You are on page 1of 40

This booklet contains 40 printed pages.

S c 40

PAPER - 1

S -

No. :

RST

: MATHEMATICS, PHYSICS & CHEMISTRY


1 : , U

Do not open this Test Booklet until you are asked to do so.

Read carefully the Instructions on the Back Cover of this Test Booklet.

S
Important Instructions :

1. Immediately fill in the particulars on this page of the Test


Booklet with Blue/Black Ball Point Pen. Use of pencil is strictly
prohibited.
2. The Answer Sheet is kept inside this Test Booklet. When you
are directed to open the Test Booklet, take out the Answer
Sheet and fill in the particulars carefully.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum
marks are 360.
5. There are three parts in the question paper A, B, C
consisting of Mathematics, Physics and Chemistry having
30 questions in each part of equal weightage. Each question
is allotted 4 (four) marks for correct response.
6. Candidates will be awarded marks as stated above in instruction
No. 5 for correct response of each question. (one fourth) marks
will be deducted for indicating incorrect response of each question.
No deduction from the total score will be made if no response is
indicated for an item in the answer sheet.
7. There is only one correct response for each question. Filling
up more than one response in any question will be treated as
wrong response and marks for wrong response will be
deducted accordingly as per instruction 6 above.
8. Use Blue/Black Ball Point Pen only for writing particulars/
marking responses on Side-1 and Side2 of the Answer Sheet.
Use of pencil is strictly prohibited.
9. No candidate is allowed to carry any textual material, printed
or written, bits of papers, pager, mobile phone, any electronic
device, etc. except the Admit Card inside the examination
hall/room.
10. Rough work is to be done on the space provided for this
purpose in the Test Booklet only. This space is given at the
bottom of each page and in one page (Page 39) at the end of
the booklet.
11. On completion of the test, the candidate must hand over the
Answer Sheet to the Invigilator on duty in the Room/Hall.
However, the candidates are allowed to take away this Test
Booklet with them.
12. The CODE for this Booklet is G. Make sure that the CODE
printed on Side2 of the Answer Sheet is the same as that on
this booklet. In case of discrepancy, the candidate should
immediately report the matter to the Invigilator for
replacement of both the Test Booklet and the Answer Sheet.
13. Do not fold or make any stray mark on the Answer Sheet.

( )

: in figures

: in words

Examination Centre Number :

Name of Examination Centre (in Capital letters) :

U ( U )
Candidates Signature :


1. U S cU U U /
U
2. U U S U U U S
, U U U U
3. U 3 U
4. U S 90 360
5. U S A, B, C ,
, U 30 U
U 4 (U)
U
6. U U 5
U U
U U U
# U
7. U U U
U U U 6 U U

8. U cU-1 cU-2 U U U U
U / U U

9. U mU U / U U
U , S, , U,
U U U U
U
10. U U S U U
cU U U U S cU U
(cU 39)
11. U U, U / U U
U U U S

12. S G U S
, U cU-2 U U U
U U U S U U U
U U
13. U U

Name of the Candidate (in Capital letters ) :


Roll Number

Test Booklet Code

1. Invigilators Signature :

2. Invigilators Signature :

PART A MATHEMATICS
1.

If x521 and x52 are extreme points of


f(x)5a log

2.

?x?1bx21x

(1)

a526, b52

(2)

a52, b52

(3)

a52, b5

(4)

a526, b5

1.

then :

1
2

1
2

1
2

1
2

The locus of the foot of perpendicular

2.

drawn from the centre of the ellipse


x213y256 on any tangent to it is :

3.

x521

x52,

f(x)5a log ?x?1bx21x


(1)

a526, b52

(2)

a52, b52

(3)

a52, b5

(4)

a526, b5

U ,

1
2

1
2

1
2

1
2

x213y256 S
U U

(1)

(x22y 2)256x 222y 2

(1)

(x22y 2)256x 222y 2

(2)

(x21y 2)256x 212y 2

(2)

(x21y 2)256x 212y 2

(3)

(x21y 2)256x 222y 2

(3)

(x21y 2)256x 222y 2

(4)

(x22y 2)256x 212y 2

(4)

(x22y 2)256x 212y 2

1
(sin k x 1 cosk x ) where
k
x e R and k/1. Then f4(x)2f6(x) equals :

Let f k ( x ) 5

3.

1
(sin k x 1 cosk x ) ,
k
x e R k/1 , f4(x)2f6(x) UU

fk ( x ) 5

(1)

1
3

(1)

1
3

(2)

1
4

(2)

1
4

(3)

1
12

(3)

1
12

(4)

1
6

(4)

1
6

G/Page 2

SPACE FOR ROUGH WORK /

4.

X5{4 n 23n21 : n e N}

natural numbers, then XY is equal to :

Y5{9(n21) : n e N} , N,
, XY UU

(1)

Y2X

(1)

Y2X

(2)

(2)

(3)

(3)

(4)

(4)

If

X5{4 n 23n21

N}

and

4.

Y5{9(n21) : n e N}, where N is the set of

5.

equals :

333
AA95A9A B5A21 A9 , BB9 UU

(1)

(1)

(2)

B21

(2)

B21

(3)

(B21)9

(3)

(B21)9

(4)

I1B

(4)

I1B

If A is an 333 non - singular matrix such


that AA95A9A and

B5A21

5.

A9, then BB9

6.

1 x1
The integral 1 1 x 2 e x d x is

6.

1 x1
1 1 x 2 e x d x
x

equal to :
1
x1
x
e

(1)

(2)

(x11) e

(3)

(4)
G/Page 3

2x

1c
1
x1
x

1
x1
x
e

(x21)

1c

1c

1
x1
x
e

1c

SPACE FOR ROUGH WORK /

1
x1
x
e

(1)

(2)

(x11) e

(3)

(4)

2x

1c
1
x1
x

1
x1
x
e

(x21)

1c

1c

1
x1
x
e

1c

UU

7.

The area of the region described by


A5{(x, y) :

8.

x21y2

[ 1 and

y2

7.

[ 12x} is :

mU

A5{(x, y) : x21y2 [ 1

(1)

p
4
2
2
3

(1)

p
4
2
2
3

(2)

p
2
2
2
3

(2)

p
2
2
2
3

(3)

p
2
1
2
3

(3)

p
2
1
2
3

(4)

p
4
1
2
3

(4)

p
4
1
2
3

2x2y1z1350

The image of the line

8.

y 23
x 21
z 24
5
5
in the plane
3
1
25

2x2y1z1350 is the line :

y2 [ 12x}

y 23
x 21
z 24
5
5
3
1
25

(1)

y 25
x 13
z 12
5
5
23
21
5

(1)

y 25
x 13
z 12
5
5
23
21
5

(2)

y 15
x 23
z 22
5
5
25
3
1

(2)

y 15
x 23
z 22
5
5
3
1
25

(3)

y 15
x 23
z 22
5
5
23
21
5

(3)

y 15
x 23
z 22
5
5
23
21
5

(4)

y 25
x 13
z 22
5
5
25
3
1

(4)

y 25
x 13
z 22
5
5
3
1
25

G/Page 4

SPACE FOR ROUGH WORK /

9.

The variance of first 50 even natural

9.

50 U

numbers is :

10.

(1)

833

(1)

833

(2)

437

(2)

437

(3)

437
4

(3)

437
4

(4)

833
4

(4)

833
4

If z is a complex number such that ?z?/2,


then the minimum value of z 1

10.

1
:
2

z ?z?/2 ,
z1

1
2

(1)

lies in the interval (1, 2)

(1)

(2)

is strictly greater than

5
2

(2)

5
2

UU

(3)

is strictly greater than

(3)

3
2

UU U

(4)

5
2

UU

than

(4)
G/Page 5

3
but less
2

(1, 2)

5
2

is equal to

5
2

SPACE FOR ROUGH WORK /

5
2

11.

Then the common ratio of the G.P. is :

U
U U
, U
U

(1)

31

(1)

31

(2)

22 3

(2)

22 3

(3)

21 3

(3)

21 3

Three positive numbers form an increasing

11.

G.P. If the middle term in this G.P. is


doubled, the new numbers are in A.P.

(4)

12.

(4)

21 3

If the coefficients of x 3 and x 4 in the

12.

expansion of (11ax1bx 2 ) (122x) 18 in


powers of x are both zero, then (a, b) is

21 3

(11ax1bx2) (122x)18 x
U x3 x4, , (a, b)
UU

equal to :

13.

(1)

14 , 251

(1)

14 , 251

(2)

14 , 272

(2)

14 , 272

(3)

16 , 272

(3)

16 , 272

(4)

16 , 251

(4)

16 , 251

Let a, b, c and d be non-zero numbers. If

13.

the point of intersection of the lines


4ax12ay1c50 and 5bx12by1d50 lies
in the fourth quadrant and is equidistant

a, b, c d U U
4ax12ay1c50 5bx12by1d50
U Z
US ,

from the two axes then :


(1)

2bc13ad50

(1)

2bc13ad50

(2)

3bc22ad50

(2)

3bc22ad50

(3)

3bc12ad50

(3)

3bc12ad50

(4)

2bc23ad50

(4)

2bc23ad50

G/Page 6

SPACE FOR ROUGH WORK /

14.

15.

If a3b b3c c3a 5l a b c then l is


equal to :

14.


2
a3b b3c c3a 5l a b c

UU

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Let A and B be two events such that


P (A B) 5

P (A ) 5

1
,
6

P (A B) 5

1
4

15.

P (A B) 5

and

1
, where A stands for the
4

P (A ) 5

1
4

, l

1
,
6

P (A B) 5

A U

1
4

U A B

complement of the event A. Then the


events A and B are :

16.

(1)

equally likely but not independent.

(1)

U S

(2)

independent but not equally likely.

(2)

S U

(3)

independent and equally likely.

(3)

(4)

mutually exclusive and independent.

(4)

USU S

(1, 21) and parallel to PS is :

PS
P(2, 2), Q(6,21) R(7, 3) (1, 21)
U U, PS U ,
U

(1)

2x19y1750

(1)

2x19y1750

(2)

4x17y1350

(2)

4x17y1350

(3)

2x29y21150

(3)

2x29y21150

(4)

4x27y21150

(4)

4x27y21150

Let PS be the median of the triangle with

16.

vertices P(2, 2), Q(6,21) and R(7, 3). The


equation of the line passing through

G/Page 7

SPACE FOR ROUGH WORK /

17.

18.

lim

sin ( p cos 2 x )
x2

x 0

is equal to :

17.

lim

sin ( p cos 2 x )
x2

x 0

(1)

(1)

(2)

2p

(2)

2p

(3)

(3)

(4)

p
2

(4)

p
2

Let a and b be the roots of equation

18.

px21qx1r50, p0. If p, q, r are in A.P.


and

1
1
1 5 4 , then the value of ?a2b?
a
b

a b U px21qx1r50, p0
p, q, r U
1
1
1 54
a
b

, ?a2b?

is :

19.

(1)

2 17
9

(1)

2 17
9

(2)

34
9

(2)

34
9

(3)

2 13
9

(3)

2 13
9

(4)

61
9

(4)

61
9

A bird is sitting on the top of a vertical

19.

pole 20 m high and its elevation from a


point O on the ground is 458. It flies off
horizontally straight away from the
point O. After one second, the elevation
of the bird from O is reduced to 308. Then

20 . U U
U U O
458 O U
U , O
U U 308 U (. . )

the speed (in m/s) of the bird is :


(1)

40 ( 3 2

(2)

(1)

40 ( 3 2

20 2

(2)

20 2

(3)

20 ( 3 2 1)

(3)

20 ( 3 2 1)

(4)

40 ( 2 2 1)

(4)

40 ( 2 2 1)

G/Page 8

2)

SPACE FOR ROUGH WORK /

2)

20.

If a e R and the equation

20.

23(x2[x])212 (x2[x])1a250

(where [x] denotes the greatest integer


possible values of a lie in the interval :

( [x] Z
[ x ) Z , a
U S ,

(1)

(1, 2)

(1)

(1, 2)

(2)

(22, 21)

(2)

(22, 21)

(3)

(2:, 22) (2, :)

(3)

(2:, 22) (2, :)

(4)

(21, 0) (0, 1)

(4)

(21, 0) (0, 1)

21.

The integral
p

22.

aeR

23(x2[x])212 (x2[x])1a250
[ x) has no integral solution, then all

21.

x
x
1 1 4 sin
2 4 sin d x equals :
2
2
2

1 1 4 sin 2

x
x
2 4 sin d x
2
2

(1)

2p
2 42 4 3
3

(1)

2p
2 42 4 3
3

(2)

4 324

(2)

4 324

(3)

4 3 2 42

(3)

4 3 2 42

(4)

p24

(4)

p24

p
3

UU

p
3

f (1)56, then for some ce]0, 1[ :

f g, [0, 1]
f (0)525g(1), g(0)50 U f (1)56 cU
U , ce]0, 1[

(1)

2f 9(c)53g9(c)

(1)

2f 9(c)53g9(c)

(2)

f 9(c)5g9(c)

(2)

f 9(c)5g9(c)

(3)

f 9(c)52g9(c)

(3)

f 9(c)52g9(c)

(4)

2f 9(c)5g9(c)

(4)

2f 9(c)5g9(c)

If f and g are differentiable functions in

22.

[0, 1] satisfying f (0)525g(1), g(0)50 and

G/Page 9

SPACE FOR ROUGH WORK /

23.

24.

If g is the inverse of a function f and


1
, then g9 (x) is equal to :
f 9 (x)5
1 1 x5
(1) 5x 4

23.

, g9 (x) UU
(1)

5x 4

(2)

1 1 { g ( x )}

(2)

1 1 { g ( x )}

(3)

11{g(x)}5

(3)

11{g(x)}5

(4)

11x 5

(4)

11x 5

If (10) 9 12(11) 1 (10) 8 13(11) 2 (10) 7 1...

24.

110 (11)95k (10)9, then k is equal to :

25.

g f f 9 (x)5 1 1 x 5

(10)912(11) 1 (10)813(11)2 (10)71...

110 (11)95k (10)9 ,

(1)

441
100

(1)

441
100

(2)

100

(2)

100

(3)

110

(3)

110

(4)

121
10

(4)

121
10

If a, b0, and f (n)5an1bn and


3

25.

a, b0, f (n)5an1bn

1 1 f (1) 1 1 f (2)

1 1 f (1) 1 1 f (2) 1 1 f (3)


1 1 f (2) 1 1 f (3) 1 1 f (4)

5K(12a) 2 (12b) 2 (a2b) 2 , then K is

5K(12a)2 (12b)2 (a2b)2

(1)

1
ab

(1)

1
ab

(2)

(2)

(3)

21

(3)

21

(4)

ab

(4)

ab

SPACE FOR ROUGH WORK /

1 1 f (1) 1 1 f (2)

1 1 f (1) 1 1 f (2) 1 1 f (3)


1 1 f (2) 1 1 f (3) 1 1 f (4)

equal to :

G/Page 10

k UU

UU

26.

The slope of the line touching both the

26.

parabolas y254x and x25232y is :

27.

28.

U y254x x25232y S
U U

(1)

3
2

(1)

3
2

(2)

1
8

(2)

1
8

(3)

2
3

(3)

2
3

(4)

1
2

(4)

1
2

The statement ~(p ~q) is :

27.

~(p ~q)

(1)

equivalent to ~p q

(1)

~p q

(2)

a tautology

(2)

(tautology)

(3)

a fallacy

(3)

(fallacy)

(4)

equivalent to p q

(4)

p q

Let the population of rabbits surviving at

28.

t U U
U

a time t be governed by the differential


dp(t)
1
5 p(t) 2200.
equation
dt
2

If p(0)5100, then p(t) equals :

p(0)5100 ,

dp(t)
1
5 p(t) 2200
dt
2

p(t) UU

(1)

3002200 e2t/2

(1)

3002200 e2t/2

(2)

6002500 et/2

(2)

6002500 et/2

(3)

4002300 e2t/2

(3)

4002300 e2t/2

(4)

4002300 et/2

(4)

4002300 et/2

G/Page 11

SPACE FOR ROUGH WORK /

mU

29.

Let C be the circle with centre at (1, 1) and

29.

radius51. If T is the circle centred at


(0, y), passing through origin and touching
the circle C externally, then the radius of

C (1, 1) U
51 T (0, y)
U C s M
S U , T UU

T is equal to :

(1)

3
2

3
2

(2)

1
2

(2)

1
2

(3)

1
4

(3)

1
4

3
2

(4)

30.

(1)

3
2

(4)

The angle between the lines whose

30.

direction cosines satisfy the equations


l1m1n50 and l25m21n2 is :

U , - , U
l1m1n50 l25m21n2 cU U ,

(1)

p
4

(1)

p
4

(2)

p
6

(2)

p
6

(3)

p
2

(3)

p
2

(4)

p
3

(4)

p
3

G/Page 12

SPACE FOR ROUGH WORK /

PART B PHYSICS
31.

When a rubber-band is stretched by a

31.

distance x, it exerts a restoring force of


magnitude F5ax1bx2 where a and b are
constants. The work done in stretching
the unstretched rubber-band by L is :

32.

U U x U
; U F5ax1bx2
a b SU
U U L U

(1)

1 aL2
bL3

2 2
3

(1)

1 aL2
bL3

2 2
3

(2)

aL21bL3

(2)

aL21bL3

(3)

1
(aL21bL3)
2

(3)

1
(aL21bL3)
2

(4)

aL2
bL3
1
2
3

(4)

aL2
bL3
1
2
3

The coercivity of a small magnet where the

32.

ferromagnet gets demagnetized is


33103 A m21. The current required to be
passed in a solenoid of length 10 cm and
number of turns 100, so that the magnet
gets demagnetized when inside the

UU ,
, 33103 A m21
100 10 cm U
U ,
U U U ,

solenoid, is :

33.

(1)

6A

(1)

6A

(2)

30 mA

(2)

30 mA

(3)

60 mA

(3)

60 mA

(4)

3A

(4)

3A

In a large building, there are 15 bulbs of

33.

40 W, 5 bulbs of 100 W, 5 fans of 80 W


and 1 heater of 1 kW. The voltage of the
electric mains is 220 V. The minimum

, 40 W 15 , 100 W
5 , 80 W 5 1 kW 1 UU
U 220 V
$

capacity of the main fuse of the building


will be :
(1)

14 A

(1)

14 A

(2)

8A

(2)

8A

(3)

10 A

(3)

10 A

(4)

12 A

(4)

12 A

G/Page 13

SPACE FOR ROUGH WORK /

34.

An open glass tube is immersed in mercury

34.

in such a way that a length of 8 cm extends


above the mercury level. The open end of
the tube is then closed and sealed and the
tube is raised vertically up by additional
46 cm. What will be length of the air

U U U
U SU 8 cm U
U U
U U U U
46 cm U U U U
S ?

column above mercury in the tube now ?

35.

(Atmospheric pressure 576 cm of Hg)

(U 5Hg

(1)

6 cm

(1)

6 cm

(2)

16 cm

(2)

16 cm

(3)

22 cm

(3)

22 cm

(4)

38 cm

(4)

38 cm

A bob of mass m attached to an

35.

inextensible string of length l is suspended


from a vertical support. The bob rotates
in a horizontal circle with an angular
speed v rad/s about the vertical. About

76 cm)

l U m
U U U
U U v rad/s
U
U

the point of suspension :


(1)

angular momentum changes both in

(1)


UU

direction and magnitude.


(2)

angular momentum is conserved.

(2)

U U

(3)

angular momentum changes in

(3)

U U U

(4)

U U
U

magnitude but not in direction.


(4)

angular momentum changes in


direction but not in magnitude.

G/Page 14

SPACE FOR ROUGH WORK /

36.

The current voltage relation of diode is


given by

I5(e1000V/T21)

36.

mA, where the

applied voltage V is in volts and the


temperature T is in degree Kelvin. If a
student makes an error measuring
60.01 V while measuring the current of

U U U- U
I5(e1000V/T21) mA , V
U U U T U
l 300 K U 5 mA U
60.01 V U U ,
U mA U ?

5 mA at 300 K, what will be the error in


the value of current in mA ?

37.

(1)

0.05 mA

(1)

0.05 mA

(2)

0.2 mA

(2)

0.2 mA

(3)

0.02 mA

(3)

0.02 mA

(4)

0.5 mA

(4)

0.5 mA

From a tower of height H, a particle is

37.

thrown vertically upwards with a


speed u. The time taken by the particle, to
hit the ground, is n times that taken by it

H U , u
U U U
U
n

to reach the highest point of its path.


The relation between H, u and n is :

H, u n

(1)

g H5(n22)u2

(1)

g H5(n22)u2

(2)

2 g H5n2u2

(2)

2 g H5n2u2

(3)

g H5(n22)2u2

(3)

g H5(n22)2u2

(4)

2 g H5nu2(n22)

(4)

2 g H5nu2(n22)

G/Page 15

SPACE FOR ROUGH WORK /

38.

A thin convex lens made from crown glass

38.

m 5 3 has focal length f. When it is

measured in two different liquids having

5
3

refractive indices

4
5
and , it has the focal
3
3

f1

f1 and f2 both become negative

(1)

f1 f2

(2)

f15f2 < f

(2)

f15f2 < f

(3)

f1 > f and f2 becomes negative

(3)

f1 > f

(4)

f2 > f and f1 becomes negative

(4)

f2 > f U f1

39.

circular plates separated by a distance of


5 mm and with a dielectric of dielectric
constant 2.2 between them. When the
electric field in the dielectric is 33104 V/m,

f2

U f2

be close to :
(1)

63104 C/m2

(1)

63104 C/m2

(2)

631027 C/m2

(2)

631027 C/m2

(3)

331027 C/m2

(3)

331027 C/m2

(4)

33104 C/m2

(4)

33104 C/m2

SPACE FOR ROUGH WORK /

U, U 5 mm ,
U ^ U
Ul SU 2.2 Ul U
Ul l 33104 V/m ,
U

the charge density of the positive plate will

G/Page 16

(1)

A parallel plate capacitor is made of two

4
3

UU ,

lengths f1 and f2 respectively. The correct


relation between the focal lengths is :

39.

m 5

40.

In the circuit shown here, the point C is

40.

kept connected to point A till the current


flowing through the circuit becomes
constant. Afterward, suddenly, point C
is disconnected from point A and
connected to point B at time t50. Ratio

U , C A
U U
U SU , ,
C A UU B t50
U t5L/R U U
U U U U U

of the voltage across resistance and the


inductor at t5L/R will be equal to :

41.

(1)

12 e
e

(1)

12 e
e

(2)

e
12 e

(2)

e
12 e

(3)

(3)

(4)

21

(4)

21

Two beams, A and B, of plane polarized

41.

light with mutually perpendicular planes


of polarization are seen through a
polaroid. From the position when the
beam A has maximum intensity (and
beam B has zero intensity), a rotation of
polaroid through 308 makes the two beams
appear equally bright.

If the initial


A B U mU
S A
(U B ) UU
308 l
U
IA IB ,

intensities of the two beams are IA and IB


IA
respectively, then I equals :
B
(1)

1
3

(1)

1
3

(2)

(2)

(3)

3
2

(3)

3
2

(4)

(4)

G/Page 17

SPACE FOR ROUGH WORK /

IA
IB

42.

There is a circular tube in a vertical plane.

42.

Two liquids which do not mix and of


densities d1 and d2 are filled in the tube.
Each liquid subtends 908 angle at centre.
Radius joining their interface makes
d1
an angle a with vertical. Ratio d is :
2

43.

U U ,
U d1
d2 , U U
908 U U cU
U a

d1
d2

(1)

1 1 sin a
1 2 cosa

(1)

1 1 sin a
1 2 cosa

(2)

1 1 sin a
1 2 sin a

(2)

1 1 sin a
1 2 sin a

(3)

1 1 cosa
1 2 cosa

(3)

1 1 cosa
1 2 cosa

(4)

1 1 tan a
1 2 tan a

(4)

1 1 tan a
1 2 tan a

The pressure that has to be applied to the

43.

ends of a steel wire of length 10 cm to keep


its length constant when its temperature

10 cm

SU U U U
h 1008C
SU U U U

is raised by 1008C is :
(For

steel

Youngs

modulus

is

231011 N m22 and coefficient of thermal


expansion is 1.131025 K21)

(SU S 231011 N m22


U U U 1.131025 K21 )

(1)

2.23106 Pa

(1)

2.23106

(2)

2.23108 Pa

(2)

2.23108

(3)

2.23109 Pa

(3)

2.23109

(4)

2.23107 Pa

(4)

2.23107

G/Page 18

SPACE FOR ROUGH WORK /

44.

A block of mass m is placed on a surface

44.

with a vertical cross section given by

cU U

U
x3

cU U S U y5
6
0.5 , U U
, U U
,

x3
. If the coefficient of friction is 0.5,
6
the maximum height above the ground at
y5

which the block can be placed without


slipping is :

45.

(1)

1
m
2

(1)

1
m
2

(2)

1
m
6

(2)

1
m
6

(3)

2
m
3

(3)

2
m
3

(4)

1
m
3

(4)

1
m
3

Three rods of Copper, Brass and Steel are

45.

welded together to form a Y - shaped


structure. Area of cross - section of each
rod54 cm 2 .

End of copper rod is

maintained at 1008C where as ends of


brass and steel are kept at 08C. Lengths of
the copper, brass and steel rods are 46, 13
and 12 cms respectively. The rods are
thermally insulated from surroundings
except at ends. Thermal conductivities of
copper, brass and steel are 0.92, 0.26 and

, SU U Y - U
U U U
S U 54 cm2 U
U 1008C
SU U 08C U U ,
SU U
46, 13 12 cms U , U
UU, U c U
, SU c
0.92, 0.26 0.12 CGS U
c U

0.12 CGS units respectively. Rate of heat


flow through copper rod is :
(1)

6.0 cal/s

(1)

6.0 cal/s

(2)

1.2 cal/s

(2)

1.2 cal/s

(3)

2.4 cal/s

(3)

2.4 cal/s

(4)

4.8 cal/s

(4)

4.8 cal/s

G/Page 19

SPACE FOR ROUGH WORK /

46.

A mass m is supported by a massless

46.

string wound around a uniform hollow


cylinder of mass m and radius R. If the
string does not slip on the cylinder, with
what acceleration will the mass fall on

R m
U U UU
m UU U
, U U
U U?

release ?

(1)

(1)

(2)

2g
3

(2)

2g
3

(3)

g
2

(3)

g
2

(4)

5g
6

(4)

5g
6

G/Page 20

SPACE FOR ROUGH WORK /

47.

Match List - I (Electromagnetic wave type)

47.

with List - II (Its association/application)


and select the correct option from the
choices given below the lists :
List - I
(a)

Infrared
waves

List - II
(i)

- I

To treat muscular
strain

(b) Radio waves (ii) For broadcasting

48.

- I (l U U )
- II ( h/)
U

To detect fracture
of bones

(c) X - rays

(iii)

Ultraviolet
(d)
rays

Absorbed by the
(iv) ozone layer of the
atmosphere

(a)

(b)

(c)

(d)

(1)

(i)

(ii)

(iii)

(iv)

(2)

(iv)

(iii)

(ii)

(3)

(i)

(ii)

(4)

(iii)

(ii)

- II

(a)

U U

(i)

(b)

UU U

(ii)

(c)

-U

(iii)

(d)

U
U

(iv)

(a)

(b)

(c)

(d)

(1)

(i)

(ii)

(iii)

(iv)

(i)

(2)

(iv)

(iii)

(ii)

(i)

(iv)

(iii)

(3)

(i)

(ii)

(iv)

(iii)

(i)

(iv)

(4)

(iii)

(ii)

(i)

(iv)

The radiation corresponding to 32

48.

transition of hydrogen atom falls on a


metal surface to produce photoelectrons.
These electrons are made to enter a
magnetic field of 331024 T. If the radius
of the largest circular path followed by

U U 32 U
cU U U UU
U U 331024 T
U U mU
10.0 mm ,

these electrons is 10.0 mm, the work


function of the metal is close to :
(1)

1.6 eV

(1)

1.6 eV

(2)

1.8 eV

(2)

1.8 eV

(3)

1.1 eV

(3)

1.1 eV

(4)

0.8 eV

(4)

0.8 eV

G/Page 21

a S

U
$
U mU

SPACE FOR ROUGH WORK /

49.

waves in a medium :

l U U
U

(1)

(1)

(2)

(3)

(4)

l
UU

During the propagation of electromagnetic

49.

Both electric and magnetic energy


densities are zero.

(2)

Electric energy density is double of


the magnetic energy density.

(3)

Electric energy density is half of the


magnetic energy density.

(4)

Electric energy density is equal to the


magnetic energy density.

50.

angle(u). Select the correct statement.

U U - UcU
U (u)

(1)

(1)

SU
U U

(2)

908 U
SU U

(3)

SU, U
U ,
U

(4)

SU, U
U ,
U

A green light is incident from the water to

50.

the air - water interface at the critical

The entire spectrum of visible light


will come out of the water at various
angles to the normal.

(2)

The entire spectrum of visible light


will come out of the water at an
angle of 908 to the normal.

(3)

The spectrum of visible light whose


frequency is less than that of green
light will come out to the air
medium.

(4)

The spectrum of visible light whose


frequency is more than that of green
light will come out to the air
medium.

G/Page 22

SPACE FOR ROUGH WORK /

51.

Four particles, each of mass M and

51.

equidistant from each other, move along


a circle of radius R under the action of their
mutual gravitational attraction. The speed

M U U
U U , U L
R U

of each particle is :

(1)

52.

1 GM
(1 1 2 2 )
2 R

(2)

GM
R

(3)

2 2

(4)

GM
(1 1 2 2 )
R

(1)

GM
R

A particle moves with simple harmonic

52.

motion in a straight line. In first t s, after


starting from rest it travels a distance a,
and in next t s it travels 2a, in same

1 GM
(1 1 2 2 )
2 R

(2)

GM
R

(3)

2 2

(4)

GM
(1 1 2 2 )
R

GM
R

U U U
US U U
t U U a U t U U 2a
U

direction, then :
(1)

time period of oscillations is 6t

(1)

6t

(2)

amplitude of motion is 3a

(2)

3a

(3)

time period of oscillations is 8t

(3)

8t

(4)

amplitude of motion is 4a

(4)

4a

G/Page 23

SPACE FOR ROUGH WORK /

53.

A conductor lies along the z-axis

53.

at 21.5 [ z < 1.5 m and carries

U U U

a fixed current of 10.0 A in 2 a z


direction (see figure).

53.0310 24

e 20.2x

10.0 A

For a field

2 az

SU U

U ( )

B 53.0310 24 e 20.2x a y T

a y T, find the

the x-axis.

SU x52.0 m, y50 m
531023 s U
x- U U

(1)

29.7 W

(1)

29.7 W

(2)

1.57 W

(2)

1.57 W

(3)

2.97 W

(3)

2.97 W

(4)

14.85 W

(4)

14.85 W

power required to move the conductor at


constant speed to x52.0 m, y50 m in
531023 s. Assume parallel motion along

54.

z- 21.5 [ z < 1.5 m

The forward biased diode connection is :

54.

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

G/Page 24

SPACE FOR ROUGH WORK /

55.

Hydrogen (1H1), Deuterium (1H2), singly


ionised Helium ( 2 He 4 ) 1 and doubly

55.

ionised lithium ( 3Li 6 ) 11 all have one


electron around the nucleus. Consider an
electron transition from n52 to n51. If
the wave lengths of emitted radiation are

l 1 , l 2 , l 3 and l 4 respectively then


approximately which one of the following

U (1H1), UUU (1H2),


(2He4)1 U m
(3Li6)11 U U
U n52 n51 U U
U U U
l1, l2, l3 l4 ,
?

is correct ?
(1)
(2)
(3)
(4)
56.

l152l253l354l4

(1)

l152l252l35l4

(3)

4l152l252l35l4

(2)

l15l254l359l4

(4)

On heating water, bubbles being formed

56.

at the bottom of the vessel detatch and rise.


Take the bubbles to be spheres of radius R
and making a circular contact of radius r
with the bottom of the vessel. If r << R,
and the surface tension of water is T, value
of r just before bubbles detatch is :
(density of water is r )
w

(1)

R2

3rw g

(2)

R2

rw g

(3)

R2

rw g

(4)

R2

rw g

G/Page 25

T
3T
6T
T

SPACE FOR ROUGH WORK /

l152l253l354l4
4l152l252l35l4

l152l252l35l4
l15l254l359l4

U U,
U U U U U
R U
S r r << R
U cU T ,
U r
( rw )

(1)

R2

3rw g

(2)

R2

rw g

(3)

R2

rw g

(4)

R2

rw g

3T
6T
T

57.

velocity of sound in air is 340 m/s.

85 cm U
U S

1250 Hz
340 m/s

(1)

(1)

(2)

12

(2)

12

(3)

(3)

(4)

(4)

A pipe of length 85 cm is closed from one

57.

end. Find the number of possible natural


oscillations of air column in the pipe whose
frequencies lie below 1250 Hz.

58.

The

Assume that an electric field E 5 30 x 2 i


exists in space. Then the potential

58.

difference V A 2V O , where V O is the


potential at the origin and VA the potential

at x52 m is :

(1)

80 J

(1)

80 J

(2)

120 J

(2)

120 J

(3)

2120 J

(3)

2120 J

(4)

280 J

(4)

280 J

G/Page 26

SPACE FOR ROUGH WORK /

l E 5 30 x 2 i
U VA2VO, VO U
VA, x52 m U ,

59.

A student measured the length of a rod

59.

and wrote it as 3.50 cm. Which instrument


did he use to measure it ?
(1)

A screw gauge having 50 divisions


in the circular scale and pitch as

l U U
3.50 cm U
?
(1) S $ U S 50
U 1 mm

1 mm.
(2)

A meter scale.

(2)

(3)

A vernier calliper where the

(3)

10 divisions in vernier scale matches


with 9 division in main scale and

UU S
U U S
10 S 9
U S 1 cm 10

main scale has 10 divisions in 1 cm.


(4)

A screw gauge having 100 divisions

(4)

in the circular scale and pitch as

S $ U S
100 U 1 mm

1 mm.
60.

One mole of diatomic ideal gas undergoes

60.

a cyclic process ABC as shown in figure.


The process BC is adiabatic.

The

temperatures at A, B and C are 400 K,


800 K and 600 K respectively. Choose the

mU
ABC U
BC Lhc A, B C
400 K, 800 K 600 K

correct statement :

(1)

The change in internal energy in the

(1)

process BC is 2500 R.
(2)

The change in internal energy in

(2)

whole cyclic process is 250 R.


(3)

The change in internal energy in the

(3)

process CA is 700 R.
(4)

The change in internal energy in the


process AB is 2350 R.

G/Page 27

SPACE FOR ROUGH WORK /

(4)

U U
2500 R
U
U 250 R
CA U U
700 R
AB U U
2350 R
BC

C U

PART C CHEMISTRY
61.

Which one is classified as a condensation

61.

U ?

polymer ?

62.

(1)

Acrylonitrile

(1)

(2)

Dacron

(2)

(3)

Neoprene

(3)

(4)

Teflon

(4)

Which one of the following properties is

62.

U
UU

U$

NO -

U ?

not shown by NO ?
(1)

Its bond order is 2.5

(1)

(2)

It is diamagnetic in gaseous state

(2)

(3)

It is a neutral oxide

(3)

(4)

It combines with oxygen to form

(4)

nitrogen dioxide
63.

U 2.5
S
U
U U
UU

which on acetylation produces C.

U $U U 1258C U
CO2 U U
U U C

The major product C would be :

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Sodium phenoxide when heated with CO2

63.

under pressure at 1258C yields a product

G/Page 28

SPACE FOR ROUGH WORK /

64.

65.

Given below are the half - cell reactions :

64.

U h

Mn2112e2 Mn ; Eo521.18 V

Mn2112e2 Mn ; Eo521.18 V

2(Mn311e2 Mn21) ; Eo511.51 V

2(Mn311e2 Mn21) ; Eo511.51 V

The Eo for 3Mn21 Mn12Mn31 will be :

3Mn21 Mn12Mn31

(1)

20.33 V ; the reaction will occur

(1)

(2)

22.69 V ; the reaction will not occur

(2)

(3)

22.69 V ; the reaction will occur

(3)

(4)

20.33 V ; the reaction will not occur

(4)

For complete combustion of ethanol,

65.

C2H5OH(l)13O2(g) 2CO2(g)13H2O(l),

Eo
20.33 V ;
22.69 V ;
22.69 V ;
20.33 V ;

,
C2H5OH(l)13O2(g) 2CO2(g)13H2O(l),

UUU 258C U
1364.47 kJ mol21
, DcH,

the amount of heat produced as measured

in bomb calorimeter, is 1364.47 kJ mol21


at 258C. Assuming ideality the Enthalpy
of combustion, DcH, for the reaction will
be :

(R58.314 kJ mol21)

(R58.314 kJ mol21)

66.

(1)

21350.50 kJ mol21

(1)

21350.50 kJ mol21

(2)

21366.95 kJ mol21

(2)

21366.95 kJ mol21

(3)

21361.95 kJ mol21

(3)

21361.95 kJ mol21

(4)

21460.50 kJ mol21

(4)

21460.50 kJ mol21

For the estimation of nitrogen, 1.4 g of an

66.

organic compound was digested by


Kjeldahl method and the evolved ammonia
M
was absorbed in 60 mL of
sulphuric
10
acid. The unreacted acid required 20 mL
M
of
sodium hydroxide for complete
10
neutralization. The percentage of nitrogen
in the compound is :

U 1.4 .
U U
M

60 10 U

U 20

5%

(1)

5%

(2)

6%

(2)

6%

(3)

10%

(3)

10%

(4)

3%

(4)

3%

SPACE FOR ROUGH WORK /

UU U

(1)

G/Page 29

M
10

67.

with silver powder is :

U UU
U U U

(1)

2 - Butene

(1)

2-

(2)

Acetylene

(2)

(3)

Ethene

(3)

(4)

2 - Butyne

(4)

2-

The major organic compound formed by

67.

the reaction of 1, 1, 12 trichloroethane

68.

ratio of number of their molecule is :

U U
1 : 4

(1)

3 : 16

(1)

3 : 16

(2)

1:4

(2)

1:4

(3)

7 : 32

(3)

7 : 32

(4)

1:8

(4)

1:8

The ratio of masses of oxygen and nitrogen

68.

in a particular gaseous mixture is 1 : 4. The

69.

1, 1, 12 UU

salts is :


U (l U)

(1)

Cr

(1)

Cr

(2)

Ag

(2)

Ag

(3)

Ca

(3)

Ca

(4)

Cu

(4)

Cu

The metal that cannot be obtained by

69.

electrolysis of an aqueous solution of its

G/Page 30

SPACE FOR ROUGH WORK /

70.

The equivalent conductance of NaCl at

70.

concentration C and at infinite dilution are


l C and l : , respectively. The correct
relationship between lC and l: is given
as :

(B SU )

(where the constant B is positive)

71.

C U U U NaCl
U lC U l:

(1)

lC5l:1(B) C

(1)

lC5l:1(B) C

(2)

lC5l:1(B)C

(2)

lC5l:1(B)C

(3)

lC5l:2(B)C

(3)

lC5l:2(B)C

(4)

lC5l:2(B) C

(4)

lC5l:2(B) C

The correct set of four quantum numbers

71.

for the valence electrons of rubidium atom

MU U (Z537) U
U U U U

(Z537) is :

72.

(1)

5, 0, 1, 1

1
2

(1)

5, 0, 1, 1

1
2

(2)

5, 0, 0, 1

1
2

(2)

5, 0, 0, 1

1
2

(3)

5, 1, 0, 1

1
2

(3)

5, 1, 0, 1

1
2

(4)

5, 1, 1, 1

1
2

(4)

5, 1, 1, 1

1
2

Consider separate solutions of 0.500 M


C 2 H 5 OH(aq), 0.100 M Mg 3 (PO 4 ) 2 (aq),
0.250 M KBr(aq) and 0.125 M Na3PO4(aq)

72.

0.500 M C2H5OH(),

0.100 M Mg 3 (PO 4 ) 2 () , 0.250 M


KBr() U 0.125 M Na3PO4()

258C U
these solutions, assuming all salts to be
UU
strong electrolytes ?
- ?
(1) 0.500 M C 2 H 5 OH(aq) has the
(1) 0.500 M C 2 H 5 OH ()
highest osmotic pressure.
U
(2) They all have the same osmotic
(2) U
pressure.

(3) 0.100 M Mg 3 (PO 4 ) 2 (aq) has the
(3) 0.100 M Mg 3 (PO 4 ) 2 ()
highest osmotic pressure.
U
(4) 0.125 M Na3PO4(aq) has the highest
(4) 0.125 M Na 3 PO 4 ()
U
osmotic pressure.
SPACE FOR ROUGH WORK / U
G/Page 31
at 258C. Which statement is true about

73.

74.

The most suitable reagent for the

73.

conversion of R2CH22OH R2CHO


is :

(1)

PCC (Pyridinium Chlorochromate)

(1)

PCC

(2)

KMnO4

(2)

KMnO 4

(3)

K2Cr2O7

(3)

K2Cr2O7

(4)

CrO 3

(4)

CrO 3

CsCl crystallises in body centred cubic

74.

lattice. If a is its edge length then which


of the following expressions is correct ?

75.

R2CH22OH R2CHO

(UU U)U

U SU
U a
- U ?
CsCl

(1)

rCs1 1 rCl25 3a

(1)

rCs1 1 rCl25 3a

(2)

rCs1 1 rCl25 3a

(2)

rCs1 1 rCl25 3a

(3)

3a
rCs1 1 rCl25
2

(3)

3a
rCs1 1 rCl25
2

(4)

3
rCs1 1 rCl25
a
2

(4)

3
rCs1 1 rCl25
a
2

In which of the following reactions H2O2

75.

acts as a reducing agent ?


U ?

H2O2

(a)

H2O21 2H112e2 2H2O

(a)

H2O21 2H112e2 2H2O

(b)

H2O222e2 O21 2H1

(b)

H2O222e2 O21 2H1

(c)

H2O212e2 2OH2

(c)

H2O212e2 2OH2

(d)

H2O21 2OH222e2 O212H2O

(d)

H2O21 2OH222e2 O212H2O

(1)

(b), (d)

(1)

(b), (d)

(2)

(a), (b)

(2)

(a), (b)

(3)

(c), (d)

(3)

(c), (d)

(4)

(a), (c)

(4)

(a), (c)

G/Page 32

SPACE FOR ROUGH WORK /

76.

For which of the following molecule

76.

significant m0 ?

77.

m0
?

(a)

(b)

(a)

(b)

(c)

(d)

(c)

(d)

(1)

(c) and (d)

(1)

(c) U (d)

(2)

Only (a)

(2)

(3)

(a) and (b)

(3)

(a) U (b)

(4)

Only (c)

(4)

On heating an aliphatic primary amine

77.

with chloroform and ethanolic potassium


hydroxide, the organic compound formed

(a)

(c)

U U U U
U UU U U
U U

is :
(1)

an alkyl isocyanide

(1)

(2)

an alkanol

(2)

(3)

an alkanediol

(3)

(4)

an alkyl cyanide

(4)

G/Page 33

SPACE FOR ROUGH WORK /

78.

In S N 2 reactions, the correct order of


reactivity for the following compounds :

78.

CH 3 Cl, CH 3 CH 2 Cl, (CH 3 ) 2 CHCl and


(CH3)3CCl is :

79.

CH3Cl, CH3CH2Cl, (CH3)2CHCl U


(CH3)3CCl SN2 U
SU

(1)

(CH3)2CHCl > CH3CH2Cl > CH3Cl


> (CH3)3CCl

(1)

(CH3)2CHCl > CH3CH2Cl > CH3Cl


> (CH3)3CCl

(2)

CH3Cl > (CH3)2CHCl > CH3CH2Cl


> (CH3)3CCl

(2)

CH3Cl > (CH3)2CHCl > CH3CH2Cl


> (CH3)3CCl

(3)

CH3Cl > CH3CH2Cl > (CH3)2CHCl


> (CH3)3CCl

(3)

CH3Cl > CH3CH2Cl > (CH3)2CHCl


> (CH3)3CCl

(4)

CH3CH2Cl > CH3Cl > (CH3)2CHCl


> (CH3)3CCl

(4)

CH3CH2Cl > CH3Cl > (CH3)2CHCl


> (CH3)3CCl

The octahedral complex of a metal ion

79.

M31

with four monodentate ligands L1,


L2, L3 and L4 absorb wavelengths in the
region of red, green, yellow and blue,
respectively. The increasing order of ligand

U U,
L1, L2, L3 U L4 cU U
, U, U S UZ
U U U U

M31

strength of the four ligands is :

80.

(1)

L1 < L2< L4 < L3

(1)

L1 < L2< L4 < L3

(2)

L4 < L3 < L2 < L1

(2)

L4 < L3 < L2 < L1

(3)

L1 < L3 < L2 < L4

(3)

L1 < L3 < L2 < L4

(4)

L3 < L2 < L4 < L1

(4)

L3 < L2 < L4 < L1

represents the correct product(s) is :

U U
,

(1)

CuSO 414 K C N K 2[Cu(CN)4]

(1)

Li2O12KCl 2LiCl1K2O

(2)

Li2O12KCl 2LiCl1K2O

(3)

[CoCl(NH3)5]115H1Co21

The equation which is balanced and

80.

1K2SO 4
(2)
(3)

[CoCl(NH3)5

]11 5 H1 Co 21

1K2SO 4

15 NH4 1Cl2
(4)

[Mg(H2O)6]211 (EDTA)42

15 NH4 1Cl2

[Mg(EDTA)]21

[Mg(H2O)6]211 (EDTA) 42
NaOH
[Mg(EDTA) ] 21

1 6H2O

1 6H2O

excess NaOH

G/Page 34

CuSO 414 K C N K 2[Cu(CN) 4]

SPACE FOR ROUGH WORK /

(4)

81.

In the reaction,

81.

LiAlH

82.

PCl

Alc. KOH

LiAlH

PCl

Alc. KOH

4
5
CH3COOH
A
B
C ,

4
5
CH3COOH
A
B
C

the product C is :

(1)

Acetyl chloride

(1)

U UU

(2)

Acetaldehyde

(2)

UUU

(3)

Acetylene

(3)

(4)

Ethylene

(4)

The correct statement for the molecule,

82.

CsI3 , is :

83.

CsI3

(1)

it contains Cs 1 , I 2 and lattice I 2


molecule.

(1)

Cs1, I2 U I2

(2)

it is a covalent molecule.

(2)

(3)

it contains Cs1 and I2


3 ions.

(3)

Cs1 U

(4)

it contains Cs31 and I2 ions.

(4)

Cs31 U I2

1
For the reaction SO2(g)1 O2(g) SO3(g),
2

83.

if KP5KC(RT)x where the symbols have


usual meaning then the value of x is :

SO2(g)1

I3

1
O
SO3(g)
2 2(g)

KP5KC(RT)x U

(assuming ideality)

U UM x

(1)

(1)

(2)

21

(2)

21

(3)

(3)

(4)

1
2

(4)

1
2

G/Page 35

1
2

SPACE FOR ROUGH WORK /

1
2

84.

For the non - stoichiometre reaction

U U 2A1B C1D
298 K U

84.

2A1B C1D, the following kinetic data


were

obtained

in

three

separate

experiments, all at 298 K.


Initial
Initial
Initial rate of
Concentration Concentration formation of C
(A)
(B)
(mol L2S2)
0.1 M
0.1 M
1.2 3 10 23

U
(A)

U
(B)

0.1 M

0.1 M

1.2 3 10 23

0.1 M

0.2 M

1.2 3 10 23

0.1 M

0.2 M

0.2 M

0.1 M

2.4 3 10 23

1.2 3 10 23

0.2 M

0.1 M

2.4 3 10 23

C U

The rate law for the formation of C is :

85.

U
U ( L2S2)
C

(1)

dc
5k[A]
dt

(1)

dc
5k[A]
dt

(2)

dc
5k[A] [B]
dt

(2)

dc
5k[A] [B]
dt

(3)

dc
5k[A]2 [B]
dt

(3)

dc
5k[A]2 [B]
dt

(4)

dc
5k[A] [B]2
dt

(4)

dc
5k[A] [B]2
dt

Resistance of 0.2 M solution of an


electrolyte is 50 V.

85.

The specific

conductance of the solution is 1.4 S m21.


The resistance of 0.5 M solution of the same
electrolyte is 280 V.

The molar

conductivity of 0.5 M solution of the


electrolyte in S m2 mol21 is :

l U 0.2 M U
50 V cU
1.4 S m21 l U 0.5 M
U 280 V l U
0.5 M U S m2 21

(1)

5310 2

(1)

5310 2

(2)

5310 24

(2)

5310 24

(3)

5310 23

(3)

5310 23

(4)

5310 3

(4)

5310 3

G/Page 36

SPACE FOR ROUGH WORK /

86.

Among the following oxoacids, the correct

86.

decreasing order of acid strength is :

87.

(1)

HClO2 > HClO4 > HClO3 > HOCl

(1)

(2)

(2)

(3)

HOCl > HClO2 > HClO3 > HClO4


HClO4 > HOCl > HClO2 > HClO3

HClO2 > HClO4 > HClO3 > HOCl


HOCl > HClO2 > HClO3 > HClO4

(3)

HClO4 > HOCl > HClO2 > HClO3

(4)

HClO4 > HClO3 > HClO2 > HOCl

(4)

HClO4 > HClO3 > HClO2 > HOCl

Which one of the following bases is not

87.

U DNA ?

present in DNA ?

88.

(1)

Thymine

(1)

(2)

Quinoline

(2)

(3)

Adenine

(3)

(4)

Cytosine

(4)

smallest pKb value ?

U U
pKb
?

(1)

C6H5NH2

(1)

C6H5NH2

(2)

(CH3)2NH

(2)

(CH3)2NH

(3)

CH3NH2

(3)

CH3NH2

(4)

(CH3)3N

(4)

(CH3)3N

Considering the basic strength of amines

88.

in aqueous solution, which one has the

89.

U
U

If

is

compressibility

factor,

89.

van der Waals equation at low pressure

Z U U
U

can be written as :
(1)

Z511

Pb
RT

(1)

Z511

Pb
RT

(2)

Z511

RT
Pb

(2)

Z511

RT
Pb

(3)

Z512

a
VRT

(3)

Z512

a
VRT

(4)

Z512

Pb
RT

(4)

Z512

Pb
RT

G/Page 37

SPACE FOR ROUGH WORK /

90.

Which series of reactions correctly

90.

represents chemical relations related to


iron and its compound ?
(1)

CO, 6008 C

O , heat

2
Fe
Fe 3O 4

- M
U U
M U ?
(1)

CO, 700 8 C

CO, 700 8 C

FeO
Fe

(2)

dil H SO

FeO
Fe
H SO , O

2
4
2
4
2
Fe
FeSO 4

(2)

O , heat

dil H SO

2
2
4
Fe
FeO

(3)

Cl , heat

heat, air

2
Fe

FeCl 3

Zn

(4)

Cl 2 ,
,
Fe
FeCl 3

Zn

FeCl 2 Fe

FeCl 2 Fe

-o0o-

-o0o-

SPACE FOR ROUGH WORK /

G/Page 38

O 2 ,
H2 SO 4
Fe
FeO

FeSO 4
Fe

heat

FeSO 4
Fe
(4)

H2 SO 4
H2 SO 4 , O 2
Fe
FeSO 4

Fe 2 (SO 4 )3
Fe

heat

Fe 2 (SO 4 )3
Fe

(3)

O 2 ,
CO, 6008 C
Fe
Fe 3O 4

SPACE FOR ROUGH WORK /

G/Page 39

Read the following instructions carefully :


U U S U U (D -1) U U
U / U U
U D-2 U U / U
/ U U
3. U S/U U U S U
R
4. U

5. U U
- () U
U U ,
U
6. U S U U
US ( U S U
S UU), U U S
U
7. U U U U
, U S
U U mU
, U D U U U
S D U (D 39)
8. U, U / U U
U U
U S
9. U U U U
10. U U
S U
11. U U U S
U U SU U U U
U U U S U SU
U U
U
U S S U

12. U/S U , U
U U
13. U U U .../U
U mU
.../U
U
14. S U S U

15. U mU U / U
U U , S,
, U, U
U U U
U

1. The candidates should fill in the required particulars 1.


on the Test Booklet and Answer Sheet (Side1) with
Blue/Black Ball Point Pen.
2. For writing/marking particulars on Side2 of the 2.
Answer Sheet, use Blue/Black Ball Point Pen only.

3. The candidates should not write their Roll Numbers


anywhere else (except in the specified space) on the
Test Booklet/Answer Sheet.
4. Out of the four options given for each question, only
one option is the correct answer.
5. For each incorrect response, onefourth () of the total
marks allotted to the question would be deducted from
the total score. No deduction from the total score,
however, will be made if no response is indicated for
an item in the Answer Sheet.
6. Handle the Test Booklet and Answer Sheet with care,

as under no circumstances (except for discrepancy in


Test Booklet Code and Answer Sheet Code), another set
will be provided.

7. The candidates are not allowed to do any rough work


or writing work on the Answer Sheet. All calculations/
writing work are to be done in the space provided for
this purpose in the Test Booklet itself, marked Space
for Rough Work. This space is given at the bottom of
each page and in one page (Page 39) at the end of the
booklet.
8. On completion of the test, the candidates must hand
over the Answer Sheet to the Invigilator on duty in the
Room/Hall. However, the candidates are allowed to
take away this Test Booklet with them.
9. Each candidate must show on demand his/her Admit
Card to the Invigilator.
10. No candidate, without special permission of the
Superintendent or Invigilator, should leave his/her
seat.
11. The candidates should not leave the Examination Hall
without handing over their Answer Sheet to the
Invigilator on duty and sign the Attendance Sheet
again. Cases where a candidate has not signed the
Attendance Sheet a second time will be deemed not to
have handed over the Answer Sheet and dealt with as
an unfair means case. The candidates are also required
to put their left hand THUMB impression in the space
provided in the Attendance Sheet.
12. Use of Electronic/Manual Calculator and any
Electronic Item like mobile phone, pager etc. is
prohibited.
13. The candidates are governed by all Rules and
Regulations of the JAB/Board with regard to their
conduct in the Examination Hall. All cases of unfair
means will be dealt with as per Rules and Regulations
of the JAB/Board.
14. No part of the Test Booklet and Answer Sheet shall be
detached under any circumstances.
15. Candidates are not allowed to carry any textual
material, printed or written, bits of papers, pager,
mobile phone, electronic device or any other material
except the Admit Card inside the examination
hall/room.

G/Page 40

You might also like