2012.8.

24

20002008,
16%,

,
:;
,
20101000
1100m3 ,900
950m3

 20202000
m3 ,14001600
m3

600700m3

,
,,
( SNG)
,
,,

2
CNGV

400Kg 10%

7000-11000

4
GHP

LPG LNG

1
5.57
1842200727

60~70%
70%25%
30~60%

CO
100%99%CO298%
100%95~98%

3~8%

1.88

SNG

SNG

17656000

1.88

33193280

0.0129

0.0242

4944000

102.56

507056640

0.0036

0.3691

17408000

0.33

5744640

0.0127

0.0042

680

40000

27200000

0.0000

0.0198

35260000

0.0257

409730000

0.2983

162110000

0.1180

8760000

0.0064

7600000

0.0055

9850000

0.0072

23860000

0.0174

277940000

0.2023

5580000

0.0041

20890000

0.0152

1534774560

1.1173

120 130 140 150

50

60

70

80

90

100

110

1.2

1.4

1.6

1.8

2.1

2.3

2.5

2.8

3.0

3.2

3.5 0.50

1.3

1.5

1.8

2.0

2.3

2.5

2.8

3.1

3.3

3.6

3.8 0.55

1.4

1.7

1.9

2.2

2.5

2.8

3.1

3.3

3.6

3.9

4.2 0.60

1.5

1.8

2.1

2.4

2.7

3.0

3.3

3.6

3.9

4.2

4.5 0.65

1.6

1.9

2.3

2.6

2.9

3.2

3.6

3.9

4.2

4.5

4.9 0.70

1.7

2.1

2.4

2.8

3.1

3.5

3.8

4.2

4.5

4.9

5.2 0.75

1.8

2.2

2.6

3.0

3.3

3.7

4.1

4.4

4.8

5.2

5.5 0.80

2.0

2.4

2.7

3.1

3.5

3.9

4.3

4.7

5.1

5.5

5.9 0.85

3R
3E



CO
COCO2

COCO2CO
CO2H2CH4 CO
CO21010-6

(300-400)

CO+CO20.8%

0. 1 10-6
2:

,
,15% ,CO35%

CO29%
2080

2070
1

(Lugri)
F-T1

1
2

19841

14(122
)18000 t/d
96% 35564kJ /m3
12. 7m31978( Top s<e)
7200 m3 /d
1981

H2/CO+CO2
, CH4
SNG CH4 94%--97.84%
3726038100kJ/m3

2:
COCO2H2
CH4

 CO +3H2CH4 +H2O H0298 = - 206 kJ /mol

CO2 +4H2CH4 +2H2O H0298 = - 165 kJ /mol

2 ,
1%CO74 ;1%
CO260
3
COCO2 H2
94%--96%

1(DAVY)(CRG)
2
3(Lugri)


1 Davy,CRG

50%2
190,300600,
7003H2,
200,CO
,250.4
,
200,
Ni(CO)4

 5n(H2)/n(CO)=36
CRGCO 7
0.110-6
,
,3010-98
,

239,
2:

 ,S;
,
10DavySNG,
94%96%,37260
38100kJ/m3,
11
(8.6-12.0MPa,485),
;1000m33t
,121000Nm3SNG
18.93Kw.h1313.3
/

CRG2080,
,
1SNG CRG
,
CRGSNG
2008

2%

MCR-2X
,,
10000h,MCR-2X
MCR-2X
45000h
MCR-2X200700
TREMPTM,
,

MCR-2X(250)
(700)
,,
,

(1)
10m3h20m3h
(2) MCR-2X

(3)MCR-2X
250700

TREMPTM
(4)
3
(5) MCR-2X,
,

(6) MCR-2X,
,TREMPTM,
84.4%;9.1%
;3%
(8.6 MPa12.0 MPa
535)
1000 m33 t

(7)(1 m3
1.8 kg)
,,

(8)94%96%,
3738038220kJ/m3,,

(9)8.0 MPa

101000Nm3SNG10.15Kw.h
110.110-6
2
,,0.003ppm

Lurgi
2070,
1,
,
(Lugri)
F-T1
;
1
2
,

,,1984
1

,, 14
(122),18000t/d,
J&MCRG Lurgi
12,3
96%,
35564kJ/m3,12.7m3

1181E1011
181R103
181
181V1011
181E1072
181E1110.1mol
MI-101
FFIC1001

181V102

CRG
2181E102
1

1
181R1012181R102
140
181R102
320C
650C1
181E103 181E104

3200C
2

2650
2181E105
181E106

181C101
1181E1071
181E1081
1

181V103

280C
1181R103

450 C2
181E102
1181E101

181E109
2(181E110)

250

181V104
2181R104
SNG2
2
181E1113181E112
SNG181E113
SNG181V105
SNGSNG

181V101
181V103
181V104SNG181V105

181E115

181E114

50 C12
3
181E108181E110181E112181E114
130
60

40%181V108

181M101
181P101A/B
12
181E107181E111
181V106

12
1181E1032
181E105

181E103181E104460
5.1 MPa(g)

181V107

 181E116

PFD
PFD.dwg

Puraspec
2020CRG
621V102
,CRGCRG
CRG-S2SCRG-S2C

CRG-S2SRCRG-S2CR
60%40%CRGS2SRCRG-S2CR30%70%

CRG
CRG
CRG-S2SCRG-S2C
40%CRG-S2S60%CRG-S2C

CRG

CRG-S2S

CRG-S2C

/mm

3.4

/mm

2.0

/mm

3.5

5.4

/kg/m3

1450

930

/kgf

16

12

%
NiO

47

SiO2

4.3

Cr2O3

1.5

CaO

7.8

Al2O3/

CRG

()

(/h)

(h)

(h)

(%)

~100

50

100

0.5

1.5

100~200

50

3.5

200

24

27.5

200~400

50

31.5

400

33.5

20

400

35.5

30

400

37.5

40

400

39.5

50

400~450

50

40.5

50

450

42.5

50

450~500

50

43.5

50

500

45.5

50

500~550

50

46.5

50

550

16

62.5

50

550

64.5

550~500

50

65.5

500~100

50

73.5

2
3.3MPa37
464565Nm3/hCH4:15.2
CO:19.18CO2:1.32H2:63.7
HTZ--54mm50m3
H2S+CO2=COS+H2O

ZnO+H2S=ZnS+H2O

37
136ST101
4.32.5mm22.1m3
COS+ H2O= H2S+ CO2
O2+ H2= H2O
C2H4+ H2=C2H6

160
220R6002-1/2

R6002-1GCC-264mm
34m3MCR115mm26.5m3

CO+3H2=CH4+H2O
CO2+4H2=CH4+2H2O
CO+H2O=CO2+H4
C2H6+H4=CH4

675E6003
320E6007
242E6008
190D6001C6001
199E6007
277

285220

255R6002-1R6002-1
E6006296
220262R6002-2
GCC--264mm27.1m3
MCR115mm17m3
CO+3H2=CH4+H2O
CO+H2O=CO2+H4
CO2+4H2=CH4+2H2O C2H6+H2=2CH4
675E6004

 330R6003
R6003MCR115mm17m3

CO+3H2=CH4+ H2O
CO+H2O=CO2+H4
CO2+4H2=CH4+2H2O
C2H6+H2=2CH4
537E6005
365E6002
300R6004 R6004PK-7R
15.2m3389E6009
310

E6011175
E6010170,E6001
154E6013
70D600270
C6002230R6005
R6005PK-7R34.2m3
301E6019139E6015
70E6016
40D60032.32MPa
40172406Nm3/hCH4:97.84

CO:14ppmCO2:0.18H2:1.44

PFD
PFD.dwg

1.

12

15CrMoR34
CrMo

2.
1 2

5.2MPaG

1 2
1 2
SA516 Gr70

3.

159

4.
2.38MPa
13.2MPaA

1H2COCO2

CO+3H2=CH4+H2O

0298= 206.2kJ.mol-1

CO2+4H2=CH4+2H2O

0298= 165.0kJ.mol-1
21% CO
721% CO260
T=72[ CO]+60[ CO2]
T--COCO2%

Ni Al2O3MgO Re2O3
Al2O3 Al2O3
Al2O3
MgO
Re2O3

1

H2CO
NiONi
Al2O3

NiO+ H2= Ni+ H2O

0298= 2.55kJ.mol-1

NiO+ CO= Ni+ CO2

0298= -30.25kJ.mol-1

350~400
400

25% 50%

4
N2-H2

3%

2N2 N2-H2

3H2N2-H2
COCO2
0.7%

4
300
CO2
CO21%
5

25%~50%1500~2500-1
6
35

7350
COCO210mg/kg

COCO2

4004~8

300
300~600

300~600CO2
600-650

650~700CO2

COCO2

CH4

COCO2

CO2CO2

CO2COCO2

:
1

2
CO CO2 H2S

1COCO2

2
1/4 ~1/3


(1).xls

 1
A
B

C
H2SCO2

A.B.C.D.

A.B.C.

A.B.C.

A.

B.

C.

D.

E.CO2H2S

 4--

A.:1

B.:11
()

C.:

A
/

B:

5
a
b
c
d

(1)

(2)

4 5

7
8

10

A.

150.2285.5
1.125420
206.7

-7.2
25 1.33Pa
0.9-9.2%
609.610-3PaS

 TEG
C6H14O4

-OH

CH2OCH2CH2OH

CH2OCH2CH2OH

LV

PV

TV

( )

LV

PV

TV

()

 TEG100

/
/

LV

PV

TV

6~12

.dwg

A.
TEG

B.TEG

C.

0.4-0.55MPa

TEGTEG

304

/
/

200-204

98.8107

 7.

10
10F(5)


204

107
105120

1kg25-60L

(1)
98.5%

(2)
7-7

98.5%()

 (3)
7-8

99.99%()-73

1
1

3
10C10C
15~21C

48C

26~43C

 2
3.45~8.27MPa
3

10C

6~8
5

 PFD
.DWG


1
112.574.2%

20mg/m3

 24.1-74.1%

35.3-15.1%