Advanced Test 6 Paper-1 Key & Sol. (08!05!2014)

Date : 08-05-2014
RIIT JEE-ADVANCED
TEST [6]
[ Paper - 1 ]
JEE | MEDICAL-UG | BOARDS | KVPY | NTSE | OLYMPIADS
Target : JEE 2014
ANSWER KEY
MATHEMATICS
1. (C) 2. (B) 3. (C) 4. (B) 5. (C)
6. (A) 7. (C) 8. (B) 9. (D) 10. (B)
11. (A,B,D) 12. (C,D) 13. (A,C,D) 14. (A,C) 15. (A,D)
16. (8) 17. (3) 18. (1) 19. (7) 20. (8)
PHYSICS
21. (D) 22. (C) 23. (D) 24. (A) 25. (B)
26. (A) 27. (C) 28. (D) 29. (B) 30. (B)
31. (ABC) 32. (ABCD) 33. (ACD) 34. (ACD) 35. (AC)
36. (2) 37. (1) 38. (6) 39. (3) 40. (4)
CHEMISTRY
41. (B) 42. (D) 43. (A) 44. (D) 45. (D)
46. (B) 47. (B) 48. (C) 49. (B) 50. (A)
51. (A,B,D) 52. (AD) 53. (AB) 54. (ABCD) 55. (ABCD)
56. (2) 57. (4) 58. (9) 59. (4) 60. (4)
RIIT JEE Advanced Test- 6/ Paper - 1 (Solutions)/ Target JEE-2014
2
PART-I: MATHEMATICS
= = = = = = = = = = = = = = = = = = = = == = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
1. (C)
1! 2! 3! 4! 33 + + + =
Topic :- Number System / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
2. (B)
( )
2
2 2
sin & 0 sin 1
4
x y
xy
+
= u s u s
Topic :- Trigonometrical Ratios and Identities / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
3. (C)
Homogenise & check
Topic :- Pair of straight - lines / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
4. (B)
tan tan 0 A A = H <
Topic :-Properties and Solutions of triangle / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
5. (C)
Equation of the tangent to the curve
2
5 6 x x + from origin at point ( ) ( )
2
, 5 6 o o o+ is
( ) ( )( )
2
5 6 2 5 y x + o o + = o + o (putting 0 x y = = ) 6 o =
Slope of tangent at point ( )

6
2 5 5 2 6 x
o=
o = + =
Now take help of the graph
Topic :- Application of Derivatives / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
6. (A)
( )
3 2
3 2
d x n n x
x x n x
+ +
+ +
}

Topic :- Indefinite Integration / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir

7. (C)
Use property IV of definite Integration
Topic :- Definite Integration / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
8. (B)
2 2 2
4
.2 2
2
x x
y e dx e ydy
dx
y

=

( )
2 2
2 2
2 2 0
x x
e e
d d x x c
y y
| |
= + =
|
\ .
Topic :- Differential equation / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
3
9. (D)
Length of diagonals of the parallelogram are equal
Topic :- Complex Number / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
10. (B)
1 x y z = = =
Topic :- Inverse Trigonometric function / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
11. (A,B,D)
Replace sin x with cosecx sin cosec x x =
2
sin 1 x =
Topic :- Functions / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
12. (C,D)
Period of ( ) f x can be
2
t
is
a b =
when ( ) , a b f x = has period t. Let us consider the domain | | 0, t
Case -I
( ) 0, ,
2
f x
t (
=
(

( )
2 2
sin cos sin a b x a b x + = + +|
where
2 2
sin
b
a b
| =
+
and
2 2
cos
a
a b
| =
+
| is an a cute angle
Clearly maximum value will occur when
2
x
t
+ | =
and minimum value at 0 x = or
2
x
t
=
Similarly Case - II
,
2
x
t | (
e t
(
\
13. (A,C,D)
Analyse case by case
14. (A,C)
x
x
A
=
A
etc.
( )
( ) ( ) ( )
2 2 2
2
a b c
a b b c c a
+ +
(
A = + +

x
q r b c
r p c a
p q a b
A =
Topic :-Determinants and matrices / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
4
15. (A,D)
Given equation can be written as
2
2
tan 1
sec
dy y
y
dx x x
+ =
Put
2
tan sec
dy dt
y t y
dx dx
= =

2
1 1 dt
t
dx x x
+ = which is a linear equations

1
.
dx
x
I F e x
}
= =

2
1
tx xdx c
x
= +
}
tan x y n x c = +
Topic :- Differential Equations / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
16. (8)
( ) 10 sin cos OA OB + = u+ u

10 2 sin
4
t | |
= u +
|
\ .
( )
max
10 2 OA OB + =
Also OA OB AB + >
Topic :- Straight line / Level :- 2 / (Adv. -1) Test - 6 / KGm Sir
17. (3)
Clearly the given fixed point is focus of the parabola and the locus is directrix.
Topic :- Parabola / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
18. (1)
2011
2011
' ' 1 P Q P P Q P = =
Topic :- Matrix and determinant / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
19. (7)

3 7 A B i j k =

Now ( ) ( )
max

3 7 A B C i j k C =

59 1 59 = =
Topic :- Vector / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir
20. (8)
Let first term is a and common difference is d.
12 a d =
sum of first nine terms
12 9 27d = +
Hence 200 12 9 27 220 d < + <
89 109
4
27 27
d d < < =
Topic :- Sequence and series / Level :- II / (Adv. -1) Test - 6 / KGm Sir
5
PART-II: PHYSICS
= = = = = = = = = = = = = = = = = = = = == = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
21. (D)

a
A
1
2
A
V
V
v sin
t
n
t
n
v cos
2 /n t
Length of the side of the regular polygon is decreasing from a to zero at the rates
2
cos V V
n
t | |
|
\ .
the
time after which the particles meet,
2
cos
a
t
v v
n
t
=
| |
|
\ .
2
2 sin
a
v
n
t
=
| |
|
\ .
the distance covered by each particle = vt

2
2sin
a
n
t
=
| |
|
\ .
Topic: Kinematic_L-2_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
22. (C)
1 1
2 2
2 2 2
m m
T
k k
t t
| | | |
= +
| |
| |
\ . \ .
1
1
2
m
k
t
| |
= +
|
\ .
( )
2 1
2
m
k
t = +
Topic: SHM_L-2__Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
6
23. (D)
6V
2V
1O
1O
The part of the circuit shown can be replaced by a single battery of emf
1 2 2 1
1 2
6 1 2 1
2
2
E r E r
E v
r r

= = =
+
Internal resistance
1 2
1 2
1
2
r r
r
r r
= = O
+
Hence original circuit diagram can be replaced by
2
A B
V V V =
Topic: Current Electricity_L-2__Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
24. (A)
For real object convex mirror always forms a virtual image
Using
1 1 1
f v u
= +
we get ,
1 1 1
v f u
=
For , u f V is ve image is real <
For , u f V is ve image is virtual > +
option (A) is correct

Topic: Optics_L-2_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
25. (B)
Since temperature remains unchanged therefore , . Uf Ui So Q W = A = A In the first step which is isochoric,
0. W A =
In second step, pressure
p
n
= . Volume V is increased from V to nV
( )
1 p n
W nV V PV
n n
| |
= =
|
\ .

1
2 1 RT
n
| |
=
|
\ .
Topic: Thermodynamic_L-I_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
7
26. (A)
Distance between plates on left hund side is d whereas on the right hand side is
( ) ( ) ( ) sin d t d l is small o o o + = + Mean distance between plates
( )
1
2
d d l o = + +
1
2
d lo = +
then using
0
,
A
C
d
c
=
we get
1
2 2
0 0
1
1
1
2
2
l l l
C
d d
d lx
c c o

| |
= = +
|
\ .
+
2
0
1
2
l l
d d
c o | |
=
|
\ .

Topic: Capacitors_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
27. (C)
Current in left network
6 2
9 3
A = =
Current in right network
12 4
9 3
A = =
( )
2 4 4
3 5 2 5 10
3 3 3
XY
V
| | | |
= + + +
| |
\ . \ .
8
3
V =
Topic: Current Electricity_L-I__Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
28. (D)
By law of refraction ( ) sin constant n = u we get
( ) sin90 sin 90 n u = ( where
u
is the angle of indination
of ray at B)
Then it implies that
1
cos
n
u =
and
2
tan 1 n u =
3/ 2 3/ 4
1 1 y y = + =
or
3/ 4 3/ 4
dy
y or dx y dy
dx
= =
or
3
1
4
1/ 4
4
3
1
4
y
x y
+
= =
+
or
4
256 x y =
Topic: Optics_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
8
29. (B)
(B) Explanation
The equation of straight line AB passsing through two point, ( ) ( )
0 0 0 0
, 3 & 3 , V P V P is
( )
0 0
0 0
0 0
3
3
3
P P
P P V V
V V
0 0 0
0
4PV PV
P
V
=
From ideal gas equation PV = nRT
0 0 0
0
4PV PV PV V
T
nR V nR
| |
= =
|
\ .
-----------------(1)
or
2
0 0 0
0
4PV V PV
T
nRV
=
---------------------------(i)
For temperature to be maximum
0 0 0
0 4 2 0
dT
PV PV
dV
= =
Using the value of volume in equation (i)
we get
( ) ( )
2
0 0 0 0 0
max
0
4 2 2 PV V P V
T
nRV
=
2 2
0 0 0 0 0 0 0 0
max
0 0
8 4 4 4 PV PV PV PV
T
nRV nRV nR
= = =
choices (A), (C) & (D) are wrong
Topic: Thermodynamics_L-II__Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
30. (B)
Using Flemings left hand rule, the Alpha particles, being positively charged and heavier, will be deflected to
the left but not large amount. Similarly electrons being negatively charged and lighter are deflected to the
right.
Topic: Magnetics_L-I_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
31. (ABC)
o
|
[sin sin ]
X
G
I
R
o | = +
[cos cos ]
Y
G
I
R
o | =
Now If o | = then
2
sin
x
G
l
R
o =
0
Y
I = so, choice (A) is correct and choice (D) is wrong.
9
If
2
t
o | = =
( If length of rod is infinite )
2
sin sin
2 2
X
G G
I
r r
t t (
= +
(

So, choice (B) is correct.
0
Y
I =
Relation between gravitational field intensity and gravitational potential,
dv
I
dr
=
0
2
v
r
G
dV dr
r
=
} }
| | | | 0 2 log log
e e
V G r =
| | 2 log log
e e
V G r =
2 log
e
r
V G
| |
=
|
\ .
log
e
r | |
|
\ .
is undefined
i.e., choice (C) is correct
Topic: Gravitation_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
32. (ABCD)
Explanation
Angular momentum = Linear momentum x Perpendicular distance from the point of rotation
L Jl =
Also
2
3
ml
I =

L Ie =
2
3 3 L Jl J
I ml ml
e

= = =
Kinetic energy
2 2 2 2
2
3
2 2 2
3
L J l J
K
ml I m
= = =

3
2 2
C
l J
V
m
e = =
So. choices (A) , (B) , (C) and (D) are correct.
Topic: Rotational_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
10
33. (ACD)
Explanation:
Epoch = Initial phase
2
t
= ( obvious )
velocity of wave
2 1
10 5
V
K
= = = =
e t
t
units
velocity of particle
( ) 2(3.5) sin 2 10
2
P
dy
V t x
dt
(
= = = +
(

t
t
units are to be observed carefully.
So choices (A), (C) and (D) are correct.
Topic: Waves_L-I_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
34. (ACD)
p
Li
7
O
o
o
u
u
O
O
Q value of reaction is
( ) 2 4 7.06 7 5.6 Q MeV =
Q = 17.28 MeV
Hence choice (A) is correct and choice (B) is wrong
Applying energy conservation
2
p
K Q K
o
+ = ----------------------(1)
where
p
K and K
o
are the kinetic energies of proton and o -particle respectively
From conservation of linear momentum,
2 2 2 cos
p p
m k m k
o o
u = ------------(2)
Squaring both sides
( )
2
2 4 2 4 cos
p p p
m k m k
o
u =
1
16
16
p
k k
o
=
i.e,
p
K K
o
= --------------------------(3)
Solving (1) and (3) with Q = 17.28 MeV
Hence choice (c) and (d) are correct,
Topic: Modern Physcis_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
11
35. (AC)
On contact , the net excess presure is given by
4 4 4 1 1 1
r a b r a b
o o o
= =
on merging
3 3 3
0 0 0
4 4 4 4 4 4
3 3 3
P r P a P b
r a b
o o o
t t t
| | | | | |
+ = + + +
| | |
\ . \ . \ .
( ) ( )
3 3 3 2 2 2
0
4 P r a b a b r o = +
r depends on
0
P and o
So, (a) and (c) are correct and (b) and (d) are incorrect.
Topic: Properties of Matter_L-II__Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
36. (2)
( ) 4 1 cos 2 U x =
du
F
dx
=

8sin2x =
( ) ( ) 8 2 ..... x xis small
16x =
16 K =
2
m
T
k
t =
1
2
16
t =
sec
2
t
=
2 n =
Topic: SHM_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
37. (1)
When shells are connected, charge on inner shell will be transferred to the outer shell
( ) 2
2 2
i
K Q KQ
V
R R
= +
i.e.,
0
3
2
KQ
V
R
=
0
V =
1 n =
Topic: Electrostatics_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
12
38. (6)
V LVB =
= (1) (2) (3)
= 6V
6
R C L
V V V V = = = ( All are in parallel)
L
di
V L
dt
=
6 2
di
dt
=
3 /
di
A S
dt
=
at 2 sec ,
3
6 I A =
Topic: EMI_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
39. (3)
Blocks A & C both move due to friction. But less friction is available to A as compared to C. Because
normal reaction between A and B is is less. Maximum friction between A and B can be
s
f , max
A
m g =

1
2
mg
| |
=
|
\ .
maximum acceleration of A can be,
max
max
2
s
f g
a
m
= =
Also, max
3
D
D
m g
a
m m
=
+
3
D
m m =
3 n =
Topic: NLM and Friction_L-II__Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
40. (4)
Mechanical energy is conserved in both the cases
2
2 2
0 0
1 5 1 1
2 4 2 2
m V mV Ie
| |
= +
|
\ .
i.e.,
2
2 2
0
0 0
25
16
V I
V V
m R
| |
= +
|
\ .
i.e.,
2
2
25
1
16
mK
mR
= +
i.e.,
3
4
R
K =
4 n =
Topic: Rotational dynamics_L-II_Target-14_JEE-Advanced Test -6_Paper-1_Physics_SPp Sir
13
PART-III: CHEMISTRY
= = = = = = = = = = = = = = = = = = = = == = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = =
41. (B)
Structure with octet complete (I and III) are more stable than structure with incomplete octet (II and IV).
(Most Important point to decide the stability of resonating structures )
Negative charge on more electronegative atom is more stable.
Topic:Concept of Resonance_L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
42. (D)
15 0.0821 223
1
mix
dRT
M
P

= =
= 33.61
( )
2
1
mix CO CO
M M x M x = +
( ) 33.61 44 28 1 x x = +

0.35 x =
1 0.65 x =
(mole fraction of CO)
Topic: Gaseous State _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
43. (A)
Topic: Chemical Bonding _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
44. (D)
In B-D glucose all OH & CH
2
OH at equatorial position (B-D glucose is more stable than
D o
glucose)
Topic: Carbohydrates _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
45. (D)
Si does not disproportionate because it cannot take negative oxidation state.
Topic: P-Block _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
46. (B)
Topic:Chemical Kinetices _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
47. (B)
2 3
88
80
2
gm
gm
FeS Fe O
Let FeS is x gm in 100 gm of ore. x gm FeS produces 80x/88 gm of Fe
2
O
3
.
80
4
88
100 100
x
x

44 x =
Topic: Mole Concept - 1 _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
14
48. (C)
H E nRT A = A +A
H E RT A = A
H E A < A
Topic: Thermodynamics - 1 _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
49. (B)
both
3
||
&
O
H C CH o group are present
Topic: Carbonyl Compound - 1 _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
50. (A)
Topic: Alcohol, Alkene, Carbonyl (Mixed)_ L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
51. (A,B,D)
( ) ( )
2 3
3 4
2 B OH H O B OH H O

( + +

( ) ( ) ( )
3 4
B OH NaOH Na B OH +
Topic: P-Block _ Sub Topic _ Boron Group _ L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
52. (AD)
(A) 10
2
M HCl will neutralise 10
2
M NaOH
7 pH =
(B)
1 4
10 10 M HCl M HCl

+
Resultant conc. = 5.0510
3
M
2.3 pH =
(C) NaCN will hydrolyse to give pH more than 7
(D) As 7
a b
pK pK pH = =
Topic: Inoic Equilibrium_ L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
53. (AB)
( )
4 3 2 4
3
12 4 3 Al C H O Al OH CH + +
( )
2 2 4
2
4 2 Be C H O Be OH CH + +
Topic: Metal Carbides _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
15
54. (ABCD)
10
1
A
A
V litre
P atm
=
=

isothermal

1
10
B
A A
B
B
V litre
P V
P atm
V
=
= =
B C adiabatic process

PV K
=

B B C C
P V P V

=

B
C B
C
V
P P
V
| |
=
|
\ .
For Monoatomic Gas
5
2
=

5/ 3
1
10
10
C
P
| |
=
|
\ .

5 2
1
3 3
10 10

= =
For Diatomic Gas
7 2
1
5 5
7
10 10
5
C
P

= = =
As the curve for compression (AB) is higher than the cruve for expansion (BC) thre network in done on the
system .
Topic: Cycloalkanes _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
55. (ABCD)
(A)

O
O
H C
3
H
(1) LiAlH
4
(excess)
(2) H O
2

OH
OH
H C
3
H
optically
in active
(B)

O
O
H C
3
H
(1) CH MgBr
3
(excess)
(2) H O
2

OH
OH
H C
3
H
optically
in active
(C)
(D)
Topic: Stereo Isomerism_L- 2_Target-14_Advanced Test [6]_P-1_KRch sir.
16
56. (2)
2
4
8
5
n factor of Cu S is
n factor of KMnO is
8 1.25 5 ? =

? 2 =
Topic: Mole _L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
57. (4)
2
13.6 IE Z eV =
4 13.6 54.4 IEof He eV
+
= =
3
16 13.6 217.6 IEof M eV
+
= =

2
16 Z =

4 Z =
Topic: Atomic Structure_L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
58. (9)
Topic: Stereo Isomerism_L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.
59. (4)
ElcB
Mech occurs when
(1) Acidic
H o
is present
(2) Poor leaving group is present
Topic: Elimination Reations_L- 2_Target-14_Advanced Test [6]_P-1_KRch sir.
60. (4)
Topic: Carbon Family_ Sub Topic : Silicates _ L- 1_Target-14_Advanced Test [6]_P-1_KRch sir.

Advanced Test 6 Paper-1 Key & Sol. (08!05!2014)

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Advanced Test 6 Paper-1 Key & Sol. (08!05!2014)

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Date : 08-05-2014

Slope of tangent at point ( )

Topic :- Indefinite Integration / Level :- 1 / (Adv. -1) Test - 6 / KGm Sir

the distance covered by each particle = vt

option (A) is correct

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