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3. Action of heat i) Colourless, odourless gas is evolved May be salt contains carbonate
Pinch of salt is heated which turns lime water milky ion.
in a dry test tube ii) Colourless pungent gas, turns May be salt contains sulphite
acidified potassium dichromate paper ion.
in to green.
iii) Reddish brown gas is evolved, May be salt contains nitrate ion.
which turns ferrous sulfate solution
into brown or black. Zn2+
i) Yellow when hot, white
when cold. Pb2+
ii) Brown when hot, yellow
Residue is observed when cold. Fe2+
after heating. iii) Original light green salt
changes into reddish brown.
iv) Pale brown changes to Fe3+
black.
v) Green changes to yellow. Ni2+
vi) Residue is black in colour. May be Cu2+, Fe3+ Mn2+, Co 2+
vii) Decrepitating sound Lead nitrate or barium nitrate.
viii) Condensation of water May be hydrated salts like
vapours copper sulfate, nitrate etc.,
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EXPERIMENT OBSERVATION INFERENCE
5. Solubility test
Salt mixture + water i) Soluble May be nitrate, sulfate and
chloride salts
ii) Insoluble May be carbonate sulfide and
sulfite(except amm.carbonate).
Salt mixture + dill HCl Soluble May be carbonate or sulfite or
sulfide
Preparation of sodium carbonate extract: Take 0.5 g of the given salt mixture + 5g sodium carbonate + 20
ml of distilled water and boil this content for about 10 minutes and then filter. The filtrate is used for the
anion analysis and also for the confirmatory test. The filtrate is sodium carbonate extract
Group –I anions
Anions identified by using dilute H2SO4 ( CO3 , SO32- NO2- CH3COO-and S2-)
2-
2
carbonates are removed
then add neutral FeCl3.
Group II anions;
Identified by using conc. H2SO4 (Cl , Br , I , NO3-, CH3COO-).
- - -
Confirmatory test
S.E or W.E + dil White curdy ppt, soluble in excess Cl- is confirmed.
HNO3 till effervescence of ammonium hydroxide solution.
ceases + AgNO3 solution.
ii) Violet vapours appear. May be I-,
May be I-,
Violet vapours intensify
May be I-,
Turns to blue-black
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Add MnO2 iii) Reddish brown gas is May be NO3-, Br-
and heat it. evolved.
. Check the Reddish brown gas intensifies May be NO3-
gas with starch paper. Reddish brown gas does not May be Br-
intensify
Confirmatory test
S.E or W.E + dil
HNO3 till effervescence Yellow ppt, dissolves in excess of Br – is confirmed.
ceases + AgNO3 solution. amm.hydroxide solution.
Add
piece of copper turning or
paper ball. Brown ring at the junction of two NO3- is confirmed.
liquids.
Confirmatory test
S.E or W.E + dil
HNO3 till effervescence
ceases + AgNO3 solution
iv) Smell of vinegar. May be CH3COO –
Confirmatory test
S.E or W.E + dil
HCl is added till all
carbonates are removed
then add neutral FeCl3.
-- Heat the red
colour solution.
Note : In all CT for anions the order should be WE or SE ,as only SE has to be acidified with acid (to
remove the CO32- which would otherwise give ppt with any reagent ) .if WE is used you do not need to
acidify
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CATION ANALYSIS
Preparation of original solution for cation analysis: original solution is prepared by dissolving the salt
mixture in any one of the following solvent.1. Water 2. dil. HCl 3. dil. HNO3 4. conc. HCl
EXPERIMENT OBSERVATION INFERENCE
0. Salt mixture + NaOH Gas evolved turns moist red litmus Group 0 present. NH4+
solution and heat. blue and gives dense white fumes may be present.
with glass rod dipped in conc.HCl
Confirmatory
test Reddish brown precipitate. NH4+ is confirmed.
Salt + NaOH, pass the gas
evolved through Nessler’s
reagent.
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Confirmatory test for Cu2+
Boil the precipitate with 5 ml
of 50% nitric acid. Blue colored solution is formed Cu2+ may be present
Divide the solution in to two
parts.
Part I + NH4OH soln. little Pale blue ppt, dissolves in excess Cu2+ is confirmed.
and then in excess. of amm.hydroxide solution.
Part II +freshly prepared White ppt formed which turns Hg2+ is confirmed.
stannous chloride (SnCl2) black.
solution.
Confirmatory test for Sn2+ Brown ppt dissolves Sn2+ may be present
Boil the ppt with yellow
ammonium sulphide
solution.(NH4)2S
Divide in to two parts
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Boil the filtrate of group II to Precipitate colour: Group III present.
expel H2S. Add few drops Gelatinous white Al3+,Fe2+, Fe3+
conc. HNO3 + pinch of Brown Cr3+
NH4Cl(s) +NH4OH solution Bluish green or grey green
in excess.
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Filtrate of group III + pinch Precipitate formation Group IV is present
of NH4Cl(s) +NH4OH + H2S Grayish white Zn2+,Ni2+,Mn2+ may be
gas. Black present
Buff coloured
8
Boil off H2S from filtrate of
group IV and reduce the
volume of the solution to 1/3 White ppt Group V is present
by heating. Now add pinch May be Ba2+, Sr 2+ , Ca2+
of NH4Cl(s) +NH4OH
solution + excess of
ammonium carbonate
solution.
Dissolve the ppt with
hot acetic acid and divide in
to four parts.
Ba2+ is confirmed.
To the 1st part add Yellow ppt of barium chromate is
pot.chromate. formed.
Ba2+ is confirmed.
nd
To the 2 part add dil H2SO4. White ppt is formed. Insoluble in
all mineral acid.
To the 3rd part add 1ml of Sr2+ is confirmed.
concentrated ammonium Formation white ppt of strontium
sulphate solution and warm. sulfate.
Note :
1. In Gp V –if you have to follow the order of Ba2+, Sr 2+ , Ca2+ eg , if your salt contains Sr 2+ , then you have
to write the tests for Ba2+ and say ppt not observed , hence Ba2+absent .Then go on to write test for
Sr 2+ .
2.CT for Mg2+ ----Boil the filtrate of group V to reduce the volume .Filter ,if necessary .To the clear solution
add an excess of disodium hydrogen phosphate and a few drops of ammonium hydroxide. Shake well and
scratch the walls of the test tube with a glass rod → White crystalline ppt on standing