File No. Iit - 260-27 CPT - 25 - (12 STD) New - MPC - 17-11-08 - Q.P.

FILE NO.
IIT- 260/27(15/11/2008)
CODE SHAKUNTAL

NARAYANA
I I T A C A D E M Y
Common Pr act i ce Test 25
XII STD NEW [89 Batches]
Test Dat e: 17
t h
Nov. 2008.
Ti me: 3 hours M!i mum mr"s: 2#6
$%ese re& 'he i(s'ru)'io(s )re*u%%+. ,ou re %%o''e& 5 mi(u'es s-e)i*i)%%+ *or 'his -ur-ose.
INSTRUCTIONS
A. Genera:
1. This booklet is your Question Paper containing 69 questions. The
booklet has 17 pages.
2. The question paper COD is printe! on the right han! top corner o"
this booklet.
#. $lank papers% clipboar!s% log tables% sli!e rules% calculators% cellular
phones% pagers% an! electronic ga!gets in any "or& are not allo'e!
to be carrie! insi!e the e(a&ination hall.
). The ans'er sheet% a &achine*rea!able Ob+ecti,e -esponse .heet
/O-.0% is pro,i!e! separately.
1. DO 2OT T34P- 56T7 8 49T6:3T T7 O-. O- T7
$OO;:T.
!. "##n$ the ORS
6. On the lo'er part o" the O-.% 'rite in ink% your na&e in bo( :1%
your -egistration 2o. in bo( :2 an! 2a&e o" the Centre in bo( :#.
Do not %r#te these an&%here ese.
7. 5rite your -egistration 2o. in ink% in the bo( :) pro,i!e! in the
lo'er part o" the O-. an! !arken the appropriate bubble UNDER
each !igit o" your -egistration 2o. 'ith a goo! quality 7$ pencil.
<. The O-. has a CODE printe! on its lo'er an! upper parts.
9. 4ake sure the COD on the O-. is the sa&e as that on this booklet
an! put your signature in ink in bo( :1 on the O-. a""ir&ing that
you ha,e ,eri"ie! this.
1=. 6> T7 COD. DO 2OT 43TC7% 3.; >O- 3 C732? O>
T7 $OO;:T.
C. '(est#on )a)er *or+at:
11. The question paper consists o" , )arts -.art I: Mathe+at#/s0 .art
II: .h&s#/s0 .art III: Che+#str&1. ach part has ) sections.
12. Se/t#on I contains 6 &ultiple choice questions. ach question has )
choices /30% /$0% /C0 an! /D0% out o" 'hich on& one #s /orre/t.
1#. Se/t#on II contains ) &ultiple correct ans'er type questions. ach
questions has ) choices /30% /$0% /C0 an! /D0% out o" 'hich one or
&ore ans'ers are correct.
1). Se/t#on III contains ) -easoning type questions. ach question
contains .T3T42T*1 32D .T3T42T*2.
$ubble /30 i" both the state&ents are T-9 an! .T3T42T*2
is the correct e(planation o" .T3T42T*1.
$ubble /$0 i" both the state&ents are T-9 but .T3T42T*2
is 2OT the correct e(planation o" .T3T42T*1.
$ubble /C0 i" .T3T42T*1 is T-9 an! .T3T42T*2 is
>3:..
$ubble /D0 i" .T3T42T*1 is >3:. an! .T3T42T*2 is
T-9.
11. Se/t#on I2 contains # sets o" :inke!*Co&prehension type question.
ach set consists o" a paragraph "ollo'e! by # questions. ach
question has ) choices /30% /$0% /C0 an! /D0% out 'hich on& one #s
/orre/t.
D. Mar3#n$ S/he+e:
16. >or each questions in Se/t#on I% you 'ill be a%ar4e4 , +ar3s i"
you ha,e !arkene! only the bubble correspon!ing to the correct
ans'er an! @ero &ark i" no bubble is !arkene!. 6n all other cases%
+#n(s one -511 +ar3 'ill be a'ar!e!.
17. >or each question in Se/t#on II% you 'ill be a%ar4e4 6 +ar3s i"
you ha,e !arkene! all the bubble/s0 correspon!ing to the correct
ans'er an! @ero &ark "or all other cases. 6" &ay be note! that there
is no ne$at#ve +ar3#n$ *or %ron$ ans%er.
1<. >or each question in Se/t#on III% you 'ill be a%ar4e4 , +ar3s i"
you !arken only the bubble correspon!ing to the correct ans'er an!
@ero &ark i" no bubble is !arkene!. 6n all other cases% +#n(s one -5
11 +ar3 'ill be a'ar!e!.
19. >or each question in Se/t#on I2% you 'ill be a%ar4e4 6 +ar3s i"
you !arken only the bubble correspon!ing to the correct ans'er an!
7ero +ar3 i" no bubble is !arkene!. 6n all other cases% +#n(s one -5
11 +ar3 %# 8e a%ar4e4
Na+e o* the St(4ent Ro N(+8er
I have rea4 a the #nstr(/t#ons an4 sha a8#4e 8& the+
AA..AAAAAAAAAAAAAAAAAAAAA
S#$nat(re o* the Can4#4ate
I have ver#*#e4 a the #n*or+at#on *#e4 #n 8& the
Can4#4ate
AAAAAAAAAAAAAAAAAAAAA..
S#$nat(re o* the Inv#$#ator
South Delhi )7*$% ;alu .arai% 2e' Delhi * 11==16 Ph.B =11*)6=<=61281#81)
No!th"West Delhi 11% Central 4arket% 5est Pun+abi $agh% 2e' Delhi * 11==26 Ph.B =11*)1=6261181281#
East Delhi #2C% Patpargan+ Dillage% 4ayur Dihar Phase * 6% Delhi * 11= =91 Ph.B =11*2271==)#812
#u!$ao% 4*21% Ol! D:> Colony% .ector*1)% ?urgaon Ph.B =12)*#217791892
D&a!'a #178#1<% Dikas .urya ?ala(y% 4ain 4kt% .ector*)% D'arka% 2e' Delhi * 11= =71 Ph.B =11*)162172)821
(a!i)a*a) .COC27% 66n! >loor% .ector * 16% >ari!aba!% 7aryana * 121==2 Ph.B =122C)=7)626% )=669#<
+ATHE+ATI CS
.ART 5 I
SECTION 5 I
Stra#$ht O89e/t#ve T&)e
This section contains 6 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D), out of
which ONLY ONE is correct.
1. 6n triangle 3$C% rightCangle! at C% tan3 E tan$ is equal to
/30 a E b /$0
2
c
ab
/C0
2
a
bc
/D0
2
b
ac

2. 6" sin ( E sin
2
( F 1% then the ,alue o" cos
12
( E # cos
1=
( E # cos
<
( E cos
6
( * 1 is equal to
/30 = /$0 1
/C0 * 1 /D0 2
#. The ,alue o"
cos ycos ( cos y cos ( sin ycos ( cos (sin y
2 2 2 2

_ _ _ _
+ +

, , , ,
is
@ero i"
/30 ( F = /$0 y F =
/C0 ( F y /D0 ( n y/n 60
)
+
). 6" sin 3 F sin $ an! cos 3 F cos $% then
/30 sin /1820 /3 * $0 F = /$0 sin /1820 /3 E $0 F =
/C0 cos /1820 /3 * $0 F = /D0 cos /1820 /3 E $0 F =
1. 3 &an is kno'n to speak the truth # out o" ) ti&es. 7e thro's a !ie an! reports that it is a
si(. The probability that it is actually a si( is
/30
#
<
/$0
1
1
/C0
#
)
/D0 none o" these
6. There are t'o balls in an urn 'hose colours are not kno'n /each ball can be either 'hite or
black0. 3 'hite ball is put into the urn. 3 ball is !ra'n "ro& the urn. The probabiloity that it
is 'hite is
/30 18) /$0 18#
/C0 28# /D0 181
SECTION 5 II
M(t#)e Corre/t Ans%er T&)e
This section contains 4 multiple correct answer(s) tpe questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE OR MORE is!are correct.
7. 6" 3 an! $ are t'o in!epen!ent e,ents such that P/30 F 182 an! P/$0 F 181% then
/30 P/3 $0 F #81 /$0 P/3 G $0 F 182
/C0 P/3G3 $0 F 186 /D0 P/3 $ G 3 $0H F =
<. >or t'o e,ents 3 an! $% i" P/30 F P/3 G $0 F 18) an! P/$ G30 F 182% then
/30 3 an! $ are in!epen!ent /$0 3 an! $ are &utually e(clusi,e
/C0 P/3 G $0 F #8) /D0 P/$ G 30 F 182
9. 6" ( F sec tan an! y F cosec E cot % then
/30
y 1
(
y 1
+
/$0
y 1
(
y 1
+
/C0
1 (
(
1 (
+
/D0 ( y E ( * y E 1 F =
1=. 6" = I % I an! cos E cos cos / E 0 F #82 then
/30
#
/$0
#

/C0 F /D0
#
+
SECTION 5 III
Reason#n$ T&)e
This section contains 4 reasonin" tpe questions. Each question has 4 choices (A), (B), (C) and (D), out of
CODE
-A1 STATEMENT51 #s Tr(e0 STATEMENT52 #s Tr(e: STATEMENT52 #s a /orre/t e;)anat#on *or STATEMENT51
-!1 STATEMENT51 #s Tr(e0 STATEMENT52 #s Tr(e: STATEMENT52 #s NOT a /orre/t e;)anat#on *or STATEMENT51
-C1 STATEMENT51 #s Tr(e0 STATEMENT52 #s "ase
-D1 STATEMENT51 #s "ase0 STATEMENT52 #s Tr(e
11. State+ent 5 1: 3 F J2% )% 6K % $ F J1% 2% #% K 'here 3 L $ are the nu&ber occuring on a
!ice% then P/30 E P/$0 F 1
!e/a(se
State+ent 5 2: 6" 3
1
% 3
2
% 3
#
... 3
n
are all &utually e(clusi,e e,ents% then
P/3
1
0 E P/3
2
0 E ... E P/3
n
0 F1.
12. State+ent 5 1: 6" P/38$0 P/30 then P/$830 P/$0
!e/a(se
State+ent 5 2: P/38$0 F
P/3 $0
P/$0
1,. State+ent 5 1: $alls are !ra'n one by one 'ithout replace&ent "ro& a bag containing a
'hite an! b black balls% then probability that 'hite balls 'ill be "irst to e(haust is a8aEb.
!e/a(se
State+ent 5 2: $alls are !ra'n one by one 'ithout replace&ent "ro& a bag containing a
'hite an! b black balls then probability that thir! !ra'n ball is 'hite is a8aEb.
16. State+ent 5 1: Out o" 1 tickets consecuti,ely nu&bers% three are !ra'n at ran!o&% the
chance that the nu&bers on the& are in 3.P. is 2811.
!e/a(se
State+ent 5 2: Out o" /2n E 10 tickets consecti,ely nu&bere!% three are !ra'n at ran!o&% the
chance that the nu&bers on the& are in 3.P. is
2
#n
)n 1
.
SECTION 5 I2
<#n3e4 Co+)rehens#on T&)e
This section contains # para"raphs. Based upon each para"raph, # multiple choice questions ha$e to %e
answered. Each question has 4 choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
.ara$ra)h *or '(est#ons Nos. 1= to 17
% % % are angles in 6% 66% 666 an! 6D qua!rant respecti,ely an! no one o" the& is an integral
&ultiple o" 82. They "or& an increasing arith&etic progression.
11. 5hich one o" the "ollo'ing is correct
/30 cos / E 0 M = /$0 cos / E 0 F =
/C0 cos / E 0 I = /D0 cos / E 0 M = or cos / E 0 I =
16. 5hich one o" the "ollo'ing is correct
/30 sin / E 0 F sin / E 0 /$0 sin / 0 F #sin / 0
/C0 tan 2/ 0 F )tan / 0 /D0 cos / E 0 F 1cos 2
17. 6" E E E F an! F 7=N%
/30 )==N I I 1<=N /$0 )7=N I I 61=N
/C0 6<=N I I <6=N /D0 1)=N I I 9==N
Paragraph for Questions Nos. 18 to 20
3 class consists o" n stu!ents. >or = k n% let
k
!enote the e,ent that e(actly k stu!ent out o" n
pass in the e(a&ination. :et P/
k
0 F p
k
an! let 3 !enote the e,ent that a stu!ent O selecte! at ran!o&
pass in the e(a&ination.
1<. 6" P/
k
0 F C "or = k n% then P/30 equals
/30 182 /$0 28#
/C0 186 /D0 18/n E 10
19. 6" P/
k
0 F C "or = k n% then the probability that O is the only stu!ent to pass the
e(a&ination is
/30 #8)n /$0 28/n E 10
/C0 28n/n E 10 /D0 #n/n E 10
2=. 6" P/
k
0 k "or = k n% then P/30 equals
/30 #8n/n E 10 /$0 /2n E 108#n
/C0 18/n E 10 /D0 18n
2
Paragraph for Questions Nos. 21 to 23
.uppose
1
%
2
%
#
be three &utually e(clusi,e e,ents such that P/
i
0 F p
i
"or i F 1% 2% #.
21. 6" p
1
F
1
2
/1 * p0% p
2
F
1
#
/1 E 2p0 an! p
#
F
1
1
/2 E #p0% then p belongs to
/30 /1% 20 /$0
1 2
%
# #
_

,
/C0
1
1%
)7
_

,
/D0
22. 6" p
1
% p
2
% p
#
are the roots o" 27(
#
* 27(
2
E a( * 1 F =% then ,alue o" a is
/30 9 /$0 6
/C0 # /D0
1
=%
1
1
1
]
2#. 6" p
1
F
1
#
/1 E #p0% p
2
F
1
)
/1 * p0 an! p
#
F
1
)
/1 * 2p0% then p belongs to
/30
1
%1
#
_

,
/$0
1 1
%
9 )
_

,
/C0
2 2
%
# #
_

,
/D0 /1% =0
,H-SI CS
.ART 5 II
SECTION 5 I
2). The !isplace&ent o" a particle is gi,en at ti&e t by B
2
sin/ 2 0 sin x A t B t + . Then%
/30 the &otion o" the particle is .74 'ith an a&plitu!e o"
2
2
)
B
A +
/$0 the &otion o" the particle is not .74% but oscillatory 'ith a ti&e perio! o" T

/C0 the &otion o" the particle is oscillatory 'ith a ti&e perio! o" T
2
/D0 the &otion o" the particle is a perio!ic.

21. 3 &ass & is suspen!e! "ro& a spring o" "orce constant k an! +ust touches
another i!entical spring "i(e! to the "loor as sho'n in the "igure. The ti&e
perio! o" s&all oscillations is
/30
&
2
k
/$0
& &
k k 8 2
+
/C0
&
#k 8 2
/D0
& &
k 2k
+
k
m
k
26. T'o i!entical ro!s o" length l an! &ass & are 'el!e! together at
right angles an! then suspen!e! "ro& a kni"eCe!ge as sho'n.
3ngular "requency o" s&all oscillations o" the syste& in its o'n
plane about the point o" suspension is
/30
l & 4
" #
/$0
l & &
" #
/C0
l &
" #
/D0 2one o" these
27. The hori@ontal plane is s&ooth. 6" the syste& is slightly !isplace! an! release!% it e(ecutes
.74. The &a(i&u& a&plitu!e% i" the upper block !oes not slip relati,e to the lo'er block% is
/k is the spring constant an! is the coe""icient o" "riction bet'een the t'o blocks0

'
4 m

m
/30
'
m" (
/$0
'
m"
/C0
'
m" #
/D0
'
m" &
2<. 3 &etal bar o" length L an! area o" crossCsection A is rigi!ly cla&pe! bet'een t'o 'alls.
The PoungQs &o!ulus o" its &aterial is Y an! the coe""icient o" linear e(pansion is
. The
bar is heate! so that its te&perature increases by
N C
. Then the "orce e(erte! at the en!s o"
the bar is gi,en by B
/30
YL
/$0 8 YL A
/C0
YA
/D0 8 Y LA .
29. T'o 'ires o" equal length an! crosssection are suspen!e! as sho'n. Their PoungQs 4o!ulii
are P
1
an! P
2
respecti,ely. The equi,alent PoungQs &o!ulus 'ill be
/30 P
1
E P
2
/$0
2
Y Y
2 1
+

/C0
2 1
2 1
Y Y
Y Y
+
/D0
2 1
Y Y
SECTION 5 II
#=. 5hich o" the "ollo'ing "unctions represents .74 R
/30
sin 2 t
/$0
2
sin t
/C0
sin 2cos t t +
/D0
sin cos 2 t t +
#1. The !isplace&ent o" a particle o" &ass 1== g "ro& its &ean position is gi,en by% y F =.=1 sin
) /1t E =.)0 Sy is in &etresH
/30 The perio! o" &otion is =.1 s
/$0 The &a(i&u& acceleration o" the particle is
2
1=
&8s
2
/C0 The energy o" the particle is
2
=.=1 +oule
/D0 The "orce acting on the particle is @ero 'hen !isplace&ent is =.=1 & "ro& &ean position
#2. 5ater is "lo'ing through a long hori@ontal tube. :et P
3
an! P
$
be the pressures at t'o points
3 an! $ o" the tube
/30 P
3
&ay be equal to P
$
/$0 P
3
&ay be greater than P
$
/C0 P
3
&ay be s&aller than P
$
/D0 P
3
F P
$
only i" the crossCsectional area at 3 an! $ are equal
##. T'o springs o" equal lengths an! equal crossCsectional areas are &a!e o" &aterials 'hose
PoungQs &o!ulii are in the ratio o" 2B#. They are suspen!e! an! loa!e! 'ith the sa&e &ass.
5hen stretche! an! release!% they 'ill oscillate 'ith ti&e perio!s in the ratio o" B
/30 # B 2 /$0 # B 2
/C0 # # B 2 2 /D0 9 B ).
SECTION 5 III
Reason#n$ T&)e
CODE
#). STATEMENT 5 1: >requency o" spring &ass syste& in t'o cases sho'n in the "igure is
sa&e.
an4
STATEMENT 5 2: >requency o" a spring &ass syste&
1 ;
"
2 4
% 'hich !oes not !epen!

upon acceleration !ue to gra,ity.
&
/ 2 0
a
=
&
/ 1 0
;
#1. STATEMENT 5 1: The graph o" total energy o" a particle in ..7.4. '.r.t. position is a
straight line 'ith @ero slope.
an4
STATEMENT 5 2: Total energy o" particle in ..7.4. re&ains constant throughout itQs
&otion.
#6. STATEMENT 5 1: 5hen there is a thin layer o" 'ater bet'een t'o glass plates% there is a
strong attraction bet'een the&.
8e/a(se
STATEMENT 5 2: The pressure bet'een the plates beco&es less than at&ospheric pressure
because pressure insi!e a bubble or !rop is greater than outsi!e pressure.
#7. STATEMENT 5 1: .train causes the stress in an elastic bo!y.
8e/a(se
STATEMENT 5 2: 3n elastic rubber is &ore plastic in nature.
SECTION 5 I2
.ara$ra)h *or '(est#ons Nos. ,8 to 60
3 particle o" &ass & oscillating un!er the in"luence o" a 7ookeQs la'
restoring "orce is gi,en by > F k( e(hibits si&ple har&onic &otion
'ith angular "requency
&
;
an! ti&e perio!
;
&
2 T . 6n the
arrange&ent sho'n in the "igure% both the springs are rela(e! an! the
&
2
&
1
k
2
k
1
/s&ooth0
blocks are !isplace! slightly% they per"or& si&ple har&onic &otion.

#<. The "requency o" such oscillation is
/30
( ) ( )
2 1 2 1
2 1
; ; & &
; ;
2
1
+ +
/$0
( )
2 1 2 1
2 1
& & ; ;
; ;
2
1
+
+
/C0
2 1
2 1
& 4
; ;
2
1
+
+
/D0
( )
2 1
2 1
& &
; ;
2
1
+
#9. The correct con!ition i" the "rictional "orce on block &
2
is to act in the !irection o" its
!isplace&ent "ro& &ean position
/30
2
1
2
1
;
;
&
&
<
/$0
2
1
1
2
;
;
&
&
<
/C0
2
1
2
1
;
;
&
&
>
/D0
2
1
1
2
;
;
&
&
>
)=. 6" the spring o" spring constant ;
2
is re&o,e! an! lo'er block o" &ass &
2
,ibrate 'ith
"requency v. Then the &a(i&u& a&plitu!e o" oscillations that the syste& can ha,e% i" the
block is not to slip on the lo'er block% 'ill be
/30
2
gv
2
4
/$0
2
gv
2
4
/C0
2
v
g
2
4
/D0
2
g
v
2
4
.ara$ra)h *or '(est#ons Nos. 61 to 6,
3n open rectangular tank 1 & T )& T #& high containing 'ater upto a height o" 2 & is accelerate!
hori@ontally along the longer si!e as sho'n in the "igure
a
=
2 &
1 &
# &
- e a r
> r o n t
)1. The &a(i&u& acceleration that can be gi,en 'ithout spilling the 'ater is
/30 2 &8s
2
/$0 ) &8s
2
/C0 1 &8s
2
/D0 # &8s
2
)2. 6" initially% the tank is close! at the top an! is accelerate! hori@ontally by 9 &8s
2
% the gause
pressure at the botto& o" the "ront 'alls o" the tank
/30 Uero /$0 ).1 T 1=
)
pa
/C0 9.= T 1=
)
pa /D0 2.21 T 1=
)
pa
)#. 6n the abo,e part% the gauge pressure at the botto& the rear 'alls o" the tank
/30 Uero /$0 ).1 T 1=
)
pa
/C0 9.= T 1=
)
pa /D0 2.21 T 1=
)
pa
.ara$ra)h *or '(est#ons Nos. 66 to 6>
The physical pen!ulu& is +ust a rigi! bo!y% o" 'hate,er shape% capable o"
oscillating about a hori@ontal a(is passing through it. >or s&all oscillations the
&otion o" a physical pen!ulu& is al&ost as easy as "or a si&ple pen!ulu&.
>igure sho's a rigi! bo!y pi,ote! about point P an! !isplace! "ro&
equilibriu& through an angle . The gra,itational "orce pro,i!e! a restoring
torque o" &agnitu!e &g l sin about point P an! ti&e perio! is gi,en by
6
T F 2
&gl
)). The perio! o" oscillation "or s&all angular !isplace&ent is

/30
g 2
: #
2 /$0
g 2
: #
2
/C0
g 6
:
2 /D0
g )
: #
2
)1. 6" the stick is pi,ote! about a point P% !istance ( "ro& the center o" &ass% the perio! o"
oscillation is
/30
g( 12
( 12 :
2
2 2
+
/$0
g( 2
( 2 : #
2
2 2
+
/C0
g( 12
( : 12
2
2 2
+
/D0
g( 2
( # : 2
2
2 2
+
)6. >or 'hat ,alue o" ( perio! o" oscillation is &ini&u&

/30
12
:
/$0 :
#
2
/C0
#
:
/D0
#
: 2
:
l
C 4
4
. t i c k
C 4
P
CHE+I ST.
-
.ART 5 III
SECTION 5 I
)
C*)
4+.
,
) *
) *
(A)
(i) -e-"Br
(ii) *
#
)
,
(B)
. what is B/
)
C*
)*
C*
#
(A)
(B)
)*
C *
#
C*)
(C)
none
(D)
C*
)*
C*
#
)*
C *
#
)<. 6!enti"y the "inal pro!uct BC
Ph *
0h
)*
1
1
C
#
#
C*
C*
1
1
C
O7

*
,
,
R
/30 Ph *
)
C
11
-e
-e
1
1
C4e /$0 Ph *
0h
C*
#
1
1
C
)
11
C
C7
#

/C0 Ph *
0h
1
C
-e
1
C
4e /D0 none
)9. 3 hy!rocarbon /30 o" the "or&ula C
7
7
12
on o@onolysis gi,es a co&poun! /$0 'hich on al!ol
con!ensation "ollo'e! by heating gi,es 1 * 3cetylcyclopentene. 3 an! $ are respecti,elyBC

C*
#
(A) and
C*
&
C*)
C
C*
#
)
(B)
C*
#
and
C*
#
)*C
)*C
(C)
C*
#
and
C*)
C*
#
) *
(D)
C*
#
C*
#
and
C*
#
)
C*
#
)
1=. The ease o" aci!Ccatalyse! !ehy!ration o" C
2
7
1
O7%/C7
#
0
2
C7O7 an! /C7
#
0
#
CO7 "ollo's the
or!er
/30 ( ) ( )
# # 2 1
# 2
C7 CO7 C7 C7O7 C 7 O7 > >
/$0 ( ) ( )
2 1 # #
2 #
C 7 O7 C7 C7O7 C7 CO7 > >
/C0 ( ) ( )
# # 2 1
2 #
C7 C7O7 C7 CO7 C 7 O7 > >
/D0 ( ) ( )
# 2 1 #
2 #
C7 C7O7 C 7 O7 C7 CO7 > >
11. Consi!er the "ollo'ing trans"or&ation
conc.76
# 2 #
heat
C7 C7 C7 O C7 C7
The &a+or pro!uct/s0 "or&e! is /are0
/30
# # 2
C7 C7 C76 an! C7 C7 6
/$0
# # 2
C7 C7 C76 an! C7 C7 O7
/C0
# 2 # 2
C7 C7 C7O an! C7 C7 6
/D0
# 2 2 #
C7 C7 C7 O C7 C7
G
6

12. The &a+or pro!uct "or&e! in the reaction
O 7
C 7 O 7
2
E C 7 C 7 6
# 2
2 a C O
2 #
a c e t o n e % h e a t
is
/30
C 7 O 7
2
O C 7 C 7
2 #
/$0
C 7 O C 7 C 7
2 2 #
O 7
/C0
C 7 O C 7 C 7
2 2 #
O C 7 C 7
2 #
/D0
C 7
#
O
O
SECTION 5 II
1#. Point out the correct synthesis B
-"Br
( & ) *
,
/ 3 0
C*
#
C C*
#
)
( 2 )
)*
3
-"Br
*
/ $ 0
3
C* 0h
)*
*
( 2 ) - " , e t h e r
( & ) 0 h 4 C * )
( # ) *
#
)
,
0h-"Br
,
C*
&
)
C*
&
/ 2 0 7
E
0h C*
&
C*
&
)*
/ C 0
0h-"Br
/ 2 0 7
E
0h C*
&
)* / D 0
, * C * )
1 ) .
C 3
)*
0h
Cl
)
&
3
*
&
5)
4
A
A l ' a l i
B
C 3
)*
0h
Cl
)
&
3
*
&
5)
4
C
A l ' a l i
D
( A )
Cl
3)
&
3* C 0h
)
C i s
( B )
C
)
3
0h
3)
&
B i s
( C )
C
)
3
0h
)
&
3
D i s
( D )
C
3*
)
)
&
3
Cl
0h
A i s
1 1 .
6
C
*
) ,
* 5 C*
&
C*
&
5 *
7 C l / g 0
C 7
2
O
7 8 9
The stable co&poun! SOH &ay be utili@e!
6
C
*
)
( A )
t o c o n , e r t
i n t o
6
C
D
)

6
C
*
) ( B ) t o c o n , e r t i n t o
6
C
*
#
C
)

6
C
*
)
( C ) t o c o n , e r t i n t o
6
C*
&
*
6
C
*
)
( D ) t o c o n , e r t i n t o
- C . 7
16. 5hich o" the "ollo'ing carbonyl co&poun! can "or& stable hy!rateR
/30 Cyclopropanone /$0 >or&al!ehy!e
/C0 7e(a"luoroacetone /D0 Trichloroacetal!ehy!e /Chloral0
SECTION 5 III
Reason#n$ T&)e
Co4e
17. STATEMENT 5 1: -Cl is hy!rolyse! to -O7 slo'ly but the reaction procee!s rapi!ly in
the presence o" catalytic a&ount o" ;6.
STATEMENT 5 2: 6
is a strong nucleophile an! it reacts 'ith -Cl to "or& -6. 6
is a better
lea,ing group than Cl
an! -6 is hy!rolyse! rapi!ly to -O7.

1<. STATEMENT 5 1: 6o!o"or& is obtaine! by the reaction o" acetone 'ith hypoio!ite an! not
'ith io!i!e.
STATEMENT 5 2: O6
C
is an o(i!i@ing agent is 'ell as an io!inating agent.
19. STATEMENT?1: 2ucleophilies attack not carbonyl groups at carbon "ro& a !irection
perpen!icular to the plane o" carbonyl group but at about 1=7
=
/obtuse angle0.
STATEMENT?2: -epulsion "ro& "ille! or orbital "orces nucleophile to attack at obtuse
angle.
6=. STATEMENT?1: DiCtert. $utyl ether cannot be prepare! by 5illia&sonQs ether synthesis.
because
STATEMENT?2: Tert. butyl bro&i!e on treat&ent 'ith so!iu& tert. buto(i!e
pre"erentially un!ergoes substitution by .
2
2
SECTION 5 I2
,a!a$!a/h 0o! 1uestio%s Nos2 34 to 35
3 young che&ist per"or&e! three !i""erent e(peri&ents in the laboratory an! got three !i""erent
results.
Experiments Number 1.

-e
-e
)
3a
Et)*
6adical Anion
Et)*
-e
-e
)*
:ntermediate

-e
-e
)
-"
%en;ene
*
,
(8)
:ntermediate
<=
=
C
*
&
5)
4
(>)

-e -e
)
6 4 C)
#
*
(46C))*)
Et
&
)
3a
(?)
61. The co&poun! O is
-e
-e
(A)
-e
-e
)*
)*
-e
-e
(B)

-e
)
)*
(C)
-e
)
)
-e
(D)
62. The co&poun! P is
-e
)
)
-e
(A)
-e
)
)
C*)
(B)
-e
)
)*
(C)
-e
)
(D)
6#. The co&poun! U is
-e
)
)
-e
(A)
)
)
C*)
(B)

-e
)
-e
C))C*
#
(C)
)*
)*
C*
#
(D)
3n organic co&poun! VOQ ha,ing &olecular "or&ula C
1=
7
16
O on re!ucti,e o@onolysis yiel!s acetone
an! t'o other co&poun!s P an! U. P on treat&ent 'ith !il. 2aO7 "inally gi,es

)
%
'hile U on
treat&ent 'ith conc. 2aO7 "ollo'e! by aci!i"ication an! heating "inally gi,es

)
)
)
.
6). The co&poun! P is
/30 Pentan!ial /$0 )Co(opentanal
/C0 PentanC2% #C!ione /D0 PentanC2% )C!ione
61. The co&poun! O is
/30 /7
#
C0
2
C F C7C7
2
C7
2
C/C7
#
0 F C7C7O
/$0 /C7
#
0
2
C F C7 C
#
G
C7
C7
C C7
2
* C7 F C7C7O
/C0 /C7
#
0
2
C F C7 * C7
2
* C7
2
* C7 F
#
G
C7
C
C C7O
/D0 /7
#
C0
2
C F C7 * C7
2
* C7 F
#
G
C7
C
C C7
2
C
GG
O
C
C7
66. The co&poun! U is
/30 C7O * C7O /$0 C7O * COO7
/C0 C7
#
C7O /D0 COO7 * COO7
6n the "ollo'ing reaction sequence pro!uct% 6% W an! : are "or&e!. ; represents a reagent.
7e( * # * ynal
)
#
1.
2.
NaBH
PBr
6
2
#
1. 8
2.
#.
g et!er
C"
H "
+
W
#

C *
#
Cl
)
7
2
0 d ! B a 5 )
4
q u i n o l i n e
( @ )
67. The structure o" the pro!uct 6 is B
/ 3 0 -e
Br
/ $ 0
-e
Br
/ C 0 -e
Br
/ D 0
-e Br
6<. The structures o" co&poun! W an! ;% respecti,ely
/ 3 0
-e C))*
a n d . O C l
2
/ $ 0 -e
)*
)
a n d . O
2
C l
2
/ C 0
a n d . O C l
2
C))*
-e
/ D 0
a n d C 7
#
. O
2
C l
C))*
-e
69. The structure o" pro!uct : is
/ 3 0
C*)
-e
/ $ 0
-e
C*)
/ C 0
C*)
-e
/D0 2one o" these
6" you ha,e any genuine question paper proble&s please contact the "ollo'ing sub+ect concerne! persons.
.a)er Setter : P92W3$6 $3?7
Mathe+at#/s : 4r. -a+i, -an+an 4obileB 9999=69<)6
.h&s#/s : 4r. D. $. .ingh 4obileB 999=#<1916
Che+#str& : 4r. .an+ay Di(it 4obileB 9<9969976=
Commo n P r a ct i c e T e s t 25
XII STD [89 Batches]
ANS@ER AEY
MATBEMATICS .BYSICS CBEMISTRY
'. No. Ans%er '. No. Ans%er '. No. Ans%ers
1 $ 26 3 67
$
2 3 2= D 68
$
, D 2> $ 6C
3
6 3 27 3 =0
3
= 3 28 C =1
C
> C 2C $ =2
3
7
3$CD
,0 3$C =,
3CD
8
3CD
,1 3C =6
3$D
C
$CD
,2 3$D ==
3$C
10
3$C
,, 3 =>
3$CD
11 C ,6 3 =7
3
12 3 ,= 3 =8
3
1, D ,> 3 =C
3
16 D ,7 $ >0
C
1= 3 ,8 C >1
$
1> 3 ,C C >2
D
17 C 60 D >,
3
18 3 61 $ >6
$
1C C 62 3 >=
3
20 $ 6, $ >>
3
21 D 66 $ >7
D
22 3 6= 3 >8
3
2, $ 6> 3 >C
C
NIIT8DEL8,B8CODE8 SHAKUNTAL9,T8:;889 XIISTD 4 2
Hints Soution
1. 5e ha,e
a
tan 3
b
an!
a
tan $
b
a b
tan 3 tan $
b a
+ +
2 2 2
a b c
ab ab
+

2. >ro& sin ( E sin
2
( F 1% 'e get sin ( F cos
2
(.
2o'% the gi,en e(pression is equal to
cos
6
( /cos
6
( E #cos
)
( E # cos
2
( E 10 * 1
F cos
6
( /cos
2
( E 10
#
* 1
F sin
#
( /sin ( E 10
#
* 1
F /sin
2
( E sin (0
#
* 1 F 1 * 1 F =.
#. The gi,en e(pression is equal to .
cos y sin ( * sin y cos ( E sin y sin ( E cos ( cos y F sin /( * y0 E cos /( * y0
1 1
2 sin/( y0 cos/( y0
2 2
1
+
1
]
2 sin /( y0
)
1
+
1
]
The gi,en e(pression 'ill ha,e ,alue @ero i"
/( y0 n
)
1
+
1
]
( y n
)

). sin 3 F sin $ sin 3 * sin $ F =
3 $ 3 $
2sin cos =
2 2
+
A../i0
an! cos 3 F cos $ cos $ * cos 3 F =
3 $ 3 $
2sin sin =
2 2
+
A../ii0
quations /i0 an! /ii0 are si&ultaneously true i" sin /1820 /3 * $0 F =% 'hile the other
"actors sin /1820 /3 E $0 an! cos /1820 /3 E $0 cannot both be @ero si&ultaneously.
1. :et !enote the e,ent that a si( occurs an! 3 the e,ent that the &an reports that it is a si(.
5e ha,e
1 1 3 # 3 1
P/0 % P/X0 % P an! P
6 6 ) X )
_ _

, ,
$y $ayeQs theore&
P/0P/38 0
P
3 P/0P/38 0 P/X0P/38 X0
_

+
,
NIIT8DEL8,B8CODE8 SHAKUNTAL9,T8:;889 XIISTD 4 &
/18 60/#8 )0 #
/18 60/#8 )0 /18 60/18 )0 <

+
6. :et
i
/= i 20 !enote the e,ent that urn contains i 'hite an! /2 * i0 black balls. :et 3
!enote the e,ent that a 'hite ball is !ra'n "ro& the urn.
5e ha,e P/
i
0 F 18# "or i F =% 1% 2 an!
P/3 G
i
0 F 18#% P/3 G
2
0 F 28# P/3 G
#
0 F 1%
$y the total probability rule
P/30 F P/
1
0 P/3 G
1
0 E P/
2
0 P/3 G
2
0 E P/
#
0 P/3 G
#
0
1 1 2 2
1
# # # #
1
+ +
1
]
7. 5e ha,e
P/3 $0 F 1 * P/3 $0 F 1 * P/30 P/$0 S
Q
3 an! $ are in!epen!entH
1 1 2 #
1 1 1 1
2 1 1 1
_ _

, ,
2e(t% P/3 G $0 F P/30 F 182% because 3 an! $ are in!epen!ent.
PS3 /3 $0H P/30 18 2 1
P/3G 3 $0
P/3 $0 P/3 $0 #8 1 6

:astly% since 3$ F /3$0& PS3$0G/3 $0H F =
<.
3 P/3 $0
P/30 P P/3 $0 P/30P/$0
$ P/$0
_

,
3 an! $ are in!epen!ent. .ince
P/3 $0 F P/30 P/$ G 30 F /18)0 /1820 F 18< =
3 an! $ cannot be &utually e(clusi,e. 3s 3 an! $ are in!epen!ent
P/3 G $0 F P/30 F 1 * P/30 F 1 * 18) F #8)
.ince 3 an! $ are in!epen!ent%
P/$0 F P/$ G 30 F 182
P/$ G 30 F P/$0 F 1 * P/$0 F 182
9. 5e ha,e
1 sin 1 cos
( % y
cos sin
+

4ultiplying% 'e get
/1 sin 0/1 cos 0
(y
cos sin
+

(y E 1 F
1 sin cos sin cos sin cos
cos sin
+ +

1 sin cos
cos sin
+

an!
/1 sin 0sin cos /1 cos 0
( y
cos sin
+

Thus ( y E ( * y E 1 F =

y 1
(
y 1
+
an!
1 (
y
1 (
+
NIIT8DEL8,B8CODE8 SHAKUNTAL9,T8:;889 XIISTD 4 #

1=. The gi,en equation can be 'ritten as
2
#
2cos cos 2cos 1
2 2 2 2
+ +
_

,
sin = an! 2cos cos
2 2 2
+
A../i0
3lso% since = I % I % 'e ha,e F . There"ore% "ro& /i0 'e get cos F Y% so that
#

11. /C0
12. /30
The state&entC1 3 is true an! "ollo's "ro& state&entC2
in!ee! P/38$0 F
P/3 $0
P/$0
P/30

P/3 $0
P/30
P/$0
P/$830 P/$0
1#. .tate&entC1 is "alse. .ince i" the colour 'hite is "irst to e(haust then last ball &ust be black.
"a,ourable sa&ple points
//a E b * 10Z0b
req. probability F
b/a b 10Z b
a bZ a b
+
+ +

/D0
1). /D0
2nE1 F 1% n F 2
P/0 F
2
#n 6 2
)n 1 11 1

>or a% b% c are in 3.P. a E c F 2b
a E c is e,en
a an! c are both e,en or both o!!.
.o% nu&ber o" 'ays o" choosing a an! c is
n
C
2
E
nE1
C
2
F n
2
'ays.
P/0 F
2
2n 1 2
#
n #n
C )n 1
+

11%16%17
= I I 9=N% 9=N I I 1<=N% 1<=N I I 27=N% 27=N I I #6=N.
27=N I E I )1=N
E lies in the 6 or 6D qua!rant an! cosine in both is positi,e.
6" ! is the co&&on ratio o" the 3.P.
Then F E !% F E 2!% F E #!.
E F E % 2/ 0 F 2! F .
3n! E F 2. 2ote F !% F #!
27=N I I #6=N
27=N I E #! I #6=N
2==N I #! I 29=N S F 7=NH
)==N I 6! I 1<=N
6<=N I ) E 6! I <6=N
6<=N I E <6=N
21. = p
1
% p
2
% p
#
1
an! = p
1
E p
2
E p
#
1
1 2
1 p % p 1% p 1
2 #

an!
#7 7
p
2# 2#

22. 9se
1
#
/p
1
E p
2
E p
#
0 F /p
1
p
2
p
#
0
18#
to obtain
p
1
F p
2
F p
#
F 18#.
2). 3
21. /D0
26. /$0
.ol. The !istance o" centre o" &ass "ro& point o" suspension C. F
& &
l
5
C
l!&
l!&
4.6. o" the syste& about . F 28# &
&
l
.
( )
&
&
&m" ! & & #"
& # m
& &

l
l
l
27. /30
.ol. :et the a&plitu!e be 3
then% the &a(i&u& co&&on acceleration 'hen
a&plitu!e is 3% is gi,en by
k3 F 1&a% a F
m (
'A
'
4 m
m
>or the upper block
" F &g%
g F
m (
'A
3 F
'
m" (

2<. /C0
29. /$0
NIIT8DEL8,B8CODE8 SHAKUNTAL9,T8:;889 XIISTD 4 (
.ol. qui,alent spring constant o" a 'ire is gi,en by

l
P3
; [ 2 1 eq
; ; ; +
or
l l l
3 P 3 P 3 2 P
2 1
+
) (
or
2
P P
P
2 1
+
l % 3
P
1
l % 3
P
2
F
l % 2 3
P
#=. /3%$%C0
#1. /3%C0
#2. /3% $% D0
##. /30
#). /30
.ol. >requency o" a spring &ass syste& !oes not !epen! upon acceleration !ue to gra,ity.
#1. /30
#6. /30
#6. The at&ospheric pressure "ro& the si!es o" t'o plates process the& to'ar!s each other.
#7. /$0
.ol.
1
elasticity
!e"or&ation
.
#<. /C0
#9. /C0
)=. /D0
)1. /$0
)2. /30
)#. /$0
)). /$0
)1. /30
)6. /30
6 7 . *
#
C
)
3aBr
4
*
#
C
)*
0Br
#
*
#
C
Br
6 < . *
#
C
Br
*
#
C
)*
)
/ i 0 4 g 8 e t h e r
/ i i 0 C O
2
/ i i i 0 7
#
O
E
6 9 . *
#
C
)*
)
*
#
C
Cl
)
7
2
8 P ! C $ a . O
)
q u i n o l i n e
. O C l
2
)
* *
C *
#
NIIT8DEL8,B8CODE8 SHAKUNTAL9,T8:;889 XIISTD 4 +

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FILE NO.

/D0 the &otion o" the particle is a perio!ic.

% 'hich !oes not !epen!

blocks are !isplace! slightly% they per"or& si&ple har&onic &otion.

)). The perio! o" oscillation "or s&all angular !isplace&ent is

)6. >or 'hat ,alue o" ( perio! o" oscillation is &ini&u&

is a strong nucleophile an! it reacts 'ith -Cl to "or& -6. 6

an! -6 is hy!rolyse! rapi!ly to -O7.

NIIT8DEL8,B8CODE8 SHAKUNTAL9,T8:;889 XIISTD 4 #

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