MATERIAL SAFETY 3M

DATA SHEET 3M Center

St. Paul, Minnesota
55144-1000
1-800-364-3577 or (651) 737-6501 (24 hours)

Copyright, 2001, Minnesota Mining and Manufacturing Company.

All rights reserved. Copying and/or downloading of this
information for the purpose of properly utilizing 3M products
is allowed provided that:
1) the information is copied in full with no changes unless
prior agreement is obtained from 3M, and
2) neither the copy nor the original is resold or otherwise
distributed with the intention of earning a profit thereon.

DIVISION: ELECTRICAL PRODUCTS DIVISION

TRADE NAME:
SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2100
U.P.C. Number:
00-54007-34530-5 00-54007-34531-2
ISSUED: August 14, 2001
SUPERSEDES: December 01, 1997
DOCUMENT: 10-2610-3

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1. INGREDIENT C.A.S. NO. PERCENT
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PART A: DIPHENYL METHANE DIISOCYANATE... 101-68-8 35.0 - 45.0

DIUNDECYL PHTHALATE..................... 3648-20-2 35.0 - 40.0
POLYBUTADIENE........................... 69102-90-5 15.0 - 20.0
GLYCOLS, POLYPROPYLENE.................. 25322-69-4 5.0 - 10.0
PART B: POLYBUTADIENE................... 69102-90-5 35.0 - 40.0
DIUNDECYL PHTHALATE..................... 3648-20-2 20.0 - 25.0
GLYCOLS, POLYPROPYLENE.................. 25322-69-4 10.0 - 15.0
N,N-DI(2-HYDROXYPROPYL)ANILINE.......... 3077-13-2 10.0 - 15.0
DIPROPYLENE GLYCOL...................... 25265-71-8 5.0 - 10.0
ZEOLITES................................ 1318-02-1 1.0 - 5.0
CASTOR OIL.............................. 8001-79-4 1.0 - 5.0

This product contains the following toxic chemical or chemicals subject to

the reporting requirements of Section 313 of Title III of the Emergency
Planning and Community Right-To-Know Act of 1986 and 40 CFR Part 372:
PART A: DIPHENYL METHANE DIISOCYANATE

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2. PHYSICAL DATA
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BOILING POINT:................. N/A

VAPOR PRESSURE:................ N/A
VAPOR DENSITY:................. N/A
EVAPORATION RATE:.............. N/A
SOLUBILITY IN WATER:........... Reacts
SPECIFIC GRAVITY:.............. PRE.:1.05 POL.:0.97
PERCENT VOLATILE:.............. 0
pH:............................ N/A
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2100
August 14, 2001 PAGE 2

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2. PHYSICAL DATA (continued)
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VISCOSITY:..................... PRE.:10p POL.:20p

MELTING POINT:................. N/D

APPEARANCE AND ODOR:

PREPOLYMER:Dark viscous liquid POLYOL:Opaque viscous liquid

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3. FIRE AND EXPLOSION HAZARD DATA
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FLASH POINT:................... Both>320F Closed Cup

FLAMMABLE LIMITS - LEL:........ N/D
FLAMMABLE LIMITS - UEL:........ N/D
AUTOIGNITION TEMPERATURE:...... N/D

EXTINGUISHING MEDIA:
Carbon dioxide, Dry chemical, Foam

SPECIAL FIRE FIGHTING PROCEDURES:

Wear full protective clothing, including helmet, self-contained,
positive pressure or pressure demand breathing apparatus, bunker coat
and pants, bands around arms, waist and legs, face mask, and
protective covering for exposed areas of the head.

UNUSUAL FIRE AND EXPLOSION HAZARDS:

See Hazardous Decomposition section for products of combustion.

NFPA HAZARD CODES: HEALTH: 2 FIRE: 1 REACTIVITY: 0

UNUSUAL REACTION HAZARD: none

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4. REACTIVITY DATA
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STABILITY: Stable

INCOMPATIBILITY - MATERIALS/CONDITIONS TO AVOID:

Amines, Alcohols, Water. Reaction with water, alcohols and amines is
not hazardous if container can vent to the atmosphere to prevent
pressure buildup.

This refers to Part A (prepolymer).

HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur.

HAZARDOUS DECOMPOSITION PRODUCTS:

Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen
Cyanide, Isocyanates, Toxic Vapors, Gases or Particulates, Irritant
Vapors or Gases.
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2100
August 14, 2001 PAGE 3

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4. REACTIVITY DATA (continued)
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5. ENVIRONMENTAL INFORMATION
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SPILL RESPONSE:
Refer to other sections of this MSDS for information regarding
physical and health hazards, respiratory protection, ventilation, and
personal protective equipment. Pour isocyanate decontaminant
solution (90% water,8% concentrated ammonia, 2% detergent) on spill
and allow to react for 10 minutes. Alternatively, pour water on spill
and allow to react for more than 30 minutes. Cover with absorbent.
Place in an approved drum, but do not seal the drum for 48 hours to
avoid possible pressure buildup. Neutralize spill residue with
decontaminant solution.

RECOMMENDED DISPOSAL:
Incinerate in an industrial or commercial facility. Dispose of
completely cured (or polymerized) material in a sanitary landfill.

ENVIRONMENTAL DATA:
No data available.

REGULATORY INFORMATION:
Volatile Organic Compounds: N/D.
VOC Less H2O & Exempt Solvents: N/D.

Since regulations vary, consult applicable regulations or authorities

before disposal.

EPCRA HAZARD CLASS:

FIRE HAZARD: No PRESSURE: No REACTIVITY: Yes ACUTE: Yes CHRONIC: Yes

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6. SUGGESTED FIRST AID
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EYE CONTACT:
Immediately flush eyes with large amounts of water. Get immediate
medical attention.

SKIN CONTACT:
Flush skin with large amounts of water. If irritation persists, get
medical attention.

INHALATION:
Remove person to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, get immediate medical
attention.

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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2100
August 14, 2001 PAGE 4

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6. SUGGESTED FIRST AID (continued)
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IF SWALLOWED:
Do not induce vomiting. Drink two glasses of water. Call a physician.

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7. PRECAUTIONARY INFORMATION
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EYE PROTECTION:
Avoid eye contact. Wear safety glasses with side shields.

SKIN PROTECTION:
Avoid prolonged or repeated skin contact. Wear appropriate gloves
when handling this material.

RECOMMENDED VENTILATION:
Provide sufficient ventilation to maintain emissions below
recommended exposure limits. If exhaust ventilation is not adequate,
use appropriate respiratory protection.

RESPIRATORY PROTECTION:
Avoid breathing of vapors. Select one of the following NIOSH
approved respirators based on airborne concentration of contaminants
and in accordance with OSHA regulations: half-mask organic vapor
respirator.

PREVENTION OF ACCIDENTAL INGESTION:

Do not ingest.

RECOMMENDED STORAGE:
Keep container in well-ventilated area. Keep out of the reach of
children.

FIRE AND EXPLOSION AVOIDANCE:

Keep container tightly closed. Do not heat under confinement.

EXPOSURE LIMITS

INGREDIENT VALUE UNIT TYPE AUTH SKIN*

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PART A: DIPHENYL METHANE
DIISOCYANATE....................... 0.02 PPM CEIL OSHA
PART A: DIPHENYL METHANE
DIISOCYANATE....................... 0.005 PPM TWA ACGIH
DIUNDECYL PHTHALATE.................. NONE NONE NONE NONE
POLYBUTADIENE........................ NONE NONE NONE NONE
GLYCOLS, POLYPROPYLENE............... 10 MG/M3 TWA AIHA
AS PARTICULATE
PART B: POLYBUTADIENE................ NONE NONE NONE NONE
DIUNDECYL PHTHALATE.................. NONE NONE NONE NONE
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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2100
August 14, 2001 PAGE 5

EXPOSURE LIMITS (continued)

INGREDIENT VALUE UNIT TYPE AUTH SKIN*

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GLYCOLS, POLYPROPYLENE............... 10 MG/M3 TWA AIHA
AS PARTICULATE
N,N-DI(2-HYDROXYPROPYL)ANILINE....... NONE NONE NONE NONE
DIPROPYLENE GLYCOL................... NONE NONE NONE NONE
ZEOLITES............................. NONE NONE NONE NONE
CASTOR OIL........................... 10 MG/M3 TWA OSHA
AS MIST

* SKIN NOTATION: Listed substances indicated with 'Y' under SKIN refer to
the potential contribution to the overall exposure by the cutaneous route
including mucous membrane and eye, either by airborne or, more particularly,
by direct contact with the substance. Vehicles can alter skin absorption.

SOURCE OF EXPOSURE LIMIT DATA:

- ACGIH: American Conference of Governmental Industrial Hygienists
- AIHA: American Industrial Hygiene Assoc. Workplace Environmental
Exposure Level Guideline
- OSHA: Occupational Safety and Health Administration

- NONE: None Established

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8. HEALTH HAZARD DATA
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EYE CONTACT:
Mild Eye Irritation: signs/symptoms can include redness, swelling,
pain, and tearing.

SKIN CONTACT:
Allergic Skin Reaction: signs/symptoms can include redness, swelling,
blistering, and itching.

Mild Skin Irritation: signs/symptoms can include redness, swelling,

and itching.

INHALATION:
Prolonged or repeated exposure may cause:

Allergic Respiratory Reaction: signs/symptoms can include

difficulty breathing, wheezing, tightness of chest, and
respiratory failure.

Irritation (upper respiratory): signs/symptoms can include

soreness of the nose and throat, coughing and sneezing.

IF SWALLOWED:
Ingestion is not a likely route of exposure to this product.

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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately
MSDS: SCOTCHCAST BRAND ELECTRICAL INSULATING RESIN 2100
August 14, 2001 PAGE 6

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SECTION CHANGE DATES
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HEADING SECTION CHANGED SINCE December 01, 1997 ISSUE

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Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately

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The information in this Material Safety Data Sheet (MSDS) is believed to

be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR
IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF
PERFORMANCE OR USAGE OF TRADE. User is responsible for determining
whether the 3M product is fit for a particular purpose and suitable for
user's method of use or application. Given the variety of factors that
can affect the use and application of a 3M product, some of which are
uniquely within the user's knowledge and control, it is essential that
the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.

3M provides information in electronic form as a service to its customers.

Due to the remote possibility that electronic transfer may have resulted
in errors, omissions or alterations in this information, 3M makes no
representations as to its completeness or accuracy. In addition,
information obtained from a database may not be as current as the
information in the MSDS available directly from 3M.