II.

Materials and Methods

A. Apparatus and Set-up
Equipments
Digital thermometer with thermocouple probe
Top loading balance
Immersion heater
Syringe, 1-m! "olumetric #as$, bea$er, iron stand and iron clamp
%ig 1.1. The temperature-monitored "apor density &T'(D) set-up.
The *gure abo"e shows the schematic drawing which will be used in this
e+periment. A 1 m! "olumetric #as$ that is almost completely
submerged in a water bath is *tted with a Te#on plug. The Te#on plug was
drilled with a 1,-. in.hole /or gas e+pansion and a larger hole were a tight
*tting stainless steel thermocouple probe is inserted. The said
thermocouple probe is connected to a digital thermometer. The water bath
is $ept at atleast 1

0 abo"e the boiling point o/ the sample.
1. 2eagents
.3 ml acetone
.3 ml .-butanone
.3 ml Ethyl acetate
.3 ml Dichloromethane
.3 ml methanol
0. 4rocedure
Dry, empty 1 ml "olumetric #as$ with Te#on plug
5eigh
4reheat with water bath until the temperature is 1
o
0 below
the boiling point o/ the sample
5eigh .3 ml sample
.3 ml sample
2eturn to water bath &complete the assembly6 attach the
thermocouple probe to the digital thermometer
0ontinue heating
Start reading the thermocouple temperature at 3 0 below
the boiling point o/ the sample
0ontinue reading the temperature &/rom the digital
thermometer) at 1-second inter"al6 Stop reading when
thermocouple temperature is . 0 abo"e the boiling point o/
the sample &or when the in#ection point is attained)
2emo"e the #as$ assembly6 weigh while still hot.
d7.8
5eigh #as$ at room temperature
98TE: Two trials will be done /or each sample.
III. Data and 2esults
Table 1.1. (apor pressure o/ saturated liquid water /rom .3
o
0 to -3
o
0;.
Temperature (
o
C) Vapor pressure(MPa)
25 .-1<==
26 .--<-=
27 .-3<>1
28 .-?>-1
29 .@=.
30 .@.@?
31 .@@=<=
32 .@?3=<
33 .3-3@
3 .3-.31
35 .3<.=
Table 1... Density o/ saturated liquid water /rom .=> A to -1 A.;
Temperature (!) "ensit# ($%&m
3
)
298 ==?.@.
300 ==<.31-
302 ==3.=@>
30 ==3.-@<
306 ==@.?11
308 ==@.@.
310 ==-.-@.
; Perry's Chemical Engineering Handbook. &.>). BSA: 'cCraw 7ill Inc.
Table 1.-. Theoretical molecular weight and boiling point o/ the samples.
'ample Theoreti(al Mole(ular
)ei%ht (%&mol)
*oilin% Point ()
+(etone (C,3C-C,3) 3>.> 3<..
2. /utanone
( C,3C-C,2C,3)
?..11 ?=.<
0th#l a(etate
(C,3C--C2,5)
>>.11 ??.<
"i(hloromethane(C,2Cl2) >@.=- @
Methanol(C,3-,) -..@ <3
;7andboo$ o/ 0hemistry and 4hysics.&1=><).<?
th
ed.1oca 2aton, %lorida:020 4ress
Inc.
Table 1.@.Thermocouple temperature readings o/ the "olatile liquid samples
obtained at 1-sec inter"als.
Time
&s)
Thermocouple temperature
Acetone .-butanone Ethyl acetate Dichlorometha
ne
methanol
T2IA!
1
T2IA!
.
T2IA!
1
T2IA!
.
T2IA!
1
T2IA!
.
T2IA!
1
T2IA!
.
T2IA!
1
T2IA!
.

1
.....
Table 1.3. E+perimental 0onditions during the e+periment.
2oom temperature &T26
o
0)
1arometric 4ressure &416 atm)
2elati"e 7umidity &27)
0orrected barometric pressure &4c, atm)
Ta/le 1161 ate222help2 di na po namin maisip $un%
ano dapat title n% ta/le na to2 ,ehe1
'ass o/ dry, empty 1 m! "olumetric #as$ with Te#on
plug &g)
'ass o/ preheated 1 m! "olumetric #as$ with Te#on
plug &g)
'ass o/ "olumetric #as$ with water &g)
'ass o/ water &g)
Temperature o/ water &
o
0)
Density o/ water &g,m!)
(apor pressure o/ water &4
;
7.8)
(olume o/ water D "olume o/ "apor &(")
Table 1.?. 4arameters needed /or the calculation o/ the molecular weight o/ the
gi"en sample /or trial 1.
Sample Trial 1
'ass o/ "-#as$ &when
temperature is .
o
0 abo"e
bp, g)
'ass o/ "apor
&m", g)
In#ection
temperature
&Ti, A)
'olecular
weight o/
"apor &'",
g,mol)
Acetone
.-butanone
Ethyl acetate
Dichloromethane
'ethanol
Table 1.>. 4arameters needed /or the calculation o/ the molecular weight o/ the
gi"en sample /or trial ..
Sample Trial .
'ass o/ "-#as$ &when
temperature is .
o
0 abo"e
bp) &g)
'ass o/
"apor&m", A)
In#ection
temperature
&Ti,
o
0)
'olecular
weight o/
"apor &'",
g,mol)
Acetone
.-butanone
Ethyl acetate
Dichloromethane
'ethanol