Vidyamandir Classes

VMC/Chemical Equilibrium 1 HWT-Solutions/Chemistry

Solutions to Home Work Test/Chemistry
1.(A)
2 (s) (g)
(g)
0
0.5
2p
0.5 p
CO C 2CO

, )
2
2
2 2
CO
p
CO
2p P 0.6
K
P 0.5 p 0.2
= = =

= 1.8
Now 0.5 P 2P 0.8 + = P = 0.3
2.(A)
5(g) 3(g) 2(g)
PCl PCl Cl +

t = 0 4 0 0
t = t
eq
2 2 2
3 2
c
5
2 2
[PCl ] [Cl ]
4 4
K
2
[PCl ]
4

= = = 0.5
6.(A)
3 2
2
p NH H S
K P P 50 50 2500 atm = = =
7.(C)
(g) (g) (g) (g)
3 4
eq
3A 4B 2C 3D
t 0
t t 3 3x 4 4x 2x 3x
+ +
=
=

Now 2x = 1

1
x
2
=
, ) , )
c
3
1
2x . 3x 1
2
K
3
3 3x 4 4x 2
2
2

= = =


9.(D) A B C D + +

t 0 a a 0 0 =
eq
t t a x a x x x =
, ) x 3 a x =
4x = 3a
3
x a
4
= .
c
3 3
a . a
4 4
K 9
a a
.
4 4
= =
Chemical Equilibrium HWT - 1
Vidyamandir Classes
VMC/Chemical Equilibrium 2 HWT-Solutions/Chemistry
1.(D)
2 2 3
1
SO O SO
2
+

t = 0 5 5 0
t = t
eq
2
3
5
2
3
total moles at equilibrium =
7 17
2 3
2 2
+ + =
2
O
2 7
P 0.4 atm.
17 2
| |
=
|
\ .
2.(A)
3 2
eq
5
[PCl ] [Cl ]
Q 1 K
[PCl ]
= = >
Hence reaction will go backward.
5.(C) Eqn III = Eqn I + Eqn II
Hence K
3
= K
1
K
2
.
6.(A)
1 2
2
y P Q
P P
x Z
P P P
K K
P P
| |
|
= =
|
\ .
eq
x 2y
t 0 1 0
at t t 1 x 2x
(
(
(
=
(
( =
(

Let total pressure P

1

1
2
2
1
P
1
2x
P
1 x
K
1 x
P
1 x
| |
|
+
\ .
=
| |
|
+
\ .
Z P Q
1 0 0
1 x x x
(
+
(
(
(
(

Let total pressure P

2

2
2 2
P
2
x x
P P
1 x 1 x
K
1 x
P
1 x
| | | |
| |
+ +
\ . \ .
=
| |
|
+
\ .
Given:
1 2
P P
K : K 1: 9 =
7.(A)
(g) (g) (g)
X Y Z +

a 0 0
a a a
2 2 2
X P
P P
.
P
3 3
P and K 1
P
3
3
= = =
P
1 and P 3
3
= = Hence P
X
= 1.
8.(B)
5(g) 3(g) 2(g)
PCl PCl Cl +

t = 0 5 0 0
t = t
eq
3 2 2
3 2
c
5
[PCl ] [Cl ] 4 4
K 2.66
[PCl ] 6

= = =
10.(D)
5 3 2
PCl PCl Cl +

t = 0 3 3 2
t = t
eq
1.5 4.5 3.5 Hence
3
PCl
n 4.5 =
Chemical Equilibrium HWT - 2
Vidyamandir Classes
VMC/Chemical Equilibrium 3 HWT-Solutions/Chemistry
2.(C)
3 2
c
5
0.4 0.4
[PCl ] [Cl ]
4 4
K
1.2
[PCl ]
4

= =
=
2
0.4 0.4
4 1.2 12
=

=
4
0.033
10 12
=

3.(B)
2 4(s) 3(g) 2(g)
2P P
3 3
NH COONH 2NH CO +

3
5
P
4P
K 2.9 10
27

= =
3 5 6
27
P 2.9 10 195 10
4

= =
Hence P = 0.0582
7.(B)
2(g) 2(g) 3(g)
1
SO O SO
2
+

t = 0 4 4 0
t = t
eq
2 3 2
8.(B)
6 12 6
C H O 6HCHO

1 0
1 x 6x
, )
, )
6
c
22
6x 1
K
1 x
6 10
= =

1/ 6
22
1
6x
6 10
| |
= |
|

\ .
Calculate 6x.
1.(B) Use , )
ng
p c
K K RT
A
=
6.(D) Final K
eq
= K
1
K
2
10.(C)
2 2 3(g)
(g) (g)
N 3H 2NH +

at t = 0 2 4 0
at t = t
eq
2 x 4 3x 2x
34
2x
17
= (Given)
x = 1
Chemical Equilibrium HWT - 3
Chemical Equilibrium HWT - 4
Vidyamandir Classes
VMC/Chemical Equilibrium 4 HWT-Solutions/Chemistry
2.(B)
, )
P
P g
2
K
K Since n 2
RT
= A = .
3.(D) Value of equilibrium constant depends upon temperature only. Changing volume will change o only.
6.(A)
4 (s) 3(g) 2 (g)
NH HS NH H S +

t = 0 0.5 0
t = t
eq
0.5 + P P
0.5 + 2P = 0.84
2P = 0.34
P = 0.17
3 2
P NH H S
K P P 0.67 0.17 0.11 = = =
10.(B)
(g) (g) (g)
A 3B 4C +

t = 0 a a 0
t = t
eq
a x a 3x 4x
a
a x 4x x
5
= =
, )
4
4 4
C
3 3 3
4a / 5
[C] 4
K 8
[A] [B] 4 2
4a 2a
5 5
= = = =

| | | |

| |
\ . \ .
.
1.(B)
5(g) 3(g) 2(g)
PCl PCl Cl +

t = 0 2 0 0
t = t
eq
1.2 0.8 0.8
0.8 0.8
2 2
C
1.2
2
0.4 0.4
K 0.266
0.6

= = =
4.(A) If K
P
> K
C

g
n 0 A >
Hence, forward reaction is favored at low pressure.
5.(C) A B C D + +

at t = 0 a a 0 0
eq
2a 2a a a
t t
3 3 3 3
=
C
1
K 0.25
4
= =
6.(B) [Products] > [Reactants]
K must be greater than 1.
Chemical Equilibrium HWT - 5
Chemical Equilibrium HWT - 6
Vidyamandir Classes
VMC/Chemical Equilibrium 5 HWT-Solutions/Chemistry
9.(C)
2(g) 2(g) 3(g)
N 3H 2NH +

t = 0 1 3 0
eq
t t 1 x 3 3x 2x =
1 x 0.6 =
x = 0.4
Total moles = 4 2x 3.2 =
10.(A) Addition of inert gas at constant pressure drives the reaction to the side with higher number of gaseous moles.
8.(B)
4 (s) 4(aq.) (aq.)
NH Cl NH Cl H ve
+
+ A = +

Increasing temperature will shift the reaction to the right.

6.(D) Addition of Cl
2
at constant volume will take the reaction to the right.
10.(A) 2A B Pr oducts +
Rate = k [A]
2
[B]
2.(A) X Y Z +

t = 0 5 3
t = t
eq
3 1 2
eq
2
k
3
=
9.(D) A 2B 2C +

t = 0 2 3 2
t = t
eq
2.5 4 1
2
c
2
1
1 2
2 4
k 0.05
16 2.5
4 2.5
4 2
2 2
| |
|
\ .
= =
| | | |

| |
\ . \ .
Chemical Equilibrium HWT - 7
Chemical Equilibrium HWT - 8
Chemical Equilibrium HWT - 9