NAME: Aaron Azose STUDENT ID: 106373

QUIZ SECTION: LAB PARTNER:

AH
Garrett Ballou

EXPERIMENT 2: STOICHIOMETRY
I. REACTION OF HYDROGEN PEROXIDE AND BLEACH II. REACTION OF IRON (II) WITH 1,10 PHENANTHROLINE
Grading: 30 pts for this template, 5 pts for notebook pages Notebook pages: Purpose/Method section complete? Are they organized and legible? Have you plotted your data as instructed?

Note: ALL sections of this report MUST be typed. With this and all future Excel-based reports, make sure that the report prints correctly (graphs, tables, and text boxes are not split across page breaks) before you turn it in. If you print it and it doesn't look okay, then use the tools in Excel to adjust the page breaks.
By signing below, you certify that you have not falsified data, that you have not plagiarized any part of this lab report, and that all calculations and responses other than the reporting of raw data are your own independent work. Failure to sign this declaration will cost you 5 points. Signature:

DATA, CALCULATIONS AND GRAPHS

Part I: Reaction Concentration of hydrogen of stock peroxide solutions and bleach
Bleach, NaOCl(aq) Hydrogen Peroxide, H2O2(aq) 6.0 3.0 %m/m NaOCl % m/m H2O2 2 pts

Mass of 0.500 mL Bleach, g 0.524 0.525 0.524 0.526 0.525 Average Density, g/mL

Density of Bleach, g/ml 1.05 1.05 1.05 1.05 1.05 1.05

Your values for mass and density should have 3 sig figs.

Run Number Run 1 Run 2 Run 3 Run 4 Run 5 Run 6 Run 7 Run 8 Run 9 Run 10 Run 11

mL of Bleach 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0

Grams of Hydrogen Peroxide 1.185 1.587 2.091 2.560 3.019 3.512 4.010 4.537

mL of Oxygen Generated 30.0 37.2 48.5 60.0 68.1 69.0 66.6 66.0

Put your Plot of Volume (mL) of O2 vs Mass (g) of H2O2 here. Make your graph big enough to cover this instruction box so that it is an appropriate size for someone else to read it.
80.0

Volume Oxygen Produced Vs Mass Hydrogen Peroxide

Use the online resources if you need help figuring out how to plot a graph in Excel. (See the links on the postlab page for this report.) 70.0
Volume of Oxygen Produced (mL)

Title the graph and label the X and Y axis, including the correct units. Be sure to double check your units and formatting once you60.0 print the report.
50.0 40.0

Using the line tool on the drawing toolbar, draw the two straight lines and read the intersection as best as you can.
2 pts

Identify and label the Equivalence point on your graph.

30.0 on your graph where the H O is the limiting reagent and where it is in excess. Indicate 2 2 20.0 10.0 0.0 0.000

0.500

1.000

1.500

2.000

2.500

3.000

3.500

4.000

4.500

5.000

Mass Hydrogen Peroxide (g)

Grams of H2O2 at the Eqv Point

2.9 g

1 pt

Moles H2O2 at the Eqv Point Moles NaOCl at the Eqv Point Stoichiometry: moles H2O2/moles NaOCl

0.0026 moles 0.0034 moles 0.76 1 pt

Type your calculation for the moles of H 2O2 at the equivalence point.
2.9g H2O2 x 1 mol H2O2 x 3.0% H2O2 34.016 g H2O2 H2O2 solution = .0026 mol H 2O2

4 pt

Type your calculation for the moles NaOCl at the equivalence point. 4.0 mL bleach x 1.05 g bleach x 6.0% NaOCl x 1 mol NaOCl mL bleach bleach 74.44 g NaOCl = .0034 mol NaOCl
4 pt

Part II: Iron(II) -Phenanthroline Reaction

Concentration of standard 1,10 phenanthroline solution Concentration of standard Fe(II) solution Volume of standard 1,10 phenanthroline solution you obtained 3.6 x 10-3 2.5 x 10-3 1.0 M M mL
1 pt 1 pt

Type your calculation of the moles of 1,10 phenanthroline that you transferred to the 50 mL volumetric flask. 1.0 mL phen solution x 1 L x 3.6 x 10-3 mol phen = 3.6 x 10-6 mol phen 1000 mL 1 L phen solution

2 pts

Volume of Fe(II) added, mL 0 100 200 300 400 500 600 700 800

Absorbance 0.001 0.001 0.038 0.086 0.136 0.172 0.165 0.169 0.169

Put your Absorbance vs mL Fe(II) here . Make your graph big enough to cover this instruction box so that it is an appropriate size for Absorbance versus Volume Fe(II) Added someone else to read it.
0.2

Use the online resources if you need help figuring out how to plot a graph in Excel. (See the links on the postlab page for 0.18 this report.)

Title 0.16 the graph and label the X and Y axis, including the correct units (Absorbance data is unitless). Be sure to double check your units and formatting once you print the report.
0.14

Using the line tool on the drawing toolbar, draw the two straight lines and read the intersection as best as you can.
Absorbance

0.12 0.1 0.08

0.06

Identify and label the Equivalence point on your graph.

2 pts

0.04 0.02 0 0 100 200 300 400 500 600 700 800 900 Volume Fe(II) Added (microliters)

mL of Fe(II) at the Equivalence Point

0.49 mL

1 pt

-6 Moles Fe(II) at the Eqv Point 1.2 x 10 -6 Moles phen at the Eqv Point 3.6 x 10

moles moles 3.0 1 pt

Stoichiometry: moles phen/moles Fe(II)

Type your calculation for the moles Fe 2+ at the equivalence point.

2 pt

.49 mL Fe(II) x 1 L x 2.5 x 1000 mL L

10-3 mol

= 1.2 x

10-6

mol Fe(II)

Type your calculation for the ratio of moles of phen to moles of Fe 2+ 3.6 x 10-6 moles phen = 3 moles phen 1.2 x 10-6 moes Fe(II) mole Fe(II)

Results and Discussion

Part I: 1. The expected stoichiometry is 1:1. How does your result compare (calculate the % error between your mole ratio and the e xpected - consult the "Intro" document online for this experiment for help)? Are you within 5% of this value? ( 1 pt) .76 - 1 = .24 = 24% This is not within 5% of the value. 1

2. What is your biggest source of error in this experiment? ( 1 pt) The biggest source of error in this experiment was the appearance of air bubbles in the flipping of the graduated cylinder. This led to uncertainty in the volume measurement, in which a slight error would have created a large variance in the equivalence point.

3. On the basis of the stoichiometry above, predict the other two products (O 2 was one of the products) and write a balanced equation for the reaction between H2O2 and NaOCl. (1 pt) H2O2 + NaOCl --> O2 + NaCl + H2O Part II 1. The expected stoichiometry is 3 phen:1 Fe(II). How does your result compare (calculate the % error between your mole rat io and the expected)? Are you within 5% of this value? (1 pt)

3.0 - 3 = 0% Yes, this is within 5% of the value. 3

2. What is your biggest source of error in this experiment? ( 1 pt) I had expected for there to be error associated with the oddity that occured at 0 and 100 microliters. For some reason, the value at 100 microliters read 0.001 absorbance. However, considering the error that would be associated given that our data was re -zeroed, I found that there would be no change in the calculated value for the volume produced, because if the points were all translated up by a constant, the equivalence point would occur at the same x-value. Thus, the error would be eliminated.

Laboratory Waste Evaluation (1 pt)

Laboratory waste is considered anything generated during an experiment that is disposed of down the sewer drain, thrown in the garbage, collected in a container for disposal by the UW Environmental Health & Safety department, or released into the environment. Based on the written lab procedure and your actions during the lab, list the identity and approximate amount (mass or volume) of waste that you generated while performing this experiment. .Volume of bleach used = 4mL x 8 runs + 2.5 mL = 34.5 mL Mass of hydrogen peroxide used = 22.501 g Volume of phen used = 1 mL Volume of Fe(II) used = .8 mL Water used = 50 mL + water used in tub + water used to wash = 5 L