By: Blake Johnson Under the direction of Dr.Teresa Litzenberger North Carolina State University Environmental Technology 201 November 15, 2013 Introduction In coordination of North Carolina State Universitys Environmental Technology program, the Little Rock Creek of Raleigh, North Carolina was assessed by a team of students, including myself, under the direction of Teresa Litzenberger. While the Little Rock Creek may, in length, be little but in importance, be large: it is part of a much greater picture. Little Rock Creek is part of the Walnut Creek watershed (Stormwater Utility). The creek is also a member of the Upper Neuse River drainage basin, which drains into Raleighs main source of drinking water, the Falls Lake Reservoir (About the Upper Neuse River Basin). About 30 years ago, a Ward Transformer building in the Upper Neuse River Basin was found to be leaking hazardous chemicals into a surrounding creek (PCB Contamination). Of these chemicals, toxic pollutants responsible for human endocrine disruptions and neurotoxicity that go by the name of polychlorinated biphenyls, or PCBs for short, were found. Stream water treatment against such chemicals began approximately 20 years ago, and PCBs remain a problem in the Upper Neuse River Basin. With that being said, problems in a stream may very well create problems across the state; the health of one stream no matter now long, is holistic for the health of water quality as a whole. Little Rock Creek meanders through southeastern Raleigh with a figure that, to the best of an attempt to relate a relatable image can be described as a rugged S, a 2 squiggly lightning bolt shape, or the function of x 3 graphed out. The bottom surface consists of sand layered with small cobbles and some gravel. A lack of large trees and a light sediment bottom allows for erosion to easily occur within the stream, and so it does, widening the greatest at moments of curves. Because of this, in wide turns the flow is slower at the arcs. Additionally, at curves pools are scattered and stream failure is evident at some points as fresh sand deposits overpower the stream causing for a backup of debris and, at times, litter. Flowing through an urban environment, the creek is approximately 3.6 miles away from the universitys campus (Raleigh, North Carolina). There is a trail that follows the entirety of the stream and much further beyond as part of the Capital Area Greenway System, a 110 mile system of mostly paved, connected trails traveling through the city of Raleigh, with many of which in close proximity to streams or creeks (Capital Area Greenway Trail System). The stream itself is cumulatively 1.1 miles in length, passing through Martin Luther King Jr Blvd, Bragg St, and Peterson St until it discharges into the Walnut Creek seven-tenths of a mile south of the intersection between Peterson St and S State St. According to Title 15A of the North Carolina Administrative Code, Rule .0302 contains the classifications for waters located within the Neuse River Basin (15A NCAC 02L .0312). However, for Little Rock Creek, this does not seem to be the case; Little Rock Creek has not yet been classified. Therefore, Rule .0301 is followed, stating that any unnamed stream that does not fit the exceptions listed, the streams of the Neuse River Basin are of no exception, shall follow the classification of the stream which it is tributary (Classifications and Water Quality Standards Assigned to Waters of the Neuse 3 River Basin). That withstanding, until Little Rock Creek is specifically, officially classified by the North Carolina Division of Water Resources, it will be classified under the guidelines of Rule .0301 as Class C / Nutrient Sensitive Water. This is so because the portion of Walnut Creek located within the Neuse River Basin (part of Walnut Creek is additionally in the Tar-Pamlico River Basin) closest to Little Rock Creek has been deemed such (15A NCAC 02B .0315). The classifications entail that Little Rock Creek to be protected for recreational and wildlife use as well as to be safe for incidental human contact. Additionally, that the water is prone to an imbalance of nutrients and in need of more nutrient management. With the stream so close to urban developments, as there is a sizable middle school in proximately as well as developed neighborhoods, the stream has great potential to be exposed to nutrients that may very well cause an overabundance of microscopic and macroscopic vegetation through yard waste such as pesticides running off into the stream or cut grass blowing into the stream, both of which adding nutrients to the nutrient sensitive water to potentially harvest algae blooms. Notwithstanding, there is a point where the stream flows underneath Peterson Street through culverts, increasing the likelihood to exposure to pollution through motor exhaust. This and the Capital Area Greenways almost completely adjacent following of the creek and surrounding tributaries spike the chances of passersby littering into the stream. Indeed, litter was noticed beginning at the first point of observation to the last from the likes of a basketball, snack food wrappers, bottles, and even a mattress. It cannot be said that the trash observed in Little Rock Creek was attributed to any other streams, as no streams are attribute to the Little Rock Creek. 4 Within a five-minute walk of the merging of the Little Rock Creek and Walnut Creek, stands a building crafted to optimum environmentally sustainable standards with a sole purpose of addressing the problems facing wetlands, the Walnut Creek Wetland Center (Walnut Creek Wetland Center). The center is more than well aware of factors concerning the well being of the backdoor wetlands, and its team has not been sitting back watching. Last year, the team developed a variety of plans to not only reduce the flooding of public streets but to increase the quality of water as well as restore and stabilize nearby streams (Stormwater Utility). Such efforts are especially needed for Little Rock Creek as erosion, and other factors that contribute to flooding and stream stability, are evident.
Assessment & Methodology Our group observed the Little Rock Creek over the course of several weeks. We arrived to our first site, WL-3, around 9:00 AM on a partly cloudy day with temperatures ~63 Fahrenheit on the 17 th of October 2013. On the first day, my group traveled to three points across the span of the creek conducting Rapid Stream Assessment Technique assessments to get an idea of the health of the stream before actually administering tests. 5
Figure 1: Little Rock Creek. Regrettably excluding WL-1, which is the culvert after crossing Peterson St from the South The RSAT is an approach for measuring observational data in the field that can indicate a streams condition. The test is administered by ranking various characteristics of a stream or river based on factors for each category. Fields include channel stability, channel scouring or sediment deposition, physical instream habitat, water quality, 6 riparian habitat conditions, and biological indicators of macroinvertebrates. For each, a ranking is given numerically, and then conditionally based on the numerical value. This can be exclusive to categories, which have varying values between the condition and numerical value, or inclusive to the testing position as a whole and tallying up the total points. Ranking for category or whole can be poor, fair, good, or excellent. For categories: 0-2 is always poor, 3-5 is generally fair, 5-7 is generally good, and excellence tends to be in the 7-9 ranges. Some categories have more maximum points than others, such as channel stability; this is because some aspects of a stream are more detrimental than other. For total points of an observed location, <16 is poor, 16-29 is fair, 30-41 is good, and 42-50 is excellent. Our first stop, site WL- 3, if following the S idea mentioned in the introduction, would be in about the middle of the bottom right dent. From this sight, S State Street can be seen peeking through some mixed hardwoods. This sight, as for most observed points, was the victim of erosion. While about 60% of the bank was stable, slumping was steep (about 4-5 feet above the stream) and fairly common as were tree roots. Additionally, the bottom was mostly erodible soils and light cobblestone. These factors made it easy to determine the stream suffered with only fair condition. Channel scouring was not so great either, as there common sand deposits large enough to the point that one could walk in the stream and not get wet. A decent mix of pools and riffles and runs were present and Image 1: WL-3 7 there with some points being slow and shallow as well as plenty some canopy over pools, so WL-3 offered a fair instream habitat, though because of how shallow it was (less than a ft.) it is hard for me to imagine sizable fish actually traveling through this. Organisms in the riparian habitat had the same quality of amenities with mostly wooded canopy with some gaps from younger trees. The water is mostly clear and offers a slight odor. Following the trail south, we went to our next point, WL-4. This was the highest ranked point of the creek we came across. At this point, Little Rock Creek tributes into Walnut Creek right as the Walnut Creek Trail goes underneath S State St. There had been modifications to stabilize this point in the stream, some riprap and netting line the sides of a portion of the bank to prevent further sloughing, though the bank was still steep. The flow is more consistent here; with some knick points and less points of failure. Even with the most depth of all previous points, large sand deposits still line near the banks. After a large knick point, some deeper pools with a toned down flow occupy a portion of bank. On the sides closer to the trail and S State St, less canopy is offered. With larger rocks, greater sedimentation, and accelerated velocity, the water just deposited from Little Rock Creek is mostly clear with only the exception of some debris that line the bottom and cloud a minor section of the odorless water though the depth allows for the best instream habitat in relation to the other sites. Image 2: WL-4 depositing into Walnut Creek 8 Working our way back up north from where we came, we visited point WL-2, which following the S concept could be said to be in the top-left arc of the S. Out of all points we observed on the creek, WL-2 was the worse in quality. This site is heavily eroded, with spacious mounts of sand and cobblestone that interrupt the flow causing complete failure at several points. There is very little to no stream stability besides what limited segment manages to curve across the banks of the sand mount, thus sharply eroding the banks of the stream parallel to the mount. Tree roots cover the banks; a small tree even grows from a cluster of sand. Despite this, the clear, odorless water that manages to progress between the sand and bank has great velocity and riffles though few pools are available for instream organisms, and the ones which are, are shallow like their jurisdiction. However, at this mark riparian species attain satisfactory, but not optimum, commodities as plenty of canopy is provided aside from few divides. The final point my team observed was the most upstream amongst all others, the point as soon as Little Rock Creek flows underneath Peterson St. Regardless of a mattress being dumped on the steep banks of the stream, in comparison to other Image 3: WL-2, observe over abundance of sediment and a fallen tree. Image 4a: WL-1, north of the Walnut Creek Wetland Center 9 territories this mark is fair. At this area, the stream is wider than all others we observed. However, it maintains greater depth than all sites but WL-4, notwithstanding this site, like the others, includes large rubbles of sediment, exposed tree roots, heavy erosion, and fallen trees. The water is mostly clear, but does not carry much velocity or offer an adequate amount of riffles and it produces a slight odor. On the 31 st of October, my team and I returned to Little Rock Creek around 9:00 AM once more in order to take water quality samples. The weather was overcast and ~60 Fahrenheit. On site, we tested pH, conductivity (s/cm), dissolved oxygen (mg/L), turbidity (NTU) and temperature (C). To do so, we used a combination of YSI tools. To find DO, conductivity, temperature at WL-3 we used YSI Pro2030. To find the same information at WL-4 and WL-2, we used YSI ProfessonalPlus. Since we tested for turbidity at WL-2 as well we also used the HACH 2100P Turbiditor in combination of the YSI 6 XLMV2600. At WL-1 we used the YSI model85 to test DO levels and used the YSI 600xl in combination of the YSI 650mds to find everything else. Before using the tools, they were calibrated by Dr. Teresa Litzenberger. In addition to this, we collected two water samples at each point in sterile, 125 mL, plastic jars, with a duplicate at WL-3, to test for E.coli contamination within the creek. We also gathered nitrate and nitrite samples to test for nitrogen compounds in the same manner though one jar for nitrite and another for nitrate. Further samples were Image 4b: WL-1, north of the Walnut Creek Wetland Center. 10 taken in 40 mL, sterile, glass VOC vials in order to test for Volatile Organic Compounds, which is testing Dr. Litzenberger conducted. When taking and working with all samples, latex gloves were worn at all times to avoid contamination of results thus maintain scientific integrity. E.coli samples were held at 4 Fahrenheit for cumulatively an hour before undergoing tests. To tests for E.coli, I individually emptied each the labeled jars to 100ml. Then, I added Colilert substrate to each and calmly shook the mixture until the substrate had dissolved. After which I poured each sample into a quantitray and fed the sample with the quantitray into the sealer. When it came out, the samples were placed into an incubator for 24 hours. At which time Dr. Teresa Litzenberger removed the samples from the incubator to observe them under fluorescent light to see which cells had indicated E.coli presence and recorded the data. To tests for nitrate and nitrite, HACH Water Quality Test Strips for Nitrate and Nitrite were dipped into our designated samples. The strips changed color indicating the amount of nitrite and nitrate present, which is then compared to the graph of color options on the back of the case. I returned to the stream independently on the 8 th of November 2013 to look over my observations and take more detailed notes regarding the characteristics of the stream.
Results and Discussion Measurements collected on the 31 st of October 2013 from cumulatively 9:00 AM to 10:40 AM are shown below.
The pH for all of the four cites is within healthy range for life, 6 9, and falls within NCDENR guidelines for Class C waters (Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of N.C. 15A NCAC 2B .0300.). If the creek were to fall below optimum pH standards, aquatic life would be stressed and the water would be deemed too acidic. Water has the ability to hold an electrical current through conductivity though water is rarely tested in mind to see how much of an electrical current it can hold, more so its mineral abundance as conductivity is a proportional indicator of dissolved solids or inorganic substances such as phosphates and sodium that can be potentially harmful to an environment. Looking at table 2, it can be seen that WL-1 had such a high level of conductivity that it went from s to ms. This could be due to the amount of impervious surfaces and urban development nearby; WL-1 and WL-4 have the highest amounts of conductivity and are the closets to urban development out of all points tested.45% of the area surrounding the creek are impervious surfaces, so it is likely runoff from pesticides or home products got into the water. This can be dangerous if it continues to increase as the nutrients will cause an overabundance in plant growth resulting in water too basic for aquatic life as the rapid plant growth absorbs too much carbon in the water during photosynthesis. While conductivity levels are still within legal range, 50-400 s/cm, they should be monitored closely because they are approaching the limit. Dissolved oxygen levels throughout the entire Little Rock Creek are much too high. The optimal levels of dissolved oxygen for aquatic life dwindle around 5 mg/L. If value lays between 2-5 mg/L, aquatic life is stressed, and when levels are below 2 mg/L 13 fish start to die off. However, at this point, the water is oversaturated with dissolved oxygen and fish are not adjusted to living with an overbalance of dissolved oxygen to water. This can also relate to the conductivity. Since the conductivity in the stream is high, perhaps it is causing and overgrowth of plants and algae and causing a fall in dissolved oxygen levels. Little Rock Creek is a Nutrient Sensitive Water and given the correlations, it may very well be on its way to the eutrophication. Nitrogen is a large contributor to eutrophication. Like phosphates and other minerals, it accelerates the growth of plant life. While eutrophication may very well be a threat to this stream, nitrogen does not seem to be where to point fingers. From the points where we tested for nitrite and nitrate, nitrogen does not seem to be very active. Nitrite was not detected through sampling; nitrate was but at a low amount. North Carolina Division of Water Quality standards has the limit set to 10 mg/L. Turbidity appeared to stay low throughout the whole creek. Though two areas were tested, and there were definitely portions of the stream with slight cloudiness, I mostly observed clear waters through my trek. For the first two points, results read well below the North Carolina Division of Water Quality standards of at most 50 NTU (15A NCAC 2B .0300.). Perhaps though it would be better if the water exemplified more turbidity, at least for this phase where eutrophication may be approaching. That way it would block plants from photosynthesizing as much and balance the dissolved oxygen level. E.coli is exposed to environments through animal waste. With trails connecting throughout the whole city, it is likely that someone walked their dog through Little Rock Trail and the dog decided it would hop in the stream and take care of business. While 14 E.coli is something totally undesirable, it is not of large concern at the moment given its occurrence is mostly always incidental or temporary. Nevertheless, E.coli, or any fecal coliform for that matter, by the North Carolina Division of Water Quality, shall not exceed a geometric mean of 200/100ml (MF count) based upon at least five consecutive samples examined during any 30 day period, nor exceed 400/100ml in more than 20 percent of the samples examined during such period. (15A NCAC 02B .0211). In that case, all of the samples for E.coli are showing an abundance of coliform and more testing needs to be conducted following the guidelines put in place for fecal coliform.
Table 3: Relationship between the conductivity levels of this year and the conductivity levels of last year.
0.000 0.050 0.100 0.150 0.200 0.250 0.300 0.350 C o n d u c t i v i t y
( m S / c m )
Conductivity WL-1 WL-2 WL-3 WL-4 0.00 2.00 4.00 6.00 8.00 10.00 12.00 D O
( m g / L )
Dissolved Oxygen WL-1 WL-2 WL-3 WL-4 Table 4: Relationship between the DO levels of this year and the DO levels of last year. 15 Conclusion The assessment of Little Rock Creek shows that the creek is facing several concerns, ranging from erosion to potential eutrophication. With the creek being located in the middle of a large city, and being connected to so many public walkways and trails, it is easy to point the finger at suburban advancement as reason for its downfall. The spreading of impervious surfaces around the streams increase the likelihood that nutrients will be taken in by the stream, thus raising its conductivity, then oversaturating its dissolved oxygen through overabundance of photosynthesis which will then crash the pH levels as well. In the areas that would bring about this downward spiral to eventual death of all stream life, namely alterations in conductivity and dissolved oxygen in turn, a raise from last years levels can be noted in tables 3 and 4. Understandably, there will be a increase in dissolved oxygen as colder weather approaches since dissolved oxygen and temperature have an inverse relationship, but a seasonal change cannot account for the increase by the year. With plans on expanding the Greenway another 4.5 miles, it is hard to say what the future holds for Little Rock Creek ("Walnut Creek Trail Will Extend Greenways in Raleigh from Umstead to Neuse."). While something as a Greenway builds appreciation for nature in some, it exposes nature to habits of others as well see urban streams become victims of neglect. The fermentation of the Walnut Creek Wetland Centers plan to restore and stabilize streams, as well as reduce flood plains, should greatly help terminate a great deal of run off making its way into the volatile, nutrient sensitive stream, Little Rock Creek.
16 References: 15A NCAC 02B .0315. United States. Environmental Management Commission. North Caroline Department of Environment & Natural Resources. Classifications and Water Quality Standards Assigned to Waters of the Neuse River Basin. Environmental Management Commission, 15 Jan. 2011. Web. 14 Nov. 2013. <http://portal.ncdenr.org/c/document_library/get_file?bajuuid=a2efae1a-06a0-43dc-b6b9- f0c3b955ce94&groupId=38364>.
15A NCAC 02L .0312. Department of Environment and Natural Resources. "North Carolina Administrative Code." Title 15A. Environmental Management Commission, 1 Jan. 2010. Web. 14 Nov. 2013. <http://portal.ncdenr.org/c/document_library/get_file?folderId=285750&name=DLFE- 14969.pdf>.
15A NCAC 2B .0300. United States. Division of Water Quality. North Caroline Department of Environment & Natural Resources. Classifications and Water Quality Standards Applicable to Surface Waters and Wetlands of N.C. 15A NCAC 2B .0300. Environmental Management Commission, 1 May 2007. Web. 14 Nov. 2013. <http://portal.ncdenr.org/c/document_library/get_file?uuid=b399d1e0-0a9e-4dcc-9605- a673d8a5c6df&groupId=38364>.
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