Answer

AITS-FT-IV-PCM (Sol)-JEE (Mai n)/14
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1

ANSWERS, HINTS & SOLUTIONS

FULL TEST IV
(Main)

S. No. PHYSICS CHEMISTRY MATHEMATICS
1. C A A
2. D C B
3. C B A
4. A C A
5. D D B
6. A D C
7. A D C
8. A D B
9. C D B
10. B D C
11. A A C
12. C A B
13. C C B
14. D C A
15. C B B
16. C A D
17. D D A
18. C C B
19. A D A
20. C C D
21. C D D
22. B D A
23. C C C
24. D D B
25. D A A
26. C C D
27. B D A
28. C C D
29. C A D
30. C D C
A
L
L

I
N
D
I
A

T
E
S
T

S
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I
E
S

FI I TJEE JEE(Main), 2014
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(
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2
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1
3

2

P P h hy ys si i c cs s PART I

SECTION A

1. Zero after decimal point is also significant.

2.
2 2 2 2 2
1
a v t v t + =

2 2
1
a
t
v v
=

A
B
a
vt
v
1
t
C

3. 600 T =ma

min
600 360
a 4
60
= = m/s
2

4.
0
0 0
mv
mgt mv
2
=

0
0
v
2gt
=

5. Friction force on upper block is f =ma
So work done =ma s

7. mu =m(v/2) +mv
v =(2/3)u

u 2u
3 3
e
u
=
e =1/3

8.
2
2
2 R
T
GM
R
t
=

2
3 2
2
GM 4
R T
t
=

2 3
2
2 2 2
1 1
4 R GM
g
R T R
t
= =

9.
dv
m 6 rv
dt
| |
= tq
|
\ .

0.5 t
2 0
dv 1
6 dt
v 18
| |
= t
|
t
\ .
} }

2 t
n
0.5 3
= t =3n4 sec

3
12.
eff
T 2
g
= t

where g
eff
=
mg qE qE
g
m m
=

13. Maximum will be corresponding to source position A
and minimum to source friction B.
So, time interval =
1
3
2cos
2 5
5
| |
|
u
\ .
=
e

C
u
u
A
B
O

18.
P pindued Pq 0
V V V V = + =

pinduced
1
kq kq
V
r r
=

O
u
R
r
P
O
r
1

20.
2
i
16
v CV
25
= (i)

i
6
q CV
5
= .(ii)

f
11
q CV
5
= (iii)

2 2
f
16 1
U CV CV
25 2
| |
= +
|
\ .

Charge flown from battery =CV
Work done =CV
2

Heat produced AH =AU +AW

2 2 2 2 2
16 1 16 1
CV CV CV CV CV
25 2 25 2
( | |
= + =
| (
\ .

21. As A and B will be at same potential so
charge flown equal to Q.

A
Q
r
R
B

22.
2 2 0 0 0 0
A B
2 I I
B B B
2 a
2 a 2

= + = =
t
t

23. Using
( )
e B d v =
}

So, e =BvR

45
P
v
O
R\2

24.
/2
/2
e B(x )dx 0
+
= e =
}

4
25.
2
2
0
1 2
1 q 1
LI
2(C C ) 2
=
+

( )
1 2 0
q L C C I = +

( )
1 1 10
1 2 1 2
q L
q C C I
C C C C
= =
+ +

27.
coherent
incoherent
I 4I
2
I 2I
= =

29. Using Einstein equation
E =W +eV

o
o
4
12400 evA
0.2 10 A
=4.6 eV +eV
V =1.6 Volts

5
C Ch he em mi i s st tr r y y PART II

SECTION A

1. For H, | |
H 3 2
0.529
r r r 9 4
1
A = =
For | | 2
2
3 2
Li
0.529
Li , r r r 9 4
3
+
+
A = =

2
H
Li
r 3
r 1
+
A
=
A

2.
2 2 2 2
2Cu S 3O 2Cu O 2SO + +

2 2
Cu O FeS FeO Cu S + +

2 2
2FeS 3O 2FeO 2SO + +
( )
2 3
FeO SiO FeSiO Slag +

4. This is a 3
o
and resonance stabilized carbocation.

5. Cumulated diene is least stable, evolve max heat in the hydrogenation reaction.

11. Number of revolution made by an electron per sec

2
n
2 2
n
2
v 2 Ze
2 r n h
nh 2
4 mZe
| |
|
t
|
= ~
|
t | |
t |
|
|
t
\ . \ .

2 2 4 2 4 2
3 3 3 3
4 mZ e 4 me Z
n h h n
| | t t
= ~
|
\ .

2
15 15
3
Z 1
6.66 10 6.66 10
8 n
= ~
=8.3 10
14

13. Vapour pressure depends on temperature not on size of container.

14. There is no intermolecular forces of attraction in ideal gases.

16. 3A B 2C +

| | | | | |
| || |
d A d B d C
1 1
r K A B
3 dt dt 2 dt
' = = = =

| |
| || | | || |
d A
3K A B K A B
dt
' = =
i.e. K 3K' =
So that
| |
| || |
d C
2K A B
dt
' = = | || |
2
K A B
3

17.
2
P CO
K P , = which will depends temperature of the system only.

6

18. Water will be neutral as [H
+
] =[OH
-
]

20. Zinc is more electropositive than silver therefore, it displaces less electropositive silver.

21. Carnalite is a double salt KCl.MgCl
2
.6H
2
O which give test of K
+
, Mg
+2
and Cl
.

22. ( )
2
2
2Cu 2CN 2Cu CN
+ +
+ +
( )
3KCN
3
4
Cu CN CuCN K Cu CN
+
( +

23. Mass number change only by o-particles and atomic number reduces by 2 unit by each o-particle
and increase by 1 unit by |-particle.

27.
Galactose unit
Glucose unit
O OH
H
H
CH
2
OH
H
OH
OH
H
O
H
O
OH
CH
2
OH
H
OH
OH
H
H
OH
H

28. The 1
st
step is electrophilic addition i.e. rate determining step, more stable will be the intermediate
better will be the rate of reactions.

29.
O
CH
2
C
O
OEt
,dry HCl
LAH/ THF
O O
CH
2
C
O
OEt
O O
CH
2
CH
2
OH EtOH +
2
H
H O
+
CH
2
CH
2
OH
O
CH
2
OH
CH
2
OH

7
M Ma at th he em ma at ti i c cs s PART III

SECTION A

1.
( ) ( )
( ) ( )
x
HHH , RR , I,I , P,P ,AYU
=
( )
12
7
7!
C 1 198 7!
2!2!
=

2.
( ) ( )
2
a b a b a b + = |a +b| =|a b|

a a
1 1
b b
+ =

a
b
is perpendicular bisector of (1, 0) and (1, 0)

a
b
is purely imaginary

3.
( )
( )
dV t
K T t
dt
=

( )
( )
2
K T t
V t C
2
= +
At t =0, V =I
2
KT
C I
2
=
Scrap value V(T) V(t =T) =C =
2
KT
I
2

4.
( ) ( )
2
2
1 1
3
2 tan x tan x 0
8

t
t =

( )
1
tan x
4
t
=
x =1

5.
( )
( )
2
t
2
2 2
t 2
lim 1
1 1 1 1
t 2 1 2 1
t t t t

=
| |
+ +
|
\ .

Now ||x 1| 6| =k has four distinct solutions if k e (0, 6)
Number of integral values of k is 5

6.
( )
x x
f x
2
=

7. CaseI: when
p 2
2
2
s p s 6 and f(2) =8
P =2
CaseII: when
p 2
2
2
> p >6

8

D
8
4a
=
( ) ( )
2
p 2 4 3p 2
8
4

=
P =8 2 5 +
p 8 2 5 = + and p 8 2 5 = (rejected)
Sum of values of p is 2 8 2 5 10 2 5 10 20 + + = + = +
m +n =30

8. We have (x y)
2
+(y 3)
2
=0
x =y =3

9. We have f(x) >f(2) x <2

( ) ( )
x 2
lim f x f 2 1
> =
a
2
9a 9 > 1
a
2
9a 10 > 0
a s 1 or a > 10
But a is positive. Hence a > 10. That is a e [10, [
Note that when a =10

( )
3 x, x 2
f x
2x 3, x 2
<
=

>

So that f is continuous at 2, f'(2) does not exist and f'(x) = 0 x e R. Therefore, x =2 is a critical
point and f'(x) changes sign from negative to positive at x =2

10. We have
1
a b
1
a
a
= +
+

( )
1
a b
1
a
a
=
+
and
1
b a
1
b
b
=
+

1
a b
1
b
b
=
+

1 1
a b
a b
+ = + (ab 1)(a b) =0
ab =1 a = b

( )
1
a b
a b
=
+
a
2
b
2
=1

11. Probability that calculator of brand r is selected and is defective
=
( ) ( )
6 6
2
1 r 1
7 r k 8k
kr 7r r
21 21 3
=
| |
= =
|
\ .

.. (1)
Let E
r
denote the event that calculator of brand r is selected P(E
r
) =kr
Since E
r
(r = 1, 2, .., 6) are mutually exclusive and exhaustive events we must have
( )
6
r
r 1
P E 1
=
=

6
r 1
kr 1
=
=

1
k
21
=
required probability =
8k 8 p
3 63 q
= =
(p +q) =71

9

12. P(r) =(2r +1)
2

( ) ( )
n 1 n 1
2
r 1 r 1
P r 2r 1 n 1

= =
= + =

2
3 2
n
1 n 1
lim
2
an bn c

=
+ +

a =0, b =2
So, (a +b) =2

13. Let tan
1
x =o and tan
1
y =| then a tan o +b sec o =c and a tan | +b sec | =c
Obviously a tan u +b sec u =c has roots tan o and tan |
(a
2
b
2
) tan
2
u 2 ac tan u +c
2
b
2
=0

2 2
2ac
tan tan
a b
o + | =
and
2 2
2 2
c b
tan tan
a b
o | =

So
2 2
x y 2ac
1 xy a b
+
=

14.
( )
( )
( )
x x 2
2
2 2
x o
5 1 1
lim e e ln5
2x x 2 tanx 2
2 x
+
| |
|
\ .

( ) ( ) ( )( )
2 x
2 x 2
2
x o
2
2
e 5 1 e 1 e
lim e ln 5 ln5
2sinx 1 cosx 2
x x
x
x

= =
| |
|
\ .

=1

15.
2 2
2 3
1 3tan 1 cot1 1 3tan 1 1
cot3 cot3 3 tan 1 3tan1 tan 1
| | | |

= | |
\ . \ .
=
1
1
tan3cot3
=

16.
( )
1/ x
2
x 0
1 sin2x
lim e
1
+
=

17. f(x) =x
2
+3x 2

( )
3 2
x 3x
f x dx 2x c
3 2
= + +
}

18. f(x) =(x 1)
4
(x 2)
3
(x 3)
2
(x 4)

( ) ( ) ( )
f 1 f 2 f ' 3 0 ''' '' = = =

( ) ( ) ( ) ( ) ( ) ( ) ( )( )
4 3 4 3 2
f' x x 1 x 2 x 3 1 x 1 x 2 2 x 3 x 4 = +

( ) ( ) ( ) ( ) ( ) ( ) ( ) ( )
4 2 3 3 2 2
x 1 3 x 2 x 3 x 4 4 x 1 x 2 x 3 x 4 + +
f'(4) =3(6
3
)

19. a +ar =12 .. (1)
ar
2
+ar
3
=48 .. (2)
r
2
=4 r =2, r = 1, 2

10
20.
3k 2 5k 3 6k 4
P , ,
k 1 k 1 k 1
+ + + | |
|
\ + + + .

Hence
3k 2 13
k 1 5
+
=
+

3
k
2
=

21.
2 2
2 2
2 2
1 2a a 1 p p
1 2b b 1 q q
1 2c c 1 r r
A = =2 2A
1
2A
2
=8A
1
A
2
=
1
8 4 16
2
=

22. (a +b)x +(2b 2a)y +(3b 3a) =0
a +b =0
a
b
=

3
y
2
=

23.
2 2
x y 1 x y 3
2 2
1
10 5/2
+ + | | | |
| |
\ . \ .
+ =
Here a
2
=10 and b
2
=5/2 and centre is (1, 2)
Locus of feet of perpendicular lie on auxiliary circle of ellipse
Equation of circle is (x 1)
2
+(y 2)
2
=10

24.
( )
4; 0 x
2
2 x
2
f x
3n
0; x
2
3
2 x 2
2
t
< <
< < t
t < <
< < t

Range of function ={0, 2, 4}

25.
2
a
1
1 cos
b c
tan
a 2 1 cos
1
b c
| |
|
u u | |
+
= = | |
\ . + u
|
+
|
+ \ .

=
b c a a b c
1
a b c a b c
+ + + | |
= =
|
+ + + + \ .

26. 3
4
=81

27. We have, cos
2
x (c 1)cos x +2c 6 > 0 x e R
(cos x 2)(cos x (c 3)) > 0
cos x s c 3
c 3 > 1 c > 4

11
28. px
2
+qx +r =0
rx
2
+qx +p =0 (on subtract)
x =1
So common root is 1
p q +r =0

29. [{x}] =0

( ) ( )
1
7
7
f x 3 x =

( ) ( ) ( )
( )
1
7
7
1
7
7
f f x 3 3 x x
| |
|
= =
\ .

f(f(x)) =x f
1
(x) =f(x)
f
1
(50) =f(50) and f(f(100)) =100
f
1
(50) f(50) +f(f(100)) =100

30. Put a =2R sin A, b =2R sin B
2R sin B (sin
2
A +cos
2
A) = 2a
2R sin B = 2a

b
2
a
| |
=
|
\ .

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AITS-FT-IV-PCM (Sol)-JEE (Mai n)/14

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