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Copper case study: Australian resources, technology and future scenarios R. Memary, D. Giurco, G. Mudd, S. Mohr, Z. Wheng 2012
Prepared by:
Institute for Sustainable Futures, University of Technology, Sydney Department of Civil Engineering, Monash University For CSIRO Minerals Down Under National Research Flagship
ABOUTTHEAUTHORS
InstituteforSustainableFutures:UniversityofTechnology,Sydney
TheInstituteforSustainableFutures(ISF)wasestablishedbytheUniversityofTechnology,Sydneyin 1996toworkwithindustry,governmentandthecommunitytodevelopsustainablefuturesthrough researchandconsultancy.Ourmissionistocreatechangetowardsustainablefuturesthatprotectand enhancetheenvironment,humanwellbeingandsocialequity.Weseektoadoptaninterdisciplinary approachtoourworkandengageourpartnerorganisationsinacollaborativeprocessthatemphasises strategicdecisionmaking. Forfurtherinformationvisitwww.isf.uts.edu.au Researchteam: Mr.RezaMemary,ResearchAssistant; Dr.SteveMohr,SeniorResearchConsultant; Dr.DamienGiurco,ResearchDirector.
DepartmentofCivilEngineering:MonashUniversity
TheDepartmentofCivilEngineering,withintheFacultyofEngineeringatMonashUniversityaimsto providehighqualityCivilEngineeringeducation,researchandprofessionalservicesgloballyforthe mutualbenefitofthestudents,thestaff,theUniversity,industry,theprofessionandthewider community Forfurtherinformationvisitwww.eng.monash.edu.au/civil/ Researchteam: Dr.GavinM.Mudd,SeniorLecturer; Mr.ZehanWheng,ResearchAssistant.
CITATION
Citethisreportas: Memary,R.,Giurco,D.,Mudd,G.,Mohr,S.,Wheng,Z.(2012).Coppercasestudy:Australianresources, technologyandfuturescenarios.PreparedforCSIROMineralsDownUnderFlagship,bytheInstitutefor SustainableFutures(UniversityofTechnology,Sydney)andtheDepartmentofCivilEngineering(Monash University),May2012.
ACKNOWLEDGEMENT
ThisresearchhasbeenundertakenaspartoftheMineralsFuturesResearchCluster,acollaborative programbetweentheAustralianCSIRO(CommonwealthScientificIndustrialResearchOrganisation);The UniversityofQueensland;TheUniversityofTechnology,Sydney;CurtinUniversity;CQUniversity;and TheAustralianNationalUniversity.Theauthorsgratefullyacknowledgethecontributioneachpartner andtheCSIROFlagshipCollaborationFund.TheMineralsFuturesClusterisapartoftheMineralsDown UnderNationalResearchFlagship,http://www.csiro.au/OrganisationStructure/Flagships/Minerals DownUnderFlagship/mineralfuturescollaborationcluster.aspx.
CONTENTS
1. BACKGROUND
1.1. 1.2. 1.3. 1.4. 1.5. 1.6. 1.7. 2.1. 2.2. 2.3. 2.4. 2.5. 3.1. 3.2. 3.3. Aim Introduction Globalcopperflows CurrentReserves Coppergrade Copperprice Copperdemand Production Producingcoppermines Copperresources,reservesandtheiroregeologyinAustralia Exportsofcopper Casestudymines Quantifyingcopperresources Briefreviewofcopperdeposittypes Globalcopperresources
5
5 5 5 6 7 7 8
2. COPPERINAUSTRALIA
9
9 11 13 15 22
3. GLOBALECONOMICCOPPERRESOURCES
17
17 17 18
4. ECONOMIC&ENVIRONMENTALISSUESWITHCOPPERMININGINAUSTRALIA
4.1. Economicfactorsaffectingcompetitiveness 4.2. EnvironmentanalysisofcopperminingusingLCA 4.2.1. Analysedtechnologies 4.2.2. LCAResults 4.3. Summaryofeconomicandenvironmentalchallenges
22
22 25 25 27 32
5. TECHNOLOGYADVANCESINCOPPERMININGANDSMELTING
5.1. 5.2. 5.3. 5.4. 5.5. 5.6. 5.7. HydrometallurgyandPyrometallurgy Bioleaching InSituLeaching(ISL) Deepseamining Recycling ProductServiceSystem(PSS) Energyoptions
33
33 33 34 34 34 36 37
6. EXPLORINGFUTURESCENARIOSFORCOPPER
6.1. Effectsoforegradechange,technologyimprovementsandbusinessmodels 6.2. Globalcontext:WorldEconomicForumscenarios 6.2.1. Greentradealliance 6.2.2. Rebasedglobalism 6.2.3. Resourcesecurity
39
39 41 41 41 42
7. CONCLUSION 8. REFERENCES
43 44
FIGURES
Figure1.1:Worldcopperproductionhistoryfrom1900 Figure1.2:TheoregradedeclinesinUSA,CanadaandAustralia Figure1.3:Thepriceofcopperovertime Figure2.1:AustralianCopperproductionsbetween18401950bystate Figure2.2:AustralianCopperproductionsbetween19502010bystate Figure2.3:Modelledcopperproductionwithpeakprediction Figure2.4:Australiascoppermines Figure2.5:Australiasexportsofcopper Figure2.6:ThevalueofAustraliascopperexports Figure3.1:HistoricaltrendsineconomicCuresourcesforAustralia,Canada,ChileandtheUSA Figure3.2:HistoricaltrendsinCuoregradesforAustralia,CanadaandtheUSA Figure4.1:Production(a)andoregrade(b)throughtime Figure4.2:ContributiontoGDPgrowthbysector Figure4.3:Reverberatoryfurnaceprocessflow Figure4.4:Flashsmeltingprocessflow Figure4.5:Globalwarmingpotentialthroughtime Figure4.6:ContributionofeachminingoperationtocarbondioxideproductionInMtIsa Figure4.7:Calculatedacidificationpotentialthroughtime Figure4.8:Calculatedphotochemicalozonecreationpotential Figure5.1:Sydneyinusecopperstocksin2000 Figure5.2:LocationsofcopperminesonthesolarradiationmapofAustralia Figure6.1:Globalwarmingpotentialofeachscenariotill2024
TABLES
Table1.1:Worldproductionofcopperin2010 Table1.2:Thereservesofcopper Table1.3:Thedemandforcopper(kilotonnes)inrecentyears Table2.1:CopperproducingminesinAustraliain2010 Table2.2:Top10coppermines,Top10copperdepositsinAustraliabycontainedcopperin2010 Table3.1:Compilationofglobalcopperresourcesbycountry(sortedbyMtCu) Table3.2:Top20copperresourcesbydeposit/project(sortedbyMtCu) Table5.1:comparingnewtechnologiesforcopper Table5.2:Examplesofenergyefficiencyopportunitiesinmining Table6.1:ModellingfuturecoppertechnologyoptionsforAustralia
Coppercasestudy:Australianresources,technologyandfuturescenarios
1. BACKGROUND
ThiscoppercasestudyispartoftheCommodityFuturescomponentoftheMineralFutures CollaborationCluster.TheCommodityFuturesresearchfocusesonthemacroscalechallenges, thedynamics,anddriversofchangefacingtheAustralianmineralsindustryandoverallproject aimsareto: Explore plausible and preferable future scenarios for the Australian minerals industry thatmaximisenationalbenefitinthecoming30to50years Identify strategies for improved resource governance for sustainability across scales, fromregionaltonationalandinternational Establish a detailed understanding of the dynamics of peak minerals in Australia, with regional,nationalandinternationalimplications Developstrategiestomaximisevaluefrommineralwealthovergenerations,includingan analysisofAustraliaslongtermcompetitivenessforspecifiedmineralspostpeak.
1.1. Aim
Theaimofthisreportistoestablishacomprehensivedatacompendiumoncopperandto explorethelinkbetweenresources,technologyandchangingenvironmentalimpactsovertime asabasisforinformingfutureresearchprioritiesintechnologyandresourcegovernance.
1.2.
Introduction
Copperscharacteristicssuchasductility,malleability,highelectricalandthermalconductivityin additiontohighcorrosionresistancehavemadeitoneofthebasemetalswithhighapplications forthousandsofyears.Ithasbeenusedinapplicationsrequiringelectricalandthermal conduction,buildingmaterials,andisthemainelementofmanyalloyssuchasbronzeand brass. Coppercontinuestoplayanessentialroleinoursocietywithelectricalapplications,power generation,transformers,motors,andcablesandelectricalequipmentlikewiringandcontacts, televisions,PCs,andmobilephones.Itisalsousedinconstructionsuchasplumbingandroofing, andtransport.Althoughithasbeenusedforthousandsofyearsitisonlythelasthundredyears thatproductionofcopperhassignificantlyincreased. Theimportanceofcopperinindustrialapplicationsisexpectedtoriseinthecomingyearsdue toitsapplicationsinenergyefficiencyprojectsandmotorsforelectricvehicles.
Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure1.1:Worldcopperproductionhistoryfrom1900,actualdatafromUSGSDS140,2010
World production is now approximately 16 Mt a year of copper (USGS DS140). As shown in Table1.1,Chileproducesalmostonethirdoftheworldscopper,andthenext5majorcountries (Peru, China, US, Australia, and Indonesia) produce another third of world production and the remainingproductionisspreadacrosstherestoftheworld.
Table1.1:Worldproductionofcopperin2010(USGSMCS). Country Chile Peru China US Australia Indonesia Zambia Russia Canada Poland Kazakhstan Mexico Other World Production(kt) 5,520 1,285 1,150 1,120 900 840 770 750 480 430 400 230 2,300 16,200
Coppercasestudy:Australianresources,technologyandfuturescenarios
24
20
Australia
16
12
Canada
0 1840
USA
1860 1880 1900 1920 1940 1960 1980 2000
Figure1.2:TheoregradedeclinesinUSA,CanadaandAustralia
Coppercasestudy:Australianresources,technologyandfuturescenarios
Price $/t
6,000 5,000 4,000 3,000 2,000 1,000 0 1900 1910 1920 1930 1940 1950 1960 1970 1980 1990 2000 2010
Figure1.3:Thepriceofcopperovertime(USGSDS1402010).
Industry Construction Construction Construction Construction Construction Infrastructure Infrastructure EquipmentManufacture EquipmentManufacture EquipmentManufacture EquipmentManufacture EquipmentManufacture EquipmentManufacture EquipmentManufacture Total(kilotonnes)
Use Plumbing Buildingplant Architecture Communication ElectricalPower Powerutility Telecom Industrial Automotive OtherTransportation ConsumerandGeneral Products Cooling Electronics Diverse All
2008 1,528 137 499 223 3,712 2,624 874 4,603 1,909 1,086
2009 1,336 133 327 193 5,273 2,541 725 2,742 1,590 967
2,001 1,814 1,643 1,330 856 768 2,252 2,359 23,947 22,098
Coppercasestudy:Australianresources,technologyandfuturescenarios
2. COPPER IN AUSTRALIA
2.1. Production
AustraliaisthefifthlargestproducerofcopperbehindChile,Peru,China,andUSAandhasbeen producingcopperforaround160years.ThecopperminesinSouthAustraliaduringthe1850s 70swereimportantgloballyatthetime.Australiashistoriccopperproductionisshownin Figures2.1andAustraliascopperproductionfromthe1950sonwardispresentedinFigure2.2 (notethechangeofscale).AsdepictedQueenslandandSouthAustraliaarethemainproducers ofcopperinAustralia,withNSWandWesternAustraliamakingsignificantcontributions. Australiasremainingeconomicresourceshavethepotentialtomaintainapositionamongthe world'sleadingmineralnations.Consequentlypropermanagementofcopperextractionand processinginAustraliashouldbeexaminedfurthertoseewhatisrequiredtoensurethe provisionoflongtermbenefitforfuturegenerations.
Figure2.1:AustralianCopperproductionsbetween18401950bystate(Mudd,2010)
Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure2.2:AustralianCopperproductionsbetween19502010bystate(Mudd,2010)
Figure2.3:Modelledcopperproductionwithpeakprediction(MuddandWard,2008).
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Coppercasestudy:Australianresources,technologyandfuturescenarios
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Table2.1:CopperproducingminesinAustraliain2010(Mudd,2010).
Mine / Project M C S R Mt Isa X X X Olympic Dam X X X X Prominent Hill X X Ernest Henry X X Nifty X X Northparkes X X Golden Grove X X Telfer X X Boddington X X Cadia Hill X X Mt Lyell X X #1 X X Osborne Mt Garnet Group X X Ridgeway X X Tritton X X Jaguar X X Sally Malay X X Rosebery X X Kambalda Field X X Cairn Hill X X #2 X X Cadia East Angas X X Peak X X Ore Type Cu Cu-U-Au-Ag Cu-Au-Ag Cu-Au Cu Cu-Au Pb-Zn-Ag-Cu-Au Au-Cu Au-Cu Au-Cu Cu-Au-Ag Cu-Au Pb-Zn-Ag-Cu-Au Au-Cu Cu Pb-Zn-Ag-Cu Ni-Cu-Co Pb-Zn-Ag-Cu-Au Ni-Cu Fe-Cu Au-Cu Pb-Zn-Ag-Cu-Au Au-Cu Totals t ore 6,092,414 7,046,000 9,537,461 9,838,428 2,250,610 5,248,000 1,597,026 22,944,000 26,619,062 17,512,000 2,120,000 1,026,043 956,767 4,312,000 683,110 363,567 630,716 724,791 1,060,823 124,444 79,000 392,144 121,158,407 %Cu 2.91 0.54 0.82 0.69 2.90 0.82 0.71 0.17 0.12 0.17 1.21 2.33 2.03 0.46 2.14 3.24 0.59 0.38 0.22 0.52 0.36 0.23 0.59 g/t Au g/t Ag 5.01 2.96 0.34 0.51 37.0 1.06 1.03 0.82 0.3 0.89 0.29 1.23 1.88 1.32 t Cu 157,696 131,800 112,171 74,595 61,061 39,000 34,291 33,213 26,309 26,026 23,777 22,676 17,773 17,351 14,274 9,660 3,626 2,087 1,923 324 240 145 810,017 kg Au 2,127.8 6,108.0 2,838.2 2,030.8 1,129.1 21,164.7 22,640.8 11,621.5 3800 839.7 106.0 4,330.2 kg Ag 17,634 19,152 t waste rock 563,680 53,353,057 16,782,266 6,527,600 %ore OC 0 0 100 100 0 0 0 74.53 100 100 0 0 6.64 0 0 0 0 0 100 0 0 0 66.69 %Cu OC 0 0 100 100 0 0 0 40.22 100 100 0 0 6.64 0 0 0 0 0 100 0 0 0 60.19 Company Xstrata BHP Billiton OZ Minerals Xstrata Aditya Birla Minerals Rio Tinto MMG Newcrest Newmont Newcrest Vedanta Resources Ivanhoe Australia Kagara Zinc Newcrest Straits Resources Jabiru Metals Panoramic Resources MMG Various IMX Resources Newcrest Terramin New Gold
2.37 0.6
24,721,000 5,627,000
3 22.9
3,025,000
63 1.72 125.0
18,336 981.2 78,709 3,098,600 51.1 94.9 79,864 7,699 235,045 113,698,203
28.2 1.6
Note:Mmine,Cconcentrator,Ssmelter,Rrefinery,OCopencut.
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Coppercasestudy:Australianresources,technologyandfuturescenarios
13
Coppercasestudy:Australianresources,technologyandfuturescenarios
Table2.2:Top10copperminesandTop10copperdepositsinAustraliabycontainedcopperin2010(Mudd,2010).
State SA NSW WA NSW WA NSW SA WA QLD NSW WA QLD QLD QLD NSW SA NSW SA QLD NSW
Mine/Deposit OlympicDam CadiaEast Boddington CadiaHill TelferMainDome Northparkes ProminentHill TelferWestDome MtIsa Ridgeway SpinifexRidge MtElliott MtIsa(OpenCut) Rocklands Marsden Carrapateena CopperHill Hillside MtDore Temora
Status Operating Operating Operating Operating Operating Operating Operating Operating Operating Operating Deposit Deposit Deposit Deposit Deposit Deposit Deposit Deposit Deposit Deposit
Mineral Type Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide Sulfide
Mtore
%Cu
g/tAu g/tAg 0.32 1.50 0.44 0.47 0.59 0.42 0.88 0.27 0.79 2.39 0.65 0.73 0.81 0.24 0.04 0.17 0.56 0.26 0.2 0.1 0.29
ktCu
kgAu
kgAg
Others U
9,075 0.87 2,347 0.28 1,531.2 0.10 408 0.12 369 0.10 365 0.55 285.35 0.89 247 0.06 200 2.01 155 0.38 843 0.085 570 0.44 283 1.11 245 0.21 224 0.32 203 1.31 173 0.31 170 0.7 145 0.52 142.2 0.32
6.0
5.9
78,952.5 2,904,000 6,571.6 1,032,680 1,103,090 1,577.2 899,148 489.6 171,360 369.0 324,720 2,000.2 99,720 2,540.2 225,922 682,919 148.2 160,550 4,028.0 589.0 113,150 125,550 712.6 2,490.0 135,000 3,130.0 505.6 9,420 716.4 37,160 2,659.3 113,680 1,218,000 536.3 44,980 1,190.0 34,000 751.1 14,500 861,300 461.4 40,825
Mo
Co U
Re,Mo Mo
14
Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure2.4Australiascoppermines(Australianminesatlas)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure2.5:Australiasexportsofcopper(ABARE,2010).
Figure2.6:ThevalueofAustraliascopperexports(ABARE,2010).
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Coppercasestudy:Australianresources,technologyandfuturescenarios
17
Coppercasestudy:Australianresources,technologyandfuturescenarios
includeironoxidecoppergold(orIOCG),magmatic(orbasaltrelated)NiCuores,aswellas oxidedeposits(i.e.weatheredores)andnative(elemental)Cuores.
80
320
60
240
40
160
20
80
0 1950
Figure 3.1: Historical trends in economic Curesources forAustralia, Canada, Chile and the USA (Mudd &Weng,2012)
AcomprehensivecompilationofCuresourcesundertakenforthisreportbydepositand countryissummarisedinTable3.1,withthe20largestCudepositsinTable3.2.
Table3.1:Compilationofglobalcopperresourcesbycountry(sortedbyMtCu)
Country Chile Peru USA Australia DRC Mexico Indonesia Zambia Canada Russia Mongolia Kazakhstan Poland PNG Philippines Argentina Pakistan Panama No. 47 39 48 150 21 29 5 19 78 12 6 7 4 12 13 6 1 1 Ore/Mt 115,102.5 27,851.9 32,785.6 20,160.5 2,288.9 16,442.6 7,458.9 4,524.5 13,093.7 4,128.3 4,485.0 6,682.0 1,539.0 5,333.8 5,363.3 6,451.5 5,867.8 6,465.0 %Cu 0.54 0.48 0.41 0.63 2.34 0.32 0.67 1.03 0.33 0.95 0.87 0.47 2.00 0.49 0.47 0.39 0.41 0.30 MtCu 627.23 134.47 134.20 126.71 53.64 53.17 50.07 46.74 42.62 39.13 39.09 31.22 30.77 26.08 25.10 25.00 24.06 19.36 Country SouthAfrica India Brazil Iran Fiji Botswana Sweden Finland Laos Zimbabwe Portugal Namibia Spain SaudiArabia Eritrea Greece Thailand Various Total No. 39 14 8 1 1 9 18 31 4 4 1 9 3 3 4 2 2 23 674 Ore/Mt 14,610.3 1,394.4 2,331.3 1,200 2,287.7 1,287.7 2,607.6 2,197.7 399.8 2,138.5 67.2 175.2 33.3 81.3 94.2 192.2 200.0 1,551.4 318,875 %Cu 0.08 0.82 0.48 0.7 0.35 0.51 0.23 0.19 0.80 0.11 2.75 0.80 3.48 1.38 1.13 0.55 0.51 0.28 0.51 MtCu 11.66 11.42 11.29 8.4 8.01 6.59 5.91 4.28 3.20 2.41 1.85 1.41 1.16 1.12 1.06 1.06 1.02 4.38 1,614.9
Notes:No.numberofdeposits;USAUnitedStatesofAmerica;DRCDemocraticRepublicofCongo;PNGPapuaNewGuinea.
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Table3.2:Top20copperresourcesbydeposit/project(sortedbyMtCu)
Deposit/Project Andina,Chile ElTeniente,Chile OlympicDam,Australia Collahuasi,Chile Chuquicamata,Chile Escondida,Chile Grasberg,Indonesia Pebble,USA TaimyrPeninsula,Russia LosPelambres,Chile LosBronces,Chile BuenavistadelCobre,Mexico RadomiroTomic,Chile RekoDiq,Pakistan Resolution,USA HugoDummettNorth,Mongolia CobrePanama,Panama Toquepala,Peru LosSulfatos,Chile CerroVerde,Peru
Ore/Mt 19,162 16,756 9,075 9,554 10,497 8,509 4,946 10,777 2,188 5,818 6,420 8,388 7,247 5,868 1,624 1,426 6,465 5,029 1,200 4,038
%Cu 0.59 0.56 0.87 0.81 0.55 0.61 0.81 0.34 1.45 0.53 0.44 0.33 0.37 0.41 1.47 1.39 0.30 0.36 1.46 0.41
MtCu 113.63 93.50 78.95 77.54 57.31 52.13 40.21 36.56 31.74 30.84 28.39 27.80 26.67 24.06 23.87 19.81 19.36 18.18 17.52 16.72
Total
144,987
0.58
834.8
12,578
Notes:Opoperating;Devunderdevelopment;Depdeposit;USAUnitedStatesofAmerica.
ForAustralia,anadditional46.0MtCu(tothefigureof85.6MtCuinFigure3.1)isreportedas subeconomicormarginalresources,givingAustraliaatotalof131.6MtCuofidentified resources.Overtime,itiscommonforidentifiedresourcestobeupgradedtoeconomicstatus afterfurtherdrilling,metallurgicalandotherstudies,andbedevelopedforproduction,showing thatthehigherresourcefigureisofimportanceforlongtermplanningormodellingofCu productionscenarios.TheOlympicDamdeposit,at79.0MtCu,representssome60%of AustraliasidentifiedCuresources,showingtheimportanceofsupergiantdeposits. ChileisclearlyinadominantpositioninglobalCuresources,withsome39%ofglobalCu resourcesbasedonourdataand9ofthetop20deposits627.2MtCualsocontrastswiththe USGSreservesestimateof150MtCu(and2008reservesbaseestimateof360MtCu). TheUSGS2010globalestimateofCureservesis~635MtCu,whilethe2008reservesbase estimatewas1,000MtCuyetthe674depositscompiledinthisstudyrepresent1,614.9Mt Cu,some60%higher.Ourdata,however,althoughcertainlycomprehensive,arenot exhaustive,asitdoesnotincludeanyCudepositsinChinaorothercountrieswithknown sizeableCuresources(eg.thedatausedforSarcheshmehinIranbeingseveralyearsold,aswell asseveralsmallersites).Asofthelate1990s,Chinahadidentified913Cudepositscontaining 73.7MtCu,althoughonlyathirdoftheseresourceswereconsideredeconomic(Hongtaoetal.
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Coppercasestudy:Australianresources,technologyandfuturescenarios
2011).Furthermore,CanadasnationalestimateforeconomicCuresourcesin2009was 7.29MtCu(NRC,variousyears)yetourdatasuggests42.6MtCu.Thislargediscrepancyis mainlyrelatedtothefactthatNaturalResourcesCanada(NRC)onlyincluderesourcesat operatingminesorthoseundergoingdevelopmentinnationalestimatesandexcludemineral resourcesatotherknowndeposits.Similarly,theUSGSestimatestheUSAsCureservesat35 MtCu,the2008reservesbaseat70MtCu,whileourdatasuggests134.2MtCu. AnimportantaspecttonoteisthatoftheCuresourcescompiled,overhalf(834.8MtCu)are containedinthe20largestdepositsalone,withthesedepositsalsocontainingsubstantialAu (andsometimesAg,Mo).Inaddition,thevastmajorityofthesedepositsarealreadybeing mined,meaningthatfutureexpansioninCuproductionmainlyneedstocomefromexpansion atexistingmines(i.e.brownfieldsgrowth),notmerelynewprojectsalone(i.e.greenfields). Finally,thetrendsovertimeinFigure3.2suggestgradualdeclinesinCuresourcesfortheUSA andCanada,comparedtostrong(almostexponential)growthforAustralia.Whilethisis temptingtolabelthedeclinesaspeakcopper,whencontrastingthedatacontainedinFigure 3.2withTable3.1(andnotingdiscussionabove),itisabundantlyclearthattheUSGSestimates ofvariousnationalCuresourcesareasignificantunderestimateofidentifiedCuresources.For example,therecent(~2000)discoveryofthegiantbutdeepResolutionCudepositinArizonain anareaofintensivehistoricalCumining(theMagmaCufield)showsthatthereremains excellentprospectsforexplorationtocontinuetofindnewdeposits,thoughmostlikelyat greaterdepththancurrentandpreviousCumines.Indeed,Australiahascontinuedtofind majornewdepositsoverthepast30years,suchasProminentHill,Rocklands,CadiaRidgeway, Northparkes,NiftyandmostrecentlyCarrapateenaaswellasongoingexpansionatexisting projects(e.g.MtIsa,MtLyell,OlympicDam).
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Coppercasestudy:Australianresources,technologyandfuturescenarios
7
USA Canada World Australia Papua New Guinea
Copper Ore Grade (%Cu)
21 18 15 12 9 6 3 27 24
3
0 1840 1860 1880 1900 1920 1940 1960 1980 2000
0 1900
1910
1920
1930
1940
1950
1960
1970
1980
1990
2000
2010
Figure3.2:HistoricaltrendsinCuoregradesforAustralia,CanadaandtheUSA(Mudd&Weng,2012)
Atglobalproductionof~16MtCuin2010andeconomicresourcesofmorethan1600MtCu, thisallowsforproductiongrowthforsomedecadesyet.Forcomparison,globalcumulative productionfrom1820to2010was~580.7MtCu. The next section discusses factors affecting the economics of copper production and explores theenvironmentalimpactsofsuchhistoricaldeclinesinoregradeforAustralia.
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Coppercasestudy:Australianresources,technologyandfuturescenarios
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure4.1:production(a)andoregrade(b)throughtime
Thispaperdoesnotdealexplicitlywithlabourcostsandothereconomiccostssuchasfuelinputs,transport
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Coppercasestudy:Australianresources,technologyandfuturescenarios
acaseinpointErnestHenryshowsacontinuousincreaseinproductionfrom1998to2005 althoughthereisadecreaseinitsoregradefrom1998to1999specificallyandgenerallyfrom 1998to2005. TheseresultsillustratethatAustraliaisfacingincreasingproductionoflowergradedminesthat increasesenergyconsumption(NorgateandHaque,2010).Howeverifanindustryfacesenergy consumptionincrease,itshouldproviderelativelymoreeconomicalbenefittomaintainthe profitabilityforthenation. However,althoughanalysingenergyconsumptionbydifferentsectorswithprojectionsto2030 alsoshowsthatthehighestrateofgrowthwilloccurintheminingsector,whichispredictedto undergo4.7%annualgrowthbetween2004and2030(AkmalandRiwoe,2005),Toppand colleagueshaveshownthattheproductivityofAustraliasmineralindustryisdecreasing,with multifactorproductivity(MFP)fallingsince2000,thebeginningofthemostrecentmining boom(Toppetal.,2008).Theauthorsattributetwothirdsofthisdeclinetofallingaverageore grades,whichrequirehighercapitalandlabourinputstoproducethesamequantityofore specificallyincaseofenergydensity.Thefinalremaindercanbeattributedtoinvestmentsnot providingreturnsyet.Thisdeclineinproductivityisreflectedinthestagnantgrowthinminings contributiontoAustraliasGDPasToppandcolleagueshavealsonotedtheimpactofthe miningindustrysrelianceonnonrenewableinputs,suchasoil,whichareincreasingly importedasAustraliansownresourcesareexhausted.Althoughthehighestrateofenergy consumptiongrowthhasbeenseeninmining,thisenergyhasnotbeenconvertedvery efficientlyintoproduct,resultinganullcontributiontoGDPgrowthbetweenDecember2009 andDecember2010(ABS,2011).ThisisshowninFigure4.2.
Figure4.2:ContributiontoGDPgrowthbysector(ABS,2011)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Reverberatoryfurnace: Before1950sReverberatorysmeltingwasthemaincoppersmeltingtechnologyintheworld (Davenportetal.,2002).Throughthisprocess,Fluidbedormultihearthroastersareusedto producealowsulphurcalcineforinjectionintothehearthareainlieuofgreencharging.Flux materialisaddedwiththeredhotcalcinebymeansoffettlingpipeswhichdistributethecharge materialalongtheinsidelongwallsoftherectangularfurnacelinedwithbasicandinsulating refractories(MoskalykandAlfantazi,2003). Thistraditionalmethodofconcentratesmeltingisstillusedworldwide(MoskalykandAlfantazi, 2003),butinrecentdecades,reverberatoryfurnacesarebeingsupersededformoreefficient, lowercostflashsmelters(Davenportetal.,2002).Theprocessflowofreverberatoryfurnace operationusedinLCAmodelsisshowninFigure4.3(Giurcoetal.,2006).
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure4.3:Reverberatoryfurnaceprocessflow(Giurcoetal.,2006)
Figure4.4:Flashsmeltingprocessflow(Giurcoetal.,2006)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
convertingstageintheflashsmeltingmodelismergedintosmeltingstage.Inputs,suchas oxygenenrichedairblastandthepercentofcopperinorefeeds,andoutputsareresetbased ondirecttoblisterprinciples.Itisworthnotingthatdirecttoblisterflashsmeltinggenerates highpercentagesofdust,andrecyclingthemconsumesenergybutthiseffectisnotconsidered inthemodels. IsasmeltTM TheIsasmeltTMprocesswasdevelopedinMountIsa,inQueensland,Australiaasacollaboration withCSIRO(Erringtonetal.,1997).Itisabathsmeltingtechnologythatfeaturestheinsertionof alanceintotheslagtoinjectoxygenenrichedairinthemoltenbath.Thismodificationcreates turbulencethatincreasestheproductivityofreactionwithfeedmaterials(ArthurandEdwards, 2003).HereitisworthnotingthatoperationsatMtIsamanagesulphurdioxideemissionsfrom thisprocessindistinctiveways,withsulphurdioxideemittedtotheairattheconversionstage, butcapturedinsmeltingstage,andsince1999convertedtosulphuricacid.However,as comparedwithIsasmeltTM,thefeedconcentrateindirecttoblisterflashsmeltinghastobepre dried,introducingadditionalenergyrequirementsandGHGemissions. 4.3.2. LCA Results
Thissectionoutlinestheresultsofthetimeserieslifecycleassessmentmodelswithtime varyinginputparametersforGlobalWarmingPotential,Acidificationpotentialand PhotochemicalOzoneCreationPotential.Wateraccessanddisposalisalsoasignificant environmentalissueforcopperminingandprocessingbutisnotexaminedindetailinthiscase study. GlobalWarmingPotential(GWP) Figure4.5(a)showsthetotalannualglobalwarmingpotentialofmineswhichisusedto measureGWPfrom1940to2008.OlympicDamhassharplysurpassedalloperationsby2000 andreachedmorethan1922ktofcarbondioxideequivalentsby2004coincidingwitharapid increaseinproduction.ThenexthighestrateofglobalwarmingpotentialbelongstoMtIsathat reachedtomorethan800ktbytheendof1996beforeinstallingIsasmeltTMfurnace.Average annualcarbondioxideproductionpermineisgentlyinclininginMtLyell(excludingthedropin 1969duetosmeltershutdown).However,thismineonlyproducescopperconcentrate,rather thanrefinedcopperasisthecaseforOlympicDamandMtIsa/Townsville.Osborneshowsa smoothdecreaseinGWPafter2005whichisduetochangesinproduction,oregrade,and transitionstoopencutmining.
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure4.5:Globalwarmingpotentialthroughtime(OlympicDamMine/Smelter;MtIsa Mine/Smelter;MtLyellmineonly;ErnestHenrymineonly;Osbornemineonly)
Inordertoclarifywhichstepsarethemaincontributorstocarbondioxideproductioninmining, adeeperlookintotheLCAmodelsisundertaken.ComparingtheresultsofMtIsaandOlympic Dam,after2000,showsahigherlevelofcarbondioxideinOlympicDamalthoughthelevelof productioninbothminesisveryclose.ThisindicatesthattheloweroregradeatOlympicDam, combinedwiththeuseofdirecttoblisterflashsmeltingresultsinhigherGWPperyear,when comparedMtIsa,whichhashigheroregradesandusestheIsasmeltTMprocess.Regardingthe impactofchangestothetypeofmining,figuresforMtLyellshowanincreaseinannualcarbon dioxideproductionfrom1972duetothehigherelectricityfeedrateinundergroundmining. TheotherimportantpointinFigure4.5isMtIsaGWPperunitofcopperwhichdropsafter installingIsasmeltTM,butstartstoincreaseaftersomeyears.Thisfactconfirmsthatthepositive effectoftechnologyimprovement,after1997,waslostinfewyearsduetochangeinother parameters,suchasadecreaseinoregrade.
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ThecontributionofeachtypeofoperationtocarbondioxideproductionatMtIsa,iscompared inFigure4.6.ThiscomparisonshowsthatthemainpartofCO2productioncomesfrommining andmilling,thenfromsmelting.Thesmeltingcontributionisalmosthalftheminingandmilling contribution.Oregradedeclineandproductionincreasesappeartohaveadominanteffecton carbondioxideproductioninmining,withamajorimpactonconcentrateproduction.This processstartswiththeoremillingandendswithaconcentratethatistheinputtosmelting process.Consequently,loweroregrademakestheconcentrateproductionmoreenergy intense,requiringmoreoretobemilledtoproducethesameamountofconcentrate.Hence,if atechnologyisexpectedtoreducecarbondioxideproductionofcopperminesinthefuture,it shouldhaveadirecteffectonconcentrateproductionortheearlyprocessingofore.
7% 5% 3% 1%
27%
57%
Figure4.6:ContributionofeachminingoperationtocarbondioxideproductionInMtIsa(2008)
Inordertolookattheglobalwarmingpotential,fromtheperspectiveoffinalcopper consumersconcernedabouttheircarbonfootprint,plottingthecarbondioxideproduction overunitofcopperasshowninFigure4.5(b)ishelpful.Figure4.5(b)showstheaverageimpact pertonneofcopperproducedinMtLyelldropsaftershuttingdownthesmelterswhich removestheimpactsfromsmeltingbutagainincreasesafterswitchingtoundergroundmining andincreaseinelectricityuse.Interestingly,by2008thelevelofGWPperunitofcopper surpassesthelevelin1965beforeshuttingdownthesmeltersthathighlightstheeffectof increasingproductionwhichalmostreachesdoublethelevelin1965.Theotherinteresting pointinFigure4.5(b)ishigherlevelsofGWPperunitofcopperinOlympicDamcomparingto MtIsaalthoughinsomeyears,productionishigherandoregradeislowerinOlympicDam whichshowstheeffectofdifferenttechnologies. ErnestHenryandOsborneshowfluctuatingcarbondioxideproductionpertonneofcopper. Thisvariabilitycreatesuncertaintyregardingfutureenvironmentalperformanceofthemines, andthecoppertheyproduce.Thisresultclarifiestheimportanceofminingparametersand regionalLCAfactorinfootprintcalculationofproductsthatusemineralcommodities.Italso confirmstheimportanceofLCAfordecisionmakinginthemineralindustry,particularlywhen consideringthedifferenceinglobalwarmingpotentialsofproductsassociatedwithdifferent mines.
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AcidificationPotential(Sulphurdioxide) Sulphurdioxideemissionsarethemainsourceofacidification,andareusedastheacidification calculation source in this paper. As shown in Figure 4.7 (below), a notable point of difference between Mt Isa and Olympic Dam in acidification graphs is the sudden decrease in Mt Isa sulphur dioxide production level after change from reverberatory to IsasmeltTM in 1997. Mt Isa processes include smelting, converting, slag cleaning, smelter and gas treatment as well as miningandmilling,withacopperrecoveryrateof90%.
Changeto TM Isasmelt
Figure4.7:Calculatedacidificationpotentialthroughtime
Coppercasestudy:Australianresources,technologyandfuturescenarios
Generally,thisdecreaseinacidificationlevelcanbeconsideredasthedominatingeffectof technologychange,however,thetreatmentofsulphuricacidasabyproduct,isnotedas problematicandalsothatnoallocationwasundertaken. At Olympic Dam, sulphur dioxide production shows a smooth increase until 1998, and then experiences a faster increase but remains less than Mt Isa. This result is interesting and shows that the effect of higher SO2eq/kWh in Mt Isas electricity source is stronger than production and ore grade effect in this case. Furthermore, Olympic dam captures all SO2 but Mt Isa just capturesSO2comingfromsmeltingandlettheSO2fromconvertersemittoair. Photochemicalozonecreationpotential(POCP) Photochemicalozonecreationpotential(POCP)graphs,calculatedinkilogramsofethylene equivalentasapotentialforsmogareshowninFigure4.8.Duringthereverberatoryfurnace useinMtIsaandMtLyell,higherproductioninadditiontohigherregionalLCAcharacterization factorinMtIsaresultsinhigherPOCPinMtIsa.Thisdifferenceremainswithdecreasein distanceafterupgradetoIsasmeltTMinMtIsa.Thedecreaseindistanceisbecauseoftheless fueluseinIsasmeltTMcomparedtothereverberatoryfurnace.ThehighestlevelsofPOCPafter 1998belongtoOlympicDamduetohigherproductionandinmostcasesloweroregradesin additiontolowerPOCPeq./KWh.LCAmodelsshowthatPOCPoriginatesfromdieselandfuel oil(52%),andelectricity(48%). AsshowninFigure4.8(below),averagePOCPissharplyrisinginMtIsaduringthe reverberatoryfurnaceusage,butincreasesmoregentlyafterchangetoIsasmeltTMbecause productionandoregradeinMtIsahavechangedlessoverthisperiodfurthermorefueloilrate islessinIsasmeltTMcomparingtoreverberatoryfurnace.Otherminesarealsoshowslight growthinPOCP.
Figure4.8:Calculatedphotochemicalozonecreationpotential
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5.2. Bioleaching
Bioleachingisproposedasasimpleandeffectivetechnologyextractingmetalsfromlowgrade oresorconcentrates(Bosecker,1997).Thistechnologyhasdevelopedrapidlyinthecourseof thelastdecade(Rohwerderetal.,2003).Thisisconsideredtobeanalternativeforsmeltingor roastingwhentherearelowerconcentrationsofmetalinore.Thebacteriafeedsonnutrients inminerals,therebyseparatingthemetalthatleavestheorganism'ssystem;thenthemetalcan becollectedinasolutionandrecoveredusingSolventExtractionandElectroWinning(SX/EW).
PartsofthisandthefollowingchapteraretakenfromMuddetal2011.Commodityfutures: lifeofresourcestrategiesforcopperandgold,MineralsEngineering(submitted).
3
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Coppercasestudy:Australianresources,technologyandfuturescenarios
5.5. Recycling
Recyclingisawaytogetcopperfromendoflifeproductswhichcontainscopperwith potentiallylessenvironmentalimpactscomparedwithprimaryminingandwithlesscost, especiallyforhighlypurecopperstreamswhichcanberemeltedratherthanlowerqualityscrap whichneedstobesortedandresmelted.Theeconomicsoftendependonthecostsof collectingmaterialandthevalueofpreciousandothermetals.Formalrecyclingisalsoexpected toprovidejobsandsocialbenefits,howeverthereareseriousenvironmentalandsocialimpacts oftheinformalrecyclingsectoroccurringincountriessuchasIndia. ThepotentialforincreasingthecopperrecyclinginAustraliaisestimatedas30%oftheendof lifematerialgeneratedinAustraliawhichisnotcurrentlyrecycledandequalsto23,000tper year(VanBeersetal.,2007).Consideringthevalueofcopperinfirstquarter2011as8300$/t thepotentialvalueofthenotrecycledcopperinAustraliawouldbealmost190milliondollars
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure5.1:Sydneyinusecopperstocksin2000(VanBeersandGraedel,2007)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Insitu mining
Deepsea mining
(Scott,2001)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Cheaperthan gettingcopper fromlowquality ores;requires transport, collection Decreasingnations demandfornew ores (Ayres,1997)
Recycling
PSS
(Schweitzerand Aurich,2010)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Theotheroptionisusingcleanenergysources.Ascurrentelectricitypricesarehigherinremote locations,thecosteffectivenessofinstallingcleanenergypowerplantsnearminesinremote placeswillincreaseinthefutureifthepowerplantscanprovidetherequiredbaseloadpower duringtheminelife.However,howdifferentdriversmightincreasecleanenergyuseinthe copperminingindustryrequiresanalysingthepossiblecleanenergyoptionsinAustralia(see Memaryetal.2011).PossiblecleanenergyoptionsinAustraliainclude: Solar(solarthermalandsolarphotovoltaic) Windturbines Energyfrombiomassandwastematerials Hybridfuels.
Figure5.2:LocationsofcopperminesonthesolarradiationmapofAustralia(AustralianMinesAtlas andCRESANU)
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Coppercasestudy:Australianresources,technologyandfuturescenarios
*whilstthesupplyofalargeAustraliancopperminewithhydroelectricityisunlikely(asoutlinedinScenario2),ithasbeen exploredasanillustrativecaseofcleanerenergy.Inaddition,importsandexportsarenotconsideredinthesescenarios.
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Coppercasestudy:Australianresources,technologyandfuturescenarios
Figure6.1:Globalwarmingpotentialofeachscenariotill2024
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Coppercasestudy:Australianresources,technologyandfuturescenarios
TheFirstscenarioofWEFminingandmetalsscenariosstatesthatfutureglobalmineraltrade happensbasedonglobalallianceswithsharedenvironmentalstandards,consequentlycash flowswillbelimitedbetweencountrieswithsamelevelsofemissionrates.Currently,average emissionsperunitofprimarymetalsproductioninAustraliaishigherthanworldaverage(Lund etal.,2008).ThisfactshowsthatAustraliancopperminesneedtodecreasetheir environmentalimpactsusingbothnewtechnologieswhichenhanceenergyefficiencyand decreasetheenvironmentalimpacts, 6.2.2. Rebased globalism
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Coppercasestudy:Australianresources,technologyandfuturescenarios
IfAustralianminesdecidetocontinuebusinessasusual,sociallicenceandmarketaccesswillbe importantfactorsinsecuringfuturejobopportunitieslossesandrestrainingdamagetothe environment.Consequently,oneoptioninthisscenarioismovingtowardsinnovationsinthe mineralindustry,suchasrecyclingorestablishingnewbusinessmodelslikeproductservice systems.Thesecondchoicecouldinvolvethemineralindustryinactivitiesthatcanprovide benefitsfortheAustraliansocietysuchasexportingminingknowledgeandensuringpositive legacyfromminingoperationstoincreasesociallicence. 6.2.3. Resource security
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Coppercasestudy:Australianresources,technologyandfuturescenarios
7. CONCLUDING DISCUSSION
Australiaasoneofthenationswithhighreservesofcopperandlonghistoryofcoppermining hasverywelldevelopedinfrastructureforcopperminingandsmeltingandhasbeenearning profitsfromthisindustryformanyyears.AvailabledepositsinAustraliashowthattherearestill goodremainingdepositsofcopperinthecountry.Forthefirsttime,acomprehensivedatabase ofcopperdepositsforAustraliahasbeencompliedonaminebyminebasisprimarilyusing companydatafromannualreportsandgovernmentstatistics. Notwithstandingsignificantreserves,thegeologicalcharacteristicsofcopperminesinAustralia showsthatoregradesarecomingunder2%inmostofthemineswhichresultsinhighamounts ofenergyintensityforextraction.Asenergypricesrise,thisfactincreasesthecostofmining anddecreasestheprofitabilityoftheindustrywithcurrenttechnologies. Theanalysispresentedinthisreportshowsthechangingimpactprofileassociatedwithcopper miningover70yearsinAustralia.Inshort,efficiencygainsmadebytheintroductionofnew technologiessuchasflashsmeltinginplaceofreverberatorysmeltershavelargelybeeneroded bydeclinesinoregrades.Furthermore,highereffortsrequiredtoextractcopperwithlower gradesfurtherpressuresthenaturalenvironmentandpublichealth. Optionstoaddressthechangesingeologicalandsocialconditionsforminingincludeusingnew technologies.Whilstsignificantfocusintechnologicaldevelopmentisoninsituanddeepsea mining,thesehavesignificantenvironmentalandsocialbarrierstowidescaledeployment. Researchfocusshouldalsobedirectedtolinkingcleanenergysourceswithhigherenergy efficiencyprocessesandthepursuitofenhancedrecyclingtechnologiesandlogistics.These shouldbeevaluatedinthecontextofchangingglobalscenariostopositionAustralianresearch andknowledgedevelopmentforvaluecreationacrosstheremainderofthiscentury.
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8. REFERENCES
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HANCOCK, B. A. & HINNEAPOLIS, M. 1977. UruL~ IUM IN SITU LEACHING: ITS ADVANTAGES, PRACTICE, PROBLEMS,ANDCOMPUTERSIMULATION. HANNIALA, P., HELLE, L. & KOJO, I. Competitiveness of the Outokumpu flash smelting technology now andinthethirdmillennium.1999.221238. HONGTAO, Z, QIHAI, J, HAIQING, H & XIAOBO, L (Ed's), 2011, China Mineral Resources, Ministry of Land andResources,Beijing,China,110p(inChinese). ISO 2006. 14040: Environmental managementlife cycle assessmentPrinciples and framework. Internationalorganizationforstandardization. JESWANI, H. K., AZAPAGIC, A., SCHEPELMANN, P. & RITTHOFF, M. 2010. Options for broadening and deepeningtheLCAapproaches.JournalofCleanerProduction,18,120127. KOJO, I. V., JOKILAAKSO, A. & HANNIALA, P. 2000. Flash smelting and converting furnaces: A 50 year retrospect.JOM,52,5761. LUND, C., HIGGING, M., JAHANSHAHI, S. & NORGATE, T. 2008. Energy Use and Greenhouse Gas Emissions Issues Facing the Minerals Processing Industry: An Issues Paper. Centre for Sustainable ResourceProcessing. MEMARY, R., GIURCO, D., MUDD, G., MASON, L. 2012, Life Cycle Assessment: a time series analysis of copper.JournalofCleanerProduction,33,97108. MEMARY, R., GIURCO, D., PRIOR, T., MASON, L., MUDD, G., & PETERSEIM, J., 2011. Clean energy and mining future synergies. 2nd AusIMM International Future Mining Conference, November 2223, Sydney. MOSKALYK, R. R. & ALFANTAZI, A. M. 2003. Review of copper pyrometallurgical practice: today and tomorrow.MineralsEngineering,16,893919. MUDD,G.2010.CopperproductiondatainAustralia. MUDD, G. M. & WARD, J. D. 2008. Will Sustainability Constraints Cause" Peak Minerals. 3rd International Conference on Sustainability Engineering & Science : Blueprints for Sustainable InfrastructureAuckland,NewZealand912Dec2008. MUDD,GM&WENG,Z,2012,BaseMetals.InMaterialsforaSustainableFuture,EditorsTLetcher,M GDavidson&JLScott,RoyalSocietyofChemistry,UK. MUNRO,M.,2011.RaceontoRegulateDeepSeaMining.TheVancouverSun. NORGATE, T. & HAQUE, N. 2010. Energy and greenhouse gas impacts of mining and mineral processing operations.JournalofCleanerProduction,18,266274. NRC, var., Canadian Minerals Yearbook. Mining Sector, Natural Resources Canada (NRC), Ottawa, Ontario, Canada, Years 1944 to 2009, www.nrcanrncan.gc.ca/mmssmm/busiindu/cmyamc eng.htm. ROHWERDER, T., GEHRKE, T., KINZLER, K. & SAND, W. 2003. Bioleaching review part A. Applied MicrobiologyandBiotechnology,63,239248. SCHWEITZER, E. & AURICH, J. C. 2010. Continuous improvement of industrial productservice systems. CIRPJournalofManufacturingScienceandTechnology. SCOTT,S.D.2001.Deepoceanmining.GeoscienceCanada,28. TAYLOR, G., FARRINGTON, V., WOODS, P., RING, R. & MOLLOY, R. 2004. Review of Environmental ImpactsoftheAcidInsituLeachUraniumMiningProcess.
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TOPP,V.,SOAMES,L.,PARHAM,D.&BLOCH,H.2008.ProductivityintheMiningIndustry:Measurement andInterpretation.:ProductivityCommissionStaffWorkingPaper,December. TREWIN, D. & AUSTRALIAN BUREAU OF STATISTICS. 2006. Measures of Australia's Progress, Australian BureauofStatistics. VAN BEERS, D. & GRAEDEL, T. 2007. Spatial characterisation of multilevel inuse copper and zinc stocks inAustralia.JournalofCleanerProduction,15,849861. VAN BEERS, D., KAPUR, A. & GRAEDEL, T. 2007. Copper and zinc recycling in Australia: potential quantitiesandpolicyoptions.JournalofCleanerProduction,15,862877. WATLING, H. R. 2006. The bioleaching of sulphide minerals with emphasis on copper sulphides A review.Hydrometallurgy,84,81108.
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