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Script e gawe wae sak okeh2e Assalaamualaykum Warahmatullaahi Wabarakaatuh The honorable judges of 2014 ICECC Poster Competition, the honorable advisors, and all participants of 2014 ICECC. Thank you for the time given to us. In this occasion, we would like to deliver presentation about our chem e car named Semar Ark 1.2. First of all, we would like to introduce ourselves. We are chem e car team from Sebelas Maret University, which is familiarly known as UNS. The name of the team is Semar Ark Team. The word Semar is acronym of Sebelas Maret, the name of our university, as we are one of pioneer team in chem e car competition from Sebelas Maret University. The word Ark shows the team's spirit and tenacity. Just like how Noah's Ark did in surviving legendary worldwide flood in the past, we want to inherit Noah's Ark spirit to be able to survive all challenge, endure all trouble, and become the lastman-standing in a competition. Semar Ark Team consists of 4 members. The team leader is Ahmad Qomaruddin, and the rest of the team are Cornelius Satria Yudha, Iddo Fadhlil Ratmana, and Nugroho Fajar Windyanto. Now, lets begin our presentation.

This is the picture of our Semar Ark 1.2. It consists of Semar Ark 1.2 is a car with pneumatic motor, which was powered by gas pressure from CO2 as a product of chemical reaction. The reaction occurs in that (sambi nunjuk) pressure vessel. CO2 from pressure vessel is transmitted to pneumatic motor through (sambi nunjuk) piping system, which consists of vessel, valves, regulator, and elastic pipe. What is the power source of the car? How is the way to control the distance traveled? Does Semar Ark 1.2. give negative effects to safety and environment? Is there any unique features equipped in the car? In this presentation, we will try to answer all these questions and explain the details of this car. The first chapter of our explanation is about originality of concept and each components function, which will be explained by my partner, Iddo Fadhlil Ratmana.

Thank you, Ahmad Qomaruddin. Now, Id like to explain the originality of concept of Semar Ark 1.2. Every originality is inspired by another originality. The reaction CaCO3 + HCl CaCl2 + CO2 +H2O is considered as new reaction to use in ICECC. Besides the reaction, another originality of the car comes from turbine as pneumatic motor, which is rarely used in this competition. Semar Ark 1.2 is using new chemical reaction concept: CaCO3 + HCl CaCl2 + CO2 + H2O as the core of the whole idea. The reaction is selected as energy source due to some considerations. 1 st, the reaction can produce pressurized CO2, which can be converted to kinetic energy by flowing it through a pneumatic motor. 2nd, the reaction itself is exothermic (H= -8.505 kJ/mole). Generation of heat of reaction will increase temperature operation. As we know from Gay-Lussacs Law (P1 / T1

= P2 / T2), the value of temperature is directly proportional to the value of pressure. Based on that law, we can conclude that the pressure of CO2 produced will be increased as well due to the increasing temperature. Thus, kinetic energy resulted from pneumatic motor will be higher as the pressure increases. Another consideration in choosing this reaction is related to the simplicity of the reaction. The reaction is a simple single reaction so that it does not need complex reaction kinetic. The reaction itself is spontaneous. It doesn't need any catalyst to speed the reaction and it doesn't need any heat to initiate the reaction. Besides that, the reactants are easy to find and relatively cheap. Despite those advantages, the reaction has some disadvantages(kelemahan/kekurangan). The main (kelemahan/kekurangan) comes from HCl, which has corrosive property. Besides that, CaCl2 as the product is a little bit harmful (ngatasine?) when its consumed by human in high amount which will cause kidney stone, constipation, bone pains and worst: coma. To overcome these (kelemahan/kekurangan), Semar Ark 1.2. has some unique features which will be further explained in the next chapter of our presentation. With these unique features, advantages of the reaction can be utilized while the (kelemahan/kekurangan) can be minimized. From the considerations above, it can be concluded that this reaction is appropriate to be used as energy source of Semar Ark 1.2. Stopping mechanism of the car is related to stoichiometry of the reaction. The car will stop when the reaction is exhausted. The amount of hydrochloric acid as limiting reactant will be varied to control the distance the car travels. Next, Id like to talk about the step-by-step process concept in this car: How Semar Ark 1.2. works from the start-up to the stopping mechanism and waste treatment of the car. The start-up is triggered by chemical reaction. The reaction happens in PV1. PV1 is equipped with: 1 hole & plug to input CaCO3; pressure gauge to check pressure in PV1; and pressure relief valve set to open at 10% higher than the maximum anticipated operating pressure. Another pressure vessel (PV2) is situated above PV1 as HCl storage. A ball valve (V2) connects PV2 and PV1, which will be opened to let HCl reacts with CaCO3. On top of PV2, there are T-fitting which is connected to two ball valves (V1& V3). Normally, V1 is closed to make sure that no chemical substance goes to surroundings through V1. V1 will be opened if only it needs to be used as HCl inlet or water inlet for rinsing residual substance after the reaction is exhausted. V3 is connected to pressure regulator and pneumatic motor. As the reaction begins, V3 and V2 is opened while V1 is closed. This allows the gas to flow from PV1 and PV2 through the regulator and to the motor. After CO 2 gas goes through pneumatic motor, the gas will be stored in a closed chamber to prevent CO2 emission to surroundings (sido gak? Nek sido termasuk unique features). The car will stop when the reaction is exhausted. The amount of HCl as limiting reactant will be varied to control the distance the car travels. We have conducted a research about the relation of the amount of HCl as limiting reactant and the distance the car travels. The result of our research is plotted in this graph (sambi nunjuk). From that graph, it can be concluded that .. After the reaction is exhausted, residual substance in PV1 needs to be disposed. The disposal is done through the 1 hole & plug in PV1. The residual substance might not in neutral condition yet. In order to make sure that it is in neutral condition, it needs to be tested with pH test strip. pH can be adjusted by adding either HCl or CaCO3 until pH is neutral (termasuk unique features).

Further explanation about unique features and design creativity of Semar Ark 1.2. will be explained by my partner, (SOPO?)

Thank you, Iddo.. Now, please allow me to explain unique features and design creativity of Semar Ark 1.2. Unique features and design creativity are very important in maintaining safety and environmental aspect of Semar Ark 1.2. Besides that, these are utilized to maximize the performance and minimize the cost of this car. The first point of this cars unique features relates to construction material of the car. The material chosen for this car is expected to endure the corrosive property of HCl. This part of the car which is expected to have contact with HCl is PV1 and PV2. Thus, PV1 and PV2 is built of carbon steel coated by stainless steel. Hence, addition of strong acids (in this issue, HCl) will not be a major problem because it can be hold by the construction material. designed with valves, so its very easy to control Self-made turbine as pneumatic motor which is easy to fabricate, cheap and simple >> bandingkan dengan biaya pembelian turbin standar yang sudah tersedia di pasar >> mugo2 lebih murah Pressure vessel designed cylindrical-shape, with safety valves and manometer. It holds high pressure Wadah CO2 ?? Neutralizing as product handling +sertakan alasan/keuntungan

Not only designed for simple reaction, Semar Ark also designed with a simple selfmade turbine as the pneumatic motor. The reasons for choosing turbine as the pneumatic motor are : 1. Simplicity 2. Easy to fabricate 3. Relatively cheap than another type of pneumatic motor Semar Ark also designed with valves which it why it is very easy to control the process. From the material and the shape of the tank, this car is cappable to hold high pressure. The manometer and safety valve are added to the pressure vessel for calculation and safety purposes.
The effects of utilizing unique features and design creativity can be seen in enhanced safety and environmental protection and low cost of this car. The explanation of safety, environmental aspect and economical aspect of the car will be further explained by my partner, (sopo??)

Thank you, . In this occasion, I would like to explain safety, environmental aspect and economical aspect of Semar Ark 1.2. Environtmental and safety responsibilities are considered to be of the utmost importance in any process. Fossil bassed fuel oxidation usually produce CO gas which is very dangerous to environtment. But from this reaction we could assure that there is no CO produced. Waste disposal is considered as simple and easy process. As explained before, in order to make sure that the waste is disposed to surroundings in neutral condition, we need to threat the acidity of product. By using pH test strip, we will be informed wether we should adjust the pH of products by HCl or CaCO3 or not. From the reactant aspect, CaCO3 is a solid non-hazardeous substance, that is why it is very easy to clean or handle when it spills. Semar Ark is designed with safe enclosed system. The chemical and mechanical components on the car are shielded by stainless steel material in order to prevent unintended human contact. It also prevents spills and minimizes handling hazards. To prevent any accident , every team member was required to complete the universitys "Laboratory Safety Principles" course before entering the lab. For proper waste disposal, all hazardous waste was disposed of properly. Material Safety Data Sheets were made available and accesible on the internet. Economical aspect??

InAcknowledgement we glad to say thank you, first to our univ Tutup + buka sesi tanya jawab

Interaksi dengan audiens kurang >>gmn??

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