Professional Documents
Culture Documents
=
( ) ( )
1 2
1 3
2
0.62 kd D d v v D e =
Note: mass transfer coefficient is the value averaged over the length
Dissolution rate of a spinning disc
A solid disc of benzoic acid 2.5 cm in diameter is
spinning at 20 rpm and 25
o
C. The diffusion
coefficients are 1.00 x 10
-5
cm
2
/sec in water and
0.233 cm
2
/ sec in air. The solubility of benzoic
acid in water is 0.003 g/cm
3
; Its equilibrium vapor
pressure is 0.30 mm Hg.
How fast will it dissolve in a large volume of water?
How vast will it dissolve in a large volume of air?
22
Dissolution rate of a spinning disc
23
Correlation for spinning
disc
Example: Gas scrubbing with a wetted-wall column
Air containing a water-soluble vapor is flowing up
and water is flowing down in the experimnental
column . The water flow iin te 0.07-cm-thick film is
3 cm/sec the column diameter is 10 cm, and the air
is essentially well-mixed right up to the interface.
The diffusion coefficient in water of the absorbed
vapor is 1.8 x 10
-5
cm
2
/s.
How long a column is needed to reach a gas
concentration in water that is 10% of saturation?
24
Example: Measuring stomach flow
We want to estimate the average flow in the stomach
by measuring the dissolution rate of a non-
absorbing solute present as a large spherical pill.
From in vitro experiments, we know that this pills
dissolution is accurately described with a mass
transfer coefficient.
How can we do this estimate.
25
Example: Glucose uptake by red blood cells
The uptake of glucose across the red blood cell membrane
has a maximum rate ranging from 0.1 to 5 mole/cm
2
-hr.
Apparently, these differences result from differences in
experimental conditions. Assume that a typical experiment is
made in a beaker containing 100 cm
3
of red blood cells
suspended in 1 liter of plasma. The beaker is stirred with a
1/50 hp motor. The cells originally contain little glucose. At
time zero, radioactively tagged glucose is added and its
uptake measured. The diffusion coefficient of glucose is
about 6 x 10
-6
cm
2
/s, and the plasma viscosity is
approximately that of water.
Using the correlation for liquid drops, estimate the effect of
mass transfer in the bulk to see when it could have
affected these uptake rates.
26
Dimensional Analysis
Method developed by Bridgeman, (1922) and
Becker (1976)
Done when existing correlations are inadequate
27
Example: Aeration
Oxygen is injected into an aqueous solution and the
steadystate oxygen concentration in the bulk is
measured as a function of position in the bed using
oxygen-selective electrodes. Different experiments
are done by varying the bubble velocity , the
solution density , viscosity , the entering bubble
diameter d, and the depth of the bed L.
Using dimensional analysis, derive the form of the
expression to correlate the mass transfer coefficient
with the variables mentioned above.
28
Example: Artificial Kidney
An artificial kidney is basically a long tubular
membrane where blood flowing through it is dialyzed
against a well-stirred saline solution outside the tube.
Toxins in the blood diffuse across the membrane into the
saline solution, thus purifying the blood. This dialysis is
often slow. To increase the rate of toxin removal, the
agitation rate of the saline solution is increased and the
membrane made as thin as possible.
After reducing these mass transfer effects to almost
negligible, we can correlate the mass transfer
coefficient as a function of blood flow , tube size d,
density and viscosity.
29
Mass Transfer Across Interfaces
30
hot benzene
cool water
INITIAL CONDITIONS
FINAL CONDITIONS AFTER ALLOWING EQUILIBRATION
warm benzene
warm water
benzene w
bromine
water w
bromine
equal bromine
concentrations
higher conc Br in
benzene
lower conc Br in
water
low conc Br in
air
high conc Br in
water
higher conc Br in
air
lower conc Br in
water
Mass Transfer Across Interfaces
31
Mass Transfer Across Interfaces
32
Mass Transfer Across Interfaces
33
Concentration Profiles for Mass Transfer Across a Gas-
Liquid Interface
34
The flux in the gas is:
N
1
=k
p
(p
10
-p
1i
)
Because the interfacial
region is thin it is at steady
state then the flux will be
equal to that in the liquid.
N
1
=k
L
(c
1i
-c
10
)
GAS LIQUID
p
10
c
10
c
1i
p
1i
Flux
The Overall Mass Transfer Coefficient
35
So the flux N
1
should be derived as:
The Overall Mass Transfer Coefficient
36
( )
*
1 10 1
*
1 10
1
1
p
p
p L
N K p p
K
k H k
p Hc
=
=
+
=
( )
*
1 1 10
*
10
1
1
1 1
L
L
L p
N K c c
K
k Hk
p
c
H
=
=
+
=
Flux of specie 1
Overall mass transfer
coefficient
equilibrium relation
overall based on
Liquid
concentrations
overall based on
Gas
concentrations
The Overall Mass Transfer Coefficient
37
There are two limiting cases of interest:
a highly soluble gas (H<<1):
a sparingly soluble gas (H>>1):
p p
K = k
L L
K = k
Oxygen Mass Transfer
38
5 2
3
2.1 10 /
0.01 0.01 18
L
L
D x cm s mol
k
cm cm cm
| |
= =
|
\ .
4 2
1.2 10 /
L
k x mol cm s
=
Oxygen Mass Transfer
39
Benzene mass transfer
40
Estimate the overall liquid-side mass transfer
coefficient in the distillation of benzene and toluene.
At the concentrations used, you expect a temperature
of 90
o
C and at equilibrium
y*=0.70x
1
+0.39
The molar volume of the liquid is about 97cm3/mol.
Assume that the thickness in the liquid is 0.01cm and
0.1cm in the gas.
Perfume extraction
41
Reading Assignment
42
Overall mass transfer coefficients in packed tower
Theories of mass transfer
Film theory
Penetration theory
Surface-renewal theory