Special media pressure vessel material selection and production specifications 1 NaOH solution 1.

1 Carbon steel and ground alloy steel welding system chemical containers, such as welding or cold working, stress relief heat treatment, the use of temperature costumes NaOH solution media should not be greater than the temperature listed in Table 1. When NaOH solution medium in with the mixture of hydrocarbons when the volume ratio is greater than or equal to 5%, should also comply with this requirement. NaOH solution medium concentration is less than or equal to 1% or NaOH solution medium when its volume is less than 5% of the mixture of hydrocarbons, are not affected by this restriction. 1.2 Chemical vessel shell containing NaOH solution medium carbon steel and low alloy steel welded steel plate corrosion allowance of not less than 3mm. 1.3 Costumes KOH solution medium carbon steel and low alloy steel welded chemical containers should refer to the provisions of paragraph 1 of this. NaOH solution, mass% Upper temperature limit 2 82 3 82 5 82 10 81 15 76 20 71 30 59 40 53 50 47

Table 1: NaOH solution in the maximum use temperature 2 Wet H2S stress corrosion environment. 2.1 Corrosive environments When the chemical container to contact the media at the same time meet the following conditions, namely wet H2S stress corrosion environment: 2.1.1 Temperature less than or equal to (60 + P) C; P is the pressure, MPa (gauge pressure). 2.1.2 H2S partial pressure is greater than or equal to 0.00035 MPa, which is equivalent to the normal temperature of H2S in the water solubility of greater than or equal to 7.7 mg / L; 2.1.3 Containing liquid water or in the water below the dew point temperature of the medium; 2.1.4 PH <7, or the presence of cyanide (HCN). 2.2 Material requirements and restrictions. The use of carbon steel and alloy steel in wet H2S stress corrosion environment should meet the following requirements: 2.2.1 Material standard specifies the lower yield strength ReL 355 Mpa 2.2.2 Material measured tensile strength Rm 630Mpa 2.2.3 Material use status should be normalized or normalizing + tempering, annealing, quenching and tempering state. 2.2.4 Carbon equivalent limit (when the carbon equivalent limits exceed the standard, should increase the hardness limit monitoring frequency): low-carbon steel and carbon manganese CE 0.43 CE = C + Mn / 6 Low alloy steel (including low-temperature nickel steel) CE 0.45 CE = Visual C + of Mn / 6 + (Cr + M0 + V) / 5 + (Ni + Cu) / 15 2.2.5 Normalizing or tempering the processed material in the non-welded parts or after welding, the hardness is as follows: Low carbon steel HV (10) 220 (a single value)

Low-alloy steel HV (10) 245 (single value) 2.2.6 Shell with steel plate thickness greater than 20mm, in accordance with the Pressure Equipment destructive testing the "JB/T4730.3 ultrasonic testing line level requirements qualified; 2.2.7 Should not be used corrosion of the steel plates and copper alloy; 2.2.8 Shell with steel corrosion allowance of not less than 3mm; 2.2.9 The surface of the material can not have sharp presence of more than 0.5mm 2.3 Manufacturing requirements 2.3.1 Cold deformation: Cold deformation amount is less than or equal to 5% of the stress relief heat treatment should be done; than 5% should be done normalizing or heat treatment; 2.3.2 After heat treatment, is not allowed in contact with the media side of the grinding and playing Seal. 2.4 Welding 2.4.1 All welds should be assessed by the welding process, including welding, repair welding, welding, pipe and tube sheet welding, welding, fillet welding; 2.4.2 Meet the strength requirements, and maximize the use of low strength welding materials; 2.4.3 The hardness of welded joints (including the weld heat affected zone and base metal) into conformity with paragraph 2.2.5 requirements; 2.4.4 Welding procedure qualification, welding test plate and a welding process of welding products weld hardness determination shall be according to the requirements of this subsection, 2.4.3. Hardness measurement on the product surface in contact with the medium side. Process assessment and hardness test panel should be measured in the cross section measurement (the distance from the surface of 1.5mm at); 2.4.5 Weld outside the arc starting, arc extinction (including temporary welds) should be polished before the post-weld heat treatment more than 0.3 mm, and to do magnetic particle or coloring check; 2.4.6 All welded joints should not leave the a closed intermediate space (liner, strengthen the board around the fillet weld), the case of the inevitable, should be opened to vent; 2.4.7 Presence of dissimilar metal weld joints between ferritic steel or duplex stainless steel and austenitic steels are not allowed. 2.5 Post-weld heat treatment 2.5.1 The container may occur Wet H2S stress corrosion environment should be carried out post-weld stress relief heat treatment, post-weld heat treatment temperature should be standard requirements as much as possible to take maximum; 2.5.2 Heat treatment should stress relief heat treatment furnace overall. 2.6 The H2S severe corrosive environments 2.6.1 The container working conditions at the same time meet the following conditions for H2S severe corrosive environment:

2.6.1.1 Working pressure greater than 1.6MPa; 2.6.1.2 Coexistence of H2S-HCN HCN> 50mg / L; 2.6.1.3 PH <7. 2.6.2 When the container in of H2S serious corrosion environment should meet the following requirements: 2.6.2.1 Chemical compositionS0.003%P0.008%Ni1.0% 2.6.2.2 Section shrinkage thickness direction 35%Average of three samples 25%A single specimen lowest value 2.6.2.3 All welded joints should be post-weld heat treatment. 3 Hydrogen corrosion environment 3.1 Corrosive environments Chemical pressure vessel design temperature is greater than or equal to 200 C and in contact with the hydrogen atmosphere is hydrogen corrosive environment. If there are other factors in the high temperature sulfur corrosion, high temperature creep, creep, and the multiplier effect of the hydrogen corrosion, temper brittleness, hydrogen corrosion environment factors should also consider the impact of these factors on the high temperature mechanical properties of steel. 3.2 Material requirements and restrictions 3.2.1 The hydrogen corrosion environment the use of state of the steel shall conform to the provisions of the standard, and post-weld stress relief heat treatment; 3.2.2 The use of ferritic steels in the corrosive environment of hydrogen temperature limits, and shall have a 20 C above the temperature safety margin; 3.2.3 Austenitic stainless steel as shown in the temperature and hydrogen partial pressure does not cause hydrogen corrosion, do not need to carry out post-weld stress relief heat treatment. 4 Liquid ammonia stress corrosion environment 4.1 Corrosive environments 4.1.1 The medium is liquid ammonia, and high water content ( 0.2%) and may be affected by the contamination of the air (O2 or CO2) Occasion; 4.1.2 Using a temperature higher than -5 C. 4.2 Liquid ammonia stress corrosion environment of low carbon steel and high-strength low-alloy steel (including welded joints) shall meet the following requirements: 4.2.1 Material requirements and restrictions specified by this standard 2.2.1-2.2.5; 4.2.2 Welding requirements under the standard 2.4.1-2.4.7; 4.2.3 Post-weld heat treatment or hardness greater than 185HB welding process welding; 4.2.4 Added to the liquid ammonia is greater than or equal to 0.2% of water as a corrosion inhibitor can also be used as auxiliary measures to prevent stress corrosion cracking. 5 Low acid value high sulfur crude oil and high sulfur environment of high acid value of crude oil processing equipment selection requirements, with reference to the "processing sour crude focused device equipment design selection guide the"

SH/T3096 provisions. Selection of the chemical container material, there should be based on the state of the media, flow velocity, flow state, and is in phase change parts, take the local structure of the equipment and materials to increase the flow area to reduce the flow rate increased shell thickness, additional blockboard, local materials upgrade measures to prevent severe localized corrosion.