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1.
(a)
temperature
/C
b.p. of benzene
0
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(6)
(b)
(i)
All lighter (more volatile) fractions from petroleum distillation are useful as fuels.
Suggest two reasons why the liquid fractions with 8 to 12 carbon atoms per
molecule are used as motor fuels, rather than the gaseous ones containing from one
to four carbon atoms.
..........................................................................................................................
..........................................................................................................................
(2)
(ii)
(iii)
Suggest two reasons why unleaded fuel has been promoted by government and the
petroleum industry.
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(2)
(Total 11 marks)
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2.
Benzene and methylbenzene may be separated by fractional distillation. Sketch the general form
of the boiling point/composition diagram for such a mixture and use it to explain the basis on
which fractional distillation rests.
b.p. of methylbenzene
temperature
/C
b.p. of benzene
0
........................................................................................................................
........................................................................................................................
........................................................................................................................
........................................................................................................................
(6)
3.
(a)
All lighter (more volatile) fractions from petroleum distillation are useful as fuels.
Suggest two reasons why the liquid fractions with 8 to 12 carbon atoms per molecule
are used as motor fuels, rather than the gaseous ones containing from one to four
carbon atoms.
........................................................................................................................
........................................................................................................................
(2)
(b)
Benzene is added to unleaded petrol to compensate for the absence of tetraethyl lead.
Both compounds are hazardous; which hazard is associated with benzene, other than
its flammability?
........................................................................................................................
(1)
(c)
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(d)
Suggest two reasons why unleaded fuel has been promoted by government and the
petroleum industry.
........................................................................................................................
........................................................................................................................
(2)
(Total 7 marks)
4.
(a)
Give the structural formula to show clearly the organic product formed from each of the
following mixtures. If you consider no reaction occurs, you should state no reaction.
(i)
(ii)
(iii)
(iv)
1-bromopropane with
potassium cyanide
(v)
(vi)
(8)
(b)
For each of the four reactions (a)(i)(iv), state what type of reaction is occurring.
Reaction (a)(i) .....................................................................................................
Reaction (a)(ii) .......................................................................................................
Reaction (a)(iii) ......................................................................................................
Reaction (a)(iv) ......................................................................................................
(4)
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(c)
(i)
Give the mechanism for the reaction of hydrogen cyanide with propanal.
(3)
(ii)
If the pH of this reaction mixture is too low or too high, the reaction is very slow.
Explain why in both cases.
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(2)
(Total 17 marks)
5.
CH 3
NH2
OH H
Draw the structures of the organic product(s) which you expect from the reaction
of A with.
(i)
phosphorus pentachloride
(1)
(ii)
(1)
(iii)
ethanoyl chloride
(2)
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(iv)
(1)
(v)
(1)
(b)
(ii)
(iii)
What simple test would you use to determine the purity of your
recrystallised material?
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(2)
(Total 15 marks)
6.
(a)
(ii)
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(iii)
(iv)
(b)
Terylene is a polymer made from ethane 1,2-diol and benzene- 1,4-dicarboxylic acid. It is
a condensation polymer.
(i)
Draw the structural formulae of the two compounds which are used to
make Terylene.
(2)
(ii)
(2)
(iii)
(iv)
Suggest why polyesters are not suitable for use under strongly alkaline conditions.
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(1)
(c)
Suggest why polymers such as Terylene soften over a range of temperatures rather than
having a sharp melting point.
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....................................................................................................................................
(1)
(Total 11 marks)
7.
(b)
(c)
(1)
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(1)
(d)
8.
Terylene is a polymer made from ethane 1,2-diol and benzene- 1,4-dicarboxylic acid. It is a
condensation polymer.
(a)
Draw the structural formulae of the two compounds which are used to make Terylene.
(2)
(b)
(2)
(c)
(d)
Suggest why polyesters are not suitable for use under strongly alkaline conditions.
........................................................................................................................
........................................................................................................................
(1)
(Total 6 marks)
9.
Suggest why polymers such as Terylene soften over a range of temperatures rather than having a
sharp melting point.
......................................................................................................................
..................................................................................................................................
(1)
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