TextforRphrases:seeSection16

MATERIALSAFETYDATASHEET
Ammoniumhydroxidewatersolution,>14NNH4OH(2530%asammonia,NH3)
Section1ChemicalProductandCompanyIdentification
MSDSName: Ammoniumhydroxidewatersolution,>14NNH4OH(2530%asammonia,NH3)
Catalog
Numbers:
A/3222/21,A/3222/PB17,A/3240/PB15,A/3240/PB17,A/3280/21,A/3280/25,
A/3280/PB15,A/3280/PB17,A/3285/PB17,A/3290/PB08,A/3290/PB15,A/3295/PB05,
A/3320/PB17,A/3360/99,A/3360/PB15,A/3360/PB17,J/9015/08
Synonyms: AmmoniumhydrateAmmoniasolutionAmmoniawaterAqueousammoniaAqua
ammonia.
CompanyIdentification: FisherScientificUK
BishopMeadowRoad,Loughborough
Leics.LE115RG
ForinformationinEurope,call: (01509)231166
EmergencyNumber,Europe: 01509231166
Section2Composition,InformationonIngredients
CAS# ChemicalName: % EINECS# HazardSymbols: RiskPhrases:
7664417 Ammonia 2530 2316353
7732185 Water 7075 2317912
HazardSymbols: CN

RiskPhrases: 3450
Section3HazardsIdentification
EMERGENCYOVERVIEW
Causesburns.Verytoxictoaquaticorganisms.
PotentialHealthEffects
Eye: Contactwithliquidorvaporcausessevereburnsandpossibleirreversibleeyedamage.
Lachrymator(substancewhichincreasestheflowoftears).
Skin: Causessevereskinirritation.Causesskinburns.Maycausedeep,penetratingulcersofthe
skin.Contactwiththeskinmaycausestaining,inflammation,andthickeningoftheskin.
Ingestion: Harmfulifswallowed.Maycausesevereandpermanentdamagetothedigestivetract.
Causesgastrointestinaltractburns.Causesthroatconstriction,vomiting,convulsions,and
shock.
Inhalation: Effectsmaybedelayed.Causessevereirritationofupperrespiratorytractwithcoughing,
burns,breathingdifficulty,andpossiblecoma.
Chronic: Prolongedinhalationmaycauserespiratorytractinflammationandlungdamage.Prolonged
orrepeatedexposuremaycausecornealdamageandthedevelopmentofcataractsand
glaucoma.
Section4FirstAidMeasures
Eyes: Incaseofcontact,immediatelyflusheyeswithplentyofwaterforatleast15minutes.
Getmedicalaidimmediately.
Skin: Incaseofcontact,immediatelyflushskinwithplentyofwaterforatleast15minutes
whileremovingcontaminatedclothingandshoes.Getmedicalaidimmediately.Wash
clothingbeforereuse.
Ingestion: Ifswallowed,doNOTinducevomiting.Getmedicalaidimmediately.Ifvictimisfully
conscious,giveacupfulofwater.Nevergiveanythingbymouthtoanunconscious
person.
Inhalation: Ifinhaled,removetofreshair.Ifnotbreathing,giveartificialrespiration.Ifbreathingis
difficult,giveoxygen.Getmedicalaid.
Notesto
Physician:
Afterinhalationexposure,observefor24to72hoursaspulmonaryedemamaybe
delayed.
Section5FireFightingMeasures
General
Information:
Asinanyfire,wearaselfcontainedbreathingapparatusinpressuredemand,
MSHA/NIOSH(approvedorequivalent),andfullprotectivegear.Duringafire,irritating
andhighlytoxicgasesmaybegeneratedbythermaldecompositionorcombustion.Use
waterspraytokeepfireexposedcontainerscool.Contactwithmetalsmayevolve
flammablehydrogengas.Containersmayexplodewhenheated.Approachfirefrom
upwindtoavoidhazardousvaporsandtoxicdecompositionproducts.Ammonium
hydroxideitselfisnoncombustible.Howeverconcentratedammoniasolutionsmaygive
offammoniavapours.Ammoniagasisgenerallynotconsideredaseriousfireor
explosionhazardbecauseammonia/airmixturesaredifficulttoignite.Arelativelyhigh
concentrationofammoniagasmustbepresentinorderforignitiontooccur.However,a
largeandintenseenergysourcemaycauseignitionand/orexplosioninaconfinedspace.
Extinguishing
Media:
Useextinguishingmediamostappropriateforthesurroundingfire.
Section6AccidentalReleaseMeasures
General
Information:
UseproperpersonalprotectiveequipmentasindicatedinSection8.
Spills/Leaks: Absorbspillwithinertmaterial(e.g.vermiculite,sandorearth),thenplaceinsuitable
container.Neutralizespillwithaweakacidsuchasvinegaroraceticacid.Avoidrunoff
intostormsewersandditcheswhichleadtowaterways.Cleanupspillsimmediately,
observingprecautionsintheProtectiveEquipmentsection.Provideventilation.Approach
spillfromupwind.
Section7HandlingandStorage
Handling: Washthoroughlyafterhandling.Removecontaminatedclothingandwashbeforereuse.Do
notgetineyes,onskin,oronclothing.Keepcontainertightlyclosed.Discardcontaminated
shoes.Donotbreathevapor.Useonlywithadequateventilation.
Storage: Donotstoreindirectsunlight.Storeinatightlyclosedcontainer.Storeinacool,dry,well
ventilatedareaawayfromincompatiblesubstances.Corrosivesarea.Isolatefromoxidizing
materialsandacids.Walls,floors,shelving,fittings,lightingandventilationsystemsin
storageareashouldbemadefromcarbonsteelorstainlesssteelwhichdonotreactwith
ammoniumhydroxide.
Section8ExposureControls,PersonalProtection
EngineeringControls:
Useprocessenclosure,localexhaustventilation,orotherengineeringcontrolstocontrol
airbornelevelsbelowrecommendedexposurelimits.Facilitiesstoringorutilizingthis
materialshouldbeequippedwithaneyewashfacilityandasafetyshower.
Exposure
Limits
CAS#1336216:
CAS#7664417:
UnitedKingdom,WELTWA:25ppmTWA(anhydrous)18mg/m3TWA
(anhydrous)UnitedKingdom,WELSTEL:35ppmSTEL(anhydrous)25mg/m3
STEL(anhydrous)
UnitedStatesOSHA:50ppmTWA35mg/m3TWA
BelgiumTWA:20ppmTWA14mg/m3TWABelgiumSTEL:50ppmSTEL36
mg/m3STEL
FranceVME:10ppmVME(restrictivelimit)7mg/m3VME(restrictivelimit)
FranceVLE:20ppmVLCT(restrictivelimit)14mg/m3VLCT(restrictivelimit)
Japan:25ppmOEL17mg/m3OEL
Malaysia:25ppmTWA17mg/m3TWA
Netherlands:50ppmSTEL36mg/m3STELNetherlands:20ppmMAC14mg/m3
MAC
Spain:20ppmVLAED(indicativelimitvalue)14mg/m3VLAED(indicativelimit
value)Spain:50ppmVLAEC(indicativelimitvalue)36mg/m3VLAEC
(indicativelimitvalue)
CAS#7732185:
PersonalProtectiveEquipment
Eyes: Wearchemicalsplashgogglesandfaceshield.
Skin: Wearappropriateglovestopreventskinexposure.
Clothing: Wearappropriateprotectiveclothingtopreventskinexposure.
Respirators: FollowtheOSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN
149.UseaNIOSH/MSHAorEuropeanStandardEN149approvedrespiratorifexposure
limitsareexceededorifirritationorothersymptomsareexperienced.
Section9PhysicalandChemicalProperties
PhysicalState: Liquid
Color: colorless
Odor: strongodorammonialike
pH: 13.6
VaporPressure: 557mmHg@21degC
Viscosity: Notavailable
BoilingPoint: 27degC(80.60F)
Freezing/MeltingPoint: 69degC(92.20F)
AutoignitionTemperature: Notapplicable
FlashPoint: Notavailable
ExplosionLimits:Lower: Notavailable
ExplosionLimits:Upper: Notavailable
DecompositionTemperature: Notavailable
Solubilityinwater: Soluble
SpecificGravity/Density: 0.89
MolecularFormula: NH4OH
MolecularWeight: 35.04
Section10StabilityandReactivity
ChemicalStability: Stableundernormaltemperaturesandpressures.Ammoniumhydroxideis
actuallyasolutionofammoniainwater.Thereforetheflammableproperties
ofammoniaapply.
ConditionstoAvoid: Hightemperatures,confinedspaces,Ammoniasolutionsarecorrosiveto
copper,zinc,aluminumandtheiralloys..
Incompatibilitieswith
OtherMaterials
Strongoxidizingagents,acids,acrolein,halogens,mercury,hypochlorite,
silvernitrate,acrylicacid,dimethylsulfate,silveroxide.
Hazardous
DecompositionProducts
Nitrogenoxides(NOx)andammonia(NH3).
Hazardous
Polymerization
Willnotoccur.
Section11ToxicologicalInformation
RTECS#: CAS#1336216:BQ9625000
CAS#7664417:BO0875000
CAS#7732185:ZC0110000
LD50/LC50: RTECS:
CAS#1336216:Draizetest,rabbit,eye:250ugSevere
Draizetest,rabbit,eye:44ugSevere
Oral,rat:LD50=350mg/kg
.
RTECS:
CAS#7664417:Inhalation,mouse:LC50=4230ppm/1H
Inhalation,mouse:LC50=4600mg/m3/2H
Inhalation,rabbit:LC50=7gm/m3/1H
Inhalation,rat:LC50=2000ppm/4H
Inhalation,rat:LC50=18600mg/m3/5M
Inhalation,rat:LC50=7040mg/m3/30M
Skin,rat:LD50=112000mg/m3/15M
Skin,rat:LD50=71900mg/m3/30M
Skin,rat:LD50=4840mg/m3/60M
.
RTECS:
CAS#7732185:Oral,rat:LD50=>90mL/kg
.
Carcinogenicity: AmmoniumhydroxideNotlistedasacarcinogenbyACGIH,IARC,NTP,orCAProp65.
AmmoniaNotlistedasacarcinogenbyACGIH,IARC,NTP,orCAProp65.
WaterNotlistedasacarcinogenbyACGIH,IARC,NTP,orCAProp65.
Other: SeeactualentryinRTECSforcompleteinformation.
Section12EcologicalInformation
Ecotoxicity: Fish:Rainbowtrout:LC50=0.008mg/L24Hr.Unspecified
Fish:FatheadMinnow:LC50=8.2mg/L96Hr.Unspecified
Fish:Bluegill/Sunfish:LC50=0.0240.093mg/L48Hr.Unspecified
WaterfleaDaphnia:EC50=0.66mg/L48Hr.22degreesC
Section13DisposalConsiderations
ProductsconsideredhazardousforsupplyareclassifiedasSpecialWasteandthedisposalofsuch
chemicalsiscoveredbyregulationswhichmayvaryaccordingtolocation.Contactaspecialistdisposal
companyorthelocalauthorityoradvice.Emptycontainersmustbedecontaminatedbeforereturningfor
recycling.
Section14TransportInformation
IATA IMO RID/ADR
ShippingName: AMMONIASOLUTION AMMONIASOLUTION AMMONIASOLUTION
HazardClass: 8 8 8
UNNumber: 2672 2672 2672
PackingGroup: III III III
USARQ:CAS#1336216:1000lbfinalRQ454kgfinalRQ
USARQ:CAS#7664417:100lbfinalRQ45.4kgfinalRQ
Section15RegulatoryInformation
European/InternationalRegulations
EuropeanLabelinginAccordancewithECDirectives
HazardSymbols:CN
RiskPhrases:
R34Causesburns.
R50Verytoxictoaquaticorganisms.
SafetyPhrases:
S26Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandseekmedical
advice.
S36/37/39Wearsuitableprotectiveclothing,glovesandeye/faceprotection.
S45Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthe
labelwherepossible).
S61Avoidreleasetotheenvironment.Refertospecialinstructions/safetydatasheets.
WGK(WaterDanger/Protection)
CAS#1336216:2
CAS#7664417:2
CAS#7732185:Notavailable
Canada
CAS#1336216islistedonCanada'sDSLList
CAS#7664417islistedonCanada'sDSLList
CAS#7732185islistedonCanada'sDSLList
USFederal
TSCA
CAS#1336216islistedontheTSCA
Inventory.
CAS#7664417islistedontheTSCA
Inventory.
CAS#7732185islistedontheTSCA
Inventory.
Section16OtherInformation
TextforRphrasesfromSection2
MSDSCreationDate: 6/22/1999
Revision#16Date 4/28/2008
Theinformationaboveisbelievedtobeaccurateandrepresentsthebestinformationcurrentlyavailableto
us.However,wemakenowarrantyofmerchantibilityoranyotherwarranty,expressorimplied,with
respecttosuchinformation,andweassumenoliabilityresultingfromitsuse.Usersshouldmaketheirown
investigationstodeterminethesuitabilityoftheinformationfortheirparticularpurposes.Innoeventshall
thecompanybeliableforanyclaims,losses,ordamagesofanythirdpartyorforlostprofitsorany
special,indirect,incidental,consequential,orexemplarydamageshowsoeverarising,evenifthecompany
hasbeenadvisedofthepossibilityofsuchdamages.