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13.2.1 Composition
The chemical composition of steel is very important since it has a significant effect on the
microstructure of the material and hence on its mechanical behavior and properties.
Steel is basically an alloy of iron and carbon, but several elements are used in various
proportions and combinations to produce different types. By definition, a steel has a
maximum carbon content of 2.0%. Structural steels normally contain less than 0.30%
carbon, however, and in terms of chemical composition can be classified as either plain
carbon or low-alloy steels. In plain carbon steels, the amounts of carbon and manganese,
the principal strengthening elements, are restricted, and other alloying elements are not
normally included. In low-alloy steels, the carbon content is also restricted, and increased
strength is achieved through the use of alloying elements such as nickel, chromium, and
molybdenum. The alloying additions usually do not exceed a total of 8%.
Carbon is by far the most important element in steel: The changes in composition
(cementite or iron carbide [Fe3C] content), microstructure (pearlite content), and mechanical
properties (strength and ductility, in particular) resulting from changes in the carbon content
in annealed plain carbon steels are shown very clearly in Fig. 13.1. In the range of carbon
contents shown in Fig. 13.1, a significant increase in strength and decrease in ductility are
produced by an increase in the carbon content in the steel.
Steels can be classified on the basis of composition. The most widely used system for
identifying or designating carbon and alloy steels is that developed by the American Iron
and Steel Institute (AISI) and the Society of Automotive Engineers (SAE). The AISI-SAE
system employs a four- or five-digit designation, where the major alloying elements in a
steel are indicated by the first two digits, and the amount of carbon, in hundredths of a
percent, by the last two or three. Examples of several steels with their AISI-SAE
designation and alloy composition are shown in Table 13.1. Structural quality steels are
further classified on the basis of strength, using a system developed by the American
Society for Testing and Materials (ASTM), as discussed in Section 13.6.
13.2.2 Microstructure
The microstructure of metals and alloys-that is, the geometric arrangements, volume
fractions, sizes, and morphologies of the constituent phases and/or grains, as observed
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Figure 13.1
Properties versus carbon content (annealed, plain carbon steels): (a) hardness and strength
versus the amount of carbon, Fe3C, and pearlite; (b) microstructure of 0.40% C (left) and
0.80% C (right) steels (X500); and (c) ductility and toughness versus the amount of carbon,
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Fe3C, and pearlite (from L. H. Van Vlack, Elements of Materials Science and Engineering,
5th ed., Addison-Wesley, 1985).
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Example
Composition
AISI-SAE Type of Steel Designation (weight %)
1040 0.37-0.44 C
0.60-0.90 Mn
41XX Chromium-
molybdenum 4140 0.30-0.43 C
0.75-1.00 Mn
0.15-0.30 Si
0.80-1.10 Cr
0.15-0.25 Mo
equilibrium or phase diagram (see Chapter 3). The following features should be noted in
the iron-cementite, Fe-Fe3C, phase diagram (Fig. 13.2):
γ →α +Fe3C.
Since the two phases that form have different compositions, atoms must diffuse during the
reaction: Most of the carbon in the austenite diffuses to the Fe3C, and most of the iron to the
ferrite (α ). Since this redistribution of atoms is easiest if the diffusion distances are short,
the α and Fe3C grow as thin lamellae, or plates, forming a structure called pearlite (Fig.
13.3).
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Figure 13.2
Iron-iron carbide equilibrium phase diagram (iron rich portion) (P. A. Thornton and V. J.
Colangelo, Fundamentals of Engineering Materials, Prentice Hall, Inc., 1985).
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Figure 13.3
Photomicrograph illustrating the lamellar nature of pearlite (xl125) (Courtesy of Theresa
Brassard).
Since the structural steels are hypoeutectoid - that is, they contain less carbon than the
eutectoid composition (0.80%) - the primary microconstituent is ferrite (a). When a
hypoeutectoid alloy cools under equilibrium conditions from some temperature above, say,
900'C, the following occurs (Fig. 13.4):
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Figure 13.4
Microstructural formation during the slow cooling of a hypoeutectoid steel from the melt
(M. E Ashby and D. R. H. Jones, Engineering Materials 2, An Introduction to
Microstructures, Processing and Design, Pergamon Press, 1986).
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Figure 13.5
Photomicrograph showing pearlite "islands" (striped regions) surrounded by primary ferrite
(X8000). Courtesy of Mary Mager, Dept. of Metals and Materials Engineering, University
of British Columbia.
1. Just below the A3 temperature, ferrite precipitates and grows, usually at the austenite
grain boundaries; primary ferrite continues to grow until the temperature falls to A1.
2. At the A1 temperature, the remaining austenite is surrounded by ferrite and its
composition has changed to the eutectoid composition (0.80% C); subsequent cooling
causes all of this austenite to transform to pearlite by the eutectoid reaction.