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CHEMISTRY
1.
Anti-Markornikoff addition occurs in Karash effect, which proceeds through free radical mechanism.
v
CH3 CH 2 CH CH3 is a secondary free radical and is more stable than CH3 CH 2 CH 2 CH 2
2.
3.
Epsomite, MgSO4. 7H2O is in rhombic system. Zinc blende, ZnS is in cubic system. White tin, Sn is in
tetragonal system. These may crystalline in body centred lattice. Blue vitriol, CuSO4.5H2O is in triclinic
system and has only primitive lattice.
4.
5.
6.
RNA contains all the bases present in DNA, except thymine. In the place of thymine, RNA contains the
base uracil.
7.
XeO4 has four double bonds. All 8 electrons in the valence shell of Xe atom are used in bonding. Hence
no lone pairs are present on the central atom.
Ammonical cupric salt with tartarate is Fehlings solution. It is a mild oxidant. It oxidises aldehydes, but
not ketones.
Hybridisation of B in BF3 is sp2
Hybridisation of N in NH3 is sp3
Hybridisation of B in H3N.BF3 is sp3
Hybridisation of N in H3N.BF3 is sp3
8.
9.
x1 P1
10.
x 2 P2
1 1
2 2
1/ n
0.1 100
(or)
0.2 400
1/ n
2/n
(or) n = 2
CH3 CH3
CH3
C=C
H
C=C
CH3
CH3
C = CH2
CH3
}}m
}}m
14
}}m
[salt]
[salt]
(or) 4.8 = 4.8 + log
[acid]
[acid]
[salt]
[salt]
log
= 0 (or)
=1
[acid]
[acid]
50 s M 100 s 0.2
50 100 50 100
M
100 s 0.2
0.4M
50
19. Basic nature of the oxide decreases and acidic nature increases, from left to right in a period.
eg : MgO, Al2O3 and SiO2
20. CO2 is gas, but SiO2 is a solid. CO2 is a linear molecule, but SiO2 is the simplest formula of Silica. C in
CO2 is sp hybridised, but Si in SiO2 is sp3 hybridised. C and Si both forms a total of 4 bonds.
21. Metal with lower reduction potential can reduce all metal ions with higher potential
Reduction potential is least for Al. Hence it reduces all other given metal cations.
22. With HCl, the reaction is to be catalysed using anhydrous ZnCl2. With HBr and HI, no catalyst is
required. With HI, the reaction is very fast.
23. [Mn(CO)5]2 is the complex. Each complex unit is square pyramidal. Two complex units are joined by
metal-metal bond.
24. For BaCl2, B 0.8 and n = 3
i 1
i 1
B
(or) 0.8 =
n 1
3 1
a
(a x)
PHYSICS
31. d1 : d2 : d3 = eV01 : eV02 :eV03
V01 : V02 : V03 = 0.001 : 0.002 : 0.004 = 1 : 2 : 4
hc vq
W0
By photoelectric equation
eM e
Compare the above equation with y = mx + c
hc
tan R
m
e
1
0.001m 1 1000nm
M 01
1
M 02
500nm ;
250nm
M 03
V0
V
n1 Rt and P2 0 n2 RT
2
2
n1 P1
n 2 P2
P1V1 = n1RT1 and P1V2 = n2RT1
V1 n1 P1
V2 n 2 P2
But V1 + V2 = V0
= V1
P1V0
PV
V2 2 0
and
P1 P2
P1 P2
33. Conceptual
34. N
RD
; RD NAD
AD
RD1
3
s 6 9cm
2
RD2
3
s 4 6cm
2
= RD1 + RD2 = 15 cm
35. Because the system is accelerating upwards, tension at any point will be T = m(g+a)
16
dW
di
Li
dt
dt
L1l1 = L2 l2
l1 L 2
di
V L
;
l2 L1
dt
V1 L2
V2 L1 ;
W
L l
1
= W Ll 2 ; 2 2 2
W1 L1 l1
2
39. t = ax2 + bx
dt
dx
dx
2ax b V(20x b)
dt
dt
dt
V = (20 x + b)1
a
40. n
dv
dx
(2ax b) 2 s 2 2av3
dt
dt
1 F
1 stress 1 Y.strain
2l AS 2l
2l
S
S
V
T3
PV
constant . From the above equations
T
dV
dT
3
V
T
But dV = vr dT
r%T
42.
3dT
T
MR 2
MR 2
M[4R 2 ]
Md2
2
4
17
G
G G
uv G uv G
j 2(xi y j)
43. y i
ux uy
JG
E 2 x2 t y2
JG
JG
G
JG
For points : x = 0; E 2yJ and E is along positive y-direction for points y > 0 and E is along negative
y-direction for points y > 0.
JG
G
JG
JG
Similarly : For point y = 0 E 2xi and E is along negative x-direction for points x > 0 and E is along
positive x-direction for points x < 0
Q
R
3 Q
Potential at the centre of the sphere = VC K
2 R
Let m and - q be the mass and charge of the particle respectively.
Let V0 = speed of the particle at the centre of the sphere
1
Q
mV2 q(VB Vs ) qk
2
R
1
3 Q
mV02 q(VB VC ) q s k
2
2 R
V02 3
Dividing 2 1.5 (or) V0 1.5V
2
V
45. Conceptual
46. Rate of cooling
eB
dT eA
(T4T04)
dt ms
dT
dt
= for x ;
dT
is more, therefore ex > ey and since absorptivity is proportional to emissivity, hence
dt
Ax > Ay
1
1 1
1 1
1 1 N1 N 2
47. Feff f f = (N1 1) (N 2 1)
B R
R B
R
1
2
48. x is greater than 28
R
x
l 100 l
=l
200
x2
When the resistances are interchanged the key shift 20 cm. Therefore
x
2
80 x lx = 2l + 40
l 20 80 l
80x = l(x + 2) + 40
On solving x = 38
49. R P 18; R Q 18; R R 28
RQ < RP < RR ; P2 < P1 < P3
18
50.
%g
g
s 100
Case C :
g
s 100 2
%T
T
s 100
Case:A
%g
%l
51. Conceptual
52. The situation is shown in figure given below. (x, y) represents the point at which the collision takes
place. Let, for the first particle time of flight before collision be t, so the time of flight for the second
shell be (t %t) , for the first shell x u cos R1t .....(1)
For the second shell x u cos R 2 t (t %t)
I
cos R1
t
s
cos R2 t %t
(x,y)
t %t cos R1
t
cos R2
%t
R1
cos R2 cos R1
.............. (3)
cos R2
%t u
x
cos R2 cos R1
cos R1 .cos R2 .......... (4)
Further y x tan R1
y x tan R2
gx 2
2u 2 cos2 R 1
gx 2
2u 2 cos2 R 2
On solving
sin(R1 R2 )
gx cos R2 cos R1
gx 4 %x
2
2s
%t
2u sin(R1 R2
g cos R1 cos R2
DM
d
19
R2
55. Let x be the compression of the spring, when the block m2 is about to shift. Therefore, for the block m2
kx = N N2 and N2 = m2g ................. (1)
Let F be the constant minimum force, then on application of F on m1 it should starts moving and should
comes to rest. This means that F NN1 Nm 1g . Now for the block m1 from work-energy theorem.
WF + Wmg + Wsp + Wfr + WN =
Fx + 0
%T
1
kx2 N m1gx + 0 = 0
2
kx
F Nm1g .............. (2)
2
From eq (1) and (2)
F Ng(m 1
m2
)
2
56. The outer circle is traversed in the anticlockwise direction while the lower circle in traversed with
clockwise direction.
JG Q
G
A (a 2 b 2 )k
2
JJJG Q 2
G
Pm (a b 2 )Ik
2
57. Conceptual
58. As the inclined plane is frictionless
1
mv 2 mgh
2
A
V 2gh
In
300
%ADB tan
600
h
3
h = 3m; V 6g 60m 1
600
3m
mk
E
300
3 3m
BE
CE
=BE = 3m
1
1
m( 45)2 M s 10 s 3 M VC2
2
2
= VC 105m 1
60. Final velocity will be horizontal, making an angle 300 with BC.
20
3
45m 1
2
MATHEMATICS
61. The two circles intersect orthogonally
the square of the distance between centres
= sum of squares of the radii
30 1 32 42 52 30 1 5
2
30 (30 1) 1 b 30 1 1 5 1 6
30 (30 1) 1 r 30 1 1 5 1 4
62. f(x) = 4x2 16x + c
f(1) > 0, f(2)< 0, f(3)>0
c > 12, c < 16, c > 12
12 < c < 16
c = 13, 14, 15
1 M
1 M
2
4M
0 M3 6M 2 11M 6 0
A3 6A2 + 11A 6I = 0
1 2
A 6 A 11I
6
5
64. f'(x) = 2ax + b and f 0 b 5a
2
c = 2 and f(1) = 1 a 14 .
f(0) = 2
= f ( x)
x2 5
x2
4 4
y + 2z = 4
(2), (4) (M 3) z (N 10)
.....(4)
.....(5)
no solution M 3 and N x 10
66.
1
12
1
32
Let x
1
52
1
r
....d
1
2
Q2
8
1
2
1
2
1
4
1
52
....d
1 1 1
1 1 1 1
2 2 2 ....d 2 2 2 ....
1 3 5
4 1 2 3
Q2
8
x
4
3 x Q2
Q2
x
4
8
6
1 and C c and B C 3 0
(B 1)
B 1
2
B 1, c 4
Q
Q 5Q
5Q
68. f'(x) < 0 on 0, , f ( x ) 0 on , and f '(x) < 0 on ,2 Q
3 3
3
3
69. Rolle's theorem doesn't explain statement I.
70. I1
1 cos2 t
sin 2 t
1 cos2 t
2
sin t
(2 x ) f (2 x ) 2 (2 x ) on
2 I 2 I1
(2 x ) f < x (2 x )>dx
I1
1
I2
( x 2 2 x 4)dx
xdr x 2 dx
1
= 19/3
72. 3n1 (4 1)n1 4M1 (1)n1
5n2 (4 1)n2 4 M 2 1
7 n3 (8 1)n3 4 M 3 ( 1)n3
73.
f (h ) f (0)
f (0) Lt
Lt
h m0
hm0
h
1
h P sin
h
h
1
Lt h P 1.sin doesnot exist
h
hm0
P 1b 0 p b 1
1
f (0) Lt x P sin 0 p 0
x
x m0
3
e x 1
x2
x
b
Lt
f
(
x
)
Lt
.
.
74.
2
x m0
x log(1 x ) sin(ax )
1s1s
1
a
a
1
b
22
75. x y
dy
( x 2 y 2 )2
dx
d( x2 y2 )
( x 2 y 2 )2
dx
1
2 x c passes through (1, 0)
( x y2 )
2
C 3
31 31
=P ,
7 7
a = 2, c = 4
5
f(0, y) = 0 = (y2)(y3) b , c 6
2
y=x
77. f(x, 0) = 0 = (x 2)
A(4,3)
= data is insufficient.
78. The circle passing through the end point of latusrectum and touching the directrix has center at four and
latusrectum is the diameter.
2
2
M
79. Let R be the angle between the plane and x-axis, then sin R
4 9 36 7
80. Lt f ( x ) Lt cos x 1
nmQ
nmQ
Lt f ( x) Lt (sin x 1) 1
nmQ
nmQ
f(x) is a continuous at x Q
hence continuous on [0, d)
81. a .b 0 x( x 1) ( x 1)1 1.a 0
x 2 2 x (a 1) 1 0, x R
4 4(a1) < 0
a>2
82. S P Mn and S .n q
Mn P .n q
=S P
P .n n
n
23
54 4 4
10
369
10 4
1
15
86. A.P. r G.P.
1
27csx 81sin
r 27csx.81sin
2
2 (3csx 4 sin)
2
9 3
87. a s d b s d c s d c s d
d s a s d d s c s d d .d c d .c d
d c (0)d
d s a s d
d
c
88. Let di = xi 8
=T 2x
T 2d
1
1
di 2 di
18
18
1
9
9
s 45
18
18
4
=T x
3
2
q is q p.
= e me + m(m1)Im2
= (1 m)e + m(m1)Im2
Im
1
mI m 2 e K 1 m, L
m
1 m
24