Common apparatus used in A Level Chemistry April 2007
Names of apparatus you should know for the exam are:
Burette (50cm 3 ), pipette (25 cm 3 , 10cm 3 ), dropping pipette, pipette filler, conical flask, volumetric flask (150 to 250 cm 3 ), measuring cylinder (25 and 50 cm 3 ), wash bottle, filter funnel, porcelain crucible, 15cm 3 with lid, evaporating basin at least 30 cm 3 , beaker 100 cm 3 , 250 cm 3 , thermometer 10 o ! to "110 o ! at 1 o ! inter#al$ 5 o ! to "50 o ! at 0%2 o ! inter#al, plastic beaker of approximate capacity 150 cm 3 , test-tubes, boiling tubes, clock or stop-watch to measure accuracy of 1s, balance 0%01& accuracy% ! "itration 'ou are familiar now with the titration experiment often used to accurately find the end point in a neutrali(ation or redox experiment and find unknown concentrations to )e used in further calculations or plannin& * analysis% e%&% Na+,(a-) " ,!l(a-) . Na!l(a-) " ,2+(l) /olumetric flask !onical flask measurin& cylinder 0f the solution )ecomes cloudy to reach endpoint (e%&% formation of sulphur in redox reaction) then a cross (#) drawn on a white piece of paper will disappear under the conical flask% 0f you were asked to descri)e a titration experiment, you should write these steps: 1% 1ipette 25 cm 3 of 0%5 moldm 3 Na+,(a-) solution into a 250 cm 3 conical flask% 2% 2dd three drops of )romophenol )lue indicator% 3% 3itrate the alkali with the a-ueous hydrochloric acid (422) to reach endpoint (the colour will chan&e from a li&ht )lue to a permanent yellow or red) and take the a#era&e of a)out three titres% 2ccuracy of "5 0%05 cm 3 in measurin& #olume chan&es with the )urette (no need to draw a picture only ta)ulate results if asked)% "5 0%05 cm 3
'ou would record the results as shown: 2#era&e titre66666%%cm 3 7uch titrations can )e used in other ways such as determinin& the amount of )ase in a mixture of compounds (e%&% a car)onate) or used in neutrali(in& acids in an e-uili)rium experiment (which you pro)a)ly carried out )efore)% 0n &eneral, plannin& and analysis follows this chart: 8here there exists a potential dan&er, e%&% corrosi#e acid (conc% ,27+9), concentrated alkali or poisonous &as released (N+2, 7+2) a precaution should )e mentioned (wear &lo#es, use fume hood)% 2! $easuring enthalpy changes in e%othermic or endothermic reactions
8ith some chemical reactions or dissol#in& a solid in water (e%&% Na+,), heat is &i#en out (,soln)% 0f you were asked to measure an enthalpy chan&e you could write to this effect: 1% 8ei&h out a)out 0%1 mol of the solid% 2% :easure 100 cm 3 of distilled water into the plastic cup% :easure its temperature to accuracy of 0%2 o !% 3% ;uickly dissol#e a)out 0%1 mol of the su)stance in water and measure its hi&hest temperature (this may take a minute)% Calculation (processing of results) 4. 3akin& the specific heat capacity, c, of water to )e 9%2 <& 1 = 1 which can )e assumed to )e the same for the solution, so & ' mc" and is )ased on one mole of su)stance and remem)er to &i#e the #alue a ne&ati#e si&n for exothermic enthalpies% 'ou may ha#e to show how the calculation is worked out and in that case 3 is the temperature chan&e shown )elow: 0nitial temperature (31)5 o ! 4inal temperature(32)5 o ! 3 (3231)5 o ! 1 2 3 2#era&e 3 . 66666666% 0n a similar way, if it was a chemical reaction then you would measure the temperature of a known amount of su)stance 421 dissol#ed in water and the add su)stance 422 (can )e a solid or known amount in a #olume of water)% >emem)er the mass, m, is the mass of the total #olume of water in &% 7ee also October/November 2003 Paper 5, :ay5<une 2009 1aper 5% thermometer )eaker plastic cup lid (! "hermal )ecomposition 1orcelain cruci)le and lid 2 porcelain cruci)le (with lid) is used to heat a small amount of su)stance (a)out 2 &) usin& a ?unsen )urner (or alcohol spirit )urner), tripod and &au(e% 2 )oilin&tu)e may alternati#ely )e used if supplied as these can withstand hi&h temperatures of a flame% Find te percentage of copper(!!) carbonate in te mineral roc" malacite% 1% 8ei&h an empty cruci)le% 2% 8ei&h the cruci)le and a)out 2%0 & of the mineral ("5 0%01&)% 3% ,eat the cruci)le and contents for 10 minutes on a tripod and &au(e 9% >ewei&h the cruci)le% 3he results are ta)ulated as )elow: :ass of cruci)le 5 & :ass of cruci)le " malachite :ass of cruci)le and contents after heatin& :ass of !+2 produced 2ssumin& the mineral to contain no other decomposition products, then accordin& to the e-uation: !u!+3(s) . !u+(s) " !+2(s) 3he difference in mass )efore and after heatin& is the mass of !+2 released% 0f we calculate the predicted mass of !+2 for the same wei&ht of pure !u!+3, the percenta&e )y mass of !u!+3 in the malachite is therefore: @ !u!+3 in malachite . mass of !+2 from malachite x 100 mass of !+2 from pure !u!+3 7ee also #a$/%une 2003 Paper 5% *! +,uilibria 3his summari(es the steps used in Practical &'( Cemistr$ in Conte)t( *aborator$ #anual( page '2+''% Plan Asin& a )urette, add the exact amount of ,!l(a-), water, ethyl ethanoate, ethanoic acid and water to a stoppered 100cm 3 #olumetric flask (or wellstoppered flask) so that the total #olume is exactly 10cm 3 % 7hake well% 2fter one week (to allow the mixture to reach e-uili)rium) titrate the whole of the mixture with 1%0 moldm 3 sodium hydroxide (422) solution usin& phenolphthalein as indicator in the flask% 3he first permanent si&n of pink is the end point% 0n order to find the exact concentration of the ,!l(a-) catalyst, titrate 5 cm 3 of the 3 moldm 3 with 1%0 moldm 3 Na+, 8ei&h 5%0 cm 3 of each of the li-uids used in the e-uili)rium experiment to determine their densities and thus find the mass of materials used ( . m5#)% 3a)ulate results: ,nal$sis 3he steps findin& the e-uili)rium constant in the manual will show you how to calculate the e-uili)rium constant, =c% 7ee also October/November 2005 Paper 5 for another e-uili)rium experiment% -! )etermining the order of a reaction 7ee Practical &5, Cemistr$ in Conte)t *aborator$ #anual% 7ee also +cto)er5No#em)er 2009 1aper 5, +cto)er5No#em)er 2002%