Cl-fEMtC-AL mUIL... lgRIll,,?

~
c:EMuItiple Choiee Questions witll ONE Correct Answer:
1. Che,;ucal equilibriumisdynamicinnaturebecause: (1977)
(a) theequilibriumismaintainedquickly
(b) theconcentrations of reactants andproducts becomesameat equilibrium
(c) theconcentrations of reactants andproducts areconstant but different
(d) bothforwardandbackwardreactions occur '!t.lll.times withsamespeed~ .
2. In.areaction theTateofieactiOn isproportional to itsactivemass. This statement.is'
termedas: (1979)
I .
(a) L~wof massaction (b) LeChatelier's pliinciplc
. (c) Faraday's lawof electrolysis (d) Lawof constant proportion
3. TheoxidationofS02 by 02 toS03 isanexothermicreaction. TheyieldofS0
3
will
bem3ximumif: (1981)
(a) teinperatureisincreasedandpressureiskept constant
(b) teinperatureisreducedandpressureisincreased
(c) bothtemperatureandpressureareincreased
. (d) b~thteinperatureandpressurearereduced
4. For illereaction, H2(g)+ 12(g) ~ 2HI(g), the equilibriumconstant Kp changes
with: . (1981)
(a) tOljllpressure (b) catalyst
(c) th~amountsofH
2
and1
2
preseni (d) temperalnre
S. Theammoniaisplacedinavessel at atemperaturewhereitsdissociationconstant is
appreciable. Inthisreaction: (1981)
(a) a doesnot changewithpressure(P)
(b)Kidoesnotchaitge significantlywithP
(c) Concentrationof ammoniadoesnot changewithpressure
(d) Concentrationof hydrogen isless thanthatof nitrogen
6. For thegasphasereaction; C2H
4
+H
2
~ C:zH
6
,11H=-136.8kllmol, carriedout in
avessel, theequilibriumconcentrationofC
2
H
4
canbeincreasedby: (1984)
(a) increasing T (b) decreasingP
(c)'removing so'meH
2
(d) addingsomeC
2
H
6
7. A Iiqui~is in eqnilibriumwithits vapour at its boiling point. On the average, the
molecuiesinthetwophaseshaveequal: (1981)
(a) inter-molecular forces (b) potential energy
(c) total energy (d) kineticenergy
8. Anexampleof reversiblereactionis: (1985)
(a) Pb(N03 h(aq)+2Nal(aq)= PbI
2
(s)+2NaN0
3
(aq)
(b) 2Na(s) +2H
2
0(1) =2NaOH(aq)+H
2
(g)
(c) KN03 (aq)+ NaCI(aq)= KCI(!N)+NaN0
3
(aq)
(d) AgN03(aq)+ HCI(aq) =AgCI(s)+RN0
3
(aq)
I

9. When NaN0
l
is heated in aclosed vessel, oxygen is liberated andNaN0
z
is left
behind. Atequilibrium: (1986)
(a) additionofNaN0
z
favoursreversereaction
(b) additionofNaN0
l
favoursforwardreaction
(c) increasingtemperaturefavours forwardreaction
(d) increasingpressurefavoursforwardreaclion
10. The equilibrium, S0202 (g)~ S02 (g)+CI
2
(g), is attained at 25C in aclosed
container andanmert gas Heis introduced. Which of the followingstatements are
incorrect? (1989)
(a){S02 ],[02 ]and[S02C1
2
]change
(b) More,hlonne isfonned
(c) ConcentrationofSO
z
isreduced
(d) MoreS02Cl2 isforrned
11. Inthereaction, A
2
(g)+ 4B
2
(g) ~ 2AB
4
(g), Ml <0,theforrnationof AB
4
(g)will
befavouredat: (1990)
(a) lowTand highP (b) highTand lowP
(c) lowT andlowP (d) highT andhighP
12. Thereactionwhichproceedsintheforwarddirectionis: (1991)
(a) Fe20l +6HCI =2FeCI
J
+3H
z
O
(b)NH
l
+H
2
0+NaCl=NH
4
Cl+NaOH
(c) sn0
4
+Hg
2
Cl
z
=snO
z
+2HgCI2
(d) 2CuI+I
2
+4K+ =2Cu
2
+ +4KI
13. Forwhichof thefollowingreactions, Kp=K
c
? (1991)
(a) H
2
(g)+ CI
2
(g) ~ 2HO(g)
(b) 2NOCI(g) ~ 2N0(g )+Oz (g)
(c) N
z
(g)+3H
2
(g) ~ 2NH
l
(g)
(d) N
2
04 (g}~2N02 (g)
14. For the reaction, PCl
s
(g) ~ PCI
l
(g)+ Cl
z
(g) the forward reaction at constant
temperatureisfavouredby: . (1991)
(a) introducinganinert gasat constantvolume
(b) introducingchlorinegasat constantvolume
(c) introducinganinert gasat constantpressure
(d) increasingthevolumeof container (E) introducingPCl
s
atconstantvolume
15. Anequilibrium"mixture for thereaction, 2HzS(g)~ 2H
z
(g)+S2 (g)had I moleof .
H
2
S,0.2 moleofH
z
3nd 0.8moleofS
2
ina2L flask. Thevalueof K
c
inmol/L is :
. . (1~
(a) 0.004 (b) 0.080 (c) 0.160 (d) 0.016
16. For the reaction CO(g)+HzO(g) ~ COz (g)+H
2
(g) at a given temperaturethe
equilibriumamountof CO
2
(g)ean beincreasedby: (1998)
(a) addingasuitablecatalyst
(b) addinganinertgas
(c) decreasingthevolumeof thecontainer
(d) increasingtheamount of CO(g)

23.
22.
20.
18.
17. For the chemical reaction 3X(g)+ Y(g);=X
3
Y(g), the amount
equilibrium isaffected by :
(a) temperature and pressure
(b) temperature only
(c) pressure only
(d) temperature, pressure and catalyst
For the reyersiblereaction, N
2
(g)+ 3H
2
(g);= 2NH
3
(g )at 50.0.C,thevalue ofk pis
144x 10.-
5
when partial pressure ismeasured inatmosphere. The corresponding value
ofk
c
' with concentration inmole litre-I,is: (2000)
(a) 144x 10-
5
(b) 144x 1O-5~
(00.82x 50.0.)-2 (&3l4x 773)-2
(c) 144x 10-
5
(d) 144x 10-
5
(00.82x 773)2 (00.82x 773r
2
When two reactants, A andB aremixed togive products Cand D, thereaction quotient
Q,at the initial stages of thereaction: (2000)
(a) is zero (b) decreases with time
(c) is independent of time (d) increases with time
One mole of Nz
4
(g) at 30.0.K is kept in aclosed container at 1atm. It is heated to
60.0.K when 20.% by mass of N
z
04 (g) decomposes to N0
2
(g) The resultant
. pressure is: (1996)
(a) 1.2atm (b) 2.0. atm (c) 2.4 atrn (d) 1.0.atm
21. At constant temperature, K
p
for the equilibrium N
2
0
4
;=2N0
2
is expressed by
. K P =(4x
2
P)! (l-x
2
), where P =pressure, x =extent of decomposition. Which of
thefollowing statements istrue? (2001)
(a) K p increases with increase of P
(b) Kp increases with increase of x
(c) K p remains constant with change in P and x
(d) Kp increases with decrease of x .
.Consider the following equilibrium in aclosed container
N
2
0
4
(g);= 2N0
2
(g)
At afixed temperature, thevolume of the reaction containeris halved. For this change,
which of the following statements holds true regarding the equilibrium constant (K
p
)
and degree of dissociation (Cl)? (2002)
(a) neither Kp nor Cl changes (b) both Kp and Cl change
(c) K p changes, but Cl does not change (d) K p does not change, but Cl changes
The Haber's process for the formation of NH3 at 298 K is N
z
+3H
z
;= 2NH
3
;
Mf =-46.o.kJ ; Which of thefollowing isthe correct statement : (2006)
(a) The condition for equilibrium is
G
N
+3G
H
=2G
NH
2 2 3 .
where G is Gibbs free energy per mole of the gaseous species measured at that
partial pressure
(b) On adding N2,the equilibrium will shift to forward direction because according to
Und law of thermodynamics the entropy must increase in the direction of
spontaneous reaction
19.
K\=3.5xI0-
3
K
z
=1.74x 10-
3
(2006)
a
3
/
Z
(d)K =--;=-
" ; 3
(c) The catalyst will increase the rate of forward reaction by 2 times and that of
backward reaction by 1.5times
(d) None of these
24. If Ag+ +NH
3
~[Ag(NH3)t
and [Ag(NH3)t +NH
3
~[Ag(NH3 h]+
the formation constantof[Ag(NHi ht is:
(a) 6.08x 10-Q (h) 6.08x 10
6
(c) 6.08x 10-
9
(d) none of these
25. The value oflog \0 K for the reaction A ~ B is :
(Given: MfO=-54.07 kJ mol-
1
, ASo= IOJ K-1mol-
1
and R =8.314 J K-1mol-
1
;
2.303x 8.314x 298 =5705) (2007)
(a) 10 (h) 100 (c) 5 (d) 95
STRAIGHT OBJECTIVE TYPE
(Single ,Correct Answer
This section contains multiple correct answer type question. Each question has 4choices
(a), (b), (c) and (d), out of which only one is correct
1. Consider the equilibrium
I
COz (g)~CO(g)+-Oz(g)
. 2
The equilibrium constant K is given by (when a<<<1):
am a
3
a
3n
(a)K=- (h)K=- (c)K=-
-.J 2 2 2
(h)Q<K
p
(d)Q<2K
p
2.
3 .
4 .
For an ideal-gas reaction 2A +B~C+D.the value of K; will be:
(it) KO =nenD V; (h)Ko =nenD x po
p n3
n
B RT
z
p n3
n
B RT
(c) KO =nenD RT (d) KO =nenD x V;
p z p z RT
nAnB V
p
.. nAnB
The equilibrium of thereaction N
z
(g)+ 3H
z
(g) ~ 2NH) (g) will be shifted to right
when:
(a)Kp>1
(c)Q=K
p
If for the heterogeneous equilibrium
Caco
3
(s)~ CaO(s)+CO
z
(g); K =1at~~trn.
the temperature is given by : V-
AS' Mf' AGo. AGO
(a)T=- (h)T=- (c)T=-.- (d)T=-
. Mfo AS . R Mfo
s. K1midK2 are the respective equilibrium constant for the reactions:
(i) XeF
6
(g)+ H
2
0(g)<=,XeOF
4
(g)+2HF(g); K)
(ii) X:e04 (g)+XeF
6
(g)<=, XeOF
4
(g)+ XeO
l
F
2
; K
2
The equilibrium constant for the reaction
xe0
4
(g)+2HF(g)<=, XeO
l
F
2
(g)+H
2
0(g)
(d) ~: .,
. [ K ] 1 / 2
(d)a=--p-
4+K
p
will be:
(a) A \
](,2
" 1
2
N]
(c)-:-
K
2
The ratio of Kp / K c for the reaction
I CO(g)+~02(g)<='C02(g)is:
2
(a) I: (b)RT
(c) (RT)l/2 (d) (RT)-l/2
For ,NH<lHS(s)<='NH
l
(g)+H
2
S(g), if K
p
=64 atm
2
, equilibrium pressure of
mixfure is:
,
(a) 8atm (b) 16atm
(c) 6r aim . (d) 4 atm
The degree of dissociatiorr' a'of the reaction :
N
2
0
4
(g)<=, lN0
2
(g)
can be related to Kpas:
, K
-" -
(a) a- p
K
4+-" -
p
( C ) 1 = [ 4:; ~ Pr
For the reaction: _
8.
7 .
9.
6 .
i N
2
(g)+ 3H
2
(g)<=,2NH
J
(g)
K p=6.1x 10-
5
at 25C. ~Gofor the reaction will be :
OO+Mt l OO- Mt l
(cH 7 . 3t l ( d)2t l
10. In wmchof the following case the reaction is nearer to completion:
(a)K=10
6
(b)K=lOJ;I
I
(c) K =10-6 (d) K =10-
12
11. In the heterogeneous equilibrium :
. Caco
J
(s)<=, CaO(s) +CO
2
(g)
whit would be the effect of addition of CaCO
J
on the equilibrium concentration of
C Oi?
, .
simultaneously
a3/2pl!2
(b)K;--~~-
(I-a)(2+a)I/2
3 3/Z
(d)K; a p
(I-a)(2+a)lIZ
and CO, two equilibria are
(a) Increases (b) Unpredictable
(c) Decreases (d) Remains unaffected
12. For the reaction, N
z
0
4
(g) "" 2NO
z
(g); if percentage dissociation of N
z
0
4
are
25%, 50%, 75% and 100%, then the sequence of observed vapour densities will be :
W~>~>~>~ OO~>~>~>~
(c)d
l
;d
z
;d
3
;d
4
(d)(d
l
;d
z
(d
3
;d
4
)
13. In asystem:
A(s) "" 2B(g)+ 3C(g)
if the concentration of C at equilibrium is increased by afactor of 2, it will cause the
equilibrium concentration of B to change to :
(a) two times of original value
(b) one half of its original value
(c) 2Ji times the original value
(d) Ir,:; times the original value
2..;2
14. For the decomposition ofNH
3
(g) in a sealed tube:
2NH
3
(g) "" N
z
(g)+ 3H
z
(g)
(a) K
p
does not change with pressure
(b) concentration of Hz (g)is less than that of nitrogen
(c) concentration of ammonia does not change with pressure
(d) Kp changes significantly with pressure
15. The equilibrium constant for the decomposition of water,
[HzO(g)"" Hz (g)+~Oz (g)]
is given by:
3 1!2
(a)K a p
. (I-a)(2-a)lIz
a3 p1l2
(c)K; Ji
16. On heating a mixture of SOzCl
z
established:
SOzCl
z
(g) "" SOz (g)+ Cl
z
(g)
CO(g)+ CI
2
(g)"" COCl
z
(g)
On adding more SOz at equilibrium what will happen?
(a) Amount of CO will decrease
(b) Amount of SOzCl
z
and COCl
z
will increase
(c) Amount of CO will remain unaffected
(d) Amount ofSOzCl
z
and CO will increase
17. Anunonium carbamate when heat~d to 200C gives a mixture of NH
3
and COz
vapour with a density of 13. What is the degree of dissociation of ammonium
carbamate?
(b) ~
2
(d) I
(d) (800R)'/z 4
3
(a) -
2
(c) 2
(e) ~
2
18. Densi\ies of diamond and graphite are 3.5 and 2.3 glmL respectively. Increase of
pressure on the equilibrium
C (diamond) .=' C(graphite)
,<a)fa~ours backward reaction (b) favours forward reaction
(c) has no effect (d) increase the reactiou rate.
19. A reaction at equilibrium involving 2moles each ofPn
s
,PCI} and Cl
z
is maintained
at 250C and atotal pressure of 3 atm. The value of K p is :
.(a) 2 I (b) 3
(c) 4 (d) I
20. Consider the reactions,
(i) PCI
s
(g).='PCI
3
(g)+CI
2
(g)
(ii)N
z
0
4
(g).=' 2NOZ(g)
The addition of an inert gas at constant volume:
. I .
(a) will increase the dissociatio.n of PCIs as well as N
Z
0
4
(b) will reduce the dissociation ofPCl
s
as well as N
z
04
(c) will increase the dissociation of PCIs and step up the formation ofNO
z
'
I
(d) will not disturb the equilibrium of the reactions . .
21. Equilibrium constant K c for the following reaction at 800K is, 4..
I 3
NH}(g).=' 2Nz (g)+2 Hz(g)
The value of kp for the following reaction will be :
. N
z
(g)+ 3H
z
(g).=' 2NH
j
(g)
z .
(a)(80~Rr (b)16x(800R)z
(c) [ 4~; O O R r
22. Given::
Eqnilibrium constant
K,
K
2
Reaction
N
z
(g)+ 3H
z
(g).=' 2NH}(g)
N
z
(g)+Oz (g).=' 2NO(g)
Hz (g)+~ 0z (g).=' HzO(g)
2
The equilibrium constant K 4 for the following reaction
5 .
2NH} (g)+- 0z (g).=' 2NO(g)+3H
z
O(g)
. 2
may be given as :
,
23.
(b) K
1
K
2
=K
4
K
3
K K
3
(d)~=K4
K
1
N
2
(g)+3H
2
(g)~2NH3 (g)
Initially the molar ratio of N
2
and H
2
was I : 3. At equilibrium, 50% of each has
reacted. If theequilibrium pressure isP, thepartiaIpressureofNH
3
at equilibrium is:
P P
(a) - (b)-
3 4
P P
(c)- (d)-
6 8
24. For the reaction,
N2(g)+3H2(g)~2NH3(g); MfO=-ve
the nwilber of moles ofH
2
at equilibrium will increase when:
(a) volwile of vessel is.increased
(b) .volume of vessel is decreased
(c) Ne gas is added at constant volume
(d) NH
3
is removed
25. Given, 2CO(g)~C(s)+C02(g); K
p1
=10-
14
atm-
I
at1120K
Cb(g)+Ci2(g)~COCI2(g); K =6xI0-
3
atm-
1
. P,
The value of K c for the following reaction at 1120 K will be :
C(s)+C0
2
(g)+2CI
2
(g)~ 2COCI
2
(g)
(a) 5.51x 10
6
M-
1
(b) 5.5x 10
10
M-
1
(c) 3.3Ix lOll M'-I (d) 4.35x 10
8
M-
1
'
26. Two solid compounds X6)and Y(s)undergo dissociation as follows:
X(s)~A(g)+2B(g); K
p1
=9xI0-
3
bar
3
Y(s)~2B(g)+C(g); K
p
, =4.5xI0-
3
bar
3
The total pressure of gaseous mixture at equilibrium will be :
(a) 4.5 bar (b) 0.45 bar
(c) 0.6 bar (d) 1.2bar
27.
When A2 and B2 areallowed to react, theequilibrium constant of the reaction at 27C
is found (K
c
=4)
A
2
(g)+ B
2
(g)~ 2AB(g)
What will be the equilibrium concentration of AB?
(a) 1.33 M (b) 2.66 M
(c) 0.66 M (d) 0.33 M
'.
"
(b) 4.7
(d) 5.7
33.
I
I
,
I
32.
At a certain temperature the equilibrium constant K c is 0.25 for the reaction:
A(g)+B(g )~C(g)+D(g)
If we take I mole of each of four gases in a 10 litre container, what would be the
equilibrium concentration of A (g)?
(a) 0.331 M (b) 0.033 M
(c) 0.133 M (d) 1.33M
The vapour pressure of mercury is 0.002 mm Hgat 27C
Hg(l)~Hg(g)
The value of equilibrium constant K c is :
(a) 1068x 10-
7
M (b) 0.002 M
(c) 8.12x 10-
5
M (d) 3.9x 10-
5
M
30. The equilibrium constant for theionization of aliphatic amine RNH
2
(glin water is :
RNH
2
(g)+H20(1)~RNH; (aq)+OW (aq)
is 8x 10-6 at 25C. Partial pressure of amine at equilibrium is 0.5 bar. The pOH of the
aqueous solution of amine will be :
(iI) 2.7
(c) 3.7
The equilibrium :
P
4
(g)+6C1
2
(g)~ 4Pci
3
(g)
is attained by mixing equal moles ofP4 and Cl
2
in an evacuated vessel. Then at
equilibrium :
(a)[Clh >[PCI
3
] (b)[Clh >[P
4
]
(c)[P
4
]>[CI
2
] (d)[PCI
3
]>[P
4
]
In"the reaction : A +B ~ 2C+D. The initial concentration of A and B are 1M each.
The value of K c is 10
8
. What is the equilibrium concentration of A?
(a) 2x 10-4 M (b) 2x 10
4
M
(c) 0.005 M (d) 0.0025 M
..For the reaction:
A(g)+2B(g)~3C(g)+D(g); K
p
; 0.05 aim at 1000 K. The value of K
c
is
represented by :
3 1 .
291
,
I
28.1
~4.
I
,
-4
(a) 5x 10-4R (b) 5x 10
R
(c) 5x 10-
5
R (d) 5x 10-
5
R
Acetic acid u?dergoes dimerisation. wh.en dissolved in benzene
, f0.... HO\"
2CH
3
-COOH ~ CH
3
-C C-CH
3
. "\,f
OH ....O
Molecular mass of acetic acid is found 120. Which among the following relation is
correct?
(
D - d )
( b) ( l~2D
2d
(d)(l~--
D-d
35.
36.
37.
38.
39.
(
D - d )
(a) (l ~2 - d -
(
d - D )
(c)(l~2 - d -
where, d~Observed vapour density
D ~Theoretical vapour density
At constant pressure, the presence of iner! gases:
(a) reduc~ the dissociation ofPCl
s
(b) increases the dissociation of PCls
(c) does not affect tbe degree of dissociation ofPCl
s
(d) steps up the formation of PCls
At the equilibrium oftbe reaction, N
z
04(g),= 2NO
z
(g),tbe observed molar mass
ofN
z
0
4
is 77.70 g. The percentage dissociation ofN
z
0
4
is:
(a) 28.4 (b) 46.7
(c) 22.4 (d) 18.4
Equilibrium constant for two complexes are :
A: K
4
[Fe(CN)61 2.6x10
37
(for dissociation)
B: K
3
[Fe(CN)61 1.9x 10
17
(for dissociation)
(a) A and B are equally stable (b) A is more stable than A
(c) Bis more stable than A (d) the predictable stability
What is AGOfor the following reaction?
I 3 4
-N
z
(g)+-H
z
(g)""NH
3
(g); K
p
~4.42xI0 at25C
.2.2. .
(a) -26.5 kJ mol-
1
(b) -11.5 J s I mol-
1
(e)-2.2kJ moC
I
(d)-Q.97kJ rnol-
1
For.the following reaction: K ~1.7x 10
1
at 25C
Ag+( aq.) + 2NH
3
( aq.) "" [Ag(NH
3
lz t
what is the value of AGOinkJ ?
(b) AGO>0, K eq. >I
(d) AGo<O, K
eq
. <1
(a)-41.2 (b)-17.9
(c) +17.9 (d) +41.2
40. If E;'u for agiven reaction is negative, which gives the correct relationships for the
values of AGOand K eq.?
(a) AGO>0, Keq <I
(c) AGo<O, Keq. >I
41. In the reaction:
NH
z
COONH
4
(s),=2NH
3
($)+ COz (g)
the equilibrium pressure was 3atIn at 1000K..The K p of the reaction:
(a) 27 (b) 4
(c) ~ (d) 27
n 4

In a two step exothermic reaction,

A
2
(g)+B
2
(g)~ 3C(g)~D(g)
Step (I) and step (II) are favoured in forward reaction respectively by:
(a) high pressure, high temperature and low pressure, low temperature
(b) low pressure, low temperature and high pressure, low temperature
(c) high pressure, low temperature and low pressure, high temperature
(d) low pressure, high temperature and high pressure, high temperature
In the reaction, AC0
3
(s) ~ AO(s)+ CO
2
(g), the equilibrium pressure of CO
2
at
127~and 147C are0.14 and 0.34 bar respectively. The enthalpy of ~e reaction is :
(a) 64 kJ /mol , (b) 35;8 leI/mol
(c) 31.1 kJ /mol (d)79.8 kJ /mol. .t
Which of the following conditionS will shift the equilibrium position to the forward
reactibn? .
: 4NH
3
(g)+50
2
(g)"" 4NO(g) +6H
2
0(g)+ heat
(a) increasing the temperature (b) increasing the pressure
(c) adding acatalyst (d) none of these
Equilibrium constant Kp increases with increase in temperature. The Ml for the
reaction would be :
(a) positive (b) negative
(c) zero (d) cannot be predicted
NH4HS(s) "" NH
3
(g)+H
2
S(g)
The equilibrium pressure at 25C is 0.66 aim. What is K p' for the reaction?
(a) 0.109 (b) 0.218
(c) 1.89 (d) 2.18
The equilibrium constants K p and K p for the reactions X "" 2Y and Z "" P +Q;
1 2
respeytivelyare inthe ratio of I :9. If the degree of dissociation of X and Zbe equal,
theri the ratio of total pressures at these equilibria is :
(a)I:,9 (b)1:36
(c)I:;1 (d)I:3
20% ~fN204 molecules are dissociated ina sample of gas at 27C and 760 torr.
Mixtufe has the, density at equilibrium equal to :
(a) 1.48 gI1.(b) 1.84 gIL
(c) 2j5 gIL (d) 3.12 gIL
The frj,., energy off ormation of NO i's78kJ mol-
I
at the temperature of an automobile
engine (1000 K).What is the equilibrium constant for this reaction at this reaction at
1000 K?
i
.!N
z
(g)+.!02(g) "" NO(g)
2 2
(a) 8Ax 10-
5
(b) 7.1 x 10-
9
(c) 4.2 x 10-
10
(d) 1.7x 10-
19
2S02 (g)+ 02 (g) "" 18
3
(g)
Given, that the equilibrium constant for the reaction above has a value of 278 at a
particular temperature, what is, the value of equilibrium constant for the, following
reaction at same-temperature? ~,
1 ""
, ' S03(g)"" S02(g)+-Oz (g)
. 2
,
45.
43.
44.
42.
46.
47.
49.
48.
so.
. .;
~i_.:
. '
(b) II only
(d) I, II and III ."
K
1
(b) 0.015M
(d) 0.097 M
K
53.
(a) 13x10-s (b) 18x10-
3
(c) 3.6x10-
3
(d) 6xIO-
z
51. Inwhich of the following reactions, theincrease involume of the container will favour
tho formation of products?
(a) C(s)+HzO(g)~ CO(g)+H
z
(g)
(b) Hz (g)+I
z
(g)~ 2HI(g)
(c) 4NH
3
(g)+50
z
(g)~ 4NO(g)+6H
z
O(I).
(d);30z (g) <=203 (g)
52. Consider the reaction; whose K c =33, (/f
SOz (g)+ NO
z
(g) <=S03 (g)+ NO(g)
If 0.1mol each ofSO
z
andNO
z
areplaced in lL container, whatis the concentration
of SOz at equilibrium?
(a) 0.OO3M
(c) 0.085 M
Reaction
. .!N
z
(g)+Oz (g)<= NO
z
(g)
2 ."
2NO
z
(g)<=N
Z
0
4
(g) K
z
Usjog above equations, write down expression for K of the following reaction :
. . I
N
Z
0
4
(g) <=N
z
(g)+2 z (g).
K
Z
(b)_z
K
1
(c) _1- (d) _1_"
KzK; K;Kz "
54. eu z+ ions reacts with Fe
z
+ ions according.to the following reaction:
Cu
z
+ +2Fe
z
+ <=Cu+2Fe
3
+
At equilibrium, the concentration of Cuz+ .ions isnot changed by the addition of:
(a) Cu z+ (b)Fe
z
+
(c) Cu (d) Fe
3
+
55. Consider this equilibrium, for which Ml < 0, .. .
HgO(s)+4r-(aq. )+HzO(I)<= HgI~- ~20K""
which changes will increase the equilibrium concentration ofHgI~- ?
I. Increasing the mass ofHgQ(s) present
.II. Increasing [r]
III. Adding I M HCI
(a) I only
(c) II and III only
56. For dissociation of a gasNzOs as :
I.
NzOs (g)<= 2NO
z
(g)+20z (g);
N
2
+02 ~2NOisKl
NO(g)~.!. N
2
(g)+.!. 02(g)is K
2
.
2 . 2 and that for
if'D' is the vapour density of equilibrium mixture and Po is the initial pressure of
N
2
Os (g), then its equilibrium pressure must not be(Mismolecular mass ofN
2
Os) :
(a) R (M -W) (b) PoM
o 3D 3D-M
(c) PoM (d) 2P
o
D
W M
57. The equilibrium constant for,
59.
.60.
pels(g)~peI3(g)+eI2(g); Kp
:::p,< r e f u U O " ' - = " ::: t' .,
Kp+P .. K
p
(c)a;~Kp +P (d)a- I
~Kp+P
In the decomposition reaction of ammonia:
2NH
3
(g)~N:i(g)+3H2 (g)
2moles ofNH
3
are introduced inthe vessel of llitt:e. At equilibrium., I mole ofNH
3
was left,.the value of K c will be :
(a) 0.75 (b) 0.70
OOI ~ OOI ~
S03 (g) is heated in aclosed vessel. An equilibrium :
15
3
(g)~ 2S0
2
(g)+02 (g)
is established. The vapour density of the mixture, in which S03 is 50% dissociated,
is:
(a) 32 (b)35
~)42 (~55
61. When In K is plotted against.!.. using the van't Hoff equation, a straight line is
T
expected with a slope equal to :
(a) 6W/RT (b) -6W/R
(c) filio/ R \ d) RI MIo
K 1and K 2 will be related as :
, 2
(a)K
1
;(;2) (b)K
t
; K;
(c)K
2
" ' U J (d)K
2
;K~
58. For;the decomposition of pels (g)in aclosed vesseJ ;the degree of dissociation is aat
total pressure P.
/
(d) 400
(b) 0.085M
2
(d) noneof these
68.
66.
62. AB2(g) dissociatesas,
AB
2
(g) ~ AB(g)+ B(g)
The initial pressure of AB
2
is 600 romHgandtotal pressure is 800 romHg. The
equilibriumconstant for thereactionwill be:
(a) 500 (b) 100 (c) 200
63. For thegaseousreaction,
GH
4
+H
2
~C2H6
Theequih1>riumconstant, hastheunits :
(a) mo1
2
dm-
3
(b)dm
3
mol-
1
(c) dm-
3
mol-
l
(d)moldm-
3
64. Theequilibrium, NH
4
HS(s) ~ NH
3
(g)+ H
2
S(g), isfollowedtoset-lipa! r27c iti
aclosedvessel. Thetotal pressureatequilibriumwas20atm. TheK c for thereaction
is:
(a) 0.092M
2
(c) 3.045M
2
65.. For thereaction,
eus0
4
.5H
2
0(s)r= eus0
4
.3H
2
0(s)+2H
2
0(g)
which one is the correct representation?
(a)K
p
:[P
H20
f (b) K
c
.:[H
2
0]2
(c)K
p
:K
c
(RT)2 (d) All of these
Whichoneisthecorrectrepresentation for,
2S0
2
(g)+ 02 (g) ~ 15
3
(g)?
[Pso
3
]2
(a)K
p
: ~_ (b)K
c
[Pso, ]2[Po, ] [S02]2 [02 ]
[nso f [ P ]- 1
(c)K
p
_' 3.. . (d) All of these
[nso, f[no,] Total mole. .
67. In a flask colourless N
2
0
4
is in equih1>riumwith brown coloured N02. At
equilibrium, when the flask is heated to 100C the brown colour deepens and on
cooling, thebrowncolour becamelesscoloured. ThechangeinenthalpyMf for the
systemis:
(a) negauve (b) positive
(c) zero (d) not defined
LeChatelier's principleisnot applicableto:
(a) Fe(s)+S(s)~ FeS(s) (b) H
2
(g)+I
2
(g)'~ 2HI(g)
(c) N
2
(g)+ 3H
2
(g) ~ 2NH
3
(g) (d)N
2
(g)+02 (g) ~ 2NO(g)
69. For thereaction, [Ag(CNh r r=Ag++2eN"" ,theequilibriumconstantKc at25C
is 4x 10-
19
; then Ag+ concentration in a solution Whichhas 0.1 M KCN and
0.03M AgN03 is:
(a) 7.5x 10
18
(b) 7.5x 10-18
(c) 7.5x 10
19
(d) 7.5x 10-19
70. The equilibrium constants for the reaction, Br2.= 2Br, at 500 K and 700 K are
Ix 10-
10
andIx 10-
5
respectively. Thereactionis :
(a) endothermic (b) exothermic
(c) fast (d) slow.
71. If theconcentrationof mr ionsinthereaction,
Fe(OHh (s) -:-" Fe
J
+ (aq.)+ 30W (aq.)
isdecreasedby 1/4times, thenequilibriumconcentrationofFe
J
+ will increaseby :
(a) 64times ~(b) 4times
(c) 8times (d) 16times
72. K
c
for A+B.=C+Dis 10at25C. Ifa container contains 1,2,3 and4mol per litre
of A, B, C andD respectively at 25C, thereactionshall:
(a) proceed fromleft toright (b) proceedfromright toleft
I ( c) beat equilibrium (d) noneof these
73. Inthepreparation of CaOfromCaco
J
usingtheequilibrium,
I Cac0
3
(s).= CaO(s)+CO
2
(g),
. 8500
K p IS expressedaslog K p =7.282-
r
;
For completedecompositionof Cac0
3
thetemperatureincelsius tobeusedis:
(a) 1167 (b) 894
.. 1 (c) 8500 (d) 850
74.' For the reactiOli, PCI5(g).=PCI
3
(g)+C1
2
(g), the forward reaction.at constant
.. temperatureis favouredby :
. 1. introducinginert gasatconstantvolume.
, IT. introducinginert gasatconstantpressure.
i ill. decreasingpressureof thereactionmixture.
, IV.by addingPCI
J
tothereactionmixture.
I
(a) I andII (b) ITandill
(c) I andill (d) ill andIV
75. For thereaction,
I A~B+C,
I
at equilibrium, theconcentrationof A isIx 10-
3
M,B is0.15MandCis0.05M. The
,toGo for thehydrolysis of A at27Cwill be: .
i(a)-5kl/mol (b)-17.3 kl/mol
(c) - 11.2kllmol (d) noneof these
76. Inwhichof thefollowingreactions, Kc andKp arenot equal?
(a) 2N0(g).= N
2
(g)+02 (g)
l( b) S02(g)+N0
2
(g).= S03(g)+NO(g)
!(C)H
2
(g)+I
2
(g).=2lll(g)
( d) 2qs)+02 (g).= 2CO(g)
77. What is the effect of atenfold increase in pressure onK p in the reaction:
N
z
(g)+ 3H
z
(g) <=' 2NH
3
(g)
at equilibrium?
(a) A tenfold increase (b) A tenfold decrease
(c) No change (d) Equal toKe
78. Consider thefollowing reactions inwhich all thereactants and products are ingaseous
state.
2PQ.=P
z
+Qi; K
1
=2.5xI0
5
PQ+!R
z
.=PQR; K, =5xI0-
3
2 -
The value of K 3 for the equilibrium :
I I. 1.
-P
Z
+-Qz +-R
Z
.=PQR
2 2 2
is:
.(a) 2.5x 10-
3
(b) 2.5x 10
3
(c) 1.0x 10-
5
(d) 5x 10
3
79. 3.1 mole of FeCl
3
and 3.2 mole of NH
4
SCN are added to one litre of water. At
equilibrium 3.0 mole of[FeSCN]z+ are formed. The equilibrium constant K e of the
reaction:
will be:
(a) 6.66x 10-
3
(b) 0.30
003~ OOI ~
80. The free energy off ormation of NO is78kJ mOl-I at theternperature ofan automobile
engine (1000 K). What is the equilibrium constant for this reaction at 1000 K?
!N
z
(g)+! 0z (g).= NO(g)
2 2
(a) 8.4x 10-
5
(b) 7.lx 10-
9
(c) 4.2x 10-
10
(d) 1.7x 10-
19
81. The equilibrium constant K p for the following reaction is equal to 3.4
Cis - 2- butene .=Trans - 2-butene
If a flask iriitiaily contains 0.25 aimof cis-2-butene and 0.125 aimof trans-2-blitene,
what is the equilibriUm of each gas?
. Cis-2-butene Trans~2-butene
(a) 0.085 aim
(b) 0.058 aim
(c) 0.028 aim
(d) 0.034 aim
0.290 aim
0.230 aim
0.156 aim
0.128 aim
(b) 0.09
(d) 0.05
MULTIPLE CORRECT ANSWER TYPE
(More than One Correct Answer
85.
86.
A vessel at 1000K contains COz withapressureof 0.5 atm. Someof the COz J
conyertedtoCO onadditionof graphite. If thetotal pressureatequilibriumis0.8atm."l
thevalueof K is : .
(a) 0.18atm (b) 1.8atm
(c) 3atm (d) O.htm
83.. TheHaber's process for theproductionof ammoniainvolvestheprocess:
I N
z
(g)+ 3H
z
(g).= 2NH
3
(g):
AssumingthatMfo andlIS0for thereactiondoesnot changewithtemperature, which
of thefollowingtemperaturecorrespondsequilibrium:
(,vjo~-95kJ mol-l; llSo~-190J K-1 mo]-l)
(a) 500K (b) 600K
I .
(c)700 K (d) 800K
84. Giventhat theequilibriumconstant for thereaction2S0
z
(g)+ 0z (g).= 2S0
3
(g)
hasavalueof 278 at aparticular temperature. What is thevalueof theequilibrium
conStantfor thefollowingreactionat sametemperature?
S03(g)~ SOz(g)+!'02 (g)
2
(a) h8x 10-
3
(b) 3.6x10-
3
(c) ~x10-z (d) 1.3x10-
5
TheI equilibrium constant (K
c
) for the reaction N
2
(g)+Oz (g).= 2N0(g) at
tem1?eratureTis 4x10-4. Thevalueof K cfor thereaction,
I I .
NO(g).=-N
z
(g)+- O
2
(g)
2 2
at thesametemperatureis :
I '" .
(a) 0.02 (b) 2.5x I O
z
(c)4.xIO~ (d)50.0
.ConSiderthe reaction 2A ~ B. The equilibriumconstant is Ix I O z . If the initial
cont\mtration.of 'A' is 0.12315 mol L-
1
, the concentration of 'B' in mol/L at
I . .- .
eqniHbriumis :
(~) oliO .
(c) 0.02
I
I '
82.
This sectiO n' contains 4multiple correct answer(s) type questions. Each question has 4
choices (a), (b), (c) and (t!), out of which one or more is/are correct
1. Unit 6f equilibriumconstant of agaseousreaction,;sexpressedas :
-6n . 6n
(a) (atm) g (b) (atm) g
(C)(~Ollitre-l)6ng (d)(~ar)&g
..
2. Whichof thefollowingis/arecorrect abouttheequilibriumof areaction? . .,
I J "
(a)6q~0
(b) Catalyst does not affect the position of equilibrium
(c) Q ~K
(d) Equilibrium constant is independent of initial concentration of reaction
3. Degree of dissociation for areversible reaction at equilibrium is calculated as
D-d
a-~---
(n -I)d
D ~Initial vapour density, d =Vapour density at eqnilibrium
The relation is correctly matched for which of the folloWing reactions :
(a) X(g)~ 5n Y(g)+!!.Z(g) (b) A(g)~!!.B(g)+ 2n C(g)
6. 6. 3 3
An n n n
(c)X(g)~5 Y(g)+"5Z(g) . (d) X(.g)~"2 Y(g)+"2 Y(g)
4. For the fe-action:
AB
Z
(g)~ A(g )+B
z
(g)
the degree of dissociation' a' is negligible as compared to I (unity); the degree of
dissociation may be expressed as :
(a)aoc ~ (b)aoc.Jv
. "p
I I
(c)aoc- (d)a
oc
-
V p
5. Which of the folloWing is/are correct about the influence of positive catalyst on a
chemical equilibrium?
. (a) Equilibrium constant is unaffected
(b) Heat of reaction Mf is unaffected
(c) Amount of product remains unaffected
(d) Larger amount of product is formed
6.. Which of the following factors will favour the backward reaction?
Cl
z
(g )+3F
z
(g)~ 2ClF
3
(g); Mf =-ve
(a) Addition of inert gas at constant pressure
(b) Addition of Cl:i gas
(c) Increase in the temperature of reaction
{rl)lncreasing the v~IUmeof the container
7. For the gas phasereaetion,
~H4 (g)+H
z
(g)~ C
Z
H
6
(g); AW~-136.8k1mol-
1
carried out in avessel, the equilibrium concentration of C
z
H
4
cali be increased by.:
(a) .increase in temperature (b) decrease inpressure .
(c) removing some Hz (d) adding some ~H6
8. An increase in temperature increases which of the following?
1. The rate constant of a reaction
2. The ionic product of water
3. The equilibrium constant of exothermic reactions
(0) I and 2 only (b) I and 3only
(c) 2 and 3only (d) 1,2 and 3
!
9. Whichof thefollowingwill favour theformationofNH
3
byHaber's process? j
(a) Increaseof temperature (b) Increaseof pressure
(c) Additionof catalyst (d) Additionof promoter . ,
10. Whichis/arecorrect?
/1H
o
/!So
(a) 2.3'103logK =-_.-+- (b) t>Go=-2.303RTIog K
RT R
/1H
o
/!So I
(c)-23031ogK =--+- (d) 2.3031ogK =_ (/1Ho+/!S0)
, RT
2
R RT
I
11. N
2
0
2
~2NOKl; G)N2 +G)02 ~NOK2 .~
: . '( I) (J )
2NO~N2 +02 K3; NO~ " 2 N
2
+ " 2 02 K
4
Correct relation(s) betweenK
1
,K
2
,K
3
andK
4
is/are:
(a)K
2
~K4 =1 (b).jK
1
xK
4
=1
(c).jK3 xK2 =1 (d).jK
3
xK
2
=1
12. Waterg~,an industrial fuel, containingCOandH
2
inequimolar amountsisobtained
bypassing stearnover red-hot cokeinaccordancewiththereaction:
. qs)+H20(g)~CO(g)+H2(g); /1H=+I3Q5kJ
TheyieJ aof water gaseanbe increasedby :
(a) reducingthetotalpressure of thesystem
(b) incrC?Singthepressureof steam
.(c) risingihe temper,.ture .
(d) iritroducinghot tarbon .
13. Thevanation of .,quilibriumconstant K withtemperatureisrepresentedby :
(a)Iog. 1
2
-log. K(=- /1HI
T
z (" !' )dT
. R 1j T
(b) {dclO
g
K} =_ /1H
dT p RT
(c) log. K,=Constant'- ::;
.. /1H
(d) log. K =Constant__ ._
. . RT
.~ ASSERTION-REASON1Y'0
I
In each ofthefo.uowing questions, two statements are given. Choose the correct code (a),
(b), (c) or (d) defined below:
(a) Statem.!nt.land Statement-2 are true, Statement-2 is a correct explanation of
Statement-I. .
,
I.
(b) Statement-I and Statement-2 are true but Statement-2 is not the correct
explanation of Statement-I.
(c) Statement-I is true and Statement-2 is false.
(d) Statement-I is false and Statement-2 is true.
I. Statement-I: Catalyst alters the rate of areaction.
Statement-Z : Catalyst does not affect the position of equilibrium.
Z. Statement-I': The equilibrium constant of the exothOrm;c reaction decreases with
Statement-Z : ::~(e:2 t]e:pe:;;.[...!.. __ 1_]
K
1
2.303R T
1
T
2
'_ "
tJl:: -ve for exothennic reaction
3. Statement-I: At equilibrium AG =0
Statement-Z : AGO =-RT logeKe at equilibrium
4. Statement-! : At equilibrium AG =0
Statement~Z : The Gibbs free energy of reactants andproducts decreases andbecome
equal at equilibrium.
5. .Statement-I: Equilibrium constant of a reaction changes on changing the
stoichiometric coefficients of the reaction.
Statement-2 : The reactions: N
2
(g)+ 3H
2
(g) ~ 2NH
3
(g)
and.!. N
2
(g)+~H2 (g)~ NH
3
(g)have same equilibrium constant
2 2
6. Statement-! : There is no effect of inert gas addition to' the following reaction:
H
2
(g)+ 1
2
(g)~ 2H1(g)
Statement~2 : When An
g
=0,there is no effect of inert gas addition.
7. Statement-! : For the reaction: N
2
(g)+ 3H
2
(g) ~ 2NH
3
(g)
The unit of K p =atm-2 .
Sfatement-2 : Unit of K p for agaseous reaction is given by the relation
Unit of K p =(Unit of Pressure)M
g
.
8. Statement-!: The Qc for the reaction:
~ . [S03f
2S02(g)+02(g)~2S03(g)ISQc =2
. [S02] [0
2
]
Statement-2 : When Q
c
<K
c
' thereaction is not at equilibrium and it will be fast in
backward direction.
9. Statement-!: The equilibrium of [PCIs (g) ~ PCl
3
(g)+ Cl
2
(g )]is not affected by
changing the volume of container.
[PCI
3
HCI
2
]
Statement-2: K
c
~--~~~-
[PCl
s
]
Equilibrium constant Kc does not depend on the volume of vessel.
to. Statement-!: The reaction : N2(g)+3H2(g)~2NH3(g) will shift in forward
direction by increase in pressure.
1 1 .
12.
1 3 .
14.
15.
16.
17.
18.
St~tement-2 : On increasing the pressure, the equilibrium will shift in forward~i
, direction. 1
Sbtement-l : Theactivemassof puresolidandpureliquidistakenunity. 1
SJ tement-2 : Theactivemassof puresolidsandpureliquidsdependsondensityand
molecular mass. Thedensity and.molecular mass of pureliquids and'
solidsareconstant.
Statement-I: Additionof inertgasesat equilibriumwill support thedissociationof
I
I PCl
s
at constanttemperature. < '.'
Statement-2 : The addition of inert gases at constant volume will not affect the
equilibrium.
Statement-I: Kp isequal 10 Kc for thefollowingreaction:
I N2(g)+02(g)~2NO(g)
Statement-2 : Kp andKc areinterrelatedbythefollowingequation:
! K p =Kc(RT)An
g
M
g
=Number of gasecus moles of products - Number of gaseous
molesof reactants
Statement-I: The value of equilibriumconstant for both forward and backward
~. reaction may be same.
Statement-2 : The equilibrium constant of a reaction is reciprocated whe':' the
.. t. reaction is reversed.
,
Statement-I: Equilibriumconstimtof areactionmayincreaseor decreasewithrise
I intemperature.
Statement-2 : Changeinequilibriumconstant of areactiondependsonwhether the
[.reaction isexothermicor endothermic. . . . .
Statement-l : For everychemical reactionatequilibriumstandardGibbsfreeenergy
of reaction is zero.
Stafi,ment-2 : At constant temperature and pressure, chemical reactions are
spontaneousinthedirectionof decreasingenergy. (2008)
Stat~ment-l : Somehydratedsaltslikeblue'vitriol dissolveinwater withabsOIption
of heat.
Statement-2 : Le-Chatelier's principle is not valid for solid-solid heterogeneous
,
system.
Statement-I: K p =I, whenthereactionapproaches completion.
Stat~ment-2 : 6Go=O, whenK
p
of thereactionisequal towiity.
.
OBJECTIV.. E QUESTIONS ON)
GRAPHICAL APTITUDE
1.
Whichof thefollowinggraphsrepresents anexothermicreaction?
(a)lnl/
i .
(b)
In~~
1rr--
1rr--
1
A
1
(c) InKp (d)
h i ~
1rr-- 1rr--
2. ThegraphrelatesInK v s ! - for areaction. Thereactionmustbe:
T
1 .
I nK /
1.5x 10-3
".,
2x 10-3 .2.5x 10-3
.1.--
T
(a) Exothermic
(b) Endothermic
(c) M/;"O
(d) Spontaneous atordinarytemperature
3. Theequilibriumconstantfor thefollowingreaction
N204(g)~2N02(g)isK (NOd
. [N
2
0
4
J
[N021 --
. Which of the following graphs is correct?
(
(b) [N021
1
(a)
E q u i l i b r i u m
'backward
r eact i on
TIme,-
(II)
R.eact ant s
Products
t.
/
. . .
Rale
Pr od u ct s
Reactants
t
Concentration
l i m e - - - . ,
(I)
[N2
0
4l__ [N~__
in thereaction, PCls (g).=: PCl
3
(g)+Cl
2
(g).Which of thegraph is/arecorrect?
forward
r eact i on .
t
Co1centration
4.
TIme_
(III)
I
~~n OO~Rill
(c) n, ill (d)I,ill
5. DecompOsition ofN
2
04 (g )takes placeas follows :
N204(g)~2N02(g)
'D';is thevapour density at initial stageand d' is thevapour density at equilibrium. We
get:folloWing graph when thedegreeof dissociation' (J . ' is plotted against. ( ~)
y
t
IX

x
What is thevalue of D at A?
i d
I
(a) 0 (b) 0. 5
I
(c) I
(d) 1. 5
6. Dissociation of PCl
s
takes place on heating as follows:
PCIs(g) ~ PC1
3
(g) +C12 (g)
'D' is the vapour density of Pels at initial state and 'd' is the vapour density of the
equilibrium mixture. Which of the fol1oWinggraph represents correct variation of the
degree of dissociation' a' against( ~)?
t
/
i
(J .
(J .
(a)
(h)
.'
Q.-
Q.-+-
d
d
i
~
t
(c) (J .
(d)
(J .
Q.- Q.-
~ . . d. . . . . . . . . .
7. For the diss~ciation of PCIs (g),the variation of(l +a)agains{ ~}s represented as: .
1 .
+
/
i
I
~
(a) (1+x)
(h) (1+x)
. '-. .
..-
Q.-
Q.-
d
d
i
~
i
. (c) (1+x)
(d) (1+x)
Q.-
Q.-
d
d
8. Variation of log K with .!.is shown by the folloWing graph. W; for the reaction
T
will be:
.1.---.
T
(a) -19.14 J mol-! (b) +19.14 J mol-I
(6) +4.606 cal mol-I (d) _ 2 cal mol-I
9. For the following isomerisation reaction:
Cyclohexane ~ hexene-J . K ~ j,732'
r
P(hexene-1 )
Pc y c ! ohexene ---+-
,
Vy'hichof the following statements holds good!tpoint 'A'?
(a)Q>K (b)Q<K '
(J)Q=K=I (d)Q=K=1.732.
10. 'For the reaction: R ~ P
Variation of concentration is plotted against time :
p
R
,
, ,
,
,
,
,
,
,
,
,
II
Iime---.
t
I
I' ,
"'Ihich of thefollowing regions show(s) equilibrium?
(a> III (b)1I
(c)r (d) ITand III both
11. Pdrcentage yield of following reaction is plotted against pressure at a definite
tetnperature :
2S0
2
(g)+ 02(g) ~ 2S0
3
(g).
Which of the following relation is correct?
t
%yield
Pr essur e ---+-
(a)T
J
>T
2
>T
3 (b)T
3
>T
2
>11
(c)T
1
=T
2
=T
3 (d) 11 >T
2
<T
3
U. For the chemical equilibrium,
Caco
3
(s)~ CaO(s) +CO
2
(g),
liH.can be determined from which one of the following graphs?
t
~
t
/
(a)
logPC02
(b)
logPC0
2
- 1
1
- - - - .-
- - ---+
T
T
t
~
t
/
(c)
logP
C02
(d)
logP
C02
logT---.
logT---.
I
MATRIX MATCH TYp~j
~
!
Eacihquestion of this section contains statements given in two collunns which have to be
matched. Statements (a, b, c, d) in.column-l have to be matched with statements (p, q, r, s)
inColumn-II. The answers to these questions have to be appropriately bubbled as illustrated
intj>efollowing example. If thecorrect matches are(a-q, r), (b-p, s), (c-r, s) and (d-q), then the
cortectly bubbled matrix will look like the following: .
p. q . r s
a0i1~0
bfrJ @0e
c0@
d0800
1. Match the Column~I with Column-II :
Column-I
(Gaseous Reaction)
(a) H
2
(g)+ CI
2
(g) "" 2HCI(g)
(b) 30
2
(g) "" 203(g)
. I. .. .
(c) S02(g)+22 (g) "" S03(g)
(d) CO(g)+3H
2
(g)""
CH
4
(g)+H
2
0(g)
2. Match the Column-I with Column-II :
COlumn-I
(a) Exothermic reaction dn
g
>0.
(b) Eodothermicreactionl\.n
g
=0
(c) Exothermic reaction with L l . n
g
= 0
(d) Endothermicreactionwithdn
g
>0
3. Malch Ihe Column-I with Column-II :
.Column-I (Reaction)
(a) PCl
s
(g) "" PCI
3
(g)+ CI
2
(g)
(b) H
2
(g)+ 1
2
(g) "" 2HI(g)
(c) N
2
(g)+ 3H
2
(g) "" 2NH
3
(g)
(d) 2802(g)+ 02(g) "" 2S0
3
(g)
Column-II
. (UnitofK
p
)
(P) atm-
1
(q) unitless.
(r) bar-
1I2
(s) atm-
2
(I) bar-
1
Column-II
(P) K
308
1 K
298
=2
(q) K
308
1 K
298
=1/2
(r) No effecl of pressure change
(s) Backward shift on increasing
pressure
Column-II (K piKe)
(P) RT
(q) I
(r) (RT)-2
(s) (RT)-l
4. Match the Column-I with Column-II:
Column-I
(Reaction)
(a) N
2
(g)+ 3H
2
(g) ~ 2NH
3
tJf =-ve
(h) N2(g)+02(g)~2NO(g)
tJ f=+ve
(c) PCI5(g)~PCl3(g)+CI2(g)
. tJf =+ve
(d) 280
2
(g)+02 (g)~ 280
3
(g)
tJf =-ve
Column-II
(Effect on equilibrinm)
(P) Forward shift by lowering of
temperature
(q) Forward shift. by rise in
temperature
(r) No effect of pressUre change
(s) Forward shift by rise in pressure
1
K
5. Match the Column-I with Column-II:
Colnmn-I
(Mathematical operation)
(a) .Divided by n
(h) Multiplied by n
Colnmn-D
(New eqnilibrium constailt)
(P) K
n
(q)
(c) Reaction is reversed.
(d) n-equations are added
(r) K[ xK
2
xK
3
x x K
n
.
'(s) (K)lln
6. '.'atchtheColum,!~I withColuri!-n-I:l f~rthefoIlo~g reac1:j6~: ,".' '.'
, ... '. '.' " NH4H8(s)~'NH3(g)+H2S(gY.>:":/;' ...:.'
.... '
.,' : C"l"mn~i
.(a)Plirti.lI pIesSure ofNH
4
HS(s)
(I) K
p
(c) Total pressureat equilibrium
(d) K
c
.(P)PNH, ~ P H 2S ' .
(CU PNH +PHS .
3 .. ' .2 .
. (r) (PNH, "PH
2
)(RT)-2
(s) Zero
7. Match the Column-l with Column-II:
Column-I
(Relation)
Column-D
(Inference)
Reaction is not at equilibrium
forward Reaction is fast in
direction
(P) Reaction is nearer to completion
(q)
(r)
(a) Q=K
(h)Q<K
(c) Q>K
(d) K >i
(s) Reaction at equilibrium
Match the Column-I with Column-II:
' "
8 .
~:
I
I
Column-I
Column-II
(a) N
2
(g)+ 3H
2
(g) ~2NH
3
(g)
(P) Forward shift by increase
in
pressure
(b) N
2
(g)+ 02 (g) ~2NO(g)
(q)
No effect of pressure change
!(c) CaC03(s)~CaO(s)+C02(g)
(r)
No effect of inert gas addition at
I
constant volume
I(d) NH2COONH4(S)~2NH3(g)
(s)
Addition of in"'lo gas wi!' favour
I +C0
2
(g)
backward direction .(Not at
constant volume)
9.
Match the Column-I with Column-II:
Column-I
Column-II
(Equations)
(Type of proeess)
(a) K
p
>Q
(P) Non spontaneous
~) AGo<RTlog.Q
(q)
Equilibrium
I
(r)
Spontaneous and endothermic
(c) K
p
=Q
(d) T>Mf
(s) Spontaneous
AS
QUESTIONS ""ITH SIN~I.;E
DI~IT AN~-=R
.;:'.;' .1 : ::;<~":," ;" ' .: : . ...
.Th~~/OUCh q"esfionof thissectionisasing1edigitinteger,rangingfrom 0109...
I . :If,t!Ie:eqi1 ilibrium constant of the reaction 2Ill(g) ~H
2
(g)+ 1
2
(g) is 0,25; the
equih1 J riJ lD!-~fofthe reaction H
2
(g)+ 1
2
(g) ~2HI(g)wiIl be__ "
2. .MiXing4moles of Awith 4moles ofB forms 2moles of C at equilibrium, according to
the reaction:
A(g)+B(g)~C(g)+D(g) ,
The value of equilibrium constant is __ " .
3. Fhr the equilibriinn AB(g) ~ A(g)+ B(g), at a givenlemperature .!rd of AB is
I 3
dissociated, then: will be nUl)lerically equal to __
p
4. In areversible reaction, if the concentration of reactants are doubles, the equilibrium
constant Kwill bex times the initial equilibrium constant. x will be equal to __ "
5. For-the reaction, .
I . " " ." A(g)+B(g)~C(g)+D(g), ." . ...
the Inltial concentrations of A and B are equal. The eqUlhbnum concentration .of C 's
mlo times the equilibrium concentration of A. The value of the equilibrium constant
" !
IS_, _"
..
802Cl2 and CI
2
are introduced into a3L vessel. Partial pressure of80
2
Cl
2
and CI
2
at equilibrium are 1atm and 2 atm respectively. The value of K p for lbe following
reaction
r
,
80
2
CI
2
(g)~ 802 (g)+CI
2
(g) is 10.
The total pressure in atmat equihbrium' would be __ '
A reaction at equilibrium involving 2mol each ofPCl
s
,PCI
3
and CI
2
ismaintained at
250C and total pressure of 3 atm. The value of Kp is __ '
For lbe equilibrium of lbe reaction,
NH4Cl(s)~NH3 (g)+HCl(g),K p ;8latm
2
Total pressure equilibrium will be x times lbe pressllre of Nfl
3
The value of x will
be __
('9. What weight of solid ammouium carbamate (NH2COONH4) when vaporised at
, _, ' 200C will have a volume of 8.96 litre at 1 atm? Assume lbat solid completely
decomposes into CO
2
and NH
3
at 200C and 1atm.
At equilibrium, K p ; I,lben lbe value of II.Gwill be equal to __ '
Given lbe hn'0lbetical reaction:
2A(s)+nB(g)~3C(g) K
p
;0.0105
andK
c
=0.45 at 250C. What is lbe value of coefficient 'n'?
12. In a reversible reaction, lbe forward reaction waS 3 times faster than lbat of reverse
reaction. The reaction quotient is __ ' ' ,
: , ;. ..

,,10.
:, 11.
UNKEDCOMPR.EHENSIONTYP~
: ~' ,.'..' .
,' ,: ' : : ==
;;.'~
~; ...;., ;. '-~'. -.
p
'.... " 'AI '
.~"f' ~.. ~_ .
, ' In,a reversible reaction, rate of f<ilwa.rd~actiOn decreasesand that of
"baCkWai' dreaction ,increases wi!h passage of lime; atequilibnum both these,rates
,become equal, chemical equilibrium is dynamic equilibrium Which can be achieved
from either side. " '
The progress of the reaction A ~ nBwith lime is presented in following
figure: "
lO.7
0.5
M 0.3
, 0.1

' "
,7
"
1/
o 3 5
time inhr
7

9
(b) 2
(d) 4
~ Answer the following questions:
IJ The value of' n' is :
I
(a) I
(c) 3
2. The equilibrium constant Kc is :
(a) 1.2 (b)2.4
(c) 1.0 (d) 1.44
The initial rate of conversion of A into products is :
(a) 0.2MIt-I (b)0.15MIt-I
(c) 0.1MIt-I (d)0.05MIt-I
,
P~f(A'iJ,~pll.'l
i Mass acti on rati o or reacti on quoti ent 0for a reacti on can be calculated usi ng
tli e law of mass acti on,
! A(g) +8(g) ~ C(g) +.O(g)
: 0; {CliO]
[A][B]
The reaction quotient Q for:
N
2
(g)+3H
2
(g)~ 2NH
3
(g)
. 2.
isgiven by Q .[NH
3
] '. Thereaction will proceed inbackward direction, when:
[N
2
][Hd .
The value of 0deci des whether the reacti on i s at equi li bri um or not
At equi li bri um, 0; K
For non-equi li bri um process .O *K
when O>'K, reacti on wi llfavollr backward di recti on' and when 0 <K,I t-wi ll
favour forward di recti on.. '.
thus, i he relati ve value of 0wi th respect to equi li bri um constant deci des the
di recti on to whi ch the reversi ble reacti on wi ll proceed.
BAnswer the followi ng Questi ons : .
1.1
I
(a)Q;K
c
(c)Q>K
c
2. For the reaction,
(b) Q<K
c
(d)Q;O
2A+B ~-3Cat298 K,K
c
;49.
A 31. vessel contains 2, I and 3 moles of A, B and Crespectively. The reaction at the
same temperature :
(a) must proceed in forward direction
(b) must proceed in backward direction
(c) must be in equilibrium
(d) cannot be predicted
, .
I
. .
.
..
The reaction is :
(a) endothermic (b) exothermic
(c) may be endothermic or exothermic (d) unpredictable
Percentage dissociation of PCIs may be given as :
(a) 4.04 (b)40.4
(c) 44.0 (d)0.404.
Equilibrium constant K c for the reaction will be :
(a) 0.66 M (b) 0.56 M
(c) 0.46 M (d) 0.36M
If pressure is increased then the equilibrium will .:
(a) be unaffected (b) shift in backward direction
(c) shift in forward direction (d) cannot be predicted
When inert gas is added to the given reversible process then the equilibrium will :
(a) be unaffected (b) shift inbackward direction
(c) shift in forward direction (d) cannot be piedicted
How many axial bonds are there in PCl
s
?
(a) 2 (b)3
(c) 4 (d)5
4.
s.
6.
2 .
3 .
r a S Answer the following Questions:
1 .
2. (d) 3. (b) 4. (b) 5. (d)
7. (b) 8- (c) 9. (a) 10. (a)
12. (a) 13. (d) 14. (a) IS. (b)
17. (d) 18. (a) 19. (d) 20. (d)
22. (d) 23. (a)
24. (a) 25. (c)
27. (c) 28. (c) 29. <a)
30. (a)
32. (b) 33. (d)
34. (c) 35. (b)
37. (c) 38-
(a) 39. (a) 40.
(a) .
42. (b) 43. (a)
. 44. (d) 45. (a)
47. (b) 48- (d)
. 49. (a) SO. .(d)
52. (b)
53.' (d) 54: (cj 55.
:(c) ..
57. (a) 58. '(a)
59: (d)
60. (a)
62. (b)
63. (b) 64. (a)
65. (d)
67. (b)
68. (a)
69. (b) 70. (a)
72. (a) 73. (b)
74. (b)
75. :(a)
77. (c)
78. ,(c) 79. (d)
SO. I (a)
82. (b)
83. (a)
84. (c) 85. (d)
[Answersheet ~
I PANORAMA (liT ROUND-UP)
Multiple Choice Questious with Oue Correct Auswer :
1. (d)
2. (a)
3. (b)
4. (d) 5. (b)
,
6. (a, b, c, d) 7. (c)
8. (c)
9. (c) 10. (a)
I
11. (a)
12. (a)
13. (a)
14. (c, d, e) 15. (d)
I
16. (d)
17. (a) 18. (d) 19. (d) 20. (0)
21. (c)
22. (d) 23. (a)
24. (a) 25. (a)
SECTI ON-!
Straight Objective Type (Single Correct Answer)
1. (a)
6. (d)
11. (d)
1~.-(d)
21. (c)
26. (b)
31. (c)
3,6. (d)
41. (b)
,
46. (a)
. I .
51. (a)
56. (a)
.~1. (b)
66; (d)
,
p. (a)
76. .(d)
81. (a)
86. (d)
I
SECTlON:-J 1
Multiple Correct Answer Type (More than One Correct Answer)
'1. (b, C,d) 2. (a, b;c, d) 3. (a, b, c, d) 4. (a, b) 5. (a, b, c)
6. (a, c, d) 7. (a, b, c, d) 8. (a) 9. (b, c, d) 10. (a,b)
11. (a, c) 12. (a, b, c) 13. (a, d)
SECTI ON:-J 1I
Assertion-Reason Type
1. (b) 2. (a)
3.. (b) 4. (a) 5. (c)
. 6.
(a) 7. (a) 8. (c) 9. (d) 10. (a)
11. (a) 12. (b) 13. (a) 14. (d) 15. (a)
16. (a) 17. (b) 18. (b)
..
1. (a)
6. (d)
11. (a)
SECTION-IV
Objective Questions on Graphical Aptitude
2. (a) 3. (b) 4. (a) 5. (c)
7. (a) 8. (a) 9. (d) 10. (c)
12. (a)
1. (lHj), (b-p, t), (c-r), (<1--<)
3. (>-p), (I Hj), (c-r), (<1--<)
5. (a-s), (b-p), (c-q), (d-r)
7. (....s), (b-q, r), (c-q), (d-p)
9. (a-s), (b-p)' (c-q), (d-r)
SECTION-V
Matrix Match Type
2. (a-q, s), (b-p, r), (c--q, r), (d--p, sJ
4. (a-p, q, s), (b-q, r). (c-q), (d--p,s)
6. (a-s),,(b-p), (c-q), (d-r)
8. (a-p, r, s), (b-q, r), (c-q, r), (~, r)
-,
1. 4
6. 8
11. 3.
SECTION-VI
Questions with Single Digit Answer
~ 1 ~ 8 . ~ 1
~ 1 ~ 2 ~ 6
12. 3
SECTIO~VII
Unked Comprehension Type.
5. 4
10. 0
Paragraph-1
1. (b) 2. (a) 3. (a)
Paragraph-2
1.' (c) 2. (a)
. 3.
(b) 4. (c) 5. (a)
Paragniph-3
1. (a) 2. (b) 3. (a) 4. (b) 5. (c)
6. (0)
.'-',
- ~- - - - - - -
Panorama (liT Round-up ofThirty Three Years)
I l (d) Chemical equil ibriumisadynamic equil ibriumbecauseat equil ibrium,
I rateof forwardreaction~rate of backwardreaction
2. (a) Accordingtothel awofmass action, therateof areactionisdirectl yproportional tothe
I product of concentration(activemass) of thereactants.
3" (b) 2S0
2
(g) +O
2
(g) """ 2S0
3
(g); Mf =-ve
M
g
=2-3=-1
Reaction is exothermic and An
g
is negative, therefor~the reaction " ,ril l favour the F.:
forward direction when temperature is reduced and pressure is increased.
4. (d) Equil ibriumconstant varieswithtemperature:
10g(~:) =2 . : R [ ;1- ;J
~. (a,b, c,d)
I <;H
4
(g)+ H
2
(g) """ C2~(g); Mf =~136.8kJ I mol
The'equil ibriumconcentration of <;H
4
wil l increase wben the reaction wil l shift in
backwarddirection. '
9
1
, (c)2NaN0
3
(s)""" 2NaN0
2
(s)+ 02(g); Mf =+ve
Addition of NaN0
3
or NaN0
2
wil l not affect the equil ibrium because, gaseous
compOnents are not present in both side of the reaction.
It is endothermic reaction, therefore, the reaction wil l shift in forward direction by
, increaseintemperature
10. (a) WhenMg'" 0andthevol umeof vessel is not conStant,,thenaddition of inert gas,wil l
'affeCt the equil ibrium. The equil ibrium shiftStowards higher vol ume direction; thus
I concentration ofS0
2
C1
2
S02 andCl
2
wil l cha:ngeonadditionof hel ium.
12.,(a) "Fe,03is basic oxide, it wil l be neritral isedby HCI hencethereaction wil l proceed in
forwarddirection.
Fe,03 +6HCl -'---> 2FeC1
3
, + 3H
2
0
(Neutral ization)
13. (a) For thereaction:
I
I
15. (d)
H
2
(g) +Cl
2
(g) """ 2HCl (g)
Mg=O
K - K (R T)""-
p- c
K
p
= K
c
2H
2
S(g) """ 2H
2
(g)+ S, (g)
concentration.!. 0.2 fig
at eqUil ibrium 2 2 2
K =[ H,r[ S,J
c [ H
2
S]'
=0.016
[ 0.1]'[ 0.4]
[ o.S]' ,
16. (d) Reactionwil l shiftinforwarddirectionby additionof CO(g), thusformationof CO
2
wil l
be favoured.
. .
18. (d) K
c
1.44 x10-
5
(0.082 x773)-2
19. (d) A+B.,=C+D
o
20
'46
I nitial DJ J I
Q =[CUD]
[A][B)
When time passes, the concentration of C and D will increase while that of A and B will
decrease thus value of Q will increase with time. ~
. N
2
0
4
(g).,= 2N0
2
(g)
100
92
80
Moles at equilibrium
92
20. (e)
21. (e)
23. (a)
. 24. (0)
25. (8)
I nitially: PI' =nRT
I xI ' = 100 x0.0821 x300
92
V=26.77L
At equilibrium: PI' =nRT
Px 26.77 =[80 +20] ,,0.082 I x600
. 92 46 . .
p= 24aim
Equilibrium constant Kp varies with tem~ture and stoichiometry of the rea~on.
At equilibrium: "G =0
'". r.Gp -r.G
R
=0
r.Gp =r.GiI
~, =Gr<;+3G
H
,
Process off ormation is Ag++2NH
3
.,='[Ag(NH3)2]+
Formation constant, K _ tAg(NH3n]+
. [Ag+][NHd
=K
1
xK
2
=3.5x10-
3
xl.74 xI O-
3
=1i08 x10-6
"Go=~2.303RT loglOK
. Mfo-TI!.S= -2.303RTlogK
-57050" -57051og
1O
K
logK =10
SECTION-l : Straight Objective Type (SingleCorrect Answer)
1
1. (8) C0
2
(g).,=CO(g)+-02(g)
2
I-a a
2
K=[al[%r
(I-a)
(a I)
(13/2
.fi
2. (d)
Reaction: 2A+ B ~C +D
,
I K =nc xnD x (! - )A n g
p n~xnB > :n
...(i)
.2a
1-0<
2
K
p
~ (PNH,)
. 2
64=(PNH,)
PNH,=8atm
, Total pressure=PNH,+PH,S
I
. =8+8=16atm
. N
2
0.(g ) ~ 2N02(g )
,
'0 1 0 I .n =I - a +2a =1+ a
9. (a) I
lin=2-1=1
. g
(2a)2 '( P )'
Kp= (I _a)x ~
2
K =~P
p _1_a
2
[
KJP )" 2
a= 4+KJP
bGo= -2303RTlog
1O
Kp
=- 2303 x 8.314x 29810g (6.1x I O"')
=+24048llmol =+24kJI mol
12. (a) ILesser is the percentage dissociation; greater is the vapo.~density.
1 3 I
15. (h) H
2
0(g )r'H
2
(g )+- O,(g ) ling=--1=-
2 2 2
8. (0)
PV =r.nRT
V I . n
_=_ . . . (ii)
RT P
fromeqs.(i)an d(ii) .
I .
. I K =ncX"Dx~
.p nA xnB RT
5. (d) (i)Xef
6
(g )+H
2
0(g ) r'XeOf.(g )+ 2Hf(g ); K[
(il)x eO.(g ) +Xef
6
(g )r' XeOf.(g )+XeO,F,; Ki
R~ equalion : x eO.(g ) +2Hf(g )r' Xe03f2(g )+H
2
(g ) .
I t is obtain edby subttaetin g (i) from(ii), hen ceequilibriumcon stan tof therequired
" - . - , - - . - . . - .
ilion will be:~~. '.
7.(h)PNl- t, =PH,S
'",
1-0<
a
a
2
. .
112
1> " , x'b ( P ) " " g
K= 2
X
_
P " H f J En
~ a x ( % r x ( _ P ) 1 1 2
(I-a) 1+0.12
a.31 2
p
1 I2
(1-0.)(2+ 0.)112
17. (d) NH 2-COONH 4 -->2NH
3
(g) +C02 (g)
D ~ Mw ~ 78~39
2 2
D-d 39-13
o.~--~
(n-I)d (3-1)13
Ln~ O.5+ 1.5+1~3
1 - 0 . 5 3 - 1 . 5
1N H , ~ XNH, xP
I P
=-xp=-
3 3
Equilibrium will shif t in backward direction when volume is increased, thus number of
moles of H z will-inCrease.
A
2
(g) +B
2
(g)'" 2AB(g)
'0 2 4 0
'0
'" , .
At constant volume, there is noef f ect of inert gas addition.
NH
3
(g)" ''!' N
2
(g) +~H
2
(g) K
c
~ 4 .
2 2
:. K
c
f or.thef ollo~ reaction:
N
2
(g)+3H
2
(g)'" 2NH
3
(g) l > ng ~2'-4~-2
will be equal to~
4
K
p
~ Kc( RT) " '"
~ ~ x(800x R) -2 ~ [ I J 2 ..
4 4xSooR
N
2
(g) +3H
2
(g)'" 2NH
3
(g)
1 3 . 0
24. (a)
27. (c)
23. (a)
20. (d)
21. (c)
2 -x 4-x
4 4
2x
4
[AB]2
K ~~~-
c [A
2
)[B
2
]
4~ [2xl4]2
( 2 ~ X ) ( 4~ X ) .
4x
2
4~---
x
2
-6x +8
x
2
-6x+ 8 =x
2
8 4
X=-=-
6 3
2x 2 4
(AB) =4=4 " x3"=0.66
28. (c) The.given reaction will go in backward direction:
1
C(g)+D(g) "" A(g) +B(g) K
c
=0.25=4
'0
l eq. 1-0: 1-0: 1+0: 1+0:
4=(l+ai
(l_a)2
2=(~) .
I-a
2-2a=l+a
. 1
a =3"=0.33
[A]=l+o =1+0.33=O.l33M
10 10 ..
29. (a) Hg(1) "" Hg(g) dng =1
. 0.002 .-6
K
p
= 760 =263xlO aim
K
p
=Kc(RT)"" .
K =K
p
_ 263xlO-6 -1068 x10-7M
c RT. 0.0821x3oo.
30. (0) K [RNH!][OIr]
[RNH
2
l.
8x10-6 = xxx.
0 . 5
x= 2x10-
3
.
[OIr]= 2xlO-
3
M
pOH =-log 2x10"3
=2.7
K 005 5x10-
5
33. (d) K - p - . =__
c - (RT)"" (1000xRl R
34. (c) For association of molecule
d-D d-'1J
a=" =- __ ~
d(l-~)d~ - n ,
2(d-D)
d
<'
0.184
35. (b) Addition of inert gas will shift the equilibrium towards higher volume direction
PCI
5
(g).,. PCI
3
(g)+CI
2
(g)
Thus, addition of inert gas at constant pressure will in~reasethe dissoci~tionof pel s.
36. (d) a Mo-M 92-77.7
(n-I)M .(2-1) x77.7
% Dissociation =18.4 .
37. (c) Stability oc' I
Equilibrium constant foe dissociation
38. (a) t.Go= -2303RTlog
lO
K
=-2303 ';8.314 x298 log (4.42 x10
4
)
=~26506J mol-I
=-26.5 kJ/mol
...(i)
...(ii)
a a
. I-a
. [ ] 2
a fJ .
K = I +c;: 2
. P2 '.[ I -a ]
--p;,
I +a
. 2
0
a " -2.
=~_a2
K
pI
=4a
211
/ a
2
p ; '
K l-a
2
l-a
2
.
P2 .
.'.=411 .
9 p ; ,
II=...'...
p;, 36
2a I-a
t1GO=-nFEO
When EO is negative, "AG0WI ll be positive.
t.Go= -2303RT loglOK
When t.Go is positive, then the value ofKwill be less than L
Kp=Pco,
K
2
Mf [ 1 I J
logK
I
=2303R 11- T
2
1" 0.34 = Mf [ _1 '_]
.g 0:14 2303x8.314 400 420
Mf =62 kJ/mol
pNH
3
=pH
2
S =0.33 atm
Kp = PNH] xPH
2
S
=0.33xU33'= UI 09atm
2
X~2Y Z~.p .+Q ' .
o I 0 0 '0
'..
[
'2 ] 2'
K _ ~II
PI - [ I .-.a ]
--II
I +a
4a
2
R
=__ 1
1_0.
2
43. (a)
40. (a)
46. (a)
47. (b)
48. (d) The reaction is :
N
2
0
4
(g)..,. 2N0
2
(g)
2
TIme--+-
Rate
i
(a) ~orward
(c) No net reaction
In the following reaction:
I 2S0z(g)+Oz(g)~2S03(g) .
the fquilibrium is not attained. The. rate of forward reaction is greater than that of
backward reaction. Thus, which of the following is the correct relation betyieen Kp
anci'Q ? -
I P'
(a)(.p =Qp (b)Qp >Kp
(c){?p <K
p
(d)K
p
=Qp =1
In the reaction:. .
I . . PC15(g)~PCI3(g)+aZ(g), . '.' .' .
a l:\Sph is plotted to show the variation of rate of forward and backward .reactions
against time. Which of the following is correct? .
I Forward
t
In areaction mixture containing H z ,N z and NH3at partial pressure of 2 atm, I atm
and a atm respectively, the value of K
p
at 725 K is 428xIO-
5
atm-
Z
In which
d
. I . th "II?
rre~tlOn enet reactIOnWI go.
N
z
(g)+3H
z
(g)~ 2NH
3
(g)
(b) Backward
(d) Direction cannot be predicted
5 .
4 .
3 .
I
Q>K
(a) 3
,(6)' I
(ci 2
(d)~' 2
Par~!"pA:3
Q<K
I
3
I
3
,
Phosphorus pentachlori de(pQ
s
) has tri gonal bi pyrami dal geometry. I t has
two types of bonds called axi al and equi tori al bonds: axi al . bonds are weaker
because they are bi gger i n length.
PG:l
s
when heated i na sealed tube at 700 K, i t undergoes decomposi ti on as,
I PCls (g) ~ PCI
3
(g) +CI
2
(g) . .
I ts equi li bri um constant Kp i s 38 atm at 700 K. The degree of di ssoci ati on a
may be gi ven as
'1 D-d
. a=~forPCls
where, D= I ni ti al vapour densi ty and d=vapour densi ty of equi li bri um mi xture,
whi ch i s equal to 74. 25.
I .
. .
20'
n~2anda ~- ~0.2
100
D~4.6, initial vapour density
d ~ vapour density at equilibrium
D-d
a~---
(n-I)d
0.2~ 46-d
(2-I)d
d ~ 38.3
. Molar mass equilibrium ~2x 38.3~76.6
Pm =dRT Here, d = density of gas mixture
d(mix)~ P m _ 1x76.6 - 3J 2g,L
RT 0.0821 x300
51. (a) Inthereactionqs)+H
2
0(g),=CO(g)+H
2
(g)
t J . n
g
> 0,_hence the reaction will shift in forW ard direction by increasing volume (or
lowering the pressure).
54. (c) Addition Cu(s) .will not cbange .theequilibrium because: '
K _ [Fe
3
+r
[Cu
2
+][Fe
2
+r
59. (d) 2NH
3
(g),= N
2
(g) +3H
2
(g) .
t " " 0 2 0 0
'",-
112 3/2
60. (a)
63. (b)
64. (a)
D-d
a~---
(n-I) d
0.5 _ 4O-d
(1.5-1) d
0.5 xO.5d ~ 40-d
1.25d ~ 40
d~ 32
Unit of K
c
= [Unit of c.once~tra~ion.]AIl
~[mol dm-
3
] (&~-1)
~dm3 moI-
1
20
pNH
3
=pH
2
S ~"2~10aim
K
p
~ pNH
3
xpH
2
S
~100 alm
2
. ~'
K'~-.1- I
.[K;.J 25 xlOs
K, '"5x10-
3
o
3
3.2
02
3.1
01.
'''I
" "
K
p
~Kc(RT)
100 ~K
c
(0.0821 x400)'
K
c
~ 0.092M'
The reaction includes only solid species hence Le Chatelier's principle is not applicable
to it.
For endothermic reactions, the equilibrium constant increases with increase in
temperature.
An
g
>.0, therefore by decreasing the pressure and by introducing inert gas at constant
pressure, the equilibrium will shift in forward direction.
K~[B][CJ _ 0.15x0.05 ~7.5
. [A] Ix10-3
l1Go~ -2303RTlog
1O
K
~-2303 x8.314 x298 log7.5
~-4992 J mol-I
~-4.992 kJ mol-I
~- 5 kJ mol-
1
In the reaction 2C(s) +O,(g) r=2CO(g)
""c '" 0hence Kp and K
c
will not be equal.
Kp does not depend on the equilibrium pressure.
I I 1
-I', +-Q2+-R, r=PQR
2 2 2
I I
-P,+-Q,r=PQ
2 2 .
I
PQ+2
R
,r=PQR
K~ ~xK2- I x5xlO-3
"K
1
.J25xlO
s
~I xlO-
s
Fe
3
++SCI< "" [Fe(SCN)]'+
1
68. (a)
I
70. (a)
74. (b)
!
75, (a)
I
76: (d)
77.1 (c)
,
78. (c)
79'1'(d)
'0
I
I
80. (a)
81. ia)
I
3
K~--~150
0.1x0.2
K~Antilog [ 2; ~~OT]
-Antilo [ -78x1000 ]
- g 2303x8.314x1000
~. 8.4 x10-
5
K PTrans-2.butene
p PCJs.2.butene
~0.290 ~3.4
0.085 .
..
. '
82.(b) CO
2
(g)+C(s) ;:=' 2CO(g)
~ Q5 0
1 1 . (O.5-.x) 2x
Total pressure =(0.5- x) +a=(0.5+x)
0.8=0.5+x
x=0.3 aim
Pro, : (0.5- 0.3) : 0.2aim
Pco =a : 0.6aim
2 2
K : Pco : (0.6) : 1.8
p P 0.2
co,
83. (a) We know, /1G: l!Jl - TI1S
.: /1G : 0at equilibrium,
:. T:l!Jl -95x1000 500K
I 1S -190
84.(c) 2S0
2
(g)+O
2
(g)~ 2S0
3
(g)
. I
S03(g)~ S02(g)+Z02(g)
. 1l5.(d) N2(g)+02(g)~ 2NO(g)
NO(g)~ .!.N
2
(g)+.!.02(g)
2 . 2 .
K
j
: 278
. K
2
: ~.: 0.0599=6x10-
2
,,278
K
j
.: 4x 10-4
1
K2:~~~:50
~4x10-4
x
B
o
x
The given reaction is :
2A ~
0.12375
(0.12375 - 2x)
K: [B]
[At
Hi
(0.12375 - a)2
'",
1=0
86. (d)
00solving we get,
'x" 0.05mol L-
1
i.e., [B]: 0.05 M
SECTION" 'I!: Multiple Correct Answer Type (More than One Correct
Answe~ .
1. (b,c,d) Unit of K
p
=(Unit ofpressure)""-
Unit of K
c
=(mol L-
1
)"'"
. An
g
=Number of gaseous moles of products - Number of gaseous moles of reactants
D-d
3. (a,b,c,d) In the reaction: u.=--'-
(n-I)d
n = Number of gaseous moles of products formed by .1mol of reactant
In all the given r~actieins. n moles of products are formed by 1 mol'ofreactant.
4. (a, b) AB
2
(g)..---- A(g)+ B
2
(g) I1ng: I
This equilibrium will shift in bac~arddirection by increasing thepressure i.e., degree of
dissociation (a.) will decrease with increase in pressure or decrease in volume.
"
. ,
6H =-ve Exothermic
5. (a, b,~) Positive catalyst only alters the equilibrium time. The amount of product, heat of reaction
and equilibrium constant remain unaffected by the catalyst.
8. (a) Rate constant of a reaction and ionic product of water both increase with increase in
temperature. Equilibrium constant of exothermic reaction will decrease with rise in
temperature.
k =Ae~EQIRT '" (i)
loglO(K
2
) =~[~-~] '"(il)
K
1
2.303R 1) T
2
Equation(i) showstherelationbetweentemperatureandrateconstant, whileequation (ii)
shows relation between temperature and equilibrium constant.
9. (b,~, d) Haber's process of ammonia manufacture: .
Fe/Mo
N
2
(g)+3H
2
(g)~ 2NH
3
(g)
M
g
=.2-4=-2
Formation of anuilonia will be supported by (i) catalyst (Fe) (ii) promotor (Mo)
(iii) increasein pressure. (forwardshift).
.10. (a, b) We know
... (i)
.. , (ii)
11. (a, <)
fiG ;"fiG'+2.303RT (oglo Q
At eqtiilibriwn fiG =oand Q'=K
... 0 =fiG'+2.303RTlog
IO
K .
fiG'= -2.303RTlog
IO
K.
fiHo-TtiS= -2.303RTlog
IO
K
t:J{0 ~o
---+- =2.303RTlog
1O
K
RT R
(i).!N
2
(g)+.!02(g) ~NO(g)
2 2. .
NO(g)~ .!N
2
(g)+.!02(g)
'. 2 2
I
K
2
xK
4
=I Since, K
4
=-
K
2
,(ii) ~N2<K)+~02(g)~ NO(g) K
2
2NO(g)~ N
2
(g)+02(g) K
3
I l'
NO(g)~2N2(g)+202(g) ,fK;
I
Here, K2 =.J 3
i ., K
2
,fK; =I
SECTioN-III: Assertion-Reason Type
1. (Ill Catalyst alters the rate of reaction, In reversible reaction, the rate of forward and
I
backward reactions are affected equally. Thus, catalyst does not aiter the position of
equilibrium.
3.~) fiG =fiGo+RTl0IleKc
At equilibrium, fiG =0
.. 6Go=-'RTl01le K
c
', '
8..(0)
K
_K1I2
2 - I
Thus, equilibrium constant changes with the stoichiometric coefficfent of the reaction.
8. (0) When Q
c
<K
c
' thenthereaction will befast iil forwardreaction. Thus, statement-2 is
wrong.
9. (d) For thereaction: PCls(g) "" PCl,(g) +Cl
2
(g)
the equilibrium will change by changing the vqlume of vessel but the eqnilibrium
constantK
c
will beunaffected. .
12. (b) PCI,(g)"" PCI, +Cl
2
(g)
M
g
> 0, volume of vessel is not constant. <;'
Thus, addition of inert gfS will shift the equilibrium towards highervolwne direction i.e.,
in forward direction.
14. (d) A+ B ""C+D K
1
C+D ""A+B K
2
K
2
=_1_i.e., equilibriumconstantwill bereceprocatedwhenthereactionisreversed.
K, '. . . ..
SECTION-IV: Objective Questions on Graphical Aptitude
1. (0) Accordingtovan't HoffeqUation:
[
M iO ] 1 !>So
10gK= -2303R x1'+]/
Y=. M xx'+ C.
WhenlogKisplottO doi.nnst.!., wegetstraightlinebaving sloP!'~~ to[- M io ] .
. '. T, 2303R
. '. .
For exothermic.reaction, slopeof thelinewill bepositive,
3. (b) Conceiitrationof[N021will decreasewithinCreaseincoiuoentration[N
2
0
4
1.
D-d
s. (c)u=--
(n-I)d
At 'A', a, =9
. D-d
0=--
(2-I)d
D
-=1
d'
7. (0) For thereaction:
PCI,(g) "" PCl,r!?)+ C1
2
(g)
D-d D-d
u=---=---
(n-I)d '(2-I)d
D
(1+u)=-
. d
Thus, (1+ a)will linearly increase with increase in Did.
M io
Slope=---
. 2303R

2303 x8.314
M!0= -2303x8.314 =-19.14 ] mol-
1
9. (d)
At point 'A',
Q =tan 60= 1.732
Q=K
UnltofK
p
Unit cell
bar-
1I2
atm-
2
o
.,1
1
2
- 2
K
308
= 2
K
298
,
We know
(Exothennlc)
AH=+ve~
H
2
(g) +CI,(g) , ' 2HCl(g) ,
32(g)~203(g) .
, ,,' 1 '
S0:i (g) +22(g) ~S03(g)
, ,
CO(g}+ 3H
2
(g) ~ CH.t (g) +H
2
0(g)
2.(a-q, s)(&-p,r) (<-'-'<I, r)(" " -i>, s)
, ~'-->There will be no effect of pressure change, on the equi1ihri,um.
, K I' .
M!=-ve--> 308 =_
K
298
' 2
(Endothennlc) ,
t.n
g
>0 --> The equilibrium will sbift inbackward direction by increasing thepressUre.
3.(a-p)(b-'q) (c-r) (d-s)
Use the relation:
Kp ;", (RT)"'"
K
c
where Ang =Number of gJ:Seous moles of products i
- Number of gaSeouS moles of reactarits
I
10. (c) In region (1), the concentration of reactants and products are constant nen" " this region
shows equihbrium.
11. (a? Reaction is exothennlc, therefore, its yield will decrease with increase in temperature.
12. (a) Forthereaction,CaC03(s)~CaO(S)+C02(g~ K=P
co
,
M!0 I
10glOK =10glOA ---x-
2303R T
, . M!0 I
logtoPco =logtoA---'-x_
, 2303R T
The reaction i; endothennlc, therefore, loglo Pco, will linearly decrease with increase in
the value OfO)
SECTION-' V :,Matrix Match TYpe
1. (a-'q) (!>--p,t) (c-r)(d-s)
Unit of Kl' =(Unit of pressure) " '"
Reaction
, .
i.e.,
4. (a-p, s) (I>-q, r) (c-q)(d-p, s)
Mi =-ve --> Forward shift by lowering of temperature
(Exothennic)
Mf =+ve --> Forward shift by rise in temperature
(Endothennic)
6n
g
=0 --> No effect of pressure change
6ng <0 --> Forward shift by rise in pressure
6.(a--'S) (b-p) (c-q) (d-'-r)
In the reaction, NH4HS(s)~ NH
3
(g) +H
2
S(g)
To K.pressure at eqnilibrium =PNH, +PH,s
K
p
=PNH
3
rPH,s
. NH
4
HS(s) is solid, its partial pressure will be zero.
K
p
=Kc(RT)"'"
K
c
=Kp(RTf"'" =[PNH, XPH,s](RTrz
9. (a--'S) (b-p)(e-q) (d-'-r) .
Where Kp > Q ; The reaction will proceed in forward direction spontaneously.
When aGo<RTlog" Q then aG =+veand the process will be non spontaneous.
aG =aGo+RTlog"Q
WhenK p =Q ; then reaction will be at equilibrium .
aG =Mf -T!1S
When Mf =+ve(Endothennic); then process will be spontaneous when
Mf-Tas<O
T
:Mf.
>-
as
SECTION-VI: Questions with Single DigitAnsll'i
1. 2fn(g) "" HZ(g) +Iz(g) K
c
=Q25
For: H2(g)+Iz(g) "" 2fn(g) Kc = o.~5. =4
2. A(g)+B(g),=C(g)+D(g)
'0
4 4 0 0
'"".
4-Z 4-Z Z z
K _[CJ(
D
l_2x2_
1
c - [AJ(B]- 2x2-
3.
AB(g),= A(g)+B(g)
'0
0 0
1 -. ! .
1 1 2 I 1 4
teq..
llt=-+~+-=_.
3 3 3
3 3 3 3

.!-=8
K
p
4: Equilibrium constant does not change on changing the concentration of reactants.
5. A(g)+ B(g) .=C(g)+ D(g)
x =2(a-x)
3x=2a
2
X=-Q
3
2 I
{A]={BJ= a-- a=- a
3 3
2
[C]= [D]=-a
. 3.
'0
'" ,.
a a
Q-X a-x
o
x
o
x
2 2
K =[C][D] =' 3
ax
' 3
a
=4
C [A][B] . .!.ax.!.a .
3 3
. 6. .S02C1i(g).= S02(g) + C1i(g)
1atm x arm 2attn
xx2
K=-=10
p 1
x= 5 atm
Total pressure of eqUilibrium =1+5+2=8atm .
7. PCls(gh=' PCl
3
(g) +C1
2
(g)
K =" Pel, x 'tl, x (!-] '
p " Pel, l:n
=2; 2
x
[ H =1
8. NH
4
C1(s).= NH
3
(g)+H CI(g)
K
p
= PNH
3
XPHCI
81=] 1
p=9alm
Total pressure =PNH , x /?H CI =18aim
Thus, total pressure is 2 times the pressure ofNH
3
.
9. PV =nRT
..

10.
11.
1 2 .
1x8.96 =n x0.0821 x473
n =0.23
NH
2
COONH.(s) --->2NH
3
(g)+ CO
2
(g)
0.23
"NHplONH, =-3-
=0.0767
Mass of NH
2
COONH. =0.0767 x74
'" 6g
!>G'=2303RT 10glOK
p
WhenK
p
= I, !>G'= 0
K
p
=Kc(RT)""g
om05 =0.45 (0.082 x523)""-
0.0233 =(0.082 ><523)"""
0.0233 =(42886)"""
logO.0233 =l>nglog 42886
-1632 =!>n
g
x16323
!>n
g
=-I
3-(2+n)= -I
2+ n =4
n= 2
Rate"offurward reaction
Q .Rate ofbac~ard reaction 3

When Q > K
c
.; the reaction will proceed in backward direction to attain equilibrium.
Q [ct [3/3t 27 =6.75
[Ar[B] [ Hm 4
Q (6.75) <K(49)
2. (a)
SECTION-VII: Linked Comprehension Type
IPlII'tlgTaph-l:
I
I 0 1. (b) Intl!e reaction.A ~ nB, n =2obeCa~ in four brs, decrease in corn:entration of A is
twice ofintrease in the concentration of [B].
I From1--->5hrs
~l>(A] ;'0.5 - 0.3 =0.2 M
+l>(B]= 0.6-0.2 =0.4 M
2. (a) K
c
=[Br =[0.61' =0.36 =1.2
o [A] 0.3 0.3
3.(a) _l>(A]=0.7-0.5=0.2Mh-
t
! > t 1
Paragraph-2 :
1. (0)
3. (~)

The reaction will proceed in forward reaction to attain equilibrium.

3. (b) The reaction is :
N2~)+3H2~)~2NH3~)
drn 3
2
'
Q - l =--=45
p PN xFfI 2xI
3
'i
, 1
Qp >Kp ; hence this reaction will proceed in backward direction to attain equilibrhnt.;
i.e., reaction will ba fast in backward direction. ' "
4. (0) When the reaction is fast in forwilrd reaction then Q
p
<Kpo The value of.Qp shaull
increase till if becomes equal to Kpo
Paragraph-3 :
1. (~) pels decomposes on heating, hence the reaction is endothermic.
2. (b) a=D-d=104.25-74.25 0.404
d 74.25
% Dissociation =a xloo =0.404 x100 =40.4
K
p
=Kc(RT)"'"
38 =K
c
(0.082 x 700)'
K, =0.66
4. (Ii) PCI5~)~I'CI3~)+CI2~)
t.n" =2-1= I
:. Reaction will sbift in backward direction when the pressure in increased.
5. (0) ,In the given reaction,
t.n" >0, hence the reaction will sbift in forward direction hy adding inert gas. On
',addition' of inert gas, the reaction sbifts in adirection of higher volume.
6. (a) "Inpels, there are lwoaxial and thiee equitorial bonds"
DO