Chemistry, Thermodynamics MCQs Questions: Paper - 1

Sr.
No.
Questions Answers
1. Standard enthalpy of vapourisation
vap
H

for water at
100 C is 40.66 kJmol
1
. he internal ener!y of
vapourisation of water at 100C "in kJmol
1
# is
"$ssume water vapour to %ehave like an ideal !as# [CBSE
AIPMT 2012]
(A) &4'.(6
(B) &40.66
(C) &'(.)6
(D) 4'.(6
Answer: (C)
*. he enthalpy of fusion of water is 1.4') k+al,mol. he
molar entropy +han!e for the meltin! of i+e at 0C
is [CBSE AIPMT 2012]
(A) ).*60 +al,"mol -#
(B) 0.)*6 +al,"mol -#
(C) 10.)* +al,"mol -#
(D) *1.04 +al,"mol -#
Answer: (A)
'. Consider the rea+tion .
N!
2(")
# !
2(")
2N
2
!
$(")
% &
r
' ( )111*+.
/f 0
*
1
)"s#
is formed instead of 0
*
1
)"!#
in the a%ove rea+tion2
the 3
r
H value will %e.
"!iven2 3H of su%limation for 0
*
1
)
is )4 kJ mol
1
# [AIEEE
2011]
(A) *14 kJ
(B) 16) kJ
(C) & )4 kJ
(D) & *14 kJ
Answer: (A)
4. 5ased on the 6rst law of thermodynami+s2 whi+h one of
the followin! is +orre+t7 [,-rn-t-*- CET 2011]
(A) 8or an isothermal pro+ess2 9 : &w
(B) 8or an iso+hori+ pro+ess2 3; : 9
(C) 8or an adia%ati+ pro+ess2 3; : w
(D) 8or a +y+li+ pro+ess2 9 : w
Answer: (D)
). he amount of the heat released when *0 ml 0.) < 0a1H
is mi=ed with 100 ml 0.1 < HCl is = kJ. he heat of
neutrali>ation is [.est Ben"-/ +EE 2011]
(A) 100 = kJ,mol
(B) )0 = kJ,mol
(C) & 100 = kJ,mol
(D) &)0 = kJ,mol
Answer: (A)
6. he %ond ener!y "in k+al mol
1
# of a C?C sin!le %ond is
appro=imately [IIT +EE 2010]
(A) 1
(B) 10
(C) 100
(D) 1000
Answer: (C)
(. he spe+ies whi+h %y de6nition has @AB1 standard molar
enthalpy of formation at *4C - is [IIT +EE 2010]
(A) 5r
*
"!#
(B) Cl
*
"!#
(C) H
*
1"!#
(D) CH
4
"!#
Answer: (B)
C. he standard enthalpy of formation of 0H
'
is 46.0 kJ mol

Answer: (C)
1
. /f the enthalpy of formation of H
*
from its atoms is 4'6
kJ mol
1
and that of 0
*
is (1* kJ mol
1
2 the avera!e %ond
enthalpy of 0 ? H %ond is 0H
'
is [AIEEE 2010]
(A) 110* kJ mol
1
(B) 464 kJ mol
1
(C) &')* kJ mol
1
(D) &10)6 kJ mol
1
4. he amount of heat evolved when )00 +m
'
of 0.1 < HCl is
mi=ed with *00 +m
'
of 0.* < 0a1H is DDDDDD. [,-rn-t-*-
CET 2010]
(A) 1.*4* kJ
(B) *.*4* kJ
(C) '.'4* kJ
(D) 0.*4* kJ
Answer: (B)
10. /n a +onstant volume +alorimeter2 '.) ! of a !as with
mole+ular wei!ht *C was %urnt in e=+ess o=y!en at *4C.0
-. he temperature of the +alorimeter was found to
in+rease from *4C.0 - to *4C.4) - due to the +om%ustion
pro+ess. Eiven that the heat +apa+ity of the +alorimeter is
*.) kJ -
F1
2 the numeri+al value for the enthalpy of
+om%ustion of the !as in kJ mol
F1
is [IIT +EE 2000]
(A) '
(B) (
(C) C
(D) 4
Answer: (D)
11. /f one mole of ammonia and one mole of hydro!en
+hloride are mi=ed in a +losed +ontainer to form
ammonium +hloride !as2 then[,-rn-t-*- CET 2001]
(A) 3H G 3u
(B) 3H : 3u
(C) 3H H 3u
(D) there is no relationship
Answer: (C)
1*. Ihi+h of the followin! is an intensive
property7 [,-rn-t-*- CET 2002]
(A) temperature
(B) surfa+e tension
(C) vis+osity
(D) all of these
Answer: (D)
1'. $n ideal !as is allowed to e=pand %oth reversi%ly and
irreversi%ly in an isolated system. /f
i
is the initial
temperature and
f
is the 6nal temperature2 whi+h of the
followin! statements is +orre+t7 [AIEEE 2003]
(A) "
f
#
irrev
G "
f
#
rev
(B)
f
G
i
for reversi%le pro+ess %ut
f
:
i
for irreversi%le
pro+ess
(C) "
f
#
rev
: "
f
#
irrev
(D)
f
:
i
for %oth reversi%le and irreversi%le pro+esses
Answer: (A)
14. he standard enthalpy of formation "3
f
H# at *4C - for
methane2 CH
4
"!#2 is (4.C kJ mol
1
. he additional
information re9uired to determine the avera!e ener!y for
C H %ond formation would %e[AIEEE 2003]
(A) the disso+iation ener!y of H
*
and enthalpy of
su%limation of +ar%on
(B) latent heat of vapori>ation of methane
(C) the 6rst four ioni>ation ener!ies of +ar%on and ele+tron
!ain enthalpy of hydro!en
(D) the disso+iation ener!y of hydro!en mole+ule2 H
*
Answer: (A)
1). he temperature of the system .de+reases in an
DDDDDD. [,-rn-t-*- CET 200$]
Answer: (D)
(A) adia%ati+ +ompression
(B) isothermal e=pansion
(C) isothermal +ompression
(D) adia%ati+ e=pansion
Chemistry, Thermodynamics MCQs Questions: Paper 2
Sr.
No.
Questions Answers
1. /dentify the +orre+t statement from the followin! in a
+hemi+al rea+tion. [.est Ben"-/ +EE 2012]
(A) he entropy always in+reases
(B) he +han!e in entropy alon! with suita%le +han!e in
enthalpy de+ides the fate of a rea+tion
(C) he enthalpy always de+reases
(D) 5oth the enthalpy and the entropy remain +onstant
Answer: (B)
*. 8or the reversi%le rea+tion2
$
"s#
& 5
"!#
C
"!#
& J
"!#
3E : ')0kJ2
whi+h one of the followin! statements is
true7 [,-rn-t-*- CET 2011]
(A) he rea+tion is thermodynami+ally nonKfeasi%le.
(B) he entropy +han!e is ne!ative.
(C) A9uili%rium +onstant is !reater than one.
(D) he rea+tion should %e instantaneous.
Answer: (C)
'. he enthalpy of vapori>ation of %en>ene is &').' kJ,mol at
its %oilin! point of C0C. he entropy +han!e in the
transition of vapour to li9uid at its %oilin! point is DDDDDD.
"in J mol
F1
-
F1
#[,-rn-t-*- CET 2011]
(A) F100
(B) &100
(C) &'4*
(D) F'4*
Answer: (A)
4. he entropy +han!e involved in the isothermal reversi%le
e=pansion of * moles of an ideal !as from a volume of 10
dm
'
to a volume of 100 dm
'
at *(C is [AIEEE 2011]
(A) 4*.' J mol
1
-
1
(B) 'C.' J mol
1
-
1
(C) ').C J mol
1
-
1
(D) '*.' J mol
1
-
1
Answer: (B)
). /n view of the si!ns of 3
r
E for the followin! rea+tions
L%1
*
& L% * L%12 3
r
E H 0
Sn1
*
& Sn * Sn12 3
r
E G 02
Ihi+h o=idation states are more +hara+teristi+ for lead and
tin7[AIEEE 2011]
(A) 8or lead &*2 for tin &4
(B) 8or lead &42 for tin &*
(C) 8or lead &*2 for tin &*
(D) 8or lead &42 for tin &4
Answer: (A)
6. he Ei%%s ener!y for the de+omposition $l
*
1
'
at )00C is
as follows.
$l
*
1
'
$l & 1
*
2 3
r
E : &466kJ mol
1
he potential diMeren+e needed for ele+trolyti+ redu+tion
of $l
*
1
'
at )00C is at least [AIEEE 2010]
(A) ).0 N
(B) 4.) N
Answer. (D)
(C) '.0 N
(D) *.) N
(. 8or a parti+ular reversi%le rea+tion at temperature 2 3H
and 3S were found to %e %oth &ve. /f
e
is the temperature
at e9uili%rium2 the rea+tion would %e spontaneous
when [AIEEE 2010]
(A) :
e
(B)
e
G
(C) G
e
(D)
e
is ) times
Answer. (C)
C. 1n the %asis of the followin! thermo+hemi+al data.
(&45'
#
(-6)
( 0)
H
*
1"l# H
&
"a9# & 1H
F
"a9#O 3H : )(.'* kJ
H
*
"!# & 1
*
"!# H
*
1"l# 3H : F*C6.*0kJ
he value of enthalpy of formation of 1H
F
ion at *)C
is . [AIEEE 2000]
(A) F**.CC kJ
(B) F**C.CC kJ
(C) &**C.CC kJ
(D) F'4'.)* kJ
Answer: (B)
4. /n a fuel +ell methanol is used as fuel and o=y!en !as is
used as an o=idi>er. he rea+tion is
CH
'
1H"l# & 1
*
"!# C1
*
"!# & *H
*
1"l#
$t *4C - standard Ei%%Ps ener!ies of formation for
CH
'
1H"l#2 H
*
1"l# and C1
*
"!# are 166.*2 *'(.* and '44.4
kJ mol
1
respe+tively. /f standard enthalpy of +om%ustion of
methanol is (*6 kJ mol
1
2 eQ+ien+y of the fuel +ell will
%e [AIEEE 2000]
(A) C(R
(B) 40R
(C) 4(R
(D) C0R
Answer (C)
10. 1ne mole of whi+h of the followin! has the hi!hest
entropy7[,-rn-t-*- CET 2001]
(A) li9uid nitro!en
(B) hydro!en !as
(C) mer+ury
(D) diamond
Answer: (B)
11. Ihen +ompared to 3E for the formation of $l
*
1
'
2 the 3E
for the formation of Cr
*
1
'
is [,-rn-t-*- CET 2001]
(A) hi!her
(B) lower
(C) same
(D) unpredi+ted
Answer: (A)
1*. Standard entropy of S
*
2 T
*
and ST
'
are 602 40 and
)0J-
F1
mol
F1
2 respe+tively.
8or the rea+tion2 S
*
& T
*
ST
'
2 3H : '0kJ2 to %e at
e9uili%rium2 the temperature will %e [AIEEE 2001]
(A) 1*)0 -
(B) )00 -
(C) ()0 -
(D) 1000 -
Answer: (C)
1'. Antropy of the universe is [,-rn-t-*- CET 2002]
(A) +ontinuously in+reasin!
Answer: (A)
(B) +ontinuously de+reasin!
(C) >ero
(D) +onstant
14. /n whi+h of the followin! pro+ess2 a ma=imum in+rease in
entropy is o%served7 [,-rn-t-*- CET 2002]
(A) dissolution of salt in water
(B) +ondensation of water
(C) su%limation of naphthalene
(D) meltin! of i+e
Answer: (C)
1). 3H
vap
: '0 -J,mole and 3S
vap
: () Jmol
1
-
1
. 8ind
temperature of vapour2 at one atmosphere [IIT +EE 200]
(A) 400-
(B) ')0 -
(C) *4C -
(D) *)0 -
Answer: (A)