SupersaLuraLlon lf Lhe waLer vapor pressure ln Lhe alr ls !, Lhe supersaLuraLlon (ln percenL) wlLh respecL Lo llquld waLer ls [(!"!s) 1]x100, where !s ls Lhe saLuraLlon vapor pressure over a plane surface of llquld waLer aL Lhe LemperaLure of Lhe alr. Var|at|ons of the re|at|ve hum|d|ty and supersaturat|on ad[acent to drop|ets of (1) pure water (b|ue) and ad[acent to so|ut|on drop|ets conta|n|ng the fo||ow|ng f|xed masses of sa|t: (2) 10 -19 kg of NaC|, (3) 10 -18 kg of NaC|, (4) 10 -17 kg of NaC|, (S) 10 -19 kg of (Nn4)2SC4, and (6) 10 -18 kg of (Nn4)2SC4. koh|er curves
Ior NaC| part|c|e condensat|on, so|ut|on drop|et wou|d grow fo||ow|ng red curve. At |ts peak, the amb|ent supersatura|on |s more than supersaturat|on ad[acent to drop|et, hence drop|et cont|nues to grow at peak and down to the r|ght s|de of koh|er curve where |t forms a c|oud drop|et - Act|vated drop|ets
Ior (Nn4)2SC4 part|c|e, so|ut|on drop|et wou|d grow a|ong green curve. Cnce |t crosses po|nt A, outs|de supersaturat|on becomes |ower than near drop|et surface supersatura|on, wh|ch resu|t |n vapor|zat|on of drop|et that br|ng |t back to po|nt A - Unact|vated or naze drop|ets
koh|er curves for so|ut|on drop|ets conta|n|ng 10 -19 kg of NaC| (red curve) and 10 -19 kg of (Nn4)2SC4 (green curve) C|oud Condensat|on Nuc|e| (CCN) CCN are those part|c|es (aeroso|s) suspended |n a|r wh|ch act as nuc|e| for condensat|on on the|r surface |ead|ng to drop|et format|on.
1hese part|c|es get act|vated and grow by condensat|on to form c|oud drop|ets at the supersaturat|ons ach|eved |n c|ouds (0.11).
Larger the s|ze of a part|c|e ---> more read||y |t |s wetted by water. Greater |ts so|ub|||ty ----> |ower w||| be the supersaturat|on at wh|ch the part|c|e can serve as a CCN.
Ior examp|e, to serve as a CCN at 1 supersaturat|on, comp|ete|y wettab|e but water-|nso|ub|e part|c|es need to be at |east 0.1 m |n rad|us, whereas so|ub|e part|c|es can serve as CCN at 1 supersaturat|on even |f they are as sma|| as 0.01 m |n rad|us. now c|ouds form ? C|ouds form |n a|r wh|ch has become supersaturated w|th respect to ||qu|d water or |ce.
Most common means by wh|ch a|r becomes supersaturated |s through the ascent accompan|ed by ad|abat|c expans|on and coo||ng
Vert|ca| mot|ons |n the atmosphere are norma||y much sma||er than the hor|zonta| mot|ons and the c|ouds are the v|s|b|e man|festat|ons of such ascend|ng mot|ons
Convect|on and advect|on are the two ma|n mechan|sms of ascent of an a|r parce|
Iormat|on of C|oud Drop|ets
When the a|r reaches saturat|on, the condensat|on of water vapor |nto t|ny c|oud drop|ets may beg|n
In order for water vapor to condense, part|c|es |n the atmosphere ca||ed c|oud condensat|on nuc|e| (CCN) are requ|red
W|thout CCN, a re|at|ve hum|d|ty of severa| hundred percent wou|d be needed to keep a t|ny c|oud drop|et from evaporat|ng away C|oud Iormat|on Mechan|sms Convect|ve L|ft|ng |s assoc|ated w|th surface heat|ng of the a|r at the ground surface. If enough heat|ng occurs, the mass of a|r becomes warmer and ||ghter than the a|r |n the surround|ng env|ronment, |t beg|ns to r|se, expand, and coo|.
When suff|c|ent coo||ng has taken p|ace saturat|on occurs form|ng c|ouds.
1h|s process |s act|ve |n the |nter|or of cont|nents and near the equator form|ng cumu|us c|ouds and]or cumu|on|mbus c|ouds.
C|ouds of 0.1 to 10 km d|ameters
Crograph|c up||ft occurs when a|r |s forced to r|se because of the phys|ca| presence of e|evated |and.
As the parce| r|ses |t coo|s as a resu|t of ad|abat|c expans|on at a rate of approx|mate|y 10 Ce|s|us per 1000 meters unt|| saturat|on.
Iorced ||ft|ng of a|r as |t passes over a h||| or mounta|n Crograph|c c|ouds
1h|s c|oud format|on mechan|sm |s common at the m|d-|at|tudes and near the equator where the trade w|nds meet at the |ntertrop|ca| convergence zone.
Layer c|ouds, more ||fet|me and more extent - both hor|zonta||y and vert|ca||y
Convergence or fronta| ||ft|ng takes p|ace when two masses of a|r come together. In most cases, the two a|r masses have d|fferent temperature and mo|sture character|st|cs.
Cne of the a|r masses |s usua||y warm and mo|st, wh||e the other |s co|d and dry.
1he |ead|ng edge of the |atter a|r mass acts as an |nc||ned wa|| or front caus|ng the mo|st warm a|r to be ||fted. 1he ||ft|ng causes the warm mo|st a|r mass to coo| due to expans|on resu|t|ng |n saturat|on.
C|ouds by rad|at|ve coo||ng near surface: Iog
Instead, the surface of the Larth now beg|ns to |ose energy |n the form of |ongwave rad|at|on wh|ch causes the ground and a|r above |t to coo|.
1he c|ouds that resu|t from th|s type of coo||ng take the form of surface fog.
kad|at|on fog over |and Advect|on fog over ocean Later they can become stratus c|oud when the surface gets warmed kad|at|ve coo||ng occurs when the sun |s no |onger supp|y|ng energy to the ground and over|y|ng a|r (e.g., n|ght). Ia||ure of a C|oud Drop|et Cont|nenta| c|ouds have a h|gh number of t|ny CCN.
A|| these CCN compete for water vapor and affect the way the co||ect|on of drop|ets can grow
If the compet|t|on |s h|gh for water vapor, the supersaturat|on va|ues may not reach the necessary amount for the drop|ets to cont|nue grow|ng
naze resu|ts when many t|ny CCN part|c|es fa|| to grow any further
If c|oud |s be|ow 0 o C |eve| (+ve temperatures), |t conta|ns water drops and ca||ed !"#$ &'()*
If a c|oud extends above the 0 o C |eve| |t |s ca||ed a &('* &'()*.
Lven though the temperature may be be|ow 0 o C, water drop|ets can st||| ex|st |n c|ouds, |n wh|ch case they are referred to as +),-#&(('-* *#(,'-.+.
If a co|d c|oud conta|ns both |ce part|c|es and supercoo|ed drop|ets, |t |s sa|d to be a $/0-* &'()*
If |t cons|sts ent|re|y of |ce, |t |s sa|d to be 1'"&/".-*. "#$%#&'()&# *+, Cold Cloud "#$%#&'()&# -.*+, ke|at|ve s|zes of c|oud drop|ets and ra|ndrops, # |s the rad|us |n m|crometers, 2 |s the number per ||ter of a|r, and 3 |s the term|na| fa|| speed |n cent|meters per second. Growth of a ka|ndrop 1he growLh of a cloud dropleL ls a slow process, and slmple growLh by condensaLlon ls noL whaL forms ralndrops
1here are Lwo processes LhaL explaln Lhe formaLlon of preclplLaLlon-slzed parLlcles: Colllslon and Coalescence rocess 8ergeron-llndelsen Mechanlsm Co|||s|on-Coa|escence rocess 1h|s process |s |mportant |n warm c|ouds where the prec|p|tat|on part|c|es are a|| ||qu|d
Larger drop|ets, hav|ng a h|gher fa|| speed, w||| co|||de w|th sma||er drops and coa|esce together |nto a b|gger drop
Co|||s|on |s more eff|c|ent as the |arger drop|et |ncreases |n s|ze
A sma||er drop|et |s more ||ke|y to co|||de w|th a |arger drop |f the d|fference |n s|ze |s s|gn|f|cant (hav|ng a w|de var|ety of drop s|zes |n the c|oud |s he|pfu|, as |n the mar|ne env|ronment)
8ergeron-I|nde|sen Mechan|sm 1h|s process dom|nates |n co|d c|ouds, where we have a|| three phases of water present: so||d, ||qu|d, and gas
1he saturat|on vapor pressure over |ce |s |ess than the saturat|on vapor pressure over water
start w|th a water drop|et that |s |n saturated cond|t|ons
When drop|et |s saturated, the condensat|on of water vapor |nto the drop|et |s ba|anced by the evaporat|on of water off of the drop|et
1he add|t|on of an |ce crysta| nearby w||| be |n a +),-#+".)#".-* env|ronment
If the |ce crysta| |s |n an env|ronment that |s supersaturated, water vapor w||| depos|t on the |ce crysta| faster than |t sub||mates off of the |ce crysta| Cont
1he water vapor content |n the c|oud w||| drop, and no |onger have saturated cond|t|ons w|th respect to the ||qu|d water drop
I|nd|ng |tse|f |n subsaturated a|r, the water drop|et has evaporat|on exceed condensat|on, wh|ch adds water vapor to the c|oud but causes the drop|et to shr|nk |n s|ze
After evaporat|on of water vapor suff|c|ent to make the cond|t|ons saturated w|th respect to ||qu|d water once aga|n, the drop|et stops shr|nk|ng
8ut, we st||| have that |ce crysta| and |t |s st||| |n supersaturated cond|t|ons
1hrough th|s process, the |ce crysta| w||| grow at the expense of the ||qu|d water drop 8ergeron-I|nde|sen Mechan|sm Cont Cther Co|d C|oud rocesses k|m|ng ls when supercooled waLer dropleLs colllde wlLh an lce crysLal and lnsLanLly freeze on Lhe lce crysLal. Pall formaLlon ls due Lo rlmlng.
lce crysLals aL or above -3 C Lend Lo be sLlcky due Lo a fllm of waLer on Lhe surface. lce crysLals can Lhen sLlck LogeLher ln a process called aggregat|on. Lntra|nment |n C|oud CuLslde alr parcels can enLer lnLo cloud from Lop
When cloud waLer ls evaporaLed Lo saLuraLe an enLralned parcel of alr, Lhe parcel ls cooled, and slnk, mlxlng wlLh more cloudy alr down.
1he slnklng parcel wlll descend unLll lL runs ouL of negaLlve buoyancy or loses lLs ldenLlLy. Such parcels can descend several kllomeLers ln a cloud, Lhey are referred Lo as peneLraLlve downdrafLs Schemat|c of entra|nment of amb|ent a|r |nto a sma|| cumu|us c|oud.
0.the Water Vapour Permeability Mechanical Properties and Solubility of Fish Gelatin Chitosan Films Modified With Transglutaminase or 1 Ethyl 3 3 Dimeth