Jee Main2013key

Sri Chaitanya IIT Academy.
, India
2013
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2013 JEE-Main QPaper with Solutions
IMPORTANT INSTRUCTIONS: CODE :P

1. Immediately fill the particulars on this page of the Test Booklet with Blue/Black ball point pen.
Use of pencil is strictly prohibited.
2. The answer sheet is kept inside this test booklet. When you are directed to open the test booklet, take
out the answer sheet and fill in the particulars carefully.
3. The test is of 3 hours duration
4. The test booklet consists of 90 questions. The maximum marks are 360
5. There are three parts in the question paper A,B,C consisting of physics, chemistry and mathematics having
30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct re-
sponse.
6. Candidates will be awarded marks as stated above in instruction No.5 for correct response of each
question. 1/4 (one fourth) marks will be deducted for indicating incorrect response of each question. No
deduction from the total score will be made if no response is indicated for an item in the answer sheet.
7. There is only one correct response for each question. Filling up more than one response in any question
will be treated as wrong response and marks for wrong response will be deducted accordingly as per
instruction 6 above.
8. Use Blue/Black Ball Pen only for writting partulars/marking responses on side-1 and side-2 of the An-
swer sheet. Use of pencil is strictly prohibited.
9. No candidate is allowed to carry any textual material, printed or written, bits of papers, paper, mobile
phone, any electronic device, etc. except the admit card inside the examination hall/room.
10. Rough work is to be done on the space provided for this purpose in the test booklet only. This space is
given at the bottom of each page and in 3 pages (pages 21-23) at the end of the booklet.
11. On completion of the test, the candidate must hand over the answer sheet to the invigilator on duty in the
room/hall. However, the candidates are allowed to take away this test booklet with them.
12. The CODE for this booklet is P. Make sure that the CODE printed on side-2 of the answer sheet is the
same as that on this booklet. In case of discrepancy, the candidate should immediately report the matter
to the invigilagor for replacement of both the test booklet and the answer sheet.
13. Do not fold or make any stray marks on the answer sheet.
Sri Chaitanya IIT Academy., India

#Corporate Office : Plot No 304, Kasetty Heights, Ayyappa Society Madhapur, Hyderabad
E-Mail - iconcohyd@srichaitanya.net, Web - www.srichaitanya.net 2/34
PART-A_PHYSICS
1. A uniform cylinder of length L and mass M having cross - sectional area A is suspended, with
its length vertical, from a fixed point by massless spring, such that it is half submerged in a
liquid of density  at equilibrium position. The extension x0 of the spring when it is in
equilibrium is
Mg Mg  LA  Mg  LA  Mg  LA 
1) 2) 1   3) 1   4) 1  
k k  M  k  2M  k  M 
(Here k is spring constant)
Ans : 3
Sol :
kx 0
LAg L
kx 0   Mg B A g
2 2
LAg
 kx 0  Mg 
2
Mg  LA 
 x0  1   Mg
k 2M 
2. A metallic rod of length ‘1’ is tied to a string of length 21 and made to rotate with angular
speed  on a horizontal table with one end of the string fixed. If there is a vertical magnetic
field ‘B’ in the region, the e.m.f. induced across the ends of the rod is:
2 Bl 2 3Bl 2 4 Bl 2 5Bl 2

1) 2) 3) 4)
2 2 2 2
Ans : 4
Sol :
3l
E  B  x dx
x 2l
5Bl2

2

3. This question has Statement 1 and Statement II. Of the four choices given after the State-
ments, choose the one that best describes the two Statements.
Statement-I: A point particle of mass m moving with speed  collides with stationary point
particle of mass M. If the maximum energy loss possible is given as
1   m 
f  m 2  then f   .
2  M m
Statement -II: Maximum energy loss occurs when the particles get stuck together as a result
of the collision.
1) Statement -I is true, Statement - II is true, Statement - II is a correct explanation of Statement -I
2) Statement -I is true, Statement - II is true, Statement -II is not a corect explanation of Statement -I
3) Statement -I is true, Statement - II is false
4) Statement -I is false, Statement - II is true.
Ans : 4
Sol :
Conceptual
4. Let 0  denote the dimensional formula of the permittivity of vacuum. If M=mass,
L = length, T=time and A=electric current, then :
1) 0    M 1 L3T 2 A 2) 0    M 1 L3T 4 A2 
3) 0    M 1 L2T 1 A2  4) 0    M 1 L2T 1 A 

Ans : 2
Sol :
q q 
0   12 2 
 rF 
 M1L3 T 4I2
5. A projectile is given an initial velocity of i  2 j m / s, where i is along the ground and j is

 
along the vertical. If g  10m / s 2 , the equation of its trajeclory is
1) y  x  5 x 2 2) y  2 x  5 x 2 3) 4 y  2 x  5 x 2 4) 4 y  2 x  25 x 2
Ans : 2
Sol :
y  ax  bx 2 = 2x  5x 2
g
a  tan   2 , b  2u2 cos 2   5

6. The amplitude of a damped oscillator decreases to 0.9 times its original magnitude in 5s. In
another 10s it will decrease to  times its original magnitude, where  equals
1) 0.7 2) 0.81 3) 0.729 4) 0.6
Ans : 3
Sol :
A  A 0e  kt
0.9A 0  A 0e 5k ...... (1)
 A 0  A 0 e 15k ......... (2)
 2
  e 10k   0.9
0.9
Solving   0.729
7. Two capacitors C1 and C2 are charged to 120 V and 200 V respectively. It is found that by
connecting them together the potential on each one can be made zero. Then:
1) 5C1  3C2 2) 3C1  5C2 3) 3C1  5C2  0 4) 9C1  4C2
Ans : 2
Sol :
C1V1  C2 V2
V
C1  C2
V0
 120C1  200C2  0
 3C1  5C2
8. A sonometer wire of length 1.5m is made of steel. The tension in it produces an elastic strain
of 1%. What is the fundamental frequency of steel if density and elasticity of steel are
7.7 103 kg / m3 and 2.2  1011 N / m 2 respectively?
1) 188.5 Hz 2) 178.2 Hz 3) 200.5 Hz 4) 770 Hz
Ans : 2
Sol :
1 T 1 stress 1 Y  strain
n0    = 178.17 Hz.
2l  2l  2l 

9. Acircular loop of radius 0.3cm lies parallel to a much bigger circular loop of radius 20cm.
The centre of the small loop is on the axis fo the bigger loop. The distance between their
centres is 15cm. If a current of 2.0 A flows through the smaller loop, then the flux linked with
bigger loop is:
1) 9.1 1011 weber 2) 6  1011 weber 3) 3.3  1011 weber 4) 6.6  10 9 weber
Ans : 1
Sol :
According to reciprocity theorem,
 
 ir 2
 0   R 2 
3/2  
 
 2 r2  x2  

= 9.1  1011 Wb.
10. Diameter of a plano - convex lens is 6cm and thickness at the centre is 3 mm. If speed of light
in material of lens is 2 108 m / s, the focal length of the lens is :
1) 15 cm 2) 20 cm 3) 30 cm 4) 10 cm
Ans :3
Sol :
2
R 2  32   R  0.3
R = 15 cm
Va 3
  , 1    1 , f = 30 cm
Vm 2 f R
11. Whata is the minimum energy required to launch a satellite of mass m from the surface of a
planet of mass M and radius R in a circular orbit at an altitude of 2R?
5GmM 2GmM GmM GmM
1) 2) 3) 4)
6R 3R 2R 3R
Ans : 1
Sol :
GMm GMm
Ei   Ef  
R 2  3R 
5GMm
W  Ef  E i 
6R

12. A diode detector is used to detect an amplitude modulated wave of 60% modulation by using
a condenser of capacity 250 pico farad in parallel with a load resistance 100
kilo ohm. Find the maximum modulated frequency which could be detected by it.
1) 10.62 MHz 2) 10.62 kHz 3) 5.31 MHz 4) 5.31 kHz
Ans : 4 (approximate)
Sol :
Question is ambiguity
13. A beam of unpolarised light of intensity I 0 is passed through a polaroid A and then through
another polaroid B which is oriented so that its principal plane makes an angle of 450 relative
to that of A. The intensity of the emergent light is:
1) I 0 2) I 0 / 2 3) I 0 / 4 4) I 0 / 8
Ans : 3
Sol :
I0
Polarised light intensity =
2
I0 I
when passed through the second one = cos 2 450  0
2 4
14. The supply voltage to a room is 120V. The resistance of the lead wires is 6. A 60 W bulb is
already switched on. What is the decrease of voltage across the bulb, when a 240 W heater is
switched on in parallel to the bulb?
1) zero Volt 2) 2.9 Volt 3) 13.3 Volt 4) 10.04 Volt
Ans : 4 (approximate)
Sol :
Question is ambiguity
120  120
Assuming 120 V rating, R   240 
60
Case – I :
120 V
 R 
>
>
>
>
6 V1   120
 R  6 
60 W
R1  R

Case –Office
#Corporate II : : Plot No 304, Kasetty Heights, Ayyappa Society Madhapur, Hyderabad
 R
120 V R
 4
 R
R 
V2  4  R
R 
>
>
> V' 6 30
>
6
R
240 W, R 2 
4
 R 
 V2   120
 R  30 
2 p0
p p0
15.
V0 2V0
V
The above p-v diagram represents the thermodynamic cycle of an engine, operating with an
ideal monoatomic gas. The amount of heat, extracted from the source in a single cycle is
 13   11 
1) p0v0 2)   p0 v0 3)   p0v0 4) 4 p0v0
2 2
Ans : 2
Sol :
Heat is extracted from the source from A to B and from B to C
nRdT 3p0 v 0
QAB  nC vdT  
 1 2
nRdT
QBC  nCpdT   5p0 v 0
 1
13p0 v 0
 Q  QAB  QBC 
2

16. A hoop of radius r and mass m rotatin with an angular velocity 0 is placed on a rough hori-
zontal surface. The initial velocity of the centre of the hoop is zero. What will be the velocity
of the centre of the hoop when it ceases to slip?
r0 r0 r0
1) 2) 3) 4) r0
4 3 2
Ans : 3
Sol :
Li  Lf
r v  r
0 
f
Mr 2 0  M  r  r  Mr2
0
 
2
r 0
v 
2
17. An ideal gas enclosed in a vertical cylindrical container supports a freely moving piston of
mass M. The piston and the cylinder have equal cross sectional area A. When the piston is in
equilibrium, the volume of the gas is V0 and its pressure is P0 . The piston is slightly displaced
from the equilibrium position and released. Assuming that the system is completely isolated
from its surrounding, the piston executes a simple harmonic motion with frequency:
1 A P0 1 V0 MP0 1 A2 P0 1 MV0
1) 2 V M 2) 2 A2 3) 2 4) 2 A P0
0 MV0
Ans : 3
Sol :
In adiabatic process
p0
p   v
v0
 Ap0  A 2p0
F    Ax  ,  k 
 v 0  v0
1 A 2p0
 frequency, n  2 Mv 0

18. If a piece of metal is heated to temperature  and then allowed to cool in a room which is at
temperature  0 , the graph between the temperature T or the metal and time t will be closest
to:
T T T T
1) 2)  0 3)  0 4)  0
O t O t O t O t
Ans : 3
Sol :
d
  k    0 
dt
0
here  decreases exponentially and reaches 0 at infinite time
19. This question has Statement I and Statement II. Of the four choices given after the State-
ments, choose the one that best describes the two Statements.
Statement - I : Higher the range, greater is the resistance of ammeter.
Statement - II : To increase the range of ammeter, additional shunt needs to be used across it.
1) Statement - I is true, Statement - II is treue, Statement - II is the correct explanation of Statement - I
2) Statement - I is true, Statement - II is true, Statement - II is not the correct explanation of Statement - I
3) Statement - I is true, Statement - II is false
4) Statement - I is false, Statement - II is true
Ans: 4
Sol :
When range is increased shunt will be lesser so net resistance decreases. Statement – I is
false when additional shunt is connected across ammeter net resistance decreases hence
range increases. Statement – II is true

20. In an LCR circuit as shown below both switches are open initially. Now switch S1 is closed,
S 2 kept open. (q is charge on the capacitor and   RC is Capacitive time constant). Which of
the following statement is correct?
R S1
C S2
1) Work done by the battery is half of the energy dissipated in the resistor
2) At t   , q  CV / 2
3) t  2 , q  CV 1  e 2 

4) t  , q  CV 1  e 
1
Ans : 3
Sol :
V
R S1
When S1 is closed, capacitor change becomes

q  q max 1  e
t
T
,q max  CV
t = 2T
q = CV (1 – e–2)

21. Two coherent point sources S1 and S 2 are separated by a small distance ‘d’ as shown. The
fringes obtained on the screen will be :
S1 S2
Screen
1) points 2) straight lines 3) semi - circles 4) concentric circles
Ans : 4
Sol :

S1 S2
For a given  , path difference and hence resultant intensity will be constant.
In 3D, it gives circle on the screen.
 Fringes will be concentric circles.
22. The magnetic field in a travelling electromagnetic wave has a peak value of 20nT. The peak
value of electric field strength is :
1) 3 V/m 2) 6 V/m 3) 9 V/m 4) 12 V/m
Ans : 2
Sol :
o  CB
 3 108  20 109
 6Vm1

23. The anode voltage of a photocell is kept fixes. The wavelength  of the light falling on the
cathode is gradually changed. The plate current I of the photocell varies as follows:
I I I I
1) 2) 3) 4)
O  O  O  O 
Ans : 4
Sol :
At any partof wave length, current never increases
24. The I - V characteristic of an LED is :

ow
en
e
d
e
l
Blu
Gr
Re
yel
B
 R Y  G  B  G V O
I I Y I
R R
1) 2) 3) 4) Y
G
O O B
I
O V V V
Ans : 1
Sol :
LED just like silicon diodes but threshold voltages increases from red to violet.
25. Assume that a drop of liquid evaporates by decrease in its surface energy, so that its tempera-
ture remain unchanged. What should be the minimum radius of the drop for this to be pos-
sible? The surface tension is T, density of liquid is  and L is its latent heat of vaporization
1)  L / T 2) T /  L 3) T /  L 4) 2T /  L
Ans : 4 Given answer ambiguity
Sol :
Decreases in surface energy = energy spent in evaporation
 4  
d  T  4r2   d  r 3  pL 
   3  
 T 8rdr  4r 2dr L 

2T
r
L
Given answer is equilibrium condition

26. In a hydrogen like like atom electron makes transition from an energy level with quantum
number n to another with quantum number (n - 1). If n>>1, the frequency of radiation emitted
is proportional to:
1 1 1 1
1) 2) 2 3) 3 4)
n n n 2 n3
Ans : 4
Sol :
If  is frequency of radiation
 1 1 

h    2
 n  1
2
n 

2n 1

n n  1
2 2
if n > > 1
1
 3
n
27. The graph between angle of deviation   and angle of incidence (i) for a triangular prism is
represented by:
   
1) 2) 3) 4)
O i O i O i O i
Ans : 3 No other answer is nearer

Sol :
i – d curve is

28. Two charges, each equal to q, are kept at x  a and x  a on the x  axis. A particle of mass
q
m and charge q0  is placed at the origin. If charge q0 is given a small displacement
2
 y  a  along the y  axis, the net force acting on the particle is proportional to:
1 1
1) y 2) -y 3) 4) 
y y
Ans : 1
Sol :
F
f' 

r  y
+q +q
a a
F  2F 'cos 
1 q q /2 y
 2.
4 0 a 2  y 2  a 2 y 2 ,
y
 F 3
a 2  y 2  2 ,if y < < a
F y
29. Two short bar magnets of length 1cm each have magnetic moments 1.20 Am 2 and 1.00 Am 2 re-
spectively. They are placed on a horizontal table parallel to each other with their N poles
pointing towards the South. They have a common magnetic equator and separated by a dis-
tance of 20.0 cm. The value of the resultant horizontal magnetic induction at the mid - point
O. of the line joining their centres is close to
(Horizontal component of earth’s magnetic induction is 3.6  10 5 Wb / m 2 )
1) 3.6 105 Wb / m 2 2) 2.56 104 Wb / m 2 3) 3.50 104 Wb / m 2 4) 5.80 104 Wb / m 2
Ans : 2
Sol :
BH
S B1 S
B2
N 0.2m N
M1  1.2Am 2
M2  1.0Am2
 B  BH  B1  B2
 0 M1
B1   1.2 104 wb/m2
4 d13
BH  3.6 105  0.36 104 wb/m2

 B  2.56 104 wb/m2

30. A charge Q is uniformly distributed over a long rod AB of length L as shown in the figure. The
electric potential at the poitn o lying at a distance L from the end A is :
O A B
L L
Q 3Q Q Q ln 2
1) 8  L 2) 4  L 3) 4  L ln 2 4) 4  L
0 0 0 0
Ans : 4
Sol :
O
x
dx
 Q
  dx
1  L 
At ‘O’, dv =
40 x
Q 2L dx
v
4 0 L  x L x
Q
 ln 2
4 0 L

PART-B_CHEMISTRY
31. Which of the following complex species is not expected to exhibit optical isomerism?
3  
1) Co  en 3  2) Co  en 2 Cl2  3) Co  NH 3 3 Cl3  4) Co  en  NH 3 2 Cl2 
Ans : 3
Sol :
[Co(NH3)3 Cl3] do not exhibit optical isomers but other exhibit.
32. Which one of the following molecules is expected to exhibit diamagnetic behaviour?
1) C2 2) N 2 3) O2 4) S 2
Ans : 1 and 2
Sol :
According to MO theory in N2 and C2 all electron s are paired. So dia magnetic.
33. A solution of (–)–1–chloro–1–phenylethane in toluene racemises slowly in the presence of

a small amount of SbCl5 , due to the formation of :
1) carbanion 2) carbene 3) carbocation 4) free radical
Ans : 3
Sol :
Cl
Ph  CH  CH3 
SbCl5
 Ph  CH  CH3  SbCl6

SbCl6
Cl
|
Ph  C H  CH3
Recimization due to formation of carbocation.
0 0
34. Given ECr 3
/ Cr
 0.74V ; EMnO 
/ Mn 2
 1.51V
4
0
E Cr2O72 / Cr 3
 1.33V ; E 0   1.36V
Cl / Cl
Based on the data given above, strongest oxidising agent will be:
1) Cl  2) Cr 3 3) Mn2  4) MnO4
Ans : 4
Sol :
It RP value is high easily reduces – powerful oxidizes agent.

35. A piston filled with 0.04 mol of an ideal gas expands reversibly from 50.0 mL to 375 mL at a
constant temperature of 37.0C . As it does so, it absorbs 208J of heat. The values of q and w
for the process will be:
( R  8.314 J / molK ) ( ln 7.5  2.01 )
1) q  208 J , w  208 J 2) q  208 J , w  208 J
3) q  208 J , w  208 J 3) q  208 J , w  208 J
Ans : 1
Sol :
Work done by system is –Ve
36. The molarity of a solution obtained by mixing 750 mL of 0.5(M) HCl with 250 mL of 2(M)
HCl will be:
1) 0.875M 2) 1.00 M 3) 1.75 M 4) 0.975 M
Ans : 1
Sol :
M1V1  M2 V2
V1  V2
37. Arrange the following compounds in order of decreasing acidity:
OH OH OH OH
; ; ;
Cl CH 3 NO2 OCH3
(I) (II) (III) (IV)
1) II > IV > I > III 2) I > II > III > IV 3) III > I > II > IV 4) IV > III > I > II
Ans : 3
Sol :
OH OH OH OH
Cl CH3 NO2 OCH3

-I-effect H ype rcon jug ative -R effect + R -effect
influ en ce
Electron donating groups decrease acidity

Electron withdrawing groups increase acidity.

38. For gaseous state, if most probable speed is denoted by C * , average speed by C and mean
square speed by C, then for a large number of molecules the ratios of these speeds are:
1) C* : C : C  1.225 :1.128 :1 2) C* : C : C  1.128 :1.225 :1
3) C* : C : C  1:1.128 :1.225 4) C* : C : C  1:1.225 :1.128
Ans : 3
Sol :
Conceptual
39. The rate of a reaction doubles when its temperature changes from 300K to 310 K. Activation
energy of such a reaction will be:
 R  8.314 JK 1
mol 1 and log 2  0.301
1) 53.6kJ mol 1 2) 48.6kJ mol 1 3) 58.5kJ mol 1 4) 60.5kJ mol 1
Ans : 1
Sol :
K 2 Ea  1 1 
2.303log    
K1 R  T1 T2 
Ea  1 1 
2.303 log 2    
8.314  300 310 
40. A compound with molecular mass 180 is acylated with CH 3COCl to get a compound with
molecular mass 390. The number of amino groups present per molecule of the former
compound is:
1) 2 2) 5 3) 4 4) 6
Ans : 2
Sol :
Mol mass difference = 390 – 180
O
||
= 210 = increased molar mass of CH  C –  43
3
210
No. of acetyl groups =
43
=5
No.of Amino functions = 5
41. Which of the following arrangements does not represent the correct order of the property
stated against it?
1) V 2   Cr 2   Mn 2   Fe 2  : Paramagnetic behaviour
2) Ni 2   Co 2   Fe2   Mn 2  : Ionic size
3) Co3  Fe3  Cr 3  Sc 3 : stability in aqueous solution
4) Sc  Ti  Cr  Mn : number of oxidation states
Ans : 1
Sol :   n n  2
42. The order of stability of the following carbocations:
CH 2
CH 2  CH  CH 2 ; CH 3  CH 2  CH 2 ;
I II III
is:
1) III > II> I 2) II > III > I 3) I > II > III 4) III > I > II
Ans : 4
Sol :
Conceptual
43. Consider the following reaction:

z
xMnO4  yC2O42  zH   xMn 2   2 yCO2  H 2O
2
The values of x, y and z in the reaction are, respectively:
1) 5, 2 and 16 2) 2, 5 and 8 3) 2, 5 and 16 4) 5, 2 and 8
Ans : 3
Sol :
2MnO4  5C2O42  16H  2Mn2  10CO2  8H2O
44. Which of the following is the wrong statement?

1) ONCl and ONO  are not isoelectronic
2) O3 molecule is bent
3) Ozone is violet – black in solid state
4) Ozone is diamagnetic gas
Ans : 1
Sol :
Conceptual
45. A gaseous hydrocarbon gives upon combustion 0.72 g of water and 3.08 g of CO2 . The
emperical formula of the hydrocarbon is:
1) C2 H 4 2) C3 H 4 3) C6 H 5 4) C7 H 8
Ans : 4
Sol :
CO2 : H2O
0.07 : 0.04, C:H=7:8
46. In which of the following pairs of molecules/ions, both the species are not likely to exist?
1) H 2 , He22  2) H 2 , He22  3) H 22  , He2 4) H 2 , He22 
Ans : 3
Sol :
In H22+ and He2 Bond order is zero so do not exhist.
47. Which of the following exists as covalent crystals in the solid state?
1) Iodine 2) Silicon 3) Sulphur 4) Phosphorus
Ans : 2
Sol :
I2 , P4 , S8 are molecular crystals
Si is covert crystal
48. Synthesis of each molecule of glucose in photosynthesis involves:

1) 18 molecules of ATP 2) 10 molecules at ATP
3) 8 molecules of ATP 4) 6 molecules of ATP
Ans : 1
Sol :
Conceptual
49. The coagulating power of electrolytes having ions Na  , Al 3 and Ba 2  for arsenic sulphide
sol increases in the order:
1) Al 3  Ba 2   Na  2) Na   Ba 2   Al 3 3) Ba 2   Na   Al 3 4) Al 3  Na   Ba 2 
Ans : 2
Sol :
Conceptual
50. Which of the following represents the correct order of increasing first ionization enthalpy
for Ca, Ba, S, Se and Ar?
1) Ca  S  Ba  Se  Ar 2) S  Se  Ca  Ba  Ar
3) Ba  Ca  Se  S  Ar 4) Ca  Ba  S  Se  Ar
Ans : 3
Sol :
Conceptual
2
18  Z 
51. Energy of an electron is given by E  2.178  10 J  2  . Wavelength of light required to
n 
excite an electron in an hydrogen atom from level n  1 to n  2 will be:
 h  6.62 10 34
Js and c  3.0  108 ms 1 
1) 1.214  10 7 m 2) 2.816 107 m 3) 6.500  107 m 4) 8.500  107 m
Ans : 1
hc
Sol : E 


52. Compound (A), C8 H 9 Br , gives a white precipitate when warmed with alcoholic AgNO3 . Oxi-
dation of (A) gives an acid (B) , C8 H 6O4 . (B) easily forms anhydride on heating. Identify the
compound (A).
CH2Br
CH 2 Br
C2H5 CH2Br
1) 2) 3) 4)
Br CH3
CH 3
CH3
Ans : 4
Sol :
C 8H9B r   
A g NO 3
 A gB r
A  (ppt)
O 

B C 8 H 6 O 4     A n h y d r id e
COOH
" B " m ust be phthaleic acid i.e.,
COOH .. so
CH2  Br
" A " must be
CH3
53. Four successive members of the first row transition elements are listed below with atomic
numbers. Which one of them is expected to have the highest EM0 3
/ M 2
value?
1) Cr  Z  24  2) Mn  Z  25  3) Fe  Z  26  4) Co  Z  27 
Ans : 4
Sol :

E Fe 3
/fe z 
 0.77 , E Ce3 /Co2  1.97
E   0.41, E  3 2  1.57
Cr 3 /Cr 2 Mn /Mn
54. How many litres of water must be added to 1 litre of an aqueous solution of HCl with a pH of
1 to create an aqueous solution with pH of 2?
1) 0.1 L 2) 0.9 L 3) 2.0 L 4) 9.0 L
Ans : 4
Sol :
M1  10 1M, V1  1 lit , M2  102 M, V2  10 lit

55. The first ionization potential of Na is 5.1 eV. The value of electron gain enthalpy of Na  will
be:
1) – 2.55 eV 2) –5.1 eV 3) –10.2 eV 4) +2.55 eV
Ans : 2
Sol :
Conceptual
56. An organic compound A upon reacting with NH 3 gives B. On heating, B gives C. C in pres-
ence of KOH reacts with Br2 to give CH 3CH 2 NH 2 . A is:
1) CH 3COOH 2) CH 3CH 2CH 2COOH
CH 3  CH  COOH
3) 4) CH 3CH 2COOH
CH3
Ans : 4
Sol :
O O
|| ||
CH3  CH2  C OH  NH3  CH3  CH2  C ONH4
 H2O
O
||
Br2 /kOH
CH3  CH2  NH2  CH3  CH2  C NH2
Hoffmann – Bramamide rearrangement.
57. Stability of the species Li2 , Li2 and Li2 increases in the order of:
1) Li2  Li2  Li2 2) Li2  Li2  Li2 3) Li2  Li2  Li2 4) Li2  Li2  Li2
Ans : 2
Sol :
Bond orders in Li2 = 1 Li2  0.5 Li2  0.5 stability is proportional to bond order. Though
bond order in Li2 and Li2 is same the electron in antibonding MO destabilize the Li2 so
order is Li2  Li2  Li2
58. An unknown alcohol is treated with the “Lucas reagent” to determine whether the alcohol is
primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism:
1) secondary alcohol by S N 1 2) tertiary alcohol by S N 1
3) secondary alcohol by S N 2 4) tertiary alcohol by S N 2
Ans : 2

Sol :
ZnCl HCl
OH 
2
 Cl  H2O
Mechanistic path is SN1
59. The gas leaked from a storage tank of the Union Carbide plant in Bhopal gas tragedy was:
1) Methylisocyanate 2) Methylamine
3) Ammonia 4) Phosgene\
Ans : 1
Sol :
Conceptual
60. Experimentally it was found that a metal oxide has formula M 0.98O. Metal M, is present as
M 2 and M 3 in its oxide. Fraction of the metal which exists as M 3 would be:
1) 7.01% 2) 4.08% 3) 6.05% 4) 5.08%
Ans : 2
Sol :
4
Percentage =  100  4.08%
98

PART-C_MATHEMATICS
61. Distance between two parallel planes 2 x  y  2 z  8 and 4 x  2 y  4 z  5  0 is :
3 5 7 9
1) 2) 3) 4)
2 2 2 2
Ans : 3
Sol :
 16  5  21 7
Distance between the planes is    6 2
16  4  16 
62. At present, a firm is manufacturing 2000 items. It is estimated that the rate of change of
dp
production P w.r.t. additional number of workers x is given by  100  12 x . If the firm
dx
employs 25 more workers, then the new level of production of items is:
1) 2500 2) 3000 3) 3500 4) 4500
Ans : 3
Sol :
dp
 100  12 x  p  100 x  8x x  C
dx
At p  2000, x  0  c  2000
 at x = 25, p  2000  100  25  8  255  3500
63. Let A and B be two sets contaning 2 elements and 4 elements respectively. The number of
subsets of A  B having 3 or more elements is:
1) 256 2) 220 3) 219 4) 211
Ans : 3
Sol :
n  A  B  2  4  8
8
C3  8C 4  ....  8C3  28   8 C0  8C1  8C2 
 256  1  8  28  256  37  219
x2 y3 z 4 x 1 y  4 z  5
64. If the lines   and   are coplanar, then k can have:
2 1 k k 2 1
1) any value. 2) exactly one value.
3) exactly two values. 4) exactly three values.
Ans : 3

Sol :
1 1 k
k 2 1 0 1   k  1  k  k  2  0
1 1 1
k 2  3k  0
k = 0, - 3
 
65. If the vectors AB  3iˆ  4kˆ and AC  5iˆ  2 ˆj  4kˆ are the sides of a triangle ABC, then the
length of the median through A is:
1) 18 2) 72 3) 33 4) 45
Ans : 3
Sol :
AB  AC  2 AD
1 1
AD 
2
 
AB  AC  8iˆ  2ˆj  8k
2
ˆ  
= 4iˆ  ˆj  4k
ˆ
|AD| 16  1  16  33
66. The real number k for which the equation, 2 x3  3x  k  0 has two distinct real roots in
 0,1
1) lies between 1 and 2. 2) lies between 2 and 3.
3) lies between -1 and 0. 4) does not exist.
Ans : 4
Sol :
Let f  x   2x 3  3x  k
 f '  x   6x 2  3  0 x  R
 f  x  is strictly increasing
67. The sum of first 20 terms of the sequence 0.7,0.77,0.777,..., is :

7 7
1)
81
179  1020  2)
9
 99  1020 
7 7
3)
81
179  1020  4)
9
 99  1020 

Ans : 3
Sol :
7
9
0.9  0.99  0.999  .....20 terms
7
 1  0.1  1  0.01  1  0.001  ....20 terms 
9
7  1  1  2  1  3  
 20          ....20 terms  
9  10  10   10   
   1  20  
 1     
7 1  10  
 20  
9 10 1
 1 
 10 
7 179  10 20  7
    179  1020 
9 9  81
68. A ray of light along x  3 y  3 gets reflected upon reaching x-axis, the equation of the
reflected ray is:
1) y  x  3 2) 3y  x  3
3) y  3 x  3 4) 3y  x 1
Ans : 2
Sol :
1
y0 
3

x 3 
3y  x  3
69. The number of values of k, for which the system of equations:

 k  1 x  8 y  4k
kx   k  3 y  3k  1
has no solution, is:
1) infinite 2) 1 3) 2 4) 3

Ans : 2
Sol :
k 1 8 4k
 
k k  3 3k  1
k3
70. If the equation x 2  2 x  3  0 and ax 2  bx  c  0, a, b, c  R, have a common root, then

a : b : c is
1) 1: 2 : 3 2) 3: 2 :1 3) 1: 3 : 2 4) 3:1: 2
Ans : 1
Sol :
x 2  2x  3  0    4  12  8  0
 both roots are common for the given equations
a b c
123  a: b:c=1:2:3
71. The circle passing through 1, 2  and touching the axis of x at  3,0  also passes through the
point:
1)  5, 2  2)  2, 5  3)  5, 2  4)  2,5 
Ans : 3
Sol :
Equation of the circle which touches x-axis at (3, 0) is in the form
 x  3   y 2  y  0
2
It also passes through 1,  2    4

2
Equation of the circle is  x  3  y 2  4y  0 and it also passes through
72. If x, y, z are in A.P. and t tan 1 x, tan 1 y and tan 1 z are also in A.P., then:
1) x  y  z 2) 2 x  3 y  6 z 3) 6 x  3 y  2 z 4) 6 x  4 y  3z
Ans : 1
Sol :
tan1y  tan1 x  tan1 z  tan1 y
1  y  x   zy yx zy

 tan    tan1    
 1  xy   1  2y  1  xy 1  2y
But x  y  y  z
 xy  yz  y  0 or x  z , x  y  z

73. Consider :
Statement-1:  p ~ q    ~ p  q is a fallacy
Statement-II:  p  q  
  ~ q ~ p  is a tautology..
1) Statement-1 is true; Statement-II is true; Statement-II is a correct explanation for Statement-I.
2) Statement-1 is true; Statement-II is true; Statement-II is a not correct explanation for Statement-I.
3) Statement-1 is true; Statement-II is false.
4) Statement-1 is false; Statement-II is true
Ans : 2
Sol :
S – I :  p ~ p    q  ~ q   c  c  c
S – II : p  q  ~ q  ~ p
  p  q   ~ q  p is a tautology
 f  x  dx    x  , then  x f  x dx is equal to:

5 3
74. If
1 3
1) x   x 3    x 2  x 3  dx   C
3 
1 3
2) x   x 3   3 x3  x3  dx  C
3
1 3
3) x   x 3    x 2  x 3  dx  C
3
1 3
4) x   x 3    x 3  x 3  dx   C
3 
Ans : 3
Sol :
Put x 3  t, then 3x 2 dx  dt
1
I t f  t dt
3
1
 t   t     t dt 
3 
1 3

3     
x  x 3  3  x 3 x 2dx   C

1 3

3
   
x  x 3   x 2  x 3 dx  C

lim
1  cos 2 x  3  cos x 
75. is equal to:
x0 x tan 4 x
1 1
1)  2) 3) 1 4) 2
4 2
Ans : 4
Sol :
lt
1  cos 2x  3  cos x   lt
2sin2 x  3  cos x 
2
x 0 x tan 4x x 0 4x 2
 /3
dx 
76. Statement-I: The value of the integral
 /6
 1 tan x
is equal to
6
b b
Statement-II:  f  x dx   f  a  b  x  dx
a a
1) Statement -I is true; Statement-II is true; Statement-II is a correct explanation for Statement-I.

2) Statement -I is true; Statement-II is true; Statement-II is not a correct explanation for Statement-I.
3) Statement -I is true; Statement-II is false.
4) Statement -I is false; Statement-II is true.
Ans : 4
Sol :
  
3
dx 
dx 3 6  
 1  tan x 
2 12
6
b b
 f  x  dx   f a  b  x  dx
a a
x2 y 2
77. The equation of the circle passing through the foci of the ellipse   1, and having cen-
16 9
tre at  0,3 is:
1) x 2  y 2  6 y  7  0 2) x 2  y 2  6 y  7  0
3) x 2  y 2  6 y  5  0 4) x 2  y 2  6 y  5  0
Ans : 1
Sol :Foci of the given ellipse are  7,0  

2
Equation of the circle is x 2   y  3  7  9  x 2  y 2  6y  7  0

78. A multiple choice examination has 5 questions. Each question has three alternative answers
of which exactly one is correct. The probability that a student will get 4 or more correct
answers just by guessing is :
17 13 11 10
1) 2) 3) 4)
35 35 35 35
Ans : 3
Sol :
4 5
 1   2 5  1 
5 11
Probability = C4      C5    5
 3  3  3 3
79. The x-coordinate of the incentre of the triangle that has the coordinates of mid points of its
sides as  0,1 1,1 and 1, 0  is:
1) 2  2 2) 2  2 3) 1  2 4) 1  2
Ans : 2
Sol :
From given data
Vertices of triangle are A   0, 0 , B   2, 0 ,C   0,2
ax1  bx 2  cx 3 4
x-coordinate of I  =  2 2
abc 42 2
040
 2 2
42 2
10
 x 1 x 1 
80. The term independent of x in expansion of  2/3 1/3  1/ 2  is :
 x  x 1 x  x 
1) 4 2) 120 3) 210 4) 310
Ans : 3
Sol :
10


 x1/3  1  
 x 1  x 1 

  1 
  x1/3  1/2 
10


x  x 1 
   x 
 10 
np  
r  3  4
pq 1 1
  
3 2
6 4
10
C4 1  1  210

81. The area (in square units) bounded by the curves y  x , 2 y  x  3  0, x-axis, and lying in the
first quadrant is :
27
1) 9 2) 36 3) 18 4)
4
Ans : 1
Sol :
9 9
 x  3
 x dx     dx
0 y 3
 2
(9, 3)
9 9
 x 3/2    x  3 2  x

(0, 0)  0) (9, 0) 
(3,
 3 / 2  0  4 
3
= 18 – 9 = 9
82. Let Tn be the number of all possible triangles formed by joining vertices of an n-sided
regular polygon. If Tn 1  Tn  10, then the value of n is
1) 7 2) 5 3) 10 4) 8
Ans : 2
Sol :
n 1
C3  nC3  10

 n  1 n  n  1  n  n  1 n  2  10
6
 n  n  1  20  5  4  n  5
 1 z 
83. If z is a complex number of unit modulus and argument  , then arg   equals:
1 z 

1)  2)  3)  4)   
2
Ans : 3

Sol :
Given that |z| = 1
 z  e i
1  z   1  cos   i sin  
 Arg  1  z   Arg  1  cos   i sin  
 Arg  cis   
84. ABCD is a trapezium such that AB and CD are parallel and BC  CD . If ADB   , BC  p and
CD  q, then AB is equal to :
p 2
 q 2  sin  p 2  q 2 cos 
1) 2)
p cos   q sin  p cos   q sin 
p 2  q2 p 2
 q2  sin 
3) 2 4) 2
p cos   q 2 sin   p cos  q sin 
Ans : 1
Sol :
p q
Sin  , cos  
p2  q 2 p2  q 2
q
D C


p2  q 2
p

A B
AB p2  q 2

sin  sin     
 AB 
p 2

 q 2 sin 
q sin   p cos 

1  3
 3 
85. If P   1 3 is the adjoint of a 3  3 matrix A and A  4 ,then  is equal t0:
 2 4 4 
1) 4 2) 11 3) 5 4) 0
Ans : 2
Sol :
|P|| A|2   2  6  16    11
x
86. The intercepts on x-axis made by tangents to the cirve, y   t dt , x  R , which are parallel to
0
the line y  2 x, are equal to :

1) 1 2) 2 3) 3 4) 4
Ans : 1
Sol :
dy
|x| 2  x  2
dx
2
If x  2  y  |t|dt  2  equation of tangent is 2x  y  2  0

1
2
If x  2  y  |t|dt  2  equation of tangent is 2x  y  2  0

1
87. Given: A circle 2 x 2  2 y 2  5 and a parabola y 2  4 5 x .

Statement-I: an equation of a common tangent to these curves is y  x  5 .
5
Statement - II : If the line, y  mx   m  0  is their common tangent, then m staisfies
m
m4  3m 2  2  0 .
1) Statement - I is true; Statment -II is true; Statement - II is correct explanation for Staement - I
2) Statement - I is true; Statment - II is true; Statement - II is not a correct explanation for Statement- I
3) Statement - I is true; Statment - II is false.
4) Statment - I is false; Statment - II is true.
Ans : 2

Sol :
Equation of a tangent to the parabola y  4 5 x having slope ‘m’ is
5
y  mx   it also touches the circle
m
5 5

m2
 1  m2
2
 
 
 m2 1  m2  2  m2  1 m  1
dy
88. If y  sec  tan 1 x  , then at x  1 is equal to :
dx
1 1
1) 2) 3) 1 4) 2
2 2
Ans : 1
Sol :
dy 1
dx
 
 sec tan1 x tan tan1 x
1  x2
 
 dy  1
  
 dx  x 1 2
tan A cot A
89. The expression  can be written as :
1  cot A 1  tan A
1) sinA cosA + 1 2) secA cosecA+1
3) tan A + cot A 4) secA + cosecA
Ans : 2
Sol :
Tan2 A 1 1  tan3 A 1  tan2 A  tan A
  
tan A  1 tan A 1  tan A  tan A 1  tan A  tan A
 sec A cos ecA  1
90. All the students of a class performed poorly in Mathematics. The teacher decided to give
grace marks of 10 to each of the students. Which of the following statistical measures will
not change even after the grace marks were given ?
1) mean 2) median 3) mode 4) variance
Ans : 4
Sol :
Variance (x + a) = variance (x)
When ‘a’ is constant

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IMPORTANT INSTRUCTIONS: CODE :P

Use of pencil is strictly prohibited.

3. The test is of 3 hours duration

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2 Bl 2 3Bl 2 4 Bl 2 5Bl 2

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3) 0    M 1 L2T 1 A2  4) 0    M 1 L2T 1 A 

5. A projectile is given an initial velocity of i  2 j m / s, where i is along the ground and j is

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0.9A 0  A 0e 5k ...... (1)

 A 0  A 0 e 15k ......... (2)

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Sri Chaitanya IIT Academy., India

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here  decreases exponentially and reaches 0 at infinite time

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When S1 is closed, capacitor change becomes

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1) points 2) straight lines 3) semi - circles 4) concentric circles

In 3D, it gives circle on the screen.

 Fringes will be concentric circles.

1) 3 V/m 2) 6 V/m 3) 9 V/m 4) 12 V/m

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24. The I - V characteristic of an LED is :

 T 8rdr  4r 2dr L 

Given answer is equilibrium condition

Ans : 3 No other answer is nearer

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BH  3.6 105  0.36 104 wb/m2

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33. A solution of (–)–1–chloro–1–phenylethane in toluene racemises slowly in the presence of

Recimization due to formation of carbocation.

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37. Arrange the following compounds in order of decreasing acidity:

(I) (II) (III) (IV)

Cl CH3 NO2 OCH3

Electron donating groups decrease acidity

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42. The order of stability of the following carbocations:

43. Consider the following reaction:

44. Which of the following is the wrong statement?

48. Synthesis of each molecule of glucose in photosynthesis involves:

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Sri Chaitanya IIT Academy., India

Hoffmann – Bramamide rearrangement.

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67. The sum of first 20 terms of the sequence 0.7,0.77,0.777,..., is :

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69. The number of values of k, for which the system of equations:

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70. If the equation x 2  2 x  3  0 and ax 2  bx  c  0, a, b, c  R, have a common root, then

It also passes through 1,  2    4

1  y  x   zy yx zy

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 f  x  dx    x  , then  x f  x dx is equal to:

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1) Statement -I is true; Statement-II is true; Statement-II is a correct explanation for Statement-I.

Sol :Foci of the given ellipse are  7,0  