it passes the test for self-heating substances as reflected in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria (see 33.3.1.3.3), and is accompanied by an appropriate certificate from a laboratory accredited by the competent authority stating that the consignment to be loaded has been correctly sampled by trained staff from that laboratory and that the sample was correctly tested and has passed the test. Packing See TABLE 2 in the introduction to this class.
BAGS (5M1), 55 kg, ARE ALLOWED
For IBCs see section 26 of the General Introduction. Stowage Category A. Keep as cool as possible. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No.
CARBON, ACTIVATED CHARCOAL, ACTIVATED
Formula
1362
4.2
Properties Black powder or granules. Liable to heat slowly and ignite spontaneously in air. Observations The material as offered for shipment should have been sufficiently heat-treated and cooled down before packing. Carbons made by a steam activation process are not subject to the provisions of this Code. The provisions of this Code should not apply to a consignment of carbon or charcoal if it passes the test for self-heating substances as reflected in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria (see 33.3.1.3.3), and is accompanied by an appropriate certificate from a laboratory accredited by the competent authority, stating that the consignment to be loaded has been correctly sampled by trained staff from that laboratory and that the sample was correctly tested and has passed the test. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
BAGS (5M1), 55 kg, in hermetically sealed plastics bags or wrapping, shrink- or stretch-wrapped on to pallets ARE ALLOWED.
For IBCs see section 26 of the General Introduction. Stowage Category A. Keep as cool as possible. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
PAGE RESERVED
UN No. 2002
CELLULOID SCRAP
Formula
Properties Plastics composed mainly of nitrocellulose containing not more than 11.5% nitrogen, and camphor. Comprises trimmings, clippings and other waste obtained in the manufacture of celluloid articles. Ignites readily. When involved in a fire, evolves toxic fumes, in enclosed cargo spaces,these fumes may form an explosive mixture with air. Observations For CELLULOID, UN No. 2000, see class 4.1. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category D.
Label of class
4.2
UN No. 1363
COPRA
Formula
Properties Dried kernels of coconuts with a penetrating rancid odour, which may taint other cargoes. Observations This substance should preferably have been weathered for not less than one month before shipment unless a certificate from a person recognized by the competent authority of the country of shipment states a maximum moisture content of 5%. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Any sift proof tear proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. Stowage Category A. Keep as dry as reasonably practicable. Protect from sparks and open flame. Provide a good through ventilation for bagged cargo. Double strip stowage recommended. The illustration on page 4236 shows how this can be achieved. The cargo should be stowed away from pipes and bulkheads, which are liable to become heated (e.g. engine room or heated fuel tank bulkheads). During the voyage, regular temperature readings should be taken at varying depths in the hold and recorded If the temperature of the cargo exceeds the ambient temperature and continues to increase ventilation should be closed down. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label NO LABEL REQUIRED Cargo transport units carrying a full load of copra to be marked CLASS 4.2.
CLASS 4.2 - Spontaneously combustible

COTTON WASTE, OILY, impregnated with 5%, or more, of animal or vegetable oil.
UN No. 1364
Formula
Properties Fibres of vegetable origin. Packaging group: III Label of class Observations
4.2
Packing Hermetically sealed. See TABLE 2 in the introduction to this class.

For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1364 Formula
COTTON WASTE, OILY impregnated with less than 5% of animal or vegetable oil.
Properties Fibres of vegetable origin in a dry state. Observations Bales carried as a full load in a cargo transport unit are exempted from displaying the label, provided the unit in which the bales are packed is placarded. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Tightly secured bales. For IBCs see section 26 of the General Introduction. Stowage Category A.
SEPARATED FROM animal or vegetable oils.
Label of class
4.2
UN No. 1365
COTTON, WET
Formula
Label of class
Properties Readily combustible, liable to ignite spontaneously according to moisture content. Observations COTTON, DRY is entered under FIBRES, VEGETABLE, DRY in class 4.1. Bales carried as a full load in a cargo transport unit are exempted from displaying the label, provided the unit in which they are packed is placarded. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Tightly secured bales. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.2
UN No. 1366
DIETHYLZINC ZINC DIETHYL ZINC ETHYL
Formula Zn(C 2H 5)2
Properties Liquid. Ignites spontaneously in air or carbon dioxide. Decomposes in contact with water, evolving ethane, a flammable gas. Observations
Packaging group: I
Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Prohibited on any ship carrying goods of class 1 with the exceptions listed in 6.1.4.2 of the introduction to class 1.
Label of class
4.2
4.3
UN No. 1370
DIMETHYLZINC ZINC DIMETHYL
Formula Zn(CH 3)2
Properties Liquid. Boiling point 46C. Ignites spontaneously in air or carbon dioxide. Decomposes in contact with water, evolving methane, a flammable gas. Observations
Packaging group: I Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Label of class Stowage Category D. Prohibited on any ship carrying goods of class 1 with the exceptions listed in 6.1.4.2 of the introduction to class 1.
4.2
4.3
FERROUS METAL BORINGS, SHAVINGS, TURNINGS, or CUTTINGS, in a form liable to self-heating. IRON SWARF. STEEL SWARF.
UN No. 2793
Formula
Properties These cargoes are liable to self-heating and to ignite spontaneously, particularly when in a finely divided form, wet or contaminated with such materials as unsaturated cutting oil, oily rags and other combustible matter. Self-heating or inadequate ventilation may cause dangerous depletion of oxygen in the stowage spaces.
Label of class
4.2
Observations Excessive amounts of cast iron borings or organic materials may encourage heating. The swarf should be protected from moisture prior to and after loading. If, during loading, the weather is inclement hatches should be closed and otherwise protected to keep the material dry. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. The provisions of this Code should not apply to consignments of this substance which are accompanied by a declaration of the shipper stating that it has no self-heating properties.
Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks, see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. Stowage Category A. Notes:
(1) Prior to loading, temperature of the swarf should not exceed 55C. Wooden sweat battens, dunnage and debris should be removed from the hold before the swarf is loaded; (2) Surface temperature of the swarf should be taken prior to, during and after loading and daily during the voyage. If the surface temperature exceeds 90C during loading, further loading should cease and should not recommence until the temperature has fallen to at least 85C. The vessel should not sail on an international voyage unless the temperature is below 65C, and has shown a steady or downward trend in temperature for at least eight hours. During loading and carriage, the bilge of each hold in which the swarf is stowed should be as dry as practicable. During loading, the swarf should be compacted in the hold as frequently as practicable with a bulldozer or by other means. After loading, the swarf should be trimmed to eliminate peaks and should be compacted; (3) Whilst at sea, any rise in surface temperature of the swarf indicates a selfheating reaction problem. If the temperature should rise to 80C, a potential fire situation is developing and the vessel should make for the nearest suitable port. Water should not be used at sea. Early application of an inert gas to a smouldering situation may be effective In port, copious quantities of water may be used but due consideration should be given to stability; (4) Entry into cargo spaces containing swarf should only be made with the main hatches open or when using breathing apparatus.
Reserve page
UN No. 2445
LITHIUM ALKYLS BUTYL LITHIUM
Formula
Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas. Observations
Packaging group: I
Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
4.2
4.3
UN No. 3053
MAGNESIUM ALKYLS DIETHYLMAGNESIUM DIMETHYLMAGNESIUM
Formula
Properties Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water acids, halogens, alcohols and amines, evolving flammable gas. Observations Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Prohibited on any ship carrying goods of class 1 with the exceptions listed in 6.1.4.2 of the introduction to class 1. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.2
4.3
UN No. 2004
Formula Mg(NH2)2
MAGNESIUM DIAMIDE
Properties White powder. Ignites spontaneously in air. Reacts violently in contact with water. Observations
Receptacle net g Package gross kg
Packing Hermetically sealed. Glass ampoules, with inert cushioning and absorbent material of sufficient capacity to absorb contents, each in a metal can, packed together in a wooden box (4C1), (4D), (4F)
50 50
45 45
wooden barrel (2C2)
4.2
Stowage Category C. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
METAL ALKYLS, WATER-REACTIVE,
N.O.S.
or METAL ARYLS, WATER-REACTIVE, N.O.S.
UN No. 2003
Formula
Properties Packaging group: I Label of class MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines evolving flammable gas. Observations Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 3049 Formula
4.2
4.3
METAL ALKYL HALIDES, WATERREACTIVE, N.O.S. or METAL ARYL HALIDES, WATERREACTIVE, N.O.S.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water acids, halogens, alcohols and amines, evolving flammable gas. Observations Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
4.2
4.3
METAL ALKYL HYDRIDES, WATERREACTIVE, N.O.S. or METAL ARYL HYDRIDES, WATERREACTIVE, N.O.S.
UN No. 3050
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids. Ignite on exposure to air or carbon dioxide. React violently in contact with water, acids, halogens, alcohols and amines, evolving flammable gas. Observations
Packaging group: I
Packing Hermetically sealed. See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Label of class Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
4.2
Subsidiary risk label of class.
4.3
POTASSIUM DITHIONITE POTASSIUM HYDROSULPHITE
UN No. 1929
Formula K2S2O4
Properties Liable to heat and ignite spontaneously in air and to evolve sulphur dioxide, an irritating gas. Observations
Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED. For IBCs see section 26 of the General Introduction. Stowage Category E. Keep as dry as reasonably practicable. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1382 Formula K2S
4.2
POTASSIUM SULPHIDE, ANHYDROUS or POTASSIUM SULPHIDE, with less than 30% water of crystallization.
Packaging group: II
Properties Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids, evolves hydrogen sulphide, a toxic and flammable gas. Observations For POTASSIUM SULPHIDE HYDRATED with not less than 30% water of crystallization, UN No. 1847, see class 8. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
Label of class
4.2
For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
CLASS 4.2 - Spontaneously combustible

PYROPHORIC LIQUID, ORGANIC, N.O.S. PYROPHORIC LIQUID, INORGANIC, N.O.S. PYROPHORIC ORGANOMETALLIC COMPOUND (liquid), WATER-REACTIVE, N.O.S.
UN No. 2845 3194 3203
Formula
Packaging group: I
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP'' in the General Index to this Code. Highly flammable liquids, may ignite spontaneously in moist air. In contact with air, evolve irritating and slightly toxic fumes. Observations
Label of class
Packing Receptacle net g Package gross g
4.2
For UN No. 3203 only. Subsidiary risk label of class
Hermetically sealed: 1 Glass ampoule packed with inert cushioning material individually in a wooden box (4C1), (4D), (4F) 2 Cylinder
500 -
4.3
For carriage in tanks of UN Nos. 2845 and 3203 see section 13 of the General Introduction. Stowage Category D. Prohibited on any ship carrying goods of with the exceptions listed in 6.1.4.2 of the introduction to . Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No.
PYROPHORIC SOLID, INORGANIC,
Formula
N.O.S.
PYROPHORIC SOLID ORGANIC, N.O.S. PYROPHORIC METAL, N.O.S. or PYROPHORIC ALLOY, N.O.S. ALUMINIUM POWDER, PYROPHORIC BARIUM POWDER, PYROPHORIC CAESIUM POWDER, PYROPHORIC CERIUM POWDER, PYROPHORIC IRON POWDER, PYROPHORIC STRONTIUM ALLOY, PYROPHORIC STRONTIUM POWDER, PYROPHORIC ZINC POWDER, DUST, PYROPHORIC PYROPHORIC ORGANOMETALLIC COMPOUND (solid) WATER-REACTIVE, N.O.S. BARIUM ALLOY, PYROPHORIC CALCIUM PYROPHORIC or CALCIUM ALLOYS, PYROPHORIC
3200 2846 1383
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liable to ignite spontaneously in air. If shaken may produce sparks In contact with water, evolve hydrogen, a flammable gas. Observations
3203 1854 1855
Packing Hermetically sealed: 1 Glass receptacles packed with inert cushioning material together in a wooden box (4C1), (4D), (4F) fiberboard box (4G) 2 Cans, packed together in a wooden box (4C2), (4D), (4F) fiberboard box (4G) 3 Drum, metal (1A2), (1B2)
Receptacle net kg
Package gross kg
2 2 15 15 -
75 40 75 40 250
Stowage Category D. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
For UN No. 3203 only Subsidiary risk label of class
4.2
4.3
UN No. 1856
RAGS, OILY
Formula
Properties Liable to ignite spontaneously according to the oil content. Label of class Observations Bales carried as a full load in a cargo transport unit are exempted from displaying the label, provided the unit in which they are packed is placarded. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to these materials due to their low degree of danger. Packing Tightly secured bales. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General introduction and introduction to this class.
4.2
SEED CAKE, containing vegetable oil (a) mechanically expelled seeds, containing more than 10% of oil or more than 20% of oil and moisture combined. MEAL, oily OIL CAKE SEED EXPELLERS, oily
UN No. 1386
Formula
Properties Residue remaining after oil has been expelled mechanically from oilbearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), Niger seed palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets, meal etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously. Observations Refuse for shipment wet, oil-stained or damaged bags. Before shipment this cargo should be properly aged, the duration of ageing required varies with the oil content. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the hold(s) at any other time. If satisfied as a result of tests that such relaxation is justified, the competent authority may permit the seed cakes described in this schedule to be carried under conditions governing SEED CAKE on page 4258. Certificates from the shipper should state oil content and moisture content and should accompany the shipment. For SEED CAKES with other oil and moisture contents, see pages 4258 and 4259. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 4.2. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehicles) or portables tanks, see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.
Label NO LABEL REQUIRED. Package to be marked CLASS 4.2.
Stowage Category E. Keep dry. Notes:

(1) Through and surface ventilation is required; (2) If the voyage exceeds 5 days, the vessel should be equipped with facilities for introducing carbon dioxide or inert gas into the hold(s); (3) Bags should always be stowed in double strip as shown on page 4236 of this Code for fishmeal, unstabilized; (4) Regular temperature readings should be taken at varying depths in the hold and recorded If the temperature of the cargo exceeds 55 C and continues to increase, ventilation to the holds should be restricted If selfheating continues then carbon dioxide or inert gas should be introduced; (5) The cargo should be stowed AWAY FROM pipes and bulkheads which are liable to become heated (e. g. engine-room bulkhead).
SEED CAKE, containing vegetable oil (b) solvent extractions and expelled seeds, containing not more than 10% of oil and, when the amount of moisture is higher than 10%, not more than 20% of oil and moisture combined MEAL, oily OIL CAKE, SEED EXPELLERS, oily
UN No. 1386
Formula
Properties Residue remaining after oil has been extracted by a solvent process or expelled mechanically from oil bearing seeds. Used mainly as animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed maize (hominy chop), Niger seed, palm kernel rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes, pellets meal etc. May self-heat slowly and, if wet or containing an excessive proportion of unoxidized oil, ignite spontaneously.
Label NO LABEL REQUIRED Package to be marked CLASS 4.2.
Observations Refuse for shipment wet, oil stained or damaged bags. Before shipment this cargo should be properly aged, the duration of ageing required varies with the oil content. The seed cake should be substantially free from flammable solvent. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the cargo space(s) at any other time. If satisfied as a result of tests that such relaxation is justified, the competent authority may permit the seed cakes described in this schedule to be carried under conditions governing SEED CAKE, UN No. 2217, on page 4259. Certificates from the shipper should state oil content and moisture content and should accompany the shipment. For SEED CAKES with other oil and moisture contents, see pages 4257 and 4259. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 4.2. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger.
Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehicles) or portable tanks, see section 25 of the General Introduction For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes.
Stowage Category A. Keep dry. Notes:

(1) Surface ventilation is required to assist in removing any residual solvent vapour; (2) The cargo should be stowed away from pipes and bulkheads which are liable to become heated (e.g. engine-room bulkhead); (3) If bags are stowed without provision for ventilation to circulate throughout the stow and the voyage exceeds 5 days regular temperature readings should be taken at varying depths in the hold and recorded; (4) If the voyage exceeds 5 days the vessel should be equipped with facilities for introducing carbon dioxide or inert gas into the hold(s).
SEED CAKE, containing vegetable oil (c) solvent extractions containing not more than 1.5% of oil and 11% of moisture. MEAL, oily OIL CAKE, SEED EXPELLERS, oily
UN No. 2217
Formula
Label NO LABEL REQUIRED Package to be marked CLASS 4.2.
Properties Residue remaining after oil has been extracted by a solvent process from oil-bearing seeds Used mainly as an animal feed or fertilizer. The most common seed cakes include those derived from coconut (copra), cottonseed, groundnut (peanut), linseed, maize (hominy chop), Niger seed, palm kernel, rape seed, rice bran, soya bean and sunflower seed and they may be shipped in the form of cake, flakes pellets, meal etc. May self-heat slowly if wet and ignite spontaneously. Observations Refuse for shipment wet, oil-stained or damaged bags. The seed cake should be substantially free from flammable solvent. Smoking and the use of naked lights should be prohibited during loading and unloading and on entry to the hold(s) at any other time. For SEED CAKES with other oil and moisture contents, see pages 4257 and 4258. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number, provided the unit in which they are packed is marked CLASS 4.2. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. The provisions of this Code should not apply to a consignment of solvent-extracted SOYA BEAN MEAL containing not more than 1.5% oil and 11% moisture, being substantially free from flammable solvent, which is accompanied by a certificate from the shipper stating that the substance, as offered for shipment meets these requirements. Packing Any sift-proof, tear-proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehicles) or portable tanks, see section 25 of the General Introduction. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. Stowage Category A. Keep dry. Notes:
(1) Surface ventilation is required to assist in removing any residual solvent vapour; (2) The cargo should be stowed AWAY FROM pipes and bulkheads, which are liable to become heated (e.g. engine-room bulkhead).
UN No.
SELF-HEATING LIQUID, INORGANIC, N.O.S. SELF-HEATING LIQUID, ORGANIC, N.O.S.
Formula
3186 3183
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any self-heating liquid which, by the definition found in the introduction, is included in this class and which is not specified elsewhere in this class. Liable to self-heating or spontaneous combustion. Observations
Packaging group: II or III according to the grouping criteria.
Label of class
4.2
Packing Hermetically sealed. See table 1 in the introduction to this class. Stowage Category C. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 1431
SODIUM METHYLATE SODIUM METHOXIDE
Formula CH3ONa
Properties White, amorphous, free-flowing, hygroscopic powder. Decomposed by water to form methanol a flammable liquid, which may be ignited by the heat of the reaction. Observations Causes burns to skin eyes and mucous membranes. For SODIUM METHYLATE, SOLUTION in alcohol UN No. 1289, see class 3.2. Packing Hermetically sealed. See TABLE 2 in the introduction to this class. BAGS ARE NOT ALLOWED. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.2
8
SODIUM SULPHIDE, ANHYDROUS or SODIUM SULPHIDE with less than 30% water of crystallization.
UN No. 1385
Formula Na2S
Properties Black solid, absorbs moisture to become crystalline. Liable to ignite spontaneously. In contact with acids evolves hydrogen sulphide a toxic and flammable gas. Observations For SODIUM SULPHIDE HYDRATED with at least 30% water, UN No. 1849, see class 8. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
Packaging group: II
For IBCs see section 26 of the General Introduction. Label of class Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.2
TEXTILE WASTE, WET WOOL WASTE, WET
UN No.
Formula
Properties Liable to ignite spontaneously according to the moisture content. Observations Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
4.2
THIOUREA DIOXIDE FORMAMIDINE SULPHINIC ACID [new schedule]
Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 3341
Formula CH4N202S
Packaging group: II or III according to the grouping criteria Label of class
Properties White to yellow-white crystalline powder. Virtually odourless. Strong reducing agent Violent exothermic decomposition above 100 C with emission of large amounts of sulphur oxides, ammonia, carbon monoxide, carbon dioxide, nitrogen oxides and hydrogen sulphide. Extended exposure to temperatures above 50 C and moisture may cause visible decomposition. Observations Dust irritating to skin, eyes and mucous membranes.
Packing Hermetically sealed: Drum, fibre (1G) Bags (5H3), (5H4), (5L3), (5M2) 250 55 Receptacle net Package gross kg
4.2
For IBCs see section 26 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 3174
Formula TiS2
Properties Yellow or grey powder with an unpleasant odour. Observations In contact with water slowly evolves hydrogen sulphide gas. Packing Hermetically sealed. See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Label of class Packing, Stowage & Segregation See also General Introduction and introduction to this class.
TITANIUM DISULPHIDE
4.2
UN No. 3254
TRIBUTYLPHOSPHANE
Formula (C4H9)3P
Properties Colourless yellowish liquid. Insoluble in water. Strong garlic odour (phosphine). Liable to heat and ignite spontaneously in air. If involved in a fire evolves phosphine, a flammable and highly toxic
gas.
Reacts violently with oxidizing substances (peroxides, halogens, nitric oxides and carbon tetrachloride). Packaging group: I Observations Irritating to mucous membranes.
Packing Hermetically sealed: Receptacle net Package gross
Label of class
Contents completely covered under an inert gas blanket such as nitrogen or carbon dioxide in 1 Glass metal or plastics receptacles, packed with cushioning material together in a wooden box (4C1), (4D), (4F) fibreboard box (4G) 2 Composite packaging (glass, porcelain or stoneware) with a hermetically sealed inner receptacle in a steel drum (6PA1) 3 Steel jerrican (3A1) 5l 60 /
4.2
2 kg 2 kg
55 kg 40 kg
Stowage Category D.
SEPARATED FROM peroxides halogens nitric oxides and carbon tetra-
chloride Packing, Stowage & Segregation See also General Introduction and introduction to this class.
XANTHATES [new schedule]
UN No. 3342
Formula
Properties Hygroscopic yellow powder with an unpleasant odour. On contact with moisture, evolves highly flammable vapours such as carbon disulphide (UN No. 1131 which has a flashpoint of -30 C and a very low ignition temperature of 100 C). When confined, can cause an explosion due to the wide explosive limits of the vapours. Finely divided dust forms explosive mixtures in air. Observations Care should be taken when opening cargo transport units (CTUs) in case carbon disulphide vapours are present. Packing Hermetically sealed. See TABLE 2 in the introduction to this class.
Packaging group: II or III according to the grouping criteria
Label of class
For IBCs see section 26 of the General Introduction. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.2
ZIRCONIUM, DRY, finished sheets, strip or coiled wire (thinner than 18 microns)
UN No. 2009
Formula Zr
Properties Hard, silvery metal, liable to ignite spontaneously in air. Observations For ZIRCONIUM, DRY, not thinner than 18 microns. UN No. 2858, see class 4.1.
Receptacle net Package gross kg 225 55
Packing Plastics wrapper in a wooden box (4C1), (4D), (4F) fibreboard box (4G)
Label of class
4.2
CLASS 4.3 D a n g e r o u s w h e n w e t
CERIUM turnings or gritty powder
UN No. 3078
Formula Ce
Properties Grey ductile metal or powder. Decomposes in water and reacts violently with acids evolving hydrogen which may be ignited by the heat of the reaction. Observations For PYROPHORIC METAL, UN No. 1383, see class 4.2.
Packing
Packaging group: II
Hermetically sealed 1 Glass receptacles packed together in a sift proof wooden box (4C2), (4D), (4F) 2 Metal cans packed together in a wooden box (4C2), (4D), (4F) fibreboard box (4G) 3 Drum metal (1A2), (1B2)
Receptacle net kg
Package gross kg
1 10 10 -
115 115 40 250
For IBCs see section 26 of the General Introduction. Label of class Stowage Category E. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.3
CHLOROSILANES, WATER-REACTIVE, FLAMMABLE, CORROSIVE, N.O.S.
UN No. 2988
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless, very volatile liquids, flammable and corrosive, with a pungent odour. Immiscible with water. React violently with water or steam to produce heat which may lead to self-ignition, toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Observations Causes burns to skin, eyes and mucous membranes.
Packing Receptacle net Package gross
Packaging group: I
Label of class
4.3
Hermetically sealed 1 Glass receptacles, packed with inert cushioning and absorbent material together in a wooden box (4C2), (4D), (4F) metal drum (1A2), (1B2) 2 Drum metal (1A1), (1B1)
1l 1l -
30 kg 30 kg 250 /
For tanks see section 13 of the General Introduction. Stowage Category D. Clear of living quarters. Segregation as for class 3 but AWAY FROM classes 3, 4.1 and 8. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
3 and 8
UN No. 1183
ETHYLDICHLOROSILANE
Formula C2H5SiHCl2
Properties Colourless, very volatile liquid with a pungent odour. Flashpoint -1 C c. c. Immiscible with water. Reacts violently with water or steam to produce heat which may lead to self-ignition, toxic and corrosive fumes will be evolved. May react vigorously in contact with oxidizing substances. Observations Causes burns to skin, eyes and mucous membranes.
Packing Hermetically sealed Receptacle net Package gross
Packaging group: I
Label of class
1 Glass receptacles, packed with inert cushioning and absorbent material together in a wooden box (4C2), (4D), (4F) metal drum (1A2), (1B2) 2 Drum, metal (1A1), (1B1) For tanks see section 13 of the General Introduction 1/ 1/ 30 kg 30 kg 250 /
4.3
3 and 8
Stowage Category D. Clear of living quarters. Segregation as for class 3 but AWAY FROM classes 3, 4.1 and 8. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
FERROSILICON with 30% or more but less than 90% silicon.
UN No. 1408
Formula
Properties In contact with moisture water alkalis or acids may evolve hydrogen a flammable gas which may form explosive mixtures with air and also arsine and phosphine which are highly toxic gases. These gases are evolved in proportions which under mechanically ventilated conditions make the poison hazard by far predominant over the explosion hazard. The rate of gas evolution is greatest from freshly broken surfaces so is liable to increase whenever the cargo is disturbed e.g. during loading. Observations Toxic if swallowed by skin contact or by vapour inhalation. Requires a certificate from maker or shipper stating the percentage of silicon and that after manufacture the shipment was stored under cover but in the open air, in the particle size in which it is to be shipped for not less than 3 days prior to shipment. The provisions of this Code should not apply to a consignment of ferrosilicon carried in packaged form if it passes the test for class 4.3, as reflected in the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria Part III - 33.4.1.4 and is accompanied by an appropriate certificate stating that the product was correctly tested and has passed the test. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Packing Any sift proof tear proof receptacle. For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks see section 25 of the General Introduction. For carriage in bulk (including shipborne barges; see the Code of Safe Practice for Solid Bulk Cargoes). Stowage Category A. Only to be loaded under dry weather conditions. Keep as dry as reasonably practicable. Under deck in a mechanically ventilated cargo space. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
4.3
6.1
ORGANOMETALLIC COMPOUND or COMPOUND SOLUTION or COMPOUND DISPERSION, WATER-REACTIVE, FLAMMABLE,
UN No. 3207
Formula
N.O.S.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any organometallic compound compound solution or compound dispersion which in contact with water emits flammable gases, which itself is flammable and which is neither specified by name in this class nor on account of its characteristics is proper to some other class. Observations
Packaging group I, II or III according to the grouping criteria.

Packing Hermetically sealed: 1 Metal cans packed together in a wooden box (4C2), (4D), (4F) fibreboard box (4G) 2 Drum metal (1A1), (1B1) 3 Cylinder
Receptacle net
Package gross
Label of class
15 kg 15 kg -
125 kg 40 kg* 250 /
4.3
* 55 kg for substances in packaging group III. For tanks see section General Introduction.
13 of the
3
Stowage Category E. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
PHOSPHORUS PENTASULPHIDE free from yellow and white phosphorus
UN No. 1340
Formula P2S5 or P4S10
Packaging group: II
Properties Yellow solid. Ignites readily by friction. Develops heat in contact with moist air evolving toxic and flammable gases. Forms explosive and extremely sensitive mixtures with most oxidizing substances, such as chlorates, nitrates, perchlorates or permanganates. Observations Harmful if swallowed or by dust inhalation.
Label of class
Packing Hermetically sealed. See table 2.4 in the introduction to this class.
4.3
For IBCs see section 26 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
4.1
UN No.
WATER-REACTIVE SOLID CORROSIVE N.O.S. WATER-REACTIVE SOLID, FLAMMABLE, N.O.S. WATER-REACTIVE SOLID TOXIC N.O.S.
Formula
3131 3132 3134
Properties MARINE POLLUTANT Packaging group: I, II or III according to the grouping criteria for each hazard Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any solid which in contact with water emits flammable gases which is corrosive or toxic and which is neither specified by name in this class nor, on account of its characteristics, is proper to some other class. Observations The conditions of transport should be approved by the competent authority of the country of origin. Packing As specifically designated by the competent authority of the country of origin. For IBCs see section 26 of the General Introduction. Stowage Packaging group I category D. Packaging group II and III category E. If under deck in a mechanically ventilated space. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
4.3
UN No. 3131 only Subsidiary risk label of class
8
4.1
6.1
PAGE RESERVED
CLASS 5.1 O x i d i z i n g s u b s t a n c e s
UN No.
OXIDIZING SOLID, TOXIC, N.O.S. OXIDIZING LIQUID, TOXIC, N.O.S.
Formula
3087 3099
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any oxidizing solid or liquid which is toxic and which is neither specified by name in this class nor on account of its characteristics is proper to some other class. Observations Toxic if swallowed by skin contact or by dust inhalation. Should be handled with care to minimize exposure particularly to dust. For TOXIC SOLID, OXIDIZING, N.O.S., UN No. 3086, see class 6.1. For TOXIC LIQUID, OXIDIZING, N.O.S., UN No. 3122, see class 6.1.
Packaging group for UN No. 3087 I, II or III according to the grouping criteria for each hazard for UN No. 3099 I, II or III according to 5.2.6 of the General Introduction.
Packing For solids of packaging group I only 1 Glass receptacles in a wooden box (4C1), (4D), (4F)
Receptacle net kg 5 5 5 5
Package gross kg 75 40 75 40 250 300 180 180 125 40 40
Label of class
fibreboard box (4G) 2 Metal cans or plastics receptacles in a wooden box (4C2), (4D), (4F) fibreboard box (4G) 3 Drum metal (1A2), (1B2) 4 Liner in a wooden barrel (2C2) fibre drum (1G) plywood drum (1D) 5 Plastics bags each in a fibreboard box in a wooden box (4C1), (4D), (4F) 6 Plastics bags in a fibreboard box (4G) 7 Plastics drum (1H2)
5.1
6.1
UN No. 3087, packaging groups II and III see table 2.4 in the introduction to this class. UN No. 3099, packaging group I see table 2.6 in the introduction to this class. Packaging groups II and III see table 2.5 in the introduction to this class. Stowage Packaging group I category D. Packaging groups II and III category B. Separated from powdered metals ammonium compounds cyanides and hydrogen peroxide. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 3356
OXYGEN GENERATOR CHEMICAL [new schedule]
Formula
Packaging group: II
Label of class
Properties Oxygen generators chemical are devices containing chemicals which upon activation release oxygen as a product of chemical reaction. Chemical oxygen generators are used for the generation of oxygen for respiratory support e.g. in aircraft submarines spacecraft bomb shelters and breathing apparatus. Oxidizing salts such as chlorates and perchlorates of lithium sodium and potassium which are used in chemical oxygen generators evolve oxygen when heated. These salts are mixed (compounded) with a fuel usually iron powder, to form a chlorate candle which produces oxygen by continuous reaction. The fuel is used to generate heat by oxidation. Once the reaction begins oxygen is released from the hot salt by thermal decomposition (a thermal shield is used around the generator). A portion of the oxygen reacts with the fuel to produce more heat which produces more oxygen, and so on. Initiation of the reaction can be achieved by a percussion device friction device or electric wire. Observations An oxygen generator chemical containing oxidizing substances should meet the following conditions: 1 the generator when containing an explosive actuating device should only be transported under this entry when excluded from in accordance with paragraph 2.1.3 of the United Nations Recommendations on the Transport of Dangerous Goods; 2 in addition to the requirements of packaging group II applicable to the package the generator without its packaging, should be capable of withstanding a 1.8 m drop test onto a rigid non-resilient flat and horizontal surface in the position most likely to cause damage without loss of its contents and without actuation; 3 when a generator is equipped with an actuating device it should have at least two positive means of preventing unintentional actuation. Packing See table 2.4 in the Introduction to this class. In addition the generator(s) should be transported in a package which will meet the following requirements when one generator in the package is actuated: 1. other generators in the package will not be actuated; 2. packaging material will not ignite; and 3. the outside surface temperature of the completed package must not exceed 100 C. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
5.1
UN No. 1496
SODIUM CHLORITE
Formula NaCIO2
Properties Colourless deliquescent solid Soluble in water. Reacts vigorously with sulphuric acid. Reacts fiercely with cyanides when heated or by friction. May form explosive mixtures with combustible material powdered metals or ammonium compounds. These mixtures are sensitive to friction and are liable to ignite. When involved in a fire may cause an explosion. Observations For SODIUM CHLORITE SOLUTION, UN No. 1908, see class 8. Packing See table 2.4 in the introduction to this class. Bags 5H3, 5H4, 5L3 and 5M2 allowed only in closed cargo transport units. For IBCs see section 26 of the General Introduction. Stowage Category A. Separated from powdered metals ammonium compounds and cyanides. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
5.1
UN No. 1498
Formula NaNO3
SODIUM NITRATE CHILE SALTPETRE
Properties Colourless deliquescent solid Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Observations Harmful if swallowed. This substance in the impure form is known as Chile Saltpetre. Packing See table 2.4 in the introduction to this class. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. For carriage in bulk packagings (freight containers road or rail vehicles) or portable tanks see section 25 of the General Introduction. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
5.1
SODIUM NITRATE AND POTASSIUM NITRATE, MIXTURE POTASSIUM NITRATE AND SODIUM NITRATE, MIXTURE
UN No. 1499
Formula NaNO3+ KNO3
Properties Colourless hygroscopic solid Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Observations Harmful if swallowed. Mixture prepared as a fertilizer. Packing See table 2.4 in the introduction to this class. For carriage in bulk (including shipborne barges) see the Code of Safe Practice for Solid Bulk Cargoes. For carriage in bulk packagings (freight containers road or rail. vehicles) or portable tanks see section 25 of the General Introduction. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1500 Formula NaNO2
5.1
SODIUM NITRITE
Properties Colourless deliquescent solid Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Mixtures with ammonium compounds or cyanides may explode. Decomposes if heated, giving off toxic nitrous fumes and gases supporting combustion. Observations Toxic if swallowed or by dust inhalation. Packing See table 2.4 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A.
SEPARATED FROM ammonium compounds and cyanides.
5.1
6.1
CLASS 5.2 O r g a n i c p e r o x i d e s
6 PACKING 6.1 6.1.1 6.1.2 6.1.3 6.1.4 General packing requirements To avoid unnecessary confinement metal packagings meeting the test criteria of packaging group I should not be used. Organic peroxides are assigned to packaging group II (medium danger). The packagings to be used should be appropriate to the physical state of the material to be transported. The packagings of an organic peroxide required to bear a subsidiary risk label of should comply with the provisions in 3.3.9 and 3.3.10 of the introduction to . All receptacles should be effectively closed. Where significant internal pressure may develop in a package by the evolution of gas a vent may be fitted provided the qas emitted will not cause danger, otherwise the degree of filling should be limited. Any venting device should be so constructed, that liquid will not escape when the package is in an upright position and it should be able to prevent ingress of impurities. The outer packaging, if any, should be so designed as not to interfere with the operation of the venting device.
6.1.5
When plastics drums plastics jerricans or composite packagings are used the compatibility of the plastics material with a liquid organic peroxide should be tested in accordance with 8.3.5 of Annex I to this Code. Organic peroxides may show damaging effects on plastics by, for example, stress, cracking, swelling or oxidative degradation. This can be tested by storing over a long period for example six months the packaging filled with the organic peroxide or with appropriate substitutes approved by the competent authority of the country of origin.
6.1.6
Packagings for organic peroxides should meet the requirements of Annex I to this Code and should be so constructed that none of the materials which are in contact with the contents will catalyse or otherwise dangerously affect the properties of their contents. For instance a metal drum should only be constructed of: 1 material compatible with its intended contents; or 2 material effectively treated so as to make it compatible with its contents or should be lined nally with an inert material. inter-
6.1.7
For combination packagings cushioning materials should not be readily combustible and should not cause decomposition of the organic peroxide, if leakage occurs. Except for classes 1.6.2 and 7 packaging requirements can be found in section 10 and Annex I of the General Introduction to this Code Provisions for the carriage of limited quantities of dangerous goods can be found in section 18. Types of packagings and limits The packing methods for organic peroxides are listed in 6.3 and are designated as OP1A to OP8A for liquids and OP1B to OP8B for solids. The quantities specified for each packing method represent the maximum currently considered good practice. The following kinds of packagings may be used: - drums conforming to 7.1, 7.2, 7.4, 7.6 or 7.7 of Annex I; or - jerricans conforming to 7.3 or 7.7; or
6.1.8
6.2 6.2.1
- boxes conforming to 7.8, 7.9, 7.10, 7.11, 7.12 or 7.13; or - composite packagings with a plastics inner receptacle conforming to 7.18 of Annex I to this Code; provided that:
I. II.
the provisions of Annex I are complied with; metal packagings (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8; in combination packagings, glass receptacles are used only as inner packagings with a maximum content of 0.5 kg or 0.5 l.
III.
6.2.2
The packing methods appropriate for the individual currently assigned organic peroxides are listed in the appendices to the individual schedules. A packing method corresponding to a smaller package size (i.e. with a lower OP number) may be used but a packing method corresponding to a larger package size (i.e. with a higher OP number) should not be used. For new organic peroxides or new formulations of currently assigned organic peroxides, the following procedure should be used to assign the appropriate packing method. 1 ORGANIC PEROXIDE TYPE B Packing method OP5A or OP5B should be assigned provided that the organic peroxide satisfies the criteria in 3.3.2 in one of the packagings shown for this packing method. If the organic peroxide can only satisfy these criteria in a smaller packaging than those listed for packing method OP5A or OP5B (i.e. one of the packagings listed for OP1A to OP4A or OP1B to OP4B) then the corresponding packing method with the lower OP number has to be assigned. 2 ORGANIC PEROXIDE TYPE C Packing method OP6A or OP6B should be assigned provided that the organic peroxide satisfies the criteria in 3.3.3 in one of the packagings shown for this packing method. If the organic peroxide can only satisfy these criteria in a smaller packaging than those listed for packing method OP6A or OP6B then the corresponding packing method with the lower OP number has to be assigned.
6.2.3
3 ORGANIC PEROXIDE TYPE D Packing method OP7A or OP7B should be assigned to this type of organic peroxide. 4 ORGANIC PEROXIDE TYPE E Packing method OP8A or OP8B should be assigned to this type of organic peroxide. 5 ORGANIC PEROXIDE TYPE F Packing method OP8A or OP8B should be assigned to this type of organic peroxide.
TABLE 1 - ORGANIC PEROXIDE LIQUID
Type and material
Packaging code (Annex I) 1A1 1A2 1B1 1B2 1D 1G 1H1 1H2 3A1 3A2 3B1 3B2 3H1 3H2 4A
Packing method OP1A P P P P 0.5 kg 0.5 kg 0.5 I 0.5 l P P P P 0.5 l 0.5 l P P 0.5 kg 0.5 kg 0.5 kg 0.5 kg 0.5 kg 0 5 kg OP2A P P P P 0.5 l / 10 kg 0.5 l / 10 kg P P P P P P 0.5 l / 10 kg 0.5 l / 10 kg 0.5 l / 10 kg 0.5 l / 10 kg 0.5 l / 10 kg 0.5 l / 10 kg
2
OP3A P P P P 5 kg 5 kg 5l 5l P P P P 5l 5l P P 5 kg 5 kg 5 kg 5 kg 5kg 5 kg
OP4A P P P P
OP5A P P P P 25 kg 25 kg 30 l 30 l P P P P 30 l 30 l P P 25 kg 25 kg 25 kg 25 kg 25 kg 25 kg
OP6A P P P P 50 kg 50kg 60 l 60 l P P P P 60 l 60 l P P 50 kg 50 kg 50 kg 50 kg 50 kg 50 kg
OP7A 60 l 50 kg 60 I 60 I 50 kg 50 kg 60 l 60 l 60 I 60 l 60 l 60 l 60 l 60 I 50kg 50kg 50 kg 50 kg 50 kg 50 kg 50 kg 50 kg
OP8A 225 l 200 kg 225 l 225 l 200 kg 200 kg 225 l 225 l 60 l 60 l 60 l 60 l 60 l 60 l 200 kg 200 kg 200 kg 200 kg 200 kg 200 kg 200 kg 200 kg
Steel drum Steel drum

3
Aluminium drum Aluminium drum Plywood drum Fibre drum

3 3
5 l / 25 kg 5 l / 25 kg P P P P P P 5 l / 25 kg 5 l / 25 kg 5 l / 25 kg 5 l / 25 kg 5 l / 25 kg 5 l / 25 kg
Plastics drum Plastics drum Steel jerrican Steel jerrican Aluminium jerrican Aluminium jerrican Plastics jerrican Plastics jerrican Steel box
3 3
Aluminium box Wooden box Wooden box Plywood box

3 3
4B 4C1 4C2 4D
3
Reconstituted wood box Fibreboard box Plastics box

3 3
4F 4G 4H2
TABLE 1 - ORGANIC PEROXIDE LIQUIDS1 (continued)

Packaging code (Annex I) 6HA1 Packing method OP1A P OP2A P
2
Type and material Plastics receptacle with outer steel drum Plastics receptacle with outer steel crate or box Plastics receptacle with outer aluminium drum Plastics receptacle with outer aluminium crate or box Plastics receptacle with outer wooden box Plastics receptacle with outer plywood drum Plastics receptacle with outer plywood box Plastics receptacle with outer fibre drum Plastics receptacle with outer fibreboard box Plastics receptacle with outer plastics drum Plastics receptacle with outer solid elastics box
OP3A P
OP4A P
OP5A p
OP6A P
OP7A 60 l
OP8A 225 l
6HA2
60 l
225 l
6HB1
60 l
225 l
6HB2
60 l
225 I
6HC
0.5 l
0.5 l / 10 kg
5l
5 l / 25 kg
25 l
50 l
60 l
225 l
6HD1
0.5 l
0.5 l / 10 kg
5l
5 l / 25 kg
25 I
50 l
60 l
225 l
6HD2
0.5 l
0.5 l / 10 kg
5l
5 l / 25 kg
25 l
50 l
60 I
225 l
6HG1
0.5 l
0.5 l / 10 kg
5I
5 l / 25 kq
25 l
50 I
60 l
225 l
6HG2
0.5 l
0.5 l / 10 kg
5l
5 l / 25 kg
25 l
50 l
60 l
225 l
6HH1
0.5 l
0.5 l / 10 kg
5l
5 l / 25 kg
25 l
50 l
60 l
225 l
6HH2
0.5 l
0.5 l
5l
5 l / 25 kg
25 l
50 l
60 l
225 l
P 1 2 3
= Prohibited
Viscous liquids should be treated as solids if the criterion in 5.1.10 of the General Introduction is met. If two values are given, the first applies to the maximum net volume per inner packaging and the second to the maximum net mass of the complete package. Only allowed as part of a combination packaging. Inner packagings should be suitable for liquids.
UN No. 3115 - Appendix

ORGANIC PEROXIDE TYPE D, LIQUID, TEMPERATURE CONTROLLED Formulations ACETYL CYCLOHEXANESULPHONYL PEROXIDE tert-AMYL PEROXY-2-ETHYLHEXANOATE tert-AMYL PEROXYNEODECANOATE tert -BUTYL PEROXY-2-ETHYLHEXANOATE+ 2,2-Dl-( tert- BUTYLPEROXY)BUTANE tert - BUTYL PEROXYISOBUTYRATE tert-BUTYL PEROXYNEODECANOATE tert-BUTYL PEROXYNEODECANOATE tert-BUTYL PEROXYNEOHEPTANOATE tert-BUTYL PEROXYPIVALATE CUMYL PEROXYNEODECANOATE CUMYL PEROXYNEOHEPTANOATE CUMYL PEROXYPIVALATE DIACETONE ALCOHOL PEROXIDES DIACETYL PEROXIDE Dl-n-BUTYL PEROXYDICARBONATE Dl-sec- BUTYL PEROXYDICARBONATE Dl-(2-ETHYLHEXYL) PEROXYDICARBONATE DIETHYL PEROXYDICARBONATE DIISOBUTYRYL PEROXIDE DIISOPROPYL PEROXYDICARBONATE DIISOTRIDECYL PEROXYDICARBONATE 2,5-DIMETHYL-2,5-Dl-(2-ETHYLHEXANOYLPEROXV)HEXANE Dl-(2-NEODECANOYLPEROXYISOPROPYLBENZENE Dl-(3,5,5-TRIMETHYLHEXANOYL) PEROXIDE ISOPROPYL sec-BUTYL PEROXYDICARBONATE + Dl-sec-BUTYL PEROXYDICARBONATE + Dl-ISOPROPYL PEROXYDICARBONATE METHYLCYCLOHEXANONE PEROXIDE(S) 1,1,3,3-TETRAMETHYLBUTYL-PEROXY-2ETHYLHEXANOATE 2,4,4-TRIMETHYLPENTYL-2-PEROXY NEODECANOATE 2,4,4-TRIMETHYLPENTYL-2-PEROXY PHENOXYACETATE Concentration (%) 32 100 77 31+ 36 52 77-100 77 77 >27-67 77 77 77 57 27 >27-52 52 77 27 32 52 100 100 52 >38-82 32+ 1518 +12-15 67 100 72 37 28 63 33 OP/A OP7A OP7A OP/A +35 +20 -5 -10 +40 +25 +'5 0 48 18 38 73 68 >48 23 23 2b 73 48 48 8 23 33 23 23 23 33 48 Diluent type A (%) Diluent type B (%) 68 Water (%) OP7A OP7A OP7A OP7A OP/A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A OP7A Control temperature (C) -10 +20 0 +35 +15 -5 0 +5 0 -10 -10 -5 +40 +20 -15 -15 -15 -10 -20 10 10 +20 -10 0 -20 C Emergency temperature (C) 0 +25 +10 +40 +20 +5 +10 +10 +10 0 0 +5 +45 +25 -1 -5 -5 0 -10 0 0 +25 0 +10 -10 C 1 2, 3
Packing method
Remarks
Remarks: 1 With 9% hydrogen peroxide available oxygen 10%. 2 Only non-metallic packaging is allowed. 3 Subsidiary risk label of class 8 is required. IMDG CODE - PAGE 5235a (page 5236 follows) Amdt. 29-98
ORGANIC PEROXIDE TYPE D, SOLID, TEMPERATURE CONTROLLED
UN No. 3116 Properties Decomposes at temperatures higher than the emergency temperature or in a fire. Burns vigorously. Insoluble in water unless otherwise indicated in the "Remarks" column of the appendix to this schedule.
Packaging group: II
Label of class
Observations Contact with the eyes and skin should be avoided. Control and emergency temperatures for each formulation are given in the appendix to this schedule. The temperature must be checked regularly. New organic peroxides or new formulations of currently assigned organic peroxides may be carried under the provisions of this schedule, see 2.5 of the introduction to this class. Packing See 6.2 of the introduction to this class. For packing methods, see appendix to this schedule. For the permitted packagings and their maximum contents see TABLE 2 in the introduction to this class. Stowage Category D. Must be transported under temperature control. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
5.2
CLASS 6.1 T o x i c s u b s t a n c e s
2.1.4
In assigning the packaging group of a toxic substance for which no specific packaging group is given in the individual schedule, due account should be taken of the toxicity exhibited by all three routes of administration and of the provisions in 2.1.3 above. The packaging group of a substance or mixture possessing more than one hazard should be determined in accordance with subsection 5.2 of the General Introduction.
2.2 2.2.1
Definitions LD50 for acute oral toxicity That dose of the substance administered which is most likely to cause death within 14 days in one half of both male and female young adult albino rats. The number of animals tested should be sufficient to give a statistically significant result and be in conformity with good pharmacological practices. The result is expressed in milligrams per kilogram body mass.
2.2.2
LD50 for acute dermal toxicity That dose of the substance which, administered by continuous contact for 24 hours with the bare skin of the albino rabbit is most likely to cause death within 14 days in one half of the animals tested. The number of animals tested should be sufficient to give a statistically significant result and be in conformity with good pharmacological practices. The result is expressed in milligrams per kilogram body mass.
2.2.3
LC50 for acute toxicity on inhalation That concentration of vapour, mist or dust which, administered by continuous inhalation to both male and female young adult albino rats for one hour, is most likely to cause death within 14 days in one half of the animals tested. A solid substance should be tested if at least 10% (by mass) of its total mass is likely to be dust in the respirable range, e.g. the aerodynamic diameter of that particle fraction is 10 microns or less. A liquid substance should be tested if a mist is likely to be generated in a leakage of the transport containment. For both solid and liquid substances more than 90% (by mass) of a specimen prepared for inhalation toxicity testing should be in the respirable range as defined above. The result is expressed in milligrams per litre of air for dusts and mists or in millilitres per cubic metre of air (parts per million) for vapours.
2.3 2.3.1
Grouping criteria The criteria for grouping a substance according to the toxicity it exhibits by all three routes of administration are presented in the following paragraphs.
2.3.2
The grouping criteria for the oral and dermal routes as well as for inhalation of dusts and mists are shown in the following table Grouping criteria for administration through oral ingestion, dermal contact and inhalation of dusts and mists
Packaging group
Oral toxicity LD50 (mg/kg) 5 > 5 - 50
Dermal toxicity LD50 (mg/kg) 40 > 40 - 200 > 200 1.000 > 200 - 1.000
Inhalation toxicity by dusts and mists LD50 (one hour) (mg/l) 0.5 > 0.5 - 2 > 2 - 10 > 2 - 10
I II III Solids Liquids

1
> 50 - 200 > 50 - 500
Tear gas substances whose toxicity data correspond to the values shown for packaging group III should nevertheless be included in packaging group II. Note: Substances meeting the criteria of class 8 and with an inhalation toxicity of dusts and mists (LD50), leading to packaging group I should only be accepted for an allocation to class 6.1 if the toxicity through oral ingestion or dermal contact is at least in the range of packaging group I or II. Otherwise an allocation to class 8 should be appropriate (see 2.1.2 of the introduction to class 8)
2.3.3
Liquids having toxic vapours should be assigned to the following packaging groups where V is the saturated vapour concentration in ml/m3 an at 20C and standard atmospheric pressure: Packaging group I Packaging group II - If V 10 LD50 and LD50 1.000 ml/m3 - If V 10 LD50 and LD50 3.000 ml/m3 and do not meet the criteria for packaging group I - If V 1/5 LD50 and LD50 5.000 ml/m3 and do not meet the criteria for packaging group I or II
Packaging group III*
* Tear gas substances whose toxicity data correspond to the values shown for packaging group III should nevertheless be included in packaging group II.
2.5.3
In the absence of LC50 data on the toxic (poisonous) constituent substances the mixture may be assigned a packaging group based on the following simplified threshold toxicity tests. When these threshold tests are used the most restrictive packaging group should be determined and used for transporting the mixture. 1 A mixture is assigned to packaging group I only if it meets both of the following criteria: 1.1 A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 1000 ml/m3 vaporized mixture in air. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14-days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have an LC50 equal to or less than 1000 ml/m3. 1.2 A sample of the vapour in equilibrium with the liquid mixture at 20 C is diluted with nine equal volumes of air to form a test atmosphere. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14 days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have a volatility equal to or greater than 10 times the mixture LC50. 2. A mixture is assigned to packaging group II only it, it meets both of the following criteria and the mixture does not meet the criteria for packaging group I. 2.1 A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 3000 ml/m3 vaporized mixture in air. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14-days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have an LC50 equal to or less than 3000 ml/m3. 2.2 A sample of the vapour in equilibrium with the liquid mixture at 20 C is used to form a test atmosphere. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14-days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have a volatility equal to or greater than the mixture LC50. 3 A mixture is assigned to packaging group III only if it meets both of the following criteria and the mixture does not meet the criteria for packaging groups I or II. 3.1 A sample of the liquid mixture is vaporized and diluted with air to create a test atmosphere of 5000 ml/m3 vaporized mixture in air. Ten albino rats (five male and five female) are exposed to the test atmosphere for one hour and observed for 14-days. If five or more of the animals die within the 14-day observation period the mixture is presumed to have an LC50 equal to or less than 5000 ml/m3. 3.2 The vapour pressure of the liquid mixture is measured and if the vapour concentration is equal to or greater than 1000 ml/m3 the mixture is presumed to have a volatility equal to or greater than 1/5 the mixture LC50.
2.6
Methods for determining oral and dermal toxicity of mixtures.
2.6.1
When classifying and assigning the appropriate packaging group to mixtures in class 6.1 in accordance with the oral and dermal toxicity criteria in 2.3.2 it is necessary to determine the acute LD50 of the mixture.
2.6.2
If a mixture contains only one active substance, and the LD50 of that constituent is known, in the absence of reliable acute oral and dermal toxicity data on the actual mixture to be transported, the oral or dermal LD50 may be obtained by the following method:
LD50 value of preparation =
LD50 value of active substance x 100 percentage of active substance by mass
2.6.3
If a mixture contains more than one active constituent, there are three possible approaches that may be used to determine the oral or dermal LD50 of the mixture. The preferred method is to obtain reliable acute oral and dermal toxicity data on the actual mixture to be transported. If reliable, accurate data is not available, then either of the following methods may be performed: .1 Classify the formulation according to the most hazardous constituent of the mixture as if that constituent were present in the same concentration as the total concentration of all active constituents; or .2 Apply the formula:
C A C B CZ 100 + + = TA TB TZ TM
where: C = the % concentration of constituent A, B ... Z in the mixture; T = the oral LD50 values of constituent A, B ... Z; TM = the oral LD50 value of the mixture.
Note: This formula can also be used for dermal toxicities provided that this information is available on the same species for all constituents. The use of this formula does not take into account any potentiation or protective phenomena.
2.7 2.7.1
Classification of pesticides Alt active pesticide substances and their preparations for which the LC50 and/or LD50 values are known and which are classified in class 6.1 should be classified under appropriate packaging groups in accordance with the criteria given in subsection 2.1 of the introduction to this class. Substances and preparations which are characterized by subsidiary risks should be classified according to the Precedence of hazard table with the assignment of appropriate packaging groups (see 5.2.7 of the General Introduction). If the oral or dermal LD50 value for a pesticide preparation is not known but the LD50 value of its active substance(s) is known, the LD50 value for the preparation may be obtained by applying the procedures described in section 2.6 of the introduction to this class. Note: LD50 toxicity data for a number of common pesticides may be obtained from the most current edition of the WHO Recommended Classification of Pesticides by Hazard and Guidelines to Classification available from the International Programme on Chemical Safety, World Health Organization (WHO), 1211 Geneva 27, Switzerland. White that publication may be used as a source of LD50 data for pesticides, its classification system should not be used for purposes of transport classification of, or assignment of packaging groups to pesticides, which should be in accordance with the provisions of this Code.
2.7.2
2.7.3 2.7.4
The proper shipping name used in the transport of the pesticide should be selected on the basis of the active ingredient, of the physical state of the pesticide and any subsidiary risks it may exhibit. A marine pollutant is indicated by either a "P" or "PP" adjacent to its name in the pesticides table. A solution or mixture containing 10% or more of a marine pollutant or marine pollutants, indicated by a "P", is a marine pollutant. A solution or mixture containing 1% or more of a marine pollutant or marine pollutants with a severe pollution potential, indicated by a "PP", is a marine pollutant. See also 2.3.2 of the General Introduction.
2.8 2.8.1
Packing - general requirements All packagings should be at least "effectively closed" However for substances which fall within the class 6.1, packaging group I or II inhalation toxicity criteria all packagings should be hermetically sealed Parts of packagings which are in direct contact with dangerous substances should not be affected by chemical or other action of those substances. Where necessary, they should be provided with a suitable inner coating or treatment. Such parts of packagings should not incorporate constituents liable to react dangerously with the contents so as to form hazardous products or to weaken them significantly. Where significant internal pressure may develop in a package by the evolution of gas from the contents (arising from temperature increase or other causes), a vent may be fitted provided the gas emitted will not cause danger, taking into account toxicity, flammability and quantity. The venting device should be so constructed that liquid will not escape when the package is in an upright position. The outer packaging should be so arranged as not to interfere with the operation of the venting device.
2.8.2
2.8.3
2.8.4
As the vapour pressure of liquids with a low boiling point is usually high, the strength of packagings for these liquids should be sufficient to withstand, with an ample factor of safety, the internal pressures likely to be generated. When filling packagings with liquids* sufficient ullage should be left to ensure that neither leakage nor permanent distortion of the packagings occurs as a result of an expansion of the liquid caused by temperatures likely to occur during transport. Unless specific requirements are prescribed in national or international rules agreements, or recommendations liquids should not completely fill a packaging at a temperature of 55 C. Unless otherwise indicated where a percentage of a substance, or of its active ingredient is stipulated, this refers to the percentage by mass in relation to the total mass of the substance in the state in which it is to be transported. Packaging requirements can be found in section 10 and Annex I of the General Introduction to this Code whilst provisions for the carriage of limited quantities of dangerous goods can be found in section 18. Packing - packaging types and limits Except where there are special packing requirements in the individual schedules, the packagings indicated in the tables in subsection 2.4 of this introduction should be used. Glass receptacles packaged in an outer packaging should be surrounded by inert cushioning material so arranged as to prevent breakage and leakage from the package. For liquids, this cushioning material should also be absorbent. This is not necessary if close fitting parts of expanded plastics are used as cushioning material and the requirements of the second sentence of 2.3.1.5 are met, when appropriate. Where glass is permitted, it should be understood to include earthenware, porcelain and other comparable materials unless stipulated otherwise. Where glass or plastics receptacles are permitted it should be understood that glass or plastics bottles or jars are included. Where wooden boxes are permitted as outer packagings, it should be understood that boxes of natural wood (4C1) plywood boxes (4D) and reconstituted wood boxes (4F) are included. Moulded expanded plastics boxes (4H1) should be constructed of a fire-resistant grade of material. When the contents are not compatible with the outer packaging, each glass bottle should be enclosed in a bag made of plastics material compatible with the contents and the bag should be effectively closed. A cylinder of the kind normally used for compressed gases, approved by the competent authority of the country concerned and with suitable valve protection, may be used to contain any toxic liquid provided that this liquid is compatible with the material of construction. Removable head packagings should not be used for the transport of liquids, except that steel and aluminium removable head drums or jerricans may be used for liquids in packaging groups II and III when these packagings successfully pass the test for liquids. Non-removable head packagings (1A1, 3A1, 1B1, 1H1 and 3H1) tested for liquids in accordance with the provisions of Annex I may also be used as packagings for solids on condition that the testing qualifications indicated in the UN mark are observed.
2.8.5
2.8.6
2.8.7 2.9 2.9.1 2.9.2
2.9.3 2.9.4 2.9.5 2.9.6
2.9.7
2.9.8
2.9.9
* With respect to ullage limits only, viscous substances with an outflow time via a DIN-cup with a 4 mm diameter outlet exceeding 10 minutes at 20 C (corresponding to an outflow time via a Ford cup 4 of more than 690 seconds at 20 C, or to a viscosity of more than 2.680 centistokes at 20 C) should be subject to the provisions applicable for packagings destined for solid substances.
2.10
Packagi ng speci fications TABLE 1 - LIQUIDS [new table]

Inner packaging Outer packaging Packaging code (A nnex 1) Maximum gross m ass or maximum liquid contents Packaging gr oup I II 125 kg 125 kg 125 kg 125 kg 125 kg 120 kg 120 kg 60 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 551 kg 55 kg 250 litres 4 250 litres 250 litres 4 250 litres 250 litres 60 litres 4 60 litres 60 litres 4 60 litres 60 litres III 125 kg 125 kg 125 kg 125 kg 125 kg 120 kg 120 kg 60 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 551 kg 55 kg 250 litres 4 250 litres 250 litres 4 250 litres 250 litres 60 litres 4 60 litres 60 litres 4 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
Receptacles, glass, porce- Drums lain and stoneware maximum contents 10 litres, or
Receptacles, plastics, maximum contents 30 litres or Receptacles, metal, maximum contents 40 litres
Jerricans
Steel Aluminium Plywood Fibre Plastics - Steel Aluminium Plastics Steel Aluminium Plywood Natural wood Reconstituted wood Solid plastics Fibreboard Moulded expanded plastics
1A2 1B2 1D 1G 1H2 3A2 3B2 3H2 4A 4B 4D 4C1, ,4C2 4F 4H2 4G 4H1 1A1 1A2 1B1 1B2 1H1 3A1 3A2 3B1 3B2 3H1 6HA2 6HB2 6HC 6HD2 6HG2 6HH2
Boxes -
75 kg 75 kg 75 kg 75 kg 75 kg 60 kg 60 kg 30 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 401 kg 40 kg 250 litres Prohibited 250 litres Prohibited 2502 litres 60 litres Prohibited 60 litres Prohibited 602 litres
Boxes Boxes Drums -
Steel Steel Aluminium Aluminium Drums - Plastics Jerricans Steel Steel Aluminium Aluminium Plastics Cylinders Plastics receptacle in a steel crate or box aluminium crate or box wooden box plywood box fibreboard box solid plastics box Notes:
1
According to the design type3 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres
2 3
When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging groups II and III and 75 kg for packaging group I. Not permitted for class 3 packaging group I. Cylinders of carbon steel, special steels copper alloy and aluminium alloy 150 litres. Receptacles of carbon steel special steels, copper alloy and aluminium alloy 100 to 1000 litres. Tested for liquids.
[new table]
Maximum gross mass or maximum liquid contents Packaging group I Plastics receptacle in a plywood drum fibre drum plastics drum Plastics receptacle in a steel drum aluminium drum Glass receptacle in a steel drum steel crate or box aluminium drum aluminium crate or box wooden box plywood drum plywood box fibre drum fibreboard box expanded plastics drum solid plastics drum Note:
2
Table 1 (continued)
Packaging code (Annex I) 6HD1 6HG1 6HH1 6HA1 6HB1 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 6PH2
II 250 litres 250 litres 250 litres 250 litres 250 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
III 250 litres 250 litres 250 litres 250 litres 250 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
1202 litres 1202 litres 1202 litres 250 litres 250 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres 602 litres
TABLE 2 - SOLIDS [new table]

Maximum gross mass Inner packaging Receptacles, glass, porcelain and stoneware, maximum contents 10 kg; or Outer packaging Drums Packaging code (Annex I) I Steel Aluminium Plywood Fibre Plastics Receptacles, plastics, maxiJerricans - Steel mum contents 30 kg, or Aluminium Plastics Receptacles, metal, maximum Boxes Plywood contents 40 kg, or Natural wood Reconstituted wood Bags maximum contents 50 kg Steel Aluminium Solid plastics Boxes Natural wood with sift proof walls Boxes Boxes Drums Steel Aluminium Plywood Fibreboard Plastics Fibreboard Expanded plastics 4G 4H1 1A1, 1A2 1B1,1B2 1D1 1G1 1H1,1H2 3A1, 3A2 3B1, 3B2 3H1, 3H2 4A 4B 4C11 4G1 4D1 4F1 4H21 4H1 4C21
1
Packaging group II 225 kg 225 kg 225 kg 225 kg 225 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 400 kg 552 kg 55 kg 400 kg 400 kg 400 kg 400 kg 400 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 60 kg 400 kg III 225 kg 225 kg 225 kg 225 kg 225 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 400 kg 552 kg 55 kg 400 kg 400 kg 400 kg 400 kg 400 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 60 kg 400 kg 125 kg 125 kg 125 kg 125 kg 125 kg 75 kg 75 kg 75 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 400 kg 402 kg 40 kg 400 kg 400 kg 400 kg 400 kg 400 kg 120 kg 120 kg 120 kg Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited 400 kg
1A2 1B2 1D 1G 1H2 3A2 3B2 3H2 4D 4C1 4F 4A 4B 4H2 4C2
Jerricans - Steel Aluminium Plastics Boxes Steel Aluminium Natural wood Fibreboard Plywood Reconstituted wood Solid plastics Moulded expanded plastics
Barrels Notes:
These packagings should not be used when the contents are likely to melt during the voyage. When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging groups II and III and 75 kg for packaging group I.
2
[new table]
Table 2 (continued) Bags woven plastics, water-resistant plastics film textile water-resistant paper multiwall, water-resistant Plastics receptacle in a steel drum aluminium drum Plastics receptacle in a plywood drum fibre drum plastics drum Plastics receptacle in a fibreboard box Glass receptacle in a steel drum steel crate or box aluminium drum aluminium crate or box wooden box plywood drum wickerwork hamper fibre drum fibreboard box expanded plastics drum solid plastics drum Notes:
1 2
Packaging code (Annex I) 5H31 5H41 5L31 5M21 6HA1 6HB1 6HD1 6HG1 6HH1 6HG2 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 6PH2
Maximum gross mass Packaging group I Prohibited Prohibited Prohibited Prohibited 400 kg 400 kg 120 kg 120 kg 120 kg 40 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg II 503 kg 502 kg 502 kg 502 kg 400 kg 400 kg 250 kg 250 kg 250 kg 55 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg III 502 kg 502 kg 502 kg 502 kg 400 kg 400 kg 250 kg 250 kg 250 kg 55 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg
These packagings should not be used when the contents are likely to melt during the voyage. When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 For bags 50 kg net mass applies.
kg for packaging groups II and III and 75 kg for packaging group I.

3
3 STOWAGE 3.1 Class 6.1 substances should be stowed as indicated in the individual schedules in accordance with one of the categories specified below. Stowage category A Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length, whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 3.1.2 Stowage category B Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length, whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 3.1.3 Stowage category C Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 3.1.4 Stowage category D Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length, whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 3.1.5 Stowage category E Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded.
3.1.1
ON DECK OR UNDER DECK
ON DECK ONLY
ON DECK ONLY
ON DECK ONLY
ON DECK ONLY
PROHIBITED
ON DECK OR UNDER DECK PROHIBITED
UN No. ALKALOIDS, SOLID, N.O.S. or ALKALOID SALTS, SOLID, N.O.S. ALKALOIDS, LIQUID, N.O.S. or ALKALOID SALTS, LIQUID, N.O.S. 3140 1544
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide range of toxic solids or liquids generally of vegetable origin. Observations Toxic if swallowed by skin contact or by inhalation. When offered for carnage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class. MARINE POLLUTANT mark (for marine pollutants only)
Packaging group: I, II or III according to toxicity criteria
Label of class
6.1
PAGE RESERVED
UN No. 1547
ANILINE AMINOBENZENE ANILINE OIL PHENYLAMINE
Formula C6H5NH2
Properties Colourless oily volatile liquid. Reacts with acids. Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 1 of the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
ANILINE HYDROCHLORIDE ANILINE CHLORIDE ANILINE SALT
UN No. 1548
Formula C6H5NH2 HCI
Properties White crystalline solid. Soluble in water. Decomposes to aniline in contact with alkalis. Observations Toxic if swallowed by skin contact or by inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 2431
ortho-ANISIDINE ortho-METHOXYANILINE ortho-AMINOANISOLE
Formula H2NC6H4OCH3
Properties Reddish or yellowish oily liquid. Immiscible with water. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
6.1
UN No. 1562
ARSENICAL DUST ARSENICAL FLUE DUST
Formula
Properties Fine powder. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 1555
Formula AsBr3
ARSENIC BROMIDE ARSENIC TRIBROMIDE ARSENOUS BROMIDE
Properties White deliquescent crystals. Melting point approximately 33 C. Decomposed by water, evolving hydrogen bromide, an irritating and corrosive gas apparent as white fumes. Observations Toxic if swallowed, by skin contact or by dust inhalation.
Packaging group: II Label of class Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Keep as cool as reasonably practicable. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
ARSENIC COMPOUND, LIQUID, N.O.S., inorganic ARSENATES, LIQUID, N.O.S., inorganic ARSENIC SULPHIDES, LIQUID, N.O.S., inorganic ARSENITES, LIQUID, N.O.S., inorganic
UN No. 1556
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic liquids. Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Substances with a flashpoint between 23 C and 61 C should be classified under TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S. , UN No. 2929 in this class or under FLAMMABLE LIQUID, TOXIC, N.O.S., UN No. 1992 in class 3.3 according to toxicity criteria. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
6.1
ARSENIC COMPOUND, SOLID N.O.S., inorganic ARSENATES, SOLID, N.O.S., inorganic ARSENIC SULPHIDES, SOLID, N.O.S., inorganic ARSENITES, SOLID, N.O.S., inorganic
UN No. 1557
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic solids. Observations Toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation and Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: I, II or III according to toxicity criteria Label of class
6.1
UN No. 1559
Formula As2O5
ARSENIC PENTOXIDE
Properties White, deliquescent powder. Soluble in water. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 1560
ARSENIC TRICHLORIDE ARSENIC CHLORIDE ARSENIOUS CHLORIDE ARSENOUS CHLORIDE
Formula AsCl3
Properties Colourless, oily liquid. Fumes in moist air, evolving hydrogen chloride, an irritating and corrosive gas, apparent as white fumes. Reacts with water. Observations Highly toxic if swallowed, by skin contact or by inhalation.
Packing Receptacle net Package gross
Packaging group: I
Label of class
Hermetically sealed: 1 Glass receptacles with inert cushioning material, or plastics receptacles, in a wooden box (4C1), (4D), (4F) fibreboard box (4G) 2 Metal cans in a wooden box (4C2), (4D), (4F) fibreboard box (4G) 3 Drum, steel (1A1) 4 Cylinder
15 / 5/ 20 / 20 / -
75 kg 40 kg 75 kg 40 kg 250 / -
6.1
For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1570
BRUCINE DIMETHOXYSTRYCHNINE
Formula C23H26N2O4
Properties White crystals or powder. Observations Highly toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 2738
Formula C6H5NH(C4H9)
N-normal-BUTYLANILINE
Properties Amber liquid with a perceptible odour. Immiscible with water. May react vigorously with oxidizing substances. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
tertiary-BUTYLCYCLOHEXYL CHLOROFORMATE
UN No. 2747
Formula (CH3)3CC6H10OCOCI
Properties Colourless to yellowish liquid. Reacts with water or decomposes if heated, evolving hydrogen, chloride, an irritating and corrosive gas apparent as white fumes. Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Keep as cool and dry as reasonably practicable. Shaded from radiant heat. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2690 Formula C7H12N2
6.1
N-normal-BUTYLIMIDAZOLE N-normal-BUTYLIMINAZOLE
Properties Colourless to amber mobile liquid. Miscible with water. Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
1,1-DICHLORO-1-NITROETHANE
UN No. 2650
Formula CH3CCI2NO2
Packaging group II Label of class
Properties Liquid. Immiscible with water. May react vigorously with oxidizing substances. Decomposes when heated evolving highly toxic fumes (oxides of nitrogen). Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Keep as cool as reasonably practicable. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2250 Formula CI2C6H3NCO
6.1
DICHLOROPHENYL ISOCYANATES
Properties Colourless to yellowish crystalline solid with an irritating odour. Insoluble in water. Reacts with water evolving carbon dioxide. Observations Toxic if swallowed by skin contact or by inhalation. May be carried in the molten state. Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. The transport temperature should be indicated on the tank. Stowage Category B. Shaded from radiant heat. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
1,3-DICHLOROPROPANOL-2 DICHLOROISOPROPYL ALCOHOL alpha-DICHLOROHYDRIN alpha-PROPENYLDICHLOROHYDRIN GLYCEROL-1,3-DICHLOROHYDRIN
UN No. 2750
Formula CICH2CH(OH)CH2CI
Properties Colourless, slightly viscous liquid with a chloroform-like odour Immiscible with water. Decomposes when heated, evolving extremely toxic fumes (phosgene). Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Keep as cool as reasonably practicable. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Packaging group: II
Label of class
6.1
UN No. 1598
DINITRO-ortho-CRESOL DNOC
Formula CH3C6H2(NO2)2OH
Properties MARINE POLLUTANT Yellow crystals or crystallized mass. Slightly soluble in water. Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: II
Label of class
6.1
DINITROPHENOL SOLUTION
UN No. 1599
Formula C6H3(NO2)2OH
Properties MARINE POLLUTANT Substance when pure consists of yellow crystals. Slightly soluble in water. May form extremely sensitive compounds with heavy metals or their salts. Observations Toxic if swallowed, by skin contact or by inhalation. For DINITROPHENOL, dry or wetted with less than 15% water, by mass, UN No. 0076, see . For DINITROPHENOL, WETTED with not less than 15% water, by mass, UN No. 1320, see class 4.1. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Label of class
Packaging group: II or III according to toxicity criteria
6.1
Stowage Category A. Away from lead and its compounds. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
ETHYLDICHLOROARSINE
UN No. 1892
Formula C2H5AsCl2
Properties MARINE POLLUTANT Packaging group: I Label of class Colourless liquid evolving irritating vapour ("Tear Gas''). Observations Highly toxic if swallowed, by skin contact or by inhalation. Packing Cylinder. For tanks see section 13 of the General Introduction. Stowage Category D. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
ETHYLENE CHLOROHYDRIN 2-CHLOROETHYL ALCOHOL 2-CHLOROETHANOL GLYCOL CHLOROHYDRIN
UN No. 1135
Formula CICH2CH2OH
Properties Colourless flammable liquid with a faint, ethereal odour. Flashpoint 60 C c.c. Explosive limits 4.9% to 15.9%. Miscible with water. When involved in a fire, evolves extremely toxic (phosgene) and corrosive (hydrogen chloride) fumes. Observations Highly toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1605 Formula CH2BrCH2Br
6.1
ETHYLENE DIBROMIDE 1,2-DIBROMOETHANE
Properties Colourless, volatile liquid. Observations Highly toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 2552
HEXAFLUOROACETONE HYDRATE
Formula CF3COCF3 H20
Properties This entry covers the solid hydrate and hexafluoroacetone in aqueous solutions. Melting point of the pure substance 23 C. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
HEXAMETHYLENE DIISOCYANATE HMDI
UN No. 2281
Formula OCN(CH2)6NCO
Properties Colourless to light yellow liquid with a pungent odour. Immiscible with water but reacts with it evolving heat and carbon dioxide gas. When heated, evolves toxic nitrous fumes. Packaging group: II Label of class Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category C. Keep as dry as reasonably practicable. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
HYDRAZINE, AQUEOUS SOLUTION, with not more than 37% hydrazine, by mass DIAMINE, AQUEOUS SOLUTION HYDRAZINE BASE, AQUEOUS SOLUTION
UN No. 3293
Formula H2NNH2
Properties Colourless liquid. Observations Toxic if swallowed, by skin contact or by inhalation.
Packaging group: III Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A.
Label of class
6.1
UN No. 1994
IRON PENTACARBONYL IRON CARBONYL
Formula Fe(CO)5
Properties Yellow to dark red volatile flammable liquid. Flashpoint -15 C c. c. Explosive limits 3.7% to 12.5%. May react with water or steam evolving carbon monoxide which is a toxic gas. Observations Highly toxic if swallowed, by skin contact or by inhalation.
Packaging group: I
Packing Hermetically sealed:
Receptacle net kg
Label of class
1 Glass receptacle sufficiently strong to withstand the internal pressures generated surrounded with inert cushioning and absorbent material in a metal can individually packed in a wooden box (4C), (4D), (4F) 2 Cylinder Carriage in tanks is prohibited
35 -
6.1
Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
ISOCYANATES, TOXIC, N.O.S. or ISOCYANATE SOLUTION, TOXIC,
UN No. 2206
Formula
N.O.S.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Liquids with a pungent odour. Immiscible with water but react with it to form carbon dioxide. Observations Toxic if swallowed, by skin contact or by inhalation.
Packaging group: II or III according to toxicity criteria
Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category E. If under-deck, with mechanical ventilation. Six air changes per hour except when carried in closed containers, when two air changes per hour are required. Shaded from radiant heat. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
6.1
ISOCYANATES TOXIC, FLAMMABLE, N.O.S. or ISOCYANATE SOLUTION TOXIC FLAMMABLE, N.O.S.
UN No. 3080
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP' in the General Index to this Code. Flammable liquids or solutions with a pungent odour. Immiscible with or insoluble in water, but react with it to form carbon dioxide. Observations Toxic if swallowed, by skin contact or by inhalation. For ISOCYANATES, FLAMMABLE, TOXIC, N.O.S. or ISOCYANATE SOLUTION, FLAMMABLE, TOXIC, N.O.S., UN No. 2478, see class 3. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category D. Shaded from radiant heat. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: II
Label of class
6.1
3
ISOCYANATOBENZOTRIFLUORIDES (ortho-, rneta-, para-) TRIFLUOROMETHYLPHENYL ISOCYANATES
UN No. 2285
Formula C8H4F3NO
Properties Colourless or yellowish liquids with a pungent odour. Flashpoint of ortho- and meta- isomers 56 C. Immiscible with water but react with it to form carbon dioxide gas. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category D. Shaded from radiant heat. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction TO this class.
UN No. 2290 Formula C12H18N2O2
6.1
3
if flashpoint is 61 C c.c. or below
ISOPHORONE DIISOCYANATE 3-ISOCYANATOMETHYL-3,5,5TRIMETHYLCYCLOHEXYL ISOCYANATE
Properties Colourless or yellowish liquid. Immiscible with water. When involved in a fire evolves nitric fumes. Observations Toxic if swallowed by skin contact or by inhalation. Packing See table 1 in the introduction to tins class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 1618
LEAD ARSENITES
Formula Pb3(AsO3)2 H2O
Properties MARINE POLLUTANT White powder. Insoluble in water. Observations Toxic if swallowed by skin contact or by dust inhalation. Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
LEAD COMPOUND, SOLUBLE,
N.O.S.
UN No. 2291
Formula
Properties MARINE POLLUTANT Packaging group: III Label of class Colourless crystals or powder. Soluble in water. Observations Lead compounds which when mixed in a ratio of 1/1000 with 0.07, molar hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C and which exhibit a solubility of 5% or less are considered insoluble. See ISO Standard 3711 1990. Toxic if swallowed, by skin contact or by dust inhalation. Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
UN No. 1620
LEAD CYANIDE
Formula Pb(CN)2
Properties MARINE POLLUTANT White powder. Slightly soluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide, a highly toxic and flammable gas. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. AWAY FROM acids. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
UN No. 1621
Formula
Properties
LONDON PURPLE
MARINE POLLUTANT Mixture of arsenic trioxide, lime and ferric oxide, used as an insecticide. Insoluble in water. Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as a pesticide, this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
MERCURY BENZOATE MERCURIC BENZOATE
UN No. 1631
Formula Hg(C6H5COO)2 H2O
Properties MARINE POLLUTANT Packaging group: II Label of class Severe marine pollutant see 23.2.2 of the General Introduction. White crystals. Observations Toxic if swallowed by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 1634 Formula HgBr2 or Hg2Br2
6.1
MERCURY BROMIDES MERCURIC BROMIDE MERCUROUS BROMIDE
Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. White crystals or powder. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
MERCURY COMPOUND, LIQUID, N.O.S.
UN No. 2024
Formula
Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packaging group: I, II or III according to toxicity criteria Packing See table 1 in the introduction to this class. Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
6.1
MERCURY COMPOUND, SOLID, N.O.S.
UN No. 2025
Formula
Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction Mercuric sulphide is a marine pollutant, not severe. Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carnage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). The provisions of this class should not apply to mercurous chloride in the pure state (see however UN No. 3077 in class 9). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class. MARINE POLLUTANT mark
Label of class
6.1
UN No. 1636
MERCURY CYANIDE MERCURIC CYANIDE
Formula Hg(CN)2
Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. White crystals or powder. Soluble in water. Reacts with acid or acid fumes evolving hydrogen cyanide, a highly toxic and flammable gas. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A AWAY FROM acids. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
UN No. 1637
Formula Hg[OOC(CHOH)4CH2OH]2
Properties
MERCURY GLUCONATE MERCURIC GLUCONATE
MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. Solid. Soluble in water. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
NAPHTHYLTHIOUREA alpha-APHTHYLTHIOUREA1-NAPHTHYLTHIOUREA
UN No. 1651
Formula C10H7NHCSNH2
Properties White crystals or powder. Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as a pesticide, this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 1652
Formula C10H7NHCONH2
NAPHTHYLUREA
Properties Crystals or powder. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
NICKEL CARBONYL NICKEL TETRACARBONYL
UN No. 1259
Formula Nl(CO)4
Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. Colourless or yellow volatile flammable liquid. Flashpoint below -20 C c.c. Oxidizes in air and explodes at a temperature of 60 C. Lower explosive limit 2.0%. Immiscible with water. Observations Highly toxic if swallowed by skin contact or by inhalation.
Packing Receptacle net kg
Packaging group: I La-
bel of class
6.1
Hermetically sealed: 1 Glass receptacle sufficiently strong to withstand the internal pressures generated surrounded with inert cushioning and absorbent material in a metal can individually packed in a wooden box (4C), (4D), (4F) 2 Cylinder Transport in tanks is prohibited 35 -
3
Stowage Category D. Clear of living quarters. Prohibited on any ship carrying goods of with the exceptions listed in 6.1.4.2 of the introduction to . Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 1653
NICKEL CYANIDE
Formula Ni(CN)2
Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. Green crystals or powder. Insoluble in water. Reacts with acids or acid fumes, evolving hydrogen cyanide a highly toxic and flammable gas. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. AWAY FROM acids. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
UN No. 1654
Formula C10H14N2
NICOTINE
Properties Thick colourless oil, turning brown on exposure to air. Miscible with water. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
NICOTINE COMPOUND, LIQUID, N.O.S. or NICOTINE PREPARATION, LIQUID,
UN No. 3144
Formula
N.O.S.
Properties A wide variety of toxic liquids. Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Liquids with a flashpoint between 23 C and 61 C c.c. should be classified under TOXIC LIQUID, FLAMMABLE, ORGANIC, N.O.S., UN No. 2929 in this class or under FLAMMABLE LIQUID, TOXIC, N.O.S. , UN No. 1992 in class 3.3, according to toxicity criteria. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1655 Formula
6.1
NICOTINE COMPOUND, SOLID, N.O.S. or NICOTINE PREPARATION, SOLID, N.O.S.
Properties A wide variety of toxic solids. Packaging group: I, II or III according to toxicity criteria Label of class Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Packaging group I category B. Packaging groups II and III category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
NICOTINE HYDROCHLORIDE SOLID or LIQUID, or NICOTINE HYDROCHLORIDE SOLUTION
UN No. 1656
Formula C10H14N2 2HCI
Properties Deliquescent crystals, solids pastes or liquids. Soluble in water. Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 1657
Formula C10H14N2C7H6O3
NICOTINE SALICYLATE
Properties White crystals. Soluble in water. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S.
UN No. 3278
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic liquids and solids. Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Packaging groups I and II category B. Packaging group III category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: I, II or III according to toxicity enter a Label of class
6.1
ORGANOPHOSPHORUS, COMPOUND, TOXIC, FLAMMABLE, N.O.S.
UN No. 3279 Properties
Formula
MARINE POLLUTANT Packaging group: I, II or III according to grouping criteria for each hazard Label of class Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. A wide variety of toxic flammable liquids. Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class. IMDG CODE - PAGE 6213-2 (page 6214 follows) Amdt. 29-98
6.1
3
ORGANOTIN COMPOUND, LIQUID, N.O.S. ORGANOTIN COMPOUND, SOLID, N.O.S.
2788 3146
Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. A wide variety of toxic solids and liquids. Observations Toxic if swallowed, by skin contact or by inhalation. When offered for carriage as pesticides, these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packaging group: I, II or III according to toxicity criteria Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Packaging group I category B. Packaging groups II and III category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class. MARINE POLLUTANT mark
Label of class
6.1
UN No. 1669
PENTACHLOROETHANE PENTALIN
Formula CHCI2CCI3
Properties MARINE POLLUTANT Colourless liquid.
Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
UN No. 3155
Formula C6Cl5OH
Properties PENTACHLOROPHENOL MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. White powder or crystals. Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as a pesticide this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
PERCHLOROMETHYL MERCAPTAN THIOCARBONYL TETRACHLORIDE TRICHLOROMETHYL, SULPHOCHLORIDE TRICHLOROMETHANE, SULPHURYL CHLORIDE
UN No. 1670
Formula CISCCI3
Properties MARINE POLLUTANT Yellow oily volatile liquid evolving irritating vapour ( Tear Gas ). Slowly decomposes in contact with water producing hydrochloric acid. Reacts with iron or steel evolving carbon tetrachloride. Corrosive to most metals... Observations Highly toxic if swallowed, by skin contact or by inhalation.
Packing Hermetically sealed: 1 Glass receptacles with inert cushioning material or plastics receptacles in a Receptacle net Package gross
Packaging group: I
Label of class
6.1
wooden box (4C), (4D), (4F) 15 / fibreboard box (4G) 5/ 2 Metal cans in a wooden box (4C), (4D), (4F) 20 / fibreboard box (4G) 20 / 3 Drum steel (1A1) 4 Cylinder For tanks see section 13 of the General Introduction.
75 kg 40 kg 75 kg 40 kg 250 / -
Stowage Category D. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No.
PESTICIDE, LIQUID, TOXIC N.O.S. CARBAMATE PESTICIDE, LIQUID, TOXIC ARSENICAL PESTICIDE LIQUID, TOXIC ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC TRIAZINE PESTICIDE, LIQUID, TOXIC
Formula Properties MARINE POLLUTANT Liquid pesticides which present a very wide range of toxic hazard. Miscibility with water depends upon the composition.
2902 2992 2994 2996 2998 3006 3010 3012 3014 3016 3018 3020 3026 3348 3352
THIOCARBAMATE PESTICIDE, LIQUID, TOXIC
COPPER-BASED PESTICIDE, LIQUID, TOXIC MERCURY-BASED PESTICIDE LIQUID, TOXIC SUBSTITUTED NITROPHENOL, PESTICIDE, LIQUID, TOXIC BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC ORGANOTIN PESTICIDE, LIQUID, TOXIC COUMARIN DERIVATIVE PESTICIDE, LIQUID TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC PYRETHROID PESTICIDE, LIQUID, TOXIC
Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active substance(s) should be mentioned in the shipping documents when a pesticide is offered for shipment.
Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction.
Stowage Packaging groups I and II category B. Packaging group III category A. Clear of living quarters.
Packaging group: I, II or III according to toxicity criteria. Label of class
6.1
UN No.
PESTICIDE, LIQUID, TOXIC, FLAMMABLE,
Formula Properties
N.O.S.
CARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE ARSENICAL PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOCHLORINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE TRIAZINE PESTICIDE, LIQUID, TOXIC, FLAMMABLE THIOCARBAMATE PESTICIDE, LIQUID, TOXIC, FLAMMABLE COPPER-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE MERCURY-BASED PESTICIDE, LIQUID, TOXIC, FLAMMABLE SUBSTITUTED NITROPHENOL PESTICIDE, LIQUID, TOXIC, FLAMMABLE BIPYRIDILIUM PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOPHOSPHORUS PESTICIDE, LIQUID, TOXIC, FLAMMABLE ORGANOTIN PESTICIDE, LIQUID, TOXIC, FLAMMABLE COUMARIN DERIVATIVE PESTICIDE LIQUID, TOXIC, FLAMMABLE PHENOXYACETIC ACID DERIVATIVE PESTICIDE, LIQUID, TOXIC, FLAMMABLE PYRETHROID PESTICIDE, LIQUID, TOXIC, FLAMMABLE
2903 2991 2993 2995 2997 3005 3009 3011 3013 3015 3017 3019 3025 3347 3351
MARINE POLLUTANT Liquid flammable pesticides having a flashpoint between 23C and 61 C c.c., presenting a very wide range of toxic hazard. They frequently contain petroleum or coal tar distillates, or other flammable liquids. Flashpoint and miscibility with water depend upon the composition. Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active substance or substances should be mentioned in the shipping documents when a pesticide is offered for shipment. For PESTICIDE, LIQUID, FLAMMABLE, TOXIC, UN No. 3021, with a flashpoint below 23 C c.c., see class 3.2.
Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction Stowage Packaging groups I and II category B. Packaging group III category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
3
PESTICIDE, SOLID, TOXIC, N.O.S. CARBAMATE PESTICIDE, SOLID, TOXIC ARSENICAL PESTICIDE, SOLID, TOXIC ORGANOCHLORINE PESTICIDE, SOLID, TOXIC TRIAZINE PESTICIDE SOLID, TOXIC THIOCARBAMATE PESTICIDE, SOLID, TOXIC
UN No. 2588 2757 2759 2761 2763 2771 2775 2777 2779 2781 2783 2786 3027 3345 3349
Formula
Properties MARINE POLLUTANT Solid pesticides present a very wide range of toxic hazard. Observations Toxic if swallowed, by skin contact or by inhalation. The name and concentration of the active substance or substances should be mentioned in the shipping documents when a pesticide is offered for shipment.
COPPER-BASED PESTICIDE, SOLID, TOXIC MERCURY-BASED PESTICIDE, SOLID, TOXIC SUBSTITUTED NITROPHENOL PESTICIDE, SOLID, TOXIC BIPYRIDILIUM PESTICIDE, SOLID, TOXIC ORGANOPHOSPHORUS PESTICIDE, SOLID, TOXIC ORGANOTIN PESTICIDE, SOLID, TOXIC COUMARIN DERIVATIVE PESTICIDE, SOLID, TOXIC PHENOXYACETIC ACID DERIVATIVE PESTICIDE, SOLID, TOXIC PYRETHROID PESTICIDE, SOLID, TOXIC
Packing 1 Glass receptacles with inert cushioning material, or plastics receptacles, in a wooden box (4C), (4D,) (4F) fibreboard box (4G) 2 Plastics or metal receptacles in a wooden box (4C), (4D), (4F) fibreboard box (4G) 3 Drum, steel (1A2) 4 Paper, plastics or metal foil bags in a wooden box (4C), (4D), (4F) fibreboard box (4G) 5 Wooden barrel (2C1) or fibre drum (1G) or plywood drum (1D) 6 Multiwall paper bag, water-resistant (5M2) 7 Plastics bags in a fibreboard box (4G) 8 Drum, plastics (1H2) 9. Strong plastics film bag (5H4)
*
Receptacle net
Package gross
15 / 5/ 20 / 20 / 15 kg 15 kg -
75 kg 40 kg* 75 kg 40 kg* 250 kg
75 kg 40 kg* 200 kg 50 kg 55 kg 200 kg 25 kg
6.1
55 kg for substances in packaging group III. Inner receptacles made of plastics materials may contain up to 25 kg of substance when transported as full container load (FCL). For substances in packaging group III only. For IBCs see section 26 of the General Introduction.
Stowage Category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
[tables deleted]
PHENACYL BROMIDE omega-BROMOACETOPHENONE
UN No. 2645
Formula BrCH2COC6H5
Properties White crystals changing to a greenish colour under the influence of light. Melting point: 50 C. Insoluble in water. Lachrymatory. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2311 Formula H2NC6H4OC2H5
6.1
PHENETIDINES ortho-PHENETIDINE para-PHENETIDINE AMINOPHENETOLES
Properties Colourless to yellowish liquids. Immiscible with water. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 2487
PHENYL ISOCYANATE PHENYL CARBIMIDE CARBANIL
Formula C6H5NCO
Properties Colourless to yellowish liquid with a pungent odour. Flashpoint 51 C c.c. Immiscible with water. Reacts with water evolving carbon dioxide. Observations Highly toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 2337
Formula C6H5SH
PHENYL MERCAPTAN BENZENETHIOL THIOPHENOL
Properties Colourless flammable liquid with a foul odour. Flashpoint 50 C c.c. Immiscible with water. In contact with acids or when involved in a fire evolves highly toxic sulphurous fumes. Observations Highly toxic if swallowed by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category B. Clear of living quarters. Away from acids. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
PHENYLMERCURIC ACETATE
UN No. 1674
Formula C6H5HgOOCCH3
Properties MARINE POLLUTANT Packaging group: II Label of class Severe marine pollutant see 23.2.2 of the General Introduction. White crystals or powder. Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as a pesticide this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 2026 Formula
6.1
PHENYLMERCURIC COMPOUND, N.O.S.
Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. Usually white crystals or powder. Packaging group: I, II or III according to toxicity criteria Label of class Observations Toxic if swallowed, by skin contact or by dust inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
SODIUM ARSENATE SODIUM ORTHOARSENATE
UN No. 1685
Formula Na3AsO4:12H2O
Properties Colourless crystals. Soluble in water. Packaging group: II Label of class Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1686 Formula NaAsO2
6.1
SODIUM ARSENITE, AQUEOUS SOLUTION
Properties Colourless liquid. Observations Toxic if swallowed by skin contact or by inhalation. When offered for carriage as pesticides this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class).
Packaging group: II or III according to toxicity criteria Label of class
Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
SODIUM ARSENITE, SOLID SODIUM METAARSENITE
UN No. 2027
Formula NaAsO2
Properties Grayish white powder. Soluble in water. Reacts with oxidizing substances evolving heat. Observations Toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as a pesticide this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
UN No. 1687
Formula NaN3
SODIUM AZIDE
Properties Colourless crystals. May react vigorously with acids to form hydrazoic acid, which is an explosive. May form extremely sensitive compounds with heavy metals or their salts. May explode if involved in a fire. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Away from lead and its compounds. Separated from class 3 and from acids. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
TETRABROMOETHANE 1,1,2,2-TETRABROMOETHANE ACETYLENE TETRABROMIDE
UN No. 2504
Formula CHBr2CHBr2
Properties MARINE POLLUTANT Colourless to yellowish liquid with a camphor like odour. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 1702 Formula CHCI2CHCl2
6.1
1,1,2,2-TETRACHLOROETHANE ACETYLENE TETRACHLORIDE
Properties MARINE POLLUTANT Packaging group: II Label of class Colourless liquid with a chloroform-like odour. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
TETRACHLOROETHYLENE PERCHLOROETHYLENE
UN No. 1897
Formula CI2C:CCI2
Properties MARINE POLLUTANT Colourless liquid with an ethereal odour. When involved in a fire evolves extremely toxic fumes (phosgene). Observations Toxic if swallowed, by skin contact or by inhalation. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 1704 Formula (C2H5)4P2O5S2
6.1
Properties
TETRAETHYL DITHIOPYROPHOSPHATE
MARINE POLLUTANT Colourless liquid. In the presence of moisture corrosive to most metals. Observations Toxic if swallowed by skin contact or by inhalation. When offered for carnage as a pesticide, this substance should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category D. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
THALLIUM COMPOUND, N.O.S.
UN No. 1707
Formula
Properties MARINE POLLUTANT Packaging group: II Label of class White crystals or powder. Observations Toxic if swallowed by skin contact or by dust inhalation. When offered for carriage as pesticides these substances should be shipped under the relevant pesticide entry and in accordance with the relevant pesticide provisions (see sections 2.6 and 2.7 in the introduction to this class). Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
UN No. 2727 Formula TINO3
6.1
Properties THALLIUM NITRATE MARINE POLLUTANT Colourless crystals. Soluble in water. Mixtures with combustible material are readily ignited and may burn fiercely. Observations Toxic if swallowed, by skin contact or by dust inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
6.1
5.1
UN No. 2785
Formula CH3SCH2CH2CHO
4-THIAPENTANAL METHYLMERCAPTOPROPIONALDEHYDE
Properties MARINE POLLUTANT Colourless liquid with an extremely foul and persistent odour. Miscible with water. Decomposes rapidly in contact with acids and bases. Observations Toxic if swallowed, by skin contact or by inhalation.
Packing Hermetically sealed 1. Glass receptacles with inert cushioning material, or plastics receptacles, in a Receptacle net Package gross
Label of class
6.1
wooden box (4C), (4D) (4F) fibreboard box (4G) 2 Metal cans in a wooden box (4C), (4D), (4F) fibreboard box (4G) 3 Drum, steel (1A1) 4 Cylinder
75 kg 55 kg 75 kg 55 kg 250 l -
For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category D. Shaded from radiant heat. AWAY FROM class 8. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
TOLUENE DIISOCYANATE TOLUYLENE DIISOCYANATE TOLYLENE DIISOCYANATE
UN No. 2078
Formula CH3C6H3(NCO)2
Properties Colourless to pale yellow liquid with a pungent odour. Immiscible with water but reacts with it to form carbon dioxide. Melting point 20 C (pure product). Observations Toxic if swallowed by skin contact or by inhalation.
Packaging group: II Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Label of class Stowage Category D.
6.1
Clear of living quarters. Shaded from radiant heat. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
TOLUIDINES LIQUID or SOLID (ortho-, meta-, para-)
UN No. 1708
Formula CH3C6H4NH2
Properties Colourless liquids or solids. para-TOLUIDINE is solid in pure form with a melting point of approximately 45 C. Observations Toxic if swallowed, by skin contact or by inhalation. Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1709 Formula CH3C6H3(NH2)2
6.1
2,4-TOLUYLENEDIAMINE, LIQUID or SOLID
Properties White crystals or powder or solution. Observations Toxic if swallowed, by skin contact or by inhalation. Packing For liquids see table 1 in the introduction to this class. For solids see TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
6.1
IMDG CODE - PAGE 6270 (page 6270 7 follows) Amdt. 27-94
VANADIUM COMPOUND, N.O.S.
UN No. 3285
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Observations Toxic if swallowed, by skin contact or by inhalation. Packing For liquids see table 1 of the introduction to this class. For solids see TABLE 2 of the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General introduction. Stowage Packaging groups I and II category B. Packaging group III category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
6.1
UN No. 2862
VANADIUM PENTOXIDE, nonfused form
Formula V2O5
Properties Brownish powder. Slightly soluble in water. Observations Toxic if swallowed, by skin contact or by inhalation. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
6.1
CLASS 6.2 I n f e c t i o u s s u b s t a n c e s
4. except when authorized for unconditional use by the Governments of the countries of origin transit and destination genetically modified micro-organisms which do not meet the definition of infectious substances but which are capable of altering animals plants or microbiological substances in a way not normally the result of natural reproduction should be classified in class 9 and assigned to UN No. 3245. 1.4 Biological products are those products derived from living organisms that are manufactured and distributed in accordance with the requirements of national governmental authorities which may have special licensing requirements, and are used either for prevention, treatment, or diagnosis of disease in humans or animals or for development experimental or investigational purposes related thereto. They include, but are not limited to, finished or unfinished products such as vaccines and diagnostic products. For the purposes of this Code, biological products are divided into the following groups.
1.
those which contain pathogens in Risk Group 1, those which contain pathogens under such conditions that their ability to produce disease is very low to none; and those known not to contain pathogens. Substances in this group are not considered to be infectious substances for the purposes of this Code. those manufactured and packaged in accordance with the requirements of national governmental health authorities and transported for the purposes of final packaging or distribution, and use for personal health care by medical professionals or individuals. Substances in this group are not considered to be infectious substances for the purposes of this Code. those known or reasonably expected to contain pathogens in Risk Groups 2, 3 or 4 and which do not meet the criteria of 1.41 above Substances in this group should be classified in class 6.2 under UN No. 2814 or UN No. 2900, as appropriate.
2.
3.
Note: Some licensed biological products may present a biohazard in certain parts of the world only. As a result, competent authorities
may require these biological products to comply with the requirements for infectious substances or may impose other restrictions.
1.5
Diagnostic specimens are any human or animal material including but not limited to, excreta, secreta blood and its components, tissue and tissue fluids being shipped for diagnostic or investigational purposes, but excluding live infected animals. For the purposes of this Code diagnostic specimens are divided into the following groups.
1.
those known or reasonably expected to contain pathogens in risk groups 2, 3 or 4 and those where a relatively low probability exists that pathogens of risk group 4 are present. Such substances should be classified in Class 6.2 and assigned to UN No. 2814 or UN No. 2900, as appropriate. Specimens transported for the purpose of initial or confirmatory testing for the presence of pathogens fall within this group;
2.
those where a relatively low probability exists that pathogens of risk group 2 or 3 are present. Specimens transported for the purpose of routine screening tests or for initial diagnosis other than for the presence of pathogens fall within this group; those known not to contain pathogens;
3.
1.6
Wastes transported under UN No. 3291 are wastes derived from the medical treatment of humans or animals or from bio research where there is a relatively low probability that infectious substances are present. Waste infectious substances which can be specified should be assigned to UN No. 2814 or to UN No. 2900. The provisions of this Code should not apply to decontaminated wastes which previously contained infectious substances unless the criteria of another class are met.
2 2.1
BIOLOGICAL PRODUCTS, DIAGNOSTIC SPECIMENS AND CLINICAL OR (BIO) MEDICAL WASTE Biological products known to contain or thought likely to contain any infectious substances should meet the requirements for infectious substances. Biological products referred to in 1.4.1 and 1.4.2 are not subject to the requirements of class 6.2. Diagnostic specimens known to contain or thought likely to contain any infectious substances should meet the requirements for infectious substances. Diagnostic specimens referred to in 1.5.2 need not meet the provisions for infectious substances when the following conditions are met. 1 the primary receptacle(s) do not contain more than 100 ml; 2 the outer packaging does not contain more than 500 ml; 3 the primary receptacles are leak proof and; 4 the packaging is in accordance with the provisions of 5.1 of this introduction.
2.2
2.3
Provided an equivalent level of performance is maintained the following variations in the primary receptacles placed within an intermediate packaging are allowed without further testing of the completed package.
1 Primary receptacles of equivalent or smaller size as compared to the tested primary receptacles may be used provided: 1.1 the primary receptacles are of similar design to the tested primary receptacle (e.g. shape round rectangular etc.); 1.2 the material of construction of the primary receptacle (glass plastics metal etc ) offers resistance to impact and stacking forces equal to or greater than that of the originally tested primary receptacle; 1.3 the primary receptacles have the same or smaller openings and the closure is of similar design (e.g. screw cap friction lid etc.); 1.4 sufficient additional cushioning material is used to take up void spaces and to prevent significant movement of the primary receptacles; and 1.5 primary receptacles are oriented within the intermediate packaging in the same manner as in the tested package. 2 A lesser number of the tested primary receptacles or of the alternative types of primary receptacles identified in 1 above may be used provided sufficient cushioning is added to fill the void space(s) and to prevent significant movement of the primary receptacles.
3 3.1
RESPONSIBILITY OF CONSIGNOR The transport of infectious substances requires co-coordinated action by the consignor the carrier and the consignee to ensure safety and arrival on time and in proper condition. 1 Dispatch of infectious substances should not take place before advance arrangements have been made between consignor carrier and consignee nor before the consignee has confirmed with his competent authorities that the substances can legally be imported and that no delay will be incurred in the delivery of the consignment to its destination.
2 In order to secure transmission without hindrance it is necessary to prepare all dispatch documents including the transport document (see section 9 of the General Introduction) in strict accordance with rules governing the acceptance of the goods to be dispatched. If the substance is perishable warnings should appear on the transport document for instance. Keep cool between +2 C and +4 C or Keep frozen or Do not freeze. The full address of the consignee should be shown on the appropriate dispatch document together with the name of a responsible person and his telephone number. 3 Whatever the mode used transport should be by the quickest possible routing. If trans-shipment is necessary precautions should be taken to ensure special care expeditious handling and monitoring of the substances in transit. Transport documents should show the number of the flight or train its date and the name(s) of the airport(s) or station(s) of trans-shipment. 4 The consignor should notify the consignee in advance of transport details such as means of transport flight or train number(s) transport document number and date and hour of expected arrival at the point of destination so that the consignment can be collected promptly. The most rapid means of communication should be used for this notification. 4 4.1 GENERAL PACKING REQUIREMENTS AND COMMUNICATION OF INFORMATION Consignors of infectious substances should ensure that packages are prepared in such a manner that they arrive at their destination in good condition and present no hazard to persons or animals during transport.
4.2 4.3 4.4
The packaging should as demonstrated by tests be capable of successfully passing the design type tests detailed in section 6 of this introduction. The terms and definitions of section 2 of Annex I and the general packing requirements of section 3 of the same Annex (except 3.3, 3.9 to 3.12 and 3.16) are applicable to the packing of infectious substances. Information should be provided as follows: 1 inside the package an itemized list of contents should be enclosed between the secondary packaging and the outer packaging; and 2 outside the package an infectious substance primary label (see 8.4 of the General Introduction) should be affixed to the outer packaging together with any other label or marking required by the nature of the contents;
4.5
Before an empty packaging is returned to the consignor or sent elsewhere it should be thoroughly disinfected or sterilized and any label or marking indicating that it had contained an infectious substance should be removed or obliterated. PACKING A packaging should include the following essential elements: 1 An inner packaging comprising: 1.1 watertight primary receptacle(s); 1.2 a watertight secondary packaging; and 1.3 absorbent material in sufficient quantity to absorb the entire contents placed between the primary receptacle(s) and the secondary packaging, if several primary receptacles are placed in a single secondary packaging they should be individually wrapped so as to prevent contact between them.
5 5.1
2 An outer packaging of adequate strength for its capacity mass and intended use and with a minimum external dimension of 100 mm 5.2 Inner packagings containing infectious substances should not be consolidated with inner packagings containing unrelated types of goods. Complete packages may be overpacked in accordance with the requirements of paragraph 10.19 of the General Introduction such an overpack may contain dry ice.
5.3
Other than for exceptional consignments e.g., whole organs which require special packaging, infectious substances should be packed in accordance with the following guidelines. 1 Lyophilized substances. Primary receptacles should include flame-sealed glass ampoules or rubber-stoppered glass vials fitted with metal seals. 2 Liquid or solid substances 2.1 For substances consigned at ambient temperature or at a higher temperature, primary receptacles should be of glass metal or plastics. Positive means of ensuring a leakproof seal should be provided, e.g. , a heat seal, a skirted stopper or a metal crimp seal. If screw caps are used, they should be reinforced with adhesive tape. 2.2 For substances consigned refrigerated or frozen, ice, dry ice or other refrigerant should be placed around the secondary packaging(s) or alternatively in an overpack with one or more complete packages marked in accordance with 5.6 Interior supports should be provided to secure secondary packaging(s) or packages in position after the ice or dry ice has dissipated. If ice is used, the outer packaging or overpack should be leakproof If dry ice is used, the outer packaging or overpack should permit the release of carbon dioxide gas. The primary receptacle and the secondary packaging should maintain their integrity at the temperature of the refrigerant used.
2.3 For substances consigned in liquid nitrogen, plastics primary receptacles capable of withstanding very low temperature should be used. The secondary packaging should also be capable of withstanding very low temperatures and in most cases will need to be fitted over the primary receptacle individually. Requirements for the consignment of liquid nitrogen should also be fulfilled. The primary receptacle and the secondary packaging should maintain their integrity at the temperature of the liquid nitrogen.
5.4
Whatever the intended temperature of the consignment, the primary receptacle or the secondary packaging should be capable of withstanding, without leakage, an internal pressure producing a pressure differential of not less than 95 kPa and temperatures in the range -40 C to +55 C. Unless an infectious substance cannot be consigned by any other means live vertebrate or invertebrate animals should not be used to consign such a substance infected animals should be consigned in accordance with conditions specified by the competent authority. A packaging that meets the requirements in sections 5 and 6 of this introduction may, after decision by the competent authority be marked with (a) the United Nations (UN) packaging symbol; (b) the Code designating the type of packaging according to the provisions of section 5 of Annex 1 to this Code; (c) the text CLASS 6.2.
5.5
5.6
(d) the last two digits of the year of manufacture of the packaging; (e) the State authorizing the allocation of the mark, indicated by the distinguishing sign for motor vehicles in international traffic; (f) the name of the manufacturer or other identification of the packaging specified by the competent authority; (g) for packagings meeting the requirements of 6.8 the letter 'U' should be inserted immediately following the marking required in (b) above. 5.7 Example of marking
4G CLASS 6.2/92 as in 5.6(a), (b), (c) and (d) S/SP-9989-ERIKSSON as in 5.6 (e) and (f)
6 6.1 TEST REQUIREMENTS FOR PACKAGINGS Other than for packagings for live animals and organisms samples of each packaging should be prepared for testing as described in 6.2 and then subjected to the tests in 6.3 to 6.5. If the nature of the packaging makes it necessary, equivalent preparation and tests are permitted, provided that these may be demonstrated to be at least as effective.
6.2
Samples of each packaging should be prepared as for transport except that a liquid or solid infectious substance should be replaced by water or, where conditioning at -18C is specified by water containing antifreeze. Each primary receptacle should be filled to 98% capacity. Packagings prepared as for transport should be subjected to the tests in table 1 which, for test purposes, categorizes packagings according to their material characteristics. For outer packagings, the headings in the table relate to fibreboard or similar materials whose performance may be rapidly affected by moisture, plastics which may embrittle at low temperature, and other materials such as metal whose performance is not affected by moisture or temperature. If a primary receptacle and a secondary packaging of an inner packaging are made of different materials, the material of the primary receptacle determines the appropriate test. In instances where a primary receptacle is made of two materials, the material most liable to damage should determine the appropriate test.
6.3
Table 1 - Tests required

Material of outer packaging Fibreboard x x x x x x 6.4.1 Plastics Other inner packaging Plastics x x x x x x x Other .1 Tests required Refer to 6.4 .2 x x .3 x x x x when dry ice is used .4 Refer to 6.5 x x x x x x
Samples should be subjected to free-fall drops on to a rigid, non-resilient, flat, horizontal surface from a height of 9 m. Where the samples are in the shape of a box, five should be dropped, in sequence.
- flat on to the base; - flat on to the top; - flat on to the longest side; - flat on to the shortest side; - on to a corner; Where the samples are in the shape of a drum, three should be dropped in sequence: - diagonally on to the top chime, with the center of gravity directly above the point of impact; - diagonally on to the base chime; - flat on to the side. Following the appropriate drop sequence there should be no leakage from the primary receptacle(s) which should remain protected by the absorbent material in the secondary packaging. (Note: While the sample should be released in the required orientation, it is accepted that for aerodynamic reasons the impact may not take place in that orientation ) 6.4.2 6.4.3 The sample should be subjected to a water spray that simulates exposure to rainfall of approximately 5 cm per hour for at least one hour It should then be subjected to the test described in 6.4.1. The sample should be conditioned in an atmosphere of -18 C or less fora period of at least 24 hours and within 15 minutes of removal from that atmosphere be subjected to the test described in 6.4.1. Where the sample contains dry ice, the conditioning period may be reduced to 4 hours. Where the packaging is intended to contain dry ice, a test additional to that specified in 6.4.1 or 6.4.2 or 6.4.3 or 6.4.2 and 6.4.3 should be carried out. One sample should be stored so that all the dry ice dissipates and then be subjected to the test described in 6.4.1. Packagings with a gross mass of 7 kg or less should be subjected to the tests described in 1 below and packagings with a gross mass exceeding 7 kg to the tests in 2 below: 1 Samples should be placed on a level hard surface A cylindrical steel rod with a mass of at least 7 kg, a diameter not exceeding 38 mm and the impact end edges having a radius not exceeding 6 mm should be dropped in a vertical free fall from a height of 1 m, measured from the impact end to the impact surface of a sample. One sample should be placed on its base. A second sample should be placed in an orientation perpendicular to that used for the first. In each instance the steel rod should be aimed to impact the primary receptacle. Following each impact, penetration of the secondary packaging is acceptable, provided that there is no leakage from the primary receptacle(s). 2 Samples should be dropped on to the end of a cylindrical steel rod. The rod should be set vertically in a level hard surface It should have a diameter of 38 mm and the edges of the upper end a radius not exceeding 6 mm. The rod should protrude from the surface a distance at least equal to that between the primary receptacle(s) and the outer surface of the outer packaging with a minimum of 200 mm. One sample should be dropped in a vertical free fall from a height of 1 m, measured from the top of the steel rod. A second sample should be dropped from the same height in an orientation perpendicular to that used for the first. In each instance the packaging should be so orientated that the steel rod would penetrate the primary receptacle(s). Following each impact, penetration of the secondary packaging is acceptable, provided that there is no leakage from the primary receptacle(s).
6.4.4
6.5
6.6
The competent authority may permit the selective testing of packagings that differ only in minor respects from a tested type, e.g. smaller sizes of inner packagings or inner packagings of lower net mass, and packagings such as drums bags and boxes which are produced with small reductions in external dimension(s). Inner receptacles of any type may be assembled within an intermediate (secondary) packaging and transported without testing in the outer packaging under the following conditions: 1 The intermediate/outer packaging combination should have been successfully tested in accordance with 6.4.1 with fragile (e.g. glass) inner receptacles; 2 The total combined gross mass of inner receptacles should not exceed one half of the gross mass of inner receptacles used for the drop test in 6.8.1; above 3 The thickness of cushioning between inner receptacles and between inner receptacles and the outside of the intermediate packaging should not be reduced below the corresponding thicknesses in the originally tested packaging, and if a single inner receptacle was used in the original test, the thickness of cushioning between inner receptacles should not be less than the thickness of cushioning between the outside of the intermediate packaging and the inner receptacle in the original test. When either fewer or smaller inner receptacles are used (as compared to the inner receptacles used in the drop test), sufficient additional cushioning material should be used to take up the void;
6.7
4 The outer packaging should have successfully passed the stacking test in 8.7 of Annex I to this Code while empty. The total mass of identical packages should be based on the combined mass of inner receptacles used in the drop test in 6.8.1 above; 5 For inner receptacles containing liquids, an adequate quantity of absorbent material to absorb the entire liquid content of the inner receptacles should be present; 6 If the outer packaging is intended to contain inner receptacles for liquids and is not leak proof or is intended to contain inner receptacles for solids and is not sift proof, a means of containing any liquid or solid contents in the event of leakage should be provided in the form of a leak proof liner, plastics bag or other equally effective means of containment; and 7 In addition to the markings prescribed in 5.6 (a) to (f), packagings should be marked in accordance with 5.6 (g). 6.8 Waste clinical or (bio) medical substances should meet all the requirements for infectious substances except the packaging requirements of sections 5 and 6 of this introduction. Such waste should be transported in rigid leak proof packagings or IBCs in accordance with the provisions of section 26 of the General Introduction and Annex I for solids, at the packaging group II performance level, provided there is sufficient absorbent material to absorb the entire amount of liquid present and the packaging or IBC is capable of retaining liquids. Packages containing larger quantities of liquid should be carried in rigid packagings or IBCs in accordance with the provisions of section 26 of the General Introduction and Annex I at the packaging group II performance level for liquids. Packagings or IBCs intended to contain sharp objects such as broken glass and needles should be resistant to puncture and retain liquids under the performance test conditions in section 26 of the General Introduction and Annex I.
7 7.1
RESPONSIBILITY OF CARRIER Carriers and their staff should fully understand all applicable regulations for the packing labelling transport and documentation of consignments of infectious substances. The carrier should accept and expedite the transport of consignments conforming to the rules in force. If the carrier finds any error in the labelling or documentation he should immediately notify the consignor or consignee so that the appropriate corrective measures may be taken.
8 8.1
RESPONSIBILITY OF CONSIGNEE The consignee should obtain from the competent authorities the necessary licence for the import of infectious substances. The consignee should also provide the consignor with any import licences authorizations or other documents required by the competent authorities. Upon receipt of known or suspected high risk infectious substances of human or animal origin the consignee should immediately acknowledge receipt to the consignor by the most rapid means of communication available to him.
8.2
The consignee should have a suitably equipped and adequately staffed receiving area. All incoming consignments of infectious substances should be unpacked in areas designated for this purpose and under conditions of containment commensurate with the degree of danger presented by the infectious substances. A record should be kept of the receipt of all substances.
9 9.1
ACTION TO BE TAKEN IN THE EVENT OF DAMAGE OR LEAKAGE If any person responsible for the carriage or opening of packages containing infectious substances becomes aware of damage to or leakage from such packages he should 1 avoid handling the package or keep handling to a minimum; 2 inspect adjacent packages for contamination and put aside any that may have been contaminated; 3 inform the appropriate public health authority or veterinary authority and provide information on any other countries of transit where persons may have been exposed to danger; and 4 notify the consignor and/or the consignee.
10 10.1
INTERNATIONAL NOTIFICATION A public health or veterinary authority to which actual or suspected leakage from or damage to a package is reported should notify the authorities of any countries in which the package may have been handled including countries of transit.
(pages 6310 to 6318 have been reserved for future amendments)
CLASS 8 C o r r o s i v e s
2.3 2.3.1 2.3.1.1
Packing - packaging types and limits Except where there are special packaging requirements in the individual schedules, the packagings indicated in the tables in section 3 of this introduction should be used Glass receptacles packaged in an outer packaging should be surrounded by inert cushioning material so arranged as to prevent breakage and leakage from the package. For liquids, this cushioning material should also be absorbent. This is not necessary if close fitting parts of expanded plastics are used as cushioning material and the requirements of the second sentence of 2.3.1.5 are met, when appropriate;
2.3.1.2 2.3.1.3 2.3.1.4 2.3.1.5
Where glass is permitted, it should be understood to include earthenware, porcelain and other comparable materials unless stipulated otherwise; Where glass or plastics receptacles are permitted, it should be understood that glass or plastics bottles or jars are included; Where wooden boxes are permitted as outer packagings, it should be understood that boxes of natural wood (4C), plywood boxes (4D) and reconstituted wood boxes (4F) are included; Moulded expanded plastics boxes (4H1) should be constructed of a fire-resistant grade of material. When the contents are not compatible with the outer packaging each glass receptacle should be enclosed in a bag made of plastics material compatible with the contents and the bag should be effectively closed. A cylinder of the kind normally used for compressed gases, approved by the competent authority of the country concerned and with suitable valve protection, may be used to contain any corrosive liquid provided that this liquid is compatible with the material of construction. Removable head packagings should not be used for the transport of liquids, except that steel and aluminium removable head drums or jerricans may be used for liquids in packaging groups II and III, when these packagings successfully pass the test for liquids. Non-removable head packagings (1A1, 3A1, 1B1, 1H1 and 3H1) tested for liquids in accordance with the provisions of Annex I may also be used as packagings for solids, on condition that the testing qualifications indicated in the UN Mark are observed.
2.3.2
2.3.3
2.3.4
PACKAGING SPECIFICATIONS
TABLE 1 - LIQUIDS [new table]

Packaging code (Annex I) 1A2 1B2 1D 1G 1H2 3A2 3B2 3H2 4A 4B 4D 4C1, 4C2 4F 4H2 4G 4H1 1A1 1A2 1B1 1B2 1H1 3A1 3A2 3B1 3B2 3H1 6HA2 6HB2 6HC 6HD2 6HG2 6HH2 Maximum gross mass or maximum liquid contents Packaging group I Drums Receptacles, glass, porcelain and stoneware, maximum contents 10 litres, or Receptacles, plastics maximum contents 30 litres, or Jerricans Steel Aluminium Plywood Fibre Plastics - Steel Aluminium Plastics Steel Aluminium Plywood Natural wood Reconstituted wood Solid plastics Fibreboard Moulded expanded plastics 75 kg 75 kg 75 kg 75 kg 75 kg 60 kg 60 kg 30 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 401 kg 40 kg II 125 kg 125 kg 125 kg 125 kg 125 kg 120 kg 120 kg 60 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 551 kg 55 kg III 125 kg 125 kg 125 kg 125 kg 125 kg 120 kg 120 kg 60 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 551 kg 55 kg 250 litres 4 250 litres 250 litres 4 250 litres 250 litres 60 litres 4 60 litres 60 litres 4 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
Inner packaging
Outer packaging
Boxes Receptacles, metal, maximum contents 40 litres
Boxes Boxes Drums - Steel Steel Aluminium Aluminium Drums - Plastics Jerricans - Steel Steel Aluminium Aluminium Plastics
Cylinders Plastics receptacle in a steel crate or box aluminium crate or box wooden box plywood box fibreboard box solid plastics box
Notes:
1
250 litres 250 litres 4 Prohibited 250 litres 250 litres 250 litres 4 Prohibited 250 litres 2502 litres 250 litres 60 litres 60 litres 4 Prohibited 60 litres 60 litres 60 litres 4 Prohibited 60 litres 2 60 litres 60 litres According to the design type3 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres 602 litres 60 litres
2 3
When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging groups II and III and 75 kg for packaging group I. Not permitted for class 3, packaging group I. Cylinders of carbon steel, special steels, copper alloy and aluminium alloy 150 litres. Receptacles of carbon steel, special steels, copper alloy and aluminium alloy 100 to 1000 litres. Tested for liquids.
[new table]
Packaging code (Annex I) 6HD1 6HG1 6HH1 6HA1 6HB1 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 6PH2 Maximum gross mass or maximum liquid contents Packaging group I Plastics receptacle in a: plywood drum fibre drum plastics drum Plastics receptacle in a: steel drum aluminium drum Glass receptacle in a: steel drum steel crate or box aluminium drum aluminium crate or box wooden box plywood drum plywood box fibre drum fibreboard box expanded plastics drum solid plastics drum
Note:
2
Table 1 (continued)
II 250 litres 250 litres 250 litres 250 litres 250 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
III 250 litres 250 litres 250 litres 250 litres 250 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres 60 litres
120 2 litres 120 2 litres 120 2 litres 250 litres 250 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres 60 2 litres
TABLE 2 - SOLIDS [new table]

Maximum gross mass Inner packaging Outer packaging Drums Receptacles, glass, porcelain and stoneware, maximum contents 10 kg or Jerricans Steel Aluminium Plywood Fibre Plastics - Steel Aluminium Plastics Plywood Natural wood Reconstituted wood Steel Aluminium Solid plastics Natural wood with sift proof walls Fibreboard Expanded plastics Packaging code (Annex I) I 1A2 1B2 1D 1G 1H2 3A2 3B2 3H2 4D 4C1 4F 4A 4B 4H2 4C2 125 kg 125 kg 125 kg 125 kg 125 kg 75 kg 75 kg 75 kg 125 kg 125 kg 125 kg 125 kg 125 kg 125 kg 400 kg Packaging group II 225 kg 225 kg 225 kg 225 kg 225 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 400 kg III 225 kg 225 kg 225 kg 225 kg 225 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 400 kg
Receptacles, plastics, maximum contents 30 kg, or
Boxes Receptacles, metal maximum contents 40 kg or Bags 1 maximum contents 50 kg
Boxes -
Boxes Boxes Drums Steel Aluminium Plywood Fibreboard Plastics Jerricans Steel Aluminium Plastics Boxes Steel Aluminium Natural wood Fibreboard Plywood Reconstituted wood Solid plastics Moulded expanded plastics Barrels
4G 4H1 1A1, 1A2 1B1, 1B2 1D 1 1G 1 1H1, 1H2 3A1, 3A2 3B1, 3B2 3H1, 3H2 4A 4B 4C1 1 4G 1 4D 1 4F 1 4H2 1 4H1 4C2 1
40 2 kg 40 kg 400 kg 400 kg 400 kg 400 kg 400 kg 120 kg 120 kg 120 kg Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited Prohibited 400 kg
55 2 kg 55 kg 400 kg 400 kg 400 kg 400 kg 400 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 60 kg 400 kg
55 2 kg 55 kg 400 kg 400 kg 400 kg 400 kg 400 kg 120 kg 120 kg 120 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 225 kg 60 kg 400 kg
Notes:
1 2
These packagings should not be used when the contents are likely to melt during the voyage.
When heavy-duty multiwall fibreboard is used for fibreboard boxes, the gross mass may be increased to 100 kg for packaging groups II and III and 75 kg for packaging group I.
CLASS 8 C o r r o s i v e s [new table]

Maximum gross mass Table 2 (continued) Bags - woven plastics water resistant plastics film textile water-resistant paper multiwall, water-resistant Plastics receptacle in a steel drum aluminium drum Plastics receptacle in a plywood drum fibre drum plastics drum Plastics receptacle in a fibreboard box Glass receptacle in a steel drum steel crate or box aluminium drum aluminium crate or box wooden box plywood drum wickerwork hamper fibre drum fibreboard box expanded plastics drum solid plastics drum
Notes:
1
Packaging code (Annex 1) I 5H3 1 5H4 1 5L3 1 5M2 1 6HA1 6HB1 6HD1 6HG1 6HH1 6HG2 6PA1 6PA2 6PB1 6PB2 6PC 6PD1 6PD2 6PG1 6PG2 6PH1 6PH2
Packaging group II 50 3 kg 50 3 kg 50 3 kg 50 3 kg 400 kg 400 kg 250 kg 250 kg 250 kg 55 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg III 50 3 kg 50 3 kg 50 3 kg 50 3 kg 400 kg 400 kg 250 kg 250 kg 250 kg 55 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg Prohibited Prohibited Prohibited Prohibited 400 kg 400 kg 120 kg 120 kg 120 kg 40 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg 75 kg
These packagings should not be used when the contents are likely to melt during the voyage. For bags, 50 kg net mass applies.
4 STOWAGE 4.1 Class 8 substances should be stowed as indicated in the individual schedules in accordance with one of the categories specified below: Stowage category A Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 4.1.2 Stowage category B Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 4.1.3 Stowage category C Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 4.1.4 Stowage category D Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. 4.1.5 Stowage category E Cargo ships or passenger ships carrying a number of passengers limited to not more than 25 or to 1 passenger per 3 metres of overall length whichever is the greater number. Other passenger ships in which the limiting number of passengers carried is exceeded. ON DECK OR UNDER DECK
4.1.1
ON DECK ONLY
ON DECK ONLY
ON DECK ONLY
ON DECK ONLY
PROHIBITED
PROHIBITED
SCHEDULES FOR CLASS 8 SUBSTANCES
ACETIC ACID, GLACIAL or ACETIC ACID SOLUTION, more than 80% acid, by mass
UN No. 2789
Formula CH3COOH
Properties Colourless flammable liquid with a pungent odour. When pure, crystallizes below 16 C. Flashpoint 40 C c.c. (pure product), 61C c.c. (80% solution). Explosive limits 4% to 17%. Miscible with water. Corrosive to lead and most other metals. Observations Corrosive to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2790 Formula CH3COOH
8
ACETIC ACID SOLUTION, more than 10% but not more than 80% acid, by mass
Packaging group: II
Properties Colourless liquid with a pungent odour. Miscible with water. Corrosive to lead and most other metals. Observations Corrosive to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
for solutions with not less than 50% but not more than 80% acid, by mass III for solutions with more than 10% and less than 50% acid, by mass Label of class
2-CHLOROPROPIONIC ACID, solid or solution alpha-CHLOROPROPIONIC ACID, solid or solution
UN No. 2511
Formula CH3CHCICOOH
Properties Crystals or a colourless aqueous solution with a specific odour. Observations Dust and liquid cause burns to skin, eyes and mucous membranes. Packing For liquids see table 1 in the introduction to this class. For solids see table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. For glass carboys category E.
Label of class
CHLOROSILANES, CORROSIVE, N.O.S.
UN No. 2987
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless liquids with a pungent odour. Immiscible with water. React violently with water or steam evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire evolve toxic gases. In the presence of moisture, highly corrosive to most metals. Observations Cause burns to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: II
Label of class
8
CLASS 8 - Corrosives
CHLOROSILANES, CORROSIVE, FLAMMABLE, N.O.S.
UN No. 2920
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Colourless, flammable liquids with a pungent odour. Immiscible with water. React violently with water or steam, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolve toxic gas. In the presence of moisture, highly corrosive to most metals. Packaging group: I or II accord- Observations ing to the grouping criteria for each Cause burns to skin, eyes and mucous membranes. For CHLOROSILANES, FLAMMABLE, CORROSIVE, N.O.S., hazard UN No. 2985, see class 3.2. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
8
3
CHLOROSULPHONIC ACID with or without sulphur trioxide
UN No. 1754
Formula CISO2OH
Properties Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. In the presence of moisture highly corrosive to most metals. Observations Causes severe burns to skin eyes and mucous membranes. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category C For glass carboys category D. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1755 Formula H2CrO4
CHROMIC ACID, SOLUTION
Properties Orange liquid. Powerful oxidant. May cause fire in contact with organic materials such as wood, cotton or straw. Corrosive to most metals. Packaging group: II or III according to corrosivity criteria Label of class Observations Causes burns to skin eyes and mucous membranes. For CHROMIC ACID, SOLID, UN No. 1463 (CHROMIUM TRIOXIDE, ANHYDROUS) see class 5.1. Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2802
COPPER CHLORIDE CUPROUS CHLORIDE CUPRIC CHLORIDE
Formula CuCI or CuCl2
Properties MARINE POLLUTANT COPPER CHLORIDE (solution) is a severe marine pollutant, see 23.2.2 of the General Introduction. White to yellow-brown crystals or powder. Partially to fully soluble in water. Both the solid and the solution are corrosive to steel. Observations Causes burns to skin, eyes and mucous membranes. Packing See TABLE 2 in the introduction to this class. For COPPER CHLORIDE (solid) in IBCs see section 26 of the General introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
8
CORROSIVE LIQUID, N.O.S.
UN No. 1760
Formula
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. Any liquid which, by the definition found in the introduction, is included in this class and which is not specified by name elsewhere in this class. Observations Causes burns to skin eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage For packaging groups I and II, category B. For packaging group III, category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: I, II or III according to corrosivity criteria Label of class
8
UN No.
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. CORROSIVE LIQUID, ACIDIC, ORGANIC,
Formula
3264 3265
N.O.S.
CORROSIVE LIQUID, BASIC, INORGANIC,
N.O.S.
CORROSIVE LIQUID, BASIC, ORGANIC,
3266 3267
N.O.S.
Properties MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this code. Any liquid, acidic or basic, inorganic or organic, which, by the definition found in the introduction, is included in this class and which is not specified elsewhere in this class. Observations Causes burns to skin, eyes and mucous membranes. Label of class Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage For packaging groups I and II, category B. For packaging group III, category A. Clear of living quarters. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Packaging group: I, II or III according to corrosivity criteria
8
NITRIC ACID, other than red fuming all concentrations
UN No. 2031
Formula HNO3
Packaging group: I*
Properties Colourless liquid. Powerful oxidant, may cause fire in contact with organic materials such as wood, cotton or straw, evolving highly toxic gases (brown fumes). Highly corrosive to most metals. Observations Causes severe burns to skin eyes and mucous membranes. * Packaging group II if concentration does not exceed 70% acid. Packing See table 1 in the introduction to this class. Plastics receptacles may only be used for concentrations not exceeding 55% unless approved otherwise by the competent authority of the country concerned. For tanks see section 13 of the General Introduction. Stowage Category D. If concentration exceeds 50% acid, segregation as for class 5.1, but SEPARATED FROM classes 4.1, 5.1 and 7. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
8
For packaging Group I only Subsidiary risk label of class
5.1
NITRIC ACID, RED FUMING
UN No. 2032
Formula HNO3 + NaO4
Packaging group: I
Properties Brown liquid. Powerful oxidant may cause fire in contact with organic materials such as wood cotton or straw. Highly corrosive to most metals. Observations Toxic if swallowed, by skin contact or by vapour inhalation. Causes severe burns to skin eyes and mucous membranes.
Packing Receptacle net 10 / Package gross 75 kg 60 / 60 / 250 /
Label of class
8
1 Receptacles, glass or plastics, in a wooden box (4C), (4D), (4F) 2 Glass receptacle in a steel drum (6PA1) wooden box (6PC) 3 Drum, steel (1A1)
For tanks see section 13 of the General Introduction
5.1 and 6.1
Stowage Category D. Clear of living quarters. Segregation as for class 5.1, but SEPARATED FROM classes 4.1,5.1 and 7. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
OCTADECYLTRICHLOROSILANE
UN No. 1800
Formula C18H37SiCl3
Properties Colourless liquid with a pungent odour. Reacts violently with water evolving hydrogen chloride an irritating and corrosive gas apparent as white fumes. When involved in a fire, evolves toxic gases. In the presence of moisture highly corrosive to most metals. Observations Vapour irritates mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1801 Formula C8H17SiCl3
OCTYLTRICHLOROSILANE
Properties Colourless liquid with a pungent odour. Reacts violently with water, evolving hydrogen chloride, an irritating and corrosive gas apparent as white fumes. When involved in a fire evolves toxic gases. In the presence of moisture highly corrosive to most metals. Observations Vapour irritates mucous membranes.
Packing See table 1 in the introduction to this class. For tanks see section 13 of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
1-PENTOL 3-METHYL-2-PENTEN-4-YNOL 1-HYDROXY-3-METHYL-2PENTEN-4-YNE
UN No. 2705
Formula CH2OHCH:C(CH3)C:CH
Properties Colourless liquid with a perceptible odour. May react in contact with a strongly alkaline substance. Observations Causes burns to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. AWAY FROM all other substances in this class. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1802 Formula HCLO4
PERCHLORIC ACID with not more than 50% acid, by mass
Properties Colourless liquid. Oxidant. Highly corrosive to most metals. Observations For PERCHLORIC ACID with more than 50% but not more than 72% acid, by mass, UN No. 1873, see class 5.1. The carriage of PERCHLORIC ACID with more than 72% acid by mass, is prohibited. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category C.
8
5.1
PIPERAZINE, SOLID or SOLUTION DIETHYLENEDIAMINE, SOLID or SOLUTION PYRAZINE HEXAHYDRIDE, SOLID or SOLUTION
UN No. 2579
Formula NHCH2CH2NHCH2CH2
Properties Colourless deliquescent crystals turning dark on exposure to light. Soluble in water. Decomposes when heated and when involved in afire evolving highly toxic nitrous fumes. The solution in water is a strong base and is highly corrosive. Observations Irritating to skin eyes and mucous membranes. Packing For liquids see table 1 in the introduction to this class. For solids see table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Keep as cool as reasonably practicable. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
UN No. 2401
PIPERIDINE HEXAHYDROPYRIDINE [new schedule]
Formula (CH2)5NH
Properties Colourless liquid with a fishy odour. Miscible with water. The solution in water is a strong alkali and is corrosive. When involved in a fire evolves toxic nitrous fumes. Flashpoint 3 C to 16 C c.c. Packaging group: I Observations Harmful by inhalation. Causes severe burns to skin eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category D. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Label of class
8
POTASSIUM HYDROGEN DIFLUORIDE, SOLID POTASSIUM ACID FLUORIDE, SOLID, POTASSIUM BIFLUORIDE, SOLID, POTASSIUM HYDROGEN, FLUORIDE, SOLID
UN No. 1811
Formula KHF2
Properties White crystalline solid. Decomposed by heat or acids evolving hydrogen fluoride a toxic extremely irritating and corrosive gas apparent as white fumes. In the presence of moisture highly corrosive to glass other siliceous materials and most metals. Observations Toxic if swallowed by skin contact or by inhalation. Causes burns to skin eyes and mucous membranes. Packing See TABLE 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Shade from radiant heat. Clear of living quarters. Away from acids. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1811 Formula KHF2
8
6.1
POTASSIUM HYDROGEN DIFLUORIDE SOLUTION POTASSIUM ACID FLUORIDE, SOLUTION POTASSIUM BIFLUORIDE, SOLUTION POTASSIUM HYDROGEN, FLUORIDE, SOLUTION
Properties Colourless liquid. Decomposed by acids evolving hydrogen fluoride a toxic extremely irritating and corrosive gas apparent as white fumes. Highly corrosive to glass other siliceous materials and most metals. Observations Toxic if swallowed by skin contact or by inhalation. Causes burns to skin eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Clear of living quarters. Away from acids. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
8
6.1
SULPHURIC ACID, with not more than 51% acid or BATTERY FLUID, ACID BATTERY ACID
UN No. 2796
Formula H2SO4
Properties Colourless liquid, mixture not exceeding 1.405 specific gravity. Highly corrosive to most metals. Observations Causes burns to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1830 Formula H2SO4
SULPHURIC ACID, with more than 51% acid
Properties Colourless, oily liquid, mixture over 1.405 up to 1.840 specific gravity. In the presence of moisture, highly corrosive to most metals. Observations Causes burns to skin, eyes and mucous membranes.
Packaging group: II Label of class Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category C. For steel drums, category B. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
SULPHURIC ACID, FUMING DISULPHURIC ACID OLEUM PYROSULPHURIC ACID
UN No. 1831
Formula H2SO4 + SO3
Properties Colourless, oily liquid, may be partly crystallized. Solution of varying quantities of sulphur trioxide in sulphuric acid. Reacts violently with water and organic material, generating heat. In the presence of moisture, highly corrosive to most metals. Observations Toxic if swallowed, by skin contact or by inhalation. Causes severe burns to skin, eyes and mucous membranes.
Packing Receptacle net Package gross 75 kg 40 kg 125 kg 250 /
Packaging group: I
Label of class
8
1 Receptacles, glass or plastics, in a wooden box (4C), (4D), (4F) 10 / moulded expanded plastics 10 / box (4H1) 2 Cans, metal, in a wooden box (4C), (4D), (4F) 30 / 3 Drum, steel (1A1) For tanks see section 13 of the General Introduction
6.1
Stowage Category C. For steel drums, category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
TETRAETHYLENEPENTAMINE
UN No. 2320
Formula HN[(CH2)2NH(CH2)2NH2]2
Properties Viscous liquid. Miscible with water. When involved in a fire, evolves toxic gases. Observations Causes burns to skin, eyes and mucous membranes. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. For glass carboys, category E. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 2698 Formula C6H8(CO)2O
8
TETRAHYDROPHTHALIC ANHYDRIDES with more than 0.05% maleic anhydride
Properties White crystalline powders. React with water, evolving heat and forming tetrahydrophthalic acid. Observations Cause burns to skin, eyes and mucous membranes. When heated, evolve acrid fumes which are irritating to skin, eyes and mucous membranes. Packages carried as a full load in a cargo transport unit are exempted from displaying the class number provided the unit in which they are packed is marked CLASS 8. The packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to these substances due to their low degree of danger. The provisions of this Code should not apply to a consignment of tetrahydrophthalic anhydrides which is accompanied by a certificate from the shipper stating that the substance as offered for shipment does not contain more than 0.05% maleic anhydride. Packing See table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
Packaging group: III Label NO LABEL REQUIRED Package to be marked CLASS 8
TETRAMETHYLAMMONIUM HYDROXIDE, SOLID OR LIQUID
UN No. 1835
Formula (CH3)4NOH
Properties Solid in the hydrated form. Melting point 60 C. More usual in liquid state very soluble in water. Reacts violently with acids. Observations
Packing For liquids see table 1 in the introduction to this class. For solids see table 2 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1940 Formula HSCH2COOH
THIOGLYCOLIC ACID MERCAPTOACETIC ACID
Properties Colourless liquid with a strong very unpleasant odour. Corrosive to most metals. Observations Harmful if swallowed. Packing See table 1 in the introduction to this class. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
CLASS 9 M i s c e l l a n e o u s d a n g e r o u s s u b s t a n c e s & a r t i c l e s
PAGE RESERVED
AIR BAG INFLATORS, pyrotechnic or AIR BAG MODULES, pyrotechnic or SEAT-BELT PRETENSIONERS, pyrotechnic
UN No. 3268
Formula
Label of class
Properties This entry applies to articles which may be classified in in accordance with paragraph 1.1 of the introduction to , which are used as lifesaving vehicle air bags or seat-belts, when transported as component parts and when "air bag inflators" or "seat-belt pretensioners" or "air bag modules" as presented for transport have been tested in accordance with test series 6 (c) of Part I of the United. Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, with the following results: 1. no explosion of the device; 2. no fragmentation of device casings; and 3. no projection hazard or thermal effect which would significantly hinder fire-fighting or other emergency response effects in the immediate vicinity. If the air bag inflator unit satisfactorily passes the test series 6 (c) test, it is not necessary to repeat the test on the air bag module itself. Observations The provisions of this Code should not apply to air bags or seat-belts installed in vehicles or in completed vehicle components such as steering columns, door panels, seats, etc.
Package gross -
Packing 1 Wooden box (4C), (4D), (4F) 2 Fibreboard box (4G)
Air bag inflators, air bag modules and seat-belt pretensioners may be transported unpackaged in dedicated handling devices or cargo transport units when they are transported from the manufacturing site to an assembly plant. Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1845
CARBON DIOXIDE, SOLID DRY ICE
Formula CO2
Properties Non-flammable gas in a white solid form. Slowly evolves vapours which are heavier than air (1.5). Observations Inhalation of vapours may lead to unconsciousness. Can cause severe burns when in contact with the skin. The provisions of this schedule should not apply to solid carbon dioxide carried on board ship for cooling purposes for certain goods shipped in a closed freight container or vehicle. Packing Only freight containers, vehicles and other receptacles that can be closed in such a way that the escape of gas is reduced to a minimum should be used for the carriage of this substance. Where the substance is loaded in a closed freight container or vehicle, special attention should be paid to the requirements of 12.7.2 and 17.8.2. respectively of the General Introduction. Stowage Category C. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
CARGO TRANSPORT UNIT, UNDER FUMIGATION CONTAINER UNDER FUMIGATION
UN No.
Formula
Fumigation Warning sign NO CLASS 9 LABEL REQUIRED
Properties A closed cargo transport unit loaded with cargoes under fumigation. The fumigant gases are either poisonous or asphyxiant. The gases are evolved from solid or liquid preparations distributed within the closed cargo transport unit. Observations Reference is made to the IMO/ILO/UN ECE Guidelines for Packing of Cargo Transport Units (CTUs) and the Recommendations on the Safe Use of Pesticides in Ships Only a cargo transport unit that can be closed in such a way that the escape of gas is reduced to a minimum should be used for the carriage of fumigated cargo. A closed cargo transport unit containing cargo under fumigation should not be allowed on board until sufficient time has elapsed to allow the attainment of a reasonably uniform gas concentration throughout the cargo. Because of variations due to types and amounts of fumigants and commodities and temperature levels, the period which should elapse between fumigant application and loading should be determined by the competent authority. Twenty-four hours is normally adequate for this purpose. The master should be informed prior to loading of a cargo transport unit under fumigation. These should be identified with a warning sign affixed to the access door(s) incorporating the identity of the fumigant and the date and time of fumigation. The transport documents for a closed cargo transport unit should show the date of fumigation and the type and amount of fumigant used. Equipment for detecting the fumigant gas or gases should be carried on the ship with the instruction for its use. The provisions of this Code should not apply to a closed cargo transport unit which has been ventilated after fumigation to ensure that no harmful concentrations of gas remain. Such a unit should also have the warning sign(s) removed. Fumigants should not be applied to the contents of a cargo transport unit once it has been loaded aboard a ship. Stowage Category B. Clear of living quarters. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
UN No. 3082 Properties
Formula
MARINE POLLUTANT Applicable only to products containing 10% or more of substance(s) identified with "P" or 1% or more of substance(s) identified with "PP" in the General Index to this Code. The provisions of this schedule are applicable to - liquid substances designated as marine pollutants under this entry as listed in the appendix to this schedule: - solutions and liquid mixtures or isomers of substances identified as marine pollutants in this Code and which meet the criteria of section 23.2 of the General Introduction and which do not meet the classification criteria of any other hazard class. Observations The following liquid substances which do not meet the classification criteria of any other hazard class may also be transported under this schedule: - liquid substances, solutions and mixtures which are subject to other transport regulations due to their potential to cause harm to environments other than the marine environment; and - wastes not otherwise subject to the provisions of this Code but covered under the Basel Convention*, in such a case the proper shipping name should be preceded by the word "WASTE" (see 9.3.7 and 27.5.2 of the General Introduction).
*
Label of class
9
Basel Convention on the Control of Transboundary Movements of Hazardous Wastes and their Disposal (1989).
Packing Any suitable packaging complying with the provisions of Annex I to this Code. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
IMDG CODE - PAGE 9028 (first of three pages) Amdt. 28-96
Appendix
LIQUID SUBSTANCES DESIGNATED AS MARINE POLLUTANTS UNDER UN No. 3082* 1 Severe marine pollutants (PP) (see 23.2.2 of the General Introduction).
CHLORINATED PARAFFINS (C10-C13), CHLORINATED PARAFFINS (C14-C17) with more than 1% shorter chain length, CRESYL DIPHENYL PHOSPHATE, TRIARYL PHOSPHATES, N.O.S., TRICRESYL PHOSPHATE not less than 1% but not more than 3% ortho-isomer. 2 Marine pollutants (P)
ALCOHOL C6-C17(SECONDARY)-POLY(3-6)ETHOXYLATE, ALCOHOL C12-C16 POLY(1-6)ETHOXYLATE, ALCOHOL C13-C15 POLY(1-6)ETHOXYLATE, ALKYLBENZENESULPHONATES, branched and straight chain, BUTYL BENZYL PHTHALATE, 1-CHLOROOCTANE, COAL TAR, COCONITRILE, CREOSOTE(COAL TAR), CREOSOTE (WOOD TAR), normal-DECALDEHYDE, normal-DECANOL, DECYL ACRYLATE, 1,3-DIBROMOBENZENE, DI-n-BUTYL PHTHALATE, para-DICHLOROBENZENE, 1,6-DICHLOROHEXANE, DIISOPROPYLBENZENES, DIISOPROPYLNAPHTHALENE, DIPHENYL/DIPHENYL ETHER (MIXTURES), DIPHENYL OXIDE and BIPHENYL PHENYL ETHER, MIXTURES, EPTC (ISO), normal-HEPTYLBENZENE, normal-HEXYLBENZENE, 2,4-HEXADIENE ALDEHYDE, ISODECALDEHYDE, ISODECANOL.
* See also the note to the appendix to the schedule for ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S., UN No. 3077.
Appendix
SOLID SUBSTANCES DESIGNATED AS MARINE POLLUTANTS UNDER UN No. 3077 1 Severe marine pollutants (PP) (see 23.2.2 of the General Introduction)
CHLORINATED PARAFFINS (C10-C13), COPPER SULPHATE, ANHYDROUS/HYDRATES, CHLORINATED PARAFFINS (C14-C17) with more than 1% shorter chain length, MERCUROUS CHLORIDE, TRIPHENYL PHOSPHATE, TRIPHENYL PHOSPHATE/tert-BUTYLATED TRIPHENYL PHOSPHATES MIXTURES, containing 10% to 48% of TRIPHENYL PHOSPHATE. 2 Marine pollutants (P)
N2-tert-BUTYL-N4-CYCLOPROPYL-6-METHYLTHIO-1,3,5-TRIAZINE-2,4 DIAMINE, 1,4-DI-tert-BUTYLBENZENE, CALCIUM NAPHTHENATE, CRESYLIC ACID SODIUM SALT, para-DICHLOROBENZENE, 2,4-DICHLOROPHENOXYACETIC ACID, 2,4-DICHLOROPHENOXYACETIC ACID DIETHANOLAMINE SALT, 2,4-DICHLOROPHENOXYACETIC ACID DIMETHYLAMINE SALT, 2,4-DICHLOROPHENOXYACETIC ACID TRIISOPROPYLAMINE SALT, DIPHENYL, DODECYL DIPHENYL OXIDE DISULPHONATE, MANCOZEB (ISO), METHYLNAPHTHALENES, NAPHTHENIC ACIDS, n-TETRAMETHYLBENZENE, TRIISOPROPYLATED PHENYL PHOSPHATES, TRIPHENYL PHOSPHATE/tert-BUTYLATED TRIPHENYL PHOSPHATES MIXTURES, containing 5% to 10% of TRIPHENYL PHOSPHATE, ZINC BROMIDE. Note: Solutions and liquid mixtures containing 10% or more of substance(s) designated as marine pollutants in this appendix or 1 % or more of substance(s) designated as severe marine pollutants in this appendix should be carried under the provisions for ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. , UN No. 3082, in this class, unless they fall within the criteria of classes 1 to 8.
FISHMEAL, STABILIZED FISHSCRAP, STABILIZED anti-oxidant treated. Moisture content greater than 5% but not exceeding 12% by mass. Fat content not more than 15% by mass.
UN No. 2216
Formula
Properties Brown to greenish brown product obtained through heating and drying of oily fish. Strong odour which may affect other cargo. Liable to heat spontaneously unless of low fat content or effectively anti-oxidant treated. Observations (a) Stabilization of fishmeal should be achieved to prevent spontaneous combustion; by effective application of between 400 and 1000 mg/kg (ppm) ethoxyquin or liquid BHT (butylated hydroxytoluene) or between 1000 and 4000 mg/kg (ppm) BHT in powder form at the time of production. The said application should occur no longer than twelve months prior to shipment. Anti-oxidant remnant concentration should be not less than 100 mg/kg (ppm) at the time of shipment. (b) Certificates from a recognized authority should state: - moisture content; - fat content; - details of anti-oxidant treatment for meals older than 6 months; anti-oxidant concentration at the time of shipment which must exceed 100 mg/kg (ppm); - packing number of bags and total mass of the consignment; - temperature of fishmeal at the time of despatch from the factory; and - date of production. Note: No weathering/curing is required prior to loading. (c) The provisions of this Code should not apply to consignments of fishmeal which are accompanied by a certificate issued by a recognized authority of the country of shipment or other recognized authority stating that the product has no self heating properties when carried in packaged form; (d) At the time of loading the temperature of the cargo should not exceed 35 C or 5 C above ambient temperature whichever is higher; (e) Refuse for shipment wet or damaged bags; (f) For UNSTABILIZED FISHMEAL and UNSTABILIZED, FISHSCRAP, UN No. 1374, see class 4.2.
Packaging group: Ill
LIFE SAVING APPLIANCES, NOT SELF-INFLATING
UN No. 3072
Formula
Properties A life-saving appliance other than a self-inflating one which includes one or more of the following dangerous goods as equipment signal devices (), gases (class 2.2) small quantities of flammable substances (classes 3.41 and 5.2), electric storage batteries (classes 8 and 9). Observations Dangerous goods packaged as part of the complete life-saving appliance are exempt from internal segregation when the appliance complies with the relevant requirements of the International. Convention for the Safety of Life at Sea, 1974 as amended. Packing As approved by the competent authority of the country concerned. Stowage Category A.
Label of class
UN No. 2990
LIFE SAVING APPLIANCES, SELF-INFLATING
Formula
Properties A life saving appliance that presents a hazard if the self-inflating device is activated accidentally and which may also include one or more of the following dangerous goods as equipment signal devices (), non-toxic gases (class 2.2) small quantities of flammable substances (classes 3.41 and 5.2) electric storage batteries (class 8) and lithium batteries (class 9). Observations Dangerous goods packaged as part of the complete life-saving appliance are exempt from internal segregation when the appliance complies with the relevant requirements of the International Convention for the Safety of Life at Sea, 1974, as amended. Packing As approved by the competent authority of the country concerned. Stowage Category A.
Label of class
LITHIUM BATTERIES LITHIUM BATTERIES CONTAINED IN EQUIPMENT or LITHIUM BATTERIES PACKED WITH EQUIPMENT
UN No. 3090
Formula
Packaging group II
Label of class
3091 Properties or descriptions Electrical batteries containing lithium or lithium alloy encased in a rigid metallic body. Lithium batteries may also be shipped in or packed with equipment. Electrical lithium batteries may cause fire due to an explosive rupture of the body caused by improper construction or reaction with contaminants. Observations Lithium cells and batteries may be transported under this entry if they meet the following requirements: (a) each cell or battery type has been determined to meet the criteria for assignment to class 9 on the basis of tests earned out in accordance with the United Nations Recommendations on the Transport of Dangerous Goods Manual of Tests and Criteria Part III sub section 38.3; (b) Each cell contains not more than 12 grams of lithium or lithium alloy; (c) Each battery contains not more than 500 grams of lithium or lithium alloy; (d) Each cell and battery incorporates a safety venting device or is designed to preclude a violent rupture under conditions normally incident to transport; (e) Each cell and battery is equipped with an effective means of preventing external short circuits; (f) Each battery containing cells or series of cells connected in parallel is equipped with diodes to prevent reverse current flow; (g) Cells and batteries are packed in inner packagings to effectively prevent short circuits and to prevent movement which could lead to short circuits. The provisions of this Code should not apply to lithium cells and batteries provided: (a) Each cell with a liquid cathode contains not more than 0.5 gram of lithium or lithium alloy and each cell with a solid cathode contains not more than 1 gram of lithium or lithium alloy; (b) Each battery with a solid cathode contains not more than an aggregate quantity of 2 grams of lithium or lithium alloy and each battery with a liquid cathode contains not more than an aggregate quantity of 1 gram of lithium or lithium alloy; (c) Each cell or battery containing a liquid cathode is hermetically sealed; (d) Cells are separated so as to prevent short circuits; (e) Batteries are separated so as to prevent short circuits and are packaged in strong packagings except when installed in electronic equipment.
IMDG CODE - PAGE 9033 (first of three pages) Amdt. 29-98
In the case of a liquid cathode battery containing more than 0.5 gram of lithium or lithium alloy, or a solid cathode battery containing more than 1 gram of lithium or lithium alloy, it does not contain a liquid or gas which is considered dangerous unless the liquid or gas, if free, would be completely absorbed or neutralized by other materials in the battery. The provisions of this Code should also not apply to lithium cells and batteries provided: (a) Each cell contains not more than 5 grams of lithium or lithium alloy; (b) Each battery contains not more than 25 grams of lithium or lithium alloy; (c) Each cell or battery is of the type proved to be non-dangerous by testing in accordance with the United Nations Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria; such testing should be carried out on each type prior to the initial transport of that type; (d) Cells and batteries are designed or packed in such a way as to prevent short circuits under conditions normally encountered in transport. The competent authority may establish conditions under which the lithium contents per individual cell may be increased to 60 grams and the total lithium contents per package to 2500 grams. Such conditions should include the requirements for packing, stowage and segregation of the cells, batteries or the equipment from other dangerous goods. The certificate of approval should accompany the shipment, Spent batteries - Cells which have been discharged to the extent that the open-circuit voltage is less than the lower of: (a) 2 volts; or (b) 2/3 of the voltage of the undischarged cell or battery containing one or more such cells, should not be transported except under provisions specified by the competent authority. Packing Cells or batteries should be packaged with hot more than 500 grams of lithium in each package. They should be packed in such manner so as to effectively prevent short circuits and be securely cushioned so as to prevent movement which could lead to short circuits. When lithium cells and batteries included in class 9 are packed with equipment, they should be packed in inner fibreboard packagings that meet the requirements for packaging group II. When lithium cells and batteries included in class 9 are contained in equipment, the equipment should be packed in strong outer packagings in such a manner as to prevent accidental operation during transport. The quantity of lithium metal contained in any battery in a piece of equipment should not exceed 12 grams per cell and 500 grams per battery. Not more than ten lithium batteries should be contained in any piece of equipment. IMDG CODE - PAGE 9033a (page 9033b follows) Amdt. 28-96
(f)
Package gross kg 1 Wooden box (4C), (4D), (4F) or fibreboard box (4G) 2 Plywood drum (1D), fibre drum (1G) or plastics drum (1H2) 3 *Steel drum (1A2) or aluminium drum (1B2) 250
250 400
* When steel or aluminium drums are used, the cells or batteries should be packaged in strong inner fibreboard packagings which should be separatee from each other and from the inner surfaces of the drum by at least 25 mm thickness of non-combustible cushioning material.
Stowage Category A. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
IMDG CODE - PAGE 9033b (page 9034 follows) Amdt. 27-94
POLYCHLORINATED BIPHENYLS PCB's
UN No. 2315
Formula C12H(8+X)CI(2 +X)
Properties MARINE POLLUTANT Severe marine pollutant see 23.2.2 of the General Introduction. Colourless liquids with perceptible odours. Immiscible with water. Observations Harmful by ingestion or by skin contact. This entry also covers appliances such as transformers and condensers containing polychlorinated biphenyls and absorbent materials such as rags, cotton waste, clothing, sawdust, etc., contaminated with polychlorinated biphenyls. Packing In general liquids or solids containing or contaminated with polychlorinated biphenyls should be packaged in accordance with table 1 or 2 respectively in the introduction to class 6.1. In general, transformers and condensers should be carried in leakproof metal packagings which are capable of holding, in addition to the transformers and condensers, at least 1.25 times the volume of the liquid present in them. There should be sufficient inert absorbent material in the packagings to absorb at least 11 times the volume of liquid which is contained in the transformers or condensers. The transformers or condensers should not be overstowed. Notwithstanding the above, liquids and solids not packaged in accordance with table 1 or 2 of the introduction to class 6.1 and unpackaged transformers and condensers should be stowed in cargo transport units (CTUs) fitted with a leakproof metal tray to a height of 800mm containing sufficient inert absorbent material to absorb at least 1.1 times the volume of any free liquid. Adequate provision should be made to seal the transformers and condensers to ensure that leakage during transport is minimized. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A.
Packaging group: II
Label of class
9
POLYHALOGENATED BIPHENYLS, LIQUID or POLYHALOGENATED TERPHENYLS, LIQUID POLYHALOGENATED BIPHENYLS, SOLID or POLYHALOGENATED TERPHENYLS, SOLID
UN No. 3151 3152
Formula
Properties MARINE POLLUTANT Severe marine pollutant, see 23.2.2 of the General Introduction. Solid or viscous liquids with a perceptible odour. Melting point of solids varies from 2 C to 164 C. Packaging group: II Observations Harmful by ingestion or by skin contact. The UN Nos. 3151 and 3152 should not be used for POLYCHLORINATED BIPHENYLS. This entry also covers appliances such as transformers and condensers containing polyhalogenated biphenyls or terphenyls and absorbent materials, such as rags, cotton waste, clothing, sawdust, etc., contaminated with polyhalogenated biphenyls or terphenyls. Packing In general, liquids or solids containing or contaminated with polychlorinated biphenyls should be packaged in accordance with table 1 or 2 respectively in the introduction to class 6.1. In general, transformers and condensers should be carried in leakproof metal packagings which are capable of holding, in addition to the transformers and condensers, at least 1.25 times the volume of the liquid present in them. There should be sufficient inert absorbent material in the packagings to absorb at least 1.1 times the volume of liquid which is contained in the transformers or condensers. The transformers or condensers should not be overstowed. Notwithstanding the above, liquids and solids not packaged in accordance with table 1 or 2 of the introduction to class 6.1 and unpackaged transformers and condensers should be stowed in cargo transport units fitted with a leakproof metal tray to a height of 800mm, containing sufficient inert absorbent material to absorb at least 1.1 times the volume of any free liquid. Adequate provision should be made to seal the transformers and condensers to ensure that leakage during transport is minimized. For IBCs see section 26 of the General Introduction. For tanks see section 13 of the General Introduction. Stowage Category A.
SEPARATED FROM foodstuffs. Packing, Stowage, Segregation & Marine Pollution Aspects See also General Introduction and introduction to this class.
Label of class
9
CLASS 9 - Miscellaneous dangerous substances & articles

POLYMERIC BEADS, EXPANDABLE, evolving flammable vapour POLYSTYRENE BEADS, EXPANDABLE, evolving flammable vapour PLASTICS MOULDING COMPOUND in dough, sheet or extruded rope form evolving flammable vapour
UN No. 2211
Formula
3314
Label of class
Properties A moulding material in bead or granular form consisting predominantly of polystyrene poly (methyl methacrylate) or other polymeric material and containing 5% to 8% of a volatile hydrocarbon which is predominantly pentane. During storage a small proportion of this pentane is released to the atmosphere, this proportion increases at elevated temperatures. Observations When shipped in secondary protection, the packaging performance tests referred to in sections 10 and 26 of the General Introduction and in Annex I to this Code should not apply to this substance due to its low degree of danger. Where the substance is loaded in a closed freight container or vehicle, special attention should be paid to the requirements of 12.7.2 and 17.8.2 respectively of the General Introduction.
Packing 1 Glass receptacles in a wooden box (4C), (4D), (4F) fibreboard box (4G) 2 Metal cans in a wooden box (4C), (4D), (4F) fibreboard box (4G) 3 Wooden box (4C2) 4 Wooden barrel (2C2), fibre drum (1G) or plywood drum (1D) 5 Steel drum (1A2) Receptacle net Package gross kg 125 55 225 55 125 200 250
For IBCs see section 26 of the General Introduction. For carriage in bulk packagings (freight containers, road or rail vehicles) or portable tanks, see section 25 of the General Introduction. Stowage Category A. When stowed under-deck, mechanical ventilation should be provided to prevent the formation of a flammable atmosphere. SEPARATED FROM goods of except from those in division 1.4 Packing, Stowage & Segregation See also General Introduction and introduction to this class.
UN No. 1931
ZINC DITHIONITE ZINC HYDROSULPHITE
Formula ZnS2O4
Properties White, amorphous solid material. Soluble in water. Liable to heat on contact with moisture and heating results in evolution of sulphur dioxide, an intensely irritating gas. Also evolves sulphur dioxide on contact with acids. Observations
Packing 1 Glass receptacles in a wooden box (4C), (4D), (4F) 2 Metal cans in a wooden box (4C), (4D), (4F) fibreboard box (4G) 3 Plastics bags in a metal drum (1A2), plywood drum (1D) or fibre drum (1G)
Receptacle net kg 2 15 15
Package gross kg 125 125 55 200 55 100 200 400 200
Label of class
4 Paper bag (5M2) 5 Textile bag (5L2), (5L3) 6 Fibre drum (1G) or plywood drum (1D) 7 Steel drum (1A2) 8 Drum, plastics (1H2) For IBCs see section 26 of the General Introduction.
Stowage Category A. Keep as dry as reasonably practicable. AWAY FROM classes 6.2 and 8. Packing, Stowage & Segregation See also General Introduction and introduction to this class.
IMDG CODE - PAGE 9037 (pages 9038 to 9999 have been Amdt. 28-96 reserved for future amendments)

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INTERNATIONAL MARITIME ORGANIZATION

INTERNATIONAL MARITIME DANGEROUS GOODS CODE (IMDG CODE)

Sales number: IMO-213E

are identified by the

IMDG CODE - PAGE 0019 Amdt. 29-98

4.3 4.3 4.3 4.3

For hazards not shown in this table see 5.2.4.

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UN No. Proper Shipping Name

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Proper Shipping Name

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UN No. Proper Shipping Name

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UN No. Proper Shipping Name

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Proper Shipping Name

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3303 3304 3305 3306 3307 3308 3309 3310 3311

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Proper Shipping Name

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Class 4.2 Class 8

7.3 7.3.1 7.3.1.1

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9 DOCUMENTATION OF DANGEROUS GOODS SHIPMENTS

See also section 7 of this General Introduction

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9. Additional handling information

* Number and kind of packages description of goods

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Marking, labelling and placarding*

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