States of Matter

/ I @ JEE Advancedl !IT-JEE 1

I t o- I 1
2. The temperature at'which a real gas obcys the ideal gas
:
latrs over a wide ranze of vressure is (1981 - I .\lark)
1. The total energy of one mole of an ideal monatomic gasat
27'C is .............. calories.
. .
(1984 - I Mark)
............... 2. :C-C,foranidealgasis: P. ( 1 9 8 4 - i ~ a r k )
3. The rate ofdiffusion ofgas is ............... p roportional to both
............... and square root of molecular niass.
(1986 - 1 Mark)
...... 4. The value of PVfor 5.6 lihes ofanideal gas is ....... :
RT,
at N.T.P. (1987- 1 Mark)
5. Eight gram each of oxygen and hydrogen at 27C will have
................ the total kinetic energy in the ratio of
(1989 ; 1 Mark)
. .......... 6. The absolute temperature of an ideal gas is : tolthan
. 'the average kinetic energy of the gas molecules.
(I 99 7C - I Mark)
1. Kinetic energy ofamolecule is zero at 0C. (1985- %Mark)
2. A gas in a closed container will exert much higher pressure
due to gravity at the bottom than at the top.
(1985 - % Mark)
3. In the van der Waals' equation [P+ $1 ( Y - = BRT
the constant 'a' reflects the actual volume of the gas
molecules. (1993 - 1 Mark)
4. A mixture of ideal gases is cooled upto liquid helium
temperature (4.22 K) to form an ideal solution.
(1 996 - 1 Mark)
I @- 0 0 11
1. Equal weights ofmethane and oxygen are mixed in an empty
container at 25C. The fraction ofthe total pressure exerted
by oxygen is (1981 - 1 Mark)
- 5
~. .
(a) Critical temperature (b) Boyle temperature
(c) Inversion temperature (d) Reduced temperature
3. The ratio of root mean square velocity to average velocity
of a gas moleculeat a particulartemperature is
. (1981- I Mark)
(a) 1.086 : 1 @] 1:1.086
(c) 2 : 1.0% (d) 1.086:2 . , .
4. Helium atom is two times heavier than a hydrogenmolecule.
At 298 K, the average kinetic energy of a helium atom is
(1982 - I Markj
(a) two times that of ahydrogen *olecule.
(b) same as that of a hydrogen molecule.
(c) four times that of a hydrogen molecule.
. .
(d) half that of a hydrogen molecule.
5 . 'Equal weights of methane and hydrogen are mixed in an
empty coitainer at 25C: The fraction ofthe total pressure
exerted by.hydrogen is : . , (1984 - 1 Mark)
6. Rate of diffus~on of a gas is : (1985 - I Mark)
(a) directly proportional to its densiiy.
(b) directly proportional to its molecular weight.
(c) ' directly proportional tothe square root of its lnolecular
weight.
(d) inversely proportional to the square root of its
molecular weight.
7. The average velocity of an ideal gas molecule at 27C is 0.3
mdsec. The averagevelocity at 927C will be: (1986-1 Mark)
(a) 0.6 mlsec @) ' 0.3 mdsec
(c) 0.9 mlsec (d) 3.0mlsec
8. 'In van der Waals equation of state for a non-ideal gas, the
term that accounts for intermolecular.forces is
(1988 - IMnrk)
( a) (v-b)' (b) RT
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. . c-74
Topic-wise Solved Papers CHEMISTRY
9. ' A bottle of dry ammonia and a bottle of dry hydrogen '17. The ratio between the root mean square speed of Hz at 50 K
chloride connected through a long tube are opened and that o f 0 2 at 800 K is, (1996 - 1 Mark)
simultaneously at both ends thewhite ammonium chloride
ring first formed will be (1988 - 1 Mark).
(a) 4 (b) 2
(c) 1 (d) 114 .
(a) at the centre of the tube.
18. X mL of H2 gas effuses through a hole in ;container in 5
(b) near the hydrogen chloride bottle.
seconds. The time taken for the effusion ofthe same volume
(c) near the ammonia bottle.
of the gas specified below under identical conditions is :
'
(d) throughout the length of the tube.
(1996 - 1 Mark)
10. The values of van der Waals constant 'a' for the gases 02, (a) 10 seconds : He @) 20 seconds : O2
N2, NH3 and CH,are 1.360,1.390,4.170 and 2.253 L2 atm
(c) 25 seconds : CO (d) 55 seconds : C02
mol-2 respectively. The gas which can mosteasilybe liquified -19. one mole of^ 0 ( at 300 K is kept in a closed container
is: (1989 - 1 Mark)
under one atmosphere. 2 4 g ) It is heated to 600K when 20% by
(a) o2 (b) N2
mass of N,O, (gj decomposes to N02(g).The resultant
(c) NH3 (dl cH4 pressure is : . . (1 996 - 1 Mark)
11. The density of neon will be highest at (1990 - I Mark) (a) 1.2atm
.
(b) 2.4 atm
(a) S.T.P. (b) 0C,2atm . (c) . 2.Oatm (d) 1.0 atm
(c) 273"C, 1 abn. (d) 273OC, 2 am. 20. The compressibility factor for an ideal gas is
12. The rate of diffusion of methane at @en temperature is (1997- 1 Mark)
twice that of a gas X. The molecular weight of xi s (a) 1.5 (b) 1.0
(1990 - 1 Mark)
(a) 64.0 @) 32.0
(c) 4.0 (d) 8.0
13. Accordingto kinetic theory of gases, for a diatomic molecule
(1991 - 1 Mark)
(a) the pressure exerted by the gas is proportional to mean
velocity of the molecule
(b) the pressure exerted by the gas is proportional to the
root mean velocity of the molecule
(c) the root mean square velocity of the molecule is
inversely proportional to the'temperature
(d) the mean translational kinetic energy ofthe molecule is
proportional to the absolute temperature.
.- 14. At constant volume, for a fixednumber of moles of a gas the
pressure ofthe gas increases with rise in temperature due to
(1992 - 1 Mark)
(a) Increase in average molecular speed
(b) Increased rate of collisions amongst molecules
(c) Increase in molecular attraction
(d) Decrease in mean free path
15. Longest mean free path stands for : . (1995s)
(a) 3 (b) N2
fc) o2 (d) C12
16. -Arrange the van der Waals constant for the gases :
(1995s)
I G6Hqg) A. 0.217 ' .
" 6 ~ s . ~ ~ 3 , B; 5.464
C 18.000
Hz0@ D. 24.060
,~ (a) I-A, II-D, III-C, N-B (b) I-D, II-A, 111-B, N-C
(c) I-C, II-D, III-A, N-B (d) I-B, II-C, III-A, N-D
. .
. .
. .
(c) 2.0 (d) 03
21.. A gas will approach ideal behaviour at (1999 - 2 Marks)-
(a) low temperature and low pressure.
@) low temperature and high
(c) - high temperature and low pressure.
(d) high temperature a?d high pressure.
22. h he rms velocity of hydrogen is J? times the rms velocity
of nitrogen. If T is the temperature of the gas, then
(2000s)
(4 7(Hz)=T(N2) (b) T(3)' T(N2)
(c) T(3)'T(N2) (d) T( H~) =J? T(N2)
23. The compres'sibility of a gas is less than unity at STP.
Therefore,. (2000s)
(a) V, >22.4'litres @) V,,, <22.4 Iitres
(c) . V,=22.41itres (d) c, =44.8 Iitres
24. At 100C and 1 atm, ifthe density ofliquid water is 1.0 g c ~n- ~.
and that of water vapour is 0.0006 g ~ r n - ~ , then the volume
occupied b j water molecules in 1 litre of 'steam at that
temperature is (2000s)
(a) 6cm3 (b) 60cm3 ,
(c) 0.6 cm3 (d) 0.06cm3
25. . The root mean square velocity ofan ideal gas at constant
pressure varies with density(d) as (2001s)
(a) . d 2 @ ) d . .
( 4 J;i ( 4
26. Which ofthe following volume (V) -temperature (T) plots
represents the behaviour of one mole of an ideal gas at one
atmospheric pressure ? (2002s)
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STATES OFMATTER C-75
. . 32. A mono-atomic ideal gas undergoes a process in which the
(38.8L, 373K)
ratio of P t o Vat any instant is constant and equals to I.
What is the molar heat capacity of the gas
273K)
3R
(a) @) 2 R (2006-3M; -I)
5R
(28.6L, 373K) (c) 0
an
2
(a) nb . ,- @) (2009- 3 ~ ; - 1 )
30.6L, 373K) V
. .
2 '
an
(4 -7 (d) -nb
~ T ( K ) ~ - - , ' .
34. For one mole of a van der Waal's gas when b = 0. and
v'"?
T = 300 K, the PV vs, I N plot is shown below. The value of
the van der Waal's constant a (atim. lite? m ~ l - ~ ) is :
27. When the temperature is increased, surface tension of water ,-.. 23.1 4 ..+. ..
(200224
(a) increases 6
(b) decreases
(c) remains constant a
z-
(d) shows irregular behaviour , ' +
.-
28. Positive deviation from ideal behaviour takes place because - -
of (2003s) +
(a) Molecular interaction betweenatoms and PV/nRT> 1
. (b) Molecular interaction between atoms and PVInRT< I .
A . -L
(c) Finite size of atoms and PVlnRT> 1 ,
(d) Finite size of atoms and PVInRT< 1 0' ~
29. The root mean square velocitvofone mole of a monoatomic
. ~
gas having molar mass Mi; U,,,,,. The relation between
thbaverage kineticeriergy (E) of the gas and U,,,is
(a) 1.0
(c) 4.5
12004s)
(h) 1.5 (d) 3.0
30. The ratio of the rate of diffusion of helium and methane
under identical condition of pressure and temperature will
be (2005s)
(a) 4 (b) 2
(c) 1 (d) 0.5
31. When one mole of monoatomic ideal gas at T.K undergoes
adiabatic change under a constant external pressure of 1
atm volume changes from 1 litre to 2 litre. The final
temperature in Kelvin would be
(2005s)
T
(b) T+ ;x0.0821
(a) 2(2/3)
(c) T
2
(d) T- -x0.0821
3
1. When an ideal gas undergoes unrestrained,expansion, no
cooling occurs because the molecules : (1984 - 1 Mark)
(a) are above the inversion temperature
(b) . exert no attractive forces on each other
(c) do work equal to loss in kinetic energy
(d) collide without loss of energy
2. If a gas is expanded at constant temperature :
(a) the pressure decreases (1986 - I Mark)
(b) ' the kinetic energy of the molecules remains the same
(c) the kinetic energy of the molecules decreases
(d) the number of molecules of the gas increases
3. Equal weights of ethane and hydrogen are mixed in an empty
container at 25C. The fraction ofthe total exerted
by hydrogen is (1993 - 1 Mark)
(a) I : 2 @) 1 : l
(c) 1: 16. (d) 15:16
1
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4. ~ c c d r d i n ~ to Graham's law, at agiven temperature the ratio
of the rates of diffusion rA/rB of gases A and B is given by
(1998 - 2 Marks)
(a) (MAmB)'" (b) ( MA/ M~) (PA/PB)I'~
(c) (pA/pd ( ~ ~ m ~ ) ' " . . id) (M*IMB) (PBPA)IR
(Where P and M are pressures and molecular weights of
gases A and B respectively.)
5. Refer to the figure given : .(2006 - 5M; -1)
Which of the following statements is wrong?
g=.c
,
. ....
,,...... gas A
,,.!... "'
.... "" :
,( ..... .' .
,,,,,,... .. , ;
...
... ideal gas
(a) For gas A, a = 0 and Zw-~tl linkarly depend on pressure
. .
(b) For gas B;b 1. 0 and Z will linearly depend on pressure.
(c) Gas C is a real gas and we can find 'a' and.'b7 if.
intersection data is given
(d) All van der Waal gases will behave like gas C and give
positive-slope at-nigh pressure.
6 .
A gas described by van der Waals equation - '
.
(2008-1Mnrk)
(a) behave similar to an ideal gas in the limit of large inolar
volumes. .
(b) behaves similar to an ideal' gas is in limit of Large
pressures
(c) is char'acterised by van der Waals coefficients that are
dependent on the identity of t he gas but are
independent of the temperature.
(d) has the pressure that is lower than the pressure exeked
by the same gas behaving ideally
7. ~c c or di i g to kinetic theory of gases (2011)
(a) collisions are always elastic
Cb) heavier molecules transfer more momentum to the wall
of the container
(c) only a small number of molecules have very high
velocity --
(d) between collisions, the molecules move in straight lines
. ~
with constant velocities
1.
Calculate density ofNH; at 30C and 5 ahn pressure. (1978)
2. 3.7 g of agas at 25C occupied the same volume as 0.184g of
hydrogen at 17'C and at the same pressure. What is the
- molecular weight of the gas? (1979)
Topic-wise Solved Papers - CHEMISTRY
3. A straight giass tube has two inlets Xand Yat two ends. The
length of tube is 200'cm. HCI gas through inlets Xand NH,
gas through inlet Yare allowed to enter the tube at thesame
time. What times appear at point P inside the tube. Find
distance of P from X. (2980)
4. 1 litre of mixture of CO and C02i s tiken.'The mixture is
passed through a tube containingred hot charcoal. The '
volume now becomes 1.6 litre. The volumes are measured
under the same conditions. Find the composition of mixture
by volume. (1980)
5. The pressure ih a bulb dropped from 2000 to 1500 mm of
mercury in 47 minutes when the contained oxygen leaked
through a small hole. The bulb was then evacuated. Amixture
. . of oxygen and another gas'of molecular weight 79 in the
molarrh* of 1 : 1 at a total pressure of4000 mm ofmercury
was i nt r odZ~ed~l ~i nd the molar ratio of the two gases
remaining in the bulb after a period of 74 minutes.
(1981 - 3 Marks)
6. ~ t r o o m temperature, ammonia gas at 1 atm pressure and
hydrogen chloride gas at P ahn pressure are allowed to effuse
through identical pin holes from opposite ends of a glafs
tube of one metre length and of uniform cross-section.
Ammonium chloride is first formed at adistance of 60 cm
&om the end through which'HC1 gas is 'sent in. What is the
value of P? (1 982 - 4 Marks)
7. Calculate the average of kinetic energy, in Joules of the
molecules in 8.0 g of methane at 27C. (1982 - 2 Marks)
8. Oxygen is present in 1 litre flask at apressure of 7.6 x 10-lo
mm ofHg. Calculate the number of oxygen molecules in the
, flaskat 0C. (1983 - 2 Marks)
9. When 2 grn of a gas A is introducedinto an evaluated flask'
kept at 25"C, the pressure is found to be one abnosphere. If
3 gm of another gas B is then added to the same flask, the
total pressure becomes 1.5 atm. Assuming ideal gas
behaviour, calculate the ratio of the molecular weights
MA : M; (1983 - 2 Marks)
10. 'Equal volumes ofgases contain equal number of atoms', is
true at what conditions. . ' - (1984- I Mark)
11. Calculate the root mean square velocity of ozone kept in a
closed vessel at 20C and 82 cm mercury pressure.
(1985 - 2 Marks)
12. A spherical balloon of21 cm diameter is to be filled up with
hydrogen at N.T.P. fiom a cylinder containing the gas at 20
atmospheres at 27C. If the cylinder.cadhcild 2.82 litres of
water, calculate the number ofballoons that can be filled up. .
(1987- 5 Marks)
13. The average velocity at TIK, and the mostprobable velocity
at T,K&~ C O ~ gas is 9.0 x 1 O4 cm sec-l: Calculate the value
of TI and T,. .
.
(I990 - 4 Marks)
14. Calculate the volume occupied by 5.0 g of acetylene gas at
50C and 740 mm pressure. (1991 - 2 Marks)
15. At 27'C, hydrogen is leaked through a tiny hole intoa vessel
for 20 minutes. Another unknown gas at;the same
temperature and pressure as that of HZ is leaked through
- ~ , .
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STATES OFMATTER
the same hole for20 minutes.~fter the effusion ofthe gases
themixture exerts apressure of 6 atmosphere. The hydrogen
.content of the mixture is 0.7 mole. I f the volume of the
container is 3 litrea, what is the moiecular weight of the
unknown gas? - (1992 - 3 Marks)
16. At room temperature the followingreactionsproceed~nearly
to completion :
. .
(1992 - 4 Murks)
2N0 + 0, + 2NO,+ N,O,
The dimer, N204, solidifies at 262 K.A250 ml flask and a 100
. .
inl. flask are separated by a stop-cock. At 300 K, the nitric
oxide in the larger flask exertsa pressure of 1.053 atm. and
the smallerone contains oxygen at 0.789 atm. The gases are
mixed by opening the stopcock and after the end of the
reaction the flasks are cooled at 220K. Neglecting the vapour
pressure of the dimer, find out the pressure and composition
ofthe gas remaining at 220 K. (Assume the gases to behave
ideally). . . ~ .
17. A gas bulb of 1 litre capacit); contains 2.0 x 102' molecules
ofnitrogen exerting apressure of7.57 x lo3 Nm-l. Calculate
the root mean square (r.m.s) speed andthe temperature of .
the gas molecules. Ifthe ratio ofthe most probable speed to
the root mean square speed is 0.82, calculate the most ,
probable speed for these molecules at this temperature.
(1 993 - 4 Marks)
18. A 4: 1 molar mixture of He and cH4 is contained in a vessel
at 20 bar pressure . Due to a hole in the vessel, the gas
mixture leaks out. What is the composition. of the mixture
effusing out initially? (I994 - 2 Murks)
. .
19. An LPG (liquefied petroleum gas)cylinder weighs 14.8 kg
when empty..When full, it weighs 29.0 kgand shows a
.
pressure of2.5 atm. In the course of use at 27" C, the weight
ofthe full cylinder reduces to 23.2 kg. Find out the volume
of the gas in cubic meters used up at the normal usage
conditions, find the final pressure insidi the cylinder.
Assume LPG to be n-butane with normal boiling point of
0C. (1 994 - 3 Marks)
20. A mixture of ethane (C2H6) and ethene (C2H4) occupies 40
litres at 1.00atm and at400 K. Themixture reacts completely
with- 130 g of O2 to produce C02 and H 2 0 Assuming ideal
gas behaviour, calculate the mole kactions of C2H4 and C2Hi
in the mixture. (1995 - 4 Marks)
21. Thecomposition oftheequilibriummixture ( CI2 +. 2CI ),
which is attained at 1200C, is determined by measuringthe
rate of effusion through apin-hole. It is observed that at
1 .SO mmHg'pressure, the mixture effuses 1.1 6 times as faSt
a s krypton.effuses under the same Londitions. calculate
the fraction of the chlorine molecules dissociated into atoms.
(Relative atomic mass of Kr = 84.) (1995 - 4 Marks)
22; A 20.0 cm3 mixture O~CO, CH,, and ~k gases is exploded by
an electric discharge a t room temperature with excess of
oxygen. Thevolume contraction is found to be 13.0 cm3. A
further contraction of 14.0 cm3 occurs when the residual
gas is treated with KOH solution. Find out the composition
of the gaseous mixture in terms of volume percentage.
. (1995- 4 Marks)
, C-77
23. One litre of a mixture of 0, a$~, - at NTP' ;~~ ailowed to
rkict with an excess of acidified solution of KI. The iodine
liberated required 40 ml of MI10 sodium thiosulphate
solution for titration. What is the weight percent of ozone in
the mixture? Ultraviolet radiation of wavelength 300 nm can
decompose ozone. Assuming that one photon can
decoinpose one ozone molecule, how many photons would
have been required for the complete decompositionof ozone
in the original mixture? (I997C - 5 Marks)
24. . One way of writingthe equation of state for real gases is.
where B is a constant. Derive roximate expression for
B in terms of the Vrin der
(1997C - 2 Marks)
25. Anevacuated glass vessel weighs 50.0 g when empty, 148.0
g when filled with a liquidofdensity0.98 . gm~-' and555 g
when filled with an ideal gas at 760 mmHg at 300K. Determine
the molar mass of the gas. (1998 - 3 Marks)
26.. The degree ofdissociation is 0.4 at400 K and 1.0 atm for the
gaseous reaction PC15 PCI, + CI Assuming ideal
?
behaviour of all gases, calculate the density of equilibrium
mixture at 4OOK and 1.0 atmosphere. (Relativeatomic mass
,
of P=31.0andC1=35.5) (1998 - 3 Marks) ,
27. Using vander waal's equation, calculate the constant, 'a'
when twomoles of a gas confined in a four litre flask exerts
a pressure of 11.0 atmospheres at a temperature of 300 K.
The value of"b' is 0.05 Lmol-I. (1 998 : 4, Marks)
28. For the reaction, N205(g) = 2N02(g) + 0.5 O,(g), calculate
the mole fraction of N20,(g) decomposed at a constant
volume and temperature, ifthe initial pressure is 600 mm Hg
and the pressure at any time is 960 mm Hg. Assume ideal
gas behaviouc
(1998 - 3 Marks)
29. One mole .of nitrogen gas at 0.8 atm takes 38 s to diffuse
through a pinhole, whereas one mole of an unknown
comp&nd of xenon with flourine at 1.6 atm takes 57 s to
~ -
diffuse through the same hole. Calculate the molecular
f ohul a of the compound. (1999- 5 Marks) .
30. ?he pressure exerted by 12 g of an ideal gas at temperature
roc in avessel of volume V litre is one atm. When the
temperature is increased by 10 degrees at the same volume;
the pressure increases by 10%. calculate the temperature t
.
and,volumeV; (Molecular weight ofthe gas= 120.)
(1999'- 5 Marks)
31. Calculate the pressure exerted by one mole of C02 gas at
273 K if the van der Waal's constant a = 3:592 dm6 atm
mol-,. Assume that the volume occupied by CO, molecules
isnegligible. (2000 - 2 Marks)
32. he compressio" fadtor(comfiessibility factor) for one mole. .~
of a van der Waals gas at 0C and 100 atmospheric pressure
i s found to be 0.5. Assuming that the volume of a gas
molecule is negligible, calculate the van der Waals constant
a. (2001 - 5 Marks)
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C-78 Topic-wise Solved Papers - CHEMISTRY
33. The density ofthe vapour of a substanceat 1 atm pressure
and 500 K is 0.36 kg ma. The vapour effuses through a
small hole at a rate of 1.33 times faster than oxygen under
the same condition. (2002 - 5 Marks)
(a) Determine
(i) molecular weight, 34.
(ii) molar volume,
35.
(iii) compression factor (2) of the vapour and
(iv) which forces among the gas molecules are
dominating, the attractive or the repulsive?
@) Ifthe vapour behaves ideally i t 1000 K, determine the
average translational kinetic energy of a molecule.
The average velocity of gas molecules is 400 mlsec. Calculate
its rms velocity at the same temperature. (2003 - 2 Marks)
A graph is plotted between PVm along Y-axis and P along
-X-axis, where Vm is the molar volume of a real gas. Find the
intercept along Y-axis. (2004 - 2 Marks)
Each question contains statements given in two columns, which havefo be matched The statements in Column-I are labelled A.
B, C and D, while the statements in Column-I1 are labelledp, q, s and t Any given statement in Column-I can have correct
matching with ONE OR MORE sfate&ent(s) in column-11. he appropriate b~bblescorresponding.to the bnswers to these
questions have to be darkened as illustrated in the following example :
Uthe correct matches are A-p, s and I; B-q andr; C-p and q; andD-s then the correct darkening ofbubbles will look like the given.
~ q r s t
,
1. Match gases under specified conditions listed in Column I with their propertiesllaws in Column 11. Indicate your answer by
darkening the appropriate bubbles of the 4 x 4 matrix given in the ORS. .
(2007)
-Column1 . . ~ol umrt II
(A) hydrogen gas (P =ZOO atm, T= 273 K) @) compressibility factor +I
@) hydrogen gas ( P- 0, T= 273 K) (q) attfactive forces are dominant
(C) C02( P= 1 am, T=273 K) (r) PV=nRT
. .
. .
@) real gas with very large molar volume
. ,
(s) P(V-nb) =nRT
Reason : Frequency of collisions and their impact both
11 increase in proportion to [he square roof of temperature.
1. Read the following statement and explanation and answer
as per the options given below :
Assertion : The value ofvan der Waals'constant 'a'is larger
for ammonia than for nitrogen.
Reason : Hydrogen bonding is in ammonia.
(1998 - 2 Marks)
(a) lfboth assertion and reason are correct, and reason is
the correct explanation ofthe assertion.
@) - If both assertion and reason are correct;but reason is
not the correct explanation of the assertion. .
.
(c) If assertion is co,rrect but reason is incorrect.
(d) If assertion is incorrect but reason is correct.
2. Read the folloying statement and explanation and answer
as per the options given below .:
Assertion : The pressure ofafixed amount of an ideal gas is
' -proportional to its temperature
(a)
If both assertion and reason are CORRECT, and reason is
the CORRECT explanation ofthe assertion.
@) If both assertion and reason are CORRECT, but reason
is NOT the CORRECT explanation of the assertion.
(c) If assertion is CORRECT, but reason is INCORRECT.
(d) If assertion is INCORRECT, but reason is CORRECT.
1. At 400 K, the root mean square (rms) speed of a gas X
(molecular weight = 40) is equal to the most probable speed
of gas Y at 60 K. The molecular weight ofthe gas Y is (2009)
2. To an evacuated vessel with movable piston under external
pressure of 1 a m, 0.1 mol ofHe and 1.0 mol ofan u wo wn
compound (vapourpressure 0.68 aim. at OC) are introduced.
Considering the ideal gas behaviour, the total volume (in
'
litre) ofthe gases atOC is close to (2011)
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STATES OF MA'ITER C-79
1. For an ideal gas, number of moles per, litre in terms of its
pressure P, gas constant R and temperatureT is
(a) PT/R (b) PRT [2002]
- (c) P/RT (d) RT/E
2 . Value of gas constant R is [ZOO21
(a) 0.082litreak ' @) 0. 987 calmol-I K3I
(c) 8.3 J mol-I K-' (d) 83 erg mol-I K-I.
3. Kinetic theory of gases proves [2002l
(a) only Boyle's law ,
(b) onlycharles' law
(c) only Avogadro's law
(d) all of these.
4.
According to the kinetic theory of gases, in an ideal gas,
between two successive collisions a gas molecule travels
(a) in a wavy path [ZOO31
(b) in a shaight line path
(c) with an accelerated velocity
(d) in a circular path
8. If dm3 of water is introduced into a 1.0 dm3 flask at
300 K, how many moles of water are in the vapour phase
when equilibrium is established ?
[20101
(Given : Vapour pressure of H20 at 300 K is 3170 Pa;
' R= 813 14 J K-I mol-I)
(a), 5 . 5 6 ~ 10-~mol (b) 1.53 x 10-~mol
(c) 4.46 x 10-~mol (d) 1 . 2 7 ~ 1 0 ~ mo l
9. 'a' and !b' are van'der Waals' constants foPgases:Chlorine
is more easily liquefied than ethane because
(a) a and b for C12 > a and b for C2H6
(b) a and b,for C12 < a and b for CiH6
(c) a for CI2 < a for C2H6 but b for C12 > b for C2H6
(d) a for Clz > a for C2Hg but b for C12 < b for C2H6
10. When r, P and Mrepresent rate of diffusion, pressure and
molecular mass, respectively, then the ratio of the rates of
diffusion (rA irB) of two gases A and B, is given as :
. (a) (PA 1 P')(MB 1 1 ~ ~ ) ~ ~ ~
5; As the temperature is raised froin 20C to 40'12, the average
kinetic energy of neon atoms changes by a factor. of which
(b) (PA ~ p n ) ' I ~ ( ~ n / MA)
. .
of the following? [2004] (c) (pA I &)(MA I MB) " ~
6. In van der Waals equation ofstate ofthe gas law, the constant
'b' is a measure of
120041
(a) volume occupied by the molecules
, .
(b) intermolecular attraction
(c) intermolecular repulsions
(d) intermolecular collisions per unit volume
7.
Which one of the following statements is NOT true about
the effectof an increase in temperature on the distribution
of molecular speeds in a gas? [2005]
(a) The areaunder the distribution curve rimains the same
asunder the lower temperature
(b) he distribution becomes broader
(c) The fraction of the molecules with the most probable
speed increases
(d) The most probable speed increases..
11. The molecular velocity of any gas is : [2011RS]
(a) inversely proportional to absolute temperature.
(b) directly proportional to square of te~nperature.
(c) directly proportional to square root of temperature.
(d) inversely proportional t o the square root of
temperature.
12. The compressibility factor for a real gas at high pressure is :
pb
(c) 1 + -
RT.
13. For gaseous state, ifmost probable speed is denoted by C*,
average speed by and mean square speed by C, then for
a large number of molecules the ratios of these speeds are :
[JEEM 20131
(a) C*:ciC=1. 225:1.!28:1
(b) 'C*: c : C=l . l 28: 1.225:l
(c) C*: C : C=1 : 1.128: 1.225
(d) C*: c :C=1:1.225: 1.128
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