Vidyamandir Classes

VMC/JEE-2015 1 3.0HRT-1(ACEG)/Solutions

Solutions to 3.0HRT-1 [ACEG]/JEE-2015/[CHEMISTRY]

1.(D) In 1 kg of sample,
3
HCO
g 305 mg 5m.moles

=

3 2
Ca(HCO )
n 2.5 m.moles =

3 2 3 2
CaO(s) Ca(HCO ) (aq) 2CaCO (s) H O( ) + +

3 2
CaO)rqd. Ca(HCO ) present
(n (n ) 2.5m.moles 2.5 56mg 140mg = = = =
2.(B)
2 3 2 2
Na CO (aq) 2HCl(aq) 2NaCl(aq) CO (g) H O( ) + + +

2 3 2
Na CO CO
2.4
n n moles
44
= =
2 3 2
2 3
Na CO CO
(x 2)
Na CO
(x 2)
2.2
gmeq gmeq 2
44
or
gmeq 2.2
n moles
x 44
=
=

= =



`

= =


)


2 3
Na CO NaCl
2.2
g 106 5.3g g 12 5.3 6.7g
44
= = = =
3.(B)
( ) ( )
3 2 3 2
Cu(NO ) Cu Cu(NO )
reqd. reqd.
31.75 1 1
n n mol g 187.5 93.75g
63.5 2 2
= = = = =
4.(C)
Si Si
0 0
7
g 7g n 0.25 moles
28
8
g 8g n 0.5 moles
16

= = =

= = =

)
formula is
0.25 0.5 2
Si O SiO

5.(B) 93% (wt/vol)
2 4
H SO 93g of H
2
SO
4
in 100 ml solution
93 g of H
2
SO
4
in 186 g of solution
solution
( d 1.86 g/ ml) =

solvent
g 186 93 93g = =
93 98 1000
m 10
93 1000 98
= = =
6.(A) Higher than molecular weight slower will be the rate.

2 4 2
SO CH H
p p p > >

7.(C) PM = dRT, Now
2
oxide O
d d =

2 2
2
O O oxide oxide oxide
oxide O
P M P M 1.5 M 4.5 32
T T 293 283

= =

oxide
4.5 32 293
M 99 g/ mol
283 1.5

=

8.(A)

2 3
2S 3O 2SO + 100 %
2 moles 3 moles 2 moles

3 2 2 4
SO H O H SO + 50%
2 moles
1
2 1mole
2
=
2 4 3 4 2 2
2P 5H SO 2H PO 5SO 2H O + + + 80%
1 mole
2
1 0.8 0.32 moles
5
=




(Yield)

Vidyamandir Classes

VMC/JEE-2015 2 3.0HRT-1(ACEG)/Solutions
9.(B)
2 2 3
Na S O
0 B
M 100 4 1000
m 7.04
1000 M(M ) (1000 12) (4 (158)

= = =



2 2 3
Na S O
Na
m 2m 2 7.04 14.08 molal
+
= = =

10.(B)
3
2
3
5 10 [Cl ] 0.5
[Cl ] [NaCl] 0.5M [BaCl ] M
2 2 10 10

= = = = =

2
BaCl
0.5 500 0.25
n moles 208 26g
2 1000 2
= = =

11.(C)
2 4
2 H SO 2 L
reqd.
(Base)
Na O 31g 0.5moles 1gmeq(x 2) (gmeq) 1 2 0.5 V V 1L
(
= = = = =


12.(D) Open vessel P, V const.
1
1 1 2 2 2
n
n T n T n
5
| |
= =
|
\ .


1 1 1 1
2
2 1
n T n T
T 5 400 2000K
n n 5
= = = =
/


13.(A)

Initial :
0 0 0 0
P , V , n , T
0 0 0 0
P , V , n , T
Final :
1 0 1 0
P , V , n , T
1 0 2 1
P , V , n , T

1 1 0 1 0 1 0 2 1
1 0 2 1 1 2
2
n 5 P V n RT n T n T
P V n RT n (400) n (500)
n 4
= =
=
` `
= =
) )


14.(B) Clearly, excess O
2
= 10 ml
2
O used
(V ) 60 10 50ml = = and
2
CO
V 40 10 30ml = =

x y 2 4
y
C H (g) x O (g) BaSO (s)
4
| |
+ +
|
\ .

10 ml
y
10 x 50
4
| |
+ =
|
\ .
. . .(i) 10x = 30 . . .(ii)
From (i) and (ii) = x = 3 and y = 8 Hydrocarbon is C
3
H
8


15.(C)
as acid as
2 3 2
4 4 4 3 4
base
HPO H PO ; HPO 2H H PO
(x 1) (x 2)
+ +
+ +
= =

16.(C)
3
3
solution
m.moles of Al ions 2 0.2 20
[Al ] 0.2M
V (mL) 20 20
+
+

= = =
+


2 0.6 20
[Cl ] 0.6M
20 20

= =
+

Now, m.moles of
2
4
SO 3 0.2 20 12m.moles

= = and m.moles of
2
Ba 0.6 20 12m.moles
+
= =
Now,
2 2
4 4
Ba (aq) SO (aq) BaSO (s)
+
+
2 2
insolution 4 insolution
[Ba ] [SO ] 0M
+
= =

17.(C) After connection :

2
total He N
n n n = +

2 2 2
H He N N T T
P V P V P V
RT RT RT
= +

T
(250 100) (150 200) 550
P 137.5mm of Hg
(250 150) 4
+
= = =
+


Vidyamandir Classes

VMC/JEE-2015 3 3.0HRT-1(ACEG)/Solutions
18.(D)
2
N old total
4
(p ) 0.4 p
(1 2 3 4)
= =
+ + +


2
N new total total
3
(p ) p 0.33 p
(1 2 3 3)
= =
+ + +

% change =
2
2
N
N old
p 0.4 0.33
100 100 17%
(p ) 0.4
A
=

19.(D)
3 2
CaCO CaO CO
A
+

2 2 3 2
CO 2NaOH Na CO H O + +
9 mmole 50 mmole
0 32 mmole 9
32 mmoles of NaOH and 9 mmoles of Na
2
CO
3
will need 41 mmole of HCl.
Since HCl is 0.5 M
volume required is 82 ml

20.(B) 2A 3B 4C 5D + +
When one mole each of A and B are reacted.
Only
2
3
mole of A will react, one complete mole of B will be consumed.
Now, moles of C formed =
4 2
1.33
2 3
=
moles of D formed =
5 2
1.67
2 3
=
moles of A left =
2 1
1 0.33
3 3
= =
moles of B left = 1 1 0 =

21.(B) Meq of Mg(OH)
2
= 2 0.1 100 ml 20 meq =
Meq of H
2
SO
4
= 200 0.01 2 4 meq =
Meq of MgSO
4
= 200 0.1 20 meq =
(MgSO
4
will give neutral solution) Resulting solution is clearly alkaline.

2
100 0.1 200 0.1
[Mg ] 0.06M
100 200 200
+
+
= =
+ +


2
4
200 0.01 200 0.1
[SO ]
500

+
=
2 20 22
0.044
500 500
+
= = =
22.(A)
2 2 2 2
1
H O H O O
2
+
40 mmole 20 mmole

2
1
Mg O MgO
2
+
20 mmole 40 mmole

23.(D) As we know, for Boyle's law :
PV C =
Take P = Y

1
x
V
=

1
y C
x
= Y Cx = Which is a straight line passing through origin.
Vidyamandir Classes

VMC/JEE-2015 4 3.0HRT-1(ACEG)/Solutions
24.(B)
2
2
SO He
SO He
M r 64
4
r M 4
= = =
As we more away from the origin, temperature of the isotherm increases. For Boyle's law.

25.(C) Statement 1 is true as equal moles contain equal molecules.
Moles of O
2
=
1
2
, moles of
2
1
SO
2
=
Statement 2 is false
2 2 2 2
1
H O H O O
2
+
Solutions to 3.0HRT-1[ACEG]/JEE-2015/[PHYSICS]

26.(A)
( )
( )
15 4 5
3
4 15 3 5
/
Qsin
tan
P Qcos P /
u
o
u
= =
+ +
27.(D)

28.(C) C is opp. to the resultant of and a b
2 2
13 units | C| a b = + =

29-30. 29.(B) 30.(C)
T
1
= 5g
T
1
= 2g + T
2

& T
2
+ N = 8g
T
1
= 50 Newton
T
2
= 30 Newton
N = 50 Newton






31.(B)




2 1
6 60 T T g sin = =
2
30 3 T N =

32.(D) ( ) ( ) ( )( )
2 2
17 8 15 2 8 15 cosu = + + 0 cosu =

33.(B) ( ) ( ) ( )( )
2 2
2 2
2 P Q P Q P Q P Q P Q cosu + = + + + +

( )
2 2 2 2 2 2
2 2 2 P Q P Q P Q cosu + = + +
( )
2 2
2 2
2
P Q
cos
Q P
u
+
=

34.(C)
2 2 2
2 R P Q PQ cosu = + +
1
2
cosu

=
2
3
t
u =

35.(D) ( ) ( )
P Q P Q + = P P P Q Q P Q Q + = ( )
0 0 2 Q P Q P Q P + + =

36.(D) ( )( )
2 2
1 2 3 2 2 3 cosu = + + 1 cosu = 180 u =

37.(B)
2 2
2
change in velocity 6 8
av.acc. = 1
time 10
m/ s
+
= =


B
T
1

T
2
2g
A
N
T
2

8g
C
T
1

5g
A
N
2

T
2

2g
T
1

T
1
N
1

6 60 g sin
6 60 g cos
P
Q
R
135
135
Vidyamandir Classes

VMC/JEE-2015 5 3.0HRT-1(ACEG)/Solutions
38.(C) 2 2 |R| | P| |Q| = =




39.(D) Distance =
( ) ( )
2 2
15 15 2 45 15 2 45 8 sin cos +
= 7 km




40-41. 40.(C) 41.(D)
Let it ace. For time t.
v = 2t and ( ) 0 4 3 v t =
t = 2 sec, and v = 4m/s
and total distance travelled = ( ) ( ) ( )( )
2 2 1 1
2 2 4 1
2 2

+
` `
) )
= 6m

42.(B) Separation is minimum when velocity becomes equal, Let it happens in time t. for rear train :
( ) 4 20 1 16 t t sec = + =
displacement of rear train =
( ) ( )
( )
2 2
4 20
192
2 1
R
S m

= =

displacement of front train = 4 16 = 64 m
minimum separation = 192 64 128m =

43.(C) x = 12 + 18t + 9t
2

v = 18 + 18t
A = 18 m/s
2
44.(A)
1
2
2 2 1 1
1 1 2 2
2 2
1 1
2 2
T H
H gT & H gT
T H
(
= = =
(


45.(A) ( ) ( )
2 1
10 8 320
2
h h m = = 80
4
h
m =
( )
2
1
80 10 4
2
t t sec = =
46.(A) Using
2
1 2 S vt / at = ( )( )
2 1
0 10 1 5
2
S m = = 47.(A)
48.(B) ( ) ( )
2 2
1 1 2 2
1 1
0 and 0
2 2
X t X t o | = + =

2
1 1
2
2
2
X t
X
t
o
|
= (i)
Let V: max. velocity
1 2
v t t o | = =

2
1
t
t
o
|
= (ii)

2
1 2 1 1
2
2 1 2
2
X t t t
.
X t t
t
= =
1 1
2 2
X t
X t
|
o
= =

49.(B) Let t: total time.
( )
2
2
1 1
1 and
2 2 2
h
g t h gt = =
( )
2
2
2 1 t t =

( )
2 2 t sec. =
But 1 t should be positive.
45
15 2 km
15 km
8 km
Vidyamandir Classes

VMC/JEE-2015 6 3.0HRT-1(ACEG)/Solutions
2 2 t = + .
50.(D) w.r.t bus:
1000
10
100
r
v m/ s = =
10 20
s B S
v v m/ s v m/ s = =
Vidyamandir Classes

VMC/JEE-2015 7 3.0HRT-1(ACEG)/Solutions
Solutions to 3.0HRT-1[ACEG]/JEE-2015/[MATHEMATICS]

51.(B) As we have to comment upon the nature of roots, find D.
( ) ( )( )( )
2
11 4 2 3 D a b c a b a b = + + ( (


=
( ) ( )
2 2
121 24 0 as + + + > = a b c a b a b .
Roots are real and unequal.

52.(B) 4 6 7 2 cos x cos x + =
2
2 2 7 2 5 0 cos x cos x + =

( )( ) 2 2 5 2 1 0 cos x cos x =
5
2 1
2
cos x , = 2 1 cos x =
2 2 x n , n I or x n , n I t t = e = e .
Sum of roots =
( )( ) 100 101
0 2 100 5050
2
..... t t t t t + + + + = =
53.(A)
2 2 2
1 1 sin x sin x sin x sin x cos x + = = =
Now,
12 10 8 6
3 3 1 cos x cos x cos x cos x + + + =
( )
6 6 4 2
3 3 1 1 cos x cos x cos x cos x + + +
=
( )
3
6 2
1 1 cos x cos x + = ( )
3
3
1 1 sin x sinx + =
( )
3
2
1 sin x sin x + = ( )
3
1 1 0 =
54.(C) ( )
( )
2 2
1
3 2 2 3
2
f sin sin . sin sin sin . sin u u u u u u u = + = +
=
| | ( ) ( )
2
1 1
1 2 2 4 1 4 2
2 2
cos cos cos cos sin u u u u u + = =
( ) 0 f u > for all real u .

55.(B)
( ) ( )
2 2 2 2
2 1 5 3 4 1 0 + + + + + = a n n a n x n n

( ) ( )
2 2 2 2
2 5 3 5 4 1 0 n a a x a a a + + + + =
it is identity in x.
(i)
2
2 5 3 0 a a + = ( ) ( ) 2 3 1 0 a a =

3
1
2
a , =
(ii)
2
5 4 0 a a + = ( )( ) 1 4 0 a a =
1 4 a , =
(iii)
2
1 0 a = 1 1 a , =
Only solution is a = 1
Number of value of a = 1.

56.(B) ( )
2
1 3 0 x a x + = has both roots positive
( )
2
1 12 0 D a = >
( )
, 1 2 3 1 2 3, a
(
e +

. . . .(i)
Sum of roots = 1 0 a > and product of roots 3 0 = > 1 a > . . . .(ii)
Common solution of (i) and (ii) is 1 2 3 a > + . . . . (1)

2
3 6 0 x x a + + = has both roots negative :
15
9 24 4 0
4
D a a = + > > . . . .(iii)
Sum of roots = 3 0 < and product of roots = 6 0 a > 6 a < . . . . (iv)
Common solution of (iii) and (iv) is
15
, 6
4
a
|
e
|
.
. . . . (2)
Common solution of (1) and (2) is
)
1 2 3 6 a ,

e +

a = 5 is the only integral solution

Vidyamandir Classes

VMC/JEE-2015 8 3.0HRT-1(ACEG)/Solutions
57.(D)
( )
2
5 7 6 0 m x x x R < e
5 0 and 0 m D < < 5 m < . . . . . (i)
and
( ) 49 24 5 0 m + < 71 24 m / < . . . . . (ii)
Common solution of (i) and (ii) is : 71 24 m / <

58.(B)
3 5
sin sin sin ....
n n n
t t t
+ + + upto n terms
Angle are in A.P. with common difference
2
n
t
=

2
,
n n
t t
o | = = Sum = ( )
( )
2
1 0
2
2
n
sin
sin sin
sin n
sin sin
n
|
t t
|
o
| t
| |
+ = =
|
\ .

59.(D)
2 2
3 3 1 3 3 sin cos cos cos u u u u + = + = or
2
3 2 0 cos cos u u + =

( ) ( ) 1 2 0 1 2 1 cos cos cos , cos u u u u = = =
The possible value of u in
| | , t t is 0 u =

60.(C) 3 1 k cos x sinx k = +
But
2 2
3 9 9 k cos x sinx k , k x R
(
e + + e
(



2 2
9 1 9 k k k + s + s +
( )
2
2
0 1 9 k k s + s + or
2 2
0 2 1 9 k k k s + + s +
( )
2
2
0 2 1 0 1 k k k k R s + + s + e
( |
2 2
2 1 9 2 1 9 4 k k k k k , + + s + + s e
Combining the above results we get
( | 4 k , e

61.(C) Let the equal roots found out by writing the co-efficient of x incorrectly are x , o o =
Then
2
c
a
o = . . . .(i)
The roots when the constant term is written incorrectly are 2 x , o o =
3
b
a
o

= . . . .(ii)
Now, for the correct equation assume that x , o = are the roots.
( ) ( )
2
k o o = or ( ) ( )
2
4 k o o o + =
or ( ) ( ) ( )
2
4 k o o + = + or ( )
2
4
b c
k
a a
| | | |
= +
| |
\ . \ .

Putting the values of
c
a
and
b
a

from (i) and (ii) in the above equation we get ( )

2 2
9 4 k o o = +
9 4 k = + or k = 5.

62.(B) Let the given expression be y
i.e.
2
2
2 3 6
x
y
x x
+
=
+ +
( ) ( )
2
2 3 1 6 2 0 x y y x y + + =
If 0 y = , then 0 A > for real x
i.e.,
2
4 0 b ac >
( ) ( )
2
3 1 8 6 2 0 y y y >
5
71
24

Common
Solution
Vidyamandir Classes

VMC/JEE-2015 9 3.0HRT-1(ACEG)/Solutions

2
39 10 1 0 y y + + >
( )( ) 13 1 3 1 0 y y + s

1 1
13 3
y s s
If y = 0, then 2 x = which is real and this value of y is included in the above range.

63.(B) Here
2 2
0 ax bx c + = does not have real roots so
2 2
0 4 0 0 < < > D b ac a
Graph of f (x) will be parabola opening upward.

( ) 0 f x x R > e
( )
2
2 0 4 2 0 f a b c > + >

64.(A)
2 2 2 2
1
16 16 10 16 16 10
sin x cos x sin x sin x
+ = + =

2
2
16
16 10
16
sin x
sin x
+ =
Put
2
16
sin x
t = to get
16
10 t
t
+ = or
2
10 16 0 t t + =
or
( )( ) 2 8 0 t t = or
2
2 8 16
sin x
t , = =

2
1 4 2
1
16 2 16
4
sin x
sin x = = = or
1
2
sin x =
or
5 7 11
6 6 6 6
x , , ,
t t t t
=

2 2
4 3 2
16 8 2 2 4 3
sin x sin x
sin x = = = or
2
3
4
sin x =
or
3 2 4 5
2 3 3 3 3
sinx x , , ,
t t t t
= =

65.(A)
( ) ( )
2 2
2 2
x x x x
sin e . cos e

= +

( ) ( ) ( )
1 2 2
2
2 4 4
x x
x x
sin e . cos e

= +
( ) ( )
1 1
2 2 2
2 4
x x x
sin e

= +
Now
( )
1 1 1
2
2 2 2
x
sin e

s s and
( )
1 1
2 2
4 2
x x
+ >

( ) ( )
1 1
2 2 2
2 4
x x x
sin e

= + iff
( ) ( )
1 1 1
2 2 2
2 4 2
x x x
sin e

= + =

( )
2 1
x
sin e = and 2 2 2
x x
+ =
2 2 2 2 1
x x x
+ = = or x = 0
But for x = 0,
( )
2 1
x
sin e = No solution of the given equation.
66.(B) As , , , o | o are the four angles of a cyclic quadrilateral o t + = and | o t + =
o t = and | t o =
or cos cos o = and cos cos | o =
or 0 cos cos o + = and 0 cos cos | o + =
0 cos cos cos cos o | o + + + =
67.(A) ( )
2
3 2 0 x a x + <
Let, ( ) ( )
2
3 2 f x x a x = +
2 and 5 must be within the roots of ( ) 0 f x =
(1) ( ) ( ) ( )
2
2 0 2 2 3 2 0 0 f a a < + + < < . . . . (i)
and (1) ( ) ( ) ( )
2
5 0 5 5 3 2 0 5 12 0 2 4 f a a a . < + + < + < < . . . . (ii)
From (i) and (ii) 2 4 a . <
x
Vidyamandir Classes

VMC/JEE-2015 10 3.0HRT-1(ACEG)/Solutions
68.(B)
( )
( )
2 2
2 2 1 0 x x + + + <

( ) ( ) ( )
2
2 0 2 1 0 2 1 , + < + < e . . . . (i)
( )
( )
2
2
D 2 4 2 0 = + + + < ;
2
5 8 4 0 + <

( ) ( ) 2 5 2 0 + <
2
2,
5

| |
e
|
\ .
. . . . (ii)

69.(B) For the equation to be formed sum of roots = b + c
and Product of roots = bc
Now, we have b o | + = and c o| =

( ) ( ) ( ) b c b c o | o| + = = + and
( ) ( ) ( ) ( ) bc b c o | o| = = +
The required equation is ( ) ( )
2
0 x x o | o| o | o| ( + + + + + =



70.(D) 36 72 108 144 sin sin sin sin

( ) ( )
2 2 2 2
1
36 72 2 36 2 72
4
sin sin sin sin
(
= =
(



( ) ( )
1
1 72 1 144
4
cos cos ( =

( ) ( )
1
1 18 1 36
4
sin cos ( = +



1 5 1 5 1
1 1
4 4 4
(
| | | |
+
( | | = + +
| |
(
\ . \ .

1 5 1 5 1 4
1
4 4 4 16
(
| | | |
| |
( | | = +
|
| |
(
\ .
\ . \ .

1 1 1 5
1
4 2 4 16
(
= + =
(


71.(C) f (0) = c > 0 . . . . (i) , a < 0 . . . . (ii) and 0 0
2

> >
b
b
a
. . . . (iii)
From (i), (ii) and (iii)
We get : ac < 0 ; ab < 0 ; bc > 0 and abc < 0

72.(C)
2
2
2 2 4
4 3
x x
y
x x
+
=
+
( ) ( )
2
2 2 1 2 4 3 0 x y x y y + =
As x 0 R , D e >
( ) ( ) ( )
2
4 1 2 4 2 4 3 0 y y y > ( ) ( ) 7 1 0 y y + > ( | | ) , 7 1, y e
73.(B)
( )
( )( )
2
1
0
2 3
x x
x x

s
+
Case I : When 0 x =
( )
( ) ( )
1
0
2 3
x
x x

s
+

Critical points : 2 3 1 , , ( ) | ) 2 1 3 x , , e
x = 0 also satisfies inequality ( ) | ) { } 2 1 3 0 x , , e is the final solution.
74.(B) ( ) ( ) ( ) ( ) ( ) ( ) ( ) 2 sin sin sin . cos cos sin o o | o | o | o | o | o | ( = + + = + + +



4 4 3 3 16 9
1
5 5 5 5 25 25
| | | |
= + = + =
| |
\ . \ .
( ) 2 0 cos o =
75.(B) ( )
2 2
2
0
2
a b
x a b x
+
+ + + =
( )
2 2
2
a b
a b , o | o|
+
+ = + =
Equation whose roots are ( )
2
o | + and ( )
2
o | has sum of roots ( ) ( )
2 2
S o | o | = = + +
( ) ( )
2 2
4 o | o | o| = + + + ( )
( )
2
2 2
2 4 a b a b ab
(
= + + =
(


Product of roots = P =( ) ( )
2 2
o | o | +
( ) ( )
2 2
4 o | o | o|
(
= + +
(

( ) ( )
( ) ( )
2
2 2
2 2 2 2
2 a b a b a b a b
(
= + + + =
(


Hence, equation is
( )
2
2 2 2
4 0 x abx a b =
2


+
1
3
+
1 2
5

2
Common
Solution