SOLUTIONS & ANSWERS FOR KERALA ENGINEERING

ENTRANCE EXAMINATION-2014
VERSION A1

[PHYSICS & CHEMISTRY]

1. Ans: 8%

Sol:
T
T
2
g
g
+

l
l

= 2% + 2 3% = 8%

2. Ans: 1 mm and 50


Sol: LC =
50
1
= 0.02 mm

3. Ans: 78.4 m

Sol: t =
r
v
s

= 4
25
100
= s
fall h =
2
gt
2
1

=
2
4 8 . 9
2
1

= 78.4 m

4. Ans: 1 : 3 : 5

Sol: S1 : S2 : S3 = 1 : 3 : 5 : .

5. Ans: 1 m s
1


Sol: S =
2
at
2
1
ut +
12 = 9 a
2
1
3 u +
42 = 36 a
2
1
6 u +
Solving a = 2 m s
2

u = 1 m s
1


6. Ans: 27 m s
1


Sol: p = 2mv = 2 10
3
10 v
v =
3
10 20
54 . 0

= 27 m s
1


7. Ans: k

3 j

+ +

Sol: p r L =
= ( ) ( ) k

2 k

2 i

+ +
= k

3 j

+ +

8. Ans: zero

Sol: zero at maximum height
9. Ans: 10t

Sol: vx = 8t
vy = 6t
v =
2
y
2
x
v v + = 10t

10. Ans: Provide required centripetal force

11. Ans: 40 N

Sol: a = 20
6
120
=
F = ma = 2 20
= 40 N

12. Ans: 5.25 J

Sol: KEtota =
2
mv
10
7

= 0.7 0.3 5
2

= 5.25 J

13. Ans: 6.66 cm

Sol: 20 a 2 v
2
v
2
2
= |

\
|

40a =
2
v
4
3

v
2
= 2a(20 + x)
v
2
= ( ) x 20 v .
160
3
. 2
2
+
x = 6.66 cm

14. Ans: Both momentum and kinetic energy are
conserved

15. Ans: 0.5 10
3
kg m
2

Sol: L1 + L2 = L
11 + 22 = L
x 2 + 5 10
3
= (x + 10
3
) 4
x = 0.5 10
3


16. Ans:
2

Sol: = 0 + t
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=
t
0


=
4
2
60 2
0 30 2
=

rad s
2

=
2

rad s
2


17. Ans:
3
2
mr
L


Sol: L = mvr
F =
2
2
mr
L
r
m
r
mv
|

\
|
=
=
3
2
mr
L


18. Ans: Gravitational potential energy
=
body the of mass
potential n gravitatio


19. Ans:
2
mgR


Sol:
R 2
GMm
R 2
GMm
R
GMm
=
=
2
mgR
R 2
m
. R .
R
GM
2
2
=

20. Ans:
2
mv
2
1


Sol: Total energy = KE
=
2
mv
2
1


21. Ans:
2
2
2
1
r r +

Sol: p1V1 + p2V2 = pV

3 3
2
2
3
1
1
r
3
4
.
r
T 2
r
3
4
.
r
T 2
r
3
4
.
r
T 2
= +
r =
2
2
2
1
r r +

22. Ans: Bulk modulus

23. Ans: 13.6 cm

Sol: hg = hwwg
hw =
3
3 3
w 10
10 6 . 13 10 10 h
=

= 13.6 10
2
m = 13.6 cm

24. Ans: 3 J

Sol: J 1 kx
2
1
2
=
( ) 1 10 k
2
1
2
3
=

k = 2 10
6

4 10 4 k
2
1
6
=


( )
(

2
3
10 k
2
1
4 = 4 1 = 4
Additional work = 4 1 = 3 J

25. Ans: m
1/2
T
1/2


Sol: v =
2
1
2 / 1
m T
m
kT 3



26. Ans: 250 K, 200 K

Sol: = 2 . 0
T
T T
1
2 1
=

( )
1
2 1
T
50 T T
= 0.4
4 . 0
T
50
T
T T
1 1
2 1
= +

T1 = 250 K
T2 = 200 K

27. Ans: 3R

Sol: 6 degrees
2
R
per mole per degree
= 3R

28. Ans: 5

Sol: Diatomic 3 + 2 = 5 degrees of freedom

29. Ans: s
2

Sol:
2
2
dt
y d
= 2y

2
2
dt
y d
=
2
y
= 2
T = s
2
2
=

30. Ans: The effective spring constant K of springs
in parallel is given by .....
K
1
K
1
K
1
2 1
+ + =

31. Ans: 50 J

Sol: TE = 100 A m
2
1
2 2
=
KE = ( )
2 2 2
x A m
2
1


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=
(
(
(

|
|

\
|

2
2
2
A
A m
2
1

=
2
A
m
2
1
2
2

= 50 J

32. Ans:
k 2

Sol: Combined form
2A sinkx cos kct
For antinode
sinkx = 1
kx =
2

x =
k 2

33. Ans: 4 and 3

Sol:


4 N and 3 A

34. Ans: In a stretched string, the first overtone is
the same as the second harmonic

35. Ans: 44.27 C

Sol: F = qE =
0
2
. e

=
0
2
E
= 20 10
7

A = 0.25 2 8.854 10
12
10
+7

= 44 C

36. Ans: QV
2
1


37. Ans: Product of the charges

38. Ans:
2 1
3 2
0
q q
mr 16


Sol:
2
2 1
2
r
q kq
r
mv
=
v =
r
q q
.
m
k
2 1

T =
2 1
q kq
mr
r 2
v
r 2
=

=
2 1
3 2
0
2 1
0
3 2
q q
mr 16
q q
4 mr 4
=





39. Ans: 10 V

Sol: F = qE, E =
q
F
= 500 N C
1

V = Ed = 500 2 10
2

= 10 V

40. Ans: 16 V

Sol: Equivalent circuit is








4 4 V = 16 V

41. Ans: 125 (Assuming 10 V instead of 10 )

Sol: 2
R 500
R 10
=
+

R = 125

42. Ans: 1

Sol:
5
r
R
E
r 5 R
E 5
+
=
+

R + 5r = 5R + r
4r = 4R
R = r
1
r
R
=

43. Ans: V
2

P = V, =
V
P

Loss in transmission =
2
r
=
2 2
2
V
1
r .
V
P


44. Ans: 6 kJ

Sol:
2
Rt = 1
2
50 120
= 6000 J
= 6 kJ

45. Ans: Introducing a medium of higher
permeability.

46. Ans: 4 Am
2


Sol: T =
mB
2


T
2
=
mB
4
2


A A A
N N
N N
2
2 4 V
2
2
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m =
2
2
BT
. 4


=
( )
4
75 . 0 10 16
10 9 4
2 5 2
5 2
=

Am
2


47. Ans: Sodium paramagnetic (contains
unpaired electron in 3 s orbital)

48. Ans: 2
2
m
2
r
2


Sol: KE = 2
2
m
2
r
2


49. Ans: 2MB

Sol: MB cos0 MB cos180
= 2MB

50. Ans: Lenzs law

51. Ans: The current and voltage are in phase

52. Ans: V

Sol: = r
2
B
= B = 0.01

dt
d
= BA cost

max
E = BA = 0.01 100 = volt

53. Ans: 55

Sol: Current step up
Voltage step down
ns =
6
n
p
= 55

54. Ans: 2.21 10
12
J m
2


Sol: U =
2
0
E
2
1

=
2 12
1 10 86 . 8
2
1



= 4.43 10
12

Average U =
12
10 43 . 4
2
1


= 2.21 10
12
J m
2


55. Ans: The energy contribution of both electric
and magnetic fields are equal.

56. Ans: Refraction

57. Ans:
|
|

\
|

3
1
sin
1


Sol: tan 60 = n = 3
sinC =
3
1
n
1
=
C =
|
|

\
|

3
1
sin
1


58. Ans: For rear view concave mirror

59. Ans: The wavelength of the source is
increased

Sol: =
d
D


60. Ans: |

\
|

5
2
sin
1


Sol: sin =
6
10
10 5 . 2
10 5000 2
b
2

= 0.4
= sin
1
(0.4) = |

\
|

5
2
sin
1


61. Ans:
e
p
m
m


Sol: =
m
1
mE 2
h
p
h
=

e
p
p
e
m
m
=

62. Ans: 40 minutes

Sol: For 50% decay 1 half life
For 100 87.5 = 12.5% decay time is 3
half life
Interval = 2 half life
= 40 minutes

63. Ans:
9
25


Sol: R A
1/3


3
5
27
125
R
R
3 / 1
A
Te
= |

\
|
=
l


9
25
3
5
A
A
2
2
2
1
= =

64. Ans: more than twice its initial value

Sol: KE = h
KE = 2h
more than double

65. Ans: whole of the positive charge is
concentrated at the centre of atom.

66. Ans: 2.5 and 2 MeV

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67. Ans: 0, 0, 1

68. Ans: 245

Sol:
B
C
R
R
.

69. Ans: a heavily doped p n junction with
forward bias

70. Ans: Fax transmission (all others are
broadcasting)

71. Ans: Rh 8

Sol: Rh 8 Rh 2 2 =

72. Ans: 3 to 30 MHz

73. Ans: 6.66 10
20

Sol:
7
8 34
10 626 . 6
10 3 10 626 . 6 hc
E

=
= 3 10
19
J
No. of photons =
19
10 3
8 . 0 250

= 6.66 10
20


74. Ans: 911.7
o
A

Sol:
(
(

=
2
2
2
1
H
n
1
n
1
R
= cm
109678
1
R
1
H
=
= 911.7
o
A

75. Ans: 1.92 10
19
J

Sol: KE = h h0
= 1.2 eV
= 1.92 10
19
J

76. Ans: to separate one mole of solid NaCl into
one mole of Na
+
(g) and one mole of Cl

(g)
to infinite distance

Sol: NaCl(s)
H
lattice
Na
+
(g) + Cl

(g)

77. Ans:
+ +
< < <
2 2 2 2
O C Li He

Sol: Bond order of C2 = 2, Li2 = 1,
+
2
O = 2.5
and
+
2
He = 0.5
Stability is of the order

+ +
< < <
2 2 2 2
O C Li He

78. Ans: SF4 Tetrahedral

Sol: SF4 see saw

S
F
F
F
F


79. Ans: Triclinic

Sol: K2Cr2O7 belongs to triclinic system

80. Ans: 2 atm

Sol: P =
41
500 082 . 0 2
V
nRT
= = 2 atm

81. Ans: 80

Sol: M
P
1

M2 =
2
5 32
= 80 g mol
1

82. Ans: hydroformylation

Sol: Hydroformylation of olefins yields
aldehydes

83. Ans: (i), (iii), (iv)

Sol: No. of electrons in
(i) NH3 = 10
(ii)
+
3
CH = 8
(iii)

2
NH = 10
(iv)
+
4
NH = 10

84. Ans: K2SO4

Sol: The substance which give lilac colour in
flame test is potassium
K2SO4 + BaCl2
ppt white
4
BaSO + 2KCl

85. Ans:
+
4
NH

Sol: The central atom N in
+
4
NH is sp
3

hybridised

86. Ans: They are all paramagnetic in nature

Sol: Interhalogen compounds are diamagnetic
in nature

87. Ans: The two oxygen-oxygen bond lengths in
O3 are different

Sol: The two oxygen-oxygen bond lengths in
the ozone molecule are identical (128 pm)

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88. Ans:
+
> >
2
2
7 2 4
VO O Cr MnO

Sol: The correct decreasing order is due to the
increasing stability of the lower species to
which they are reduced

89. Ans: 5, 1, 3

Sol: s e 5 Mn O Mn
2
4
7
+
+



+

+
e 1 O Mn O Mn
2
4
6
4
7

s e 3 O Mn O Mn
2
4
4
7

+


90. Ans: 4.90 BM

Sol: M
2+
(Z = 24) [Ar] 3d
4
4s
0

= ) 2 n ( n + BM
= ) 2 4 ( 4 + = 4.9 BM

91. Ans: 100 J K
1


Sol: A(
l
) A(g) S = 58 J K
1
mol
1

For A(g) A(
l
)
S =
58
100

58 J K
1

= 100 J K
1


92. Ans: 2.5 10
4


Sol: = 1 . 0
400
40
0
c
= =

Ka = C
2
= 0.025 10
2

= 2.5 10
4


93. Ans: 1.6 10
3


Sol: No. of moles of C = 2
50
1

= 0.04
Partial pressure of C =
V
nRT


6 . 24
300 082 . 0 04 . 0
=
= 0.04
Kp = p
2
C = 1.6 10
3
atm
2

94. Ans: 5 10
7

Sol: [OH

] = 10
2
mol / L
[X
2+
] = 5 10
3
mol / L
KSP = 5 10
3
10
4

= 5 10
7
mol
3
L
3


95. Ans: 400

Sol: 0.125 =
1
W 6 . 111
1000 3 86 . 1

W1 = 400g

96. Ans: 5

Sol: D.O concentration = 5 mg / kg water
ppm = 5

97. Ans: decreases by 60 mV

Sol: Cu
2+
+ 2e

Cu
] Cu log[
2
06 . 0
E E
2
el el
+
+ =
o


2
2
1
2
el el
] Cu [
] Cu [
log 03 . 0 E E
2 1 +
+
=
= 0.03 2 = 0.06 V

98. Ans: E3 > E2 > E1

Sol: E1 = E 0.03
E2 = E
E3 = E +0.03
E3 > E2 > E1

99. Ans: 0.03 mol L
1
min
1

Sol:
dt
] A [ d
= 0.02 mol L
1
min
1

02 . 0
2
3
dt
] C [ d
=
= 0.03 mol L
1
min
1


100. Ans: rate = k
2
2 4
] NO [ ] NH [
+


Sol: From expt 3 and 1
rate
2
2
] NO [


From expt 1 and 2
rate ] NH [
4
+

rate = k
2
2 4
] NO [ ] NH [
+


101. Ans: reduction of gold (III) chloride with formalin

Sol: 2AuCl3 + 3HCHO + 3H2O
reduction

2Au(sol) + 3HCOOH + 6HCl

102. Ans: Diaminetetraaquacobalt(III) chloride

Sol: According to IUPAC rules

103. Ans: methanal and 3-pentanone

Sol: CH
3
CH
2
C CH
2
CH
2
CH
3

O H / Zn ) ii (
O ) i (
2
3



HCHO + CH
3
CH
2
C CH
2
CH
3
O








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104. Ans: trans-2-butene is formed

Sol: CH3CCCH3
3
NH liq
Na


C C
CH
3
H
3
C
H
H


105. Ans: RI > RBr > RCl > RF

Sol: Order of reactivity of alkyl halides :
RI > RBr > RCl > RF

106. Ans: 2,2-dimethylpropanal

Sol: CH
3
C CHO
CH
3
CH
3

(2,2-Dimethylpropanal)
Since it does not contain H, it does not
undergo aldol condensation

107. Ans: mixture of 2-methylpentane and
3-methylpentane

Sol: n-hexane undergoes isomerisation when
heated with AlCl3 / HCl(g) to a give a
mixture of 2-methylpentane and 3-methyl
pentane

108. Ans: 4

Sol: The isomers are

ClCH
2
CH CH
2
CH
3
CH
3
,

CH
3
CCl CH
2
CH
3
CH
3
,

CH
3
CH CHCl CH
3
and
CH
3

CH
3
CH CH
2
CH
2
Cl
CH
3

109. Ans: carbonyl chloride

Sol: CHCl3

h
O
2
COCl2 + HCl

110. Ans: Diphenyl methanol

Sol: Alcohols of the type CH3CHOHR
(where R=H or alkyl or aryl group)
undergo iodoform reaction. Diphenyl
methanol (C6H5CHOHC6H5) does not
undergo iodoform reaction

111. Ans: two moles of ethanal

Sol:
NaOH . dil
3
CHO CH 2
CH
3
CH CH
2
CHO
OH

CH3CH=CHCHO

112. Ans: IV < I < II < III

Sol: Presence of electron withdrawing group in
benzoic acid increases the acid strength
while presence of electron donating group
decreases the acid strength

113. Ans: 2-methylbenzaldehyde

Sol:
CHO
CH
3

] O [
COOH
COOH


114. Ans: Carbylamine reaction

Sol: C6H5NH2 + CHCl3 + 3KOH
C6H5NC + 3KCl + 3H2O

115. Ans: (iv) > (ii) > (iii) > (i)

Sol: Aliphatic 2 amines are more basic than
1 and 3 amines. Aryl amines are less
basic than NH3

116. Ans: ethanamine

Sol: Gabriels phthalimide synthesis is used for
the preparation of aliphatic 1 amines

117. Ans: -D-ribose

Sol: Sugar present in RNA is -D-ribose

118. Ans: initial product obtained in the
condensation of phenol and formaldehyde
in the presence of acid catalyst

Sol: Phenol and formaldehyde undergo
polymerization to form novolac and
bakelite

119. Ans: glycogen

Sol: Glycogen is known as animal starch

120. Ans: utilization of existing knowledge base for
reducing the chemical hazards along with
developmental activities

Sol: It is the definition of green chemistry

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