Vidyamandir Classes

VMC/ Oxygen Containing Organic Compounds - III 21 HWT-7/Chemistry

DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : CBX [1]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Identify D in the following reaction :
1. CO H O
2 2
3
CH 2. H O
4 3 H
CH CH CH MgBr A B C D
+
+

(A)
2
HOOC CH COOH (B)
2
OHC CH COOH
(C)
2
OHC CH CHO (D) HO CH CH COOH =
2.
2
3
Br / P (i) KCN
3
(ii) H O
CH COOH Y X
+
Here, X is :
(A) glycolic acid (B) hydroxy propionic acid o
(C) succinic acid (D) molonic acid
3. Which of the following is a better reducing agent for the following reduction?
2
RCOOH RCH OH
(A) SnCl
2
/HCl (B) NaBH
4
/ether (C) H
2
/Pd (D) LiAlH
4
/ether
4.
(A) (B) (C) (D)
5. Identify A and B in the following reaction :
B A
3 3 3 3 2
CH CH CH COOH CH CH OH
A B A B
(A) HI + red P LiAlH
4
(B) Ni / A LiAlH
4
(C) LiAlH
4
HI + red P (D)
4
Pd BaSO Zn + HCl
6. In the following reaction,
3 2
NH Br / P
2
alc.
RCH COOH X Y
The major amounts of X and Y are :
(A) RCHBrCONH
2
; RCH(NH
2
)COOH (B) RCHBrCOOH ; RCH(NH
2
)COOH
(C) RCH
2
COBr ; RCH
2
COONH
4
(D) RCHBrCOOH ; RCH
2
CONH
2
7. The property which distinguishes formic acid on from acetic acid is :
(A) Only ammonia salt of formic acid on heating gives amide
(B) When heated with alchohol/H
2
SO
4
only acetic acid forms ester
(C) Only acetic acid gives off CO
2
with NaHCO
3
(D) Only formic acid reduces Fehlings solution
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - III 22 HWT-7/Chemistry
8.
The compound B is :
(A) (B) (C) (D)
9. The gas evolved on heating alkali formate with soda-lime is :
(A) CO (B) CO
2
(C) hydrogen (D) water vapour
10. End product of the given reaction is :
2
Cl Alc. KOH
3 2
red P
CH CH COOH X
(A)
3
CH CHCOOH
|
OH
(B)
2 2
CH CH COOH
|
OH
(C) CH
2
= CHCOOH (D)
2
CH CHCOOH
| |
OH OH
11. 2, 4-dichlorophenoxy acetic acid is used as :
(A) fungicide (B) insecticide (C) herbicide (D) moth repellan
12. In a set of the given reactions, acetic acid yielded a product C.
3 5
CH COOH PCl A +
6 6 2 5
3
C H C H MgBr
anh. AlCl ether
A B C . Product C would be :
(A) CH
3
CH(OH)C
6
H
5
(B)
2 5
3 6 5
C H
|
CH C(OH)C H
(C) CH
3
CH(OH)C
2
H
5
(D) CH
3
COC
6
H
5
13. When
2
CH CH COOH = is reduced with LiAlH
4
, the compound obtained will be :
(A)
3 2
CH CH COOH (B)
2 2
CH CH CH OH =
(C)
3 2 2
CH CH CH OH (D) CH
3
CH
2
CHO
14. Which of the following gives oxalic acid?
(A) Heating of acetic acid (B) Action of nitric acid on glucose
(C) Acidic hydrolysis of cyanogen (D) Strong heating of sodium formate
15. Identify the compound Z in the given reaction sequence
3 2 2
NH Br KOH HNO
3 2
CH CH COOH X Y Z :
+
A

(A) CH
3
OH (B) CH
3
CH
2
NH
2
(C) CH
3
CH
2
OH (D) CH
3
CH
2
CH
2
OH
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - III 23 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : CBX [2]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The reagent which does not give acid chloride on treating with a carboxylic acid is :
(A) PCl
5
(B) Cl
2
(C) SOCl
2
(D) PCl
3
2. When CH
3
COOH reacts with
3
CH MgX
(A) CH
3
COX is formed(B) Methane is formed (C) Acetone is formed (D) No reaction
3. Which of these does not contain COOH group?
(A) Aspirin (B) Benzoic acid (C) Picric acid (D) Salicylic acid
4. 4-methyl benzene sulphonic acid reacts with sodium acetate to give.
(A) (B) (C) (D)
5. Which of the acids cannot be prepared by Grignard reagent?
(A) Acetic acid (B) Succinic acid (C) Formic acid (D) All of these
6. Cinnamic acid is formed when
6 5
C H CHO condenses with (CH
3
CO)
2
O in presence of :
(A) concentrated H
2
SO
4
(B) sodium acetate
(C) sodium metal (D) anhydrous ZnCl
2
7. Sodium ethoxide has reacted with ethanoyl chloride. The compound that is produced in the above reaction is :
(A) diethyl ether (B) 2-butanone (C) ethyl chloride (D) ethyl ethanoate
8. Acetic anhydride is best prepared in the laboratory by heating sodium acetate with.
(A) ethyl chloride (B) acetyl choride (C) conc. H
2
SO
4
(D) zinc dust
9. In the reaction
the structure of the product T is :
(A) (B)
(C) (D)
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - III 24 HWT-7/Chemistry
10. Which one of the following will undergo meta-sustitution on monochlorination?
(A) Ethoxybenzene (B) Chlorobenzene (C) Ethyl benzoate (D) Phenol
11. Identify Z in the sequence
2 5 2
P O H O/ H
3 4
CH COONH X Y Z
+
A
A
.
(A) CH
3
CH
2
CONH
2
(B) CH
3
CN (C) CH
3
COOH (D) (CH
3
CO)
2
O
12. The most suitable reagent A, for the reaction :
is(are) :
(A) O
3
(B) H
2
O
2
(C) NaOH-H
2
O
2
(D) m-chloroperbenzoic acid
13. Potassium cyanate is heated with ammonium sulphate. The product formed is :
(A) urea (B) ammonia (C) potassium sulphate (D) ammonium cyanide
14. Which one of the following pairs gives effervescence with aq. NaHCO
3
?
I. CH
3
COCl II. CH
3
COCH
3
III. CH
3
COOCH
3
IV. CH
3
COOCOCH
3
The correct choice is :
(A) I and II (B) I and IV (C) II and III (D) I and III
15. When acetamide is hydrolysed by boiling with acid, the product obtained is :
(A) Acetic acid (B) Ethyl amine (C) Ethanol (D) Acetamide
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - III 25 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : CBX [3]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. An ester (A) with molecular formula C
9
H
10
O
2
was treated with excess of CH
3
MgBr and the complex so formed was treated with
H
2
SO
4
to give an olefin (B). Ozonolysis of (B) gave a ketone with molecular formula C
8
H
8
O which shows positive iodoform test.
The structure of (A) is :
(A) C
6
H
5
COOC
2
H
5
(B) C
6
H
5
COOC
6
H
5
(C) C
6
H
5
COOCH
3
(D)
3 6 4 3
p H CO C H COCH
2. Which of the following diacid readily gives anhydride on heating?
(A) Fumaric acid (B) Maleic acid (C) Malonic acid (D) Terephthalic acid
3.
2
H O
2 2
(CH CO) O RMgX ? +
(A) ROOC(CH
2
)COOR (B) RCOCH
2
CH
2
COOH (C) RCOOR (D) RCOOH
4. Trans esterification is the process of :
(A) conversion of an aliphatic acid to ester (B) conversion of an aliphatic acid to ester
(C) conversion of one ester to another ester
(D) conversion of an ester into its components namely acid and alcohol
5. Rate of reaction:
Is fastest when Z is _________ & slowest when Z is _______.
(A) Cl, OC
2
H
5
(B) NH
2
, Cl (C) Cl, NH
2
(D)
3
Cl, O COCH
6.
3 2 5
2 5
2 4
2
CH C OC H
||
O C H OH
3
H SO /
H ,H O
CH MgX A B
+

A
. The product B is :
(A)
3 3
O
||
CH C CH
(B)
3 3 2 5
(CH ) C O C H (C) C
2
H
5
OC
2
H
5
(D)
3 2 5
CH C OC H
||
O

7. An organic compound is boiled with alcoholic potash. The product is cooled and acidified with HCl. A white solid separates out.
The starting compound may be :
(A) ethyl benzoate (B) ethyl formate (C) ethyl acetate (D) methyl acetate
8. A nitrogen containing organic compound gave an oily liquid on heating with bromine and potassium hydroxide solution.
On shaking the product with acetic anhydride, an antipyretic drug was obtained. The reactions indicates that the starting compound
is:
(A) aniline (B) benzamide (C) acetamide (D) nitrobenzene
9.
H
3 3
CH COOCH excess PhMgBr product X
+
A
+
The product X is :
(A) 1,1-diphenylethanol (B) 1, 1-diphenylethene (C) methyl phenylethanol (D) methyl phenylketone
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - III 26 HWT-7/Chemistry
10. Ethyl benzene reacts with PCl
5
to give :
(A) C
2
H
5
Cl + C
6
H
5
COCl + POCl
3
+ HCl (B) C
2
H
5
Cl + C
6
H
5
COCl + POCl
3
(C) CH
3
COCl + C
6
H
5
COCl + POCl
3
(D) C
2
H
5
Cl + C
6
H
5
COOH + POCl
3
11. Ethyl ester
3
CH MgBr
(excess)
P , the product P will be :
(A) (B) (C) (D)
12. The product of acid hydrolysis of P and Q can be distinguish by :
(A) Lucas reagent (B) 2, 4-DNP (C) Fehlings solution (D) aldehyde
13. When an acyl chloride is heated with Na salt of a carboxylic acid, the product is an :
(A) ester (B) anhydride (C) alkene (D) aldehyde
14. Acetamide and ethyl amine are distinguished by reacting with :
(A) Br
2
water (B) acidicKMnO
4
(C) aq. NaOH and heat (D) aq. HCl and heat
15. Which one of the following methods is uses to prepare Me
3
COEt with a good yield?
(A) Mixing EtONa with Me
3
CCl
(B) Mixing Me
3
CONa with EtCl
(C) Heating a mixture of (1 : 1) EtOH and Me
3
COH in the presence of conc. H
2
SO
4
(D) Treatment of Me
3
COH with EtMgI