AP Chemistry Free Response by Topicss

Adrian Dingles Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009, 2010, 2011, 2012.
All rights reserved. These materials may NOT be copied or redistributed in any way, except for individual class instruction.
Revised August 2011
AP Free Response Summary 1990-2011
Question #
Parts
Topic(s)
a-d
Gases, Kinetics
a-g
2011
Lewis diagrams, VSEPR, IMFs, Hydrolysis, REDOX, entropy, bond making/breaking
a-c
Net Ionic Equation Writing
a-g
Delta H, Electrochemistry
a-c
Quantitative Lab, Dilution, Gravimetric Analysis
a-d
pH, Kb, Ka, Buffers
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Page 1 of 32
Adrian Dingles Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009, 2010, 2011, 2012. All rights reserved. These materials may NOT be copied or redistributed in any way, except for individual class instruction.
Revised August 2011
Question #
Parts
Topic(s)
a-c
Hybridization, VSEPR, Lewis Structures, Hbonding, Kinetics
2011 B
a-d
Qualitative Acid Base Titration
a-c
a-d
Empirical formula, Delta H, G = H - TS
a-c
Stoichiometry, Gases, IMFs
a-d
pH, Ksp, Kp, Delta G
Page 2 of 32
Revised August 2011
Question #
Parts
Topic(s)
a-g
Electronic configuration, Ionization energy, REDOX, Electrochemistry
a-f
2010
Lewis diagram, bond length, shape, inter versus intra, polarity, IMFs
a-c
a-d
Stoichiometry, PV = nRT, Kinetics
a-f
Quantitative Lab; Enthlapy of solution, G = H TS, % error
a-f
Ksp
Page 3 of 32
Revised August 2011
Question #
Parts
Topic(s)
a-h
Kinetics, Mechanisms
2010 B
a-f
Acid Base Titration
a-c
a-f
Quantitative Lab; REDOX, Oxidation numbers, REDOX titration
a-f
Electrochemistry, REDOX stoichiometry
a-f
Organic isomerism, IMFs, Kc, PV = nRT
Page 4 of 32
Revised August 2011
Question #
Parts
Topic(s)
a-d
Electronic Configuration, VSEPR, IMFs
a-f
2009
Kp, Le Chatelier, Bond Energies, Entropy and Enthalpy
a-c
a-e
Limiting Reactant, Moles, Photon Wavelength, Mechanisms
a-g
Quantitative Lab; PV=nRT, molar mass of gas
a-d
Ka and Buffers
Page 5 of 32
Revised August 2011
Question #
Parts
Topic(s)
a-g
Electrochemistry
2009 B
a-e
Lewis Structures, Moles, Bond Energies, Entropy, Delta H, Delta S
a-c
a-f
Quantitative Gases, Oxidation Numbers, REDOX
a-e
Quantitative Lab; Kinetics
a-d
Concentration, Kb, Buffers
Page 6 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
IMFs solubility, IMFs Boiling point, bonding melting point, IMFs boiling point
a, b, c, d, e, f
2008
Ionization energy, Lewis structures, VSEPR, hybridization
a-c
a, b, c, d, e, f
Electrochemistry, Delta G, Delta S, Kinetics
a, b, c, ,d, e
Lab question; Hydrated salt, gravimetric analysis
a, b, c, d, e
Kp
Page 7 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Delta H, Delta S, Delta G, Le Chat, Delta G
2008 B
a, b, c, d, e
Qualitative analysis
a-c
a, b, c, d, e
Solubility rules, stoichiometry, limiting reactant, concentration, solubility rules
a, b, c, d, e, f, g
Kinetics
a, b, c, d
PV=nRT, Kc, mole fraction
Page 8 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d, e, f, g
Lewis structures, Resonance, Hybridization, Catalysis, Equilibrium
a, b, c, d, e
LAB Redox Titration
2007
a-c
a, b, c, d, e, f
Electrolysis, Delta G
a, b, c, ,d, e
Delta G, Equilibrium, Delta H, Bonds/Bond Energy
a, b, c, d, e
Ka, titration, pH
Page 9 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d, e, f
Periodicity
2007 B
a, b, c
Lewis Structures, Dilution, Buffers (LAB)
a-c
a, b, c
Stoichiometry, Redox, Electrolysis
a, b, c
Isotopes, Emission Spectra, Bond Energy/Photons
a, b, c, d, e, f
Kp, Delta G, Delta S, Delta H
Page 10 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d, e, f
Electronic configuration, electronic configuration, periodicity, electronic configuration, periodicity, stoichiometry/solubility rules Lewis structures/hybridization/shape/bond angles, Lewis structures/hybridization/shape/bond angles + oxidation #
a, b
a, b, c, d
2006
IMF, H-bonds/polarity, IMF, Kinetics
a, b, c, d, e
Qualitative analysis, precipitation, slat hydrolysis, dilution, solubility/flame test
a-h
a, b
Combustion Analysis, Gas calculations
a, b, c, ,d, e
Delta H combustion, Delta S, Delta G, Delta G, K in relation to Delta G
a, b, c, d
Ksp
Page 11 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Redox, Gases, Bonding, Acid/Base neutralization
a, b, c, d
Periodicity, Lewis Structure & Electron Deficiency, Ionization Energy, Electronic Configuration
2006 B
a, b
Lewis Structures/Bond Angles/Hybridization/Bond Angles/Polarity
a, b, c, d
Spectrophometric Analysis/Beer's Law
a-h
a, b, c, d, e, f
Delta G/Delta S/Keq/Delta H
a, b
Voltaic Cell, Nernst Equation
a, b, c
Ka/pH/Buffers, Hydrolysis of Salts, Acid Base Titration/Stoich
Page 12 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Delta G, Delta S, Delta H, Electrolysis
a, b, c, d
IMF's, Ionic Bonding, Ionization Energy, Average Atomic Mass
a, b, c
2005
Lewis Structures, VSEPR/Hybridization, Bonding/Formal Charge
a, b, c
Qualitative Analysis of Gases, Periodicity of Oxides, Solubility/Precipitates
a-h
a, b, c
Kinetics
a, b, c, ,d, e
Empirical Formula, Freezing Point Depression, Molecular Formula related to Empirical, Organic Functional Group
a, b, c, d, e
Ka, pH, Buffer, Kb/Ka, Acid Strength
Page 13 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d, e
Bonding
a, b, c, d, e
Combustion Equation, Delta H, Formation Equation, Delta S, Bond Energy
2005 B
a, b, c, d, e
Gases
a, b, c, d
Laboratory (Synthesis of a Salt)
a-h
a, b, c, d, e, f
Kinetics
a, b, c, d, e, f
Electrolysis, Electrolysis, Stoichiometry, Electrolysis, PV=nRT, Water Vapor Pressure
a, b, c, d
Ka, pH, Acid-Base Equation, moles/Buffers/Kw'
Page 14 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d, e
Lewis diagram, VSEPR, Periodicity, Boyles Law, Gases
a, b, c, d
Inter molecular Bonding, Ionic Bonding, VSEPR, Hydrogen Bonding
a, b, c, d, e, f
Electrochemistry
2004
a, b, c
Qualitative Analysis (Solubility rules precipitation reactions)
a-h
a, b, c, d, e
Beers Law, Kinetics, Kinetics, Kinetics (halflife), Kinetics (Graphs)
a, b, c, ,d, e
Stoichiometry, limiting reagent, stoichiometry, Delta G, Delta H, Delta S, Delta H
a, b, c, d, e, f, g
Ksp
Page 15 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Equilibrium, Equilibrium, Equilibrium, Organic
a, b, c, d, e
Bond Energies, Entropy, Delta G, Equilibrium constant, Equilibrium constant
2004 B
a, b, c, d
Electrochemistry
a, b, c, d, e, f, g
Acid Base Titration
a-h
a, b
Stoichiometry (Density, moles), Kinetics (Graphs, halflife)
a, b, c, d
Empirical Formula, Density of gases, Gases, Gas Stoichiometry
a, b, c, d
Kp, Kp, Kc, Kp
Page 16 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Organic nomenclature/bonding, intermolecular bonding, isomerism, hybridization/sigma/pi
a, b, c, d
H, Entropy, G, Kinetics (Eact)
a, b, c, d
2003
Acid + carbonate, Colligative properties, Ideal and real gases, kinetic theory
a, b, c, d, e
Dilution, Beers Law, Beers Law, Beers Law, Beers Law, Transition metals
a-h
a, b, c, d, e
Orders from initial rate data, Rate equation, Rate constant, Ecell, REDOX half-equations
a, b, c, d, e
PV=nRT, PV=nRT (Partial Pressures), Diffusion, Gas Stoichiometry
a, b, c, d, e
Kb, Kb, Buffer calc, titration calc, Indicators
Page 17 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d, e
Radioactivity, Radioactivity, Radioactivity, Kinetics, Radioactivity
a, b, c, d
Ionic Radii, Periodicity, Periodicity, Ionization Energies REDOX equation writing, Ecell calculation, Electrochemistry, Electrochemistry, Electrochemistry
2003 B
a, b, c, d, e
a, b, c, d, e
Laboratory (REDOX titration)
a-h
a, b, c, d
Empirical formula, PV=nRT, Delta H formation, Q = m c Delta T
a, b
Stoichiometry, Stoichiometry & pH
a, b, c, d, e, f
Kc, Kc, Kc, equilibrium, Kc & Kp, Equilibrium
Page 18 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Thermochemistry, thermochemistry, thermochemistry, equilibrium
a, b, c, d
Kinetics
a, b, c, d
2002
Periodicity, periodicity, bonding, bonding
a, b, c, d, e
Laboratory (q = mcT, neutralization)
a-h
a, b, c, d, e
Equation Writing (Combustion), Stoichiometry (Gases), Energetics, Diffusion, Isomerism Stoichiometry (Limiting reagent/concentration), Electrochemistry, Electrochemistry, Electrochemistry Ka, Ka, Titration calculation/Salt hydrolysis, Buffers, Acid Strength
a, b, c, d, e
a, b, c, d, e
Page 19 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Titration curves, Ka, Titration curves, Titration
a, b, c, d
Electrochemistry, Electrochemistry, Electrochemistry, Electrochemistry Lewis Structures/Bonding, Polarity/Shape, Shape, Lewis Structures/Shape, Acid Strength
2002 B
a, b, c, d
a, b, c, d, e
Laboratory (Qualitative)
a-h
a, b, c, d
REDOX equation writing, Kp, Delta G/Delta S/Delta H, Delta G and Kp
a, b, c, d
PV=nRT & Partial Pressures, mole fraction, density, Stoichiometry
a, b, c, d
Ka, pH, Buffers, Weak acids
Page 20 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Bonding
a, b, c, d
Electrochemistry
a, b, c, d, e
Kinetics
2001
a, b, c, d, e
BPE, Acid-Base, Solutions, REDOX & Electrochemistry, Solutions
a-h
a, b, c, d
Stoichiometry, Stoichiometry (combustion), Titration Calculation, Acid-Base
a, b, c, d
H (combustion), G, S, Bond Energies
a, b
Ksp
Page 21 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Acid-Base
a, b, c, d
Atomic Structure, Electron Configuration, Periodicity, Lewis Structure & Shape
a, b, c, d, e
2000
H, S, G, Kinetics, Mechanisms
a, b, c, d
Laboratory (FPD)
a-h
a, b, c
Stoichiometry, Stoichiometry & Gas Stoichiometry, REDOX Titration Calculation
a, b, c
Electrochemistry
a, b, c, d, e
Equilibrium (Kc)
Page 22 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b
Lewis Structures & Bond Length, Lewis Structures & Shape & Polarity
a, b, c, d
Solutions, FPD, Vapor Pressure, Acid-Base
a, b
1999
H & S & G, G & Catalysts
a, b, c, d, e
Laboratory (Gases)
a-h
a, b, c, d
Kinetics
a, b
Electronic configuration
a, b, c, d, e
Kc, Acid-Base, Kb, Acid-Base, Titration Acid-Base Calculation
Page 23 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Solutions, Transition Metals, Polarity, REDOX
a, b, c, d, e
Electrochemistry
a, b, c, d
Equilibrium (Le Chateliers Principle)
1998
a, b, c
Kinetics
a, b, c, d, e
Acid-Base
a-h
a, b, c, d
H (combustion), H (formation), G, Gas Calculation
a, b, c, d
Stoichiometry, FPD, Gases, Stoichiometry
a, b
Ksp, Ksp & Solutions
Page 24 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Laboratory (Stoichiometry)
a, b, c, d
Radioactivity
a, b, c, d
S, G, Le Chateliers Principle, Le Chateliers Principle
1997
a, b, c, d
Periodicity
a, b, c
Lewis Structure & Shape, Polarity, Bonding
a, b, c, d, e
Kinetics
a, b, c, d, e
Electrochemistry
a, b, c, d
Titration Calculation, Equilibrium, AcidBase, Kb
a-h
Page 25 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Hydrogen Bonding, Polarity, Bond Length, Expanded octets & Shape
a, b, c, d
Kinetics
a, b, c, d, e
Electrochemistry
1996
a, b, c, d
Acid-Base
a, b, c, d
Gases
a, b, c, d
Stoichiometry
a, b, c, d
S, G, Equilibrium Constant, Bond Energies
a, b, c, d, e
Acid-Base
a-h
Page 26 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Kinetics
a, b, c, d
Entropy, Ksp, Equilibria, G
a, b, c, d
Paramagnetism, Lewis Structures & Dipoles & Shape, Transition Metals, Bonding
1995
a, b, c, d
Phase Diagrams
a, b, c, d
Laboratory (Bonding)
a-h
a, b, c, d
Gas Stoichiometry, Equation Writing, Stoichiometry, Stoichiometry
a, b, c, d, e
Equation Writing, Gas Stoichiometry, H, H
a, b, c, d, e
Equilibrium
Page 27 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Periodicity
a, b, c, d
FPD, Bonding, Bonding, Equation Writing
a, b, c, d
Acid-Base
1994
a, b, c, d
S, G, Equilibrium Constant, G
a, b, c, d
Vapor Pressure, BPE, Electrochemistry, Bonding
a-h
a, b, c, d
Gases
a, b, c, d, e
Kinetics
a, b, c, d
Ksp
Page 28 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Gases
a, b, c, d
S, G, H, Kinetics
a, b, c
Electrochemistry
1993
a, b, c, d
Periodicity, Periodicity, Electronic Structure, Expanded octet/Shape
a, b, c, d
Equation Writing, Bonding, Equation Writing, Acid-Base
a-h
a, b, c, d, e
Stoichiometry, Stoichiometry, Laboratory (Titration), Gases, Acid-Base
a, b, c, d, e
Empirical Formulae, FPD, Mole Fraction, Vapor Pressure
a, b, c, d
Acid-Base
Page 29 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Lewis Structures, Bond Angles, Hybridization, Dimerization
a, b, c, d
Bonding
a, b, c, d, e
Laboratory
1992
a, b, c, d
Acid-Base
a, b, c, d
Kinetics
a-h
a, b, c, d
Equilibrium Constant & S
a, b, c, d
Electrochemistry
a, b, c, d
Stoichiometry, Stoichiometry, Kp, Gas Stoichiometry
Page 30 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c, d
Nuclear Chemistry (Radioactivity)
a, b, c, d
Bonding
a, b, c, d
Electrochemistry
1991
a, b, c, d
Laboratory (Gases)
a, b, c, d
S, H, G, Equilibrium Constant
a-h
a, b, c, d
Kinetics
a, b, c, d
Stoichiometry, Stoichiometry, FPD, Stoichiometry
a, b, c, d
Acid-Base
Page 31 of 32
Revised August 2011
Question #
Parts
Topic(s)
a, b, c
Laboratory (Stoichiometry)
a, b, c, d
Acid-Base
a, b, c, d
Kinetics
1990
a, b, c, d
Periodicity
a, b, c, d
Bonding
a-h
a, b, c, d
H, S, Equilibrium Constant, Equilibrium Constant
a, b, c
Gas Stoichiometry
a, b, c, d
Ksp
Page 32 of 32

AP Chemistry Free Response by Topicss

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Adrian Dingles Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009, 2010, 2011, 2012.

Revised August 2011

AP Free Response Summary 1990-2011

Lewis diagrams, VSEPR, IMFs, Hydrolysis, REDOX, entropy, bond making/breaking

Net Ionic Equation Writing

Quantitative Lab, Dilution, Gravimetric Analysis

pH, Kb, Ka, Buffers

Revised August 2011

Hybridization, VSEPR, Lewis Structures, Hbonding, Kinetics

Qualitative Acid Base Titration

Net Ionic Equation Writing

Empirical formula, Delta H, G = H - TS

Stoichiometry, Gases, IMFs

pH, Ksp, Kp, Delta G

Revised August 2011

Electronic configuration, Ionization energy, REDOX, Electrochemistry

Net Ionic Equation Writing

Stoichiometry, PV = nRT, Kinetics

Quantitative Lab; Enthlapy of solution, G = H TS, % error

Revised August 2011

Acid Base Titration

Net Ionic Equation Writing

Quantitative Lab; REDOX, Oxidation numbers, REDOX titration

Electrochemistry, REDOX stoichiometry

Organic isomerism, IMFs, Kc, PV = nRT

Revised August 2011

Electronic Configuration, VSEPR, IMFs

Kp, Le Chatelier, Bond Energies, Entropy and Enthalpy

Net Ionic Equation Writing

Limiting Reactant, Moles, Photon Wavelength, Mechanisms

Quantitative Lab; PV=nRT, molar mass of gas

Revised August 2011

Lewis Structures, Moles, Bond Energies, Entropy, Delta H, Delta S

Net Ionic Equation Writing

Quantitative Gases, Oxidation Numbers, REDOX

Quantitative Lab; Kinetics

Concentration, Kb, Buffers

Revised August 2011

Ionization energy, Lewis structures, VSEPR, hybridization

Net Ionic Equation Writing

Electrochemistry, Delta G, Delta S, Kinetics

Lab question; Hydrated salt, gravimetric analysis

Revised August 2011

Delta H, Delta S, Delta G, Le Chat, Delta G

Net Ionic Equation Writing

Solubility rules, stoichiometry, limiting reactant, concentration, solubility rules

PV=nRT, Kc, mole fraction

Revised August 2011

Lewis structures, Resonance, Hybridization, Catalysis, Equilibrium

LAB Redox Titration

Net Ionic Equation Writing

Delta G, Equilibrium, Delta H, Bonds/Bond Energy

Revised August 2011

Lewis Structures, Dilution, Buffers (LAB)

Net Ionic Equation Writing

Stoichiometry, Redox, Electrolysis

Isotopes, Emission Spectra, Bond Energy/Photons

Kp, Delta G, Delta S, Delta H

Revised August 2011

IMF, H-bonds/polarity, IMF, Kinetics

Qualitative analysis, precipitation, slat hydrolysis, dilution, solubility/flame test

Net Ionic Equation Writing

Combustion Analysis, Gas calculations