IIT JEE MODEL GRAND TEST II

Paper 2: Solutions
KEY

PHYSICS:
1) C 2) C 3) B 4) B 5) D 6) B 7) B 8) C 9) C 10) A 11) D 12) D 13) D
14) D 15) C 16) D 17) B 18) A 19) D 20) A Q; B S; C R; D P
21) A Q; B R; C P; D S22) A P; B S; C Q; D R
CHEMISTRY:
23) A 24) C 25) B 26) C 27) D 28) B 29) C 30) C 31) A 32) B 33) C 34) C
35) D
36) C 37) C 38) C 39) C 40) B 41) D 42) A Q; B P; C PS; D QR
43) A PQR; B PQ; C PQR; D PRS 44) A S; B R; C P; D Q
MATHEMATICS:
45) A 46) B 47) D 48) C 49) C 50) C 51) C 52) B 53) C 54) A 55) A 56) C 57) B
58) B 59) A 60) D 61) C 62) B 63) D 64) A Q, B Q, C Q, D S
65) A R, B S, C P, D Q 66) A Q, B S, C R, D P



Physics:
1) C 2) C 3) B 4) B 5) D 6) B 7) B 8) C
9) C 10) A 11) D 12) D 13) D

Comprehension-I

[14) D 15) C 16) D]
Kinetic energy K =
2
1
mv 2 KeV
2
=
Speed v =
7
2k
2.65 10 m/ s
m
=
B
min
=
3
2 mvcos
4.73 10 T
q(GS)

=

Comprehension-II

[17) B 18) A 19) D]
Final pr = p
0
+
kx
A

= 2 10
5
v/m
2

Applying
1 1 2 2
1 2
p v p v
T T
=
We get T
2
= 800 k

Heat supplied Q = w
gas
+ u
= p
0
(v) +
2
v
1
kx n.c .dt
2
+
n =
1 1
1
p v
RT
Q = 720 J

20. A Q; B S; C R; D P
A Q R = R
0

( )
n
1
2

C R
( )
2 4
1 2
2 H He
i.e; 2(2 1.1) = 4.4 MeV
4(7.0) = 28.0 MeV
Energy released = 23.6 MeV
D P
min 3
12.375 12375
v 20 10
= =

= 0.62 A



21. A Q; B R; C P; D S
For hydrogen like atoms,
E
n
=
2
2
z
13.6 eV
n
| |

|
\

for z = 3 and n = 1
We get -122.4 eV

12375 12375
310 nm
w 4
= =
n sin 45 = 1
n =
1
2
sin 45
=
i = i
0
(1 e
-t/
)
i
0
=
12
2A
6
=
i = 1A, t = 1 ms





22. A P; B S; C Q; D R

n
th
minima of 400 nm coincides with m
th
minima of 560 nm
n = 4 m = 3
List of this minima = 14 mm
Similarly for next n = 11 m = 8
And dist = 42 mm
difference = 28 mm
Fringe width w =
D
d

When wave length is decreased from 600 nm to 400 nm fringe width also decreases by
factor
4
6

no. of fringes will increase by
3
2

i.e., 12
( )
3
2
= 18.


Chemistry:
23. (A)
E
0
= E(cathode) + E(anode)

24. (C)
Crystal radius > covalent

25. (B) unpaired e
-


26. (C)

27. (D) Ag
2
O Ag + O
2


28. (B)

29. (C) (MgCO
3
white ppt

30. (C)
O
| |
CN C

31. (A) 32. (B) 33. (C) 34. (C) 35. (D)

36. (C) Para more basic (e
-
releasing)



37. (C) Oxygen withdraws e
-


38. (C) Greater the no. of C in alkyl, more e
-
releasing

39. (C) max. unpaired e
-


40. (B) 2 unpaired e
-


41. (D) Cu
2+
1 unpaired e
-


42. A Q; B P; C PS; D QR
3
2 2
OA HNO
Be(OH) amphoteric HNO OA, RA

3
Al(OH) OA, gel white ppt

43. A PQR; B PQ; C PQR; D PRS
enthalpy extensive, state, KJ
Entropy no units
Free energy extensive, state, KJ

44. A S; B R; C P; D Q
Named reaction


Mathematics:

45. (A)
Given a(p + q)
2
+ 2bpq + c = 0 and a(p + r)
2
+ 2bpr + c = 0
q and r satisfy the equation a(p + x)
2
+ 2bpx + c = 0
q and r are the roots of a (p + x)
2
+ 2bpx + c = 0
i.e., q and r are the roots of ax
2
+ 2(ap + bp)x + c + ap
2
= 0
qr = product of roots =
2
2
c ap c
p
a a
+
= +

46. (B)
If x = 2m + y where m is an integer and 0 y < 1, then [x] = 2m and

x x 1 2m y 1
m, m
2 2 2
+ + + ( (
= = =
( (


1 x y
1
2 2
+ | |
< <
|
\


x x 1
x
2 2
+ ( (
+ =
( (


Also if x = (2m + 1) + y, then
x
m,
2
(
=
(


x 1 2m, y 1
m 1
2 2
+ + + ( (
= = +
( (


But [x] = 2m + 1 =
x x 1
2 2
+ ( (
+
( (



[ ]
x x 1
x
2 2
+ ( (
+ =
( (

for every positive real number

47. (D)
Let z = x + iy, then arg (z 3i) = arg (x + iy 3i) =
3
4

x < 0, y 3 > 0
3
is in 1 quadrant
4
| |
|
\

And
y 3 3
tan 1
x 4

= = y = x + 3 x < 0 and > 3 -------- (1)
And arg (2z + 1 2i) = arg [(2x + 1) + i (2y 2)] =
4

2x + 1 > 0, 2y 2 > 0 is in 1 quadrant
4
| |
|
\

And
2y 2
tan 1 2y 2 2x 1
2x 1 4

= = = +
+

y =
3 1
x x , y 1
2 2
+ > > ---------- (2)
x
y
(0.3)
y = x +
3
2
1
1
2

y = x + 3


From equations (1) and (2) we get graph it is clear from the graph that two lines do not intersect.
No point of intersection

48. (C)
Let the common difference of the given A.P. between then
d = a
2
+ b
2
+ c
2
a + 3t = a
2
+ (a + t)
2
+ (a + 2t)
2

5t
2
+ 3(2a 1) t + 3a
2
a = 0
t is real 0 0 9 (2a 1)
2
4(5) (3a
2
a) 0
24a
2
+ 16a 9 0
1 70 1 70
a
3 12 3 12
< < +
a = 1, 0 [ a is integer]
When a = 1, from (1) : t = 0,
3
5
(rejecting both these values since t must be non-zero integer]
When a = 1, from (1) : t = 1,
4
5
t = 1 a + b + c + d = 1 + 0 + 1 + 2 = 2

49. (C)
Let, s(1 + x)
1000
+ 2x(1 + x)
999
+ 3x
2
(1 + x)
998
+ - - - - - - + 1001x
1000

x
1 x +
s = x (1 + x)
999
+ 2x
2
(1 + x)
998
+ - - - - - + 1000x
1000
+
1001
1001x
1 x +

Subtract above equations,
1001
1000 999 2 998 1000
x 1001x
1 s (1 x) x(1 x) x (1 x) ........ x
1 x 1 x
| |
= + + + + + + +
|
+ +
\

s = (1 + x)
1001
+ x (1 + x)
1000
+ x
2
(1 + x)
999
+ - - - - - + x
1000
(1 + x) 1001x
1001

( )
1001
1001
1001
x
1 x 1
1 x
1001x
x
1
1 x
(
| |
+ (
|
+
( \

=

+
[sum of G.P]
= (1 + x)
1002
x
1002
1002 x
1001

coefficient of x
50
in s = coefficient of x
50
in [(1 + x)
1002
x
1002
1002x
1001
] =
1002
c
50


50. (C)
The number of triangles with vertices on different lines =
p p p 3
1 1 1
c c c p =
The number of triangles with 2 vertices on the line and the third vertex on any one of the other two lines
=
{ }
3 p 2p
1 2 1
p(p 1)
c c c 6p
2

= =
The required number of triangles = p
3
+ 3p
2
(p 1)

51. (C)
Let A =
1 4
3 2
(
(

and B =
16 6
7 2
(
(

then the matrix equation is AX = B

1 4
A 2 12 0
3 2
(
= = +
(

, so A is an invertible matrix
Let c ij be the cofactors of elements a ij in A = [a ij]
Then, c
11
= (1)
1 + 1
(2) = 2, c
12
= (1)
1 + 2
(3) = 3, c
21
= (1)
2 + 1
(4) = 4, c
22
= (1)
2 + 2
(1) = 1
adj A =
T
2 3 2 4
4 1 3 1
( (
=
( (

So, A
1
=
1
A
adj A =
2 4
1
3 1 10
(
(

Now, AX = B A
1
(AX) = A
1
B (A
1
, A)X = A
1
B
1 A
1
B X = A
1
B X =
6 2
2 4 16 16
1
11
2 3 1 7 2 10
2
(
( (
= (
( (

(



52. (B)
f(x) is an odd function, hence g(x) = f(x) = f(x)
f(x).g(x) =
2
3 4
x 1 1
sin x 2x 1
x 3x 1



f(x) =
2 2
3 4 3 4
x 1 1 x 1 1
sin x 2x 1 sin x 2x 1
x 3x 1 x 3x 1
multiplying row by row
=
2 2 4
2 2 4 3 6
4 3 6 6 4
x 2 xsin ( x) 2x 1 4x 1
x sin ( x) 2x sin ( x) 4x 1 x sin( x) 6x 1
4x 1 x sin ( x) 6x 1 x 9x 1
+ + + +
+ + + + +
+ + + + +

f(1) g(1) =
3 3 5
3 5 7 4
5 7 11
=

53. C
Let p = 2 cos x + sin
2
x = 2 cos x + 1 (cos
2
x + cos x) = 3

2 2
1 1 13 1
cos x cos x
2 4 4 2

| | | |
+ = +
`
| |
\ \

)

p max =
13
4
, when cos x =
1
2

p min =
13 9
1,
4 4
= when cos x = 1

p max 13
p min 4
=


Assertion Reasoning:

54. (A)
cot tan = 2 cot 2 tan + 2 tan 2 + 4 tan 4 + 8 tan 8 - 16 cot 16 = cot

55. (A)

1 1 1 1 1
3 1
3 1 x y x
4 7
tan tan tan tan tan
3 1
4 7 4 4 y x 4
1 .
7 7

| |
+
|
| | | | | |
+ = = = + =
| | | |
+
\ \
\
|

\


56. (C)
We know that incentre is equidistant from the three sides of the triangle.
(0, 0) is equidistance from three given lines. Therefore in centre = (0, 0)

57. (B)
For x
2
+ y
2
+ 2x = 0, c
1
(-1, 0), r
1
= 1, for x
2
+ y
2
6x = 0, c
2
(3, 0), r
2
= 3
point of contact of circle ( )
3 3
E , 0 3, 0
1 3
| | +
= =
|

\
, Angle between the tangent from (-3, 0) to the
circle x
2
+ y
2
+ 2x = 0 is = 2 tan
1

1
3 9 0 6
| |

= |
|
+
\
and c
1
c
2
= r
1
+ r
2
.
Therefore the common tangents from an equilateral triangle and they touch each other externally. The
assertion A is correct and reason is also correct, but R is not the correct explanation of A.

Comprehension 1:

58. (B)

AC AB = =
CD = sin and OD = cos
Therefore AD = 1 cos
Therefore area of trapezoid ABCD = y
2
(AB + CD) AD

2
( sin ) (1 cos )
( sin ) sin
2 2
+
= = +

59. (A)
Q O
P R
A
B
C

D


ABQ and DCQ are similar, so
AB AQ AQ
CD DQ AQ AD
= =

( )
AQ
sin AQ 1 cos

=

or,
( ) 1 cos
AQ
sin

=



60. (D)

( )
0 0 0 0
1 cos
1 cos sin 2sin cos
lim AQ lim lim lim 3
sin 1 cos sin
+ + + +


+ +
= = = =



Comprehension 2:
61. (C)
Differentiating both the sides of (1), we get
dy dy
f (x y) 1 f (x) f (y) f (x) f (y)
dx dx

+ + = +
`
)

Above holds for all x, y, so
dy
0
dx
=
f (x y) f (x) f (y) + =

62. (B)
Put x = 0, we get f (y) = f(y) = f (0) f(y)

f (x)
f (0) 2 y
f (y)

= =

63.
2x 2x
x 0 x 0
f (x) f ( x) e e
lim lim 2 ( 2) 4
x x

= = =



Match the following:

64. A Q, B Q, C Q, D S
A) g(x) can be defined as g(x) =
f (x), 2 x 1
1, 1 x0 0
0, 0 x 2
f (x), 2 x 3
<

<

<

or
g(x) =
2
2
x 2x, 2 x 1
1, 1 x 0
0, 0 x 2
x 2x, 2 x 3
+ <

<

<

clearly g(x) is discontinuous at x = 0
g(x) is not differentiable at x = 0, 2
g(x) has no extremum and absolute maximum value = f(3) = 3

65. A R, B S, C P, D Q
A) we have -1 x 1 and x x
2
0 0 x 1, curve has two branches
y = sin
-1
x
2
x x and lies between x = 0 and x = 1
desired area =
1
1 1
2 2
1 2
0 0 0
2x 1
y y dx 2 x x dx 2 x x
4
(
= =
(


+ ( )
1 1
0
2
sin 2x 1 |
8 4

=
B) If x + y 0 and x y 0, then
1
x 2
2

If x + y 0 and x y < 0, then
1
y 2
2


-2
-1
0
1
2 3
C D
x + y = 0
y x = 0
A
B
Q
R S
P
x
y
2
2
1
2
1
2


If x + y < 0 and x y > 0 then
1
2 y
2

If x + y < 0 and x y < 0 then
1
2 x
2

Desired are =
( ) ( )
2 2
2 2 2 6 =


C) Area, A = ( ) ( )
2
ax 2 x 3

(
+

2 3
ax x
dx 5x
2 3

(
= +
(


= ( ) ( ) ( )
2 2
a 1
5
2 3
(
+ + + +
(


, are roots of x
2
ax 5 = 0 + = a, = -5

2
2
a 10
A a 20
6 3
(
= + +
(

, which is minimum if a = 0

D) on solving two equations we get x = 0, x =
2
k
(say)
1 k
=
+

So, the area A =
2
2
0
x
x kx dx
k

| |

|
\

2 3 3 2
k 2
A 3 2k
2 3 3k 6 k
| |
=
|
\

=
( )
2 2 2
2 2 2
2
2k 2 k
3
6 1 k 1 k
6 1 k
(
=
(
+ +
+

Clearly it altains its maximum when k = 1




66. A Q, B S, C R, D P
A) Let D, E, F be the mid point then EF
2
=
2
BC
4
BC
2
= 4 (b
2
+ c
2
)
Similarly AB
2
= 4 (a
2
+ b
2
) and AC
2
4 (a
2
+ c
2
)
A
B D
C
E
F


2 2 2
2 2 2
AB BC CA
8
a b c
+ +
=
+ +


B) The image (x
1
, y
1
, z
1
) is given by
1 1
x 1 y 2 z 3 2
(1 2 3 5)
1 1 1 3
+
= = = +

1 1 1
(x , y , z ) (3, 4, 5) =
desired distance = 50 5 2 =

C) D.R. of edge OA are 1, 0, 0 and D.R. of diagonal OP are 1, 1, 1

1
cos tan 2
3
= =
B
y
O
p
C
z
x
A

x
y
(0, 2)
y = ax + 2
x
y
ky = x
2
y = x kx
2

O


D) we have
3 1
p
2 2
3
1 1 0
2
1
1 q
2
= and p + 1 + q = 0

4pq 4p 5q + 5 = 0 and p + 1 + q = 0
Eliminating p, we get q = -3,
3
4