CLASS 12 CHEMISTRY NUMERICAL TEST

MM. 30
1. Nitrogen pentaoxide decomposes according to equation:

60 MIN

2 N 2 O5 ( g ) 4 NO2 ( g ) O2 ( g )
This first order reaction was allowed to proceed at 40 and the data below were collected:

2. 3.

4. 5.

[N2O5] [M] Time (min) 0.400 0.00 0.289 20.0 0.209 40.0 0.151 60.0 0.109 80.0 (i) Calculate the rate constant. Include units with your answer. (ii) Calculate initial rate of reaction. (iii) After how many minutes will [N2O5] be equal to 0.350 M? The half-life for a first order reaction is 5 x 104s. What percentage of the initial reactant will in 2 hours? Calculate. Three electrolytic cells A, B and C containing solutions of zinc sulphate, silver nitrate and copper sulphate respectively are connected in series. A steady current of 1.5 A was passed through them until 1.45 g of silver were deposited at the cathode of cell B. How long did the current flow? What mass of copper and what mass of zinc were deposited in the concerned cells? (at. Mass of Ag)= 108, Zn = 65.4, Cu = 63.5). The resistance of a conductivity cell containing 0.001 M KCl solution at 298 K is 1500 ohm. What is the cell constant if the conductivity of 0.001 M KCl solution at 298 K is 0.146 x 10-3 S cm-1? Calculate the cell emf and rG for the cell reaction at 25 Zn(s) | Zn2+ (0.1 M) || Cd2+ (0.01 M) | Cd(s) [Given, E
Zn 2 / Zn

= - 0.763 V,

Cd 2 / Cd

= -0.403 V

1 F = 96500 C mol-1

R = 8.314 JK-1mol-1]

6. An anti-freeze solution is prepared from 222.6 g of ethylene glycol C2H4(OH)2 and 200g of water. Calculate the molality of the solution. If the density of this solution be 1.072g mL-1, what will be the molarity of the solution? 7. Calculate the amount of KCl which must be added to 1 kg of water so that the freezing point is depressed by 2 K. (Kf for water = 1.86 K kg mol-1).

OR
A solution containing 8 g of a substance in 100 g of diethyl ether boils at 36.60 35.60 . Determine the molecular mass of the solute (For ether, Kb = 2.02 K kg mol-1) ether boils at

8. Calculate the mass of a non-volatile solute (molar mass 40 g mol-1), which should be dissolved in114 g of octane to reduce its vapour pressure to 80%. (Molar mass of octane = 114 g mol-1) 9. The density of lead is 11.35 g cm-3 and the metal crystallizes with fcc unit cell. Estimate the radius of lead atom (at. Mass of lead = 207 gmol-1 and NA = 6.02 x 10 23 mol -1) 10. Aluminium crystallizes in a cubic closed packed structure. Radius of the atom in the metal is 125 pm. (i) What is the length of the side of the unit cell? (ii) How many unit cells are there in 1 cm3 of aluminium?

SUDEEPS CHEMISTRY FOR CLASS XI-XII & JEE AND MEDICAL EXAMINATIONS