Space for rough work

CHEMISTRY
SECTION I
Single Correct Choice Type
This section contains 9 single correct choice type questions. Each question has 4 choices: (a),
(b), (c) and (d) for its answer, out of which ONLY ONE is correct.



1. The energy of the second Bohr orbit in the hydrogen atom is 3.41 eV. The energy of the
second Bohr orbit of He
+
ion would be
(a) 0.85 eV (b) 13.64 eV
(c) 1.70 eV (d) 6.82 eV

2. Which of the following statement for crystals having Frenkel defect is not correct?
(a) Frenkel defects are observed where the difference in sizes of cations and anions is large.
(b) The density of crystals having Frenkel defect is lesser than that of a pure perfect crystal.
(c) An ionic crystal may have Frenkel defect along with the Schottky defect.
(d) Pure alkali halides do not have Frenkel defect.

3. The lattice energy of solid NaCl is 180 kcal/mol. The dissolution of the solid in water in the
form of ions is endothermic to the extent of 1 kcal/mol. If the solution energies of Na
+
and Cl

are in the ratio 6 : 5, what is the enthalpy of hydration of Na
+
ion?
(a) 85.6 kcal mol
1
(b) 97.6 kcal mol
1

(c) 82.6 kcal mol
1
(d) +100 kcal mol
(a)
1


4. Amongst the following carboxylic acids, the strongest acid is (for first dissociation of
dicarboxylic acid)

C C
HOOC
H
COOH
H
(b)

C C
H
H
COOH
HOOC

(c) CH
3
CH
2
COOH (d) CH
3
COOH


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5.

C=N
Ph
CH
3

OH
.
.
on treatment with acid followed by hydrolysis yields
(a)

CH
3
COH and
NH
2

O
(b)

and CH
3
CH
2
NH
2

COH
O

(c)

and HCOH
CH
2
NH
2

O
(d)

CH
2
COH and CH
3
NH
2

O


6. The product (X) in the following reaction is

CH
3

O
+one equivalent of HI

(X)

(a)

I
OH
CH
3

(b)

O
CH
2
l

(c)

OH
CH
2
l
CH
3

(d)

I
CH
2
l
CH
3



7. The mechanism of ester formation in acidic medium is as follows.


RCOH


O
H
+

RCOH RCOH


Step (i)
HO
+
HO

+ROH; H
+

RCOH
HO

OR



H
+

Step (iii)
Step (ii)
RCOH
HOH

OR



H2O
Step (iv)
+
RCOR
H
+

Step (v)
HO
+

RCOR
O



+

The slowest step in the above mechanism is
(a) Step (i) (b) Step (ii)
(c) Step (iii) (d) Step (iv)


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8. PCl
3
and PCl
5
both exist but only PH
3
exists while PH
5
does not exist. This is because
(a) H is less electronegative than P.
(b) the activation energy for the formation of PH
5
is very high.
(c) PH
5
immediately decomposes to PH
3
and H
2
as its equilibrium constant for the
decomposition is very high.
(d) Cl is more electronegative than P while it is not so for H and P.

9. A galvanic cell is composed of two hydrogen electrodes, of which cathode is a standard
hydrogen electrode. In which of the following solutions should the other half cell be
immersed to get maximum EMF?
(a) 0.1 M C
6
H
5
CO
2
H (b) 0.1 M CH
3
CO
2
H
(c) 0.1 M HCO
2
H (d) 0.1 M H
2
C
2
O
SECTION II
4


Multiple Correct Choice Type
This section contains 4 multiple correct choice type questions. Each question has
4 choices: (a), (b), (c) and (d) for its answer, out of which ONE OR MORE is/ are correct.



10. Which of the following heterocyclic compound would not have aromatic character?
(a)

N
N
(b)

N HN
(c)

NH
NH
(d)

NH
N


11. The difference in properties of CH
4
and SiH
4
is due to
(a) large difference in the electronegativity of carbon and silicon
(b) large difference in size of carbon and silicon atoms
(c) the inability of carbon to expand its octet
(d) the inability of silicon to form double bonds

12. On mixing 1 mole of C
6
H
6
(P =42 mm Hg) and 2 mole of C
7
H
8
(P =36 mm Hg), one can
conclude that
(a) total vapour pressure of mixture is 38 mm Hg.
(b) mole fraction of C
6
H
6
in vapour state above liquid mixture is 7/19.
(c) solution would show positive deviation from Raoults law.
(d) ideal solution is formed.



Space for rough work
13. 0.1 mole of

4
MnO in acidic medium can oxidize
(a) 0.5 mole of Fe
+2
(b) 0.167 mole of FeC
2
O
2
4 2
O C
4
(c) 0.25 mole of (d) 0.60 mole of
2
7 2
O Cr



SECTION III
Reasoning Type
This section contains 3 reasoning type questions numbered 14 to 16. Each question contains
Statement-1 and Statement-2. Each question has 4 choices (a), (b), (c) and (d), out of which
ONLY ONE is correct.



Directions: Read the following questions and choose
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for
Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is not a correct explanation for
Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.

14. Statement 1 : 3d
xy
, 4d
xy
, 5d
xy
all are having the same shape i.e., the double dumb bell.
Statement 2 : The size of orbitals are independent of the principal quantum number.
(a) A (b) B (c) C (d) D

15. Statement 1 : Chloroform, bromoform and iodoform all form at the same rate in the alkaline
medium from acetone.
Statement 2 : Cl
2
, Br
2
and I
2
all are having same electrophilicity.
(a) A (b) B (c) C (d) D

16. Statement 1 : The addition of one equivalent of HCl on CH
2
=CHC CH takes place on
C C bond and not on C =C bond.
Statement 2 : The product is a conjugated diene which is more stable.
(a) A (b) B (c) C (d) D





Space for rough work
SECTIONIV
MatrixMatch Type
This section contains 2 questions. Each question contains statements given in two columns,
which have to be matched. The statements in Column I are labelled A, B, C and D, while the
statements in Column II are labelled 1, 2, 3, 4 and 5. Any given statement in Column I can
have correct matching with ONE OR MORE statement(s) in Column II. The appropriate
bubbles corresponding to the answers to these questions have to be darkened as illustrated in
the following example:
If the correct matches are A 1, 4 and 5; B 2 and 3; C 1 and 2; and D 4 and 5; then the
correct darkening of bubbles will look like the following.

A

1 2 3 4
1 2 3 4
1 2 3 4
1 2 3 4
B

C

D

1 2 3 4
5
5
5
5
5




1.

Column I Column II
(A) 2p 1. n =2
x

(B) 2s 2. no radial node is present
(C) 2p 3. l =0
z

(D) 3p 4. l =1
y

5. are perpendicularly aligned




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2.
Column I Column II
(A)

CH
3
O



1. No geometrical isomer on treatment with NH
2
OH, H
+
(B)

=O

2. Racemisation on treatment with aqueous H
+
/OH

(C) CH
2
3. Michael addition with CH =CHCH=O
2
(COOEt)
2
, EtO

(D)

CH
3
O


4. Condensation with PhCHO, H O

5. Molecule shows resonance