2

nd
Sem, AY 2008-2009
CHEM 17: 2
nd
Long Exam
I. True or False:
1. Strong acid and strong bases have an activity equal to one.
2. All salts have neutral ! equal to ".
#. $oncentrated solutions o% strong acids all have ! equal to 1.
&. 'u%%er caacity is deendent on the ratio o% acid and base comonents o% bu%%er.
(. A bu%%er can be created by only using stoc) !#*+& acid sol,n and -+!.
.. /he ! o% bu%%ers can 0ithstand any amount o% strong acid or base added to them.
". A $aS+& reciitate dissolves less readily in 1.0 1 2a2+# sol,n than in 1.0 1 2a2S+& sol,n.
8. 3n shi%ting equilibrium e4eriment, addition o% !#*+& acid caused the roduction o% more
reciitate.
9. 5aising the temerature o% an equilibrium system moves the equilibrium in the direction that
absorbs heat.
10. /he equilibrium constant %or a reaction has the same value as the equilibrium constant %or its
reverse.
II. Cause and Effect: Write increase, decrease, no effect, indeterminate
$+263/3+2 *A5A17/75
1. A%ter measuring the ! o% a 0.1 1 !#*+& sol,n, the ! meter
0as not rinsed.
! o% the ne4t samle
80.1 1 2a#*+&9
2. /he !+Ac-+Ac bu%%er 0as heated to (0
o
$. ! o% bu%%er
3. Adding 10 m: o% istilled !2+ to a (0 m: saturated $a8+!92
sol,n 80; susended $a8+!92 reciitate9
molar solubility, S
4. <sing mineral !2+ instead o% distilled !2+ to resusend the
$a8+!92 reciitate.
ionic strength
5. /he volume o% 1.0 1 $a82+#92 and 1.0 1 2a+! sol,ns used to
reciitate out $a8+!92 0as doubled.
=m: titrant needed to reach the
endoint
6. !$l 0as added to the $u82!#9&
2>
comle4. intensity o% dee blue solution
7. !$l concentration used %or the titration o% 0.01 1 $2!(2
8yridine9 0as changed %rom 0.1 1 to 0.( 1
? hydrolysis o% salt
8. /he ! o% the $u8+!92 system 0as increased. amount o% reciitate resent
III. Prolem !ol"ing
1.'. 85ecall the Spectrophotometric Keq Determination Experiment)
a. @hy must 0e limit the solutions, both Ae
#>
8aq9 B S$2
-
8aq9 to lo0 concentration valuesC
b. @hy is lo0 ! environment re%erred 0hen rearing the blan), standard B un)no0n
solutionsC
c. Dusti%y 0hy the e4eriment 0ould %ail should the solution be made basic.
2. Aor the dietide used as a s0eetener, 8asartyl-henylalanine-1-methylester9, -a o% asartyl 5
containing E$++! is #.8.. 3t is most stable at ! o% &.#0 0here its hal%-li%e is #00 days. 3n cola drin)s
incororating $+#
2-
B *+&
#-
acid bu%%er constituents, 0hich o% the %ollo0ing may be a suitable media
%or asartameC $hoices areF
8a9 !2$+# B !$+#
-
G -a1 H &.2 4 10
-"
B -a2 H &.8 4 10
-11
8b9 !$+#
-
8c9 !#*+& B !2*+&
-
G-a1 H 2.1#, -a2 H ".21, -a# H 12.#2
8d9 !2*+&
-
+utline stes to reare a 100 m: solution o% &.#0 ! o% 0.10 1 bu%%er. Sho0 calculations or amounts
needed. +nly sodium salts 2a2$+# 8I H 10..09 B 2a#*+& 8I H 1.&.09 are available in stoc) along 0ith
2a+! ellets. 8I H &0.009
JAillF 819 0eigh KKK g o% salt, KKK.
829 dissolve the salt in L1 in (0 m: distilled !2+.
8#9 1easure KKK amount o% 121 !$l.
8&9 Add to (0 m: o% distilled !2+.
8(9 $hec) the ! 0ith a ! meter, then adMust !.