Product: Oxygen, Compressed P-4638-H Date: December 2009

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Praxair Material Safety Data Sheet
1. Chemical Product and Company Identification
Product Name: Oxygen, compressed
(MSDS No. P-4638-H)
Trade Names: Oxygen, MediPure Oxygen
Chemical Name: Oxygen Synonyms: Dioxygen
Chemical Family: Permanent gas Product Grades: Industrial, Oxygen Aviators
Breathing, USP, 2.6, 2.6-Zero, 4.0
Hydrocarbon Free, 4.3-UHP, 5.0-Research,
6.0
Telephone: Emergencies: 1-800-645-4633* Company Name: Praxair, Inc.
CHEMTREC: 1-800-424-9300* 39 Old Ridgebury Road
Routine: 1-800-PRAXAIR Danbury, CT 06810-5113
* Call emergency numbers 24 hours a day only for spills, leaks, fire, exposure, or accidents
involving this product. For routine information, contact your supplier, Praxair sales
representative, or call 1-800-PRAXAIR (1-800-772-9247).
2. Hazards Identification
EMERGENCY OVERVIEW
WARNING! High-pressure, oxidizing gas.
Vigorously accelerates combustion.
Self-contained breathing apparatus may be required by rescue workers.
Under ambient conditions, this is a colorless, odorless, and tasteless gas.
OSHA REGULATORY STATUS: This material is considered hazardous by the OSHA Hazard
Communications Standard (29 CFR 1910.1200).
POTENTIAL HEALTH EFFECTS:
Effects of a Single (Acute) Overexposure
Inhalation. Breathing 80 percent or more oxygen at atmospheric pressure for more than a
few hours may cause nasal stuffiness, cough, sore throat, chest pain, and breathing
difficulty. Breathing oxygen at higher pressure increases the likelihood of adverse
effects within a shorter time period. Breathing pure oxygen under pressure may cause
lung damage and also Central Nervous System (CNS) effects resulting in dizziness,
poor coordination, tingling sensation, visual and hearing disturbances, muscular
twitching, unconsciousness, and convulsions. Breathing oxygen under pressure may
cause prolongation of adaptation to darkness and reduced peripheral vision.
Skin Contact. No harm expected.
Swallowing. This product is a gas at normal temperature and pressure.
Eye Contact. No harm expected.
Effects of Repeated (Chronic) Overexposure. No harm expected.
Product: Oxygen, Compressed P-4638-H Date: December 2009
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Other Effects of Overexposure. See section 11, Toxicological Information.
Medical Conditions Aggravated by Overexposure. See section 11, Toxicological
Information.
CARCINOGENICITY: Oxygen is not listed by NTP, OSHA, or IARC.
POTENTIAL ENVIRONMENTAL EFFECTS: For further information, see section 12, Ecological
Information.
3. Composition/Information on Ingredients
See section 16 for important information about mixtures.
COMPONENT CAS NUMBER CONCENTRATION
Oxygen 7782-44-7 >99%*
*The symbol > means greater than.
4. First Aid Measures
INHALATION: Immediately remove to fresh air. If not breathing, give artificial respiration. Keep
victim warm and at rest. Call a physician. Advise the physician that the victim has been
exposed to a high concentration of oxygen.
SKIN CONTACT: Wash with soap and water; seek medical attention if discomfort persists.
SWALLOWING: This product is a gas at normal temperature and pressure.
EYE CONTACT: Flush eyes thoroughly with water. Hold the eyelids open and away from the
eyeballs to ensure that all surfaces are flushed thoroughly. Get medical attention if discomfort
persists.
NOTES TO PHYSICIAN: Supportive treatment should include immediate sedation, anti-
convulsive therapy if needed, and rest. See section 11, Toxicological Information.
5. Fire Fighting Measures
FLAMMABLE PROPERTIES: Oxidizing agent; vigorously accelerates combustion. Contact
with flammable materials may cause fire or explosion.
SUITABLE EXTINGUISHING MEDIA: Vigorously accelerates combustion. Use media
appropriate for surrounding fire. Water (e.g., safety shower) is the preferred extinguishing
method for clothing fires.
PRODUCTS OF COMBUSTION: Not applicable.
PROTECTION OF FIREFIGHTERS: WARNING! High-pressure, oxidizing gas. Evacuate all
personnel from danger area. Immediately deluge cylinders with water from maximum distance
until cool; then move them away from fire area if without risk. Self-contained breathing
apparatus may be required by rescue workers. On-site fire brigades must comply with OSHA
29 CFR 1910.156.
Specific Physical and Chemical Hazards. Heat of fire can build pressure in cylinder and
cause it to rupture. Oxygen cylinders are equipped with a pressure relief device. (Exceptions
may exist where authorized by DOT.) No part of cylinder should be subjected to a temperature
higher than 125F (52C). Smoking, flames, and electric sparks in the presence of enriched
oxygen atmospheres are potential explosion hazards.
Product: Oxygen, Compressed P-4638-H Date: December 2009
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Protective Equipment and Precautions for Firefighters. Firefighters should wear self-
contained breathing apparatus and full fire-fighting turnout gear.
6. Accidental Release Measures
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
WARNING! High-pressure, oxidizing gas.
Personal Precautions. Shut off flow if without risk. Ventilate area or move cylinder to a well-
ventilated area. Remove all flammable materials from vicinity. Oxygen must never be permitted
to strike an oily surface, greasy clothes, or other combustible material.
Environmental Precautions. Prevent waste from contaminating the surrounding environment.
Keep personnel away. Discard any product, residue, disposable container, or liner in an
environmentally acceptable manner, in full compliance with federal, state, and local regulations.
If necessary, call your local supplier for assistance.
7. Handling and Storage
PRECAUTIONS TO BE TAKEN IN HANDLING: Protect cylinders from damage. Use a
suitable hand truck to move cylinders; do not drag, roll, slide, or drop. Never attempt to lift a
cylinder by its cap; the cap is intended solely to protect the valve. Never insert an object (e.g.,
wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a
leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open valve.
If valve is hard to open, discontinue use and contact your supplier. Close cylinder valve after
each use; keep closed even when empty. Never apply flame or localized heat directly to any
part of the cylinder. High temperatures may damage the cylinder and could cause the pressure
relief device to fail prematurely, venting the cylinder contents. For other precautions in using
this mixture, see section 16.
PRECAUTIONS TO BE TAKEN IN STORAGE: Store and use with adequate ventilation, away
from oil, grease, and other hydrocarbons. Separate oxygen cylinders from flammables by at
least 20 ft (6.1 m) or use a barricade of noncombustible material. This barricade should be at
least 5 ft (1.53 m) high and have a fire resistance rating of at least hour. Firmly secure
cylinders upright to keep them from falling or being knocked over. Screw valve protection cap
firmly in place by hand. Store only where temperature will not exceed 125F (52C). Store full
and empty cylinders separately. Use a first-in, first-out inventory system to prevent storing full
cylinders for long periods.
RECOMMENDED PUBLICATIONS: For further information on storage, handling, and use, see
Praxair publications P-14-153, Guidelines for Handling Gas Cylinders and Containers; P-15-
276, Storage and Safe Handling of Oxygen; and P-3499, Safety Precautions and Emergency
Response Planning. Obtain from your local supplier.
8. Exposure Controls/Personal Protection
See section 16 for important information on by-products generated during use
in welding and cutting.
COMPONENT OSHA PEL ACGIH TLV-TWA (2009)
Oxygen Not Established. Not Established.
IDLH = Not available.
Product: Oxygen, Compressed P-4638-H Date: December 2009
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ENGINEERING CONTROLS:
Local Exhaust. Use a local exhaust system, if necessary, to prevent increased oxygen
concentration and, in welding, to keep hazardous fumes and gases below the applicable
exposure limits in the workers breathing zone.
Mechanical (General). General exhaust ventilation may be acceptable if it can maintain a
supply of air that is not too rich in oxygen and, during welding, can keep hazardous fumes and
gases below applicable TLVs in the workers breathing zone.
Special. None
Other. None
PERSONAL PROTECTIVE EQUIPMENT:
Skin Protection. Wear work gloves when handling cylinders; welding gloves for welding.
Gloves must be free of oil and grease. Metatarsal shoes for cylinder handling. Select in
accordance with OSHA 29 CFR 1910.132 and 1910.133. As needed for welding, wear hand,
head, and body protection to help prevent injury from radiation and sparks. (See ANSI Z49.1.)
At a minimum, this includes welders gloves and protective goggles, and may include arm
protectors, aprons, hats, shoulder protection, as well as substantial clothing. Regardless of
protective equipment, never touch live electrical parts.
Eye/Face Protection. Wear safety glasses when handling cylinders. For welding, wear
goggles with filter lens selected as per ANSI Z49.1. Provide protective screens and goggles, if
necessary, to protect others. Select as per OSHA 29 CFR 1910.33
Respiratory Protection. None required. However, air supplied respirators are required while
working in oxygen deficient atmospheres such as confined spaces.
9. Physical and Chemical Properties
APPEARANCE: Colorless, odorless, tasteless gas at normal
temperature and pressure.
ODOR: None
ODOR THRESHOLD: Not available.
PHYSICAL STATE: Gas at normal temperature and pressure
pH: Not applicable.
MELTING POINT at 1 atm: -361.82F (-218.79C)
BOILING POINT at 1 atm: -297.36F (-182.98C)
FLASH POINT (test method): -62F (-52.2C) TCC ASTM D56
EVAPORATION RATE (Butyl Acetate = 1): Not applicable.
FLAMMABILITY: Not applicable.
FLAMMABLE LIMITS IN AIR, % by volume: LOWER: Not
applicable.
UPPER: Not
applicable.
VAPOR PRESSURE at 68F (20C): Not applicable.
VAPOR DENSITY at 70F (21.1C) and 1 atm: 0.0827 lb/ft
3
(1.325 kg/m
3
)
SPECIFIC GRAVITY (H
2
O = 1) at boiling point 1.141
SPECIFIC GRAVITY (Air = 1) at 70F (21.1C)
and 1 atm:

1.105
SOLUBILITY IN WATER, vol/vol at 32F (0C): 0.0489
PARTITION COEFFICIENT: n-octanol/water: Not available.
Product: Oxygen, Compressed P-4638-H Date: December 2009
Page 5 of 10
AUTOIGNITION TEMPERATURE: Not applicable.
DECOMPOSITION TEMPERATURE: Not available.
PERCENT VOLATILES BY VOLUME: 100
MOLECULAR WEIGHT: 31.9988
MOLECULAR FORMULA: O
2

10. Stability and Reactivity
CHEMICAL STABILITY:

Unstable Stable
CONDITIONS TO AVOID: None known.
INCOMPATIBLE MATERIALS: Combustible materials, asphalt, flammable materials, especially
oils and greases. Oxygen reacts with many materials.
HAZARDOUS DECOMPOSITION PRODUCTS: None known.
POSSIBILITY OF HAZARDOUS REACTIONS: May Occur Will Not Occur
11. Toxicological Information
ACUTE DOSE EFFECTS: The welding process may generate hazardous fumes and gases.
(See sections 2, 10, 15, and 16.)

At atmospheric concentration and pressure, oxygen poses no toxicity hazards. At high
concentrations, newborn premature infants may suffer delayed retinal damage (retrolental
fibroplasia) that can progress to retinal detachment and blindness. Retinal damage may also
occur in adults exposed to 100% oxygen for extended periods (24 to 48 hours) or at pressures
exceeding atmospheric pressure, particularly in individuals whose retinal circulation has been
previously compromised. All individuals exposed for long periods to oxygen at high pressure
and all who exhibit overt oxygen toxicity should have ophthalmologic examinations.

At two or more atmospheres, CNS toxicity occurs. Symptoms include nausea, vomiting,
dizziness or vertigo, muscle twitching, vision changes, and loss of consciousness and
generalized seizures. At three atmospheres, CNS toxicity occurs in less than two hours; at six
atmospheres, in only a few minutes.
Patients with chronic obstructive pulmonary disease retain carbon dioxide abnormally. If
oxygen is administered, raising their blood-oxygen concentration, their breathing becomes
depressed, and retained carbon dioxide rises to a dangerous level.

Airway obstruction during high oxygen tension may cause alveolar collapse following absorption
of the oxygen. Similarly, occlusion of the eustachian tubes may cause retraction of the
eardrum, and obstruction of the paranasal sinuses may produce vacuum-type headache.

STUDY RESULTS: Animal studies suggest that the administration of certain drugs, including
phenothiazine drugs and chloroquine, increases the susceptibility to toxicity from oxygen at high
concentrations or pressures. Animal studies also indicate that vitamin E deficiency may
increase susceptibility to oxygen toxicity.
Product: Oxygen, Compressed P-4638-H Date: December 2009
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12. Ecological Information
ECOTOXICITY: No known effects.
OTHER ADVERSE EFFECTS: The atmosphere contains approximately 21 percent oxygen. No
adverse ecological effects expected. Oxygen does not contain any Class I or Class II ozone-
depleting chemicals.
13. Disposal Considerations
WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused quantities.
Return cylinder to supplier. For emergency disposal, secure cylinder in a well-ventilated area or
outdoors; then slowly discharge gas to the atmosphere.
14. Transport Information
DOT/IMO SHIPPING NAME: Oxygen, compressed
HAZARD
CLASS:

2.2
PACKING
GROUP/Zone:

NA*
IDENTIFICATION
NUMBER:

UN1072
PRODUCT
RQ:

None
SHIPPING LABEL(s): OXYGEN. An oxygen label may be used for domestic shipment in
the United States and Canada in place of the NONFLAMMABLE
GAS and OXIDIZER labels (49 CFR Part 172).
PLACARD (when required): NONFLAMMABLE GAS or OXYGEN
*Not available.
SPECIAL SHIPPING INFORMATION: Cylinders should be transported in a secure position, in a
well-ventilated vehicle. Cylinders transported in an enclosed, nonventilated compartment of a
vehicle can present serious safety hazards.
Shipment of compressed gas cylinders that have been filled without the owners consent is a
violation of federal law [49 CFR 173.301(b)].
MARINE POLLUTANTS: Oxygen is not listed as a marine pollutant by DOT.
15. Regulatory Information
The following selected regulatory requirements may apply to this product. Not all such
requirements are identified. Users of this product are solely responsible for compliance with all
applicable federal, state, and local regulations.
U.S. FEDERAL REGULATIONS:
EPA (ENVIRONMENTAL PROTECTION AGENCY)
CERCLA: COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION,
AND LIABILITY ACT OF 1980 (40 CFR Parts 117 and 302):
Reportable Quantity (RQ): None
SARA: SUPERFUND AMENDMENT AND REAUTHORIZATION ACT:
SECTIONS 302/304: Require emergency planning based on Threshold Planning
Quantity (TPQ) and release reporting based on Reportable Quantities (RQ) of
Extremely Hazardous Substances (EHS) (40 CFR Part 355):
TPQ: None
EHS RQ (40 CFR 355): None
Product: Oxygen, Compressed P-4638-H Date: December 2009
Page 7 of 10
SECTIONS 311/312: Require submission of MSDSs and reporting of chemical
inventories with identification of EPA hazard categories. The hazard categories for
this product are as follows:
IMMEDIATE: No PRESSURE: Yes
DELAYED: No REACTIVITY: No
FIRE: Yes
SECTION 313: Requires submission of annual reports of release of toxic chemicals
that appear in 40 CFR Part 372.
Oxygen is not subject to reporting under Section 313.
40 CFR 68: RISK MANAGEMENT PROGRAM FOR CHEMICAL ACCIDENTAL
RELEASE PREVENTION: Requires development and implementation of risk
management programs at facilities that manufacture, use, store, or otherwise handle
regulated substances in quantities that exceed specified thresholds.
Oxygen is not listed as a regulated substance.
TSCA: TOXIC SUBSTANCES CONTROL ACT: Oxygen is listed on the TSCA inventory.
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION:
29 CFR 1910.119: PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS
CHEMICALS: Requires facilities to develop a process safety management program
based on Threshold Quantities (TQ) of highly hazardous chemicals.
Oxygen is not listed in Appendix A as a highly hazardous chemical.
STATE REGULATIONS:
CALIFORNIA: Oxygen is not listed by California under the SAFE DRINKING WATER AND
TOXIC ENFORCEMENT ACT OF 1986 (Proposition 65).
PENNSYLVANIA: Oxygen is subject to the PENNSYLVANIA WORKER AND COMMUNITY
RIGHT-TO-KNOW ACT (35 P.S. Sections 7301-7320).
16. Other Information
Read and understand all labels and instructions supplied with all containers of this product.

WARNING: Medical grades of oxygen are subject to strict federal regulations and are for use
only under the control of a licensed physician or clinician familiar with the product and its
hazards.

OTHER HAZARDOUS CONDITIONS OF HANDLING, STORAGE, AND USE: High-pressure,
oxidizing gas. Clean all gauges, valves, regulators, piping, and equipment to be used in
oxygen service in accordance with CGA pamphlet G-4.1. Keep cylinders and their valves free
of oil and grease. Use piping and equipment adequately designed to withstand pressures to be
encountered. Use a backflow prevention device in any piping. Never use oxygen as a
substitute for compressed air. Never use an oxygen jet for cleaning purposes of any sort,
especially for clothing. Oxygen increases the likelihood of an engulfing fire. Never work on a
pressurized system. If a leak occurs, close the cylinder valve. Blow down the system in a safe
and environmentally sound manner in compliance with all federal, state, and local laws; then
repair the leak. Never place a compressed gas cylinder where it may become part of an
electrical circuit.
Personnel who have been exposed to high concentrations of oxygen should stay in a well-
ventilated or open area before going into a confined space or near an ignition source.
Product: Oxygen, Compressed P-4638-H Date: December 2009
Page 8 of 10
SPECIAL PRECAUTIONS: Use in welding and cutting. Read and understand the
manufacturers instructions and the precautionary label on the product. Ask your welding
products supplier for a copy of Praxairs free safety booklet, P-2035, Precautions and Safe
Practices for Gas Welding, Cutting, and Heating, and for other manufacturers safety
publications. For a detailed treatment, get ANSI Z49.1, Safety in Welding, Cutting, and Allied
Processes, published by the American Welding Society (AWS), 550 N.W. Le Jeune Rd., Miami,
FL 33126, http://www.aws.org/, or see OSHAs Web site at http://www.osha-
slc.gov/SLTC/weldingcuttingbrazing/. Order AWS documents from Global Engineering
Documents, 15 Inverness Way East, Englewood, CO 80112-5710, http://global.ihs.com/.
Arcs and sparks can ignite combustible materials. Prevent fires. Refer to NFPA 51B, Standard
for Fire Prevention During Welding, Cutting, and Other Hotwork. Do not strike an arc on the
cylinder. The defect produced by an arc burn could lead to cylinder rupture.
Mixtures. When you mix two or more chemicals, you can create additional, unexpected
hazards. Obtain and evaluate the safety information for each component before you produce
the mixture. Consult an industrial hygienist or other trained person when you evaluate the end
product. Remember, chemicals have properties that can cause serious injury or death.
HAZARD RATING SYSTEMS:
NFPA RATINGS: HMIS RATINGS:
HEALTH = 0 HEALTH = 0
FLAMMABILITY = 0 FLAMMABILITY = 0
INSTABILITY = 0 PHYSICAL HAZARD = 3
SPECIAL = OX
STANDARD VALVE CONNECTIONS FOR U.S. AND CANADA:
THREADED: 0-3000 psig
3001-4000 psig
4001-5500 psig
CGA-540
CGA-577
CGA-701
PIN-INDEXED YOKE: 0-3000 psig CGA-870 (Medical Use)
ULTRA-HIGH-INTEGRITY CONNECTION: 0-3000 psig CGA-714
Use the proper CGA connections. DO NOT USE ADAPTERS. Additional limited-standard
connections may apply. See CGA pamphlet V-1 listed below.
Product: Oxygen, Compressed P-4638-H Date: December 2009
Page 9 of 10
Ask your supplier about free Praxair safety literature as referred to in this MSDS and on the
label for this product. Further information can be found in the following pamphlets published by
the Compressed Gas Association, Inc. (CGA), 4221 Walney Road, 5
th
Floor, Chantilly, VA
20151-2923, Telephone (703) 788-2700, http://www.cganet.com/Publication.asp

AV-1 Safe Handling and Storage of Compressed Gases
AV-8 Characteristics and Safe Handling of Cryogenic Liquid and Gaseous Oxygen
G-4 Oxygen
G-4.1 Cleaning Equipment for Oxygen Service
P-1 Safe Handling of Compressed Gases in Containers
P-2 Characteristics and Safe Handling of Medical Gases
P-39 Oxygen-Rich Atmospheres
SB-2 Oxygen-Deficient Atmospheres
SB-8 Use of Oxy-Fuel Gas Welding and Cutting Apparatus
V-1 Compressed Gas Cylinder Valve Inlet and Outlet Connections
Handbook of Compressed Gases, Fourth Edition
Product: Oxygen, Compressed P-4638-H Date: December 2009

Praxair MSDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers
who package and sell our products. To obtain current MSDSs for these products, contact your Praxair
sales representative or local distributor or supplier, or download from www.praxair.com. If you have
questions regarding Praxair MSDSs, would like the form number and date of the latest MSDS, or would
like the names of the Praxair suppliers in your area, phone or write the Praxair Call Center (Phone: 1-
800-PRAXAIR; Address: Praxair Call Center, Praxair, Inc., PO Box 44, Tonawanda, NY 14151-0044).
Praxair, the Flowing Airstream design, and Medipure are trademarks or registered trademarks of
Praxair Technology, Inc. in the United States and/or other countries.


Praxair, Inc.
39 Old Ridgebury Road
Danbury, CT 06810-5113

Printed in USA Page 10 of 10
Praxair asks users of this product to study this MSDS and become aware of product hazards
and safety information. To promote safe use of this product, a user should (1) notify employees,
agents, and contractors of the information in this MSDS and of any other known product
hazards and safety information, (2) furnish this information to each purchaser of the product,
and (3) ask each purchaser to notify its employees and customers of the product hazards and
safety information.








The opinions expressed herein are those of qualified experts within Praxair, Inc. We
believe that the information contained herein is current as of the date of this Material
Safety Data Sheet. Since the use of this information and the conditions of use of the
product are not within the control of Praxair, Inc., it is the users obligation to
determine the conditions of safe use of the product.