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Q.1 The electronic configuration of four elements are given in brackets
L(1s
2
, 2s
2
2p
1
); M(1s
2
, 2s
2
2p
5
); Q(1s
2
, 2s
2
2p
6
, 3s
1
); R(1s
2
, 2s
2
2p
2
)
The element that would most readily form a diatomic molecule is
[1] Q [2] M [3] R [4] L
Q.2 The electronic configuration of four elements L, P, Q and R are given in brackets
L (1s
2
, 2s
2
2p
4
); Q(1s
2
, 2s
2
2p
6
, 3s
2
3s
5
); P(1s
2
, 2s
2
2p
6
, 3s
1
): R(1s
2
, 2s
2
2p
6
, 3s
2
)
The formulae of ionic compounds that can be formed between these elements are
[1] L
2
P, RL, PQ and R
2
Q [2] LP, RL, PQ and RQ
[3] P
2
L, RL, PQ and RQ
2
[4] LP, R
2
L, P
2
Q and RQ
Q.3 In the following which bond will be responsible for maximum value of hydrogen bond
[1] O H [2] NH [3] SH [4] FH
Q.4 Which compound is highest covalent
[1] LiCl [2] LiF [3] LiBr [4] LiI
Q.5 In BeCl
2
, which type of hybridization is present in beryllium atom
[1] sp [2] sp
2
[3] sp
3
[4] sp
3
d
Q.6 In the following metals which one has lowest probable interatomic forces
[1] Copper [2] Silver [3] Zinc [4] Mercury
Q.7 Contrary to other hydrogen halides, hydrogen fluoride is a liquid because
[1] Size of F atom is small [2] HF is weak acid
[3] HF molecule are hydrogen bonded [4] Fluorine is highly reactive
Q.8 In the following which molecule or ion possesses electrovalent, covalent and coordinate bond at the
same time
[1] HCl [2] NH
4
+
[3] Cl

[4] H
2
O
2
Q.9 The nature of bonding in graphite is
[1] Covalent [2] Ionic [3] Metallic [4] Coordinate
Q.10 In the following which species does not contain sp
3
hybridization
[1] NH
3
[2] CH
4
[3] H
2
O [4] CO
2
Q.11 As a result of sp hybridization, we get
[1] Two mutual perpendicular orbitals [2] Two orbitals at 180
[3] Four orbitals in tetrahedral directions [4] Three orbitals in the same plane
Q.12 The reason for exceptionally high boiling point of water is
[1] Its high specific heat [2] Its high dielectric constant
[3] Low ionization of water molecules [4] Hydrogen bonding in the molecules of water
Q.13 Which one in the following is not the resonance structure of CO
2
[1] O = C = O [2]

O C O
+
[3]
+
O C O

[4] O C = O
Q.14 The bond in the formation of fluorine molecule will be
[1] Due to s-s overlapping [2] Due to s-p overlapping
[3] Due to p-p overlapping [4] Due to hybridization
Exercise
CHEMICAL BONDING
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Q.15 An atom of sodium loses one electron and chlorine atom accepts one electron. This result the formation
of sodium chloride molecule. This type of molecule will be
[1] Coordinate [2] Covalent [3] Electrovalent [4] Metallic bond
Q.16 Silicon carbide (SiC) is
[1] Ionic solid [2] Molecular solid [3] Covalent solid [4] Metallic solid
Q.17 Which type of overlapping results the formation of a bond
[1] Axial overlapping of s-s orbitals [2] Lateral overlapping of p-p orbitals
[3] Axial overlapping of p-p orbitals [4] Axial overlapping of s-p orbitals
Q.18 For the formation of covalent bond, the difference in the value of electronegativities should be
[1] Equal to or less than 1.7 [2] More than 1.7
[3] 1.7 or more [4] None of these
Q.19 The valency of carbon is four. On what principle it can be explained in a better way
[1] Resonance [2] Hybridization [3] Electron transfer [4] None of the above
Q.20 Which type of compounds show high melting and boiling points
[1] Electrovalent compounds [2] Covalent compounds
[3] Coordinate compounds
[4] All the three types of compounds have equal melting and boiling points
Q.21 Each of the following pairs of chemical species will combine. Which of the following combination is
best explained by the coordinate covalent bond
[1] H
2
+ I
2
[2] Mg +
1
2
O
2
[3] Cl + Cl [4] H
+
+ H
2
O
Q.22 Select the compound from the following which dissolves in water
[1] CCl
4
[2] CS
2
[3] CHCl
3
[4] C
2
H
5
OH
Q.23 Bond order is a concept in the molecular orbital theory. It depends on the number of electrons in
the bonding and anti bonding orbitals. Which of the following statements is true about it ? The bond
order
[1] Can have a negative quantity
[2] Has always an integral value
[3] Can assume any positive or integral or fractional value including zero
[4] Is a non zero quantity
Q.24 Electrovalent compounds do not have
[1] High M.P. and Low B.P. [2] High dielectric constant
[3] High M.P. and High B.P. [4] High polarity
Q.25 The dipole moment of chlorobenzene is 1.73D. The dipole moment of p-dichlorobenzene is expected
to be
[1] 3.46 D [2] 0.00 D [3] 1.73 D [4] 1.00 D
Q.26 The bond order of NO molecule is
[1] 1 [2] 2 [3] 2.5 [4] 3
CHEMICAL BONDING
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Q.27 When two atomic orbitals combine they form
[1] One molecular orbital [2] Two molecular orbital
[3] Three molecular orbital [4] Four molecular orbital
Q.28 The shape of H
3
O
+
ion is
[1] Linear [2] Angular [3] Trigonal planar [4] Triangular pyramidal
Q.29 Compound formed by sp
3
d hybridization will have structure
[1] Planar [2] Pyramidal [3] Angular [4] Trigonal bipyramidal
Q.30 Which of the molecules is of V-shaped
[1] SO
2
[2] C
2
H
2
[3] SnCl
4
[4] CO
2
Q.31 Which of the following statement is not correct
[1] Hybridization is the mixing of atomic orbitals prior to their combining into molecular orbitals
[2] sp
2
hybrid orbitals are formed from two p atomic orbitals and one s atomic orbital
[3] d
2
sp
3
hybrid orbitals are directed towards the corners of a regular octahedron
[4] dsp
3
hybrid orbitals are all at 90 to one another
Q.32 The structure of [Cu(H
2
O)
4
]
++
ion is
[1] Square planar [2] Tetrahedral [3] Distorted rectangle [4] Octahedral
Q.33 Molecular orbital theory was developed mainly by
[1] Pauling [2] Pauling and Slater [3] Mulliken [4] Thomson
Q.34 The bond order of a molecule is given by
[1] The difference between the number of electrons in bonding and anti bonding orbitals
[2] Total number of electrons in bonding and anti bonding orbitals
[3] Twice the difference between the number of electrons in bonding and anti bonding electrons
[4] Half the difference between the number of electrons in bonding and anti bonding electrons
Q.35 Oxygen molecule is paramagnetic because
[1] Bonding electrons are more than anti bonding electrons
[2] Contains unpaired electrons
[3] Bonding electrons are less than anti bonding electrons
[4] Bonding electrons are equal to anti bonding electrons
Q.36 The bond order in N
2
+
ion is
[1] 1 [2] 2 [3] 2.5 [4] 3
Q.37 In which of the following the central atom does not use sp
3
hybrid orbitals in its bonding
[1] BeF
3

[2] OH
3
+
[3] NH
2

[4] NF
3
Q.38 The sp
3
d
2
hybridisation of the central atom of a molecule would lead to
[1] Square planar geometry [2] Tetrahedral geometry
[3] Trigonal bipyramidal geometry [4] Octahedral geometry
CHEMICAL BONDING
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Q.39 Which of the following occurs when two hydrogen atoms bond with each others
[1] Potential energy is lowered [2] Kinetic energy is lowered
[3] Electronic motion ceases [4] Energy is absorbed
Q.40 XeF
2
involves hybridisation
[1] sp
3
[2] sp
3
d [3] sp
3
d
2
[4] None of these
Q.41 A set of molecular orbitals which is degenerate
[1]
y
2p and
x
2p [2]
y
2p and
z
x
2p [3]
y
2p and
z
2p [4] 1s and 2s
Q.42 Which molecular orbital in N
2
has least energy
[1] 2p
y
[2] 2p
z
[3] 2s [4]
x
2p
x
Q.43 Which molecule has the highest bond order
[1] N
2
[2] Li
2
[3] He
2
[4] O
2
Q.44 The molecular electronic configuration of H
2

ion is
[1] (1s)
2
[2] (1s)
2
(
x
1s)
2
[3] (1s)
2
(
x
1s)
1
[4] (1s)
3
Q.45 Octahedral molecular shape exists in ............hybridisation
[1] sp
3
d [2] sp
3
d
2
[3] sp
3
d
3
[4] None of these
Q.46 Energy required to dissociate 4gm of gaseous hydrogen into free gaseous atoms is 208 kcal at 25C.
The bond energy of H-H bond wilsl be
[1] 104 kcal [2] 10.4 kcal [3] 1040 kcal [4] 1.04 kcal
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 2 3 4 4 1 4 3 2 1 4 2 4 4 3 3 3 2 1 2 1
Qus. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 4 4 3 1 2 3 2 4 4 1 4 1 3 4 2 3 1 4 1 2
Qus. 41 42 43 44 45 46
Ans. 3 3 1 3 2 1
Ans Ans Ans Ans Ans w ww ww er K er K er K er K er K e ee ee y yy yy
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Q.1 Which of the following compounds is not linear : [CPMT 1996]
[1] SnCl
2
[2] HCl [3] CO
2
[4] HgCl
2
Q.2 Electrovalent compounds are : [CPMT 1996]
[1] Good conductor of electricity [2] Polar in nature
[3] Low M.P. and low B.P. [4] Easily available
Q.3 Atomic number of an element is 26. The element shows : [CPMT 1996]
[1] Ferromagnetism [2] Diamagnetism [3] Paramagnetism [4] None of these
Q.4 Among the following compounds, the one that is polar and has the central atom with sp
2
hybridisation
is : [IIT 1997]
[1] H
2
CO
3
[2] SiF
4
[3] BF
3
[4] HClO
2
Q.5 Which one of the following is having zero dipole moment : [RPMT 1997]
[1] CCl
4
[2] CH
3
Cl [3] CH
3
F [4] CHCl
3
Q.6 The correct order towards bond angle is : [RPMT 1997]
[1] sp < sp
2
< sp
3
[2] sp
2
< sp < sp
3
[3] sp
3
< sp
2
< sp [4] Bond angle does not depend on hybridisation
Q.7 Which bond is strongest : [RPMT 1997]
[1] FF [2] BrF [3] ClF [4] IF
Q.8 Which compound has dipole moment : [RPMT 1997]
[1] CCl
4
[2] BF
3
[3] CO
2
[4] NH
3
Q.9 Which has weakest bond : [RPMT 1997]
[1] Diamond [2] Neon (Solid) [3] KCl [4] Ice
Q.10 Which has a coordinate bond : [RPMT 1997]
[1]
2
3
SO [2] CH
4
[3] CO
2
[4] NH
3
Q.11 The geometry and the type of hybrid orbital present about the central atom in BF
3
is :
[IIT 98; BHU 01]
[1] Linear, sp [2] Trigonal planar, sp
2
[3] Tetrahedral, sp
3
[4] Pyramidal, sp
3
Q.12 Asserti on : The electronic structure of O
3
is
O
+1
O
O
1
[IIT 1998]
Reason :
O
O O
structure is not allowed because octet around O cannot be expanded.
[1] Both assertion and reason are correct and reason is the correct explanation of assertion
[2] Both assertion and reason are correct but reason is not the correct explanation of assertion
[3] Assertion is correct but reason is incorrect
[4] Assertion is incorrect but reason is correct
Q.13 Which of the following have both polar and nonpolar bonds : [AIIMS 1997]
[1] C
2
H
6
[2] NH
4
Cl [3] HCl [4] AlCl
3
Q.14 Which of the following is not paramagnetic : [AIIMS 1997]
[1] S
2
[2] N
2

[3] O
2

[4] NO
Entrance Exam Questions
CHEMICAL BONDING
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Q.15 Which one of the following shows bond in silica : [CPMT 1997]
[1] SiOSiOSi
| | |
[2] SiCSiOSi [3] SiCSiCSi [4] SiSiSiSi
Q.16 The number of electrons shared by each outer most shell of N
2
is : [AFMC 1998]
[1] 2 [2] 3 [3] 4 [4] 5
Q.17 Ethanol and dimethyl ether form a pair of functional isomers. The boiling point of ethanol is higher
than that of dimethyl ether due to the presence of : [AIIMS 1998]
[1] Hydrogen bonding in ethanol [2] Hydrogen bonding in dimethyl ether
[3] CH
3
group in ethanol [4] CH
3
group in dimethyl ether
Q.18 When the hybridisation state of carbon atom changes from sp
3
to sp
2
to sp, the angle between the
hybridised orbitals : [AIIMS 1998]
[1] Decreases gradually [2] Increases gradually
[3] Decreases considerably [4] All of these
Q.19 The compound containing coordinate bond is : [AFMC 1999]
[1] O
3
[2] SO
3
[3] H
2
SO
4
[4] All of these
Q.20 CO
2-
3
anion has which of the following characteristics : [Roorkee 1999]
[1] Bonds of unequal length [2] sp
2

hybridization of C atom
[3] Resonance stabilization [4] Same bond angles
Q.21 The correct order of dipole moment is : [Roorkee 1999]
[1] CH
4
< NF
3
< NH
3
< H
2
O [2] NF
3
< CH
4
< NH
3
< H
2
O
[3] NH
3
< NF
3
< CH
4
< H
2
O [4] H
2
O < NH
3
< NF
3
< CH
4
Q.22 Which of the following hydrides are ionic : [Roorkee 1999]
[a] CaH
2
[b] BaH
2
[c] SrH
2
[d] BeH
2
Correct answer is
[1] a,b,c [2] a,b,c,d [3] b,c [4] b,c,d
Q.23 Highest melting point would be of : [RPMT 1999]
[1] He [2] CsCl [3] NH
3
[4] CHCl
3
Q.24 Maximum covalent character is associated with the compound : [RPMT 1999]
[1] NaI [2] MgI
2
[3] AlCl
3
[4] AII
3
Q.25 According to Fajjans rule, covalent bond is favoured by : [AIIMS 1999]
[1] Large cation and small anion [2] Large cation and large anion
[3] Small cation and large anion [4] Small cation and small anion
Q.26 Asserti on (A) : A resonance hybrid is always more stable than any of its canonical structures.
Reason (R) : This stability is due to delocalization of electrons [AIIMS 1999]
[1] Both A and R are true and R is a correct explanation of A
[2] Both A and R are true but R is not a correct explanation of A
[3] A is true but R is false
[4] Both A and R are false
Q.27 Asserti on (A) : Bond order can assume any value number including zero [AIIMS 1999]
Reason (R) : Higher the bond order, shorter is bond length and greater is bond energy
[1] Both A and R are true and R is a correct explanation of the A
[2] Both A and R are true but R is not a correct explanation of the A
[3] A is true but R is false
[4] Both A and R are false
CHEMICAL BONDING
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Q.28 Asserti on (A) : Ortho nitrophenol molecules are associated due to the presence of intermolecular
hydrogen bonding while paranitrophenol involves intramolecular, hydrogen bonding
Reason (R) : Ortho nitrophenol is more volatile than the para nitrophenol [AIIMS 1999]
[1] Both A and R are true and R is a correct explanation of A
[2] Both A and R are true but R is not a correct explanation of A
[3] A is true but R is false
[4] A is false but R is true
Q.29 Which compound does not possess linear geometry [RPET1999]
[1] CH
2
= CH
2
[2] HC CH [3] BeCl
2
[4] CO
2
Q.30 Which of the following molecule does not show tetrahedral shape [RPET1999]
[1] CCl
4
[2] SiCl
4
[3] SF
4
[4] CF
4
Q.31 Which molecule does not show zero dipole moment [RPET1999]
[1] BF
3
[2] NH
3
[3] CCl
4
[4] CH
4
Q.32 The shape of CH
3
+
species is [RPET1999]
[1] Tetrahedral [2] Square planar [3] Trigonal planar [4] Linear
Q.33 Hybridisation state of chlorine in ClF
3
is [RPET1999]
[1] sp
3
[2] sp
3
d [3] sp
3
d
2
[4] sp
3
d
3
Q.34 Pyramidal shape would be of [RPET1999]
[1] NO
3

[2] H
2
O [3] H
3
O
+
[4] NH
4
+
Q.35 Which of the following exhibits the weakest intermolecular forces [AIIMS1999]
[1] He [2] HCl [3] NH
3
[4] H
2
O
Q.36 The hybridization of atomic orbitals of nitrogen in NO
2
+
, NO
3

and NH
4
+
are [IIT 2000]
[1] sp, sp
3
and sp
2
respectively [2] sp, sp
2
and sp
3
respectively
[3] sp
2
, sp and sp
3
respectively [4] sp
2
, sp
3
and sp respectively
Q.37 Molecular shapes of SF
4
, CF
4
and XeF
4
are [IIT 2000]
[1] The same with 2, 0 and 1 lone pairs of electrons respectively
[2] The same, with 1, 1 and 1 lone pairs of electrons respectively
[3] Different, with 0,1 and 2 lone pairs of electrons respectively
[4] Different, with 1,0 and 2 lone pairs of electrons respectively
Q.38 The dipole moment of diatomic molecule AB is 0.98 D and its experimental value is 1.4 D. The covalent
character of molecule is
[1] 20 [2] 10 [3] 30 [4] 70
Q.39 In which of the following pairs the two molecules have identical bond order [MPPMT 2000]
[1] N
2
, O
2
2+
[2] N
2
, O
2

[3] N
2

, O
2
[4] O
2
+
, N
2
Q.40 Which of the following is not conduct electricity in the fused state [Roorkee 2000]
[1] BeCl
2
[2] MgCl
2
[3] SrCl
2
[4] BaCl
2
Q.41 The order of dipole moments of the following molecules is [Roorkee 2000]
[1] CHCl
3
> CH
2
Cl
2
> CH
3
Cl > CCl
4
[2] CH
2
Cl
2
> CH
3
Cl > CHCl
3
> CCl
4
[3] CH
3
Cl > CH
2
Cl
2
> CHCl
3
> CCl
4
[4] CH
2
Cl
2
> CHCl
3
> CH
3
Cl > CCl
4
Q.42 How many -bonds are there in a nitrogen molecule [RPMT 2000]
[1] One [2] Two [3] Three [4] Zero
CHEMICAL BONDING
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Q.43 The geometry of the molecule with sp
3
d
2
hybridised central atom is [RPMT 2000]
[1] Square planar [2] Trigonal bipyramidal
[3] Octahedral [4] Square pyramidal
Q.44 The bond angle in PH
3
is [RPMT 2000]
[1] Much less than NH
3
[2] Equal to that of NH
3
[3] Much greater than NH
3
[4] Slightly greater than NH
3
Q.45 Choose the correct statement [RPMT 2000]
[1] Amino polarizations is more pronounced by highly charged cation
[2] Small cation has minimum capacity to polarize an anion.
[3] Small anion has maximum polarizability
[4] None of these
Q.46 Which type of bonding exists in Li
2
O and CaF
2
respectively [RPET 2000]
[1] Ionic, Ionic [2] Ionic, covalent [3] Covalent, ionic [4] Coordinate, ionic
Q.47 Nonpolar solvent is [RPET 2000]
[1] Dimethyl sulphoxide [2] Carbon tetrachloride
[3] Ammonia [4] Ethyl alcohol
Q.48 Glycerol has strong intermolecular bonding therefore it is [RPET 2000]
[1] Sweet [2] Reactive [3] Explosive [4] Viscous
Q.49 Resonance hybrid of nitrate ion is [RPET 2000]
[1]
-1/2
O N O
O
-1/2
-1/2
[2]
-2/3
O N O
O
-2/3
-2/3
[3]
-1/3
O N O
O
-1/3
-1/3
[4]
-2/3
O N O
O
-2/3
-2/3
+
Q.50 The electronic configuration of COCl
2
is [RPET 2000]
O
..
..
:
[1] Cl..
..
:
..
Cl
..
Cl
..
..
:
.. [2] Cl
..
:
..
::C:O
..
..
Cl
..
..
:
.. [3] Cl
..
:
..
:
O
..
..
:
C
..
:Cl
..
..
: [4] None of these
Q.51 Which of the following has tetrahedral structure [CPMT 2000]
[1] CO
3

[2] NH
4
+
[3] K
4
[Fe(CN)
6
] [4] None of these
Q.52 Which of the following is the correct reducing order of bond-angle [BHU 2000]
[1] NH
3
<CH
4
<C
2
H
2
<H
2
O [2] C
2
H
2
>NH
3
>H
2
O<CH
4
[3] NH
3
>H
2
O>CH
4
<C
2
H
2
[4] H
2
O<NH
3
>CH
4
<C
2
H
2
Q.53 The correct order of the OO bond length in O
2
. H
2
O
2
and O
3
is [BHU 2000]
[1] O
2
> O
3
> H
2
O
2
[2] O
3
> H
2
O
2
> O
2
[3] O
2
>H
2
O
2
> O
3
[4] H
2
O
2
> O
3
> O
2
Q.54 An atom with atomic number 20 is most likely to combine chemically with the atom whose atomic
number is [BHU 2000]
[1] 11 [2] 14 [3] 16 [4] 10
Q.55 Bond formed in crystal by anion and cation is [CBSE 2000]
[1] Ionic [2] Metallic [3] Covalent [4] Dipole
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Q.56 The single, double and triple bond lengths of carbon in carbon dioxide are respectively
[1] 1.15, 1.22 and 1.10 [2] 1.22, 1.15 and 1.10
[3] 1.10, 1.15 and 1.22 [4] 1.15, 1.10 and 1.22 [AIIMS 2000]
Q.57 Shape of BF
3
molecule is [CPMT 2001]
[1] Linear [2] Planar [3] Tetrahedral [4] Square pyramidal
Q.58 The correct order of hybridization of the central atom in the following species NH
3
[PtCl
4
]
2
, PCl
5
and BCl
3
is [IIT 2001]
[1] dsp
2
, dsp
3
, sp
2
and sp
3
[2] sp
3
, dsp
2
, dsp
3
, sp
2
[3] dsp
2
, sp
2
, sp
3
, dsp
3
[4] dsp
2
, sp
3
, sp
2
, dsp
3
Q.59 The common features among the species CN

, CO and NO
+
are [IIT 2001]
[1] Bond order three and isoelectronic [2] Bond order three and weak field ligands
[3] bond order two and -acceptors [4] Isoelectronic and weak field ligands
Q.60 The number of SS bonds in sulphur trioxide trimer (S
3
O
9
) is [IIT 2001]
[1] Three [2] Two [3] One [4] Zero
Q.61 Which of the following pairs has same structure [BHU 2001]
[1] PH
3
and BCl
3
[2] SO
2
and NH
3
[3] PCl
5
and SF
6
[4] NH
4
+
and SO
4
2
Q.62 Which of the following is a polar compound [AIIMS 2001]
[1] HF [2] HCl [3] HNO
3
[4] H
2
SO
4
Q.63 The smallest bond angle is found in [AIIMS 2001]
[1] IF
7
[2] CH
4
[3] BeF
2
[4] BF
3
Q.64 Asserti on (A) : Diborane is electron deficient [AIIMS 2001]
Reason (R) : There are no enough valence electrons to form the expected number of covalent bonds
[1] Both A and R are true and R is a correct explanation of A
[2] Both A and R are true but R is not a correct explanation of A
[3] A is true but R is false
[4] Both A and R are false
Q.65 The bond order is not three for [CBSE 2001]
[1] N
2
+
[2] O
2
2+
[3] N
2
[4] NO
+
Q.66 Which of the following has p-d bonding [CBSE 2002]
[1] NO
3

[2] CO
3
2
[3] BO
3
3
[4] SO
3
2
Q.67 In H
2
O
2
molecule, the angle between the two OH planes is [CBSE 2002]
[1] 90 [2] 101 [3] 103 [4] 105
Q.68 As the s-character of hybridisation orbital increases, the bond angle [BHU 2002; RPMT 2002]
[1] Increases [2] Decreases [3] Becomes zero [4] Does not change
Q.69 Which of the following has the highest dipole moment [AIIMS 2002]
H CH
3
CH
3
H Cl CH
3
| | | | | |
[1]
H
C
H
=O [2] C = C [3] C = C [4] C = C
| | | | | |
CH
3
H CH
3
H CH
3
Cl
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Q.70 Which of the following arrangement of molecules is correct on the basis of their dipole moments
[1] BF
3
> NF
3
> NH
3
[2] NF
3
> BF
3
> NH
3
[3] NH
3
> BF
3
> NF
3
[4] NH
3
> NF
3
> BF
3
[AIIMS 2002]
Q.71 Which of the following molecule has highest bond energy [AIIMS 2002]
[1] F F [2] C C [3] N N [4] O O
Q.72 Number of sigma bonds in one of its resonance structure of P
4
O
10
is [AIEEE 2002]
[1] 6 [2] 7 [3] 17 [4] 18
Q.73 Which of the following statements is true [AIEEE 2002]
[1] HF is less polar than HBr [2] Absolutely pure water does not contain any ions
[3] Chemical bond formation take place when forces of attraction overcome the forces of repulsion
[4] In covalency transference of electron takes place
Q.74 In which of the following species is the interatomic bond angle is 10928 [AIEEE 2002]
[1] NH
+
4
, BF
4

[2] (NH
4
)
+
, BF
3
[3] NH
3
, BF
4
[4] (NH
2
)
1
, BF
3
Q.75 The energy that opposes dissolution of a solvent is [CPMT 2002]
[1] Hydration energy [2] Lattice energy [3] Internal energy [4] Bond energy
Q.76 Which of the following is weakest bond [CPMT 2002]
[1] Ionic [2] Covalent [3] Metallic [4] van der Waal
Q.77 The bond angle of water is 104.5 due to [CPMT 2002]
[1] Repulsion between lone pair and bond pair [2] sp
3
hybridization of O
[3] Bonding of H
2
O [4] Higher electronegativity of O
Q.78 Which of the following is correct for N
2
triple bond [CPMT 2002]
[1] 3 [2] 1, 2 [3] 2, 1 [4] 3
Q.79 Coordinate bond is absent in [RPMT 2002]
[1] BH
4

[2] CO
3
2
[3] H
3
O
+
[4] NH
4
+
Q.80 The values of electronegativity of atoms A and B are 1.20 and 4.0 respectively. The percentage of
ionic character of AB bond is [MP PET 2003]
[1] 50% [2] 43% [3] 55.3% [4] 72.24%
Q.81 The bond energies of HH and ClCl are 430 kJ mol
1
and 242 kJ mol
1
respectively, H for HCl
is 91 kJ mol
1
. The bond energy of HCl will be [MP PET 2003]
[1] 427 kJ [2] 766 kJ [3] 285 kJ [4] 245 kJ
Q.82 Which of the following has dsp
2
hybridization [MP PET 2003]
[1] NiCl
4
2
[2] SCl
4
[3] NH
4
+
[4] PtCl
4
2
Q.83 Which of the following compounds has coordinate (dative) bond [RPET 2003]
[1] CH
3
NC [2] CH
3
OH [3] CH
3
Cl [4] NH
3
Q.84 Which of the following have highest melting points [RPET 2003]
[1] Alkali metals [2] Transitional metals
[3] Alkaline earth metals [4] All of these
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Q.85 True order of bond angle is [RPET 2003]
[1] H
2
O > H
2
S > H
2
Se > H
2
Te [2] H
2
Te > H
2
Se > H
2
S > H
2
O
[3] H
2
S > H
2
O > H
2
Se > H
2
Te [4] H
2
O > H
2
S > H
2
Te > H
2
Se
Q.86 Which of the following has highest melting point [RPET 2003]
[1] BeCl
2
[2] MgCl
2
[3] CaCl
2
[4] BaCl
2
Q.87 Which of the following compounds doesnt have linear structure [RPET 2003]
[1] CO
2
[2] SO
2
[3] BeCl
2
[4] C
2
H
2
Q.88 Which of the following compounds has least dipole moment [RPET 2003]
[1] PH
3
[2] CHCl
3
[3] NH
3
[4] BF
3
Q.89 Which of the following statements is not true for ionic compounds [RPET 2003]
[1] High melting point [2] Least lattice energy
[3] Least solubility in organic compounds [4] Soluble in water
Q.90 Which of the following is Lewis acid [RPET 2003]
[1] BF
3
[2] NH
3
[3] PH
3
[4] SO
2
Q.91 Water has high boiling point because [CPMT 2003]
[1] It has higher molecular weight [2] It has more lattice energy
[3] It is weak acid [4] It associated with hydrogen bonding
Q.92 H
2
O is a liquid while H
2
S is gas due to [BHU 2003]
[1] Covalent bonding [2] Molecular attraction
[3] H-bonding [4] H-bonding and molecular attraction
Q.93 Isoelectronic species are [BHU 2003]
[1] N
3
, O
2
[2] Na
+
, Ca
2+
[3] O
2
, C
2
[4] K
+
, Na
+
Q.94 H-bonding is maximum in [BHU 2003]
[1] C
6
H
5
OH [2] C
6
H
5
COOH [3] CH
3
CH
2
OH [4] CH
3
COCH
3
Q.95 Diamond exists as [BHU 2003]
[1] Planner [2] Octahedral [3] Tetrahedral [4] None of these
Q.96 CO is isoelectronic with [AFMC 2003]
[1] NH
3
[2] N
2
[3] O
2
[4] NO
2
Q.97 The structure of H
2
O
2
is [AFMC 2003]
[1] Planar [2] Non-planar [3] Linear [4] Three dimensional
Q.98 The correct order of bond angle (smallest first) in H
2
S, NH
3
, BF
3
and SiH
4
is- [AIEEE 2004]
[1] H
2
S < NH
3
< BF
3
< SiH
4
[2] NH
3
< H
2
S

< SiH
4
< BF
3
[3] H
2
S < NH
3
< SiH
4
< BF
3
[4] H
2
S < SiH
4
< NH
3
< BF
3
Q.99 The bond order in NO is 2.5 while that in NO
+
is 3. Which of the following statements is true for
these two species ? [AIEEE 2004]
[1] Bond length is unpredictable
[2] Bond length in NO is greater than in NO
+
[3] Bond length in NO
+
is equal to that in NO
[4] Bond length in NO
+
is greater than in NO
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Q.100 Which of the following has the regular tetrahedral structure ? [AIEEE 2004]
[1] [Ni(CN)
4
]
2
[2] SF
4
[3] BF
4

[4] XeF
4
Q.101 Which of the following molecules has trigonal planer geometry ? [CPMT 2005]
[1] IF
3
[2] PCl
3
[3] NH
3
[4] BF
3
Q.102 Which chloride is formed by an element X whose atoms have the electronic configuration
1s
2
2s
2
2p
6
3s
2
3s
6
3d
10
4s
2
? [VITEEE 2005]
[1] X
2
Cl [2] XCl [3] XCl
2
[4] XCl
3
Q.103 Which one of the following species is diamagnetic in nature ? [AIEEE 2005]
[1] H
2
[2] He
2
+
[3] H
2

[4] H
2
+
Q.104 Lattice energy of an ionic compound depends upon [AIEEE 2005]
[1] Size of the ion only [2] Charge on the ion only
[3] Charge on the ion and size of the ion [4] Packing of ions only
Q.105 The molecular shapes of SF
4
, CF
4
and XeF
4
are [AIEEE 2005]
[1] the same with 1, 1 and 1 lone pair of electrons on the central atoms respectively
[2] the same with 2, 0 and 1 lone pairs of electrons on the central atom, respectively
[3] different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively
[4] different with 0, 1 and 2 lone pairs of electrons on the central atom, respectively
Q.106 The number and type of bonds between two carbon atoms in calcium carbide are [AIEEE 2005]
[1] 1, 2 [2] 1, 1 [3] 2, 2 [4] 2, 1
Q.107 Which of the following hydrogen bonds is the strongest? [AIEEE 2007]
[1] O H .... O [2] O H .... F [3] O H .... N [4] F H .... F
Q.108 Which of the following species exhibits the diamagnetic behaviour? [AIEEE 2007]
[1] O
2
[2] NO [3] O
2
2
[4] O
2
+
Qus. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
Ans. 1 2 1 1 1 3 1 4 4 1 2 2 2 1 1 2 1 2 4 2
Qus. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
Ans. 1 1 2 4 3 1 2 4 1 3 2 3 2 3 1 2 4 3 1 1
Qus. 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans. 4 2 3 1 1 1 2 4 3 1 2 2 4 3 1 2 2 2 1 4
Qus. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
Ans. 4 1 1 1 1 4 1 1 1 4 2 4 3 1 2 4 1 3 2 4
Qus. 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
Ans. 4 4 1 2 1 4 2 4 2 1 4 3 1 3 3 2 2 3 2 3
Qus. 101 102 103 104 105 106 107 108
Ans. 4 3 1 3 3 1 4 3
Ans Ans Ans Ans Ans w ww ww er K er K er K er K er K e ee ee y yy yy