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IN Resonance Educating for better tomorrow JEE (MAIN)-2014 rr) Preece eee) 10. 1. 12. 13. IMPORTANT INSTRUCTIONS Immediately fll the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen. Use of pencil is strictly prohibited, ‘The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take ut the Answer Sheet and fil in the particulars carefully. The test s of 3 hours duration, The Test Booklet consists of 90 questions, The maximum marks are 360. There are three parts in the question paper A, B, C consisting of Physics, Chemistry and Mathematics having 30 questions in each part of equal weightage. Each question is allotted 4 (four) marks for correct response, Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each question. % (one fourth) marks will be deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response is indicated for an item in the answer sheet. There is only one correct response for each question. Filling up more than one response in any question will be treated as wrong response and marks for wrong response will be deducted accordingly as per instructions Gabove. Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and Side-2 of the Answer Sheet. Use of pencil is strictly prohibited. No candidate is allowed to carry any textual material, printed or written, bits of papers, paper, mobile phone, any electronic device, etc., except the Admit Card inside the examination hall/room. Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is given at the bottom of each page and in 3 pages at the end of the booklet. (On completion of the test, the candiate must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However, the candidates are allowed to take away this Test Booklet with them, ‘The CODE for this Booklet is P. Maken sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this booklet. In case of discrepancy, the condidate should immediately report the matter to the Invigilator for replacement of both the Test Booklet and the Answer Sheet. Do not fold or make any stray marks on the Answer Sheet. Namo ofthe Candiato (in Capital letters) comnancenorimie:[ [| Name of Examination Centre (in Capital eters) Candidate's Signature Invigiators Signature Resonsence Educating for better tomorrow REMARKABLE Performance in Just SECOND YEAR (Established in 2011-12) Total Selections a ‘Selections Overall 595: 10 ‘Success Rate ‘Declared Eile (Out of 708) Students Appeared (Classroom: 422 | Distance Learning: 141 | elearning: 22) | | Allfrom Classroom Contact Programs ASHINI PATEL INEET2015 AN (UR356 | ANC: 79 | ASA=MLF UR 17 J ASR 0 PT aams-2ota ar: a7 (cen) Ge ee ee re eee A Aa ae Me Se ee Met ‘A) Upto 5 Scholarship in Classroom Coaching Fea Lowest Coursa Fea 2583/-Por Annu) 18) Ruivursunn ui Haste Raw& Mes Fowl expanse (ya B00/-pe ras ©) Lump SumRawardan Selection in AIPMT/ AMS (upc ® 2500007) ‘) Sua spr MBS Sud Cov Med Gly (yLUE 000-pK) Total Course Foe (deposited et Resonance aftr ‘Scholarship ofthe stadt shal be refunded in casei he/she selected in AIPM AIDS & tthe Admission ina Govt. Medial Cologe for MBBS Cours tough Al FEE REFUND = ‘ose For a CLASS-XI (Two Year) Classroom Contact Program Studont Cooctng ae Rosas: 1 4.088 5 soto sean orpanene PRO Lac +: Saeciennarwrans:e2soco0: 4 Mis Studes YZ. thn fe bene sc fe ed Ae sii Resonance Eduventures Prt. Ltd, EORPORATE OFICE (Mow Campo: 2 ovr, 6652. Sol. Sol. PART-A (PHYSICS) ‘The Current voltage relation of diode is given by | =(e"""_1) mA, where the applied voltage Vis in volts and the temperature T is in degree Kelvin. Ifa student makes an error measuring + 0.01V while measuring the current of 5 mA at 300K, what will be the error in the value of current in mA? (1)0.2mA (2)0.02ma ()0.5mA (4) 0.05 mA, We srs & enr—areean GT 1 =(e"""_1) ma & A Me 8 | Get Vers aE ateeen ates 4 ote aT 7 ft aor A 8 | aR ew Peel 300K eS mA ART ATE ge ATH +O.O1V ah AE aN 8, aw aT art ma 4 aft an ert 2 (1)0.2mA (2)0.02mA (2) 0.5 mA (4)0.08ma 0 sev ot Ittze 7, 1000 log (+1) = at Ta at _ 1000 1 a1___ 1000 Gra ~ 300 d1=0.2mA (0.01) From a tower of height H, a particle is thrown vertically upwards with a speed u. The time taken by the particle, to hit the ground, is a n times that taken by it to reach the highest point of its path. ‘The relation between H, uand nis (1)2gH= nit Q)gH=(n-2)'F —()2gH=nu(n=2) (4) gH=(n—-2)u" Sarg HA yo AAS, aa US GH om aT Rake GR A she Get ore 8] aot a geA aw FR A eT er Gad Gere kg cro we HG oT nT EL Huy nd da aed e (1) 2gH=n'vt @2)gH=(n-2)u? —@)2GH=nu"n-2) (A) GH=(n-2)? ® ulg (1) This solution was download from Resonance JEE Main 2014 solution portal Resonance Page #3 ht 23 @) 1 h'+H= Sa (ntpe 8 aetom a” ag *H= pam) Ge (n= 1Pu? _u? ye ete 2g 2g 3. Amass'm' supported by a massless string wound around a uniform hollow oylinder of mass m and radius R. IT the string does not slip on the cylinder, with what acceleration will the mass fall on release ? Rom Rod Ra mo yw YORAM Glas Fort aI Tew yw RATAN ST Sw OAT msc S) afe SO aa wy fire ae 2, ga BTS GM wR cari fire cae @ fe ? 2 5 wo? @% oe 9 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page #4 (1) (2) 4A. Ablookot mass mis placed on asutace wih vertical cross seton gen by y =%.tthecoeeent of friction is 0.5, the maximum height above the ground at which the block can be placed without slipping is a4 a) a+ a) 4 Or zm @zm @ 5m ae x 1 IT m aT etl eT es AA ae aR wre y =F A a ee EW 0.5 &, wa ech & orae ae aan ong, fret we ea Foes witon wear on wT & 1 1 (2) 2 (3) 1 (4) 1 Mem am @am 5m Ans. (1) dy Sot. = tan = jin limiting case aera Ret A dy 3x2 4 x6 2 1 This solution was download from Resonance JEE Main 2014 solution portal Resonance —$ Page #5 Sol. Sol. ‘When a rubber-band is stretched by a distance x, itexerts a restoring force of magnitude F = ax + bx?where and b are constants. The work done in stretching the unstretched rubber-band by Lis al? bl mee ata @ et a ww wag } wed hx GO ow aaa fret one @ ; a ORAM F = ax + bx? oT yo wer aa Tee uel a vib Rein &) far afta cag H west a LA afta wes A fren rer weds 1 a2 pL tfal? bl? (yal? +L (2) 7@L+bL) Oss alas (3) ‘Work done is streching the rubber band ay avg wt hte 4 fen ten ort 2a we ffaxibeyan = 2B 3 ‘Abob of mass m attached to an inextensibe string of length lis suspended from a vertical support. The bob rotates in a horizontal circle with a angular speed, radis about the vertical. About the point of suspension : (1) angular momentum is conserved (2) angular momentum changes in magnitude but natin direction (3) anguiar momentum changes in diction but not in magnitude. (4) angular momentum changes both in direction and magnitude. aang A em tart SSA ATT ma EH are a Gey Grae ee Soe AB | ara eae Te ator eet «rads & aw Aor ar yt ae & | Pekar eg oe (1) whe iar siviara vee 8 | (2) refs eid aftarer Haare & weg fer A Eh | (9) whois eid er A Rear @ oeog oRRT 4Eh| (4) rohan ah ene Rar oRRactre 8 ® Angular momentum of the pendulum about the suspension point 'O'is, L=m@«v) Then ¢ can be resolved into two components, radial componentr,,,, and axial componentr,,.- DUe 10 F.,, Lill be axial and due to r,,. L will be radially outwards as shown. This solution was download from Resonance JEE Main 2014 solution portal Resonance Page #6 So net angular momentum will be as shown in figure whoose value will be constant ([L| = mv ). But its direction wil change as shown in the figure. fry Od arte gam a aha aa Lem@-v) FBS ee A fers fren om rar By GH ee Praha, AT, TT fy OTL ow Seg eT ‘ral, reer L Proce fe A ares a site ee] ea A rafter & same ator eter ar ag er (IL = vi) Peres wor fey ara Fe aka eT | Short Solution ‘Angular momentum of the pendulum about the suspension point'O' will have a constant magnitude :(L) = mv (0p) butits direction will change as shown in the figure. fay O'S ter aretha wa wT ETT Fra (L)= mv (op) # As ga fen seTeTe Rage eee 7. Four particles, each of mass M and equidistant from each other, move along a circle of radius R under the action oftheir mutual gravitational attration. the speed of each particle is : [om GM GM 1 [GM, / j2v2 [1 202] I 22 OR (2) yaa (we ) a sy grb av) srt eat Mab ae aon i Fe GS a eB, Ge GR S ores rarer era A Poet R owe 7a W afeeha 8 | wets oT a oa a [om 56M [om F 1 [6M F OR @ a2e OlR 4-22) 4 ay Re?) Ans. (4) This solution was download from Resonance JEE Main 2014 solution portal Resonance fom. Page #7 8. The pressure that has to be applied to the ends of a stee! wire of length 10 cm to keep its length constant when its temperature is raised by 100°C is : (For steel Young's modulus is 2 * 10!'N mand coefficient of thermal expansion is 1.1 = 10*K=) (1)22%10°Pa (2)22%10°Pa (3)2.2%10'Pa (4)22%10°Pa tOom ararg 3 yw wha & are & AAR ae or ATTA H af 100°C wh unk & aa Gera Gea Rew eat forg fara oe crEN aa ara (eEte a ie eRe oT 2 x 10" N m= sie A Hee UT 1.1 x 10K"! €) (1) 22 10"Pa (2)22*10°Pa (9)22x10'Pa (4)22*10"Pa Ans. (1) P Sew P= Yuwi= 2 101.4 x 104% 100 =22%10'Pa 9. Thereis a circular tube in a vertical plane. Two liquids which do not mix and of densities d, and d, are filed in the tube. Each liquid subtands 90° angle at centre. Radius joining their interface makes an angle with 4s vertical Ratio gis: ye gare eh Gate aa A BY eh a, Gh gw GRE BMP ET ea en fT CHT 4, Wa, 8, AH A ay a8 | wets oa dee oe 90° ar BI sata See F | SAS sia: Ts TT visa are fon Heater S cw Sa 4, fiagas ge f 4. 4 tesinc A408 tetancr tesinos 1) 1- sinc, @ 1—cosey @) A-tancr 4 1—cosce Ans. @) This solution was download from Resonance JEE Main 2014 solution portal Resonance fom Page #8 Sol. Rsinu d, + Reos d, + R(1 —cos)d, = R(1=sinc) d, (sin + cose) d, = d,(cosc.—sinc ) dy _ ti tana @ Ttanw 10. _Onheating water, bubbles beings formed atthe bottom ofthe vessel detatch and rise. Take the bubles to be spheres of radius R and making a circular contact of radius r withthe bottom of the vessel I'r< Bw) 73 1 3=2+2x ox= 52 cosr pipe of length 85 cm is closed from one end. Find the number of possible natural oscillations of air column in the pipe whose frequencies lie below 1250 Hz. The velocity of sound in aris 340 mis. ‘Brag 85 0m wee TR we A a are we Aor OTT @ TEA ary RAT a Ta pw ett aH ae ‘son Pratt frre orafty 1250 Hz 8 we @ | ary H eafH wr a 340 mis | (re 28 (6 @a @) (ans iy For closed organ pipe fc six referer = (02 O42) ent. 1M 1260 4.085 30 85m (2n + 1) < 1250 x (2n+1)<125 2n< 11.50 n<5.25 So n=0,1,2,3...5 Sowe have 6 possibileties Sik BH 6 TTETY F) This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 13 16. Sol. 7. Sol. 18. Sol. Resonance ‘Assume that an electric field E —39x2} exists in space. Then the potential difference V, - Vj, where V, is the potential atthe origin and V, the potential at x= mis ar & aia 4 gw fage et € 30x27] 1 ca fare V,—V,, URTV, yeifeg oe fara Gd V,, x= 2m We fara & (11204 (21204 (3)-804 (4)800 (3) A parallel plate capacitor is made of two circular plates separated by adistance of 5 mm and with a dielectric of dielectric constant 2.2 between them. When the electric field in the dielectric is 3 x 10' Vim, the charge density ofthe positive plate willbe close to a aha Sei, rah Ata GA Smmé, 8 yw wae ver dents ear Aare rad Ate Iga Reo 2.2 20 Go cere wear wen By ra RTS Age Sy 3 x 10! Vim 8, a ETT eT RT TT SEPT am (1)6 «10°CIm= (2)3 x 101m? (3)3* 10cm? (4)6<10°Cm* “0 Electric field inside deletric wrt Fag 84 jy, = 9% 10" 2.2 « 8.85 x 10-# «3 x 10! 6 x 10" Cim? Ina large building, there are 15 bulbs of 40W, 5 bulbs of 100 W, 5 fans of 80 W and 1 heater of 1 KW. The voltage ofthe electric mains is 220 V. The minimum capacity of the main fuse of the building willbe: ‘we aes HTH, AOW S 15404, 100W 5 aca, COWS SHS Ce TKWoar 1 aiee | aura Are a ate 220V 81 as oye gM A Ap ee er (18a (2) 10 (12a (4140 ® Total power (P) = 15 « 40) + (5 x 100) + (5 x 80) +(1 x 1000) = 2500 P=vI 2500 "220 28 ot =113A Minimum capacity should be 12A Sp TET ARTA aUReY This solution was download from Resonance JEE Main 2014 solution portal pore! page # 14 19. Sol. Sol. Resonance ‘Aconductor lies along the z-axis at —1.5=2 < 1.5m and carties a fixed current of 10.0 Ain~4, direction (see figure). For afield B=3.0 1022", T, find the power required to move the conductor at constant speed to x= 2.0 m, y= 0 min 5 x 10s. Assume parallel motion along the x-axis yo Gara 2s wes 1.52 2< 1.5m wy var 8 othe ge a, fen A Ree an 10.0A zara a <2 81 (fra 8a) 5 B= 3.0% 1042714, TS fa, Gara w fer aaa aft oe & fry omar afte aH or BARRE | sere TTT AA AT S| Om oH 5x 10984 2.0m, (y.s7w (2)297W (3) 14.85 (@)207W @ Fa, = B(x) IL 17, 14 1 i519 4e 02" = 1 [Fon = + feQoidx = +, [3.10 10. 3d Pay [Fa ix i [a0 Ke Sao! e ix = Ofte The coercivity of a small magnet where the ferromagnet gets demagnelized is 3 x 10° Amr". The current required to be passed in a solenoid of length 10 cm and number of turns 100, so that the magnetic gets demagnetized when inside the solenoid, is : woe yaw a Praia, wel stages orqyraaia et on 8, 3« 10*AMe'é | at a sem 100d aE J0cm a ye aftatran & warfare eer ar rs, FSrERY Re eae ofa ore ak we orga eh ara, @ (1)30maA (2)60mA (3A (46a (3) For solenoid uftaferant & fer This solution was download from Resonance JEE Main 2014 solution portal pore! page # 15 21. Sol. Sol. In the circuit shown here, the point'C"is kept connected to point‘ til the current flowing through the circuit becomes constant. Afterward, suddenly point ‘is disconnected from point'A’ and connected to point at time t= 0. Ratio of the voltage across resistance and the inductor at t= L/R will be equal to: ae cara me aRtaer fey aH Ag A'S a Te HS aT omen 2 re rw Rae A wear are Ree Bong | area srarre fg ‘C's fag A'S eeraR fg BS t= OTT ts ar OMEN 8 t= UR wf rag dear & agers ee ae @1 @- as (3) After changing the switch, the circuit will act like an L-R discharging circuit. ooh a eenfia wet oe ae LRart aftaer at ave rd eT R Applying Kirchoff loop eqation. fereaits an Fram ay aa Va+Vi=0 = Ve = Ve som: ~B= oa: During the propagation of electromagnetic waves in a medium (1) Electric energy density is double of the magnetic energy density. (2) Electric energy density is half of the magnetic energy density (3) Electric energy density is equal to the magnetic energy density. (4) Both electric and magnetic energy densities are zero. ge mre A Ree Grae ae} ae het (1) eaptea gat era geri wat a ar STE (2) rete wrt cree Grate wort eee wT ame By 8) Reta wat cre grata wot wa wee (4) stoi Rete ea gevebher graf rea BB | @) Both the energy densities are equal et Sal ara wa 1 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 16 23. Sol. Athin convex lens made from crown glass | \' = > | has focal length f. When it is measured in two different 4.5 liquids having refractive indices = and =, it as the focal lengths f, and f, respectively. The correct relation between the focal length is (Eat fandt, becomes negative (3)f,>fand, becomes negative (4)f, and f, both become negative (3 45. corsa aia | | 8 a8 oe wo Soe aH A hoe aE 1B) ote ga asi F od aa Sl MI seal A cere ara ore &, oa hoe are orf, EL he range A a aE (iene (2)f,>f of f, seamen &t aan 81 (@)f,> fate f, seomeern eb omen & (4)f, 04 4, ah seo a oT 8 @ 4 (3124/1 [224] 4 12-912} = tan tat it ¥, 8x 4(2x) 4f af Analytically, Ifa lense is inserted in a denser sourrounding the sign of focal length changes and if lens is inserted in a rarer sourrounding , the sign of focal length remain same. I lense is inserted in rarer medium the focal length increases. aft Ge wh wert mre A gate eT ah tee yA ar Aare fake a oT ae ae a Peer ae AH gaa orn ot vies qf or firs ad eeu ae THe GA as UTA A green lights incident from the water to the air - water interface at the eriical angle (). Select the correct, statement. (1) The entire spectrum of visible light will come out ofthe water at an angle of 90° to the normal (2) The spectrum of visible light whose frequency is less than that of green light will come out ot the air medium (3) The spectrum of visible ight whose frequency is more than that of green light will come out to the air medium (4) The entire spectrum of visible light will come out ofthe water at various angles to the normal Ww RST Tore TAS agora oreTeTOTS we afer IM (0) B sae | A TeT_gPT (1) sires & 90° an oe oH ee Here or age wae TER Pras | (2) 23a ware an ae sage Perea ental eR gore a oH 8, oF Sag eT A are PST (3) 3a ware on ae sagy fore cated RR ro a aie & UN Sarg S mre A are PST (4) 3x4 were or Tee Sa OFS saftoea SAAT ato oe aTeR Pre (Q)IN HINDI(3) This solution was download from Resonance JEE Main 2014 solution portal Resonance fomi.Page# 17 Sol. Air 1 here wel sin C = 5, enavenn,., = 2/2. Iffrequencyis less > is greater and hence Ril. (.,)is less and therefore, critical angle increases. “af ora aa & at cy cater St ei (gy) A TTL ge TENT fem aT BAT | 25. Tow beams, A and B, of plane polarized light with mutually perpendicular planes of polarization are seen through a polaroid. From the position when the beam A has maximum intensity (and beam B has zero intensity), a rotation of polaroid through 30° makes the two beams appear equally bright. Ifthe initial intensities la ofthe two beams are |, and! respectively then , equals 3 1 (3 Qs (3)1 Ms gam d orth araaq oat ard ar gdta ware A ah Gor Ae B yw chores ere ef oh 81 oa Rea Sel gai AG sift haan & (sire or BA EET haan 8) EES a7 20° A Se GS GT gfe ath ahr 1 a ah Ah meer ae ae he TE A 4) 22 3)1 ay 4 “ @> @ 3 Ans. (4) This solution was download from Resonance JEE Main 2014 solution portal Resonance fomi.Page # 18 Initial , ntaly Finally : ? Polaroid Transmission axis 26. The radiation corresponding to 3 > 2 transition of hydrogen atom falls on a metal surface to produce photoelectrons. These electrons are made to enter a magnetic field of 3x 10~ T. Ifthe radius ofthe largest circular path followed by these electrons is 10.0 mm, the work function of the metal is close to ()teev Qitev @osev (4) 1.6ev mIggon TAT $3 QeimHm & eine Pen ya eg TS wR suite dae UlelgaaCTA TOA wee 81a scagit 3 104 To yw Gaaha da a wae oed 8) ate seas arr agra aera afta et att Pea 10.0 mm, 8 aa arg a ord wae STB ()18ev Q)titev @osev (@)16ev Ans. (2) mv eB? _ mv? Sol. e233 Pe%B? _ mv? am 2 rep? ay 2m 100. 10° 1.6.10 .9. 10 . 259.1107 16.9 2.94 1.89-0.79 = 1.1eV = 1.89 - This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 19 Sol. Sol. Hydrogen (,H'), Deuterium (,H?), singly ionised Helium (,He*)* and doubly ionised lithium (,Li)** allhave one electron around the nucleus. Consider an elelctron transition from n = 2 ton = 1. Ifthe wave lengths of emitted radiation are’... and 3, respectively then approximately which one of the following is correct ? (4%, i, B)i, Fh. ra Oy iy = Bia ERT (\H!), Sehr (1), Goer sea Aika (ety sie fae oraPia Aer (Ley wh A ew RH satis art she Bi n= 29 n= 1 d cain aor oe fare afhry | aly eatin afer aA eee ar ia 04 i804 Prafattaa saat 4 a ater ar wel 8? aa (3)i, ® 1 lea | =R«1)°4) -n26/) a i Tg 9 So option (3) is correct rat: fears (3) wat BI ‘The forward biased diode connection is xa are arn rats org & os a 2) py a @™ w wo ou ” For forward bias V, > V, om aif % fae V,>V, soot 2p} m2 foar biased om aftrate & | Match List (Electromagnetic wave type) with Listl (Its association/application) and select the correct option from the choices given below the lists List Lista (a) [infrared waves [(i) [To treat muscular strain (o) [Radio waves _[(i) [For broadcasting (c)_|Xrays |(iii) [To detect fractureof bones ‘sorbed By the ozone layer (d)_ [Ultraviolet l(iv) |of the atmosphere (@) ) ©) @) ow (i) w 0 2 0 ‘i ) (ii @® wi ‘i 0 ) ® 0 w (i) Oo) Resonance Iti sliton was download trom Resonance JEE Main 2014 solution Port paag y 20 Sol. Sol. “ted (Peg gemete ree ene) aH RH (SR AR ae) GAR wHfhry oe eft ob a A faoad a8 TA Rarer gC: List 0 (a) foran aet_ |) [arate a Right & gare Pay oy rea wet |i) [rene oA (@)_ pete iy [each oan A aaa + Fae (ay_feeederah fareet_|ivy [aren aA ater oer erat arte (a) (b) (c) @ (1) (wy) (il) (i) @) (2) @ il) (wy) i) (3) (il) il) @ wy) (4) @ (i) (il) ™ (4) Option 4 Is Correct ‘femey (4) wel 8) ‘Atudent measured the length ofa rod and wrote i as 3.50 em. Which instrument did he use tomeasure it? (1)Ameter scale. (2) Avernier caliper where the 10 divisions in vernier scale matches with 9 dvision in main scale and main scale has 10 divisions in 1 em. (3) Ascrew gausge having 100 divisions in the cular scale and pitch as 1 mm. (4) Ascrew gauge having 50 divisions in the circular scale and pitch as 1 mm, we Rlenelt yo ws A ararg mre 3.50 om fare) gerat ATA A ga Fre eI or Bete Pat 7 (1) ya ee at (2) or afte ferns ret affect B10 arr eT Ge Om | Pond & ote ger wha 1 emH 10 are (3) vor way to frend afte bet H 100 aT @ sie ft 1 mm ei (4) om way to fore afer eet A Soar & ott fa 1 mm & @ If'student measure 3.50 cm it means that there in an uncertainly of order 0.01 em aft va 3.50 ef ra 8 ch gear af 8 fh ae afar 0.01 cm wa a S| L.C of V.c = 1 MSD-1VSD affae tart a1 serie = 1MSD-1VSD 2 Af5 40|'"70! So Bis Correct option ce: (8) farea eal 81 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 21 at. Sol. Sol. Sol. 33. Sol. Resonance PART-B (CHEMISTRY) ‘The correct set of four quantum numbers for the valence electrons of rubidium atom (Z= 37)is efafan weary (Z= 37) & fa ASH aah + oft ae aaa NI aT ae erate 1 1 1 1 (1)5,0,0,+ 5 2)5,1,0,+ 5 @B)5A14 5 45.01.45 (a) Z=37. Rbis in fifth period [kr]5s' is its configuration Son=5,1=0,m= z=37. Rb aad srad a ae 21 gacnr fara Kr]5s' 3 1 1 .m=0,s=+s ors m=0,8=+5 of aren = 5,12 " 2 IfZis a compressibility factor, vander Waals equation atlow pressure can be written as a Z sists gern et ot ar ara we aiseareR wean wh PeraT oT eT & Pb = ayz=1+ PE ~ RT @z= RT RT a ()z=14 21-year @z @ Inlow pressure region, vanderwaal equation becomes. 2p are Sa A, arvsearer tare er el oe 8 CC! crystallises in body centred cubic lattice. If'a' its edge length then which of the following expressions Is correct ? CsCl ara dftaa ware wrote 4 fineefers chen | afe fee a crag ‘at et ot AT Gat AS ate Sta am? (1) Fog. op ten Hor 2 toy 8) tog. Hoe = 38 ® In CsCl, Clie at comers of simple cube and Cs" at the body centre. Hence. Along the body diagonal, Cs" & CI-touch each other so CsCl, Cha area oH wT oe ae Cs* arr aoe oe Ree 8, ge TOR a Ral d orga Cs" ae Chaven wert # 28 € or This solution was download from Resonance JEE Main 2014 solution portal pore! page # 22 Sol. Sol. For the estimation of nitrogen, 1.4 g of an organic compound was digested by Kjeldahl method and the M M evolved ammonia was absorbed in 60 mL of +5 sulphuric acid. The unreacted acid required 20 mL of +5 sodium hydroxide for complete neutralization. The percentage of nitrogen in the compound is agers # carport & fry 1.4 a, wren hes star A seg are Khar Ta ear Ba gy eA 60 felt u ‘arama are H orev ren aan ait areata opt ereiitanen 3 fey 20 Fh x afer arggiangs A oraeerna ge | aiff A argcrort a after & (1) 6% (2) 10% (3)3% (4)5% (2) Mass of organic compound = 1.4 g let it contain x mmole of N atom, corganiccompound __, NH, xm mole 2NH, +H,SO, —_. (NH,), SO,. (1st) 6 mmole initially taken, H,SO, +2NaOQH ___, Na,SO, +2H,0 (2nd) 2mmole reacted Hence m moles of H,SO, reacted in 2nd equation = 1 m moles of H,SO, reacted from 1st equation = 6 — 1 = 5m moles m moles of NH, in 1st equation = 2 x 5 = 10m moles m moles of N atom in the organic compound = 10 m moles mass of N= 10 x 109% 14 0.149 0.14 sot = 98 400 =10% corde atten or gears = 1.49 sara fv ae Nowra d Xm mole tam @ carafe ater — NH, xm mole 2NH,+H,SO, _, (NH,), SO, (st) 6m mole see fer a H,SO, +2NaQH — > Na,SO, +2H,0 (2nd) 2mmole cara era #1 2a FeO fia etree sitar H,SO, 3 mmole > erftere (1) 4% siren H,SO, m mole = 6=1 = 5 > tet ener 4 NH, mmole = = 2% 5= 10 mmoles covittcn ahftes # N oeaTai & mmole = 10 mmoles Neo gamer = 10 « 102 * 14 20.149 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 23 35. Sol. Sol. Resistance of 0.2 M solution of an electrolyte is 50. The specific conductance of the solution of 0.5M solution of the same electrolyte is 280). The molar conductivity of 0.5 M solution of the electrolyte is ‘Sm? mot is ‘yw rege rere 0.2 M fora aor 0c) fetes @ 1 er reer ar free rene 1.4 S mB ge eT race 0.5M ferro after 280) & fger ommerea a 0.5M fra Hare aTETET S m2 aa eh (1) 5. 10-4 (2)5. 108 (3) 5» 10° (4) 5» 102 “0 x= 1.4 Sim. R=50() M=02 1 RR od 214% 50m4 R Now, new soltuion has M= 0.5, R= 280 © 80 «) 7000-M 1000.0.5 2000 For complete combustion of ethanol, C,H,OH(I) + 30,(g) —» 2CO,(g) + 3H,0(), the amount of heat produced as measured in bomb calorimeter, is 1364.47 kJ moH at 25°C. Assuming ideality the Enthalpy of combustion, (GH, forthe reaction willbe (R= 8.314 kJ mor) whia $ pi wat 3 fa, CyHJOH(N) + 30,(9) » 260,(6) + 3H,O(), a Seehof Sra 25°C we 1364.47 kd mob 81 ores ar gy var a aed, GH ahh (R=8.314kJ mob) (1)= 1366.95 kJ mo" (2)=1361.95 kJ mor (3)— 1460.50 kJ mo" (4) 1350.50 kJ mot a ©,H,OH(\) +309) —_, 2C0,(6)+34,0(0) = 1364.47 Kslmol \U+ An, RT -1 ¥ ~senar+ == 1364.47 2.4776 =~ 1366.94 KJ/mol. This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 24 37. Sol. Sol. Sol. Note : Sol. Note : Resonance “The equivalent conductance of NaCl at concentration C and at infinite dilution are’. and : correct relationship between j,, and ., is given as: (where the constant B is positive) “amr C othe OFT ATE NaCl fare aH TART whe Se 7, AT EY ST ome ee Fer wou e (Gv Rex sia #) , respectively. The (Ac =A ABC ie @) -B)C QB) ie=4,-(BVE (4) ie = 1, +(8)VE BYE (Debye Huckel onsagn equation) -BYC (sag geq siti writen) Consider separate solution of 0.500 M C,H,OH(aq), 0.100 M Mg,(PO,),(aq), 0.250 M KBr(aq) and 0.125 MNa,PO,(aq) at 25°C. Which statements true about these solution, assuming ll salls to be strong electrolytes ? (1) They allhave the same osmotic pressure (2)0.100 M Mg,(PO,),(aq) has the highest osmotic pressure. (3)0.125 M Na.PO,(aq) has the highest osmotic pressure. (4) 0.500 M C,H,OH(aq) has the highest osmotic pressure. 0.500 M C,H,OH (a2), 0.100 M Mg,(PO,),(S4) 0.250 M KBr (aca) sx 0,125 MNa,PO4(sreta) fart wh 25°C me exra @) Ans. (2) Sol. K,=K, (RT) 40. For the non - stoichiometre reaction 2A + B > C + D, the following kinetic data were obtained in three separate experiments, all at 298 K. Initial Concentration | Initial Concentration Initial rate of formation of C (A) ®) (molL"s) o1M o1M 1.2107 o1M 02M 1.2.10 0.2M o1M 24.10% ‘The rate law for the formation of C is a f e a () KANG) @) = KARE] «= @) GHAI arafioren fact siffivan # Ata ere wait 4 208 K ue fer aftres stirs are fer a = KIA] [oeire ise | aRP@ ais | Ca A UR ex | (A) (8) Gia Ls*) 01M OAM 1.2510 01M 02M 1.2.10 02M o1M 2.4.10 afin & ferg © ar an ae Perr erm: = MARIE] (@) £ a 7MAIGP (4) = KA] [B] (2) & = KA] dc a ‘at at Ans. (4) 1.2% 10°=K (0.1) (0.1) 1.2*10°=K (0.1) (0.2)" 2.4 x 109 =K (0.2): (0.1)" R=K [Ay [BP This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 26 a. Sol. 42. Sol. 43, Sol. Resonance Among the following oxoacids, the correct decreasing order of acid strength is, Fer ore ora & fey ore eet at aenef mea a eT (1) HOCI> HCIO, > HCIO, > HCIO, (2) HCIO, > HOCI> HCIO, > HCIO, (3) HCIO, > HCIO, > HCIO, > HOC! (4) HCIO, > HCIO, > HCIO,> HOCI @ Decreasing order of strength of oxoacids sitaet ort ah erred or gem EON A HCIO, > HCIO, > HCIO, > HOC! Reason Consider the structures of conjugate bases rer digeh ani dt teernsit we flere afer 1 q : Gh AlNe- oF eon oN oe ot I-06 Negative charge is more delocalized on CIO, due to resonance, hence CIO, is more stable (& less basic) ore eM C1O,- we eM sits Rrearsra e oren #1 gaAAG CIO, ser sere & (ig aH era & ) “The metal that cannot be obtained by electrolysis of an aqueous solution of is sats is cag oft ote} sav cha eral eer (ga sen) Be wes eH eT ea ere & (1)Aq (ca (cu (@)cr @ Reason : Higher the position of element in the electrochemical series, more difficult is the reduction ofits cations. If Ca* (aq) s electrolysed, water is reduced in preference to it. Hence it cannot be reduced electrolytically from an aqueous solutions. eer gs eran ht Ar at Rae fort er rae) ih, Ger A eT era am once ef er aS Cat (acta) a Aga oreo eter 8, ch gata ger A ort or wren wu S ones eh 8, ge HR Ge rcs frat & ger eae rae ora El et wT 8 ‘The octahedral complex of a metal ion M°* with four monodentate ligands L,, L,, Ls and L, absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength ofthe four ligands is Mi eg, ome or aT Ger TIS ARSE, Ly, Ly, Lae Ly ee oe aT eae aT, we, Ha othe ANS vera Sakae ar margER sree eer By aT Peet A er a age we (i green (L,) > yellow (L,) > red (L,) L,>L,>L,>L, in fleld strength of ligands. This solution was download from Resonance JEE Main 2014 solution portal pore! page # 27 Sol. Sol. 45, Sol. Sol. Li be bs | be ‘ara | wa | tan | ato ae i sraeita sere BA rat or orate a, reer da Pes & sat were an wafer ee &, oe: Forts or dra aed sea eter #1 ‘watt «ston (L)> eer (L,) > ston (L,)> aT (L,) L> Lele, (ris 3 aa aed 4) Which of the following properties is not shown by NO ? (1) tis dimagnetic in gaseous state (2) Itis a neutral oxide {3) It combines with oxygen to form nitrogen dioxide (4) I's bond order is 2.5 NO ahaa Pret gor wef ah avec B ? (1) tr craven weg 8 | (2)2 we sand stags 81 (3) ae attain 8 att oy Agglort SigsiieNTgS FATA 21 (4) geht wa wHEZ5BL “ NO is paramagnetic in gaseous state. ‘ra sranen # NO sragracta 8 | In which of the following reactions HO, acts as a reducing agent ? ‘er fees aaftvenatl A H,O, yap arate an an area & ? (@) H,0, + 2H" +2e°—2H,0 (b) H,0,-2e° —>0,+2H" (©) H,0, +2e°—»20H™ (6) H,0, + 20H” —2e" — > 0, +2H,0 (1) (@),(B) (2) (c), (a) (3) (a). (c) (4)(b), (a) 4) H,0, acts as reducing agent when it releases electrons, ie. (b) & (a) HO, orrareren caters oh ance orf ee Bort ae e- eet wea & | ete (0) (A) ‘The correct statement for the molecule, Csl,, is (1)itis a covalent molecule. (2)it contains Cs* and 15 (3) itcontains Cs** and I~ ions. (4) itcontains Cs*, I” and lattice 1, molecule. Cal, 9, fer tenet wert em (1) 2 Ge aero ry 1 (2) ea cst ote 15 omert eta 81 (3) Sei Cs oe Pores a 8 (4) gai Cs*, ott, orate BE @ Itis a simple & popular fact. We We ara ¢ fread ore 81 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 28 47. Sol. Sol. 49, Resonance The ratio of masses of oxygen and nitrogen in a particular gaseous mixture is 1 :4. The ratio of number of their molecule is, ‘ye fite Aetea frame a cttattort afte argos @ gam a sigue 1:48) g8 Mam A gr ory densi oT aged een (yi (27:32 @te (43:16 @ (0,) Me) By, My, Mo, |28 1 28 =|im,, 132-4" 32 _7 32 Given below are the half-cell reactions Mn2* + 26» Mn ; E°=—1.18 V 2(Mn** + &° — > Mn2*) ; E°= +1.51 V The E° for 3Mn®* > Mn + 2Mn°* will be : (1) -2.69 V ; the reaction will not occur (2) -2.69 V’; the reaction will occur (3) =0.33 V: the reaction will not occur (4) -0:33 V: the reaction will occur Are yo ore Ges airy ag & Mn2* + 26" — » Mn ; E°=—1.18 V 2(Mn°* + e~ — Mn2*) | E°= +1.51V 3Mn?* — > Mn + 2Mn®* % fey £° eer (1) 2.69; crifvan 8h eo] (2)-2.69V ; siren er (3)-0.33 V; cif 8 | (4) 0.33; svar er “ Mn? 82250, Mn ete Mn for Mn* disproportionation, E® = —1.51 V-1.18V 269V<0 Reaction is non-spontaneous. Mn? E215, Mne els tev, Mn Mn Reverrtteree 3 fee? =1.51V-1.18V 2.69V<0 cafifiver area: ert Which series of reactions correctly represents chemical relations related to iron and its compound ? dil H,S0, 1,804.02 heat (1)Fe FeSO, Fe{SO,), Fe Ozheat IHS, (2)Fe FeO FeSO, _heal_,Fe Cleat heatair 2a (3)Fe Fecl, S28" 5 Fecl, 2° 5 Fe This solution was download from Resonance JEE Main 2014 solution portal pore! page # 29 Sol. Sol. Oahoat 60, 600% £0, 700" (are Ti 8 aPhfirenstl ar ster wa mene we A ote ote ged hal A create Penal wy Prefer wea 8? (Fe >Fe,O, >FeO >Fe SaSPe_, Feso, HOH ,Fe,(s0,), —“ > Fe 1 —Hs804 an (2) Fe 22 Fe Feso, —“ sre an. ag zn (Fe 22 rec, Feol, 2" sre (4) Fo 22 F,0, CBWE 9 COTE eg (4) The correct reaction are as follows Fe,(SO,), 1, Fe,O, (s) + 380, * (This is given Wrongly) °, ()Fe > FeO (it could also be Fe,O, or Fe,O,) FeO +H,SO, __, FeSO, +H,O (3) Fe > FeCl, —> no reaction (it cannot give FeCl.) ()Fe > Fe,0, > Feo —S> Fe This is correct. 8 after Fe To Se Fe(S0), —L., Fe,0, (6) +380, * (ue set ean ra &) (2)Fe +> Fe0 (ae Fe,0, se1at Fe,0, 3 wart #1) FeO +H,S0, —_, FeSO, +H,0 Fe,0, + $0, +80, (3)Fe > Fect, > ang siftfirar a (as FeCl, & wae 8) a) Fe > Fe,0, 22> Feo > Fe => Fe.0, ap Tore ae wa 2) ‘The equation which is balanced and represents the correct product(s) is (1) Li,0 + 2KCI— 2LICI+ K,0 (2) [CoCKNH,) Co®* + SNH," + C- (3) [Mg(H,0),)2 + (EDTA) _222885N2OH_, (Mg(EDTA)}* + 6H,0 (4) CuSO, + 4KCN > K, [Cu(CN),] + K,SO, This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 30 Sol. st. Sol. woe ot igitra & she wens! fren weit BH aw 8, & (1) Lz0 + 2KCI-> 2LICI+ K,0 (2) [CoCKNH,),}* + 5H" > Co®* + SNH," + Cl- (3) [Mg(H,0),P* + (EDTA) —N2OHs shes (4) CuSO, + 4KCN + K, [Cu(CN),] + K,SO, @ (1) Li,0 + KCI— » 2LiCl+K,O ‘wrong equation, since a strenger base (K,0) cannot be generated by a weaker base Li,O sro woes, BR Ya Gdet Ae LiO, ge YH Hae TE (KO) AE MII et HAT BY (2) [CoCKNH,)] + 5H” — + Co* (aq) +5NH,+ Cr ‘This is correct. All ammine complexes can be destroyed by adding H ae 88 8) wh Geis age a Ho Proves Renfra fa ot wae EI om > [Mg(EDTA)}* + 6H,0 (3) [Mg(H,0),}* + edta > [Mg(edtaj* + 6H,O ‘This is wrong, since the formula of complex must be [Mg(edta)]~ ae Tra &, ft iar aT I [Mgledta)}- en aa (4) 2CuSO, + 10KCN — 2K,[Cu(CN),] + 2K,SO, + (CN), * itis a wrong option, as given in paper ae Ger se fewon & She wea A Ra 8 In S,2 reactions, the correct order of reactivity forthe following compounds : CHCl, CH,CH,Cl, (CH,),CHCI and (CH,),CClis (CH,), CHCI> CH,CH,C1> (CH,),CCI (2) CHCI> CH,CH,CI> (CH,),CHCI>(CH,), CCI (3) CH,CH,Cl> CH,CI> (CH,),CHCI> (CH,), CCI (4) (CH,),CHCI> CH,CH,CI> CH,CI>(CH,), CCI @ 4 Rate of 8,2 *? ” Steric crowding ofc C CH, t CH.CI > CH,CH.CI > CH.-CH-CI > CH,-G-Cl CH, cH, 4° Crowded 2 * we CH.CI > CH,CH.CI > CH,-GH-cl cH, oo aan 2 . This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 31 Sol. 53. Sol. Sol. Resonance On heating an aliphatic primary amine with chloroform and ethanolic potassium hydroxide, the organic compound formed is, (1)an alkanol (2)an alkanediol ()an alky\ cyanide (4) an alky!isocyanide erbite mee Gita ar acikrorl she waht dette eggs BWI TRA aT TR aa SIR Aha ame (1) we teortt 2) ye tebrsrite 8) 06 tite frames (4) We bites sngetrarngs ) R-NH, + CH), CHOHIKOH, py 4° amine alkyl isocyanide R—NH, + CHo|, SHOHIKOH, p_Rg ie era RATES ‘The most suitable reagent for the conversion of R-CH,-OH > R-CHO is (1) KMno, Q)K,C,,0, (cro, (4) PCC (Pyridinium Chiorochromate) RACH,-OH > R-CHO# agent ar aad aft oye siftore erat B : (1) KMno, (2)K,Cr,0, (cro, (4) PCC (PRS aire) (4) R-CH,OH PS +R-CH=OH Pyridinium chlorochromate is the mild oxidising agent. fash ama yw Ae altar afte 8 | ‘The major organic compound formed by the reaction of 1,1,1-trichloroethane with silver powder is (1) Acetylene (2)Ethene (3)2-Butyne. (4)2-Butene 1A A gIgaeRgos wT Peas USSR wer fren at oe wae ash Arar A aT afer aor eter & (1) gfe Qe (2-314 (2m (3) 2cH,-ccl, SAD H.-C = C-CH, + 6AgCI But2-yne 2cH-cc1, AB CHC = C-CH, + 6Agcl aeons This solution was download from Resonance JEE Main 2014 solution portal pore! page # 32 55. Sol. Sol. ‘Sodium phenoxide when heated with CO, under pressure at 125°C yields a product which on acetylation produces C. Che ag ‘The major product C would be : ifar darrengs Hi Gea ara she 125°C we CO, Safire wey we ot atte ure eer 8 web yee wy firm wai C eter 81 oe sg sco, #9840 a8 war fren va Cem ou 9cocr, H ococ, och, o) on @ ® Go ® O. coon COCH, (1 Itis a kolbe schmidt reaction. ae ye aiet—fere affine 21 Na COONa COOH F 125°C. OH 2, Ac/0 ace +00, a Satm Asprine (pain Kier) Na cooNa cooH F . 0-C-CH, +00, 2286 Baim wer (et Rae) Considering the basie strength of amines in aqueous solution, which one has the smallest pK, value ? cicha Row ¥ ital A ania wala} ogee Preifafiach aa free fet pkyar ar wr S wa ee? (1) (CH,),NH (2)CH,NH, (3) (CH,),N (4) CH.NH, “ Order of basic strength of aliphatic amine in aqueous solution is as follows (order of K,) (CH).NH > CHANH, > (CH) > CHIH: ‘As we know pk, = og K, 80 (CH,).NH will have smallest pk, value ‘rch tara oferta Gt aA anda emmecier a wa Penge 81 (Ka AY (CH) .NH > CH,NH, > (CH).N > CHNH, BH IT # fF pk, = og K, -wafere (CH,).NH 848 FH pk, HF waa 21 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 33 57. Forwhich of the following molecule significant = 0? a ON OH (a) O (b) © (c) O (a) a CN OH (1) Only (@) (2) (ayand() (2) Oniy (e) (4)(c) and (a) ft HG fra org AR age ten aw ORM 7 SH SH a ON OH SH (a) @ (b) O (co) O (a) 1 CN OH SH (1) eet (a) (2) (a)sie(b) (3) Bae (c) (4) (c) site (4) Ans. (4) OH SH Sol. inthe quinol O and thioquinol ©ormessane do notcancelise ther dipole moment OH sy as they exist in different conformations. Kg-H get ‘same as in thioquinol, Ay OH SH me Gyre Ot ete te ma by SH vag fates sewer fora Hora ora 8 oH © ©) (aretfeasita 4 oh ten erm) wn we This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 34 58. Which one is classified as a condensation polymer ? (1) Dacron (2)Neoprene (3) Teflon (4) Acryonitrile eri & frmat aetaters aga ara a ? (year (2) Freier ()@ear (4) Sireirrgerg Ans. (1) Sol. Dacron is a condensation polymer of ethylene glycol and methyl terpthalate Sa, oProts carnal Ga Ara cece ar gw eens age a | . i ° (m1) sop Dacron 4 (ot) sorte 59. Which one of the following bases is not presentin DNA ? (1) Quinotine (2)Adenine (3) Cytosine (4) Thymine rer are Sah GH ONAA AE aren ora 2 (1) faerie (2 er (gyre (4) omg Ans. (1) Sol. Quinoline is an alkaloid, itis not present in DNA, DNA has four nitrogenous bases in adenine, guanine, cytosine & thymine freiot yw vedere 8, ae DNA H AE aren ore 2, DNA are aTegloniterd are seiq gsi, sari, engereis aren ergeia ord oa 8 | This solaton wes downlad trom Resonance IEE Main 2014 slston pot Resenence mm Page #35 60. Inthe reaction, ale Poy Ae. KOH CH,COOH MAH 5 a POL yp —AEHOH the product C is (1)Acetaldehyde ——_(2)Acetylene (2) Ethylene (4) Acetyl chloride aifirar Fe, cl,cooH HAM, a PL, g —ASKOH 4 fr 7a Catan 8 (ytettsems (ay efhfeciet (enter cay oPaege ache Ans. @) AIH, Pcl, Sol. — CH,COOH ——*> CH,CH,OH ——> CH,CH,CI (B) (A) HCI] Alc. KOH CH, H, (©) ethylene AIH, PCI, CH,COOH ——> CH,CH,OH ——> CH,CH.Cl (8) (A) +10 |e KoH This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 36 PART - C (MATHEMATICS) 61. X= (4°—3n—1: nN) and Y = (9(n—1):n-< N}, whereN is the set of natural numbers, then XY is equal to af X= (4 3n—1 sm NP TOM Y= (9(0= 1): N), 8, TEE Nr eet a TET cH XO Y RTE @y @N (@y-x Sol. 4°—3n—1} Y=(0,9,....., 9(n—1)} Now 4°—3n—1=(341)'—3n—1 =P tn3' +... #°C, 9. is a multiple of 9 ‘Aiso Y consists ofall multiples of from 0, 9, Hence all values of X are subset of values of ¥. Thus XUY=¥ Hind! X= (0, 9, n.d" —3n=1) Y= (0,9, 2.2, (0 =1)) gmt YP=3n=1= (8+ 1) 3n=1 2d +n +... #90, 9. om ome aan Y, 9% wi qo waaT 0,9, ore: xX wh art Ya are aT TET & om XLY=Y (1) is strictly greater than 5/2 (2)is strictly greater than 3/2 but less than 5/2 (3)is equal to 5/2 (4) lie in the interval (1, 2) a Ze te oa seem & Pe fe)22@, at fed a pre aT (1) 512% Pree as 8 (2)312 & Prem ae 8 aeYsDS wre (3)512% are (4) sieert (1, 2) 3% Fre & Sol. Ans. (4) 4 1 245] is distance of 2 from - > Cleariy its minimum value is when z = -2 which is 3/2 OY Hindi. | ont “pig went a 22-28 oe SAT ETI A 3I2e This solution was download from Resonance JEE Main 2014 solution portal Resonance fomi.Page # 37 63, a= Rand the equation —3(x—[x))’ +2 (x -[x]) +a? = 0 (where [x] denotes the grealest integer 4 re2tys sin(xcos” x) im Sn(roos" x) 70, ty SB1E28 i aquatto sg E80 a a (y= @ (ane «4 This solution was download from Resonance JEE Main 2014 solution portal Resonance —$ Page # 40 Sol. m1. Sol. 72. Sol. 73. Sol. Resonance 0 {Storm sin(xcos* x) _ sin(rsin® x) _ sin? x x sin’ x eo If gis the inverse of a function fand f(x) = +. then g'(x) equal to The aR g ver Fm apa B met) = Fh B A ote) mE 1 *) Tea (2)1 + {9e0y" Q)1+e (4)5x¢ ‘Ans. 2) If f(x) & g(x) are inverse of each other then, A x) 3 9x) Gar Ga afta & ae, 1 a0)= Fey Here 72 x= oly) oy) =1+ (WP 9&)=1 +900" It fand g are ditferentiable functions in [0,1] satisfying (0) = 2 = g(1), g(0) = 0 and f(1) = 6, then for some ce]0, 1[ a fae g,[0, 1] errant wert vi (0) = g(t), g(0) = Oste (1) =6 a4 age wed & ch Peet ce]0, 11% fay (f= 910) (2)f(¢) =29(6) (3)2"(6)=9(6) (4) 2"(6)=30'0) Ans. (2) Consider f(x) — 29(x) = h(x) Then, h(x) is continuous and differentiable in [0,1] Also h(0) = 2& h(1) =2 Hence h(x) Satisfies conditions of Rolles Theorem in (0, 1) Thus, There exist a‘c’ such that he) = 0 where c « (0, 1) = He)=29(6) “APT PB f(x) — 2g(x) = h(x) wa h(o), (0, 1] 4 a sie starts & wahO)=2 a h(t) =2 Fe: x) (0,1) 4 Stor mer ab ee ere a gS are & ‘tc! ene Petar & FR hi(c) =O rel ¢ < (0,1) (e)=29(6) Ifx ==1 and x = 2 are extreme points of f(x) = rlog|x| + fix? + x then caf x = =1 Tem x= 2, (x) = cloghy| + [ve +x aRAKay 2, at 1 1 1 1 (unape-k Qusaped Bus6 p24 @ur-6 p24 Ans. (1) f(x) = 01 nfx| =x? =x a = DP? xt (y= 4 2vcet.= A Since x =—1, 2 are extreme points — f(x) = 0 at these points. 1) = 0g Parga =6)) -3=0 Bee This solution was download from Resonance JEE Main 2014 solution portal pore! page #41 74. Sol. 75. Sol. tnt The integral -1 p's 7 integral []14x—1 p" Fdx is equalto area [ft-x—1 pax aera 8 x (are +e @-xeF +e @a-teF +e — yxe Ans. (4) (a warmer ee Oe We get, le" dx = x0" — fete" Fax Fox =x eX +6. ; 2X x The integral [yt 148i"? —A4sin% ax equals } coor {fe asin oe ree 8: 2s (1) 8-4 (2) V3 -4— (@)n=4 (4) G48 Ans. (2) = | fitonef tang are [t= 2onnrzion = [it-2sinxi2i+ fir-2sinx/2 oe = [(t-2sinxi2yix [(2sinx!2—t)be nia! Int = F428 4-1 428 47/3 SA + 4/3 This solution was download from Resonance JEE Main 2014 solution portal Resonance 76. The area of the region described by A= {(x, y):x° + y’<1 andy? = 1—x) is A(X y)oe+ yet aan y= 1x) % grt aan Ba or Sawa z 2 2,2 z,4 z 5-5 O55 Oss @> Sol. Ans. (3) Intersection of ¢ + y= 1 &y'=1—x isx=0,1 “The required portion is shaded as shown. ‘Acea of region is area of semicircle plus area bounded by parabola & y-axis. 7 rca semicircle is $ 2 ‘Area bounded by parabola = © of corresponding rectangle 2 reaet 3 3 Hence total area = Method - 1 Required area = area of semicircle + area bounded by parabola x 3 = yet Ey aot Bs Hindi. xe ya1ayatoxd aera x=0,1 cae are fer & eaten en & aa or dawg, oraan ar arm ote ye cen tea S aRRae St ar at & on) or aa a1 a7 5 eae & ag daa = 2 sna oe wr dart Method - 4 site dawa = ofan wm daw + aca 3 ohtag da [-yy¢y By [ove = 5 +2| +E e2|t- z 2 This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 43 Sol. 78. Sol. Resonance oot Letnepopuaon crete siringatatn tbe govrnay te teretauaton 2 = 1 9 2a. pt) = 10,6 pans dp(t) _ 4 sar Pre ere to het oA) orate oraaret tare SE = > p(t) 200 arr Fria 1 ‘af& p(0) = 100%, at p(t) wee (1) 600-500 e (2) 400 - 300 e~* (3)400-300e (4)300-200 e* Ans. (3) 1 pit) = 5 Plt) —200 1 P= 3 Plt) =-200 Hence solutions is oie BAS ot @ = f-200e "et = 4000 7 + ora p(t) = 400+ Ce “§f% Since p(0) = 100 100 = 400+C >C=~300 “Thus ait p(t) = 400 ~300 e* Let PS be the median of the triangle with vertices P(2, 2),@ (6,1), and R (7, 3). The equation ofthe line passing through (1, ~1) and parallel to PS is ara PS var Pryor a mae & fared eid P(2, 2), Q (6,—1), Fa R(T, 3) 81 (1,—1) 8 ere oT arch Rear oh PS & ark 8, ao eters ()4x+7y+3=0 — (@)2x-y—11=0 (8) 4x—7y—11=0 (A) +947 =O Ans. (4) (2.2) @ \_ Srv.) e-9 Oy 13 Stope of PSA weer = 5 = z Hence equation of ine through (1, ~1) & parallel to PS is: Se (1,1) 8 TF TSA she PSS TA ea a wieT: _2 Wt = > &-1) oy +2e+7=0 Leta, b, cand d be non-zero numbers. Ifthe point of intersection of the ines 4ax + ay + ¢ = 0 and 5bx + 2by + d = O lies in the fourth quadrant and is equidistant from the two axes then APT a,b, owe dep weary # |W Tanah dax + Zay += OTe Sbx+ 2dy+d= Om wide fg ae agate # & ven a oat 8 wage @, dt (1) 3be—2ad = 0 (2) 3be + 2ad = 0 (3) 2bc—3ad = 0 (4) 2be + 3ad = 0 This solution was download from Resonance JEE Main 2014 solution portal pore! page # 44 Sol. Sol. at. Ans. (1) dax + 2ay + Sbx + 2by + x oy 4 2ad-2bc 5bc-4ad~ Bab —10ab be-ad )_ dad—Sbe ab * y 2ab In fourth quadrant point equidistant from axis will have sum of x & y co-ordinate = 0 cagelaquia # ont & aerae @Qh oe x, yo Peet a eer eh =O Be -2ad | dad—Bbe Zab” (ab 2ad—3be = 0 The locus of the foot of perpendicular drawn from the centre of the ellipse x? + 3y* = 6 on any tangent to itis, arian e+ ay = 6d de Bea fet wel tar oe aha ay dao ore wr fg we (1) 02 + y= 6x? + 297 (2) 02 +? = 6x? — 2 (3) Ge yf = 6x +27 (4) Gey = 6e— 2" Ans. (1) eth) x +3y=6 equation of line through (h, k) & perpendicular to line joining it to origin FS Ch) TPT aT He er Fg Sere oN TA ear be, ear or tare + y= = Zen) mh Nak? Kt Kk Since itis tangent to elipse, “ff ze aha # eral Yar & site CH= atm? + bt SGP +y!F= 6x + 2y7 Is the regd. locus. sife fArguet Let Ce the circle with centre at (1, 1)and radius = 1. ITs the circle centred at (0, y), passing through origin and touching the circle C externally, then the radius of Tis equal to ET Cw ae 8 farsa Ba (1,1) 8 sen Boat = 18 | aS Te (0,y) aa ag ot aS fy a a TET tan aa Cat ae wed wad oem 8 TA Bom aaa é: 1 1 8 Mz Qz we This solution was download from Resonance JEE Main 2014 solution portal Resonance fom. Page # 45 Sol. Sol. 83. Sol. Ans. (2) e,(1,1)r,=4 ©,(0,y)F,= ce,=1, +t, yl-0F +(1-y)P = 1+ Wy (0, ¥). ay. 2-2 +yay+2yie4 ly “The slope ofthe line touching both the parabolas y* = 4x and x? = — 32y is weal y= 4x cee == 32 Sat a eet eA aT ea A aM 8: 1 2 1 3 Oy QZ @z > Ans. @) 1 = 4x Sy=mx+ + yee ax oy =mx+ = xis-32y yen-a2 [mer 22 wereme Zao 7 D=0 + (32m)-4« 25 m gem’ =4 x 2-4 The image of the line == inthe plane 2x-y +z +3=0 is the line 3 =5 art Qeny+ 2+ 3208 teat 31 YO8 24s stata ach tent x3 _y48 Ma Ans. (3) xot_ y-3_ 2-4 | -22-31419) tant This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 46 Sol. 85. Sol. Image of point (1, 3, 4)on given line in the given plane is (-3, 5, 2) are Rea fy (1, 3, 4) aT wT F we 8 3,5, 2) Line is parallel to given plane Yar f&& wars # TAR #3, 1,6 So, image safe afta x43_y-5_ 2-2 “The angle between the lines whose direction cosines satisly the equations +m +n = 0 and (®= m+ n*is St Rang ford Rey aioe, eae [m+ n=O cM P= me +n a age ae eb da wr site : : x : me @} Oy oF Ans. (3) +m4n=0 (1) Pom? yn? (2) > Pama jem =0 2mim+ )=0 m=0 o | |zom so direction ratios are gufery fm agua &—1,0,1 six and—1, 1,0 aa, +bb, +00, Ja? 1b? 1 o2 fad | b3 0% oo; 4 v2| “2 B aft [6.66.66 .a]=sfab ef 8 2 were et (yo @1 @2 (3 Ans. @) éo.al-ifb P then? is equtto LHS=[2 xb bd Gx a] [pbx E Gx 8] (where wi p = 4 * B) p x(b xc). (x a) P- 6)b —(P-b)E}. (Ex a) ={[4 6 S]b [2 6 G]e}(exa) (As p=axb) = [4 6 Eb aJ-0(-[ 4 b b]=0) ab €P([b € a]=[4 b é)) RH het [ab ep This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 47 Sol. 87. Sol. LetA and B be two event such that P(&B)= i P(AMB) Where stands for the complement of the event A. Then the events A and B are (1)independent but not equally likely (2)independent and equally likely (3) mutually exclusive and independent (4) equally likely but not independent ar Ager 82) th weal # Ph PACE aie @1 at cer Ace B (1) sada 8 eg wT ae 8 (2) eta & en ere & (3) seer sree gen waa (4) aera & eg ela TAB Ans. (1) Given fear war @ p (AUB) J otace)= joe PAR)= 3 8 rats Ret Ad RH a »Paane)=7,PA)=4 a 4—p (AuB)-2 7 6 1-P(A)-P@):PALIB)-2 (. PA)=1-P (A) 1 1 =PB)= 2-556 3 ‘Aand B are not equally likely. Agen Berndt 78 & 3 ~ Further P(A). P(B)= 9" =g = PANE) ‘AandBareindependentevents Asie Beacra wet & ‘The variance of first 50 even natural numbers is wee 50 BH Breve sensi oT eT 437 833 (1437 as oF (4)833 Ans. (4) ge Sov-x? Vo0- 51? _ 2? 49? =. 492) _ 2 +2? -.... +502) -2(2? +42 +... 50) ~ 50 - 50 ~ 50 “ 50 = 833 1 Lett (x)= | (sinh + cos'x) where x = R and k = 1. Then f(x)—f,(x) equals rf, 0)= PE (sinix + costs) 8, TE KER oI E18 at 10) =f) ae 44 2) 4 a4 ay 4 My Qa Os 3 This solution was download from Resonance JEE Main 2014 solution portal Resonance fomi.Page # 48 Sol. Sol. Sol. Ans. @) t00= Beinoxe cos 4 gin x08" x) (sin? x -cos® x) = 2 1 1 (sin* x-+cos* x)—1(sin® x ~c0s® x) = (1 —2sin? x cos?x) ~ (1 —3sin?x cost qOsint x +008" x)—F¢ ) = F(1 —2sin# x c0s*x) ~5 (1 —3sinx cos) 4.44 476 12 Abirdis siting on the top of a vertical pole 20 m high and ts elevation from a point O on the ground is 45°. It flies off horizontally straight away from the point O. After one second, the elevation of the bird from O is reduced to 30°. Then the speed (in mis) ofthe bird is ye veh 2088, Sa yw Gears Gg Rene oe Aor 8 cen gee yA} gw Reg OF sreH wie 45°81 TE veh O8 WR Aft en HF sear 8) ww Sais S ae, O8 veh a GeV BW Ue we BO" ee TT BI ot Gf. aft &. 8) woh Ht ara (1) 20 V2 (2)20( 3 -1) (3)40( /2 -1) (4)40( (3 -/2) 8 B OnN'= 3 BA 20 OA+AA'= 3 x20 Aa= (,/3 -1)20 £¢e) A ° a (v3 -1)20 “m = (J -1)20 ‘The statement ~(p <> ~a)is (1)atautology (2)a fallacy (3) equivalenttop <> q (4) equivalent to~p «> 4 BAA~(p o ~g)® (1) ye ref (tautology) (2) ya Rca (fallacy) po ada 4)-p oat Tr Ans. (3) Method-1 ~(peoma) Pp q ~9 |p _~q|-~(p_-@) ~p ~p_-q|p_q TPT PF) F TTF F T tle |r] or FOF T F Flr |el t FOOT T F File | tle TOIT F T Method-2: logically equivalent of ~(p<>q) a afta vt isp og® This solution was download from Resonance JEE Main 2014 solution portal Resonance Page # 49 PSEA SN ae UC ae OOM ROA UREA CLT rN Resonence Educating for better tomorrow rer Coe Ceo Cec Cea) cor pt Cr 3m Capt Sear ee eee) ete er eae EE (Advanced) 2013 en ign: 6 Weeks | Medium: English & Hindi © Chaseraon Teaching © Test Discussion Ces (© Compted sprinted aassroom LeetureNates © MateralUsousson Less © Periodic Tea (Onceine Weetd © Open Test (OT) GEE Preparatory Tests PTs) 1. Tas, crass

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