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L6 FINALS 2009

SEKOLAH MENENGAH KEBANGSAAN BANDAR UTAMA

NO. 1, PINTASAN BANDAR UTAMA 47800 PETALING JAYA

PEPERIKSAAN AKHIR TAHUN

OKTOBER 2010
FORM LOWER 6 SCIENCE
ONE HOUR FORTY FIVE MINUTES

CHEMISTRY PAPER 1
1 HOURS

Instructions to candidate: DO NOT OPEN THIS QUESTION PAPER UNTIL YOU ARE TOLD TO DO SO. There are fifty questions in this paper. For each question, four suggested answers are given. Choose one correct answer and indicate it on the multiple-choice answer sheet provided. Read the instructions an the multiple-choice answer sheet carefully. Answer all questions. Marks will not be deducted for wrong answers. Arahan kepada calon: JANGAN BUKA KERTAS SOALAN INI SEHINGGA ANDA DIBENARKAN BERBUAT DEMIKIAN. Ada lima puluh soalan dalam kertas ini. Bagi setiap soalan, empat cadangan jawapan diberikan. Pilih satu jawapan yang betul dan tandakan jawapan itu pada helaian jawapan aneka pilihan yang dibekalkan. Baca arahan pada helaian jawapan aneka pilihan itu dengan teliti. Jawab semua soalan. Markah tidak akan ditolak bagi jawapan yang salah. This question paper consists of 11 printed pages. (Kertas soalan ini terdiri daripada 11 halaman bercetak) Lau Kah Pew SMKBU 2010

Section A Four suggested answers labelled A, B, C and D are given for each question. Choose one correct answer.
1.

An element X with the electronic configuration of 1s22s22p63s23p63d104s24p1 exist as isotopes mX and nX which have 38 and 40 neutrons respectively. What is the percentage abundance of mX? [Relative atomic mass of X is 69.7] (STPM 09 P1-1) A) 35.0 B) 45.5 C) 54.5 D) 65.0

STPM CHEMISTRY 962/1

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L6 FINALS 2009

2. A small spacecraft of capacity 10 m3 is connected to another of capacity 30 m3. Before connection, the pressure inside the smaller craft is 50 kPa and that inside the larger one is 100 kPa. If all measurements are made at the same temperature, what is the pressure in the combined arrangement after the connection? (A-lvl(s) D90 P1-5) A) 75 kPa B) 87.5 kPa C) 100 kPa D) 125 kPa 3. The value of PV is plotted against P for two gases, an ideal gas and a non-ideal gas, where P is the pressure and V is the volume of the gas.

Which of the following gasses shows the greatest deviation from reality? A) methane B) ammonia C) ethene D) carbon dioxide

4. A 2 g sample of hydrogen at temperature T and of volume V exerts a pressure P. 2 Deuterium, 1 H, is an isotope of hydrogen. Which of the following would also exert a pressure P at the same temperature T?
(A-lvl(s) J98 P3-8)

A) B) C) D)

2 g of deuterium of volume V. 4 g of deuterium of volume V. a mixture of 1 g of hydrogen and 2 g of deuterium of total volume V. a mixture of 2 g of hydrogen and 1 g of deuterium of total volume 2 V.

5. When heated, solid iodine readily forms iodine vapour. What does this information suggest about the nature of the particles in these two physical states of iodine? A) B) C) D) solid ionic ionic molecular molecular vapour atomic molecular atomic molecular

6. ABABA......... represents an arrangement of layers called A) cubic closed packing B) body-centred cubic packing STPM CHEMISTRY 962/1 C) face-centred closed packing D) hexagonal closed packing 2 [Turn over (Lihat sebelah) CONFIDENTIAL* SULIT*

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(A-lvl(s) D925 P4-18)

L6 FINALS 2009

7. Graphite can be used as a lubricant, diamond cannot. This is because graphite has A) B) C) D) mobile delocalized electrons. a hexagonal arrangement of atoms in layers. covalent bonds between atoms in layers. van der Waals forces between the layers of atoms.

8. Which of the following diagrams correctly represents the Boltzmann distribution of molecular speeds at two temperatures, T1 and T2; where T2 > T1? (A-lvl(s) D92 P4-6) A) C)

B)

D)

9. What is the maximum number of spectral lines that could be produced by electrons going from n = 5 to n = 2, by all possible routes?

A) 2

B) 3

C) 4

D) 5

10. Which of the following is the best reason why electrons are treated as standing waves in the modern quantum theory of the atom? A) B) C) D) The wavelength of an electron depends on its velocity. It is impossible to determine both the location and momentum of an electron. An electron can remain in a particular orbit as long as it emits energy. Spinning charged particles generate a magnetic field.

11. The rule which states that no two electrons in an atom can have the same set of quantum numbers is known as: A) Hunds rule B) Aufbau principle C) Paulis exclusion principle D) Heisenbergs uncertainty principle

STPM CHEMISTRY 962/1

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L6 FINALS 2009

12. A line in the Pfund series (nlow = 5) occurs at 3.74 x 10-6 m. What is nhigh for this transition? The Rydberg constant equals 2.18 x 10-18 J. A) 6 B) 7 C) 8 D) 9

13. Which of the following elements has the highest second ionization energy? (A-lvl(s) D87 P3-1) A) O B) Ne C) Na D) Mg 14. Which equation represents the ionisation energy of magnesium? A) Mg(g) Mg+(g) + e C) Mg(g) Mg2+(g) + 2e B) Mg(s) Mg+(g) + e D) Mg(s) Mg2+(g) + 2e 15. The first to fourth ionization energies of four elements are as follows: Elements P Q R S Ionization energy/kJ mol-1 First 577 418 736 494 Second 1 820 3 070 1 450 4 560 Third 2 740 4 600 7 740 6 940 Fourth 11 600 5 860 10 500 9 540

Which statement about P, Q, R and S is TRUE? (STPM 09 P1-4) A) B) C) D) Q is more electronegative than S. Melting point of S is higher than that of R. Enthalpy of vaporization of Q is higher than that of R. Oxide Q is more basic than oxide P.

16. The ionic radii of four ions are as follows: Ion P+ Q2+ R S Ionic radius/nm 0.095 0.031 0.136 0.126

Which ionic compound has bonding with the greatest covalent character? (STPM 08 P1-5) A) PR B) PS C) QR2 D) QS2 17. Rank the following molecules in order of decreasing ionic character of their bonds. SiCl2 NaCl PF3 A) NaCl > PF3 > SiCl2 B) SiCl2 > PF3 > NaCl STPM CHEMISTRY 962/1 C) NaCl > SiCl2 > PF3 D) PF3 > SiCl2 > NaCl 4 [Turn over (Lihat sebelah) CONFIDENTIAL* SULIT*

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L6 FINALS 2009

18. Polyatomic molecules and ions have varied geometries. Which species and geometry corresponds CORRECTLY? (STPM 09 P1-6) Species A) B) C) D) NH2 H3O
+

Geometry Linear Trigonal planar Square planar T-shape

SiCl4 ICl3

19. Based on the band theory, the conductivity of metal is due to delocalized electrons in the conduction band. How many electrons are found in the conduction band of a 10.0 g magnesium metal strip? [Relative atomic mass of Mg is 24.0; Avogadro constant is 6.02 x 1023 mol-1] (STPM 09 P1-7) A) 2.51 x 1023 B) 5.02 x 1023 C) 2.51 x 1024 D) 3.01 x 1024

20. VSEPR theory is a model for predicting A) the strength of bonds C) how covalent bonding forms B) the shape of molecules D) the type of bonding that occurs 21. The number of and bonds respectively in O 3 is: A) B) C) D) bonds 1 2 1 2 bonds 1 1 2 2

22. Which molecule is planar? A) NF3 B) C2Cl4

C)

C3H6

D) NH4+

23. Which hybridisation occurs at the central atom for SF 4 molecule? A) sp2 B) sp3 C) sp3d D) sp3d2

24. MTBE is a constituent of petrol.

angle P H3C

CH3 C CH3 O

angle Q CH3

What are the values of angle P and Q in the MTBE molecule? A) B) C) D)

(A-lvl(s) J97 P3-4)

angle P 90 90 109.5 109.5

angle Q 105 180 105 180 [Turn over (Lihat sebelah) CONFIDENTIAL* SULIT*

STPM CHEMISTRY 962/1

CONFIDENTIAL*/SULIT* 25. Which of the following isomers is likely to have the highest boiling point? A) CH3CHOHCH3 C) CH3CH2CH2CHO B) CH3CH2CH2Cl D) CH3CH2CH2CH2CH3

L6 FINALS 2009

26. Which of the following statements explain why copper conducts electricity when a potential difference is applied? (A-lvl(s) J91 P1-7) A) electrons combine with the Cu2+ ion. B) bonding electrons in the crystal lattice move. C) Cu2+ ions move from the anode to the cathode. D) electrons are excited from lower energy level to higher energy levels 27. Which type of bond is responsible for intermolecular forces in liquid nitrogen? A) covalent bonding C) induced dipole-induced dipole attractions B) hydrogen bonding D) permanent dipole- permanent dipole attractions 28. What is the bond angle around a triple bond? A) 90 B) 109.5 C) 120

D) 180

29. Trimethylamine, (CH3)3N, reacts with boron trifluoride, BF 3, to form a compound of formula (CH3)3NBF3. How may this reaction be written in terms of the shapes of the reactants and products?
(A-lvl(s) J95 P4-3)

H3C

F N

H3C H3C F H3C N F

F B F

A)

H3C H3C

+
F

H3C

F N

CH3 F N H3C CH3

H 3C H 3C F H3C
H 3C F H 3C H3C N

F B F
F N B F
F B F F

B)

H3C H3C
H3C

B F
F

C)

H3C H3C
H3C

+
F

F N

D)

H3 C H3C

B F

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L6 FINALS 2009

30. Which of the following molecular structures below will have the smallest overall dipole?
H3C Cl C Cl C CH3

H3C

Cl C C Cl CH3 C C Cl

A)

C)
H3C H3C

H3C

CH3 C C Cl

B)
Cl

D)
H3C

31. The graphs of initial rate versus concentration of reactants for the reaction; X + Y Z, are shown below:

What is the order of reaction with respect to X and Y? (STPM 08 P1-8) A) B) C) D) X 0 1 1 2 Y 1 0 2 1

32. The following reaction is first order with respect to [P] and zero order with respect to [Q]. P + Q products If the rate constant doubles for each 10C rise in temperature, which of the following sets of conditions will give the greatest rate of reaction? (A-lvl(s) J88 P3-12) A) B) C) D) [P]/mol dm-3 0.1 0.1 0.3 0.3 [Q]/mol dm-3 0.2 0.3 0.1 0.1 Temperature/ C 40 30 30 20

33. For a first order reaction, rate constant is 0.6932 hr-1. Determine the half-life for the reaction. A) 0.1 hr B) 1 hr C) 2 hrs D) 10 hrs STPM CHEMISTRY 962/1 7 [Turn over (Lihat sebelah) CONFIDENTIAL* SULIT*

CONFIDENTIAL*/SULIT* 34. For the reaction H2(g) + I2(g) 2HI(g), the rate of reaction is expressed as A)
[I2 ] [H 2 ] 1 [HI] t t 2 t

L6 FINALS 2009

C)

[H 2 ] 1 [I2 ] [HI] t 2 t t

B)

[I2 ] [H 2 ] [HI] t t 2 t

D) None of these

35. For the reaction; OCl (aq) + I(aq) OI(aq) + Cl(aq), the following data were collected at constant temperature. What is the rate law for this reaction? Experiment 1 2 3 A) Rate = k [OCl] B) Rate = k [OCl] [I] [OCl] 1.7 x 10-3 3.4 x 10-3 1.7 x 10-3 [I] 1.7 x 10-3 1.7 x 10-3 3.4 x 10-3 C) Rate = k [OCl]2 [I] D) Rate = k [OCl] [I]2 Rate (mol dm-3 s-1) 1.75 x 104 3.50 x 104 3.50 x 104

36. The rate of a gaseous reaction is given by the expression k [A] [B]. If the volume of the reaction vessel is suddenly reduced to th of the initial volume, the reaction rate relating to original rate will be A) 0.10 B) C) 8 D) 16 37. The decomposition of hydrogen peroxide follows a first order kinetic. Which of the following graphs correctly represent this reaction? A) C)

B)

D)

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L6 FINALS 2009

38. Which one of the following correctly represents the units of the rate constant, k, for a second order reaction? A) s-1 B) mol dm-3 s C) mol dm-3 s-1 D) mol-1 dm3 s-1 39. Consider the reaction: S2O82-(aq) + 2I(aq) 2SO42-(aq) + I2(aq) The rate equation is: Rate = k [S2O82-] [I]; where k is the rate constant. Which of the following conclusions can be drawn from this information? A) the reaction goes to completion B) the reaction is second order with respect to I C) the reaction is first order with respect to S2O82D) the value of k depends on the concentrations of S2O82- and I 40. If a reaction involving a single reactant is first order with a rate constant of 4.50 x 10-2 s-1, how much time is required for 75% of its initial concentration of reactant to be used up? A) 16.7s B) 25.3s C) 23.1s D) 30.8s

Section B For each of the questions in this section, one or more of the three numbered statements 1 to 3 may be correct. The responses A to D should be selected on the basis of the following. A 1 only is correct B 1 and 2 only are correct C 2 and 3 only are correct D 1, 2 and 3 are correct

41. Simple ionic crystals have good cleavage planes because the particles in the crystals are
(A-lvl(s) D90 P1-33)

1. arranged in a regular lattice. 2. separated by large distances. 3. held by electrostatic forces. 42. Which of the following statements about the s, p and d orbitals of principal quantum numbers 1, 2 and 3 are TRUE? (A-lvl(s) D90 P1-31) 1. Each s orbital can contain a maximum of two electrons 2. A series of transition elements arises from the filling of d-orbitals. 3. A p-orbital has a higher energy than the s-orbital of the same principal quantum number.

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CONFIDENTIAL*/SULIT* A 1 only is correct B 1 and 2 only are correct C 2 and 3 only are correct D 1, 2 and 3 are correct

L6 FINALS 2009

43. Which of the following is/are part of Bohrs interpretation of the hydrogen line spectrum? 1. different wavelengths of light correspond to electrons dropping between different quantum levels 2. electrons release energy as light as they move to a higher energy level 3. the potential energy of an electron decreases as it moves further from the nucleus 44. Choose the statement(s) that are TRUE 1. Outer electrons can penetrate the electron cloud of inner electrons. 2. Outer electrons experience partial nuclear charge 3. The 2s and 2p electrons are of different energy levels except in hydrogen atoms. 45. The Group 2 metals have higher melting points than the Group 1 metals. Which factors could contribute towards the higher melting points? (A-lvl(s) J97 P3-35) 1. There are smaller interatomic distances in the metallic lattices of Group 2 metals. 2. Two valency electrons are available from each Group 2 metal atom for bonding the atoms into the metallic lattice. 3. Group 2 metals have higher first ionization energies. 46. The melting and boiling points of sulphur are higher than chlorine because 1. Sulphur form larger and heavier molecules. 2. Chlorine has a higher relative atomic mass. 3. Sulphur molecules are more polarized compared to chlorine molecules. 47. The bond lengths and bond angles in the molecules of methane, ammonia and water may be represented as follows:

What causes this trend in the bond angles shown? (A-lvl(s) J92 P4-31) 1. Increasing repulsion between hydrogen atoms as the bond length decreases. 2. The number of non-bonding electron pairs in the molecule. 3. A non-bonding electron pair having a greater repulsive force than a bonding electron pair.

STPM CHEMISTRY 962/1

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CONFIDENTIAL*/SULIT* A 1 only is correct B 1 and 2 only are correct C 2 and 3 only are correct D 1, 2 and 3 are correct

L6 FINALS 2009

48. Select the compound that has resonance structures 1. SO2 2. HCOO 3. NO2 49. After an oil spillage at sea, a liquid hydrocarbon layer floats on the surface of the water. Which of the following statement(s) help explain why liquid hydrocarbons both float on, and are less dense water? (A-lvl(s) D90 P1-32) 1. There are only van der Waals interactions between hydrocarbon molecules. 2. Hydrogen bonding between molecules in liquid water causes them to pack closer together. 3. Hydrocarbon molecules are not solvated by water. 50. The rate equation for the reaction: 2A + B + C products; is Rate of reaction = k [A] [B]2 It can be concluded that 1. the overall order of reaction is 3 2. the rate of reaction will increase 8 folds when concentration A, B and C are doubled 3. the amount of products is not dependant on the amount of C used.

END OF QUESTION PAPER

Prepared by, (LAU KAH PEW) Subject Teacher

Checked by,

Verified by,

STPM CHEMISTRY 962/1

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L6 FINALS 2009

PV non-ideal gas

ideal gas

Proportion of molecules

T2 T1

Molecular speed

STPM CHEMISTRY 962/1

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