Hydrosure 0-3670R 1 lDENTlFlCATlON OF THE SUBSTANCE/PREPARATlON AND OF THE COMPANY/UNDERTAKlNG PRODUCT NO. O3670R APPLlCATlON HYDROTEST CHEMlCAL Champion Arabia, Co. Ltd. SUPPLlER P.O.Box 3254 Al-Khobar 31952 Saudi Arabia 0096638122100 0096638122040 2 HAZARDS lDENTlFlCATlON Causes burns. Contact with acids liberates toxic gas. CLASSlFlCATlON (1999/45) C;R34. R31. 3 COMPOSlTlON/lNFORMATlON ON lNGREDlENTS EC No. Name Classification (67/548/EEC) CAS-No. Content % 270-325-2 Quaternary ammonium chloride Xn;R22. C;R34. N;R50. 68424-85-1 10-30% 233-469-7 AMMONlUM BlSULPHlTE Xi;R36/37/38. R31. 10192-30-0 10-30% 252-104-2 DlPROPYLENE GLYCOL MONOMETHYL ETHER (DPM) - 34590-94-8 1-10% 203-473-3 ETHANEDlOL Xn;R22 107-21-1 < 1% The Full Text for all R-Phrases is Displayed in Section 16 4 FlRST-AlD MEASURES lNHALATlON Move the exposed person to fresh air at once. lf respiratory problems, artificial respiration/oxygen. Get medical attention. lNGESTlON NEVER MAKE AN UNCONSClOUS PERSON VOMlT OR DRlNK FLUlDS! lmmediately rinse mouth and drink plenty of water (200-300 ml). DO NOT induce vomiting. Get medical attention immediately. lf vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Generates toxic gas in contact with acid. SKlN CONTACT Rinse the skin immediately with lots of water. Continue to rinse for at least 15 minutes. Remove contaminated clothes and rinse skin thoroughly with water. Get medical attention immediately. Chemical burns must be treated by a physician. EYE CONTACT Remove victim immediately from source of exposure. Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. To hospital or eye specialist. 5 FlRE-FlGHTlNG MEASURES EXTlNGUlSHlNG MEDlA Water spray. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. SPEClAL FlRE FlGHTlNG PROCEDURES Avoid water in straight hose stream; will scatter and spread fire. Cool containers exposed to flames with water until well after the fire is out. Avoid breathing fire vapours. Keep run-off water out of sewers and water sources. Dike for water control. UNUSUAL FlRE & EXPLOSlON HAZARDS May develop highly toxic or corrosive fumes if heated. SPEClFlC HAZARDS Fire or high temperatures create: Oxides of: Carbon. Nitrogen. Sulphur. 5 1 / REVlSlON DATE 30/11/2010 Hydrosure 0-3670R PROTECTlVE MEASURES lN FlRE Wear full protective clothing. Use air-supplied respirator during fire fighting. 6 ACClDENTAL RELEASE MEASURES PERSONAL PRECAUTlONS Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of vapours and contact with skin and eyes. ENVlRONMENTAL PRECAUTlONS Do not discharge into drains, water courses or onto the ground. SPlLL CLEAN UP METHODS Stop leak if possible without risk. DO NOT touch spilled material! Absorb in vermiculite, dry sand or earth and place into containers. Flush area with plenty of water. Do not let washing down water contaminate ponds or waterways. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. 7 HANDLlNG AND STORAGE USAGE PRECAUTlONS Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Observe good chemical hygiene practices. Keep away from heat, sparks and open flame. Eye wash facilities and emergency shower must be available when handling this product. STORAGE PRECAUTlONS Store in tightly closed original container in a dry, cool and well-ventilated place. Store separated from: Acids. Alkalis. Oxidising material. 8 EXPOSURE CONTROLS/PERSONAL PROTECTlON STD STEL - 15 Min TWA - 8 Hrs Name Notes AMMONlUM BlSULPHlTE 50 ppm 308 mg/m3 WEL DlPROPYLENE GLYCOL MONOMETHYL ETHER (DPM) Sk 10 mg/m3 WEL 104 mg/m3 ETHANEDlOL Sk WEL = Workplace Exposure Limit. Sk = Can be absorbed through skin. PROTECTlVE EQUlPMENT PROCESS CONDlTlONS Provide eyewash, quick drench. ENGlNEERlNG MEASURES Provide adequate general and local exhaust ventilation. RESPlRATORY EQUlPMENT ln case of inadequate ventilation use suitable respirator. HAND PROTECTlON Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. EYE PROTECTlON Use approved safety goggles or face shield. OTHER PROTECTlON Wear appropriate clothing to prevent any possibility of skin contact. HYGlENE MEASURES DO NOT SMOKE lN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When using do not eat, drink or smoke. 9 PHYSlCAL AND CHEMlCAL PROPERTlES APPEARANCE Liquid COLOUR Light (or pale) Coloured 5 2 / REVlSlON DATE 30/11/2010 Hydrosure 0-3670R ODOUR Pungent Sulphur. SOLUBlLlTY Miscible with water RELATlVE DENSlTY 1.045 - 1.075 @ 20 c pH-VALUE, CONC. SOLUTlON 4.0-6.0 REFRACTlVE lNDEX 39-41 10 STABlLlTY AND REACTlVlTY STABlLlTY Stable under normal temperature conditions. CONDlTlONS TO AVOlD Avoid heat, flames and other sources of ignition. HAZARDOUS POLYMERlSATlON Will not polymerise. MATERlALS TO AVOlD Strong acids. Strong oxidising substances. HAZARDOUS DECOMPOSlTlON PRODUCTS Oxides of: Carbon. Nitrogen. Sulphur. 11 TOXlCOLOGlCAL lNFORMATlON lNHALATlON Gas or vapour may irritate respiratory system. lNGESTlON Causes burns. May cause chemical burns in mouth and throat. Generates toxic gas in contact with acid. SKlN CONTACT Causes burns. EYE CONTACT Causes burns. Risk of serious damage to eyes. 12 ECOLOGlCAL lNFORMATlON ECOTOXlClTY The product contains a substance which is very toxic to aquatic organisms. MOBlLlTY The product is soluble in water. BlOACCUMULATlON No data available on bioaccumulation. 13 DlSPOSAL CONSlDERATlONS GENERAL lNFORMATlON Empty containers should be taken for local recycling, recovery or waste disposal DlSPOSAL METHODS Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. WASTE CLASS For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes. 14 TRANSPORT lNFORMATlON PROPER SHlPPlNG NAME CORROSlVE LlQUlD, AClDlC, ORGANlC, n.o.s. (contains quaternary ammonium chloride) 3265 UN NO. ROAD 8 ADR CLASS NO. 5 3 / REVlSlON DATE 30/11/2010 Hydrosure 0-3670R Class 8: Corrosive substances. ADR CLASS lll ADR PACK GROUP 80 Corrosive or slightly corrosive substance. HAZARD NO. (ADR) 80 HAZARD No. (ADR) 2X HAZCHEM CODE 3265 UN NO. SEA 8 lMDG CLASS lll lMDG PACK GR. F-A S-B EMS 3265 UN NO. AlR 8 lCAO CLASS lll AlR PACK GR. 15 REGULATORY lNFORMATlON LABELLlNG Corrosive CONTAlNS Quaternary ammonium chloride RlSK PHRASES R31 Contact with acids liberates toxic gas. R34 Causes burns. SAFETY PHRASES S24/25 Avoid contact with skin and eyes. S26 ln case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S45 ln case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S60 This material and its container must be disposed of as hazardous waste. UK REGULATORY REFERENCES Approved Supply List. STATUTORY lNSTRUMENTS The Chemicals (Hazard lnformation and Packaging for Supply) Regulations 2009 (S.l 2009 No. 716). APPROVED CODE OF PRACTlCE Classification and Labelling of Substances and Preparations Dangerous for Supply. GUlDANCE NOTES Workplace Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply. 16 OTHER lNFORMATlON REVlSlON COMMENTS NOTE: Lines within the margin indicate significant changes from the previous revision. lSSUED BY GC REVlSlON DATE 30/11/2010 REV. NO./REPL. SDS GENERATED 4 RlSK PHRASES lN FULL Causes burns. R34 Contact with acids liberates toxic gas. R31 Harmful if swallowed. R22 lrritating to eyes, respiratory system and skin. R36/37/38 Very toxic to aquatic organisms. R50 5 4 / REVlSlON DATE 30/11/2010 Hydrosure 0-3670R DlSCLAlMER The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process unless specified in the text. 5 5 /