Piñuna 5

Final Report
of
Reservoir Fluid Study

for
VETRA Exploracin y Produccin Colombia S.A.

Piua Field
Piua-5 Well
A Product of
PENCOR Advanced Fluid Studies
RFL 2010-36721
8-Oct-2010
The analyses, opinions or interpretations in this report are based upon observations and material supplied by the client to whom, and for
whose exclusive and confidential use, this report has been made. The interpretations or opinions expressed represent the best judgement
of Core Laboratories. Core Laboratories and its officers and employees assume no responsibility and make no warranty or representations,
express or implied, as to the productivity, proper operation or profitability of any oil, gas, coal or any other mineral, property, well or sand
formation in connection with which such report is used or relied upon for any reason whatsoever.
6316 Windfern Rd. Houston, Texas 77040, USA

Tel: 713-328-2673 Fax: 713-328-2697 Web: http://www.corelab.com
Core Laboratories, LP
Pencor Advanced Fluid Studies
6316 Windfern Rd,
Houston, TX. USA 77040
Fax: 713-328-2697
Tel: 713-328-2674
Web: http://www.corelab.com
October 8th, 2010

Carrera 7 No. 71-52
Torre A Piso 10
Bogot, Colombia
Attention : Eng. Javier Aguillon
Subject:
Field:
Well:
File:
Reservoir Fluid Study

Piua
Piua-5
2010-36721
Dear Eng. Aguillon;

A series of bottom-hole reservoir fluid samples were collected from the subject well on
June 26, 2010 by Core Laboratories representatives. The samples were received by our
Pencor Advanced Fluid Studies Laboratory in Houston, USA on September 14, 2010.
Initial sample validation and quality control procedures commenced upon receipt, and the
laboratory received approval to perform the Reservoir Fluid / PVT study on the selected
sample on September 23, 2010.
The final report containing the data for the completed laboratory study is presented in the
following pages.
It has been a pleasure to be of service to VETRA Exploracin y Produccin Colombia S.A.
Should any questions arise or if we may be of further service in any way, please do not
hesitate to contact us.
Sincerely,
David McEvoy
Project Manager
PENCOR Advanced Fluid Studies Laboratory

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Table of Contents
Section A - Summary of Analysis Methods and PVT Data
Page
Summary of analysis methods......................................................................................... A.1-A.2

Summary of PVT Data....................................................................................................
A.3
Section B - Summary of Samples Received and Validation Data

Well and sampling information........................................................................................
B.1
Summary of samples received........................................................................................
B.2
Section C - Compositional Analysis of Bottom-hole Reservoir Fluid Sample

Compositional analysis of bottom-hole sample to C36+................................................... C.1-C.2
Section D- Constant Composition Expansion (CCE)
Constant composition expansion data at 203 F............................................................... D.1-D.2
Graphs of constant composition expansion data at 203 F...............................................
D.3
Section E - Differential Vaporization (DV)

Differential vaporization data............................................................................................
E.1
Graphs from differential vaporization................................................................................
E.2
Produced gas and residual liquid compostions from differential vaporization....................
E.3-E.5
Differential vaporization data converted to production separator conditions......................
E.6
Section F - Separator Test Data

Data from separator test..................................................................................................
F.1
Compositional analysis of produced gases and stocktank oil from separator test.............
F.2-F.4
Section G - Reservoir Fluid Viscosity Data

Reservoir fluid viscosity at 203 F....................................................................................
G.1
Section H - Appendix
Data used in gas compositional calculations....................................................................
H.1
Data used in liquid compositional calculations..................................................................
H.2
___________________________________________________________________________________________
Core Laboratories LP

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section A - Summary of Analysis Methods and PVT Data
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Summary of Analyses Methods

Sample Validation
The visual bubble point pressure at reservoir temperature, and free water content, were
measured as initial quality checks for each bottomhole sample. The visual bubble point is
obtained by charging a small volume of sample to a PVT cell, and quickly lowering the pressure
until the first gas bubble is observed. The results for the two samples showed good agreement.
The sample is checked for the presence of free water, which is drained and the volume
measured. The entrained water content was determined by Karl Fischer titration.
Based on the sample evaluations, cylinder no. 818386 was selected for full PVT analysis.
Heat Treatment
The selected sample cylinder was heated to the reservoir temperature of 203 F prior to
subsampling to avoid potential wax deposition problems and ensure representative sample
transfers at all stages of testing.
Pressurized Fluid Composition
Approximately 25 cc of pressurized fluid was flashed to atmospheric pressure at 120 F and
separated into its respective gas and oil phases. The evolved gas and residual liquid were
analyzed separately, using gas-liquid chromatography and recombined on a weight basis to
produce a C36+ weight percent composition.
Gas Compositions
Gas compositions were measured using a "one shot" Varian 3800 gas analyzer using method
GPA 2286. The gas chromatograph utilizes 3 columns to clearly identify all the eluted
components from N2, CO2 and C1 through C11+.
The chromatograph is calibrated weekly using air and synthetic hydrocarbon gas with a known
composition. The resultant calibration data is checked statistically against previous calibrations
prior to performing analyses on unknown samples.
Liquid Composition
Residual / stocktank liquid composition were measured using a Varian 3600 chromatograph.
The gas chromatograph utilizes a cold on column, "sandwich injection" technique to ensure that
a representative sample is injected and swept onto the column. The sample is run twice; first
the original fluid and then the fluid spiked with n-tetradecane. This allows the laboratory to take
into account any heavy end (C36+) losses that may have occurred during the chromatographic
run, and make an accurate correction prior to reporting the liquid composition. The data
obtained from the gas chromatograph is in weight %. Calculations to mole% and the plus
fractions properties are described later.
The chromatograph is checked daily, using a gravimetric n-paraffin mix containing a range of
pure components from C8 through C36 and a synthetic gas-oil mix (D2887) with a known
composition. The resultant calibration data is checked statistically against previous calibrations
prior to perform analyses on unknown samples.
___________________________________________________________________________________________
A.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Summary of Analyses Methods, continuation

Calculation of Mole% Compositions and Plus Fraction Properties
The residue or stocktank liquid whole sample molecular weight and density are measured using
a cryscope and a PAAR densimeter respectively.
The mole% data is calculated using GPSA mole weight and density data, where individual
components are identified from carbon dioxide through decanes. Katz and Firoozabadi data are
used from undecanes through pentatriacontanes. The residue mole weight and density values
are calculated so that the pseudo average mole weight and density are the same as the
measured values. This can lead to anomalous residue mole weights and densities where the
Katz and Firoozabadi values may not be suitable for the isomer groups detected.
Constant Composition Expansion
A portion of the reservoir fluid sample was charged to a high pressure visual cell at reservoir
temperature. A constant composition expansion was carried out during which the bubble point
pressure at reservoir temperature, and pressure-volume data for the single phase and two
phase fluid, were determined. The density of the single phase fluid was measured via an Anton
Paar high-pressure densitometer connected directly to the cell at 5000 psig. Density data for
other pressures were calculated using the data from the pressure-volume relationship.
Differential Vaporization
The differential vaporization test was carried out in a high pressure visual cell at reservoir
temperature. Beginning with the fluid sample in a single-phase state above the measured
saturation pressure, the pressure was lowered to the first depletion stage pressure and
thoroughly equilibrated. The evolved gas was displaced from the cell and its volume,
compressibility, gravity and molar composition were measured. This process was repeated at
successively lower pressure stages until the last stage was reached. The final stage was
carried out at atmospheric pressure when the residual liquid was pumped out of the cell and its
volume, density, molecular weight and composition were measured.
Separator Test
A single-stage separator test was carried out using a pressurized test separator cell. A portion
of the recombined reservoir fluid sample was charged to the cell and stabilized at the pressure
and temperature required for the first stage of separation. The gas evolved was pumped out of
the cell and the volume and composition were measured. The final (stocktank) stage was
carried out at atmospheric pressure and 60F and the density and composition of the residual
liquid were determined.
Reservoir Fluid Viscosity
Live-oil viscosity was measured in an electromagnetic viscometer at reservoir temperature.
Viscosity determinations were carried out over a wide range of pressures from above the
reservoir pressure to atmosheric pressure.
The measurements were repeated at each pressure stage until five or more results agreed to
within 0.5%. The densities, obtained from the constant composition expansion and differential
vaporization tests, were used in the calculation of viscosities in centipoise.
___________________________________________________________________________________________
A.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Summary of Laboratory Data
Constant Composition Expansion of Reservoir Fluid at 203 F

Saturation pressure (bubble-point)
942 psig
Average single phase compressibility

(From 3485 psig to 942 psig)
8.07
Density at saturation pressure
x 10 -6 psi-1
0.7996 g cm-3
Differential Vaporization at 203 F

Solution gas-oil ratio at saturation pressure
262 scf/bbl of residual oil at 60F
Relative oil volume at saturation pressure
1.216 vol / vol of residual oil at 60F
Density of residual oil
0.8983 g cm-3 at 60F
Separator Test Data

Pressure
(psig)
Temperature
(F)
Formation Volume
Factor
(Bl sat/bbl)
Total Solution Stocktank Oil

Gas-oil ratio Density at 60 F
(scf/bbl)
(g cm-3)
942
203
1.163
45
100
168
60
23
191
0.8899
Reservoir Fluid Viscosity at 203 F

Viscosity at reservoir pressure
2.129 centipoise at 3485 psig
Viscosity at saturation pressure
Viscosity at atmospheric pressure
___________________________________________________________________________________________
A.3

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section B - Summary Of Samples Received And Validation Data
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Reported Well and Sampling Information

Reservoir and well information
Field...................................................................... Piua
Well....................................................................... Piua-5
Reservoir Fluid...................................................... Black Oil
Formation.............................................................. Villeta (U Sand)
Current Reservoir Pressure .................................. 3500 psia
Reservoir Temperature.......................................... 203 F
Installation............................................................. *
DST....................................................................... *
Perforated Interval ................................................ 9,508 - 9,524 ft.; 9,544 - 9,558 ft.;
9,574 - 9,580 ft.
Sampling information
Date sampled........................................................
Time sampled .......................................................
Type of samples....................................................
Sampling company................................................
Sampling Depth....................................................
26-Jun-10
12:00
BHS
Core Laboratories
7,650 ft.
Choke.................................................................... *
Status of well......................................................... Pumping (ESP)
Bottomhole pressure.............................................. 3283 psia at sampling depth
Bottomhole temperature........................................ 230 F at sampling depth (estimated)
Wellhead pressure................................................. *
Wellhead temperature........................................... *
Separator pressure ............................................... *
Separator temperature .......................................... *
Pressure base........................................................ 14.7 psia
Temperature base ................................................ 60 F
Separator gas rate.................................................
Separator oil rate ..................................................
Water flowrate.......................................................
Gas gravity (Air = 1)..............................................
Supercompressibility factor....................................
H2S.......................................................................
BS&W...................................................................
API Oil Gravity .....................................................
*
*
*
*
*
*
*
*
Comments:
* Data not provided to Core Laboratories
___________________________________________________________________________________________
B.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Summary of Samples Received

Bottomhole samples
Sample Cylinder
number number
Sampling
pressure
Temp.
(psia)
(F)
Laboratory visual
bubble point
Pressure
Temp.
(psig)
(F)
Water
recovered
(cc)
Sample
volume
(cc)
Entrained
Water
Content
(%)
1.1
818408
3283
230 *
820
203
600
4.15
1.2
818386
3283
230 *
840
203
600
3.03
Notes:
* The temperature at sampling depth is estimated.
The samples were subjected to a dehydration procedure consisting of 48 hours of thermal cycling.
Following this period subsamples were removed and measured for entrained water content.
Cylinder 818408 was reduced to a 0.76 wt. % water content and cylinder 818386 was reduced to
0.05 wt. %.
Sample cylinder number 818386 was selected for PVT analysis.
___________________________________________________________________________________________
B.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section C - Compositional Analysis of Bottom-hole Reservoir Fluid Sample
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Bottomhole Sample to C36 plus
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
Methyl-Cyclopentane
Benzene
Cyclohexane
C7
Heptanes
Methyl-Cyclohexane
Toluene
C8
Octanes
EthylBenzene
M/P-Xylene
O-Xylene
C9
Nonanes
TrimethylBenzene
C10 Decanes
C11 Undecanes
C12 Dodecanes
C13 Tridecanes
C14 Tetradecanes
C15 Pentadecanes
C16 Hexadecanes
C17 Heptadecanes
C18 Octadecanes
C19 Nonadecanes
C20 Eicosanes
C21 Heneicosanes
C22 Docosanes
C23 Tricosanes
C24 Tetracosanes
C25 Pentacosanes
C26 Hexacosanes
C27 Heptacosanes
C28 Octacosanes
C29 Nonacosanes
C30 Triacontanes
C31 Hentriacontanes
C32 Dotriacontanes
C33 Tritriacontanes
C34 Tetratriacontanes
C35 Pentatriacontanes
C36+ Hexatriacontanes +
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6
Totals :
Mole %
0.00
0.00
1.59
1.02
13.86
4.33
7.95
1.72
4.20
0.02
2.00
1.93
2.55
1.06
0.17
0.42
2.85
1.07
0.47
3.31
0.47
0.48
0.28
2.87
0.32
3.21
2.95
2.59
2.96
2.38
2.35
1.95
1.79
1.90
1.80
1.34
1.23
1.14
1.06
0.98
0.93
0.82
0.82
0.76
0.76
0.72
0.68
0.58
0.54
0.51
0.48
7.83
_____
100.000
Weight %
0.00
0.00
0.37
0.15
1.19
0.70
1.88
0.53
1.31
0.01
0.77
0.74
1.17
0.48
0.07
0.19
1.53
0.56
0.23
2.02
0.26
0.27
0.16
1.97
0.20
2.45
2.32
2.23
2.77
2.41
2.59
2.32
2.27
2.55
2.54
1.97
1.91
1.87
1.81
1.73
1.71
1.57
1.65
1.57
1.63
1.61
1.57
1.39
1.32
1.30
1.24
32.94
_____
100.000
___________________________________________________________________________________________
C.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Bottomhole Sample to C36 plus
Calculated Residue Properties
C7 plus
Mole %
Mole Weight (g mol-1)
Density at 60F (g cm-3)
58.83
290
0.9047
C11 plus
Mole %
41.85
361
0.9323
C20 plus
Mole %
21.18
519
0.9788
C36 plus
Mole %
Molecular Weight (g mol-1)
7.83
786
1.0617
Calculated Whole Sample Properties

Average mole weight (g mol-1)
187
0.8444
___________________________________________________________________________________________
C.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section D- Constant Composition Expansion (CCE)
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Constant Composition Expansion at 203F

Single-phase Fluid Properties
Saturation pressure (bubble-point pressure)
942 psig
Average single phase compressibility

(From 3485 psig to 942 psig)
8.07 x 10 -6 psi-1
Density at saturation pressure
0.7996 g cm-3
Mean Single-phase Compressibilities

Pressure Range
Initial Pressure
(psig)
Final Pressure
(psig)
Mean
Compressibility
(psi-1) (1)
5000
4000
6.51
x 10 -6
4000
3000
7.01
x 10 -6
3000
2000
7.71
x 10 -6
2000
942
8.84
x 10 -6
(1) Mean compressibility = (V2-V1) / [(V1+V2)/2] x 1/(P1 - P2)
___________________________________________________________________________________________
D.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Constant Composition Expansion at 203F

Pressure
(psig)
Relative
Volume (1)
Density
(g cm-3)
Instantaneous
Compressibility
(psi-1 x 10-6) (2)
5000
4500
4000
3485
3000
2500
2000
1500
1300
1100
1000
942
939
935
931
927
924
920
905
885
857
806
724
610
472
337
290
248
216
193
175
159
146
135
127
0.9699
0.9730
0.9762
0.9797
0.9831
0.9868
0.9907
0.9949
0.9967
0.9985
0.9994
1.0000
1.0011
1.0025
1.0039
1.0053
1.0064
1.0079
1.0136
1.0216
1.0335
1.0581
1.1071
1.2034
1.3995
1.7856
2.0199
2.3152
2.6268
2.9211
3.2102
3.5262
3.8370
4.1491
4.4114
0.8245
0.8218
0.8191
0.8162
0.8134
0.8104
0.8072
0.8037
0.8023
0.8008
0.8001
0.7996
6.31
6.51
6.74
7.01
7.31
7.69
8.17
8.77
9.06
9.38
9.54
Reservoir pressure
Saturation pressure
Y-Function (3)
2.851
2.756
2.613
2.417
2.190
2.098
2.009
1.935
1.877
1.829
1.784
1.746
1.712
1.686
(1) Relative Volume = V / Vsat ie. volume at indicated pressure per volume at saturation pressure.
(2) Instantaneous compressibility = (V2-V1) / V1 x 1/(P1-P2)
(3) Y-function = (Psat - P ) / ((Pabs)(V/Vsat - 1)).
___________________________________________________________________________________________
D.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Graphs of Constant Composition Expansion Data

Relative Volume vs Pressure
1.005
Relative Volume, V/Vsat
1.000
0.995
0.990
0.985
0.980
0.975
0.970
0.965
0
1000
2000
3000
4000
5000
6000
Pressure (psig)
Y Function vs Pressure
3.000
2.500
Y-Function
2.000
1.500
1.000
0.500
0.000
0
100
200
300
400
500
600
700
800
900
Pressure (psig)
___________________________________________________________________________________________
D.3

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section E - Differential Vaporization (DV)
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Differential Vaporization at 203F
Pressure
(psig)
Solution
Gas-Oil
Ratio
Rs(1)
Relative
Oil
Volume
Bod(2)
Relative
Total
Volume
Btd(3)
942
800
600
400
200
100
0
262
238
205
168
121
87
0
1.216
1.207
1.193
1.177
1.156
1.135
1.065
1.216
1.295
1.474
1.878
3.239
6.057
At 60F =
Density
(g cm-3)
Deviation
Factor
(Z)
0.7996
0.8021
0.8061
0.8111
0.8167
0.8235
0.8432
0.908
0.918
0.931
0.952
0.969
Gas
Formation
Volume
Factor (4)
Incremental
Gas Gravity
(Air = 1.000)
Saturation Pressure
0.02089
0.823
0.02797
0.851
0.04208
0.904
0.08309
1.049
0.15838
1.281
1.902
1.000
Residual Oil Properties

0.8983
API
25.9
g cm-3 at 60F
(1) GOR in cubic feet of gas at 14.696 psia and 60F per barrel of residual oil at 60F.
(2) Volume of oil at indicated pressure and temperature per volume of residual oil at 60F.
(3) Volume of oil plus liberated gas at indicated pressure and temperature per volume of residual oil at 60F.
(4) Volume of gas at indicated pressure and temperature per volume at 14.696 psia and 60F.
___________________________________________________________________________________________
E.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Graphs of Differential Vaporization

Solution Gas-Oil Ratio v Pressure
300
Gas-Oil Ratio (scf / bbl)
250
200
150
100
50
0
0
100
200
300
400
500
600
700
800
900
1000
800
900
1000
Pressure (psig)
Relative Oil Volume v Pressure

1.250
Relative Oil Volume (V/Vr)
1.200
1.150
1.100
1.050
1.000
0
100
200
300
400
500
600
700
Pressure (psig)
___________________________________________________________________________________________
E.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Differential Vaporization Gases to C11+

Sample I.D.
Test Stage
Stage Pressure (psig)
1
800
2
600
3
400
4
200
5
100
6
0
0.00
0.00
4.58
10.34
66.37
7.42
6.81
0.91
1.72
0.01
0.59
0.43
0.37
0.08
0.00
0.04
0.14
0.04
0.01
0.07
0.00
0.00
0.00
0.04
0.00
0.02
0.01
_____
100.00
0.00
0.00
5.10
7.26
65.34
8.70
8.22
1.11
2.11
0.01
0.68
0.52
0.42
0.10
0.01
0.05
0.16
0.05
0.01
0.08
0.00
0.00
0.00
0.05
0.00
0.02
0.00
_____
100.00
0.00
0.00
5.77
4.09
61.73
10.83
10.77
1.45
2.74
0.01
0.77
0.66
0.53
0.13
0.01
0.06
0.19
0.06
0.01
0.10
0.01
0.00
0.00
0.06
0.00
0.02
0.00
_____
100.00
0.00
0.00
6.32
1.51
49.42
14.63
17.05
2.45
4.71
0.02
1.26
1.00
0.73
0.18
0.02
0.09
0.28
0.08
0.02
0.13
0.01
0.00
0.00
0.06
0.00
0.02
0.01
_____
100.00
0.00
0.00
5.77
0.40
30.89
17.87
26.05
4.01
7.94
0.04
2.32
1.85
1.35
0.33
0.03
0.17
0.48
0.14
0.03
0.21
0.01
0.01
0.00
0.08
0.00
0.02
0.00
_____
100.00
0.00
0.00
1.59
0.04
4.33
9.64
31.63
7.64
18.74
0.09
7.72
6.66
5.69
1.46
0.16
0.69
1.94
0.53
0.15
0.76
0.05
0.03
0.02
0.29
0.01
0.12
0.09
_____
100.00
0.851
0.904
1.049
1.281
1.902
Component (Mole%)
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
1,2,4-TMB
C10
Decanes
C11+ Undecanes plus
Totals :
Calculated Gas Properties

Gas Gravity
(Air = 1.000)
0.823
Note: 0.00 means less than 0.005.
___________________________________________________________________________________________
E.3

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Differential Vaporization Residue to C36+
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30
C31
C32
C33
C34
C35
C36+
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
Heptanes
M-C-Hexane
Toluene
Octanes
E-Benzene
M/P-Xylene
O-Xylene
Nonanes
1,2,4-TMB
Decanes
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes
Hexatriacontanes plus
Mole %
0.00
0.00
0.00
0.00
0.00
0.02
0.50
0.35
1.31
0.00
1.21
1.36
2.70
1.30
0.21
0.50
3.89
1.57
0.70
4.94
0.71
0.75
0.43
4.48
0.50
5.07
4.73
4.16
4.74
3.82
3.82
3.14
2.88
3.06
2.90
2.14
2.00
1.86
1.75
1.57
1.49
1.37
1.27
1.24
1.21
1.17
1.10
0.96
0.90
0.81
0.76
12.65
_____
Weight %
0.00
0.00
0.00
0.00
0.00
0.00
0.08
0.07
0.27
0.00
0.31
0.35
0.84
0.40
0.06
0.15
1.40
0.56
0.23
2.03
0.27
0.29
0.17
2.07
0.22
2.59
2.50
2.41
2.98
2.61
2.83
2.51
2.46
2.76
2.75
2.12
2.09
2.04
2.00
1.87
1.84
1.76
1.71
1.73
1.75
1.75
1.71
1.53
1.49
1.38
1.33
35.73
_____
Totals :
100.00
100.00
___________________________________________________________________________________________
E.4

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Differential Vaporization Residue to C36+

C7+
Mole%
92.55
295
0.9061
C11+
Mole%
67.50
361
0.9316
C20+
Mole%
34.25
518
0.9775
C36+
Mole %
12.65
786
1.0593

Density at 60F (g cm-3) [Measured]
API
278
0.8983
25.9
___________________________________________________________________________________________
E.5

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Differential Vaporization Data Converted to Production Separator Conditions
Pressure
(psig)
Oil
Density
(g cm-3)
5000
4500
4000
3485
3000
2500
2000
1500
1300
1100
1000
942
800
600
400
200
100
0.8244
0.8218
0.8191
0.8162
0.8133
0.8103
0.8071
0.8037
0.8023
0.8008
0.8001
0.7996
0.8021
0.8061
0.8111
0.8167
0.8235
Reservoir pressure
Saturation pressure
Solution
Gas/Oil
(scf / bbl)
Rs(1)
Formation
Volume
Factor
Bo(1)
Gas Formation
Volume
Factor
Bg(2)
191
168
137
102
56
24
1.128
1.132
1.135
1.139
1.143
1.148
1.152
1.157
1.159
1.161
1.162
1.163
1.154
1.141
1.126
1.105
1.085
0.02089
0.02797
0.04208
0.08309
0.15838
Notes:
(1) Differential data corrected to surface separator conditions of :Stage 1
Stage 2
45 psig and 100F

0 psig and 60F
Rs = Rsfb - (Rsdb - Rsd) x (Bofb / Bodb)

Bo = Bod x (Bofb/Bodb)
(2) Volume of gas at indicated pressure and temperature per volume at 14.696 psia and 60F.
___________________________________________________________________________________________
E.6

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section F - Separator Test Data
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Separator Test Data
Pressure
(psig)
Temperature
(F)
Gas-Oil
Ratio
Oil
Density
(g cm-3)
(1)
Gas-Oil
Ratio
Rsfb
(2)
Formation
Volume
Factor
Bofb (3)
Separation Gas Gravity

Volume
of flashed gas
Factor
(Air = 1.000)
(4)
1.163
Saturation Pressure
942
203
191
0.7996
45
0
100
60
164
23
168
23
0.8736
0.8899
1.027
1.000
1.040
1.421
Residual Oil Properties **

0.8899
API gravity
27.3
g cm-3 at 60F
Note :
* Evolved gas collected and analyzed to C10+.
** Stocktank oil collected and analyzed to C36+.
(1) GOR in cubic feet of gas at 14.696 psia and 60F per barrel of oil at indicated pressure and temperature.
(2) GOR in cubic feet of gas at 14.696 psia and 60F per barrel of stocktank oil at 60F.
(3) Volume of saturated oil at 942 psig and 203F per volume of stocktank oil at 60F.
(4) Volume of oil at indicated pressure and temperature per volume of stocktank oil at 60F.
___________________________________________________________________________________________
F.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Separator Test Gases to C10+

Sample I.D.
Test Stage
Stage Pressure (psig)
Component (Mole%)
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
C7
Heptanes
M-C-Hexane
Toluene
C8
Octanes
E-Benzene
M/P-Xylene
O-Xylene
C9
Nonanes
C10+ Decanes plus
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6
Totals :
1
45
2
0
0.00
0.00
4.87
3.20
49.54
12.92
18.49
2.56
5.05
0.02
1.17
1.00
0.56
0.16
0.02
0.07
0.14
0.06
0.02
0.09
0.00
0.00
0.00
0.04
0.02
_____
100.00
0.00
0.00
4.23
0.27
17.98
18.20
35.80
5.70
10.68
0.05
2.89
2.07
1.17
0.26
0.02
0.11
0.30
0.08
0.03
0.11
0.00
0.00
0.00
0.04
0.01
_____
100.00
1.040
1.421
Calculated Gas Properties

Gas Gravity
(Air = 1.000)
Note: 0.00 means less than 0.005.
___________________________________________________________________________________________
F.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Stocktank Oil to C36+
H2
H2S
CO2
N2
C1
C2
C3
iC4
nC4
C5
iC5
nC5
C6
C7
C8
C9
C10
C11
C12
C13
C14
C15
C16
C17
C18
C19
C20
C21
C22
C23
C24
C25
C26
C27
C28
C29
C30
C31
C32
C33
C34
C35
C36+
Component
Hydrogen
Hydrogen Sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
Hexanes
M-C-Pentane
Benzene
Cyclohexane
Heptanes
M-C-Hexane
Toluene
Octanes
E-Benzene
M/P-Xylene
O-Xylene
Nonanes
1,2,4-TMB
Decanes
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes
Hexatriacontanes plus
Mole %
0.00
0.00
0.00
0.00
0.02
0.25
2.48
1.07
3.35
0.00
2.16
2.16
3.45
1.52
0.24
0.55
4.19
1.59
0.67
4.88
0.67
0.69
0.40
4.23
0.52
4.63
4.30
3.73
4.28
3.43
3.42
2.81
2.57
2.74
2.57
1.94
1.78
1.64
1.54
1.40
1.33
1.22
1.12
1.09
1.06
1.02
0.97
0.85
0.79
0.72
0.67
11.29
_____
Weight %
0.00
0.00
0.00
0.00
0.00
0.03
0.43
0.25
0.76
0.00
0.61
0.61
1.17
0.50
0.07
0.18
1.65
0.61
0.24
2.19
0.28
0.29
0.17
2.13
0.25
2.58
2.48
2.35
2.94
2.55
2.76
2.44
2.39
2.70
2.65
2.10
2.03
1.96
1.92
1.82
1.80
1.72
1.65
1.66
1.68
1.67
1.64
1.47
1.42
1.33
1.28
34.59
_____
Totals :
100.00
100.00
___________________________________________________________________________________________
F.3

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Compositional Analysis of Stocktank Oil to C36+

C7+
Mole%
85.06
288
0.9028
C11+
Mole%
60.28
360
0.9305
C20+
Mole%
30.43
517
0.9764
C36+
Mole %
11.29
783
1.0569

Density at 60F (g cm-3) [Measured]
API
255
0.8899
27.3
___________________________________________________________________________________________
F.4

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section G - Reservoir Fluid Viscosity Data
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Reservoir Fluid Viscosity Data at 203F

Pressure
(psig)
Oil
Viscosity
(cP)
5000
4000
3485
3000
2000
1500
1000
942
800
600
400
200
100
0
2.411
2.225
2.129
2.037
1.846
1.748
1.648
1.637
1.826
2.054
2.259
2.534
2.831
4.544
Reservoir pressure
Saturation pressure
Calculated
Gas Viscosity
(cP) (1)
Oil/Gas
Viscosity
Ratio
0.0139
0.0133
0.0127
0.0119
0.0109
131.755
154.039
177.260
213.858
259.783
Reservoir Fluid Viscosity v Pressure at 203F
5.00
4.50
4.00
Viscosity (cP)
3.50
3.00
2.50
2.00
1.50
1.00
0.50
0.00
0
1000
2000
3000
4000
5000
6000
Pressure (psig)
(1) Calculated using the method of Lee, Gonzales and Eakin, JPT, Aug 1966.
___________________________________________________________________________________________
G.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Section H - Appendix
___________________________________________________________________________________________

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Data Used in Gas Compositional Calculations

Component
Hydrogen
Oxygen/(Argon)
Nitrogen (Corrected)
Methane
Carbon Dioxide
Ethane
Hydrogen Sulphide
Propane
i-Butane
n-Butane
Neo-Pentane
i-Pentane
n-Pentane
22DMC4
23DMC4/CYC5
2MC5
3MC5
Hexanes (nC6)
22DMC5
M-C-Pentane
24DMC5
223TMC4
Benzene
Mole Weight
Density
Component
(g mol-1) (g cm-3 at 60F)
*
**
**
**
**
**
**
**
**
**
*
**
**
*
*
*
*
*
*
*
*
*
*
2.016
31.999
28.013
16.043
44.010
30.070
34.080
44.097
58.123
58.123
72.15
72.150
72.150
86.18
78.16
86.18
86.18
86.18
100.20
84.16
100.20
100.20
78.11
N/A
1.1410
0.8086
0.2997
0.8172
0.3558
0.8006
0.5065
0.5623
0.5834
0.5968
0.6238
0.6305
0.6529
0.7129
0.6572
0.6682
0.6631
0.6814
0.7533
0.6757
0.6947
0.8820
33DMC5
Cyclohexane
2MC6/23DMC5
11DMCYC5/3MC6
t13DMCYC5
c13DMCYC5/3EC5
t12DMCYC5
Heptanes (nC7)
22DMC6
MCYC6
ECYC5
223TMC5/24&25DMC6
ctc124TMCYC5
ctc123TMCYC5
Toluene
Octanes (nC8)
E-Benzene
M/P-Xylene
O-Xylene
Nonanes (nC9)
Decanes
Undecanes
Dodecanes
Mole Weight
Density
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
*
***
***
***
100.20
84.16
100.20
99.20
98.19
99.20
98.19
100.20
114.23
98.19
98.19
114.23
112.21
112.21
92.14
114.23
106.17
106.17
106.17
128.26
134
147
161
0.6954
0.7827
0.6917
0.7253
0.7528
0.7262
0.7554
0.6875
0.6994
0.7740
0.7704
0.7060
0.7511
0.7574
0.8734
0.7063
0.8735
0.8671
0.8840
0.7212
0.778
0.789
0.800
Data Source Refs :

* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.
** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas,
GPA 2145-96.
*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.
Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.
Note :
The gas mole % compositions were calculated from the measured weight % compositions using the
most detailed analysis results, involving as many of the above components as were identified. The
reported component mole % compositions were then sub-grouped into the generic carbon number
components.
___________________________________________________________________________________________
H.1

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Data Used in Oil Compositional Calculations

Component
Hydrogen
Hyd. sulphide
Carbon Dioxide
Nitrogen
Methane
Ethane
Propane
i-Butane
n-Butane
i-Pentane
n-Pentane
Hexanes
Me-cyclo-pentane
Benzene
Cyclo-hexane
Heptanes
Me-cyclo-hexane
Toluene
Octanes
Ethyl-benzene
Meta/Para-xylene
Ortho-xylene
Nonanes
1-2-4-T-M-benzene
Decanes
Mole Weight
Density
Component
*
**
**
**
**
**
**
**
**
**
**
**
*
*
*
**
*
*
**
*
*
*
**
*
**
2.016
34.080
44.010
28.013
16.043
30.070
44.097
58.123
58.123
72.150
72.150
86.177
84.16
78.11
84.16
100.204
98.19
92.14
114.231
106.17
106.17
106.17
128.258
120.19
142.285
N/A
0.8006
0.8172
0.8086
0.2997
0.3558
0.5065
0.5623
0.5834
0.6238
0.6305
0.6634
0.7533
0.8820
0.7827
0.6874
0.7740
0.8734
0.7061
0.8735
0.8671
0.8840
0.7212
0.8797
0.7334
Undecanes
Dodecanes
Tridecanes
Tetradecanes
Pentadecanes
Hexadecanes
Heptadecanes
Octadecanes
Nonadecanes
Eicosanes
Heneicosanes
Docosanes
Tricosanes
Tetracosanes
Pentacosanes
Hexacosanes
Heptacosanes
Octacosanes
Nonacosanes
Triacontanes
Hentriacontanes
Dotriacontanes
Tritriacontanes
Tetratriacontanes
Pentatriacontanes
Mole Weight
Density
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
***
147
161
175
190
206
222
237
251
263
275
291
305
318
331
345
359
374
388
402
416
430
444
458
472
486
0.789
0.800
0.811
0.822
0.832
0.839
0.847
0.852
0.857
0.862
0.867
0.872
0.877
0.881
0.885
0.889
0.893
0.896
0.899
0.902
0.906
0.909
0.912
0.914
0.917
Data Source Refs :

* ASTM Data Series Publication DS 4B (1991) - Physical Constants of Hydrocarbon and Non-Hydrocarbon
Compounds.
** GPA Table of Physical Constants of Paraffin Hydrocarbons and Other Components of Natural Gas
GPA 2145-96.
*** Journal of Petroleum Technology, Nov 1978, Pages 1649-1655.
Predicting Phase Behaviour of Condensate/Crude Oil Systems Using Methane Interaction Coefficients
- D.L. Katz & A. Firoozabadi.
Note :
The residue mole weight and density values ( eg heptanes plus, undecanes plus, eicosanes plus) are
calculated so that the calculated average mole weights and densities correspond with the measured
values. This can lead to anomalous residue mole weights and densities where the Katz and
Firoozabadi values may not be suitable for the isomer groups detected.
___________________________________________________________________________________________
H.2

Piua-5
Well
RFL 2010-36721
___________________________________________________________________________________________
Report prepared by
Report approved by
David McEvoy
Project Manager
Richard M. (Rikki) Fyfe

Operations Manager
___________________________________________________________________________________________

Piñuna 5

Uploaded by

Document Information

Original Description:

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Piñuna 5

Uploaded by

Copyright:

Available Formats

Final Report

Reservoir Fluid Study

VETRA Exploracin y Produccin Colombia S.A.

PENCOR Advanced Fluid Studies

6316 Windfern Rd. Houston, Texas 77040, USA

October 8th, 2010

Reservoir Fluid Study

Dear Eng. Aguillon;

VETRA Exploracin y Produccin Colombia S.A.

Summary of analysis methods......................................................................................... A.1-A.2

Section B - Summary of Samples Received and Validation Data

Summary of samples received........................................................................................

Section C - Compositional Analysis of Bottom-hole Reservoir Fluid Sample

Section E - Differential Vaporization (DV)

Graphs from differential vaporization................................................................................

Produced gas and residual liquid compostions from differential vaporization....................

Differential vaporization data converted to production separator conditions......................

Section F - Separator Test Data

Section G - Reservoir Fluid Viscosity Data

Data used in liquid compositional calculations..................................................................

VETRA Exploracin y Produccin Colombia S.A.

Section A - Summary of Analysis Methods and PVT Data

VETRA Exploracin y Produccin Colombia S.A.

Summary of Analyses Methods

VETRA Exploracin y Produccin Colombia S.A.

Summary of Analyses Methods, continuation

VETRA Exploracin y Produccin Colombia S.A.

Summary of Laboratory Data

Constant Composition Expansion of Reservoir Fluid at 203 F

Average single phase compressibility

Density at saturation pressure

Differential Vaporization at 203 F

262 scf/bbl of residual oil at 60F

Relative oil volume at saturation pressure

1.216 vol / vol of residual oil at 60F

Density of residual oil

0.8983 g cm-3 at 60F

Separator Test Data

Total Solution Stocktank Oil

Reservoir Fluid Viscosity at 203 F

2.129 centipoise at 3485 psig

Viscosity at saturation pressure

1.637 centipoise at 942 psig

Viscosity at atmospheric pressure

4.544 centipoise at 0 psig

VETRA Exploracin y Produccin Colombia S.A.

Section B - Summary Of Samples Received And Validation Data

VETRA Exploracin y Produccin Colombia S.A.

Reported Well and Sampling Information

VETRA Exploracin y Produccin Colombia S.A.

Summary of Samples Received

VETRA Exploracin y Produccin Colombia S.A.

Section C - Compositional Analysis of Bottom-hole Reservoir Fluid Sample

VETRA Exploracin y Produccin Colombia S.A.

VETRA Exploracin y Produccin Colombia S.A.

Calculated Whole Sample Properties

VETRA Exploracin y Produccin Colombia S.A.

Section D- Constant Composition Expansion (CCE)

VETRA Exploracin y Produccin Colombia S.A.

Constant Composition Expansion at 203F

Average single phase compressibility

Density at saturation pressure