222716954.xls.

ms_office

A
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66

M W as p e r TAB LE 1.
ID
1
2
3
4
5
6
7
8
9
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#

Component
CH4
Methane
C2H6 Ethane
C3H8 Propane
C4H10 N-Butane
C4H10 I-Butane
C5H12 N-Pentane
C5H12 I-Pentane
C5H12 2,2-Dimethylpropane
C6H14 N-Hexane
C6H14 2-Methylpentane
C6H14 3-Methylpentane
C6H14 2,2-Dimethylbutane
C6H14 2,3-Dimethylbutane
C7H16 N-Heptane
C8H18 N-Octane
C9H20 N-Nonane
C10H22N-Decane
C5H10 Cyclopentane
C6H12 Methylcyclopentane
C7H14 Ethylcyclopentane
C6H12 Cyclohexane
C7H14 Methylcyclohexane
C8H16 Ethylcyclohexane
C6H6 Benzene
C7H8 Toluene
C8H10 Ethylbenzene
C8H10 o-Xylene
C1H4O Methanol
C1H4S Methanethiol
H2
Hydrogen
H2O
Water
H2S
H2S
NH3
Ammonia
HCn
HCN
CO
CO
COS Carbonyl Sulfide
CS2
Carbon Disulfide
He
Helium
Ne
Neon
Ar
Argon
N2
Nitrogen
O2
Oxygen
CO2
CO2
SO2
SO2
N2O
Dinitrogen Monoxide
K
Krypton
Xe
Xenon
Air

72
73
74
75
76
77 CV: v o l
78
79 CV: v o l
80
81 CV: mas s

TOTAL Mole%

M o le %
86.978821
7.101859
2.094905
0.386079
0.218057
0.066633
0.064865
0
0.046202

0.862475
2.179687

Normalised
Mole%
0.86979
0.07102
0.02095
0.00386
0.00218
0.00067
0.00065
0
0.00046
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.00862
0
0.0218
0
0
0
0
0

99.999583

Normalised
Mass%
Unrounded-Rounded mole*mw
74.620169
-0.00024
13.95407
11.419908
-0.00036 2.1355379
4.9400405
-0.00048 0.9237941
1.2000002
0.0004 0.2244016
0.6777588
0.0004 0.1267418
0.2570886
0.00028 0.0480759
0.2502672
0.00028 0.0468003
0
0.00028
0
0.2129165
0.00016 0.0398157
0
0.00016
0
0
0.00016
0
0
0.00016
0
0
0.00016
0
0
4E-05
0
0
-8E-05
0
0
-0.0002
0
0
-0.00032
0
0
0.0004
0
0
0.00028
0
0
0.00016
0
0
0.00028
0
0
0.00016
0
0
4E-05
0
0
-0.00036
0
0
-0.00048
0
0
0.0004
0
0
0.0004
0
0
0.00016
0
0
-0.00024
0
0
-2E-05
0
0
-2E-05
0
0
-0.00012
0
0
-4E-05
0
0
-0.00032
0
0
0.0004
0
0
0.0004
0
0
0
0
0
0
0
0
0
0
0
0
0
1.2920253
-2E-05 0.2416104
0
0
0
5.129826
-0.0002 0.9592842
0
-0.0002
0
0
0
0
0
-83.8
0
0
-131.29
0
0
-28.9626
0

Rel Mol Mass

18.70013245 using Table 1

T crit (K)
P crit (kPa)
Xi Summ Factors

206.3062967
4654.233683
0.051574154

Z mix (15C,1bar)

0.997340107

RD Ideal
RD real

0.645664838
0.647114916

100

0.7929809 kg/m3

Hs(15,15) (MJ/m3)
Hi(15,15) (MJ/m3)

40.46989752 Ideal Sup

36.56526323 Ideal Inf

Using Table 3
40.57783022 Real Sup
Using Table 5
Hs(15,15) (MJ/m3)
40.57805207 Real Sup

ID
1
2
3
4
5
6
7
8
9
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#
#

KEL

N O P Q R S

T
R
k0
k 15
k25

AA

AB

8.31451 J/mol/K Gas Const 0.00007

0.04461
0.04229 Factors to convert CV in kJ/mol to MJ/m3
0.04087

AC

AD

MM air
28.9626
Z air (15C,1bar)
0.99958
Density (15C)
1.22541

ISO 6976:1995
Composition
C H O N
1 4
2 6
3 8
4 #
4 #
5 #
5 #
5 #
6 #
6 #
6 #
6 #
6 #
7 #
8 #
9 #
# #
5 #
6 #
7 #
6 #
7 #
8 #
6 6
7 8
8 #
8 #
1 4 1
1 4
2
2 1
2
3
1
1 1
1
1
1
1
1
1

1
2

2
1

2
2
2
1

1
2

132.55

3769

313

92.5

0.316

0.9996

10.1

18.6998864 using "un-rounded" Table 1

-0.0013157 %diff from Table 1

-100 %errors

-100

-100

-100

FisCal

KEL

S500

%errors

-100
-100

-100
-100

-100
-100

%errors from Table 3Table 3 figures are the "preferred option".

Table 5 figures are derived from Table 3 and then rounded to 2 decimal
%errors from Table 5

-100

-100

-100

%errors.

-100

%errors.

Hs(15,15) (MJ/m3)

Hs(15,15) (MJ/kg)

Wobbe (MJ/m3)

Hi(15,15) (MJ/m3)
Hi(15,15) (MJ/m3)

places.

51.17125798 Real Sup

50.44267572

Using Table 3
36.66278232 Real Inf
Using Table 5
36.66324661 Real Inf

-100

-100

FisCal

KEL

S500

-100
-100

-100
-100

-100
-100

AF

AG

AH

AI

AJ

AK

AL

AM

AN

kg/kmol
kg/m3

Figures in this colour from GERG Technical Monograph TPC/1 (1986)

ISO 6976:1995
kJ/mol
T crit(K) P crit (kPa) D crit kg/m3mVol crit cm3/mol
Comprs critAcentric Factor
Comp(15, 1.01325bar)
Summ Factor
2nd
(15C,101.325kPa)
Virial Coeff
CVsup25
(@15C
CVinf25
, cm3/mol)CVsup20 CVinf20
CVsup15 CVinf15
CVsup0
CVinf0
190.555
4598.8
164.1
97.76
0.284
0.0115
0.9980
0.0447
47
890.63
802.60
891.09
802.65
891.56
802.69
892.97
802.82
305.83
4880
203
148.1
0.284
0.0908
0.9915
0.0922
199.1
1560.69
1428.64
1561.41
1428.74
1562.14
1428.84
1564.34
1429.12
369.82
4250
217
203.2
0.281
0.1454
0.9821
0.1338
415
2219.17
2043.11
2220.13
2043.23
2221.10
2043.37
2224.01
2043.71
425.14
3784
228
254.9
0.273
0.1928
0.9650
0.1871
799
2877.40
2657.32
2878.57
2657.45
2879.76
2657.60
2883.82
2658.45
408.13
3648
221
263
0.283
0.1756
0.9680
0.1789
738
2868.20
2648.12
2869.38
2648.26
2870.58
2648.42
2874.20
2648.83
469.69
3364
232
311
0.268
0.251
0.9370
0.251
1398
3535.77
3271.67
3537.17
3271.83
3538.60
3272.00
3542.89
3272.45
460.39
3381
236
305.7
0.27
0.2273
0.9480
0.228
1170
3528.83
3264.73
3530.24
3264.89
3531.68
3265.08
3535.98
3265.54
433.75
3199
238
303.2
0.269
0.197
0.9550
0.2121
1027
3514.61
3250.51
3516.01
3250.67
3517.43
3250.83
3521.72
3251.28
506.4
3030
233
369.9
0.266
0.2957
0.9130
0.295
2053
4194.95
3886.84
4196.58
3887.01
4198.24
3887.21
4203.23
3887.71
497.5
3010
235
366.7
0.267
0.2791
0.9140
0.2933
1853
4187.32
3879.21
4188.95
3879.38
4190.62
3879.59
4195.61
3880.09
504.4
3120
235
366.7
0.273
0.275
0.9170
0.2881
1809
4189.90
3881.79
4191.54
3881.97
4193.22
3882.19
4198.24
3882.72
488.7
3080
240
359.1
0.272
0.231
0.9310
0.2627
1626
4177.52
3869.41
4179.15
3869.59
4180.83
3869.80
4185.84
3870.32
499.9
3130
241
357.6
0.269
0.2473
0.9250
0.2739
1634
4185.28
3877.17
4186.93
3877.36
4188.60
3877.57
4193.63
3878.11
539.2
2740
232
431.9
0.264
0.3506
0.8660
0.3661
3165
4853.43
4501.30
4855.29
4501.49
4857.18
4501.72
4862.87
4502.28
568.4
2490
232
492.4
0.259
0.3942
0.8020
0.445
4687
5511.80
5115.66
5513.88
5115.87
5516.01
5116.11
5522.40
5116.73
594.4
2280
232
552.8
0.255
0.4437
0.7100
0.5385
6855
6171.15
5730.99
6173.46
5731.22
6175.82
5731.49
6182.91
5732.17
617.8
2090
233
610.7
0.248
0.4902
0.5840
0.645
9826
6829.77
6345.59
6832.31
6345.85
6834.90
6346.14
6842.69
6346.88
511.61
4502
270
259.8
0.275
0.1923
0.9470
0.2302
1248
3319.59
3099.51
3320.88
3099.76
3322.19
3100.03
3326.14
3100.77
532.73
3784
264
318.8
0.272
0.2395
0.9210
0.2811
1860
3969.44
3705.34
3970.93
3705.59
3972.46
3705.86
3977.04
3706.60
569.46
3397
262
374.8
0.269
0.2826
0.8760
0.3521
2938
4628.47
4320.36
4630.19
4320.63
4631.95
4320.92
4637.27
4321.75
553.5
4074
271.8
309.6
0.274
0.2144
0.9180
0.2864
1936
3952.96
3688.86
3954.47
3689.13
3956.02
3689.42
3960.67
3690.23
572.12
3471
267
367.7
0.268
0.2333
0.8860
0.3376
2699
4600.64
4292.53
4602.35
4292.78
4604.09
4293.06
4609.34
4293.82
609
3040
250
449
0.269
0.2426
0.8240
0.4195
4167
5263.05
4910.92
5264.98
4911.19
5266.95
4911.49
5272.88
4912.29
562.16
4898
304.4
256.6
0.269
0.21
0.9260
0.272
1613
3301.43
3169.38
3302.15
3169.48
3302.86
3169.56
3305.03
3169.81
591.8
4106
291.3
316.3
0.264
0.2566
0.8830
0.3421
2770
3947.89
3771.83
3948.84
3771.95
3949.81
3772.08
3952.72
3772.42
617.2
3606
283.5
374.5
0.263
0.3011
0.8230
0.4207
4197
4607.15
4387.07
4608.32
4387.20
4609.53
4387.37
4613.14
4387.77
630.33
3734
288
368.6
0.263
0.3136
0.8040
0.4427
4628
4596.31
4376.23
4597.46
4376.34
4598.64
4376.48
4602.17
4376.80
512.64
8092
272
117.8
0.224
0.556
0.8720
0.3578
2633
764.09
676.06
764.59
676.14
765.09
676.22
766.59
676.44
470
7230
332
144.9
0.268
0.153
0.9770
0.1517
547
1239.39
1151.36
1239.83
1151.39
1240.28
1151.41
1241.63
1151.48
33.2
1297
31
65
0.306
-0.218
1.0006
-0.0048
-14
285.83
241.81
285.99
241.76
286.15
241.72
286.63
241.56
647.14
22064
332
55.9
0.229
0.328
0.9450
0.2345
1224
44.02
0.00
44.22
0.00
44.43
0.00
45.07
0.00
373.2
8940
346
98.5
0.284
0.109
0.9900
0.1
229
562.01
517.99
562.19
517.97
562.38
517.95
562.94
517.87
405.5
11350
235
72.5
0.244
0.25
0.9880
0.1095
282
382.81
316.79
383.16
316.82
383.51
316.86
384.57
316.96
456.7
5390
195
138.6
0.197
0.388
0.9120
0.2966
1900
671.50
649.50
671.60
649.50
671.70
649.50
671.90
649.40
132.85
3494
304
92.2
0.291
0.053
0.9995
0.0224
10.5
282.98
282.98
282.95
282.95
282.91
282.91
282.80
282.80
378.8
6349
445
135.1
0.272
0.096
0.9870
0.114
298
548.23
548.23
548.19
548.19
548.15
548.15
548.01
548.01
552
7900
440
173.1
0.298
0.109
0.9620
0.1949
875
1104.49
1104.49
1104.41
1104.41
1104.32
1104.32
1104.06
1104.06
0
5.19
227
70
57.2
0.301
-0.365
1.0005
0.0002
-11.9
0
44.4
2760
484
41.7
0.312
-0.029
1.0005
0.0002
-11.2
0
150.65
4866
529.1
75.5
0.293
0.001
0.9992
0.0283
18.2
0
126.2
3390
313
89.5
0.289
0.039
0.9997
0.0173
7.1
0
154.58
5043
436
73.4
0.288
0.025
0.9992
0.0283
18.4
0
304.2
7386
468
94
0.275
0.239
0.9944
0.0748
132.3
0
430.8
7884
525
122
0.269
0.256
0.9790
0.1449
484

S500
-100

AE

just
TAB LE 5
comparing
M J /m3
Component Table 5 CVsup15 CVinf15
Methane
37.7061
37.706
33.948
Ethane
66.0665
66.07
60.43
Propane
93.9354
93.94
86.42
N-Butane
121.792
121.79
112.4
I-Butane
121.403
121.4
112.01
N-Pentane 149.656
149.66
138.38
I-Pentane
149.363
149.36
138.09
Neo-Pentane 148.76
148.76
137.49
N-Hexane
177.553
177.55
164.4
2-Methylpentane
177.231
177.23
164.08
3-Methylpentane
177.341
177.34
164.19
2,2-Dimethylbutane
176.817
176.82
163.66
2,3-Dimethylbutane
177.146
177.15
163.99
N-Heptane 205.421
205.42
190.39
N-Octane
233.285
233.28
216.37
N-Nonane
261.19
261.19
242.4
N-Decane 289.064
289.06
268.39
Cyclopentane140.503
140.5
131.11
Methylcyclopentane
168.004
168
156.73
Ethylcyclopentane
195.896
195.9
182.74
Cyclohexane167.309
167.31
156.03
Methylcyclohexane
194.718
194.72
181.56
Ethylcyclohexane
222.751
222.75
207.72
Benzene
139.686
139.69
134.05
Toluene
167.047
167.05
159.53
Ethylbenzene194.948
194.95
185.55
o-Xylene
194.487
194.49
185.09
Methanol
32.3574
32.36
28.6
Methanethiol52.4543
52.45
48.7
Hydrogen
12.1019
12.102
10.223
Water
1.87917
1.88
0
H2S
23.7843
23.78
21.91
Ammonia
16.2195
16.22
13.4
HCN
28.4077
28.41
27.47
CO
11.9649
11.96
11.96
Carbonyl Sulfide
23.1825
23.18
23.18
Carbon Disulfide
46.7042
46.7
46.7
Helium
0
Neon
0
Argon
0
Nitrogen
0
Oxygen
0
CO2
0
SO2
0
Dinitrogen Monoxide
Krypton
Xenon
Air

AO

AP AQ

AR

AS

%errors from Table 3

%errors from Table 5

Page 1

AT

AU

Atomic Weights
Carbon
12.011
Hydrogen
1.00794
Oxygen
15.9994
Nitrogen
14.0067
Sulphur
32.066
ISO 6976 - 1983
ID Component
Mole% Normalised
Methane
86.9788
0.86979
Ethane
7.10186
0.07102
Propane
2.09491
0.02095
N-Butane
0.38608
0.00386
I-Butane
0.21806
0.00218
N-Pentane
0.06663
0.00067
I-Pentane
0.06487
0.00065
Neo-Pentane
0
0
N-Hexane
0.0462
0.00046
2-Methylpentane
0
0
3-Methylpentane
0
0
2,2-Dimethylbutane 0
0
2,3-Dimethylbutane 0
0
N-Heptane
0
0
2-Methylhexane
0
3-Methylhexane
0
N-Octane
0
0
N-Nonane
0
0
N-Decane
0
0
2,2,4-Trimethylpentane
0
Cyclohexane
0
Methylcyclohexane
0
Benzene
0
0
Toluene
0
0
Hydrogen
0
0
CO
0
0
H2S
0
0
Helium
0
0
Argon
0
0
Nitrogen
0.86248
0.00862
Oxygen
0
0
CO2
2.17969
0.0218
Water
0
0
Air
0
0

AV

AW

AX

Table 2
(15,1.01325)
Molec WeightIdeal RD Ideal Density
16.04260
0.5539
0.6785
30.06940
1.0382
1.2717
44.09620
1.5224
1.865
58.12300
2.0067
2.4582
58.12300
2.0067
2.4582
72.14980
2.491
3.0514
72.14980
2.491
3.0514
72.14980
2.491
3.0514
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
86.17660
2.9753
3.6477
#######
3.4596
4.2379
#######
3.4596
4.2379
#######
3.4596
4.2379
#######
3.9439
4.8312
####### 4.42816
####### 4.91245
#######
3.9439
4.8312
84.16080
2.9057
3.5593
98.18760
3.39
4.1527
78.11340
2.6969
3.3037
92.14020
3.1812
3.8963
2.01580
0.0696
0.0852
28.01040
0.9671
1.1846
34.07600
1.1765
1.4412
4.00260
0.1382
0.1693
39.94800
1.3792
1.6895
28.01340
0.9672
1.1848
31.99880
1.1048
1.3533
44.00980
1.5195
1.8613
18.01520
0.622
0.7619
28.96410
1
1.225

TOTAL

99.9996

Molec Wieght

18.6997

Ideal Density
Summation

0.79088 C9&C10 have zero value at the moment

0.05145

Zmix

0.99735

CV Sup (Ideal)
CV Sup (Real)

40.4597
40.5671 MJ/m3

Ideal RD
Real RD

0.64564
0.64708

Wobbe (MJ/m3)

50.4307

#VALUE!
Rel Mol Mass

FisCal

L
Atomic Weight
12.011
1.00794
15.9994
14.00674
32.066

Component
Molec Weight Un-rounded Molecular Weight
16.043
16.04276
Methane
30.07
30.06964
Ethane
44.097
44.09652
Propane
58.123
58.1234
N-Butane
58.123
58.1234
I-Butane
72.15
72.15028
N-Pentane
72.15
72.15028
I-Pentane
72.15
72.15028
Neo-Pentane
86.177
86.17716
N-Hexane
86.177
86.17716
2-Methylpentane
86.177
86.17716
3-Methylpentane
86.17716
2,2-Dimethylbutane 86.177
86.17716
2,3-Dimethylbutane 86.177
100.204
100.20404
N-Heptane
114.231
114.23092
N-Octane
128.258
128.2578
N-Nonane
142.285
142.28468
N-Decane
70.134
70.1344
Cyclopentane
84.16128
Methylcyclopentane 84.161
98.188
98.18816
Ethylcyclopentane
84.161
84.16128
Cyclohexane
98.188
98.18816
Methylcyclohexane
112.215
112.21504
Ethylcyclohexane
78.114
78.11364
Benzene
92.141
92.14052
Toluene
106.167
106.1674
Ethylbenzene
106.167
106.1674
o-Xylene
32.042
32.04216
Methanol
48.109
48.10876
Methanethiol
2.0159
2.01588
Hydrogen
18.0153
18.01528
Water
34.082
34.08188
H2S
17.0306
17.03056
Ammonia
27.026
27.02568
HCN
28.01
28.0104
CO
60.076
60.0764
Carbonyl Sulfide
76.143
76.143
Carbon Disulfide
4.0026
4.0026
Helium
20.1797
20.1797
Neon
39.948
39.948
Argon
28.0135
28.01348
Nitrogen
31.9988
31.9988
Oxygen
44.01
44.0098
CO2
64.065
64.0648
SO2
44.0129
Dinitrogen Monoxide 44.0129
83.8
Krypton
131.29
Xenon
28.9626
Air

18.700132

-100
STD Density (Real)

K
Carbon
Hydrogen
Oxygen
Nitrogen
Sulphur

ISO 6976 1983 (Tw e ak e d f o r C9 & C10) s t ar t s at c o lu mn AO

67
68
69
70
71

82
83
84
85
86
87
88
89
90
91
92

ISO 6976 - 1995

Other data source - GERG Technical Monograph No. TPC/1 (1986)

BG
38.9038
-4.10006

S500
38.902
-4.10452 %errors

AY

AZ

BA

BB

BC

BD

BE

Table 6
Table 8
CV Hsup
CV Hinf Z (15,1.01325)
Summation Component
37696
33938
0.998
0.0447 Methane
66035
60397
0.9914
0.0927 Ethane
93975
86459
0.9806
0.1393 Propane
121782
112387
0.9634
0.1913 N-Butane
121428
112034
0.9659
0.1847 I-Butane
149676
138402
0.944
0.2366 N-Pentane
149336
138062
0.9499
0.2238 I-Pentane
148850
137576
0.9579
0.2052 Neo-Pentane
177556
164401
0.9115
0.2975 N-Hexane
177230
164075
0.9198
0.2832 2-Methylpentane
177342
164187
0.9193
0.2841 3-Methylpentane
176837
163683
0.9307
0.2632 2,2-Dimethylbutane
177179
164024
0.9245
0.2748 2,3-Dimethylbutane
205432
190398
0.8653
0.367 N-Heptane
205133
190099
0.8781
0.3491 2-Methylhexane
205276
190242
0.8781
0.3491 3-Methylhexane
233287
216374
0.7986
0.4488 N-Octane
#######
0.7100
0.5385 N-Nonane
#######
0.5840
0.645 N-Decane
232645
215732
0.8611
0.3727 2,2,4-Trimethylpentane
167311
156037
0.9183
0.2858 Cyclohexane
194722
181569
0.8811
0.3448 Methylcyclohexane
139694
134057
0.9277
0.2689 Benzene
167054
159537
0.8824
0.3429 Toluene
12102
10223
1.0006
0 Hydrogen
11966
11966
0.9995
0.0224 CO
23807
21967
0.9904
0.098 H2S
1.0005
-0.016 Helium
0.9992
0.0283 Argon
0.9997
0.0173 Nitrogen
0.9993
0.0265 Oxygen
0.9943
0.0614 CO2
0.971
0.17 Water
0.99958
0 Air

BF