TEST 1 FEB 2011 CHEMISTRY FORM 5 (1 HOUR) NAME: ................................................ CLASS:.........................

SECTION A : Each question is followed by four option A, B, C and D. Choose the best option for each question. BAHAGIAN A : Setiap soalan diikuti dengan empat pilihan awapan A, B, C and D. !ilih awapan yang terbaik bagi setiap soalan.
". #he following are units of the rate of reaction e$cept A g s%" B g min%" C mol s%" D mol dm%" &. #he graph below shows the 'olume of gas produced plotted against time. Volume of gas (cm3) 60 50 40 30 20 10 1 2 Time (minute) 3

Based on the graph, find the a'erage rate of reaction for the first two minutes. A "(.( cm) min%" B &(.( cm) min%" C )(.( cm) min%" D *(.( cm) min%" ). +hich of the following cannot be used to determine the rate of reaction, .olume of gas released per unit time -Change of colour intensity per unit time --- /ass of precipitate produced per unit time -. -ncrease in the mass of reactant per unit time A --- only B -. only C - and -- only D --- and -. only

*. #he graph below shows the 'olume of carbon dio$ide gas liberated plotted against time for the reaction between marble and !c "" hydrochloric acid. Volume of carbon dioxide gas (cm3)

Energy

% "# mol$1 eactants ! "# mol$1 &roducts

6 Time (s)

Based on the abo'e energy profile diagram, the amount of acti'ation energy is.. A 78 9 :; k< mol%" B : k< mol%" C 7: 9 8; k< mol%" $ 8 k< mol%" =. 0 g magnesium carbonate is placed in a conical flask on an electronic balance and &0 cm) dilute hydrochloric acid is added. #he change in mass is recoded at )( s inter'als. #he results of the e$periment are shown in the diagram below. 'las" ( contents
40 30 20 10 0 10 20 30 40

#he 'olume of carbon dio$ide remains constant after * minutes because A the mass of catalyst decreases B all the marble has been used up C all the hydrochloric has been used up D the rate of reaction remained constant 0. +hich of the following # "t describe the properties of catalyst, A catalyst increases the rate of collision -A catalyst increases a quantity of product --- A positi'e catalyst is used to accelerate reactions -. 1nly a small amount of catalyst is needed to cataly2e a reactions A - and -- only B - and --- only C -- and -. only D --- and -. only 3. +hen the temperature decreases, the number of effecti'e collisions also decreases because A the acti'ation energy increases B the a'erage kinetic energy decreases C the number of atoms increases when the bonds are broken D the particles collide more often increases the acti'ation energy 4. 5inc powder reacts faster with hydrochloric acid than a 2inc strip because A there is a layer of 2inc o$ide on the 2inc strip B the 2inc powder has a larger total surface area C the particles of 2inc powder ha'e more kinetic energy D the particles in the 2inc strip packed more closely together 6. #he diagram shows an energy profile diagram.

Time (s) At what time was the rate of reaction the highest, A "( min B &( min C )( min $ *( min "(. -n an e$periment, 2inc metal is mi$ed with 0( cm) of acid. +hich of the following mi$ture will yield gas with the lowest initial rate of reaction, A 3 g of granulated 2inc with (.* mol dm%) ethanoic acid. B 3 g 2inc powder with (.* mol dm%) hydrochloric acid. C "& g granulated 2inc with (.& mol dm%) sulphuric acid. $ "& g of 2inc powder with (.& mol dm%) hydrochlporic acid. "". Cur'e > in the following graph shows the decomposition of )( cm) of (.0( mol dm%) of hydrogen pero$ide by using (.& g of

manganese7-.; o$ide as catalyst at a temperature of )( oC. Volume of oxygen (cm3)

Energy

4+0 "#

350 "# )

)
&(*

Time (min) +hich of the following e$periments will produce cur'e S, Volume of H2O2 / cm3 )( "0 )( *( Concentration of H2O2 / mol dm-3 (.3( (.3( (.*( (.*(

"0. #he diagram shows an energy le'el for the reaction ! A B S. +hat is the acti'ation energy for this reaction, A ")( k< mol%" B )0( k< mol%" C *6( k< mol%" $ 6)( k< mol%"

A B C $

N2 (g) + 3H2 (g) <=> 2NH3 (g)

"3. #he equation abo'e represents the Caber process. #he rate of reaction increases if pressure increases because A the kinetic energy of nitrogen gas molecules and hydrogen gas molecules increases. B the acti'ation energy is lowered under high pressure. C the co'alent bonds in molecules ?& and C& are easily broken under high pressure. $ the concentration of nitrogen gas and hydrogen gas increases under high pressure. Energy

"&. +hich of the following statements about the characteristic of a catalyst are t%& , I >eacts specifically for a certain reaction only. II ?ormally used in small quantity. III At the end of reaction catalyst may change their physical character. I' #he catalyst use only to speed the rate of reaction A -- and -. only B -, -- and -. only C -, -- and --- only $ -, --, --- and -. "). #he best definition for a catalyst is a chemical compound that can change the rate of chemical reaction and A is used widely in industrial fields. B does not change chemically at the end of a reaction. C does not take part directly in a reaction. $ is a comple$ molecule that is produced by plants.

Ea Ea,
& ( *

Reducing the size of reactants will increase the rate of reaction

"*. +hich of the following statements gi'es the # "t e$planation for the statement gi'en abo'e, A @inetic energy of molecules decreases. B Bonds are easier to break. C Acti'ation energy is lowered. $ Chances to ha'e effecti'e collisions are increased.

"4. +hich of the following will change Ea to EaD , A ?egati'e catalyst B !ositi'e catalyst C !ressure $ !romoter

"6. Eood is stored in a refrigerator last longer than food stored in a kitchen cabinet becauseF. A the food particles ha'e less kinetic energy B the dehydration of food decreases the temperature of food C the concentration of food decreases the surface areas of food $ the lower temperature decreases the rate of the reaction of bacteria on food. "=. +hich of the following statements is not true about the collision theory, A All the collisions of the particles will produce a reaction. B #he reaction will only occur when the particles possess energy equal or more than Ea . C A greater surface area will produce more effecti'e collisions among the particles. $ #he rate of collision increases with a temperature rise. &(. & g magnesium ribbon is dissol'ed in an e$cess of (." mol dm%) of hydrochloric acid to produce magnesium chloride and hydrogen. +hich of the following factors will produce a greater 'olume of hydrogen gas, A Gse ) g magnesium ribbon. B Gse concentrated hydrochloric acid C +arm the solution of the mi$ture. $ Gse & g of magnesium powder.

An"( % Fo% S ct)on A Questio Answer n 1 2 3 4

Question 11 12 13 14

Answer

5 6 7

15 16 17 1

! 1"

1! 2"

S ct)on B #nstruction$ Answer all t%e &uestions in s'ace 'ro(ided) ". An e$periment was conducted to study the effect of temperature on the rate of reaction between 0( cm) of sodium thiosulphate solution (.& mol dm%) and 0 cm) of sulphuric acid ".( mol dm%) to form a yellow precipitate. Diagram " shows the set%up of apparatus for the e$periment.
#he e$periment was repeated fi'e times using different temperatures. #able " shows the temperature and time taken for mark H:D to disappear from 'iew.

0( cm) of sodium thiosulphate solution (.& mol dm%) A 0 cm) of sulphuric acid " mol dm%)

E$periment " & ) * 0

#emperatureIoC &6.( *(.( 0(.( 3(.( 4(.(

#imeIs 00 )) &) "4 ")

7a; Draw a graph of temperature against time for this e$periment. J* marksK

7b; Erom the graph, calculate the rate of reaction in 7i; E$periment &

J& marksK 7ii; E$periment *

J& marksK 7c; Compare the rate of reaction between E$periment & and E$periment *. E$plain your answer by using the Collision #heory. FFFF. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF. FFFFFFFF FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF. FFFFFFFFFFFFFFFFFFFF FFFFFFFFFFFFFFFFFFFFFFFFF. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF FFFFFFFFFFFFF.. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF J0 marksK 7d; +rite the chemical equation for the reaction. FFFFFFF. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF FFF J" markK 7e; ?ame the yellow precipitate formed. FFFFF.. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF FFFFF J" markK 7f; State one other factor that can affect the rate of reaction for this e$periment. FFFFF.. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF FFFF.. J" markK

2- T.o ex/eriments are carried out to study t0e effect of t0e si1e of calcium carbonate on t0e rate of reactionEx/eriment 23 1 g of calcium carbonate c0i/s react .it0 20-0 cm3 of 0-2 mol dm$3 0ydroc0loric acid Ex/eriment 223 1 g of calcium carbonate /o.der react .it0 20-0 cm3 of 0-2 mol dm$3 0ydroc0loric acid T0e rate of reaction is determined by measuring t0e 4olume of of carbon dioxide gas gi4en off against time using t0e do.n.ard dis/lacement of .ater met0od- T0e 4olume of gas released is recorded in Table 2-1 and Table 2-2 belo.Ex/eriment 1 Time5s 6urette reading 5 cm3 Volume of gas5 cm3 Ex/eriment 22 Time5s 6urette reading 5 cm3 Volume of gas5 cm3 0 50-00 0-00 60 120 Table 2-1 0 50-00 0-00 60 22-00 120 13-50 Table 2-2 1+0 7-00 240 +-00 300 +-00 360 +-00 1+0 240 7-50 300 +-00 360 +-00

Diagram below shows the burette reading for E$periment - at 3(, "&( and "6( seconds. 7a; >ecord the burette reading and the 'olume of gas released at 3(, "&( and "6( seconds in #able &.". J) marksK 7b; >ecord the 'olume of gas released in both e$periments in #able &." and #able &.&. J3 marksK 7c; 7i; State the 'ariables in'ol'ed in this e$periment. /anipulated 'ariable FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF FFFFFFFF. >esponding 'ariable FFFFFFFFFFFFFFFFFFFF. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF Constant 'ariable FFF. FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF F.. J) marksK 7ii; State the hypothesis for these e$periments. FFF..F....FFFFFFFFFFFFFFFF...FFFFFFFFFFFFFFFFFFFF...F.. FFFFFFFF ...FFFFFFFFFFFFFFFFFFFFFFFFFFFFF.FFF. FFFFFFFFFFFFFFFFFFF J" markK 7d; !redict the 'olume of gas released at *&( seconds in E$periment --. FFFFF..FFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFFF...F J" markK L11D MGC@ A?D #>8 81G> BES#

SECTION A SECTION B TOTAL MARKS

20 30 50