FILE NO.

IIT 180/26 (01/11/2008)

CODE DHAMAKA

NARAYANA
I I T A C A D E M Y
Common Pract i ce Test
XII Std C/F Other Than Spark [79 Batches]
Test Dat e: 03
RD
NOV. 2008.
Ti me: 3 hours Maxi mum mars: 2!6
"#ease rea$ %he i&s%ru'%io&s 'are(u##). *ou are a##o%%e$ + mi&u%es s,e'i(i'a##) (or %his ,ur,ose.
INSTRUCTIONS
A. General:
1. This booklet is your Question Paper containing 69 questions. The
booklet has 17 pages.
2. The question paper COD is printe! on the right han! top corner o"
this booklet.
#. $lank papers% clipboar!s% log tables% sli!e rules% calculators% cellular
phones% pagers% an! electronic ga!gets in any "or& are not allo'e!
to be carrie! insi!e the e(a&ination hall.
). The ans'er sheet% a &achine*rea!able Ob+ecti,e -esponse .heet
/O-.0% is pro,i!e! separately.
1. DO 2OT T34P- 56T7 8 49T6:3T T7 O-. O- T7
$OO;:T.
B. Flln! t"e ORS
6. On the lo'er part o" the O-.% 'rite in ink% your na&e in bo( :1%
your -egistration 2o. in bo( :2 an! 2a&e o" the Centre in bo( :#.
D# n#t $rte t"ese an%$"ere else.
7. 5rite your -egistration 2o. in ink% in the bo( :) pro,i!e! in the
lo'er part o" the O-. an! !arken the appropriate bubble UNDER
each !igit o" your -egistration 2o. 'ith a goo! quality 7$ pencil.
<. The O-. has a CODE printe! on its lo'er an! upper parts.
9. 4ake sure the COD on the O-. is the sa&e as that on this booklet
an! put your signature in ink in bo( :1 on the O-. a""ir&ing that
you ha,e ,eri"ie! this.
1=. 6> T7 COD. DO 2OT 43TC7% 3.; >O- 3 C732? O>
T7 $OO;:T.
C. &'est#n (a(er )#r*at:
11. The question paper consists o" 3 (arts +,art I: Mat"e*at-s. ,art
II: ,"%s-s. ,art III: C"e*str%/. ach part has ) sections.
12. Se-t#n I contains 6 &ultiple choice questions. ach question has )
choices /30% /$0% /C0 an! /D0% out o" 'hich #nl% #ne s -#rre-t.
1#. Se-t#n II contains ) &ultiple correct ans'er type questions. ach
questions has ) choices /30% /$0% /C0 an! /D0% out o" 'hich one or
&ore ans'ers are correct.
1). Se-t#n III contains ) -easoning type questions. ach question
contains .T3T42T*1 32D .T3T42T*2.
$ubble /30 i" both the state&ents are T-9 an! .T3T42T*2
is the correct e(planation o" .T3T42T*1.
$ubble /$0 i" both the state&ents are T-9 but .T3T42T*2
is 2OT the correct e(planation o" .T3T42T*1.
$ubble /C0 i" .T3T42T*1 is T-9 an! .T3T42T*2 is
>3:..
$ubble /D0 i" .T3T42T*1 is >3:. an! .T3T42T*2 is
T-9.
11. Se-t#n IV contains # sets o" :inke!*Co&prehension type question.
ach set consists o" a paragraph "ollo'e! by # questions. ach
question has ) choices /30% /$0% /C0 an! /D0% out 'hich #nl% #ne s
-#rre-t.
D. Mar0n! S-"e*e:
16. >or each questions in Se-t#n I% you 'ill be a$ar1e1 3 *ar0s i"
you ha,e !arkene! only the bubble correspon!ing to the correct
ans'er an! @ero &ark i" no bubble is !arkene!. 6n all other cases%
*n's #ne +23/ *ar0 'ill be a'ar!e!.
17. >or each question in Se-t#n II% you 'ill be a$ar1e1 4 *ar0s i"
you ha,e !arkene! all the bubble/s0 correspon!ing to the correct
ans'er an! @ero &ark "or all other cases. 6" &ay be note! that there
is n# ne!at5e *ar0n! )#r $r#n! ans$er.
1<. >or each question in Se-t#n III% you 'ill be a$ar1e1 3 *ar0s i"
you !arken only the bubble correspon!ing to the correct ans'er an!
@ero &ark i" no bubble is !arkene!. 6n all other cases% *n's #ne +2
3/ *ar0 'ill be a'ar!e!.
19. >or each question in Se-t#n IV% you 'ill be a$ar1e1 4 *ar0s i"
you !arken only the bubble correspon!ing to the correct ans'er an!
6er# *ar0 i" no bubble is !arkene!. 6n all other cases% *n's #ne +2
3/ *ar0 $ll 7e a$ar1e1
Na*e #) t"e St'1ent R#ll N'*7er
I "a5e rea1 all t"e nstr'-t#ns an1 s"all a71e 7% t"e*
AA..AAAAAAAAAAAAAAAAAAAAA
S!nat're #) t"e Can11ate
I "a5e 5er)e1 all t"e n)#r*at#n )lle1 n 7% t"e
Can11ate
AAAAAAAAAAAAAAAAAAAAA..
S!nat're #) t"e In5!lat#r
S!th De"h# $ )7*$% ;alu .arai% 2e' Delhi * 11==16 Ph.B =11*)6=<=61281#81)
%rth/&est De"h# $ 11% Central 4arket% 5est Pun+abi $agh% 2e' Delhi * 11==26 Ph.B =11*)1=6261181281#
East De"h# $ #2C% Patpargan+ Dillage% 4ayur Dihar Phase * 6% Delhi * 11= =91 Ph.B =11*2271==)#812
'!r(an $ 4*21% Ol! D:> Colony% .ector*1)% ?urgaon Ph.B =12)*#217791892
D)arka $ #178#1<% Dikas .urya ?ala(y% 4ain 4kt% .ector*)% D'arka% 2e' Delhi * 11= =71 Ph.B =11*)162172)821
Far#da*ad $ .COC27% 66n! >loor% .ector * 16% >ari!aba!% 7aryana * 121==2 Ph.B =122C)=7)626% )=669#<
MATHEMATI CS
,ART 2 I
SECTION 2 I
Stra!"t O78e-t5e T%(e
This section contains 6 &ultiple choice questions. ach question has ) choices /30% /$0% /C0 an! /D0%
out o" 'hich ON9Y ONE is correct.
1. The ,alue o" a% b% c "or 'hich the &atri(
= 2b c
a b c
a b c
1
1

1
1
]
is orthogonal is
/30
1 1 1
% %
2 6 #
_

,
/$0
1 1 1
% %
# 6 2
_

,
/C0
1 1 1
% %
6 2 #
_

,
/D0
1 1 1
% %
2 # 6
_

,
2. 6" a% b% c% ! are real nu&bers an! 3E
a b
c !
1
1
]
then a
2
* /a F !0a is equal to
/30 /a! * bc0i /$0 /bc * a!0i
/C0 /ac * b!0i /D0 /ab * c!0i
#. 6" P/(0% Q/(0 an! -/(0 are polyno&ials o" !egree one an! a
1
% a
2
% a
#
be real nu&bers then
1 2 #
1 2 #
1 2 #
P/a 0 P/a 0 P/a 0
Q/a 0 Q/a 0 Q/a 0
-/a 0 -/a 0 -/a 0
1
1
1
1
]
is equal to
/30 1 /$0 =
/C0 * 1 /D0 none o" these
). 6" the base o" a triangle an! the ratio o" tangent o" hal" the base angles are gi,en then the
locus o" the ,erte( o" the triangle is
/30 parabola /$0 ellipse
/C0 hyperbola /D0 none o" these
1. 6"
cos sin
3 %
sin cos
1

1

]
then
n
n
3
li&
n

is /'here -0
/30 a @ero &atri( /$0 an i!entity &atri(
/C0
= 1
= 1
1
1

]
/D0
= 1
1 =
1
1

]

6. The solution o" the equation
2
( (
G ( G
( 1 G ( 1G
+

is
/30 ( = /$0 ( H =
/C0 ( /1% 0 /D0 none o" these

SECTION 2 II
M'lt(le C#rre-t Ans$er T%(e
This section contains ) &ultiple correct ans'er/s0 type questions. ach question has ) choices /30%
/$0% /C0 an! /D0% out o" 'hich ONE OR MORE is8are correct.
7. The equation o" the asy&ptotes o" the hyperbola (y * #y * 2( E = is
/30 ( E y /$0 ( E #
/C0 y E 1 /D0 y E 2
<. 6" @
1
% @
2
% @
#
% @
)
are the "our co&ple( nu&bers represente! by the ,ertices o" a qua!rilateral
taken in or!er such that @
1
* @
)
E @
2
* @
#
an!
) 1
2 1
@ @
a&p
@ @ 2
_

,
% then the qua!rilateral is a
/30 -ho&bus /$0 square
/C0 -ectangle /D0 cyclic qua!rilateral
9. The ,alue o"
1 1 1
a/a b c0 b/a b c0 c/a b c0
tan tan tan
bc ca ab

+ + + + + +
+ + is equal to
/30
)

/$0
2

/C0 /D0 =
1=. 6" 3 an! $ are in,ertible square &atrices o" the sa&e or!er% then 'hich o" the "ollo'ing is
correctI
/30 a!+/3$0 E /a!+$0 /a!+30
/$0 /a!+30 E /a!+30
/C0 Ga!+ 3G E G3G
n * 1
% 'here n is the or!er o" &atri( 3
/D0 a!+/a!+$0 E G$G
n * 2
$% 'here n is the or!er o" &atri( $
SECTION 2 III
Reas#nn! T%(e
This section contains ) reasoning type questions. ach question has ) choices /30% /$0% /C0 an! /D0% out o"
'hich ON9Y ONE is correct.
CODE
+A/ STATEMENT23 s Tr'e. STATEMENT22 s Tr'e: STATEMENT22 s a -#rre-t e;(lanat#n )#r STATEMENT23
+B/ STATEMENT23 s Tr'e. STATEMENT22 s Tr'e: STATEMENT22 s NOT a -#rre-t e;(lanat#n )#r STATEMENT23
+C/ STATEMENT23 s Tr'e. STATEMENT22 s False
+D/ STATEMENT23 s False. STATEMENT22 s Tr'e
33. State*ent 2 3 B 6"
a = =
3 = b = %
= = c
_

,
then

1
1
= =
a
1
3 = =
b
1
= =
c

,
Be-a'se
State*ent 2 2 B The in,erse o" a !iagonal &atri( is a !iagonal &atri(.
32. State*ent 2 3 B 6" 3 is a ske' sy&&etric &atri( o" or!er # J #% then !et/30 E =.
Be-a'se
State*ent 2 2 : 6" 3 is square &atri(% then !et/30 E !et/30 E !et/30.
33. State*ent 2 3 B
21 22 2#
#1 #2 ##
)1 )2 )#
/1 (0 /1 (0 /1 (0
" /(0 /1 (0 /1 (0 /1 (0
/1 (0 /1 (0 /1 (0
+ + +
+ + +
+ + +
% then coe""icient o" ( in "/(0 is @ero.
Be-a'se
State*ent 2 2 B 6" >/(0 E 3
=
F 3
1
( F 3
2
(
2
F A.. F 3
n
(
n
. then 3
1
E >/=0% 'here !ash !enotes
the !i""erential coe""icient.
34. State*ent 2 3 B 6" a% b% c are !istinct an! (% y% @ are not all @ero an! a( F by F c@ E =%
b( F cy F a@ E =% c( F ay F b@ E =% then a F b F c E =.
Be-a'se
State*ent 2 2 B a
2
F b
2
F c
2
H ab F bc F ca% i" a% b% c are !istinct.
SECTION 2 IV
9n0e1 C#*(re"ens#n T%(e
This section contains # paragraphs. $ase! upon each paragraph% # &ultiple choice questions ha,e to be
ans'ere!. ach question has ) choices /30% /$0% /C0 an! /D0% out o" 'hich ON9Y ONE is correct.
,ara!ra(" )#r &'est#ns N#s. 3< t# 3=
6" 'e rotate the a(es o" the rectangular hyperbola (
2
* y
2
E a
2
through an angle 8) in the clock'ise
!irection% then the equation (
2
* y
2
E a
2
re!uces to
2
2
2
a a
(y c
2 2
_


,
/say0. .ince ( E ct%
c
y
t

satis"ies (y E c
2
.
/(% y0 E /ct% c8t0 /t =0 is calle!
11. :et % be the roots o" the equation t
1
(
2
* )( F 1 E = an! % be the roots o" t
2
(
2
* 6( F 1 E =
an! % % % are in 7.P. then the point o" intersection o" nor&als at Kt
1
L an! Kt
2
L on (y E c
2
/30
2#27c 1#921c
%
26) 26)
_

,
/$0
#27c 291c
%
26) 26)
_

,
/C0
72#c 129c
%
26) 26)
_

,
/D0 none o" these
16. 6" e
1
an! e
2
are the eccentricities o" the hyperbolas (y E 9 an! (
2
* y
2
E 21% then /e
1
% e
2
0 lie on
a circle C
1
'ith centre origin then the square o" the ra!ius o" the !irector circle o" C
1
is
/30 2 /$0 )
/C0 < /D0 16
17. 6" the nor&al at the point Kt
1
L to the rectangular hyperbola (y E c
2
&eets it again at the point
Kt
2
L% then the ,alue o" t
1
t
2
is
/30
1
1
t

/$0
2
1
t

/C0
#
1
t

/D0
)
1
t

Paragraph for Questions Nos. 18 to 20

.uppose a% b% c% !% be nonC@ero real nu&bers an! ab H =% an!
2 2
1 2
( # 2 ( # 2
= =
/1 e 0/a( b( c( !0!( /1 e 0/a( b( c( !0!( = + + + + + + + +

1<. 5hich state&ent is correctI
/30 ac H = /$0 ab M=
/C0 a! H = /D0 none o" these
19. The equation a(
#
F b(
2
F c( F ! E = has
/30 three positi,e roots /$0 three negati,e roots
/C0 t'o positi,e an! one negati,e roots /D0 one positi,e an! t'o negati,e roots
2=. -olleLs theore& can be applie! "or a(
#
F b(
2
F c( F ! in the inter,al
/30 N1% 2O /$0 N=% 2O
/C0 N1% 2O /D0 none o" these
Paragraph for Questions Nos. 21 to 23
:et 3 an! $ are t'o &atrices o" sa&e or!er # J #% 'here
1 # 2 # 2 )
3 2 ) < % $ # 2 1
# 1 1= 2 1 )
+ _ _




, ,
21. 6" 3 is singular &atri(% then tr/3 F $0 is equal to
/30 6 /$0 12
/C0 2) /D0 17
22. 6" E #% then
1
7
/tr/3$0 F tr/$300 is equal to
/30 #) /$0 )2
/C0 <) /D0 6#
2#. The correct state&ent is
/30 /3 F $0 /3 * $0 E 3
2
F $
2
* 23$ /$0 /3 F $0
2
E 3
2
F $
2
F 3$ F $3
/C0 /3 F $0
2
E 3
2
F $
2
F 23$ /D0 none o" the abo,e
+H,SI CS
,ART 2 II
SECTION 2 I
Stra!"t O78e-t5e T%(e
This section contains 6 &ultiple choice questions. ach question has ) choices /30% /$0% /C0 an! /D0%
out o" 'hich ON9Y ONE is correct.
2). 3 satellite . is &o,ing in an elliptical orbit aroun! the earth. The &ass o" the satellite is ,ery
s&all co&pare! to the &ass o" the earthB
/30 The acceleration o" . is al'ays !irecte! to'ar!s the centre o" the earth.
/$0 The angular &o&entu& o" . about the centre o" the earth changes in !irection% but its
&agnitu!e re&ains constant.
/C0 The total &echanical energy o" . ,aries perio!ically 'ith ti&e.
/D0 The linear &o&entu& o" . re&ains constant in &agnitu!e.
21. 3 hy!rogen ato& is in an e(cite! state o" principle quantu& nu&ber n. 6t e&its a photon o"
'a,elength 'hen returns to the groun! state. The ,alue o" n is /- E -y!berg constant0
/30
0 1 - / -
/$0
-
0 1 - /

/C0
1 -
-

/D0
0 1 - /

26. 6n PCray tube 'hen the accelerating ,oltage D is hal,e!% the !i""erence bet'een the
'a,elengths o" ;

line an! &ini&u& 'a,elength o" continuous PCray spectru&

/30 re&ains constant /$0 beco&es &ore than t'o ti&es
/C0 beco&es hal" /D0 beco&es less than t'o ti&es
27. The acti,ities o" three lu&ps o" a ra!ioacti,e substance are in the ratio o" 1 B 2 B # at any
"uture !ate the ratio o" their acti,ities 'ill be
/30 # B 2 B 1 /$0
2 2 2
1 B 2 B #
/C0
2 2 2
# B 2 B1 /D0 1B 2B # .
2<. .topping potential increases 'ith
/30 !ecrease in &o&entu& o" inci!ent photon
/$0 increase in the intensity o" inci!ent photon
/C0 increase in the 'ork "unction o" photo &etal
/D0 increase in the "requency o" inci!ent light.
29. 3 neutron colli!es hea!Con 'ith a stationary hy!rogen ato& in groun! state. 5hich o" the
"ollo'ing state&ent is correctI
/30 6" kinetic energy o" the neutron is less than 1#.6eD% collision &ust be elastic.
/$0 6" kinetic energy o" the neutron is less than 1#.6eD% collision &ay be inelastic.
/C0 6nelastic collision &ay take place only 'hen initial kinetic energy o" neutron is greater
than 1#.6eD.
/D0 Per"ectly inelastic collision cannot take place.
SECTION 2 II
M'lt(le C#rre-t Ans$er T%(e
This section contains ) &ultiple correct ans'er/s0 type questions. ach question has ) choices /30%
/$0% /C0 an! /D0% out o" 'hich ONE OR MORE is8are correct.
#=. The PCray bea& co&ing "ro& an PCray tube 'ill be
/30 4onochro&atic
/$0 7a,ing all 'a,elengths bet'een a &ini&u& an! a &a(i&u& 'a,elength
/C0 7a,ing all 'a,elengths s&aller than a certain &a(i&u& 'a,elength
/D0 7a,ing all 'a,elengths larger than a certain &ini&u& 'a,elength
#1. 5hen photoelectrons o" energy ).21 eD strike the sur"ace o" a &etal 3% the e+ecte!
photoelectrons ha,e &a(i&u& kinetic energy T
3
eD an! !eC$roglie 'a,elength
3
. The
&a(i&u& kinetic energy o" photoelectrons liberate! "ro& another &etal $ by photons o"
energy ).7= eD is T
$
E /T
3
1.1=0eD. 6" the !eC$roglie 'a,elength o" these photoelectrons is

$
E 2
3
% then
/30 The 'ork "unction o" 3 is 2.21 eD /$0 T
3
E 2.== eD
/C0 The 'ork "unction o" $ is ).2= eD /D0 T
$
E 2.71 eD
#2. 3 s&all &ass & is &o,e! slo'ly "ro& the sur"ace o" the earth to a height h abo,e the sur"ace.
The 'ork !one /by an e(ternal agent0 in !oing this is
/30 &gh% "or all ,alues o" h /$0 &gh% "or h MM -
/C0
1
&g-% "or h -
2
/D0
1
&g-% "or h -
2

##. 3 soli! sphere o" uni"or& !ensity an! ra!ius ) units is locate! 'ith its centre at the origin o"
coor!inates% O. T'o spheres o" equal ra!ii o" 1 unit% 'ith their centres at 3 / 2% =%=0 an! $
/2%=%=0 respecti,ely% are taken out o" the soli! sphere% lea,ing behin! spherical ca,ities as
sho'n in the "igure.
y
x
z
/30 The gra,itational "orce !ue to this ob+ect at the origin is @ero
/$0 The gra,itational "orce at the point $/2%=%=0 is @ero
/C0 The gra,itational potential is the sa&e at all points o" the circle y
2
F @
2
E #6
/D0 The gra,itational potential is the sa&e at all points on the circle y
2
F @
2
E )
SECTION 2 III
Reas#nn! T%(e
This section contains ) reasoning type questions. ach question has ) choices /30% /$0% /C0 an! /D0%
out o" 'hich ON9Y ONE is correct.
CODE
+A/ STATEMENT23 s Tr'e. STATEMENT22 s Tr'e: STATEMENT22 s a -#rre-t e;(lanat#n )#r STATEMENT23
+B/ STATEMENT23 s Tr'e. STATEMENT22 s Tr'e: STATEMENT22 s NOT a -#rre-t e;(lanat#n )#r STATEMENT23
+C/ STATEMENT23 s Tr'e. STATEMENT22 s False
+D/ STATEMENT23 s False. STATEMENT22 s Tr'e
#). STATEMENT 2 3 : 6n the photoelectric e""ectQ the photoelectron current is increase! 'hen
"requency o" inci!ent photons is !ouble!.
an1
STATEMENT 2 2 : Photoelectric e""ect "ollo's the instein equation h, E h,
=
F ;.
The ; o" photoelectron is increase! an! not is the increase o" nu&ber o" photo electron.
#1. STATEMENT 2 3 : 6" the accelerating ,oltage is !ouble!Q then &ini&u& 'a,elength o"
e&itte! continues P*rays is hal,e!.
an1
STATEMENT 2 2 : The 'a,elength o" characteristic P*rays is in!epen!ent o" applie!
accelerating ,oltage.
#6. STATEMENT 2 3 : 6" a train is &o,ing in straight line% an! its "requency o" 'histle is ". 3n
obser,er 'hich lies on perpen!icular o" path o" train. Obser,er is stationaryQ "requency han!
by obser,er 'ill be continuously increasing.
an1
STATEMENT 2 2 : 6" relati,e &otion occur bet'een source an! obser,er then "requency
obser,e! by obser,er 'ill be !i""erent "ro& "requency pro!uce! by source.
#7. STATEMENT 2 3 : 6" an ob+ect is pro+ecte! "ro& earth sur"ace 'ith escape ,elocity path o"
ob+ect 'ill be parabola.
an1
STATEMENT 2 2 : 5hen ob+ect is pro+ecte! 'ith ,elocity less than escape ,elocity "ro&
hori@ontal sur"ace an! greater than orbital ,elocity. Path o" ob+ect 'ill be ellipse.
SECTION 2 IV
9n0e1 C#*(re"ens#n T%(e
This section contains # paragraphs. $ase! upon each paragraph% # &ultiple choice questions ha,e to be
ans'ere!. ach question has ) choices /30% /$0% /C0 an! /D0% out o" 'hich ON9Y ONE is correct.
,ara!ra(" )#r &'est#ns N#s. 38 t# 40
T'o &etallic plates 3 an! $% each o" area 1 J 1=
)
&
2
% are place! parallel to each other at a
separation o" 1 c&. Plate $ carries a positi,e charge o" ##.7 J 1=
12
C. 3 &onochro&atic bea& o"
light % 'ith photons o" energy 1 eD each % starts "alling on plate 3 at t E = so that 1=
16
photons "all on
it per square &eter per secon!. 3ssu&e that one photoelectrons is e&itte! "or e,ery 1=
6
inci!ent
photons. 3lso assu&e that all the e&itte! photoelectrons are collecte! by plate $ an! the 'ork
"unction o" plate 3 re&ains constant at the ,alue 2eD.
#<. The nu&ber o" photoelectrons e&itte! up to t E 1= s
/30 1 J 1=
7
/$0 1 J 1=
6
/C0 21 J 1=
<
/D0 2one o" these
#9. The &agnitu!e o" the electric "iel! bet'een the plates 3 an! $ at t E 1= s
/30 1=== 28C /$0 2== 28C
/C0 2=== 28C /D0 Rero
)=. The kinetic energy o" the &ost energetic photoelectron e&itte! at t E 1= s 'hen it reaches
plate $.
/30 2#eD /$0 21eD
/C0 12 eD /D0 )6eD
,ara!ra(" )#r &'est#ns N#s. 43 t# 43
:ight "ro& a !ischarge tube containing hy!rogen ato&s "alls on the sur"ace o" a piece o" so!iu&.
The kinetic energy o" the "astest photoCelectrons e&itte! "ro& so!iu& is =.7# eD. The 'ork "unction
"or so!iu& is 1.<2 eD.
)1. The energy o" the photons causing the photoCelectric e&ission
/30 2.)= eD /$0 2.11 eD
/C0 =.<1 eD /D0 =.7# eD
)2. The quantu& nu&ber o" the photons causing the photoCelectric e&ission.
/30 ) an! 2 /$0 # an! 2
/C0 ) an! 1 /D0 # an! 1
)#. The change in the angular &o&entu& o" the electron in the hy!rogen ato& in the abo,e
transition
/30 2h8 /$0 #h8
/C0 h8 /D0 /#820h8
,ara!ra(" )#r &'est#ns N#s. 44 t# 4>
3 single electron orbits a stationary nucleus o" charge FRe% 'here R is a constant an! e is the
&agnitu!e o" electronic charge. 6t requires )7.2 eD to e(cite the electron "ro& the secon! orbit to
thir! $ohr orbit. >in!
)). The ,alue o" @
/30 21 /$0 1
/C0 2= /D0 1=
)1. The energy require! to e(cite the electron "ro& the thir! to the "ourth $ohr orbit.
/30 #6.1 eD /$0 16.1# eD
/C0 2= eD /D0 #= eD
)6. The 'a,elength o" electro&agnetic ra!iation require! to re&o,e the electron "ro& "irst $ohr
orbit to in"inity.
/30 #6.1 3
o
/$0 1#.6 3S
/C0 )2.7 3S /D0 7# 3S
CHEMI ST-
,
,ART 2 III
SECTION 2 I
Stra!"t O78e-t5e T%(e
This section contains 6 &ultiple choice questions. ach question has ) choices /30% /$0% /C0 an! /D0% out o" 'hich ON9Y
ONE is correct.
)7. The stan!ar! o(i!ation potential o" 2i82i
2F
electro!e is =.2#6D. 6" this is co&bine! 'ith a
hy!rogen electro!e in aci! solution at 'hat p7 o" the solution 'ill the &easure! e.&.". be
@ero at 21SC. 3ssu&e N2i
2F
O E 14 an!
2
7
p
E 1 at&I
/30 p7 E ) /$0 p7 E 2
/C0 p7 E # /D0 p7 E 1
)<. 3 hy!rocarbon 'ith &ini&u& nu&ber o" carbon ato&s% capable o" sho'ing geo&etrical
iso&eris& as 'ell as optical iso&eris& isB
/30 #C&ethylpentene /$0 #C&ethylpenteneC2
/C0 )C&ethylhe(eneC2 /D0 )C&ethylhepteneC#
)9. .tan!ar! electro!e potentials "or the gain o" one electron by the ions Cu
F
/aq0 an! Cu
2F
/aq0
are as "ollo's B
Cu
F
/aq0 F e

Cu/s0 S E F =.12 D
Cu
2F
/aq0 F e

Cu
F
/aq0 S E F =.16 D
The stan!ar! potential "or the !isproportion%
2 Cu
F
/aq0 Cu
F2
/aq0 F Cu/s0% 'oul! be
/30 =.6< D /$0 =.#6 D
/C0 F =.#6 D /D0 F =.6< D
1=. >or the calo&el hal"Ccell% 7g% 7g
2
Cl
2
G Cl

/aq0 ,alues o" electro!e potentials are plotte! at

!i""erent log NCl

O. Dariation is represente! by

/30

O
logNCl
C
O
/$0

O
logNCl
C
O
/C0

O
logNCl
C
O
/D0

O
logNCl
C
O
11. The !epression in "ree@ing point o" equi&olal aqueous solution 'ill be highest "or B
/30 C
6
7
1
27
#
Cl /$0 Ca/2O
#
0
2

/C0 :a/2O
#
0
#
/D0 C
6
7
12
O
6

12. The plots o"
1 1
.
A A
vs
X Y
/'here P
3
an! T
3
are the &ole "raction o" liqui! 3 in liqui! an!
,apour phase respecti,ely0 is linear 'ith slope an! intercepts respecti,ely
/30
( )
= =
=
3
= =
P
an!
B
A
B B
P
P
P P

/$0
( )
= =
=
$
= =
P
an!
A
A
B B
P
P
P P

/C0
( )
= =
=
3
= =
P
an!
B
B
A B
P
P
P P

/D0
( )
= =
=
$
= =
P
an!
A
B
A B
P
P
P P

SECTION 2 II
M'lt(le C#rre-t Ans$er T%(e
This section contains ) &ultiple correct ans'er/s0 type questions. ach question has ) choices /30% /$0% /C0 an! /D0% out
o" 'hich ONE OR MORE is8are correct.
1#. 5hat can be sai! about the ,olu&e an! pressure o" one &ole o" a real gas at .TP i" the
,olu&e correction is ignore! an! the pressure correction is ignore! respecti,ely
/Pi E i!eal gas pressure% Pr E real gas pressure0
/30 Pi H Pr /$0 Di H Dr
/C0 Dr H Di /D0 Pr H Pi
1). Correct state&ents are
/30 6.. "or hy!rogen ato& E 1#.6 e,
/$0 6.. o" :i
2F
in the "irst e(cite! state is #=.6eD
/C0 6.. o" $e
#F
in the "irst e(cite! state is 1).) eD
/D0 6.. o" :i
2F
in the "irst e(cite! state in 1=.6 eD
11. 5hen 2a
2
. is a!!e! to so!iu& nitroprussi!e solutionB
/30 ,iolet colour is pro!uce!
/$0 3 co&ple( N>e/C20
1
2O.O
)C
is "or&e!
/C0 The co&ple( 2a
)
N>e/C20
1
2O.O is "or&e!
/D0 2a
2
N>e/C20
1
2O.O is "or&e!
16. Consi!er the "ollo'ing alkene an! select correct alternate/s0
C 7
#
C 7
#
C7
2
/30 3 #S alcohol is "or&e! by aci!ic hy!ration
/$0 3 1S alcoholi s "or&e! by hy!roborationCo(i!ation
/C0 3 race&ic &i(ture o" 2S alcohols is "or&e! by o(y&ercurationC!e&ercuration
/D0 3 race&ic &i(ture o" 1S alcohols is "or&e! by o(y&ercurationC!e&ercuration
SECTION 2 III
Reas#nn! T%(e
This section contains ) reasoning type questions. ach question has ) choices /30% /$0% /C0 an! /D0% out o" 'hich ON9Y
ONE is correct.
CODE
+A/ STATEMENT23 s Tr'e. STATEMENT22 s Tr'e: STATEMENT22 s a -#rre-t e;(lanat#n )#r STATEMENT23
+B/ STATEMENT23 s Tr'e. STATEMENT22 s Tr'e: STATEMENT22 s NOT a -#rre-t e;(lanat#n )#r STATEMENT23
+C/ STATEMENT23 s Tr'e. STATEMENT22 s False
+D/ STATEMENT23 s False. STATEMENT22 s Tr'e
17. STATEMENT?3: 2a
F
ions are !ischarge! in pre"erence to hy!rogen ions at the &ercury
catho!e.
STATEMENT?3: The nature o" the catho!e can a""ect the or!er o" !ischarge o" ions.
1<. STATEMENT?3: =.1 4 solution o" glucose has higher incre&ent in the "ree@ing point than
=.1 4 solution o" urea
STATEMENT?2: ;
"
"or their aqueous solution has sa&e ,alues.
19. STATEMENT?3: ?eo&etry o" .>
)
&olecule can be ter&e! as !istorte! tetrahe!ron% a
"ol!e! square or see sa'.
because
STATEMENT?2: "our "luorine ato&s surroun! or "or& bon! 'ith sulphur ato&.
6=. STATEMENT?3: lectrophilic substitution reaction on cu&&ene is slo'er than toluene.
because
STATEMENT?2: Positi,e in!ucti,e e""ect o" isopropyl group is lesser than &ethyl group.
SECTION 2 IV
9n0e1 C#*(re"ens#n T%(e
This section contains # paragraphs. $ase! upon each paragraph% # &ultiple choice questions ha,e to be ans'ere!. ach
question has ) choices /30% /$0% /C0 an! /D0% out o" 'hich ON9Y ONE is correct.
+ara(raph .r /!est#ns %s0 12 t 13
4olar con!uctance is use! to !e"ine as the con!ucting po'er o" all the ions pro!uce! by one &ole o"
the electrolyte in a gi,en solution.
1===
C
m
K
m


; E speci"ic con!uction% C
&
E concentration at in"inite !ilution each ion &akes itLs contribution
to'ar!s equi,alent con!uctance o" the electrolyte an! at in"inite !ilution equi,alent con!uctance is
gi,en by su& o" equi,alent con!uctance o" the con!ucting ions.

m
x y

+
+
'here ( an! y nu&ber o" ions per "or&ulae unit o" electrolyte. $y &easuring the con!uctance /i0 'e
can calculate !egree o" !issociation an! ;
a
an! ;
b
,alue.
C
=

2
a 2
C
;
1

2
b
C
;
1

/ii0 'e can &easure solubility pro!uct o" sparingly soluble salt. 6" solute is sparingly soluble in a
gi,en sol,ent% its concentration is taken as its solution in the saturate! solution.
C a

+ /

o" salt 'ill be calculate! by ;ohlrauschLs la'0 $y kno'ing C 'e can calculate
;
sp
.
61. The ,alue o"
C
"or =.==1= 4 aqueous solution o" 27
#
'ill be B
/gi,en ;
b
"or 27
#
E 1.6 J 1=
1
%
=
E 2.# J 1=
2
. &
2
&ole
1
0
/30 2.1< J 1=
2
/$0 #.=1 J 1=
#
/C0 1.179 J 1=
1
/D0 1.17 J 1=
)
62. The !egree o" !issociation o" 'ater 'ill be /gi,en
=
/7
F
0 E #.)1<2 J 1=
2
%

=
/O7

0 E 1.9< J 1=
2
.&
2
&ol
1
an! ; E 1.7 J 1=
6
. &
1
0
/30 1.<71 J 1=
7
U /$0 #.)17 J 1=
2
U
/C0 1.27 U /D0 2.161 J 1=
1
6#. The speci"ic con!uctance o" =.==21 4 2a
2
.O
)
solution 'oul! be B
/?i,en resistance o" 2a
2
.O
)
E #26.= oh&% 'hen the sa&e cell is "ille! 'ith 2aCl 'hich has
speci"ic con!uctance o" =.276< oh&
1
&
1
% resistance o" <2.) 0.
/30 =.=7 oh&
1
&
1
/$0 1.7 oh&
1
&
1
/C0 =.=#7 oh&
1
&
1
/D0 .==217 oh&
1
&
1
+ara(raph .r /!est#ns %s0 14 t 11
>orce per unit area applie! by ,apour on the upper thrust on the container at equilibriu& state i.e.%
'hen rate o" e,aporation is equal to rate o" con!ensationQ is calle! ,apour pressure. 6t !epen!s on
te&perature.
The ,apour pressure abo,e a solution o" 1.= g& acetic aci! an! in 1== g& 7
2
O /
2
=
2#.716
H O
P
torr
at 21SC0 'as 2#.) torr V in 1== g& C
6
7
6
/
6 6
=
72.1
C H
P
torr at 21SC0 'as 7= torr. 3ccor!ing to
-aoultLs :a' the ,apour pressure o" a solution containing non*,olatile solute is equal to the ,apour
pressure o" pure sol,ent ti&es the &ole traction o" the sol,ent
i.e.% P
solution
E P
sol,ent
P
sol,ent

The abnor&al beha,ior o" the solution is calculate! by DanLt 7o"" "actor /i0
5hen i H 1 /solute sho's !issociati,e nature0
i M 1 /solute sho's associati,e nature0
i E 1 /solute sho's neither !issociation nor association0
6). >ro& the abo,e !ata% acetic aci! in 'ater sho's
/30 !issociati,e nature
/$0 associati,e nature
/C0 neither !issociati,e nor associati,e nature
/D0 none o" these
61. The &olecular 'eight o" acetic aci! in ben@ene is
/30 6= /$0 12=
/C0 11#.1 /D0 121.1
66. The &olality o" aq. .olution o" acetic aci! is
/30 =.<# /$0 =.1=
/C0 =.#= /D0 =.1=
+ara(raph .r /!est#ns %s0 17 t 19
.tability o" alkenes can be co&pare! by con,erting these co&poun!s to a co&&on pro!uct an!
co&paring the a&ounts o" heat gi,en o"". One possibility 'oul! be to &easure heats o" co&bustion
"ro& con,erting alkenes to CO
2
an! 7
2
O. 7eats o" co&bustion are large nu&bers% ho'e,er% an!
&easuring s&all !i""erence in these large nu&bers is !i""icult. 3lkene o" lo'est heat o" co&bustion
a&ong the iso&eric alkenes is o" lo'est energy an! &ost stable.
.tability o" alkenes are o"ten co&pare! by &easuring the heat o" hy!rogenation the heat gi,en o""
/7S0 !uring catalytic hy!rogenation. 7eats o" hy!rogenation are s&aller nu&bers an! pro,i!e &ore
accurate energy !i""erence.
>or a co&poun! containing &ore than one !ouble bon! 'e &ight e(pect a heat o" hy!rogenation that
is the su& o" the heats o" hy!rogenation o" the in!i,i!ual !ouble bon!s. >or non con+ugate! !ienes
this a!!iti,e relationship is "oun! to hol!. >or con+ugate! !ienes% ho'e,er% the &easure! ,alues are
slightly lo'er than e(pecte!. Cu&ulate! !ienes e,en less stable than nonCcon+ugate! !ienes.
.tabler the alkene lo'er the heat o" co&bustion an! heat o" hy!rogenation. 4ore highly substitute!
!ouble bon!s are usually &ore stable. 6n case o" cycloalkenes co&poun!s ha,ing higher angle strain
are less stable.
67. 6n 'hich a&ong the "ollo'ing co&poun!s heat o" hy!rogenation is &a(i&u& I
/30 C7
2
E C7
2
/$0 C7
2
E C E C7
2
/C0 C7
2
E C7 W C7 E C7
2
/D0 C7
2
E C7 W C7
2
W C7 E C7
2
6<. 4atch the correct option
3lkene 7eat o" 7y!rogenation /*
o
"
7 0 ;cal8&ol
/a0 2 &ethyl * 2 butene /i0 27.6
/b0 trans 2Cpentene /ii0 26.9
/c0 cis 2Cpenteen /iii0 #=.#
/!0 # &ethyl 1 butene /i,0 2<.6
/30 /a0 /i0% /b0 /i,0% /c0 /ii0% /!0 /iii0
/$0 /a0 /ii0% /b0 /i0% /c0 /i,0% /!0 /iii0
/C0 /a0 /ii0% /b0 /i,0% /c0 /iii0% /!0 /i0
/D0 /a0 /iii0% /b0 /i,0% /c0 /i0% /!0 /ii0
69. 3&ong the "ollo'ing pairs in 'hich case the secon! co&poun! has higher heat o"
hy!rogenation than the "irst
/30
%
cis 2Cbutene% transC2Cbutene
/C0
%
1Cbutene% 2Cbutene
6" you ha,e any genuine question paper proble&s please contact the "ollo'ing sub+ect concerne! persons.
,a(er Setter : P92X3$6 $3?7
Mat"e*at-s : Mr. B.,. Sn!" M#7le: 0@@<80>8=84
,"%s-s : Mr. Rs" A"a M#7le: 0@@@@@=203=
C"e*str% : Mr. V0as Man Tr(at" M#7le: 0@@@@<@>3<0
Co mmon P r ac t i ce T es t
XII Std C/F Other Than Spark [79 Batches]
ANSBER CEY
MATDEMATICS ,DYSICS CDEMISTRY
&. N#. Ans$er &. N#. Ans$er &. N#. Ans$ers
3 3 24 3 4= 3
2 $ 2< C 48 C
3 $ 2> $ 4@ C
4 C 2= D <0 C
< 3 28 D <3 C
> C 2@ 3 <2 $
=
$D
30 $D <3 3C
8
CD
33 3$C <4 3$C
@
CD
32 $C << 3$C
30
3$CD
33 3CD <> 3$C
33 $ 34 C <= 3
32 C 3< $ <8 D
33 3 3> D <@ $
34 3 3= $ >0 C
3< D 38 3 >3 $
3> C 3@ C >2 3
3= $ 40 3 >3 3
38 C 43 $ >4 C
3@ C 42 3 >< C
20 $ 43 C >> 3
23 C 44 $ >= $
22 3 4< $ >8 $
23 $ 4> 3 >@ C
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 1
Hints /Solution
MATDEMATICS
1. :et
= 2b c
3 a b c
a b c
1
1

1
1
]
no'
T
= a a
3 2b b b
c c c
1
1

1
1
]
Q
a is orthogonal
aa
t
E i

= 2b c = a a 1 = =
a b c 2b b b = 1 =
a b c c c c = = 1
1 1 1
1 1 1

1 1 1
1 1 1
] ] ]
equating the correspon!ing ele&ents 'e get
1 1 1
a % b % c
2 6 #

2. a
2
* /a F !0a F /a! * bc0i
2
2
a b 1 = a bc ab b!
/a !0 /a! bc0
c ! = 1 ac c! bc !
1 + + 1 1
+ +
1 1 1
+ +
] ] ]

2 2
2 2
a bc a a! a! bc ab b! ab b! =
ac c! ac c! = bc ! a! ! a! bc
1 + + + +

1
+ + + +
]

= =
= =
1

1
]
#. :et p/(0 E a( F b
q/(0 E &( F n
r/(0 E c( F !
require! !eter&inant re!uces to

1 2 #
1 2 #
1 2 #
aa b aa b aa b
&a n &a n &a n
ca ! ca ! ca !
+ + +
+ + +
+ + +

applying c
1
c
1
* c
2
% c
2
c
2
* c
#
'e get
1 2 2 # #
1 2 2 # #
1 2 2 # #
a/a a 0 a/a a 0 aa b
&/a a 0 &/a a 0 &a n
c/a a 0 c/a a 0 ca !
+
+
+
E /a
1
* a
2
0/a
2
* a
#
0
#
#
#
a a aa b
& & &a n =
c c ca !
+
+
+
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 2
). clearly
/s c0/s a0
s/s b0 tan $8 2
tanC8 2 /s a0/s b0
s/s c0

2s 2c a b c
k
2s 2b a b c
+

+

k 1 b c
k 1 a

+
/using co&pen!o an! !i,i!en!o0

k a
b c a
k 1

_


+
,
constant
ca * ba E constant
9. :et
2
a b c
t
abc
+ +

1 1 1
a/a b c0 b/a b c0 c/a b c0
tan tan tan
bc ca ab

+ + + + + +
+ +
E tan
*1
at F tan
*1
bt F tan
*1
ct
1
2
at bt ct at.bt.ct
tan
1 t /ab bc ca0

+ +

' ;
+ +

1
2
/a b c0t /a b c0t
tan
1 t /ab bc ca0

+ + + +

' ;
+ +

E tan
*1
/=0 E =%
11.
a = =
3 = b =
= = c
_

,
Q
GaG E abc
an! a!+
bc = =
3 = ca =
= = ab
_

1
1
= =
a
a!+3 1
3 = =
G 3G b
1
= =
c

_








,
12.
= c b
3 c = a
b a =
_

,
Q
Q
a E a /
Q
a is ske'y sy&&etric0
!et /a0 E !et/a0
E !et/a0
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 3
E !et a
!et a E =
Q
!et a E !et/a0 is not true
!et/a0 E /10
#
!et /a0 E !et a
1#. :et "/(0 E a
=
F a
1
( F a
2
(
2
F A.
" /(0 E = F a
1
F 2a
2
( F A.
or " /=0 E a
1

1
21 22 2# 1 1 1 1 1 1
a 1 1 1 #1 #2 ## 1 1 1
1 1 1 1 1 1 )1 )2 )#
+ + +
E = F = F =
E =
1).
Q
# # #
a b c
b c a /a b c #abc0
c a b
+ +
E /a F b F c0 /a
2
F b
2
F c
2
* ab * bc * ca0 E =
/
Q
a F b F c E =0 /non tri,ial0
an! a
2
F b
2
F c
2
* ab * bc * ca
1
2
Y/a * b0
2
F /b * c0
2
F /c * a0
2
Z H =
11.
1 1
) 1
%
t t
+ Q
A../i0
an!
2 2
6 1
%
t t
+
A../ii0
also % % % are in h.p.

1
1
1
2
t 2 1
)
2
t

+
N"ro& eq./i0O
an!
2
2
1
2
t 2 1
6
#
t

+
N"ro& eq. /ii0O
no'% lie on t
1
(
2
* )( F 1 E =

2
1
1 1
t ) 1 =
# #
_ _
+

, ,
t
1
E #
an! lie on t
2
(
2
* 6( F 1 E =

2
2
1 1
t 6 1 =
2 2
_ _
+

, ,
t
2
E 2
Q
nor&al at Kt
1
L is
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 4
# )
1 1 1
(t yt ct c = + A../iii0
an! nor&al at Kt
2
L is
# )
2 2 2
(t yt ct c = + A../i,0
sol,ing eqs. /iii0 an! /i,0% 'e get point o" intersection is
2 2 # # 2 2
1 2 1 1 2 2 1 2 1 1 2 2
1 2 1 2 1 2 1 2
cYt t /t t t t 0 1Z cYt t /t t t t 0 1Z
%
t t /t t 0 t t /t t 0
_ + + + + +

+ +
,
or
1 2
2#27c 1#921c
% / t #% t <0
26) 26)
_


,
Q

16. both (y E 9 an! (
2
* y
2
E 21 are rectangular hyperbolas

1 2
e e 2

2 2
1 2
e e 2 2 ) + +
/e
1
% e
2
0 lie on (
2
F y
2
E ) A../i0
!irector circle o" eq. /i0 is
(
2
F y
2
E <
/ra!ius0
2
E <
17.
Q
nor&al at Kt
1
L to the hyperbola (y E c
2
is
# )
1 1 1
(t yt ct c = +
but this passes through Kt
2
L then
# )
2 1 1 1
2
c
ct t t ct c =
t
+

2 # )
2 1 1 1 2 2
t t t t t t = +

#
1 2
t t 1
or
2
1 2 1
t t t

1<. :et "/(0 E a
2
(
#
F ab(
2
F ac( F a!
"/(0 has one negati,e root
"/=0 H =
a! H =
19. a
2
(
#
F ab(
2
F ac( F a! E =
has three real roots
a(
2
F b(
2
F c( F ! E =
has t'o positi,e an! one negati,e real roots.
2=. Clearly a(
#
F b(
2
F c( F ! takes t'o turns in N=% 2O.
7ence ( N=% 2O
21.
Q
a is singular

1 # 2
G 3G = 2 ) < =
# 1 1=
+

1/)= * )=0 * #/2= * 2)0 F / F 20 /1= * 120 E =
12 * 2 ) E =
E )
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 5

) 1 1=
3 $ 1 6 1#
1 6 1)
_

+


,
tr/a F b0 E ) F 6 F 1) E 2)
22. "or E #
1 # 1 # 2 )
3 2 ) < an! $ # 2 1
# 1 1= 2 1 )
_ _




, ,
Q
tr/ab0 F tr/ba0 E 2tr /ab0
Q
tr/ab0 E c
11
F c
22
F c
##
E 119

1
7
/tr /ab0 F tr/ba00 E
1
7
/2#<0 E #)
2#.
Q
/a F b0
2
E /a F b0 /a F b0
E a
2
F ab F ba F b
2

E a
2
F b
2
F ab F ba
CDEMISTRY
)7. /30
)7.
2
2i 2i 2e
+
+
2
2i 8 2i
=.2#6D
+

2
27 2e 7
+
+
2
7 8 7
o
cell
=
=.2#6D
+

2
o
cell cell 1=
2
=.=19 N7 O
log
2 N2i O
+
+
+
2
1=
=.=19
=.2#6 log N7 O
2
+
+
* log N7
F
O E )
)<. /C0
)9. /C0
)9.
cell
"or !ispropotionation 'ill be
E .=12 =.16 E =.#6 D.
1=. /C0
1=.
2 2
7g Cl 2 27g F2Cl e

+
2
S
cell
.=191
E log C
2
l

1
]

S
cell
E .=19log Cl

1
]
11. /C0
12. /$0
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 6
=
A A A
P P X an!
=
B B B
P P X
an!
B M B
P P Y

= =
A A B
A B
P X P
Y Y

or
( )
( )
=
= =
1
1
B A
A B B
A B B
P X
P P X
X Y Y

or
( )
= =
=
= =
1 1
.
B A
A
A A B B
P P
P
X Y P P

+
or y E &( F C
slope E & E
=
=
A
B
P
P
an! intercept
C E
( )
= =
=
B A
B
P P
P

1#. 3C
1). 3$C
11. 3$C
16. 3$C
17. /30
1<. /D0
19. /$0
6=. /C0
61. /$0
61.
) #
27 O7/ .27 0 aq

F
)
27 FO7

$y Ost'al!Ls !ilution la'

1
#
1.6 1=
=.1261
C 1 1=
b
K
x

/&olar con!uctance at in"inite !ilution 0 E 2.#< J 1=

2
. &
2
&ol
1
C

/&olar con!uctance at a gi,en concentration0 E

C
x
E =.1261 J 2.#< J 1=
2
. &
2
&ol
1
E #.=1 J 1=
#
. &
2
&ol
1
62. /30
62. C /concentration o" 7
2
O0 E 1=== g
:
1
E
1
1===
&ol :
1<

6
#
1=
&ol &
1<

( ) ( ) ( )
F
= 2 = =
7 O 7 O7

+
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 7
( )
2 2 2 1
#.)9<2 1= 1.9< 1= .& &ol

+
2 1
1.)7<2 1= .&


6 1
6
#
1.7 1=
1=
1<

C
S m
C
mol m
1= 2 1
1.=26 1=

Sm mol
1=
2 1
2 2 1
=
1.=26 1=
1.)7<2 1=
C
S m mol
x
Sm mol

7
1.<71 1= U

6#. /30
6#. .peci"ic con!uctance E
Cell constant
-esistance
Cell constant E =.276< J <2.)
7ence speci"ic con!uctance o" 2a
2
.O
)
5ill be E 22.<18#26 E =.=7 oh&
1
&
1
6). /C0
2
=
2#.716
H O
P
Torr% n7
2
O E
1==
1<
&ol
P
solution
E 2#.) Torr% n 3CO7 E
1
AcOH
M
2
2
=
=
2
H O solution
ACOH
H O
P P
nACOH
X
nH O P

2#.716 2#.) 18
2#.716 1==81<
mACOH

4
3CO7
E 6=.=1 g8&ol
The original ,alue o" 4
3CO7
E 6= g8&ol.
3cO7 re&ains as &ono&er.
61. /C0
6 6
6 6
=
=
6 6
C H solution
C H
P P
nACOH
nC H P

72.1 7= 1 7<
72.1 1== mACOH

&
3CO7
E 11#.1 g&ol
*1
66. /30
& E
2
2
=
=
2
1===
H O solution
H O
P P
mH O P

E
2#.716 2#.) 1===
=.<#
2#.716 1<

67. /$0
6<. /$0
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 8
69. /C0
C+T5637798C/F9Other Than Spark 8XII std9 CODE $ DHAMAKA - 9