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1 Demo Version
Engineering Software
Copyright 1996 P.O. Box 1180 Germantown, MD 20875 Phone/FAX: (301) 540-3605 E-Mail: info@engineering-4e.com http://www.engineering-4e.com
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 0.130 -206.314 -141.045 0.474 12.00 0.693 0.711 298 1.00
Temperature [K]
Minimum
2,000
1,000
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 2,937.582 1,552.050 -3,824.137 3.381 12.00 0.693 2.050 2,000 1.00
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 298 1.00 0.082 -0.667 -1,239.333 -19,452.177 65.274 2.00 4.157 14.427 1.405
Temperature [K]
Minimum
2,000
1,000
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] 2,000 1.00 0.012 26,476.589 18,163.400
Gibbs Free Energy [kJ/kg] -161,822.667 Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 94.150 2.00 4.157 17.096 1.321
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 0.529 -76.888 -296.525 0.997 32.00 0.260 0.691 298 1.00
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 298 1.00 1.145 -0.165 -88.641 -2,037.859 6.838 28.00 0.297 1.040 1.400
Temperature [K]
Minimum
2,000
1,000
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 2,000 1.00 0.171 2,003.764 1,409.965 -15,989.830 8.997 28.00 0.297 1.286 1.300
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 298 1.00 1.309 -0.149 -77.566 -1,909.150 6.406 32.00 0.260 0.917 1.395
Temperature [K]
Minimum
2,000
1,000
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 2,000 1.00 0.195 1,848.778 1,329.204 -14,938.405 8.394 32.00 0.260 1.182 1.282
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 298 1.00 0.736 -15,878.521 -16,016.150 -17,035.630 3.883 18.00 0.462 4.183 1.124
Temperature [K]
Minimum
298
273
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 298 1.00 1.186 -172.742 -258.167 -2,164.625 6.684 29.00 0.287 1.006 1.398
Temperature [K]
Minimum
2,000
1,000
Pressure [atm]
1.00
Output Values:
Temperature [K] Pressure [atm] Density [kg/m^3] Enthalpy [kJ/kg] Internal Energy [kJ/kg] Gibbs Free Energy [kJ/kg] Entropy [kJ/kg*K] Molecular Weight [kg/kmol] Gas Constant [kJ/kg*K] Specific Heat [kJ/kg*K] Kappa [/] 2,000 1.00 0.177 1,789.964 1,216.312 -15,811.078 8.801 29.00 0.287 1.261 1.294
Working Fluid Kappa [/] Specific Heat [J/kg*K] Compressor Inlet Temperature [K] Compressor Inlet Pressure [atm] Turbine Inlet Temperature [K] Turbine Inlet Pressure [atm] Working Fluid Mass Flow Rate [kg/s] Fuel HHV [Btu/lbm]
Air 1.40 1,004.0 298.0 1.00 1,500.0 15.00 1.0 24,000 Compressor Outlet Temperature [K] Turbine Outlet Temperature [K] Cycle Efficiency [%] Heat Rate [Btu/kWhr] Power Output [kW] Fuel Mass Flow Rate [kg/s] 646.0 691.9 53.87 6,334 462 0.015
1,500.0
1.0
298.0
Working Fluid
Air
1,000 800
1,000
1,500.0
1.0
298.0
Working Fluid
Air
Cycle Efficiency and Heat Rate vs Compression Ratio 100 10,000 9,000 8,000 60 7,000 40 6,000 5,000 5 10 15 20 25
80
20
1,500.0
1.0
298.0
Working Fluid
Air
Power Output and Fuel Mass Flow Rate vs Compression Ratio 600 0.020 0.018 0.016 400 0.014 300 0.012 0.010 5 10 15 20 25
500
200
Output Values:
750
500
250
0 5 10 15 20 25
750
500
250
0 5 10 15 20 25
Output Values:
Combustion Products Composition MW [kg/kmol] 44.00964 18.015324 64 28.0134 31.99886 Mass Basis [kg] 2.723 2.210 0.000 39.534 7.628 52.095 Mass Basis [kg/kg] 0.052 0.042 0.000 0.759 0.146 1.000 Mole Basis [kmol] 0.062 0.123 0.000 1.411 0.238 1.834 17.411 51.095
Combustion Products
Maximum 1,000
298
273
-0.0700
Combustion -- Coal/Oil
Stoichiometry [/] 1.0 1.5 2.0 2.5 3.0 CO2 [kg/kg] 0.249 0.171 0.130 0.105 0.088 H2O [kg/kg] 0.041 0.028 0.021 0.017 0.014 SO2 [kg/kg] 0.005 0.004 0.003 0.002 0.002 N2 [kg/kg] 0.705 0.724 0.735 0.741 0.745 O2 [kg/kg] 0.000 0.073 0.111 0.135 0.151
0.75
0.50
0.25
Stoichiometry [/]
CO2 H2O SO2 N2 O2
Combustion -- Coal/Oil
Stoichiometry [/] 1.0 1.5 2.0 2.5 3.0 CO2 [kmol/kmol] 0.170 0.115 0.087 0.070 0.059 H2O [kmol/kmol] 0.068 0.046 0.035 0.028 0.024 SO2 [kmol/kmol] 0.002 0.002 0.001 0.001 0.001 N2 [kmol/kmol] 0.759 0.769 0.774 0.777 0.779 O2 [kmol/kmol] 0.000 0.068 0.103 0.135 0.138
0.75
0.50
0.25
Stoichiometry [/]
CO2 H2O SO2 N2 O2
Combustion -- Coal/Oil
Stoichiometry [/] 1.0 1.5 2.0 2.5 3.0 Flame Temperature [K] 2,484 1,880 1,544 1,329 1,178 Oxidant to Fuel Ratio [/] 10.487 15.740 20.992 26.245 31.497
2000 1500
25
20
15
1000
500 0 1 1.5 2 2.5 3
10 5 0
Stoichiometry [/]
Flame Temperature Oxidant to Fuel Ratio
2500
30
298
273
-0.1617
Normal Shock
Input/Inlet Values: Output Values:
Working Fluid Kappa [/] Specific Heat [J/kg*K] Gas Constant [J/kg*K] Stagnation Temperature [K] Stagnation Pressure [atm] Velocity [m/s] Static Temperature [K] Static Pressure [atm] Mach Number [/]
Air 1.40 1,004.0 286.7 1,500.0 2.00 900.0 1,096.6 0.67 1.36 Stagnation Temperature [K] Stagnation Pressure [atm] Velocity [m/s] Static Temperature [K] Static Pressure [atm] Mach Number [/] 1,500.0 1.94 557.6 1,345.3 1.32 0.76
Normal Shock
Inlet Stagnation Temperature [K] 900.0 1,100.0 1,300.0 1,500.0 1,700.0 Inlet Stagnation Pressure [atm] Inlet Static Temperature [K] 496.6 696.6 896.6 1,096.6 1,296.6 Inlet Static Pressure [atm] 0.25 0.40 0.54 0.67 0.77
2.00
900.0 Air
Stagnation Inlet Static Temperature Temperature and and Pressure Pressure vs vs Static Inlet Temperature Stagnation Temperature
1,600 1,200 1,400 900 1,200 600 1,000 300 800 0 600 900 1100 800 1000 1300 1200 1500 1400 1700
1,800 1,500
2.5 1.0
Normal Shock
Inlet Stagnation Temperature [K] 900.0 1,100.0 1,300.0 1,500.0 1,700.0 Inlet Stagnation Pressure [atm] Inlet Mach Number [/] 2.02 1.70 1.50 1.36 1.25
2.00
900.0 Air
Mach Number Static Temperature Inlet Mach Number vs vs Inlet Stagnation Temperature
2.5 2.0
1.5
1.3
1.0 1.0
900 600
1100 800
1300 1000
1500 1200
1700 1400
Normal Shock
Inlet Stagnation Temperature [K] 900.0 1,100.0 1,300.0 1,500.0 1,700.0 Stagnation Pressure [atm] 2.00 Outlet Stagnation Temperature [K] 900.0 1,100.0 1,300.0 1,500.0 1,700.0 Outlet Stagnation Pressure [atm] 1.43 1.71 1.86 1.94 1.97 Velocity [m/s] Working Fluid 900.0 Air
Stagnation Stagnation Temperature Temperature and Pressure and Pressure vs Static vs Stagnation Temperature Temperature
1,600 1,700 1,400 1,400 1,200 1.5 1.6 1,100 1,000 800 600 900 1100 800 1000 1300 1200 1500 1400 1700 1.0 1.4 2.0 1.8
1,800 2,000
2.5 2.0
Normal Shock
Inlet Stagnation Temperature [K] 900.0 1,100.0 1,300.0 1,500.0 1,700.0 Stagnation Pressure [atm] 10.00 Outlet Static Temperature [K] 844.4 1,016.9 1,183.9 1,345.3 1,501.3 Outlet Static Pressure [atm] 1.14 1.30 1.34 1.32 1.28 Velocity [m/s] Working Fluid 900.0 Air
Stagnation Outlet Static Temperature Temperature and and Pressure Pressure vs vs Static Inlet Temperature Stagnation Temperature
1,600 1,400 1,400 1,200 1,200 1,000 1,000 800 600 900 1100 800 1000 1300 1200 1500 1400 1700 1.8 2.0 1.6 1.4 1.5 1.2 1.0
1,800 1,600
2.5 2.0
Normal Shock
Inlet Stagnation Temperature [K] 900.0 1,100.0 1,300.0 1,500.0 1,700.0 Inlet Stagnation Pressure [atm] Outlet Mach Number [/] 0.57 0.64 0.70 0.76 0.81
2.00
900.0 Air
Mach Number vs Static Temperature Outlet Mach Number vs Outlet Stagnation Temperature
1.0 2.0
0.0 1.0
900 600
1100 800
1300 1000
1500 1200
1700 1400
Thrust (Ideal)
Input Values: Output Values:
Working Fluid Kappa [/] Specific Heat [J/kg*K] Gas Constant [J/kg*K] Stagnation Temperature [K] Stagnation Pressure [atm] Velocity [m/s] Mass Flow Rate [kg/s] Ambient Pressure [atm]
Air 1.40 1,004.0 286.7 1,500.0 10.00 500.0 1.0 1.00 Static Temperature [K] Static Pressure [atm] Mach Number [/] Thrust [N] 1,375.5 7.38 0.67 1,181.9
Thrust (Ideal)
Stagnation Temperature [K] 700.0 900.0 1,100.0 1,300.0 1,500.0 Stagnation Pressure [atm] Ambient Pressure [atm] 10.00 1.00 Static Temperature [K] 575.5 775.5 975.5 1,175.5 1,375.5 Static Pressure [atm] 5.04 5.94 6.57 7.03 7.38 Velocity [m/s] Mass Flow Rate [kg/s] Working Fluid 500.0 1.0 Air
1,300 7 1,100 900 700 5 500 300 700 900 1100 1300 1500 4 6
Thrust (Ideal)
Stagnation Temperature [K] 700.0 900.0 1,100.0 1,300.0 1,500.0 Stagnation Pressure [atm] Ambient Pressure [atm] 10.00 1.00 Mach Number [/] 1.04 0.90 0.80 0.73 0.67 Thrust [N] 764.5 869.8 974.2 1,078.2 1,181.9 Velocity [m/s] Mass Flow Rate [kg/s] Working Fluid 500.0 1.0 Air
1.0 0.9 0.8 900 0.7 0.6 700 900 1100 1300 1500 700
Thrust [N]
1,100
Engineering Equations
Here are some of the basic engineering formulas/equations related to energy conversion systems which are built into the Engineering Software product line: Continuity Equation m = vA Momentum Equation F = (vm + pA)out - (vm + pA)in Energy Equation Q - W = ((h + v^2/2 + gh)m)out - ((h + v^2/2 + gh)m)in State Equation for Ideal Gas pv = RT/MW Perfect Gas cp = constant k = cp/cv Isentropic Compression T2/T1 = (p2/p1)^(k - 1)/k T2/T1 = (V1/V2)^(k - 1) p2/p1 = (V1/V2)^k Combustion h reactants = h products Isentropic Expansion T1/T2 = (p1/p2)^(k - 1)/k T1/T2 = (V2/V1)^(k - 1) p1/p2 = (V2/V1)^k
Sonic Velocity vs = (kRT/MW)^1/2 Mach Number M = v/vs Isentropic Flow Tt/T = (1 + M^2(k - 1)/2) pt/p = (1 + M^2(k - 1)/2)^k/(k - 1) ht = (h + v^2/2) Tt = (T + v^2/(2cp)) Cycle Efficiency Cycle Efficiency = Net Work/Heat Brayton Cycle Efficiency Brayton Cycle Efficiency = 1 - 1/(p2/p1)^(k - 1)/k Otto Cycle Efficiency Compression Ratio = V1/V2 Otto Cycle Efficiency = 1 - 1/Compression Ratio^(k - 1) Diesel Cycle Efficiency Compression Ratio (CR) = V1/V2 Cut-Off Ratio (COR) = V3/V2 Diesel Cycle Efficiency = 1 - (COR^k - 1)/(k*CR^(k - 1)(COR - 1)) Heat Rate Heat Rate = (1/Cycle Efficiency)*3,412 Thrust Thrust = vm + (p - pa)A
Physical Properties
For each reaction species, the thermodynamic functions specific heat, enthalpy and entropy as functions of temperature are given in the form of least squares coefficients as follows: Cp/R = A1 + A2*T + A3*T^2 + A4*T^3 + A5*T^4 H/(R*T) = A1 + A2*T/2 + A3*T^2/3 + A4*T^3/4 + A5*T^4/5 + A6/T S/R = A1*lnT + A2*T + A3*T^2/2 + A4*T^3/3 + A5*T^4/4 + A7 or S/R = A1*lnT + A2*T + A3*T^2/2 + A4*T^3/3 + A5*T^4/4 + A7 - lnp For each species, two sets of coefficients are included for two adjecent temperature intervals, 273 to 1,000 [K] and 1,000 to 5,000 [K]. The data have been constrained to be equal at 1,000 [K]. Also, U = H - p*v*MW or U = H - R*T G = H - S*T and u = h - p*v or u = h - R*T/MW g = h - s*T
Legend:
Cp -- Specific Heat [kJ/kmol*K] cp -- Specific Heat [kJ/kg*K] MW -- Molecular Weight [kg/kmol] R -- Universal Gas Constant [kJ/kmol*K] Gas Constant = R/MW [kJ/kg*K] H -- Enthalpy [kJ/kmol] h -- Enthalpy [kJ/kg] T -- Temperature [K] S -- Entropy [kJ/kmol*K] s -- Entropy [kJ/kg*K] p -- Pressure [atm] U -- Internal Energy [kJ/kmol] u -- Internal Energy [kJ/kg] V -- Volume [m^3] v -- Specific Volume [m^3/kg] G -- Gibbs Free Energy [kJ/kmol] g -- Gibbs Free Energy [kJ/kg]
Assumptions
This Engineering Software product allows quick and reliable calculation of thermodynamic and transport properties of gaseous, liquid and solid species, contains coefficients for the calculation of physical properties, steam approximations for both saturated and superheated areas, provides analyses of power cycles, power cycle components/processes and compressible flow. The aforementioned engineering calculations are valid under the following assumptions: Thermodynamic and Transport Properties Single species consideration Ideal gas approach is used (pv=RT) Specific heat is not constant Coefficients describing thermodynamic and transport properties were obtained from the NASA Glenn Research Center at Lewis Field in Cleveland, OH -- such coefficients conform with the standard reference temperature of 298.15 K (77 F) and the JANAF tables Power Cycles Single species consideration -- fuel mass flow rate ignored and its impact on the properties of the working fluid Basic equations hold (continuity, momentum and energy equations) Specific heat is constant Power Cycle Components/Processes Single species consideration Basic equations hold (continuity, momentum and energy equations) Specific heat is constant Compressible Flow Single specie sconsideration Basic equations hold (continuity, momentum and energy equations) Specific heat is constant
Disclaimer of Warranty
Engineering Software has made every effort to verify that this spreadsheet provides accurate, helpful information to assist you in carrying out your calculations. However, you must be aware that the information in this spreadsheet is sold to you "AS IS", without any warranty of any kind. The only exception is the 30-day warranty for replacement of defective disks. In no event shall Engineering Software be liable or responsible for any problems that arise because of the defects with this spreadshet. The ultimate responsibility for the accuracy of your calculations remains with the user.
License Agreement
This spreadsheet is the property of Engineering Software and is protected by federal copyright law. While Engineering Software continues to own the spreadsheet, you will have certain rights to use the spreadsheet after your acceptance of this license. Your rights and obligations with respect to the use of this spreadsheet are as follows: You may: use one copy of the spreadsheet on a single computer, make one copy of the spreadsheet for backup purposes and use the spreadsheet on a network, provided that you have a licensed copy of the spreadsheet for each computer that can access the spreadsheet over the network You may not: copy the documentation which accompanies the spreadsheet, sublicense, rent or lease any portion of the spreadsheet and reverse engineer, decompile, disassemble, modify, translate, make any attempt to discover the source code of the spreadsheet or create derivative works from the spreadsheet